Two Or More Radiation-sensitive Layers Containing Other Than That Characterized By The Composition Of A Single Sensitive Layer Patents (Class 430/502)
  • Patent number: 4314019
    Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer. By the selection of amine-responsive reducing agent precursors, the amines released by the cobalt(III)complexes cause an amplified image.
    Type: Grant
    Filed: August 2, 1979
    Date of Patent: February 2, 1982
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, James C. Fleming
  • Patent number: 4312938
    Abstract: A broadband laser recording and data storage medium for direct read after writing, formed from a photosensitive silver-halide emulsion in four steps. First, a non-saturating actinic radiation exposure is used to create latent images. A normal photographic development is used to produce a medium of gray neutral density. The surface of the remaining silver halide is fogged in a water or alcohol based solution to create a very thin layer of silver precipitating nuclei on the surface. Finally, a single-step, negative silver diffusion transfer process is used to dissolve the unexposed and undeveloped silver halide, forming silver ion complexes.
    Type: Grant
    Filed: October 17, 1980
    Date of Patent: January 26, 1982
    Assignee: Drexler Technology Corporation
    Inventors: Jerome Drexler, Eric W. Bouldin
  • Patent number: 4299912
    Abstract: A process for producing a lithographic printing plate from a light-sensitive lithographic printing plate comprising a support, a non-silver light-sensitive layer which is provided on the support and which forms a water-insoluble lipophilic image and a gelatino-silver halide light-sensitive emulsion layer on the non-silver light-sensitive layer, which process comprises the steps of:(a) imagewise exposing the light-sensitive lithographic printing plate;(b) developing the gelatino-silver halide light-sensitive emulsion layer;(c) exposing the non-silver light-sensitive layer to light;(d) washing out the gelatino-silver halide light-sensitive emulsion layer in the presence of a proteolytic enzyme; and(e) developing the non-silver light-sensitive layer.
    Type: Grant
    Filed: August 7, 1980
    Date of Patent: November 10, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Sho Nakao, Tadao Toyama
  • Patent number: 4297431
    Abstract: A diffusion control layer comprising a polymerization product of a monomer capable of undergoing .beta.-elimination in an alkaline environment is disclosed for use in diffusion transfer film units, as an interlayer or overcoat in photosensitive elements, or as a timing layer or overcoat in image-receiving elements.
    Type: Grant
    Filed: March 14, 1980
    Date of Patent: October 27, 1981
    Assignee: Polaroid Corporation
    Inventor: Charles I. Sullivan
  • Patent number: 4293641
    Abstract: A photographic light-sensitive material is described comprising a support having thereon at least two silver halide photographic emulsion layers capable of forming a silver image upon treatment with an alkaline processing solution in the presence of a developing agent for silver halide after exposure, said material containing an interlayer positioned between said emulsion layers, wherein the improvement comprises said interlayer containing a complex which is formed from a mixture of hydroquinone derivatives having a solidifying point of 100.degree. C. or less, and which are different compounds from the developing agent for silver halide used in the treatment of the material, and a homopolymer or copolymer containing a recurring unit represented by formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom or a methyl group; Q represents of chemical bond, --COOR.sub.2 -- or --CONHR.sub.2 --; A represents a chemical bond or an oxygen atom; B represents a chemical bond or ##STR2## D represents --CH=CH).
    Type: Grant
    Filed: April 24, 1980
    Date of Patent: October 6, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Osamu Takahashi, Shinji Sakaguchi
  • Patent number: 4288528
    Abstract: An improved process for forming an embossed pattern through the use of a writing concentrated beam opening holes in a film capable of undergoing residue free evaporation. A layer of photoresist is overlayed with the film and upon being exposed and processed the layer supplies the prospective embossed pattern.
    Type: Grant
    Filed: June 11, 1979
    Date of Patent: September 8, 1981
    Assignee: Thomson-CSF
    Inventors: Jean E. Picquendar, Michel Marchal, Jean C. Dubois, Eugene Duda
  • Patent number: 4282311
    Abstract: A method of making flyleads for video disc playback cartridges wherein a dry film resist is coated on both sides of a metal sheet, one side is exposed through a patterned mask, the patterned side is developed and etched, and the remaining photoresist is removed.
    Type: Grant
    Filed: October 3, 1979
    Date of Patent: August 4, 1981
    Assignee: RCA Corporation
    Inventor: Joseph R. Dinardo, Jr.
  • Patent number: 4271255
    Abstract: The invention provides a novel method for the preparation of a printing plate suitable for dry planographic printing without supply of dampening water utilizing the ink-repellency of a cured silicone resin. In the inventive method, a base plate provided with two successive layers of a first adhesive agent and a photocurable organopolysiloxane composition is overlaid with a UV-transparent covering sheet provided with a layer of a second adhesive agent in such a manner that the layers of the organopolysiloxane composition and the second adhesive agent are in direct contact with each other and irradiated with UV light pattern-wise through the sheet.
    Type: Grant
    Filed: March 27, 1980
    Date of Patent: June 2, 1981
    Assignees: Dai Nippon Printing Co. Ltd., Shin-Etsu Chemical Co. Ltd.
    Inventors: Kenji Cho, Minoru Takamizawa, Yoshio Inoue
  • Patent number: 4267961
    Abstract: Photocross-linkable, organic solvent-soluble polymers having a Tg greater than 200.degree. C. are disclosed. The polymers contain sufficient radiation-sensitive cross-linkable units to render the polymers insoluble in organic solvents on exposure to radiation to which the cross-linkable units are sensitive. Also disclosed are supports, particularly supports having a radiation-sensitive surface, having thereon a layer of the described photo-corss-linkable polymers. The polymers are capable of receiving heat-transferrable dyes and are useful in forming color filter arrays for solid-state imaging devices. A particularly convenient method of forming solid-state color imaging devices having a layer containing an array of color filters is also disclosed.
    Type: Grant
    Filed: September 14, 1979
    Date of Patent: May 19, 1981
    Assignee: Eastman Kodak Company
    Inventors: Thomas W. Martin, Mohammad A. Sandhu, Dennis J. Savage
  • Patent number: 4268609
    Abstract: A process for preparing a photosensitive lithographic printing plate precursor wherein a layer containing a water-insoluble lipophilic resin is disposed on a support having a hydrophilic surface, the coating of a silver halide emulsion is directly applied to said layer and dried, said coating of silver halide emulsion is dried with hot air at 60.degree. to 150.degree. C. without permitting the same to set.
    Type: Grant
    Filed: July 16, 1980
    Date of Patent: May 19, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Tadao Toyama, Sho Nakao
  • Patent number: 4267250
    Abstract: In a color diffusion transfer photographic element containing at least one dye-releasing redox compound-containing layer associated with a silver halide photographic emulsion and capable of releasing a diffusible dye as a result of a redox reaction with the oxidation product of a developing agent produced by the development of silver halide with an alkaline processing solution, and at least one layer containing an antistain agent, the improvement which comprises said dye-releasing redox compound-containing layer associated with said silver halide photographic emulsion being spaced from the adjacent interlayer containing said antistain agent by a spacer layer essentially containing a hydrophilic colloid or by a silver halide emulsion layer having substantially the same spectral sensitivity as that of the associated silver halide emulsion.
    Type: Grant
    Filed: October 11, 1979
    Date of Patent: May 12, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiki Sakanoue, Kokichi Waki, Motohiko Tsubota, Osamu Takahashi, Asao Nakatsuka
  • Patent number: 4264705
    Abstract: This invention relates to a multilayered printing plate consisting of (1) a photosensitive printing layer comprising an elastomeric polymer, an ethylenically unsaturated monomer and a photoinitiator, (2) an elastomeric backing layer which is partially photocured and made from a vinyl terminated prepolymer containing a photoinitiator and (3) an optional supporting layer. The multilayer structure is useful for flexographic printing.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: April 28, 1981
    Assignee: Uniroyal, Inc.
    Inventor: Richard B. Allen
  • Patent number: 4258117
    Abstract: A method is disclosed of photographically processing a negative-working imagewise exposed silver halide photographic element to produce a reversal dye image comprising (a) developing the imagewise exposed silver halide with an electron transfer agent to produce oxidized electron transfer agent which reacts with a competing oxidizable substance and (b) developing silver halide remaining with the electron transfer agent in the presence of a dye image providing compound capable, after the competing oxidizable substance has been depleted, of reacting with the oxidized electron transfer agent to produce a reversal dye image. Image transfer film units are disclosed useful in the practice of this method. Such film units include those containing in addition to the competing oxidizable substance and initially immobile dye image providing compound a layer containing additional silver halide and a scavenger separating the additional silver halide from the immobile dye image providing compound.
    Type: Grant
    Filed: November 1, 1979
    Date of Patent: March 24, 1981
    Assignee: Eastman Kodak Company
    Inventors: John Morgan, Peter D. Marsden
  • Patent number: 4256816
    Abstract: A lift-off mask for the patterned deposition of thin films comprises a three layer sandwich of photoresist-aluminum-photoresist on a substrate. Deposition occurs through an opening in the top photoresist layer and through larger size (i.e., undercut) openings in the aluminum and bottom photoresist layers. The top layer of photoresist remains on the mask during deposition and defines the pattern, the bottom photoresist is fully exposed and in the openings provides an undercut which prevents edge tearing during lift-off, and the aluminum layer (typically 50-200 Angstroms thick) protects the bottom layer of photoresist from dissolving during formation of the top photoresist layer. Also described is a technique in which the edges of thin films are tapered by depositing them from a direction oblique to the substrate surface and by rotating the substrate during deposition. These techniques are specifically discussed in the context of fabricating Josephson junction devices.
    Type: Grant
    Filed: February 7, 1980
    Date of Patent: March 17, 1981
    Assignee: Bell Telephone Laboratories, Incorporated
    Inventor: La Rue N. Dunkleberger
  • Patent number: 4254209
    Abstract: Original plates for producing dry planographic printing plates comprising (a) a support, and over and in contact with the support, (b) a light-sensitive adhesive layer made of a photopolymerizable composition comprising one or more photopolymerizable ethylenically unsaturated compounds and one or more photopolymerization initiators and overlying said light-sensitive adhesive layer, (c) a light-sensitive ink-repellent layer made of a silicone composition comprising one or more silicones, one or more photopolymerizable ethylenically unsaturated compounds and one or more photopolymerization initiators. Dry planographic printing plates can be produced from the original plates by image-wise exposing to actinic light and developing.
    Type: Grant
    Filed: April 16, 1979
    Date of Patent: March 3, 1981
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Kohki Abe, Hiroyuki Tsuchiya, Masayoshi Mizuno
  • Patent number: 4254210
    Abstract: To reduce silver coating weight in photographic silver halide elements (e.g., medical X-ray films) the density of the silver image is increased by forming a black-toned, direct positive image in a photopolymer layer on the reverse side from the silver image.
    Type: Grant
    Filed: May 11, 1978
    Date of Patent: March 3, 1981
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Albert L. Van Stappen
  • Patent number: 4254216
    Abstract: A color photographic material comprising a support and at least one layer thereon containing at least one compound of formula [I]: Formula [I] ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each are defined in the specification and claims of this application.The compound of formula [I] is incorporated in a color photographic material to prevent the discoloration and fading-in-color of the color photographic material.
    Type: Grant
    Filed: September 6, 1978
    Date of Patent: March 3, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takashi Uchida, Takashi Sasaki, Shoji Kikuchi, Katsuo Mogaki, Masahiko Taguchi, Syun Takada
  • Patent number: 4248960
    Abstract: A relief producing laminate having an over-lamina comprised of an unsaturated natural-like rubber composition characterized by relief differentiation in response to patterned radiation exposure and an under-lamina comprised of a resilient composition and adhered to the over-lamina. The term "natural-like rubber" as used herein includes both natural and synthetic rubbers which exhibit creep as a result of stress relaxation after being cast or formed.The over-lamina is preferably a butadiene homopolymer or copolymer resin composition, more preferably a halogenated butadiene composition and most preferably a neoprene composition. The composition preferably includes a thiol, a monomer and a photoinitiator.The under-lamina composition may be a woven textile or a polymer and is preferably a monoalkenyl aromatic-diene block copolymer resin composition. It is preferably radiation cured and preferably includes a monomer and a photoinitiator.
    Type: Grant
    Filed: January 23, 1978
    Date of Patent: February 3, 1981
    Assignee: W. R. Grace & Co.
    Inventors: Paul R. Hein, Michael W. Yang, Robert A. Irvin, Steven E. Bauer, Roland L. Orem
  • Patent number: 4247623
    Abstract: A three-layer blank and a process are disclosed for the formation of frames of metal beam leads that are bonded to integrated circuit chips. The blank incorporates an improved negative-working resist having adhesion to the metal as well as flexibility. The process of forming the leads includes the step of fully photopolymerizing the resist to avoid outgassing of residual monomer as would otherwise occur during bonding.
    Type: Grant
    Filed: June 18, 1979
    Date of Patent: January 27, 1981
    Assignee: Eastman Kodak Company
    Inventor: John R. Guild
  • Patent number: 4246337
    Abstract: A photosensitive medium for storing optical information relating to the intensity and polarization of incident light, consisting of an inorganic multilayer film comprising multiple thin layers of silver chloride to which additive coloration has been imparted by chemical means, is described.
    Type: Grant
    Filed: May 1, 1978
    Date of Patent: January 20, 1981
    Assignee: Corning Glass Works
    Inventors: Nicholas F. Borrelli, Peter L. Young
  • Patent number: 4243746
    Abstract: A novel dispersion imaging material comprising a substrate, a sublayer thereon comprising at least 70% by weight of a member selected from palladium, gold, germanium and combinations thereof and having a thickness of 5 A to 200 A, and a main imaging layer on said sublayer comprising at least 50% by weight of tin, and optionally as the outermost layer a protective layer comprising an organic polymer. The sublayer modifies the layer structure of the tin-based main imaging layer. The imaging material has a high safety in respect of toxicity as well as an excellent gradation and a high sensitivity. The imaging material can form thereon an image by a dry process even in a light room without the conventional development and fixation steps.
    Type: Grant
    Filed: March 5, 1979
    Date of Patent: January 6, 1981
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Takeshi Ueda, Shozo Kinoshita, Kiichiro Sasaguri, Hidehiko Kobayashi
  • Patent number: 4239338
    Abstract: Optically bleachable multilayer films containing additively colored silver chloride which exhibit high infrared transmittance and good bleaching sensitivity, and optical information storage media incorporating such films, are described.
    Type: Grant
    Filed: October 22, 1979
    Date of Patent: December 16, 1980
    Assignee: Corning Glass Works
    Inventors: Nicholas F. Borrelli, Peter L. Young
  • Patent number: 4234670
    Abstract: A method for producing visible images in certain charge sensitive, dry processable recording elements. Image recording is accomplished by flowing, in a resistive recording element containing a reducible metal compound, an imagewise pattern of electrical current of sufficient magnitude to produce therein a storable latent image. The metal compound in the latent image areas is subsequently reduced by a dry development technique to produce a visible image.
    Type: Grant
    Filed: September 27, 1979
    Date of Patent: November 18, 1980
    Assignee: Eastman Kodak Company
    Inventors: Joseph Y. Kaukeinen, Duane A. Rockafellow
  • Patent number: 4233390
    Abstract: A method for preparing aluminum based lithographic printing plates which comprises treating at least one surface of an aluminum base sheet with lithographically suitable, photosensitive, preferably water-soluble, diazo composition and then applying to said surface a lithographically suitable photopolymerizable composition to yield the desired photosensitive lithographic printing plate of improved characteristics.
    Type: Grant
    Filed: July 20, 1979
    Date of Patent: November 11, 1980
    Assignee: Polychrome Corporation
    Inventor: Paul Jargiello
  • Patent number: 4230795
    Abstract: A multipart photosensitive element having a predetermined saturation density including at least two partial record portions for forming a full record, each partial record portion controlling a preselected density range of the full record; all of the partial record portions combining to produce the predetermined saturation density of the full record; at least one of the partial record portions including a fixed contrast emulsion and at least one of the partial record portions including a variable contrast emulsion for varying the contrast of that partial record portion over its preselected density range, each of the variable contrast emulsions being photoresponsive in a different spectral region from the other variable contrast emulsions in the other partial record portions for independently selectively varying the contrast in each of the partial record portions including a variable contrast emulsion.
    Type: Grant
    Filed: April 26, 1979
    Date of Patent: October 28, 1980
    Inventor: Donald Krause
  • Patent number: 4218532
    Abstract: A lift-off mask for the patterned deposition of thin films comprises a three layer sandwich of photoresist-aluminum-photoresist on a substrate. Deposition occurs through an opening in the top photoresist layer and through larger size (i.e., undercut) openings in the aluminum and bottom photoresist layers. The top layer of photoresist remains on the mask during deposition and defines the pattern, the bottom photoresist is fully exposed and in the openings provides an undercut which prevents edge tearing during lift-off, and the aluminum layer (typically 50-200 Angstroms thick) protects the bottom layer of photoresist from dissolving during formation of the top photoresist layer. Also described is a technique in which the edges of thin films are tapered by depositing them from a direction oblique to the substrate surface and by rotating the substrate during deposition. These techniques are specifically discussed in the context of fabricating Josephson junction devices.
    Type: Grant
    Filed: October 13, 1977
    Date of Patent: August 19, 1980
    Assignee: Bell Telephone Laboratories, Incorporated
    Inventor: LaRue N. Dunkleberger
  • Patent number: 4211838
    Abstract: A dry process high sensitivity imaging film includes a solid, high optical density and substantially opaque film of dispersion imaging material deposited on a substrate. The film of dispersion imaging material comprises a plurality of separate layers of different and substantially mutually insoluble metal components having relatively high melting points and relatively low melting point eutectics, and interfaces between said layers having relatively low melting points.
    Type: Grant
    Filed: August 25, 1977
    Date of Patent: July 8, 1980
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Masatsugu Izu, Vincent D. Cannella
  • Patent number: 4211837
    Abstract: Removable opaque backing layers for photographic silver halide elements are described. The opaque backing layer contains carbon black and a scavenging agent for impurities of the carbon black selected from fine-rain photosensitive silver halides, silver nitrate, and halides of iron, zinc and mercury. The scavenger prevents the impurities from fogging the photographic silver halide emulsion layers of the elements.
    Type: Grant
    Filed: October 1, 1976
    Date of Patent: July 8, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ralph K. Blake, James G. Morgan, David W. Woodward
  • Patent number: 4209329
    Abstract: The silver halide coating weight of a lithographic element can be reduced by ca. 40% by coating two layers of gelatino-silver halide emulsion on a support, and dividing a speed-adjusting polyoxyethylene compound unequally between the two layers.
    Type: Grant
    Filed: July 31, 1978
    Date of Patent: June 24, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Donald Lohner
  • Patent number: 4201588
    Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer. By the selection of amine-responsive reducing agent precursors, the amines released by the cobalt(III) complexes cause an amplified image.
    Type: Grant
    Filed: September 7, 1976
    Date of Patent: May 6, 1980
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, James C. Fleming
  • Patent number: 4201591
    Abstract: A photographic speed-increasing concentration of a certain organic photographic speed-increasing electron acceptor provides increased photographic speed in a charge-sensitive recording composite material having an ohmic resistivity of at least about 1.times.10.sup.10 ohm-cm. The charge-sensitive recording material can comprise (a) a first electrically conducting layer in association with (b) a photoconductor layer, (c) an electrically activated recording layer comprising an image-forming combination of (i) an organic, heavy metal salt oxidizing agent with (ii) a reducing agent and (iii) the described speed-increasing electron acceptor, and a binder, and (d) a second electrical conducting layer. This recording material can be room light handleable and can provide a developed image with increased speed by dry development subsequent to electrical exposure.
    Type: Grant
    Filed: November 17, 1978
    Date of Patent: May 6, 1980
    Assignee: Eastman Kodak Company
    Inventor: Raymond F. Reithel
  • Patent number: 4197128
    Abstract: A light-sensitive copying material comprising at least two organic coating layers on a support, at least one of the coating layers being a light-sensitive layer which comprises an O-quinone diazide compound whose alkali solubility is increased by irradiation with active rays.
    Type: Grant
    Filed: November 2, 1977
    Date of Patent: April 8, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaru Watanabe, Tadao Yoyama, Azusa Ohashi
  • Patent number: 4197127
    Abstract: Disclosed herein are compositions useful for the preparation of flexible coatings, particularly to photographic materials, which have improved stability to organic solvents and dissolved salts. The compositions comprise an aqueous dispersion of a hydrophilic colloid and a copolymer having a glass transition temperature less than or equal to 60.degree. C. comprising: from about 50 to about 70 percent by weight of an ester of an ethylenically unsaturated carboxylic acid; from about 2 to about 18 percent by weight of an amide of an ethylenically unsaturated carboxylic acid; from about 10 to about 30 percent by weight of a vinyl benzene; and from about 2 to about 18 percent by weight of a sulfonate monomer having the formula ##STR1## wherein R is hydrogen or alkyl; R.sup.1 is selected from the group consisting of alkylene and ##STR2## R.sup.2 is amino substituted with alkyl or hydrogen, or --CH.sub.2).sub.n O-- wherein n is an integer from 0 to 5; m is either 0 or 1; and X is hydrogen or a monovalent cation.
    Type: Grant
    Filed: August 25, 1978
    Date of Patent: April 8, 1980
    Assignee: Eastman Kodak Company
    Inventor: Thomas G. Mecca
  • Patent number: 4196001
    Abstract: Photographic elements are protected against the adverse effects resulting from accumulation of static electrical charges by incorporating in the element an antistatic layer formed from an aqueous coating composition containing a water-soluble film-forming polymeric anionic polyelectrolyte in free acid form, a water-soluble film-forming cross-linkage polymeric binder, and an acid-acting cross-linking agent for the polymeric binder. The antistatic layer is useful with both photographic films and photographic papers employed in black-and-white photography or in color photography and will function as an effective anticurl layer as well as providing excellent protection against static. It is durable, abrasion resistant, non-tacky and highly resistant to the aqueous processing baths employed in photographic processing.
    Type: Grant
    Filed: April 16, 1975
    Date of Patent: April 1, 1980
    Assignee: Eastman Kodak Company
    Inventors: Douglas C. Joseph, Ronald L. Hartman
  • Patent number: 4195998
    Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand-containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer.
    Type: Grant
    Filed: October 27, 1977
    Date of Patent: April 1, 1980
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, James C. Fleming