Abstract: The invention pertains to a method for rebalancing a solvent solution useful for treating photosensitive printing elements having a photopolymerizable layer. The solvent solution becomes contaminated with unpolymerized material and other materials that release from the photosensitive printing elements during washout treating, and separation of contaminates also removes some of one or more components in the used solvent solution. The method rebalances the proportion of the components in a solvent solution having 3 or more components. The method includes measuring a reclaimant, which has been separated from the contaminates, for two or more properties, calculating a mass of the components to be added to the reclaimant based on an equation generated for each measured property, and adding the mass of the component or components to the reclaimant to adjust the proportion of the components in the reclaimant to targeted proportions.

Abstract: The invention provides a manufacturing method of a substrate having a film pattern including an insulating film, a semiconductor film, a conductive film and the like by simple steps, and also a manufacturing method of a semiconductor device which is low in cost with high throughput and yield. According to the invention, after forming a first protective film which has low wettability on a substrate, a material which has high wettability is applied or discharged on an outer edge of a first mask pattern, thereby a film pattern and a substrate having the film pattern are formed.

Abstract: A method of producing an organic silver salt dispersion, the method comprising: mixing a first aqueous solution including a water-soluble silver ion supplier and a second aqueous solution including an alkali metal salt of an organic acid to form an organic silver salt dispersion; wherein, the mixing is conducted in the presence of at least one compound selected from polyacrylamide and derivatives of polyacrylamide, and at least 10 mass % (in terms of silver quantity) of the organic silver salt in the organic silver salt dispersion is formed by simultaneous addition of the first aqueous solution and the second aqueous solution to an aqueous medium followed by mixing.

Abstract: A carrier coating that may be used to coat carrier particles, including a specific additive that imparts the coating with superior storage stability and wherein the carrier coating includes an acrylic-based polymeric powder obtained from an emulsion of an acrylic-based polymer, a surfactant, a cationic initiator, and a conductive filler.

Abstract: A bundle for simultaneous refilling of chemicals for processing color photography silver halide materials in an automatic processing apparatus, wherein the bundle comprises at least one bottle with the refilling solution for a color developer and at least two bottles with refilling solutions for a bleach-fixing bath, characterized in that the bottle with the refilling solution for the color developer comprises more than 60 g of color developer substance per 1 L of bottle volume, is distinguished in that the capacity of the bundle is increased.

Abstract: The present invention relates to a developer composition comprising (a) alkali metal carbonate salt; (b) alkali metal bicarbonate salt; (c) nonionic surfactant of the following formula (I): wherein, R1, R2, n, and m are define the same as the specification; and (d) nonionic surfactant of the following formula (II): wherein, R3, p, and q are define the same as the specification. The present invention also relates to a developer.

Abstract: A concentrated composition of a color developer replenisher for a silver halide color photographic material, the composition comprising a single solution, wherein the solution comprises 0.14 mol/liter or more of a p-phenylenediamine color developing agent, the solution has a specific gravity of 1.2 or more, the solution has pH of 13.3 or more, the solution comprises from 0.2 to 1 mol/liter of at least one compound selected from benzenesulfonic acids which may be substituted with an alkyl group, and lactams, and the solution comprises substantially no alkanolamine.

Abstract: A method of making a printing plate from a heat-sensitive PS plate of a positive-working mode for lithographic printing includes the steps of exposing the heat-sensitive PS plate to light and developing the PS plate using an alkaline developing solution containing at least one compound selected from the group consisting of cationic surfactants and compounds having three or more of an ethylene oxide-terminal group in the molecule thereof. The PS plate has a substrate and an image forming layer formed thereon, said image forming layer comprising a lower layer which is formed on the substrate and contains a water-insoluble and alkali-soluble resin and an upper heat-sensitive layer which is overlaid on the lower layer and contains a water-insoluble and alkali-soluble resin and an infrared absorption dye and exhibits an elevated solubility with respect to alkaline aqueous solutions when heated.

Abstract: The present invention provides an aqueous regenerator for addition to an aqueous developer that contains an organic solvent, a dispersing agent and a weak base, and has a pH of between about 8 and less than about 13. The aqueous regenerator includes an organic solvent, dispersing agent, and an effective amount of a strong base such that the regenerator has a greater pH than the developer into which the regenerator is to be added.

Abstract: The present invention relates to a resist remover composition for removing resists during manufacturing processes of semiconductor devices such as integrated circuits, large scale integrated circuits and very large scale integrated circuits. The composition comprises a) 10 to 40 wt. % of water-soluble organic amine compound, b) 10 to 60 wt. % of water-soluble polar organic solvent, c) 10 to 30 wt. % of water, and d) 0.1 to 10 wt. % of organic phenol compound containing two or more hydroxyl groups, and it is characterized in that the water-soluble polar organic solvent is 2-hydroxyisobutyric acid methylester (HBM).

Abstract: This invention describes photopolymer printing plate developing solvents comprising diisopropylbenzene, alone or in combination with one or more co-solvents. Compared with solvents of the prior art, the developing solvents of the present invention have lower toxicity, higher flash points, a milder and more pleasant odor, increased resistance to thermal decomposition, higher solvency, faster dry time, and pose reduced threat to the environment. The solvents of the present invention can exhibit azeotropic-like properties resulting in improved recycling characteristics and reduced drying times. Also, the solvents of the present invention exhibit a degree of selective solvency towards non-crosslinked photopolymers vs. crosslinked photopolymers that is not seen in solvents of the prior art.

Abstract: A single-part, single-phase liquid color developer concentrate for color photographic development having at least one color developing agent of p-phenylenediamine or a derivative or salt thereof, an aqueous solution containing one or more organic solvents in a weight ratio of water to the organic solvent greater than or equal to about 60:40, a molar ratio of [Na+]/[K+] of at least about 1:2, preferably at least about 2:1, and/or a molar ratio of the organic solvent of Formula (I) to a free base of the p-phenylendiamine or p-phenylendiamine derivative is from about 3:1 to about 30:1 is described. The color developer concentrate is simple to manufacture, stable, compact, easy to use, has good water solubility upon dilution, minimizes mixing errors, and can be used with a very low replenishment rate. A method for processing image-wise exposed photographic color silver halide emulsions using the single-part, single-phase liquid color developer concentrate is also provided.

Abstract: Rapid development of silver bromoiodide color negative photographic films and formation of high quality negative images suitable for scanning to produce display images of excellent quality is made possible by a novel developer solution composition and method of development. The solution is characterized by containing, in addition to the color developer compound and conventional photographic developer solution components, a water soluble pyrrolidone polymer, a high concentration of sulfite ion and a low concentration, or the absence of, bromide ion. In the novel method the developer composition contacts the exposed film at elevated temperature, e.g., 40 to 66° C., for a short development time, e.g., 20 to 90 seconds. The developed image has image quality suitable for scanning and digital manipulation to produce a digital record for forming a color display image of high quality.

Abstract: The invention provides a method of photographic processing, comprising the step of applying a photographic processing solution to the surface of a photographic material, wherein the surface tension of the processing solution is controlled to be between about 40 and about 50 dyne/cm.

Abstract: A one-part photographic developing concentrate comprising: (i) a paraphenylene diamine color developing agent; and (ii) a water-soluble organic solvent, wherein a molar ratio of sodium ion to potassium ion is at least 3, and a molar ratio of sulfate ion to carbonate ion is at least 0.25.

Abstract: A single-part colour developing concentrate with a pH greater than or equal to 7 which contains at least 0.02 mol of a colour developer substance and at least 0.015 mol of an antioxidant per litre, characterised in that the concentrate contains 0.05 to 35 g per litre of a wetting agent soluble in water in this amount, is distinguished by very good stability in storage at low temperatures and the discharge behaviour from the concentrate bottle is considerably improved and soiling of the processing equipment is avoided. Furthermore, the optical brightener precipitation occurring in practice in the bleach fixing bath is also prevented.

Abstract: A black-and-white photographic developing composition or developing kit includes an ascorbic acid developing agent and is essentially free of hydroquinone and similar developing agents. The developing composition further includes a water-miscible hydroxy-containing organic solvent having a molecular weight of from about 50 to about 200. The weight ratio of the organic solvent to water is from about 0.1:1 to about 8:1.

Abstract: An aqueous, homogeneous, single-part color developing concentrate comprises a color developing agent in free base form and an N,N-dialkyl- or N,N-diarylhydroxylamine antioxidant that has at least one solubilizing substituent.

Abstract: The present invention is a liquid processing composition for a color development of a silver halide color photographic material, which comprises: at least one specific compound; at least one glycol selected from the group consisting of ethylene glycol, diethylene glycol and triethylene glycol; and at least one polyethylene glycol having a number average molecular weight of from 1,000 to 2,000, and a development processing method using the same.

Abstract: A method of processing photosensitive materials in which one or more chemical compounds are at least partially retained after processing. The chemical compounds are unique to a particular process used by a copyright owner. The absence of the unique compounds in a processed material thus indicates that the processing has been without the authorization of the copyright owner.

Abstract: The invention relates to a photographic element comprising a base and hydrophillic colloid layers comprising at least one layer comprising photosensitive silver halide, wherein said hydrophilic colloid imaging layers further comprise a flexibilizer agent and said flexibilizer agent has a logP of greater than −1.2.

Abstract: A black-and-white photographic developing composition or developing kit includes an ascorbic acid developing agent and is essentially free of hydroquinone and similar developing agents. The developing composition further includes a water-miscible hydroxy-containing organic solvent having a molecular weight of from about 50 to about 200. The weight ratio of the organic solvent to water is from about 0.1:1 to about 8:1.

Abstract: The present invention is a liquid processing composition for a color development of a silver halide color photographic material, which comprises: at least one specific compound; at least one glycol selected from the group consisting of ethylene glycol, diethylene glycol and triethylene glycol; and at least one polyethylene glycol having a number average molecular weight of from 1,000 to 2,000, and a development processing method using the same.

Abstract: A developer for a photopolymerizable presensitized plate for use in making a lithographic printing plate characterized in that it comprises an alkali silicate and a nonionic compound represented by the following general formula (I), it has a molar ratio: SiO2/M2O (wherein M represents an alkali metal or an ammonium group) ranging from 0.75 to 4.0, a pH value ranging from 11.5 to 12.

Abstract: A photoresist developer which is excellent in the wettability of a non-soluble portion of a photoresist after exposure and the solubility of a soluble portion and controls the dissolving speed of the non-soluble portion effectively.

Abstract: A black-and-white photographic developing composition or developing kit includes an ascorbic acid developing agent and is essentially free of hydroquinone and similar developing agents. The developing composition further includes a water-miscible hydroxy-containing organic solvent having a molecular weight of from about 50 to about 200. The weight ratio of the organic solvent to water is from about 0.1:1 to about 8:1.

Abstract: Rapid development of silver bromoiodide color negative photographic films and formation of high quality negative images suitable for scanning to produce display images of excellent quality is made possible by a novel developer solution composition and method of development. The solution is characterized by containing, in addition to the color developer compound and conventional photographic developer solution components, a water soluble pyrrolidone polymer, a high concentration of sulfite ion and a low concentration, or the absence of, bromide ion. In the novel method the developer composition contacts the exposed film at elevated temperature, e.g., 40 to 66° C., for a short development time, e.g., 20 to 90 seconds. The developed image has image quality suitable for scanning and digital manipulation to produce a digital record for forming a color display image of high quality.

Abstract: A stabilized solution of an alkali metal or alkaline earth metal salt of N-ethyl-N-2-(methanesulfonylaminoethyl)-2-methyl-p-phenylenediamine includes from about 10 to 40 weight percent of an alkali metal or alkaline earth metal salt of N-ethyl-N-2-(methane sulfonylaminoethyl)-2-methyl-p-phenylene-diamine; from about 30 to 70 weight percent of at least one photographically inactive water-miscible or water-soluble hydroxy-containing, organic solvent of the alkali metal or alkaline earth metal salt of N-ethyl-N-2-(methane sulfonylaminoethyl)-2-methyl-p-phenylene-diamine; from about 5 to 40 weight percent water; and from about 1 to 40 weight percent of a preservative for the alkali metal or alkaline earth metal salt of N-ethyl-N-2-(methane sulfonylaminoethyl)-2-methyl-p-phenylene-diamine, wherein the weight percentages are based on the total weight of the stabilized solution. Another aspect of the invention are processes for making stabilized p-phenylenediamine color developer solutions.

Abstract: A method for developing exposed lithographic printing plate precursors using a developer and replenisher is disclosed. The replenisher contains a higher concentration of a coating attack-suppressing agent than the developer, so that the aggressiveness of the developer remains substantially constant during the developer loading cycle.

Abstract: An alkaline liquid developer suitable for development of an infrared radiation-presensitized plate for use in making a lithographic printing plate, which developer comprises at least one selected from the group consisting of amphoteric surfactants and cationic surfactants; a method for preparing a lithographic printing plate comprising the steps of imagewise light-exposing to infrared radiation, a presensitized plate for use in making a lithographic printing plate, said presensitized plate having an image-forming layer which comprises an IR-absorbing agent, and developing the light-exposed plate with an alkaline liquid developer comprising at least one selected from the group consisting of amphoteric surfactants and cationic surfactants. The alkaline liquid develper can provide a highly sharp and clear image in a lithographic printing plate without damages to the image areas, simultaneously exhibiting highly development performance to the non-image areas.

Abstract: Photographic developer replenisher concentrates comprising more reactive developers, like 4(N-ethyl-N-2-hydroxyethyl)-2 -methylphenylenediamine (CD-4) undergo rapid oxidation, and consequently, have shorten shelf-life stabilities. Hydroxylamine type derivatives, while disclosed as being useful as a class of antioxidants for stabilizing photographic developer replenishers, most were found to impart either inadequate shelf-life stability for CD-4 developer, or interfered with “satisfactory developer performance.” Surprisingly, it was discovered the shelf-life stability of replenisher concentrates comprising CD-4 photographic developer could be extended for periods of 2 years or longer, and also provide satisfactory developer performance when the hydroxylamine antioxidant comprises at least N,N-bis(2 -sulfoethyl) hydroxylamine (SEHA) or a salt thereof.

Abstract: An aqueous developer for imageable elements that contain a radiation-sensitive initiator system and at least one free radical polymerizable material is disclosed. The developer develops these plates quickly, with high throughput, but with no sludge formation in the developing process. The developer contains water, a buffer, and one or more filter dyes and/or one of more free radical inhibitors. The imageable elements are useful as printing plates.

Abstract: The present invention provides an overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight of a enzyme-degradable biopolymer and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat). An enzyme is applied to the element before, during, or after conventional photoprocessing. According to one embodiment of the invention, the photographic element can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.

Abstract: A stabilized solution of an alkali metal or alkaline earth metal salt of N-ethyl-N-2-(methanesulfonylaminoethyl)-2-methyl-p-phenylenediamine includes from about 10 to 40 weight percent of an alkali metal or alkaline earth metal salt of N-ethyl-N-2-(methane sulfonylaminoethyl)-2-methyl-p-phenylene-diamine; from about 30 to 70 weight percent of at least one photographically inactive water-miscible or water-soluble hydroxy-containing, organic solvent of the alkali metal or alkaline earth metal salt of N-ethyl-N-2-(methane sulfonylaminoethyl)-2-methyl-p-phenylene-diamine; from about 5 to 40 weight percent water; and from about 1 to 40 weight percent of a preservative for the alkali metal or alkaline earth metal salt of N-ethyl-N-2-(methane sulfonylaminoethyl)-2-methyl-p-phenylene-diamine, wherein the weight percentages are based on the total weight of the stabilized solution. Another aspect of the invention are processes for making stabilized p-phenylenediamine color developer solutions.

Abstract: A stabilized p-phenylenediamine color developer solution having about 10 to 40 weight percent of a p-phenylenediamine free base color developer, about 40 to 70 weight percent of a hydroxy-containing organic solvent for the p-phenylenediamine free base color developer, and about 1 to 40 weight percent of a preservative for the p-phenylenediamine free base color developer, wherein the weight percentages are based on the total weight of the stabilized solution. Another aspect are processes for making stabilized p-phenylenediamine color developer solutions.

Abstract: The present invention provides an overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight of a enzyme-degradable biopolymer and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat). An enzyme is applied to the element before, during, or after conventional photoprocessing. According to one embodiment of the invention, the photographic element can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.

Abstract: A single-part, single-phase liquid color developer concentrate for color photographic development having at least one color developing agent of p-phenylenediamine or a derivative or salt thereof, an aqueous solution containing one or more organic solvents in a weight ratio of water to the organic solvent greater than or equal to about 60:40, a molar ratio of [Na+]/[K+] of at least about 1:2, preferably at least about 2:1, and/or a molar ratio of the organic solvent of Formula (I) to a free base of the p-phenylendiamine or p-phenylendiamine derivative is from about 3:1 to about 30:1 is described. The color developer concentrate is simple to manufacture, stable, compact, easy to use, has good water solubility upon dilution, minimizes mixing errors, and can be used with a very low replenishment rate. A method for processing image-wise exposed photographic color silver halide emulsions using the single-part, single-phase liquid color developer concentrate is also provided.

Abstract: An alkaline liquid developer suitable for development of an infrared radiation-presensitized plate for use in making a lithographic printing plate, which developer comprises at least one selected from the group consisting of amphoteric surfactants and cationic surfactants; a method for preparing a lithographic printing plate comprising the steps of imagewise light-exposing to infrared radiation, a presensitized plate for use in making a lithographic printing plate, said presensitized plate having an image-forming layer which comprises an IR-absorbing agent, and developing the light-exposed plate with an alkaline liquid developer comprising at least one selected from the group consisting of amphoteric surfactants and cationic surfactants. The alkaline liquid develper can provide a highly sharp and clear image in a lithographic printing plate without damages to the image areas, simultaneously exhibiting highly development performance to the non-image areas.

Abstract: Human papillomavirus (HPV) antigen formulations are disclosed which prevent protein aggregation and show prolonged stability as aqueous solutions. These formulations comprise a salt (such as sodium chloride) and a non-ionic surfactant (Polysorbate 80 such as Tween 80®) in physiologically acceptable concentrations.

Abstract: The present invention is also directed to a method of photoprocessing a photographic imaging element having a processing-solution-permeable overcoat that comprises at least one water-dispersible hydrophobic polymer interspersed with a water-soluble hydrophilic polymer. During photoprocessing, a surface-active water-soluble hydrophilic polymer is leached into a photoprocessing solution. However, foaming due to the hydrophilic polymer in the photoprocessing solution is prevented by the presence of a non-ionic surfactant having an HLB of less than 12.

Abstract: A multi-part color developing kit includes at least two parts (or solutions) of photochemical compositions that can be mixed to provide a color developing composition useful for obtaining color photographic images. A first aqueous solution is formulated with a color developing agent in free base form, an antioxidant for the color developing agent, an inorganic base, a triazinylstilbene optical brightening agent, an chemical base and a water-miscible or water-soluble hydroxy-substituted, straight-chain organic solvent. A second aqueous solution is formulated with a buffering agent, the same or different chemical base and a phosphonic acid metal ion sequestering agent. Both solutions have a pH and homogeneity to provide a clear color developing composition that is safer for use and disposal.

Abstract: A multi-part color developing kit includes at least two parts (or solutions) of photochemical compositions that can be mixed to provide a color developing composition useful for obtaining color photographic images. A first aqueous solution is formulated with a color developing agent in free base form, an antioxidant for the color developing agent, an inorganic base, a triazinylstilbene optical brightening agent, an chemical base and a water-miscible or water-soluble hydroxy-substituted, straight-chain organic solvent. A second aqueous solution is formulated with a buffering agent, the same or different chemical base and a phosphonic acid metal ion sequestering agent. Both solutions have a pH and homogeneity to provide a clear color developing composition that is safer for use and disposal.

Abstract: The present invention provides a method for formation of a pattern of a photosensitive resin composition, which method is superior in sensitivity and film-thinning ratio, generates no scum in pattern formation, and gives a high resolution. That is, the present invention lies in a method for forming a pattern of a photosensitive resin composition, which comprises coating, on a substrate or the like, a positive photosensitive resin composition composed of a polyamide of particular structure and a diazoquinone compound, subjecting the resulting material to prebaking and then to light exposure, and dissolving and removing the exposed portions of the material with an aqueous alkaline solution containing an anionic surfactant and at least one kind of compound selected from compounds of calcium, strontium and barium, to obtain a pattern. The feature of the present invention lies particularly in using such an aqueous alkaline solution as a developing solution.

Abstract: The present invention provides an overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight of a enzyme-degradable biopolymer and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat). An enzyme is applied to the element before, during, or after conventional photoprocessing. According to one embodiment of the invention, the photographic element can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.

Abstract: The present invention relates to imaging elements, including photographic elements and recording media, having a protective overcoat that resists fingerprints, common stains, and spills. More particularly, the present invention provides a processing-solution-permeable protective overcoat that is water resistant in the final processed product. The overcoat, before formation of the image, comprises hydrophobic polymeric particles in a gelatin matrix. Subsequent treatment of the overcoat, after formation of the image, to remove the gelatin, causes coalescence of the hydrophobic particles, resulting in the formation of a water-resistant continuous protective overcoat.

Abstract: An alkaline aqueous developing solution for developing photoresists or the like contains, as an anti-scum agent: A) between about 0.05 and about 1.0 wt % of a first surfactant or surfactant mixture, the first surfactant(s) having the general formula: R—O—(AO)n—H where AO are alkylene oxide units selected from ethylene oxide units (CH2—CH2—O) and propylene oxide units (CH(CH3)—CH2—O) or (CH2—CH(CH3)—O) and mixtures of ethylene and propylene oxide units, either in the mixture of molecules, where R is a hydrophobic group, n is between about 8 and about 200, and B) as a second surfactant, between about 0.05 and 1.0 wt % of an organic salt having the formula: where R is an alkyl or aryl group, preferably phenyl, A is selected from carboxyl, sulfonyl, phosphonyl and mixtures thereof, preferably sulfonyl. M is a charge-balancing cation, and n is between 1 and about 200, preferably between 2 and about 100.

Abstract: An aqueous solution for developing a silver halide photographic product comprises an alkanolamine in an amount greater than or equal to 0.6 mol/l, at least one wetting agent that is stable at a high pH and miscible in said developing solution, a developing agent capable of reducing the silver ions, and a quaternary ammonium salt having the following formula wherein R1, R2, R3 and R4 are independently hydrogen, an alkyl group of 1 to 4 carbon atoms, an aromatic carbocyclic group or heterocyclic group that can contain one or more nitrogen atoms, or R1 and R2 together, or R1, R2 and R3 together represent the atoms or bonds necessary for forming a ring with the nitrogen atom, having 5 or 6 atoms in the ring, and X is an anion.

Abstract: A tetraalkylammonium hydroxide (TAAH) solution recovered from a development waste through separation therefrom of impurities such as photoresist is mixed with a surface-active substance to have the surface tension thereof adjusted to a desired one, and then reused as a rejuvenated developer. Thus, the surface-active effect (wetting properties) of the rejuvenated developer recovered from the development waste is properly adjusted and controlled, whereby fine photoresist patterns can be stably and effectively developed. Usable surface-active substances include surfactants, and dissolved photoresist contained in the development waste or a photoresist-containing solution such as a photoresist-containing treated solution derived therefrom.

Abstract: A method for processing a silver halide photographic light-sensitive material is disclosed. The method comprises the step of supplying a photographic processing solution on the image forming surface of the silver halide photographic material by a processing solution supplying means, and said processing solution has a contact angle to the image forming surface of said silver halide photographic light-sensitive material of not more than 45°.

Abstract: A homogeneous, ready to use, single-part color developing concentrate comprises a color developing agent in free base form, an antioxidant for the color developing agent, a buffering agent, and a water-miscible or water-soluble hydroxy-substituted, straight-chain organic solvent present in an a concentration such that the weight ratio of water to the organic solvent is from about 15:85 to about 50:50. In addition the concentrate includes a mixture of a specific polyaminopolyphosphonic acid and either a hydroxyalkylidenediphosphonic acid or morpholinomethanediphosphonic acid (or salt thereof) for stability in the presence of calcium ions. This concentrate is prepared by mixing the components in a unique order for improved safety and manufacturability. It can be used to make a working strength processing solution, or it can be used as a replenishing composition with proper dilution to provide color images in photographic silver halide materials.