Hydroxy Developer Patents (Class 430/485)
  • Patent number: 4774167
    Abstract: A method for processing a silver halide color photographic material is provided, which comprises subjecting an imagewise exposed silver halide color photographic material having at least one silver halide emulsion layer on a reflective support to color development for a period not exceeding 2 minutes and 30 seconds using a color-developing solution containing substantially no benzyl alcohol, a sulfite in a concentration of 8.times.10.sup.-3 mol/liter or less, and a hydroxylamine in a concentration of 1.5.times.10.sup.-2 mol/liter or less, thereby achieving high color densities of the developed images and reduced fog. The effects of this method are particularly significant in photographic paper containing a pyrazoloazole type magenta coupler.
    Type: Grant
    Filed: February 24, 1987
    Date of Patent: September 27, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshio Koshimizu, Takatoshi Ishikawa, Shinji Ueda
  • Patent number: 4756997
    Abstract: An aqueous alkaline photographic silver halide developer composition comprising a dihydroxy benzene developing agent, an auxiliary superadditive developing agent, an antifogging agent, an antioxidant and a buffering agent, characterized by the fact that the composition further comprises a stabilizing amount of an .alpha.-ketocarboxylic acid.The developer composition has a better resistance against air oxidation and can be left in continuous transport automatic processors for several days without undergoing any substantial decrease of its developing properties.The developer composition is particularly useful in a process for the formation of a high contrast silver image by developing silver halide photographic elements including at least a negative acting surface latent image type silver halide emulsion in the presence of a hydrazine compound, preferably in the additional presence of an effective amount of a contrast promoting agent.
    Type: Grant
    Filed: July 21, 1987
    Date of Patent: July 12, 1988
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Carlo Marchesano
  • Patent number: 4738917
    Abstract: A method for processing a silver halide photographic material by processing a silver halide color photographic light-sensitive material containing at least a silver halide emulsion layer comprising a silver halide grain essentially consisting of silver chlorobromide and a binder having a swelling rate of T 1/2 of 2 sec. to 30 sec. The color developer contains a n-hydroxyalkyl-p-phenylenediamine derivative at a temperature not less than 30.degree. C. for a time not more than 150 sec. The time and temperature are effective to process the silver halide color photographic light-sensitive material without decreasing the stability of the resulting dye image.
    Type: Grant
    Filed: May 15, 1986
    Date of Patent: April 19, 1988
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shigeharu Koboshi, Satoru Kuse, Kazuhiro Kobayashi, Masao Ishikawa, Masayuki Kurematsu
  • Patent number: 4699868
    Abstract: An alkaline aqueous tanning developing solution for photographic image development comprising at least one hydroxylamine derivative. Preferred formulations may also contain at least one water-miscible polyhydroxy aliphatic organic solvent and/or a developing agent which comprises a polyhydroxybenzene compound having at least two hydroxy groups and at least one electron withdrawing and good leaving group suitable for nucleophilic addition.
    Type: Grant
    Filed: August 18, 1986
    Date of Patent: October 13, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Gebran J. Sabongi
  • Patent number: 4636456
    Abstract: A process for forming photographic image is disclosed, comprising photographically developing, in the presence of a polyalkylene oxide compound, a silver halide photographic light-sensitive material including at least one silver halide emulsion layer and containing in at least said emulsion layer or other hydrophilic layer a compound represented by formula (I). ##STR1## wherein: A and A' each represents a hydrogen atom or an alkalihydrolyzable group;R.sub.1, R.sub.2, and R.sub.3 each represents a group capable of substituting a hydrogen atom on the hydroquinone nucleus, with R.sub.2 and R.sub.3, A and R.sub.1, or A and R.sub.2 together form a ring; andX represents a group which shows a development-inhibiting effect after being released.
    Type: Grant
    Filed: May 7, 1985
    Date of Patent: January 13, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiro Takahashi, Koki Nakamura
  • Patent number: 4632896
    Abstract: There is disclosed a processing solution for silver complex diffusion transfer process which contains at least one amino alcohol having a pKa value of less than 9 and at least one amino alcohol having a pKa value of 9 or more which are measured in a 50 wt % aqueous ethanol solution at 25.degree. C.
    Type: Grant
    Filed: September 10, 1985
    Date of Patent: December 30, 1986
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Yasuo Tsubai, Koji Okazaki
  • Patent number: 4598040
    Abstract: There is provided a developer for use in a one-step process for the development of exposed film resulting in an exposurewise pattern of silver particles which are large enough to be used as printing elements in ink-printing techniques, providing a wide range of densities in the developed film. The developer is based on a buffered system of a developing agent, a sulfinic acid salt of the type HO-R-SO.sub.2.M..times.H.sub.2 O where R is a hydrocarbyl group and M is a cation, and a formaldehyde source, with conventional adjuvants such as anti-fogging agents and the like. Instead of the sulfinic acid salt defined above there may be used any compound which upon dissociation in a aqueous medium results in the same active ionic species.
    Type: Grant
    Filed: September 12, 1983
    Date of Patent: July 1, 1986
    Inventors: Yoel Netz, Arnold Hoffman
  • Patent number: 4587210
    Abstract: A color photographic silver halide light-sensitive material is described, characterized by containing at least one of the compounds represented by the general formula (I) and their precursors. ##STR1## wherein R represents ##STR2## (wherein R.sub.1 and R.sub.2 are each a hydrogen atom or an alkyl group and may combine with R.sub.3 to form a ring having 5 to 10 carbon atoms, provided that R.sub.1 and R.sub.2 are not hydrogen atoms at the same time, R.sub.3 is a substituted or unsubstituted aryl group, and n is an integer of 1 to 4), and R' has 1 to 20 carbon atoms and represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituent defined by R as defined above). This light-sensitive material provides color images which are stabilized, i.e., freed of fading and the discoloration of the white ground.
    Type: Grant
    Filed: March 30, 1984
    Date of Patent: May 6, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Michio Ono, Masakazu Morigaki, Takayoshi Kamio, Kozo Aoki, Kazuhiko Furuya
  • Patent number: 4546069
    Abstract: The processing time of exposed photographic silver dye bleach materials is shortened by using a bleach preparation which contains a strong acid, a water-soluble iodide, a water-soluble organic nitro compound, an anti-oxidizing agent, a bleach catalyst, an organic photographic developing agent and/or a benzotriazole derivate.
    Type: Grant
    Filed: July 18, 1984
    Date of Patent: October 8, 1985
    Assignee: Ciba-Geigy AG
    Inventors: Arnost Libicky, Meinrad Schar
  • Patent number: 4542086
    Abstract: A color diffusion transfer photographic element comprising (a) a light sensitive component containing at least one light sensitive silver halide emulsion layer associated with a dye releasing redox compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b) and (c) containing a diffusible hydroquinone type compound having the half wave potential of polarography in the range of from -300 mV to -380 mV measured using a saturated calomel electrode as a reference electrode in a buffer solution having a pH of 13.0.degree. at 25.degree. C. The diffusible hydroquinone type compound has excellent gradation control properties and is particularly suitable for controlling gradation of the toe part in a photographic characteristic curve of a color diffusion transfer photograph.
    Type: Grant
    Filed: May 26, 1981
    Date of Patent: September 17, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobutaka Ohki, Motohiko Tsubota, Masakazu Morigaki, Tsutomu Hamaoka
  • Patent number: 4540655
    Abstract: A method of processing a direct positive silver halide photographic light-sensitive material which comprises processing a direct positive silver halide photographic light-sensitive material comprising a support having coated thereon at least one hydrophilic colloid layer containing a compound represented by the following general formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an unsubstituted or substituted aryl group or an unsubstituted or substituted alkyl group; and R.sup.2 represents a hydrogen atom, an unsubstituted or substituted aryl group or an unsubstituted or substituted alkyl group, with a developing solution containing not less than 25 g per liter of a hydroquinone and having a pH of from 11.0 to 13.0. According to the processing method an excellent reversal photographic image can be obtained using a high pH type developing solution which is stable wherein a change of pH due to exhaustion and aerial oxidation is considerably small.
    Type: Grant
    Filed: October 11, 1984
    Date of Patent: September 10, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Takagi, Shigeo Hirano, Tadao Sugimoto
  • Patent number: 4533622
    Abstract: A photographic element for a color diffusion transfer process comprising a support having thereon at least one silver halide emulsion layer and associated therewith a non-diffusible redox compound capable of releasing a diffusible dye or a precursor thereof as the result of treatment with an alkaline processing solution in the presence of a silver halide developing agent after exposure to light, the alkaline processing solution containing a compound represented by the following general formula (I): ##STR1## wherein R represents an alkyl group, an alkoxy group, an aromatic group or an alkylthio group, and each of these groups has 12 or less carbon atoms; and M represents a cation.
    Type: Grant
    Filed: April 9, 1984
    Date of Patent: August 6, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Osamu Takahashi, Mitsugu Tanaka
  • Patent number: 4481286
    Abstract: Novel compounds which are capable of forming a coordination complex with a metal and which include a silver halide developing substituent or a precursor thereof. The compounds are useful as silver halide developing agents and as intermediates for dye developers which are utilized in photographic applications.
    Type: Grant
    Filed: October 29, 1982
    Date of Patent: November 6, 1984
    Assignee: Polaroid Corporation
    Inventors: Patrick F. King, Stephen G. Stroud
  • Patent number: 4429031
    Abstract: A color diffusion transfer photographic element is disclosed, comprising (a) a photosensitive component containing at least one photosensitive silver halide emulsion layer combined with a DRR compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b), and (c) containing a compound represented by the formula (I) ##STR1## wherein R represents a substituted or unsubstituted alkyl group having from 1 to 18 carbon atoms.
    Type: Grant
    Filed: October 3, 1980
    Date of Patent: January 31, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Motohiko Tsubota, Masakazu Morigaki, Tsutomu Hamaoka, Nobutaka Ohki
  • Patent number: 4420557
    Abstract: Compounds corresponding to the formula: ##STR1## wherein R.sup.1 represents an aromatic group, andR.sup.2 represents H, alkyl, alkenyl, aryl or acyl, are suitable ED precursor compounds for use in color photographic recording materials. They are preferably used in combination with reducible dye releasers. They are also suitable as so-called scavengers.
    Type: Grant
    Filed: October 25, 1982
    Date of Patent: December 13, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Heinrich Odenwalder, Paul Marx
  • Patent number: 4383023
    Abstract: A gelatino-silver halide film is exposed and then developed with a tanning developer bearing a positively or negatively charged substituent, e.g., a quaternary amine-substituted hydroquinone, to produce a charged matrix in the gelatin. To enhance the image the film is then processed to mordant an oppositely charged species, e.g., an anionic dye, to the charged matrix.
    Type: Grant
    Filed: October 1, 1981
    Date of Patent: May 10, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Frank L. Schadt, III
  • Patent number: 4383028
    Abstract: A photographic chemistry comprised of a solution containing a mixture of different chemicals which cooperate to minimize the need for long film exposure times to achieve high film quality and contrast. The photographic chemistry includes a number of alkalies in a pH range from about 8 to 14, a developer in solution with the alkalies, a solvent mixed with the alkalies and the developer, a modified alkanolamide in solution with the alkalies, the developer and the solvent, and a hydrotrope mixed with the modified alkanolamide. Other chemicals that can be used in the photographic chemistry include an emulsion penetrant, a cleaner for various components of film processing equipment, a chelating agent, and an enzyme to enhance the reactions of the various chemicals in the photographic chemistry. A specific mixture of chemicals is disclosed.
    Type: Grant
    Filed: August 3, 1981
    Date of Patent: May 10, 1983
    Assignee: Lorin W. Boots
    Inventor: Byron R. Boots
  • Patent number: 4366234
    Abstract: Photographic solutions containing hydroquinone monosulphonate are prepared by a process comprising forming hydroquinone monosulphonate by reacting in solution hydroquinone, a salt of sulphurous acid and hydrogen peroxide. The reaction may be effected in the presence of one or more chemicals required for a photographic developer or after the formation of hydroquinone monosulphonate such material may be added. The invention is useful for making sodium or potassium hydroquinone monosulphonate and may be used in the preparation of a first developer for processing color reversal film, such as by the Kodak E6 process.
    Type: Grant
    Filed: May 29, 1981
    Date of Patent: December 28, 1982
    Assignee: Staveley Chemicals Limited
    Inventors: John B. Wheatcroft, Edward N. Wall
  • Patent number: 4332878
    Abstract: A photographic image-forming method comprising imagewise exposing a silver halide photographic light-sensitive element containing a specific hydroquinone derivative in the silver halide emulsion layer of substantially the surface latent image type or at least one hydrophilic colloid layer thereof and then developing the exposed light-sensitive element in the presence of a specific hydrazine compound. The method forms a photographic image having markedly high negative gradation.
    Type: Grant
    Filed: April 30, 1981
    Date of Patent: June 1, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshitaka Akimura, Shigeo Hirano, Hiroyuki Mifune, Eiichi Okutsu
  • Patent number: 4323642
    Abstract: Lignosulfonates are incorporated in photographic developing compositions containing an indazole antifoggant in order to prevent or retard the precipitation of the indazole. Both black-and-white developing compositions, containing such developing agents as dihydroxybenzenes and/or pyrazolidones, and color developing compositions, containing primary aromatic amino color developing agents, are effectively stabilized against precipitation of indazole antifoggants by the lignosulfonates.
    Type: Grant
    Filed: March 9, 1981
    Date of Patent: April 6, 1982
    Assignee: Eastman Kodak Company
    Inventor: Steven R. Levinson
  • Patent number: 4310621
    Abstract: New DIR-compounds of the formula ##STR1## are useful in photographic materials and processes.
    Type: Grant
    Filed: December 16, 1980
    Date of Patent: January 12, 1982
    Assignee: AGFA-Gevaert Aktiengesellschaft
    Inventors: Heinrich Odenwalder, Karl Frank, Reinhard Muller
  • Patent number: 4298673
    Abstract: A lithographic type diffusion transfer developing composition which provides high contrast images having sharp toe-gradation for developing silver halide light-sensitive materials contains at least one amine represented by one of the following general formulae (I), (II) or (III):H.sub.2 N-C.sub.n H.sub.2n -X (I) ##STR1## X, X', R.sub.1, n and m are defined in the specification. The process of developing using such a composition is also disclosed.
    Type: Grant
    Filed: March 6, 1978
    Date of Patent: November 3, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kikuo Kubotera, Eiichi Mizuki, Masato Satomura, Haruhiko Iwano, Tadahiro Fujiwara
  • Patent number: 4294915
    Abstract: There are described novel compounds which include a silver halide developing function, a colorless ligand which is a radical of an iminodiacetic acid and a radical containing an onium group. The compounds are useful in photography as silver halide developing agents and also may be complexed with metals to form dye developers.
    Type: Grant
    Filed: July 11, 1980
    Date of Patent: October 13, 1981
    Assignee: Polaroid Corporation
    Inventor: Elbert M. Idelson
  • Patent number: 4292391
    Abstract: Pyrazolo [3,4-d] pyrimidine, and derivatives thereof, can be added to either a silver halide emulsion, or to a hydroquinone (litho) developer to accelerate development and reduce the induction period.
    Type: Grant
    Filed: February 6, 1980
    Date of Patent: September 29, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Joseph D. Overman
  • Patent number: 4278750
    Abstract: Novel electron donor precursors have the structure: ##STR1## where: R is an alkali labile group;Y is an aliphatic or aromatic group; andZ is an electron withdrawing group.The compounds are useful in photographic elements, film units and processes to provide electrons to immobile compounds which must accept at least one electron before releasing a diffusible dye or photographic reagent.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: July 14, 1981
    Assignee: Eastman Kodak Company
    Inventor: Chung Y. Chen
  • Patent number: 4201588
    Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer. By the selection of amine-responsive reducing agent precursors, the amines released by the cobalt(III) complexes cause an amplified image.
    Type: Grant
    Filed: September 7, 1976
    Date of Patent: May 6, 1980
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, James C. Fleming