Heterocyclic Developers Patents (Class 430/483)
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Patent number: 7384731Abstract: A method for forming color images comprising subjecting a silver halide color photosensitive material to a development processing in the presence of a compound (A) defined below, wherein the silver halide color photosensitive material having a blue-sensitive unit, a green-sensitive unit and a red-sensitive unit, each of which comprises at least one silver halide emulsion layer, and at least one non-light-sensitive layer on a support, compound (A): a heterocyclic compound having one or two hetero atoms, the heterocyclic compound being capable of increasing speed of the silver halide color photosensitive material by the presence thereof in comparison to the case where the heterocyclic compound is absent.Type: GrantFiled: September 21, 2004Date of Patent: June 10, 2008Assignee: FUJIFILM CorporationInventors: Junichiro Hosokawa, Naoharu Kiyoto, Yoshio Ishii, Takanori Hioki, Katsumi Kobayashi, Takashi Hoshimiya
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Patent number: 7037641Abstract: A silver halide emulsion sheet for detecting track of charged elementary particles, in which emulsion at least one silver halide emulsion layer and at least one hydrophilic protective colloid layer are applied on both surfaces of a transparent support, and a compound selected from benzotriazoles is contained in said at least one silver halide emulsion layer. A processing method for processing the above-described silver halide emulsion sheet with a developer comprising a developing agent represented by formula (A): wherein R1 represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group. A developer for use in developing the above-described silver halide emulsion sheet, comprising a developing agent represented by the above-mentioned formula (A).Type: GrantFiled: May 18, 2005Date of Patent: May 2, 2006Assignee: Fuji Photo Film Co.,Ltd.Inventor: Ken-ichi Kuwabara
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Patent number: 7026490Abstract: The invention relates to luminophores having semiconducting properties and to the production and use thereof in organic luminous diodes (OLEDS) and organic solar cells. The novel materials are easy to prepare and exhibit excellent current density and efficiency when used in organic luminous diodes.Type: GrantFiled: February 7, 2002Date of Patent: April 11, 2006Assignee: Osram Opto Semiconductors GmbHInventors: Horst Hartmann, Arvid Hunze, Andreas Kanitz, Wolfgang Rogler, Dirk Rohde
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Patent number: 6916600Abstract: A silver halide emulsion sheet for detecting track of charged elementary particles, in which emulsion at least one silver halide emulsion layer and at least one hydrophilic protective colloid layer are applied on both surfaces of a transparent support, and a compound selected from benzotriazoles is contained in said at least one silver halide emulsion layer. A processing method for processing the above-described silver halide emulsion sheet with a developer comprising a developing agent represented by formula (A): wherein R1 represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group. A developer for use in developing the above-described silver halide emulsion sheet, comprising a developing agent represented by the above-mentioned formula (A).Type: GrantFiled: September 17, 2002Date of Patent: July 12, 2005Assignee: Fuji Photo Film Co., Ltd.Inventor: Ken-ichi Kuwabara
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Patent number: 6645711Abstract: A silver halide color photographic light-sensitive material containing a compound of the formula: wherein R1, R2 and R3 each represent a hydrogen atom or a substituent; R4 represents an alkyl, aryl or heterocyclic group; R1 and R2, or/and R2 and R4 may combine with each other to form a 5-membered, 6-membered or 7-membered ring; Z represents a group of non-metallic atoms that form a 5-membered, 6-membered or 7-membered ring together with the nitrogen atom and two carbon atoms in the benzene ring; R5 represents an alkyl, aryl or heterocyclic group, in which the compound of the formula contains none of a hydroxyl group, a carboxyl group and a sulfo group in each of R1, R2, R3 and R4.Type: GrantFiled: July 18, 2002Date of Patent: November 11, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Osamu Uchida, Toshio Kawagishi, Masaaki Tsukase, Kazuhiko Matsumoto
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Publication number: 20030162136Abstract: A black-and-white photographic developing composition or developing kit includes an ascorbic acid developing agent and is essentially free of hydroquinone and similar developing agents. The developing composition further includes a water-miscible hydroxy-containing organic solvent having a molecular weight of from about 50 to about 200. The weight ratio of the organic solvent to water is from about 0.1:1 to about 8:1.Type: ApplicationFiled: February 26, 2003Publication date: August 28, 2003Inventors: Paul A. Schwartz, Susan M. Flavin
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Publication number: 20030152876Abstract: A black-and-white photographic developing composition has improved stability and is more compatible with the environment when discarded. The composition includes one or more ascorbic acid developing agents and is essentially free of hydroquinone and similar developing agents. It comprises a mono- or disaccharide such as ribose, fructose, lactose, glucose or galactose as a stabilizing agent for the developing agent.Type: ApplicationFiled: January 23, 2003Publication date: August 14, 2003Inventors: Shirleyanne E. Haye, Janet M. Huston, Jacques Roussilhe
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Publication number: 20030096203Abstract: A silver halide emulsion sheet for detecting track of charged elementary particles, in which emulsion at least one silver halide emulsion layer and at least one hydrophilic protective colloid layer are applied on both surfaces of a transparent support, and a compound selected from benzotriazoles is contained in said at least one silver halide emulsion layer.Type: ApplicationFiled: September 17, 2002Publication date: May 22, 2003Inventor: Ken-ichi Kuwabara
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Publication number: 20030091944Abstract: A black-and-white photographic developing composition or developing kit includes an ascorbic acid developing agent and is essentially free of hydroquinone and similar developing agents. The developing composition further includes a water-miscible hydroxy-containing organic solvent having a molecular weight of from about 50 to about 200. The weight ratio of the organic solvent to water is from about 0.1:1 to about 8:1.Type: ApplicationFiled: November 2, 2001Publication date: May 15, 2003Applicant: Eastman Kodak CompanyInventors: Paul A. Schwartz, Susan M. Flavin
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Patent number: 6489090Abstract: A black-and-white photographic developing composition has improved stability and is more compatible with the environment when discarded. The composition includes one or more ascorbic acid developing agents and a preservative (such as a sulfite) and is essentially free of hydroquinone and similar developing agents. It comprises an &agr;-ketocarboxylic acid stabilizing agent at a molar ratio to the ascorbic acid developing agent of from about 0.05:1 to about 2.5:1, and at a molar ratio to the preservative of from about 0.05:1 to about 6.25:1.Type: GrantFiled: August 21, 2000Date of Patent: December 3, 2002Assignee: Eastman Kodak CompanyInventors: Shirleyanne E. Haye, Janet M. Huston, Jacques Roussilhe, Hugh G. McGuckin
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Patent number: 6444414Abstract: A black-and-white photographic developing composition has improved stability and is more compatible with the environment when discarded. The composition includes one or more ascorbic acid developing agents and a preservative (such as a sulfite) and is essentially free of hydroquinone and similar developing agents. Improved stability is provided using a sulfo-substituted organic compound as a stabilizing agent. Such compounds are either aliphatic sulfo compounds or hydroxy-free aromatic sulfo compounds.Type: GrantFiled: October 20, 2000Date of Patent: September 3, 2002Assignee: Eastman Kodak CompanyInventors: Shirleyanne E. Haye, Janet M. Huston, John S. Badger, Jacques Roussilhe
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Patent number: 6379877Abstract: According to this invention a developer has been disclosed having a low pH value between 9.6 and 11.0, preferably between 9.6 and 10.3, and comprising hydroquinone in an amount from 0 to less than 30 g per liter, an auxiliary developing agent, and as silver halide complexing agents alkali metal sulphite salts, preferably sodium salts, in an amount from 0 to less than 50 g per liter, more preferably to less than 40 g per liter, and thiocyanate salts in amounts from 0.1 to 3 g, more preferably from 0.5 to 2.Type: GrantFiled: January 31, 1996Date of Patent: April 30, 2002Assignee: Agfa-GevaertInventors: Freddy Henderickx, Ann Verbeeck, Pascal Meeus, Hieronymus Andriessen
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Publication number: 20020038860Abstract: A luminescence device exhibiting a better luminescence efficiency is provided by disposing between a pair of electrodes a luminescence layer comprising a mixture of a liquid crystal compound assuming discotic phase or smectic phase with a phosphorescent compound preferably having a planar molecular skeleton.Type: ApplicationFiled: July 16, 2001Publication date: April 4, 2002Inventors: Akira Tsuboyama, Shinjiro Okada, Takao Takiguchi, Takashi Moriyama, Jun Kamatani
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Patent number: 6337177Abstract: Disclosed is a silver halide color photographic material comprising a support, photosensitive silver halide emulsion layers grouped into at least three units according to their color sensitivities, each of which comprises a blue-sensitive, green-sensitive or red-sensitive silver halide emulsion, a color developing agent and a coupler, and a light-insensitive layer, wherein the photographic material has a total silver coverage of at most 5.0 g/m2, and at least one emulsion comprised in the highest-speed emulsion layer of at least one of each unit is a tabular silver halide emulsion that comprises tabular silver halide grains having an average thickness of from 0.05 to 0.20 &mgr;m.Type: GrantFiled: September 3, 1999Date of Patent: January 8, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Makoto Kikuchi
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Color-developing agent, silver halide photographic light-sensitive material and image-forming method
Patent number: 6277994Abstract: There is disclosed a novel color-developing agent of a 1,2,4-thiadiazol-5-yl hydrazine type. There is also disclosed a silver halide photographic light-sensitive material which gives sufficient color formation by development and forms an image excellent in image quality and image storability, by using the color-developing agent. Further, there is disclosed an image-forming method using the light-sensitive material.Type: GrantFiled: March 31, 2000Date of Patent: August 21, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Osamu Uchida, Yasuhiro Ishiwata, Kiyoshi Takeuchi, Taiji Katsumata, Takashi Nakamura -
Patent number: 6130022Abstract: There is disclosed a heat-developable color photographic light-sensitive material having on a base at least a light-sensitive silver halide, a binder, a coupler, and a reducing agent, wherein, as the reducing agent, a co-emulsion comprising at least one silver-developing reducing agent and at least one color-image-forming reducing agent is contained, and the silver-developing reducing agent is a specific sulfonamidophenol compound, and wherein the coupler forms a diffusion dye by reaction with an oxidized product of the color-image-forming reducing agent. The light-sensitive material can secure good discrimination by rapid processing and it is excellent in raw stock storability.Type: GrantFiled: September 7, 1999Date of Patent: October 10, 2000Assignee: Fuji Photo Film Co., Ltd.Inventor: Hideaki Naruse
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Patent number: 6110655Abstract: Low silver black-and-white photographic elements, such as radiographic films, can be processed quickly using black-and-white developing and fixing compositions having reduced photoprocessing activity. The entire process is fairly rapid and effective despite the lowered concentrations of photographic developing and fixing agents. The processing compositions are more environmentally friendly because the conventional hydroquinone is replaced with an ascorbic acid developing agent. In addition, the processing compositions are free of ammonium ions.Type: GrantFiled: October 26, 1999Date of Patent: August 29, 2000Assignee: Eastman Kodak CompanyInventors: Alan S. Fitterman, Robert E. Dickerson
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Patent number: 6083673Abstract: The present invention concerns an organic/inorganic developer composition comprising a regeneratable iron chelate, novel codevelopers of the phenidone type including one or more solubilizing groups that are not directly attached to the phenyl nucleus or to the pyrazolidino nucleus and optionally ascorbic acid. These compositions are particularly useful for the black-and-white development of films or photographic papers, in particular for the fast development of radiographic products.Type: GrantFiled: March 31, 1998Date of Patent: July 4, 2000Assignee: Eastman Kodak CompanyInventors: Jacques Roussilhe, Siu Chung Tsoi
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Patent number: 6077652Abstract: A photographic developer which is improved in storage stability is disclosed, comprising a developing agent represented by formula (1) and a compound represented by formula (2). ##STR1## wherein R.sub.1 are ##STR2## R.sub.2 and R.sub.3 independently are a hydrogen atom or an alkaline metal atom;formula (2)M.sub.n HAO.sub.3wherein M is a univalent or bivalent atom and A is an atom of the 5B group of the periodic table, except for N.Type: GrantFiled: April 23, 1998Date of Patent: June 20, 2000Assignee: Konica CorporationInventor: Yuji Hosoi
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Patent number: 6013421Abstract: There is disclosed a silver halide photographic light-sensitive material containing a color-developing agent of formula (I) and a coupler of formula (II), in at least one photographic constitutional layer: ##STR1## In formula (I), Z is a carbamoyl, acyl, alkoxycarbonyl, or aryloxycarbonyl group, and Q is a group of atoms that, together with the C, form an unsaturated ring. In formula (II), Cp is a coupler residue, Time is a group that releases PUG upon released from Cp by coupling reaction, PUG is a photographically useful group, and t is 0, 1, 2, or 3. There is also disclosed a silver halide photographic light-sensitive material containing a color-developing agent of formula (I), a dye-forming coupler, and a non-dye-forming coupler (that is unsubstituted on its active site), in at least one photographic constitutional layer. There is further disclosed methods for forming an image using the light-sensitive materials.Type: GrantFiled: July 18, 1997Date of Patent: January 11, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Koki Nakamura, Kazuhiko Matsumoto
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Patent number: 5998112Abstract: A photographic developer composition is disclosed, comprising a reductone, as a developing agent and a compound represented by the following formula (1). The reductone is a compound represented by following formula (A). The processing method by use of the developer composition is also disclosed.Type: GrantFiled: April 27, 1998Date of Patent: December 7, 1999Assignee: Konica CorporationInventor: Hirobumi Yamashita
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Patent number: 5998110Abstract: A black-and-white aqueous alkaline photographic developer composition is described which is free of dihydroxybenzene developing agent and comprises a p-aminophenol primary developing agent and an auxiliary superadditive 3-pyrazolidone developing agent, wherein the p-aminophenol primary developing agent is represented by the following formula: ##STR1## wherein R.sub.1, and R.sub.2, which may be the same or different, each represents a hydrogen atom, an alkyl group, or R.sub.1, and R.sub.2 together represent the carbon atoms required to complete a 5-membered saturated ring, R.sub.3 represents a hydrogen atom, an alkyl group or an alkoxy group, n represents 0 or 1, and HX represents HCl or 1/2 H.sub.2 SO.sub.4.A process for forming a black-and-white photographic silver image comprising developing a silver halide photographic element with the black-and-white aqueous alkaline photographic developer composition is also described.Type: GrantFiled: November 6, 1997Date of Patent: December 7, 1999Assignee: Ferrania S.p.A.Inventor: Filippo Faranda
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Patent number: 5994040Abstract: A processing composition for silver halide photographic light-sensitive material, which comprises at least one compound represented by the following formula (A), (A-I) or (A-II) and at least one compound represented by the following formula (B): ##STR1## Also disclosed are a developer prepared from the processing composition, and a processing method using the developer.Type: GrantFiled: March 4, 1997Date of Patent: November 30, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinnichi Morishima, Kohzaburoh Yamada, Seiji Yamashita, Minoru Sakai, Kouta Fukui, Eiichi Okutsu
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Patent number: 5976756Abstract: A diffusion transfer silver halide photographic material containing a color developing agent represented by the following formula (I) in a hydrophilic colloid layer provided on a support: ##STR1## wherein C.sub..alpha. represents a carbon atom; Z represents a carbamoyl group, an acyl group, an alkoxycarbonyl group, or an aryloxycarbonyl group; and Q represents an atomic group for forming a unsaturated ring together with C.sub..alpha., whereby a color diffusion transfer silver halide photographic material containing a novel color developing agent from which a diffusible dye can be formed is provided.Type: GrantFiled: November 29, 1996Date of Patent: November 2, 1999Assignee: Fuji Photo Film, Co., Ltd.Inventors: Koki Nakamura, Kiyoshi Takeuchi, Taiji Katsumata, Toshiki Taguchi
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Patent number: 5972584Abstract: A class of pyrazolidone compounds suitable for use as electron transfer agents in photographic development comprises pyrazolidones substituted in the 1-position by an aromatic group that is substituted in the ortho, meta or para position by --O--CO--R, wherein R is a monovalent organic group having up to 24 carbon atoms. This ester group is hydrolyzable in an alkaline developer solution, thereby deactivating the electron transfer agents after a period of time and reducing the contamination effect of seasoning into the developer solution. Photographic recording materials can be developed in reactive association with the electron transfer agent. The electron transfer agent can be present in the photographic recording materials, or in develper solutions.Type: GrantFiled: February 23, 1999Date of Patent: October 26, 1999Assignee: Eastman Kodak CompanyInventors: Siu C. Tsoi, Peter J. Twist
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Patent number: 5962200Abstract: A method for forming a color image comprising developing an image-wise exposed silver halide color photographic photosensitive material in the presence of certain 6-aminotetrahydroquinoline color developing compounds or analogues thereof. A rapid process can be attained and an image of a low fog density can be obtained.Type: GrantFiled: July 15, 1997Date of Patent: October 5, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Masato Taniguchi, Kiyoshi Morimoto, Keizo Kimura, Kazumi Nii, Shigeo Hirano
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Patent number: 5942379Abstract: The present concerns compounds of the 3-pryazolidone type comprising solubilizing groups which are not directly attached to the phenyl ring or to the pyrazolidino ring. These compounds can be used as co-developing agents in the development of black and white photographic products.Type: GrantFiled: January 21, 1998Date of Patent: August 24, 1999Assignee: Eastman Kodak CompanyInventors: Jacques Roussilhe, Siu C. Tsoi
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Color-developing agent, silver halide photographic light-sensitive material and image-forming method
Patent number: 5874203Abstract: There is disclosed novel color-developing agents of the formula (I). There is also disclosed silver halide photographic light-sensitive materials and image-forming methods, using the color-developing agent. The color-developing agent is excellent in color-forming property, and the image obtained from the color-developing agent is good in hue. ##STR1## wherein R.sub.1 to R.sub.4 each represent a group of nonmetal atoms required to form, together with the carbon atom, a monocyclic 5-membered aromatic ring or a 5-membered aromatic ring condensed with another ring, with the proviso that at least two of R.sub.1 to R.sub.4 are nitrogen atoms; and Z represents an acyl group, a carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group, a sulfamoyl group, an amidino group, or an imidoyl group.Type: GrantFiled: November 26, 1996Date of Patent: February 23, 1999Assignee: Fuji Photo Film, Co., Ltd.Inventors: Kensuke Morita, Hiroo Takizawa, Taiji Katsumata -
Patent number: 5871880Abstract: There is disclosed a silver halide color photographic light-sensitive material having at least one photographic constitutional layer coated on a support, wherein at least one of the photographic constitutional layers contains at least one reducing agent for color formation represented by formula (I), at least one coupler for forming a diffusive dye, and at least one mordant. The material is capable of reducing the amount of developer and to be replenished or discharged after processing, and of reducing the occurrence of stain after development during storage of the material. There is also disclosed an image-forming method using the material. ##STR1## wherein C.alpha. represents a carbon atom; Z represents a carbamoyl, acyl, alkoxycarbonyl, or aryloxycarbonyl group; and Q represents a group of atoms to form, together with C.alpha., an unsaturated ring.Type: GrantFiled: November 26, 1996Date of Patent: February 16, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiyuki Makuta, Koki Nakamura
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Patent number: 5840472Abstract: A developer for a silver halide photographic photosensitive material containing at least one of monocyclic dimercaptotriazine compounds, bis-type dimercaptotriazine compounds, mercapto-1,2,4-triazine compounds and dimercaptopyrimidine compounds, and a process for developing a silver halide photographic photosensitive material using the developer. The compounds of the present invention provides excellent effect in preventing silver stains without affecting the photographic properties of the photographic material.Type: GrantFiled: February 7, 1997Date of Patent: November 24, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirotomo Sasaki, Harumi Watanabe, Kohzaburoh Yamada
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Patent number: 5837434Abstract: The invention concerns a developer solution for processing silver halide photographic products. This developer solution contains an ascorbic acid developing agent, a auxiliary developing agent which is a substituted phenidone and a development accelerator which is a thioether having an ammonium group, a triazolium thiolate or a substituted thioalkane.Type: GrantFiled: September 25, 1997Date of Patent: November 17, 1998Assignee: Eastman Kodak CompanyInventors: Jacques Roussilhe, Siu-Chung Tsoi
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Patent number: 5834171Abstract: A solid processing composition for developing a silver halide black-and-white photographic light sensitive material containing a compound represented by the following formula as a developing agent, in which a metabisulfite, or the metabisulfite and a sulfite is contained in an amount of 1 to 50% by weight of the composition, a molar ratio of the sulfite to the metabisulfite being not more than 0.85.Type: GrantFiled: January 10, 1997Date of Patent: November 10, 1998Assignee: Konica CorporationInventors: Tetsuya Suzuki, Akira Shimizu, Kenji Ishida, Hiroshi Yamashita
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Patent number: 5824458Abstract: A one-part liquid developer for a black and white silver halide photographic material, comprising:i) an ascorbic acid or derivative thereof as a developing agent,ii) an auxiliary developing agent having super-additivity,iii) an alkali agent necessary for giving a pH of about 9, andiv) a compound for enhancing development.Type: GrantFiled: May 19, 1997Date of Patent: October 20, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Eiichi Okutsu, Rikio Inoue
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Patent number: 5821041Abstract: The invention provides a liquid developer for photographic silver halide photosensitive material comprising a silver halide emulsion layer containing at least 50% based on the projected area of tabular silver halide grains with an aspect ratio of at least 3.0 and having a swelling factor of 130-250%. In the liquid developer containing ascorbic acid or a derivative thereof as a developing agent or preservative, a compound of formula (I): ##STR1## wherein each of R.sub.1 and R.sub.2 is a C1-C3 hydroxyalkyl group or C1-C3 alkyl group and R.sub.3 is a C1-C3 hydroxyalkyl group is added for preventing the developer from coloring with the lapse of time.Type: GrantFiled: December 31, 1996Date of Patent: October 13, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Eiichi Okutsu, Shigeo Hirano, Kazue Sano
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Patent number: 5821040Abstract: Disclosed is a method for developing a silver halide photographic material, which comprises processing the silver halide photographic material having at least one silver halide emulsion layer containing silver halide grains, with a substantially hydroquinone-free developing solution containing (i) a compound represented by formula (A) as a developing agent, wherein at least 50% of the sum of the projected area of the silver halide grains are tabular silver halide grains having an aspect ratio of 3.0 or more, and said developing solution contains (ii) a compound represented by formula (B): ##STR1## wherein R.sub.1 represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; and ##STR2## wherein X represents an oxygen atom or a sulfur atom, Y represents a hydrogen atom or a substituent group, and M represents a hydrogen atom, an alkali metal ion, a quaternary ammonium ion or a quaternary phosphonium ion.Type: GrantFiled: June 21, 1996Date of Patent: October 13, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Eiichi Okutsu, Shinnichi Morishima
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Patent number: 5804358Abstract: A solid developing composition for a silver halide black-and-white photographic light sensitive material is disclosed, comprising a developing agent selected from the group consisting of a dihydroxybenzene compound and a compound represented by formula (A), and the developing composition further comprising a compound represented by formula (1). ##STR1##CH.sub.3 (CH.sub.2).sub.n --(O).sub.m SO.sub.Type: GrantFiled: November 25, 1996Date of Patent: September 8, 1998Assignee: Konica CorporationInventors: Hideki Komatsu, Shoji Nishio
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Patent number: 5780212Abstract: The present invention concerns a developer for silver halide photographic products comprising a co-developing agent of the 1-phenyl-3-pyrazolidinone type. These co-developing agents comprise solubilizing groups which are not attached directly to the phenyl ring or the pyrazolidine ring, and improve the stability of the developer composition.Type: GrantFiled: June 24, 1997Date of Patent: July 14, 1998Assignee: Eastman Kodak CompanyInventors: Jacques Roussilhe, Siu C. Tsoi
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Patent number: 5773203Abstract: Disclosed are 4-(N,N-dialkylamino)aniline compounds having a 4-N substituent which is a polyethyleneoxy group and which forms a condensed ring with benzene ring, such as aniline compounds having the following structure, a processing composition containing such a compound and a method for forming a color image with the processing solution. The aniline compound is useful as a color developing agent capable of having a low fog density and sufficient yellow and cyan image densities and suitable for the rapid process.Type: GrantFiled: May 14, 1997Date of Patent: June 30, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Keizo Kimura, Shigeo Hirano, Hiroshi Kawamoto
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Patent number: 5770351Abstract: There is described a method of processing silver halide photographic material in a processing machine using a developing solution which comprises either a hydroquinone type developing agent or a reductone type developing agent, together with an electron transfer agent as an auxiliary developing agent, and with at least one basic compound the anion of which is carbonate, sulphite or hydroxide, where in the presence of a compound of formula (I), Ar is an aromatic ring or heterocyclic aromatic ring which is optionally substituted.Type: GrantFiled: August 15, 1997Date of Patent: June 23, 1998Assignee: Ilford LimitedInventors: William Edward Long, Michael John Parker
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Patent number: 5766833Abstract: An image-forming process developing a previously image-exposed silver halide photographic material with an alkaline developer containing a reductone compound as a main developing agent in the presence of a 1,2,5-thiadiazole compound and/or a 2,1,3-benzothiadiazole compound, and the silver halide photographic material and the photographic developer being used for the process are disclosed. In this case, the 1,2,5-thuiadiazole compound and/or the 2,1,3-benzothiadiazole may be contained in the silver halide photographic material and/or the alkaline developer. Super high-contrast images for photomechanical process having a gamma of higher than 15 and having no pepper and less fog can be obtained.Type: GrantFiled: July 8, 1997Date of Patent: June 16, 1998Assignee: Dainippon Ink and Chemicals Inc.Inventors: Kiyoshi Suematsu, Hiroaki Muratake, Haruhiko Kaji, Naoki Obi, Yasuhiko Kojima, Yasuo Shigemitsu
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Patent number: 5766832Abstract: A solid processing composition in the form of granules or a tablet for use as a replenisher of a developer for processing a silver halide black-and-white photographic light sensitive material is disclosed, wherein the solid processing composition is substantially free from a dihydroxybenzene as a developing agent and comprises a cyclodextrin compound.Type: GrantFiled: September 20, 1996Date of Patent: June 16, 1998Assignee: Konica CorporationInventor: Shoji Nishio
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Patent number: 5756271Abstract: A black-and-white developing composition includes as ascorbic acid developing agent, an auxiliary super-additive developing agent, borate buffer and a preservative. The composition pH is from 7 but less than 9. The composition can be formulated from two separately packaged parts that may be in dry or liquid form. The borate buffer is present to maintain the desired pH, and the two developing agents are present in desired molar ratios for optimal developing activity. Improved photographic properties are obtained while avoiding the use of environmentally unfriendly dihydroxybenzenes.Type: GrantFiled: May 27, 1997Date of Patent: May 26, 1998Assignee: Eastman Kodak CompanyInventors: Robert John Opitz, Silvia Zawadzki
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Color-developing agent, silver halide photographic light-sensitive material and image-forming method
Patent number: 5756275Abstract: There is disclosed novel color-developing agents of the formula (I-1), (I-2), (1-3), or (1-4). There is also disclosed silver halide photographic light-sensitive materials and image-forming methods, using the color-developing agent. ##STR1## wherein R.sup.1 represents a halogen atom or an aliphatic group substituted with at least one halogen atom; R.sup.2 represents a substituent; L represents --CONR.sup.4 --, --COO--, --CO--, --SO.sub.2 NR--, --C(.dbd.NR.sup.4)NR.sup.5 --, or --C(.dbd.NR.sup.4)O--; R.sup.3, R.sup.4, and R.sup.5 each independently represent a hydrogen atom, an aliphatic, aryl, or hererocyclic group; in formula (I-1), n is 1 or 2, m is 0 or 1, and the sum of n and m is 1 or 2; in formulae (I-2) to (I-4), n is 1 to 3, m is 0 to 2, and the sum of n and m is 1 to 3. R.sup.1 and R.sup.2, R.sup.1 and R.sup.1, and R.sup.2 and R.sup.2, respectively, do not bond together to form any ring. R.sup.Type: GrantFiled: November 26, 1996Date of Patent: May 26, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroo Takizawa, Taiji Katsumata, Toshiyuki Makuta, Toshiki Taguchi -
Patent number: 5747229Abstract: A solid developing composition for processing a silver halide photographic light sensitive material is disclosed which contains a compound represented by the following formula (1) and a compound represented by the following formula (2): formula (1) ##STR1## formula (2) ##STR2##Type: GrantFiled: January 30, 1997Date of Patent: May 5, 1998Assignee: Konica CorporationInventor: Takuji Hasegawa
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Patent number: 5738979Abstract: A photographic silver halide element, such as a radiographic film, can be developed using a black-and-white developing solution containing an ascorbic acid developing agent. This solution is replenished with a replenisher solution of basically the same components but the amounts may be greater. Moreover, the replenisher solution pH is from 0.1 and up to 0.3 pH units higher than that of the developing solution. Both developing and replenisher solutions are free of hydroquinone. Replenishment can be carried out at relatively low rates with less impact on the environment without sacrificing sensitometric performance.Type: GrantFiled: January 6, 1997Date of Patent: April 14, 1998Assignee: Eastman Kodak CompanyInventors: Alan S. Fitterman, Franklin C. Brayer, Joan F. Rachel
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Patent number: 5721093Abstract: A method for forming a color image comprises the step of developing an image-wise exposed silver halide color photographic photosensitive material at the presence of the following color developing agent or its analogue. According to this method, the rapid process can be attained, forming an image having only a slight fog, sufficient yellow and cyan image densities and a high image fastness.Type: GrantFiled: March 6, 1996Date of Patent: February 24, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Keizo Kimura, Shigeo Hirano
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Patent number: 5721094Abstract: A method of processing an exposed silver halide photographic light sensitive material is disclosed which comprises the steps of:developing the exposed material with developer, the developer being replenished with developer replenisher and the developer containing no dihydroxy benzene and containing a developing agent represented by the following Formula ?1!: ##STR1## wherein R.sub.1 and R.sub.2 independently represent an alkyl group, an amino group, an alkoxy group or an alkylthio group, or R.sub.1 and R.sub.2 combine with each other to form a ring, k represents 0 or 1, and X represents --CO-- or --CS--;fixing the developed material;stabilizing the fixed material with a washing water which is replenished with water replenisher in a replenishing amount of 0.5 to 2 liter/m.sup.2 or with a rinsing solution which is replenished with a rinsing replenisher in a replenishing amount of 0 to 2 liter/m.sup.2 ; anddrying the stabilized material.Type: GrantFiled: August 14, 1996Date of Patent: February 24, 1998Assignee: Konica CorporationInventors: Hideki Komatsu, Shoji Nishio
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Patent number: 5707786Abstract: By means of a development intensification process for processing color photographic silver halide materials, the silver halide emulsions of which contain more than 90 mol. % of AgCl and less than 0.8 g of silver halide per m.sup.2 (stated as the equivalent quantity of AgNO.sub.3), short processing times accompanied by stable replenishment rates are obtained if at least one compound of the formulae (I), (II) or (III) is used as the developer substance in a quantity of 0.002 to 0.04 mol/l of developer solution ##STR1## in which R.sub.1 to R.sub.3, R.sub.10 to R.sub.17, R.sub.21 to R.sub.23, m, n and Y have the meaning stated in the specification.Type: GrantFiled: July 8, 1996Date of Patent: January 13, 1998Assignee: Agfa-GevaertInventors: Arno Schmuck, Jorg Hagemann, Norman Klaunzer
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Patent number: H2048Abstract: A non-hydroquinone photographic developer composition comprising: (a) a developer selected from the group consisting of ascorbic acid and sugar-type derivatives thereof, or alkali metal salts and mixtures thereof, in an amount of 0.1 to 0.4 mol/liter (mol/l); (b) an effective amount of an auxiliary developing agent comprising a 3-pyrazolidone compound, an aminophenol or a mixture thereof; (c) an alkali metal sulfite in an amount less than or equal to 0.32 mol/l; (d) an alkali metal carbonate in an amount of 0.1 to 0.4 mol/l; (e) an alkali metal hydroxide in an amount of from 0.08 to 2.0 mols/l; (f) with the developer composition having a pH of 11.8 or higher at 25° C.Type: GrantFiled: February 14, 1995Date of Patent: September 3, 2002Assignee: Fuji Hunt Photographic Chemicals, Inc.Inventors: Haixing Wan, Diane Zhang, David Carlson, Alan A. Bornstein
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Patent number: RE36384Abstract: The invention comprises a process for forming a high contrast photographic image including the steps of imagaewise exposing a silver halide photographic element containing a hydrazine compound which functions as a nucleating agent, wherein the element is free of incorporated amine boosters. The exposed element is developed with a chemically stable aqueous alkaline developing solution that is free of dihydroxybenzene developing agents and has a pH between 9.5 and 11. The developing solution comprises an ascorbic acid developing agent; an auxiliary developing agent; and a combination of an alkali metal carbonate and an alkali metal borate comprising between 0.125 and 0.5 molar concentration of the carbonate and between 0.04 and 0.35 molar concentration of the borate.Type: GrantFiled: November 17, 1997Date of Patent: November 9, 1999Assignee: Kodak Polychrome Graphics, LLCInventors: John L. Adkins, Dinesh P. Patel