Hydroxy Developer Patents (Class 430/485)
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Patent number: 4774167Abstract: A method for processing a silver halide color photographic material is provided, which comprises subjecting an imagewise exposed silver halide color photographic material having at least one silver halide emulsion layer on a reflective support to color development for a period not exceeding 2 minutes and 30 seconds using a color-developing solution containing substantially no benzyl alcohol, a sulfite in a concentration of 8.times.10.sup.-3 mol/liter or less, and a hydroxylamine in a concentration of 1.5.times.10.sup.-2 mol/liter or less, thereby achieving high color densities of the developed images and reduced fog. The effects of this method are particularly significant in photographic paper containing a pyrazoloazole type magenta coupler.Type: GrantFiled: February 24, 1987Date of Patent: September 27, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshio Koshimizu, Takatoshi Ishikawa, Shinji Ueda
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Photographic silver halide developer compositions and process for forming photographic silver images
Patent number: 4756997Abstract: An aqueous alkaline photographic silver halide developer composition comprising a dihydroxy benzene developing agent, an auxiliary superadditive developing agent, an antifogging agent, an antioxidant and a buffering agent, characterized by the fact that the composition further comprises a stabilizing amount of an .alpha.-ketocarboxylic acid.The developer composition has a better resistance against air oxidation and can be left in continuous transport automatic processors for several days without undergoing any substantial decrease of its developing properties.The developer composition is particularly useful in a process for the formation of a high contrast silver image by developing silver halide photographic elements including at least a negative acting surface latent image type silver halide emulsion in the presence of a hydrazine compound, preferably in the additional presence of an effective amount of a contrast promoting agent.Type: GrantFiled: July 21, 1987Date of Patent: July 12, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventor: Carlo Marchesano -
Patent number: 4738917Abstract: A method for processing a silver halide photographic material by processing a silver halide color photographic light-sensitive material containing at least a silver halide emulsion layer comprising a silver halide grain essentially consisting of silver chlorobromide and a binder having a swelling rate of T 1/2 of 2 sec. to 30 sec. The color developer contains a n-hydroxyalkyl-p-phenylenediamine derivative at a temperature not less than 30.degree. C. for a time not more than 150 sec. The time and temperature are effective to process the silver halide color photographic light-sensitive material without decreasing the stability of the resulting dye image.Type: GrantFiled: May 15, 1986Date of Patent: April 19, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Shigeharu Koboshi, Satoru Kuse, Kazuhiro Kobayashi, Masao Ishikawa, Masayuki Kurematsu
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Patent number: 4699868Abstract: An alkaline aqueous tanning developing solution for photographic image development comprising at least one hydroxylamine derivative. Preferred formulations may also contain at least one water-miscible polyhydroxy aliphatic organic solvent and/or a developing agent which comprises a polyhydroxybenzene compound having at least two hydroxy groups and at least one electron withdrawing and good leaving group suitable for nucleophilic addition.Type: GrantFiled: August 18, 1986Date of Patent: October 13, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventor: Gebran J. Sabongi
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Patent number: 4636456Abstract: A process for forming photographic image is disclosed, comprising photographically developing, in the presence of a polyalkylene oxide compound, a silver halide photographic light-sensitive material including at least one silver halide emulsion layer and containing in at least said emulsion layer or other hydrophilic layer a compound represented by formula (I). ##STR1## wherein: A and A' each represents a hydrogen atom or an alkalihydrolyzable group;R.sub.1, R.sub.2, and R.sub.3 each represents a group capable of substituting a hydrogen atom on the hydroquinone nucleus, with R.sub.2 and R.sub.3, A and R.sub.1, or A and R.sub.2 together form a ring; andX represents a group which shows a development-inhibiting effect after being released.Type: GrantFiled: May 7, 1985Date of Patent: January 13, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiro Takahashi, Koki Nakamura
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Patent number: 4632896Abstract: There is disclosed a processing solution for silver complex diffusion transfer process which contains at least one amino alcohol having a pKa value of less than 9 and at least one amino alcohol having a pKa value of 9 or more which are measured in a 50 wt % aqueous ethanol solution at 25.degree. C.Type: GrantFiled: September 10, 1985Date of Patent: December 30, 1986Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Yasuo Tsubai, Koji Okazaki
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Patent number: 4598040Abstract: There is provided a developer for use in a one-step process for the development of exposed film resulting in an exposurewise pattern of silver particles which are large enough to be used as printing elements in ink-printing techniques, providing a wide range of densities in the developed film. The developer is based on a buffered system of a developing agent, a sulfinic acid salt of the type HO-R-SO.sub.2.M..times.H.sub.2 O where R is a hydrocarbyl group and M is a cation, and a formaldehyde source, with conventional adjuvants such as anti-fogging agents and the like. Instead of the sulfinic acid salt defined above there may be used any compound which upon dissociation in a aqueous medium results in the same active ionic species.Type: GrantFiled: September 12, 1983Date of Patent: July 1, 1986Inventors: Yoel Netz, Arnold Hoffman
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Patent number: 4587210Abstract: A color photographic silver halide light-sensitive material is described, characterized by containing at least one of the compounds represented by the general formula (I) and their precursors. ##STR1## wherein R represents ##STR2## (wherein R.sub.1 and R.sub.2 are each a hydrogen atom or an alkyl group and may combine with R.sub.3 to form a ring having 5 to 10 carbon atoms, provided that R.sub.1 and R.sub.2 are not hydrogen atoms at the same time, R.sub.3 is a substituted or unsubstituted aryl group, and n is an integer of 1 to 4), and R' has 1 to 20 carbon atoms and represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituent defined by R as defined above). This light-sensitive material provides color images which are stabilized, i.e., freed of fading and the discoloration of the white ground.Type: GrantFiled: March 30, 1984Date of Patent: May 6, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Michio Ono, Masakazu Morigaki, Takayoshi Kamio, Kozo Aoki, Kazuhiko Furuya
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Patent number: 4546069Abstract: The processing time of exposed photographic silver dye bleach materials is shortened by using a bleach preparation which contains a strong acid, a water-soluble iodide, a water-soluble organic nitro compound, an anti-oxidizing agent, a bleach catalyst, an organic photographic developing agent and/or a benzotriazole derivate.Type: GrantFiled: July 18, 1984Date of Patent: October 8, 1985Assignee: Ciba-Geigy AGInventors: Arnost Libicky, Meinrad Schar
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Patent number: 4542086Abstract: A color diffusion transfer photographic element comprising (a) a light sensitive component containing at least one light sensitive silver halide emulsion layer associated with a dye releasing redox compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b) and (c) containing a diffusible hydroquinone type compound having the half wave potential of polarography in the range of from -300 mV to -380 mV measured using a saturated calomel electrode as a reference electrode in a buffer solution having a pH of 13.0.degree. at 25.degree. C. The diffusible hydroquinone type compound has excellent gradation control properties and is particularly suitable for controlling gradation of the toe part in a photographic characteristic curve of a color diffusion transfer photograph.Type: GrantFiled: May 26, 1981Date of Patent: September 17, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobutaka Ohki, Motohiko Tsubota, Masakazu Morigaki, Tsutomu Hamaoka
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Patent number: 4540655Abstract: A method of processing a direct positive silver halide photographic light-sensitive material which comprises processing a direct positive silver halide photographic light-sensitive material comprising a support having coated thereon at least one hydrophilic colloid layer containing a compound represented by the following general formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an unsubstituted or substituted aryl group or an unsubstituted or substituted alkyl group; and R.sup.2 represents a hydrogen atom, an unsubstituted or substituted aryl group or an unsubstituted or substituted alkyl group, with a developing solution containing not less than 25 g per liter of a hydroquinone and having a pH of from 11.0 to 13.0. According to the processing method an excellent reversal photographic image can be obtained using a high pH type developing solution which is stable wherein a change of pH due to exhaustion and aerial oxidation is considerably small.Type: GrantFiled: October 11, 1984Date of Patent: September 10, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshihiro Takagi, Shigeo Hirano, Tadao Sugimoto
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Patent number: 4533622Abstract: A photographic element for a color diffusion transfer process comprising a support having thereon at least one silver halide emulsion layer and associated therewith a non-diffusible redox compound capable of releasing a diffusible dye or a precursor thereof as the result of treatment with an alkaline processing solution in the presence of a silver halide developing agent after exposure to light, the alkaline processing solution containing a compound represented by the following general formula (I): ##STR1## wherein R represents an alkyl group, an alkoxy group, an aromatic group or an alkylthio group, and each of these groups has 12 or less carbon atoms; and M represents a cation.Type: GrantFiled: April 9, 1984Date of Patent: August 6, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Osamu Takahashi, Mitsugu Tanaka
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Patent number: 4481286Abstract: Novel compounds which are capable of forming a coordination complex with a metal and which include a silver halide developing substituent or a precursor thereof. The compounds are useful as silver halide developing agents and as intermediates for dye developers which are utilized in photographic applications.Type: GrantFiled: October 29, 1982Date of Patent: November 6, 1984Assignee: Polaroid CorporationInventors: Patrick F. King, Stephen G. Stroud
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Patent number: 4429031Abstract: A color diffusion transfer photographic element is disclosed, comprising (a) a photosensitive component containing at least one photosensitive silver halide emulsion layer combined with a DRR compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b), and (c) containing a compound represented by the formula (I) ##STR1## wherein R represents a substituted or unsubstituted alkyl group having from 1 to 18 carbon atoms.Type: GrantFiled: October 3, 1980Date of Patent: January 31, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Motohiko Tsubota, Masakazu Morigaki, Tsutomu Hamaoka, Nobutaka Ohki
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Patent number: 4420557Abstract: Compounds corresponding to the formula: ##STR1## wherein R.sup.1 represents an aromatic group, andR.sup.2 represents H, alkyl, alkenyl, aryl or acyl, are suitable ED precursor compounds for use in color photographic recording materials. They are preferably used in combination with reducible dye releasers. They are also suitable as so-called scavengers.Type: GrantFiled: October 25, 1982Date of Patent: December 13, 1983Assignee: Agfa-Gevaert AktiengesellschaftInventors: Heinrich Odenwalder, Paul Marx
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Patent number: 4383023Abstract: A gelatino-silver halide film is exposed and then developed with a tanning developer bearing a positively or negatively charged substituent, e.g., a quaternary amine-substituted hydroquinone, to produce a charged matrix in the gelatin. To enhance the image the film is then processed to mordant an oppositely charged species, e.g., an anionic dye, to the charged matrix.Type: GrantFiled: October 1, 1981Date of Patent: May 10, 1983Assignee: E. I. Du Pont de Nemours and CompanyInventor: Frank L. Schadt, III
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Patent number: 4383028Abstract: A photographic chemistry comprised of a solution containing a mixture of different chemicals which cooperate to minimize the need for long film exposure times to achieve high film quality and contrast. The photographic chemistry includes a number of alkalies in a pH range from about 8 to 14, a developer in solution with the alkalies, a solvent mixed with the alkalies and the developer, a modified alkanolamide in solution with the alkalies, the developer and the solvent, and a hydrotrope mixed with the modified alkanolamide. Other chemicals that can be used in the photographic chemistry include an emulsion penetrant, a cleaner for various components of film processing equipment, a chelating agent, and an enzyme to enhance the reactions of the various chemicals in the photographic chemistry. A specific mixture of chemicals is disclosed.Type: GrantFiled: August 3, 1981Date of Patent: May 10, 1983Assignee: Lorin W. BootsInventor: Byron R. Boots
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Patent number: 4366234Abstract: Photographic solutions containing hydroquinone monosulphonate are prepared by a process comprising forming hydroquinone monosulphonate by reacting in solution hydroquinone, a salt of sulphurous acid and hydrogen peroxide. The reaction may be effected in the presence of one or more chemicals required for a photographic developer or after the formation of hydroquinone monosulphonate such material may be added. The invention is useful for making sodium or potassium hydroquinone monosulphonate and may be used in the preparation of a first developer for processing color reversal film, such as by the Kodak E6 process.Type: GrantFiled: May 29, 1981Date of Patent: December 28, 1982Assignee: Staveley Chemicals LimitedInventors: John B. Wheatcroft, Edward N. Wall
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Patent number: 4332878Abstract: A photographic image-forming method comprising imagewise exposing a silver halide photographic light-sensitive element containing a specific hydroquinone derivative in the silver halide emulsion layer of substantially the surface latent image type or at least one hydrophilic colloid layer thereof and then developing the exposed light-sensitive element in the presence of a specific hydrazine compound. The method forms a photographic image having markedly high negative gradation.Type: GrantFiled: April 30, 1981Date of Patent: June 1, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshitaka Akimura, Shigeo Hirano, Hiroyuki Mifune, Eiichi Okutsu
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Patent number: 4323642Abstract: Lignosulfonates are incorporated in photographic developing compositions containing an indazole antifoggant in order to prevent or retard the precipitation of the indazole. Both black-and-white developing compositions, containing such developing agents as dihydroxybenzenes and/or pyrazolidones, and color developing compositions, containing primary aromatic amino color developing agents, are effectively stabilized against precipitation of indazole antifoggants by the lignosulfonates.Type: GrantFiled: March 9, 1981Date of Patent: April 6, 1982Assignee: Eastman Kodak CompanyInventor: Steven R. Levinson
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Patent number: 4310621Abstract: New DIR-compounds of the formula ##STR1## are useful in photographic materials and processes.Type: GrantFiled: December 16, 1980Date of Patent: January 12, 1982Assignee: AGFA-Gevaert AktiengesellschaftInventors: Heinrich Odenwalder, Karl Frank, Reinhard Muller
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Patent number: 4298673Abstract: A lithographic type diffusion transfer developing composition which provides high contrast images having sharp toe-gradation for developing silver halide light-sensitive materials contains at least one amine represented by one of the following general formulae (I), (II) or (III):H.sub.2 N-C.sub.n H.sub.2n -X (I) ##STR1## X, X', R.sub.1, n and m are defined in the specification. The process of developing using such a composition is also disclosed.Type: GrantFiled: March 6, 1978Date of Patent: November 3, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Kikuo Kubotera, Eiichi Mizuki, Masato Satomura, Haruhiko Iwano, Tadahiro Fujiwara
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Patent number: 4294915Abstract: There are described novel compounds which include a silver halide developing function, a colorless ligand which is a radical of an iminodiacetic acid and a radical containing an onium group. The compounds are useful in photography as silver halide developing agents and also may be complexed with metals to form dye developers.Type: GrantFiled: July 11, 1980Date of Patent: October 13, 1981Assignee: Polaroid CorporationInventor: Elbert M. Idelson
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Patent number: 4292391Abstract: Pyrazolo [3,4-d] pyrimidine, and derivatives thereof, can be added to either a silver halide emulsion, or to a hydroquinone (litho) developer to accelerate development and reduce the induction period.Type: GrantFiled: February 6, 1980Date of Patent: September 29, 1981Assignee: E. I. Du Pont de Nemours and CompanyInventor: Joseph D. Overman
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Patent number: 4278750Abstract: Novel electron donor precursors have the structure: ##STR1## where: R is an alkali labile group;Y is an aliphatic or aromatic group; andZ is an electron withdrawing group.The compounds are useful in photographic elements, film units and processes to provide electrons to immobile compounds which must accept at least one electron before releasing a diffusible dye or photographic reagent.Type: GrantFiled: September 6, 1979Date of Patent: July 14, 1981Assignee: Eastman Kodak CompanyInventor: Chung Y. Chen
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Patent number: 4201588Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer. By the selection of amine-responsive reducing agent precursors, the amines released by the cobalt(III) complexes cause an amplified image.Type: GrantFiled: September 7, 1976Date of Patent: May 6, 1980Assignee: Eastman Kodak CompanyInventors: Anthony Adin, James C. Fleming