Azo Dye Patents (Class 430/561)
  • Patent number: 4242430
    Abstract: Organic substrates, especially photographic dyes, are stabilized against light by using a Cu, Co, Ni, Pd or Pt complex of formula (I). ##STR1## wherein M represents Cu, Co, Ni, Pd or Pt; R.sub.1 and R.sub.6 may be the same or different and represent a hydrogen atom or an alkyl group, an aryl group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylsulfonyl group or an arylsulfonyl group; and R.sub.2, R.sub.3, R.sub.4 and R.sub.5 which may be the same or different represent a hydrogen atom, a halogen atom, a cyano group, or an alkyl group, an aryl group, a cycloalkyl group or a heterocyclic group bonded to a carbon atom on a benzene ring directly or through a divalent linking group, or R.sub.2 and R.sub.3, R.sub.3 and R.sub.4 or R.sub.4 and R.sub.5 respectively may combine and represent the non-metallic atomic groupings required to form a 6-membered ring.
    Type: Grant
    Filed: November 14, 1978
    Date of Patent: December 30, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Hara, Kotaro Nakamura, Yoshiaki Suzuki
  • Patent number: 4242441
    Abstract: A color image forming process comprising processing a photographic element having silver image-wise distributed therein in the presence of a specific type of complexing agent, an oxidizing agent which is peroxo acid or salt thereof, and a dye or dyes, to oxidatively bleach the dye or dyes. By the process of this invention, color images which are stable to light, heat and moisture are obtained using photosensitive materials containing a reduced amount of silver salt or silver without using chemicals causing pollution problems for the processing.
    Type: Grant
    Filed: February 28, 1979
    Date of Patent: December 30, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeru Nakamura, Isao Shimamura
  • Patent number: 4242431
    Abstract: A method of stabilizing an organic substrate material such as a photographic dye against the action of light having an absorption maximum between about 300 nm and about 800 nm in wavelength by making co-exist with the organic substrate material at least one compound represented by the formula (I) defined in the specification is disclosed.
    Type: Grant
    Filed: December 14, 1978
    Date of Patent: December 30, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Hara, Kotaro Nakamura, Yoshiaki Suzuki
  • Patent number: 4239843
    Abstract: The stability of organic substrates having an absorption maximum between 300 and 800 nm in wavelength can be improved by at least one compound represented by the formula (I); ##STR1## wherein M represents Cu, Co, Ni, Pd or Pt; X.sub.1, X.sub.2, X.sub.3 and X.sub.4 eachrepresents an oxygen or sulfur atom, R.sub.1 and R.sub.2 each represents an alkyl, an aryl, a cycloalkyl, an oxocyclalkyl or a heterocyclic group attached to the carbon atom on the chelate ring directly or through a divalent connecting group, R.sub.3 represents a hydrogen atom, an alkyl, an aryl, a cycloalkyl, an oxocycloalkyl or a heterocyclic group attached to the carbon atom on the chelate ring directly or through a connecting group whereby R.sub.1, R.sub.2 and R.sub.3 may be the same or different and R.sub.1 and R.sub.3 or R.sub.2 and R.sub.3 may combine with each other to form a 5-, 6- or 7- member ring structure.
    Type: Grant
    Filed: October 30, 1978
    Date of Patent: December 16, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Hara, Yoshiaki Suzuki
  • Patent number: 4195993
    Abstract: Cyan azo dye-providing compounds have the formula: ##STR1## wherein: R.sup.1 is selected from the group consisting of aryl, alkyl or NR.sup.11 R.sup.12 wherein R.sup.11 is alkyl or aryl and R.sup.12 is alkyl, or R.sup.11 and R.sup.12, taken together with the nitrogen atom to which they are attached, is a heterocyclic group;X is --CO-- or --SO.sub.2 --;R.sup.3 is --COOH or --CAR and is attached in the meta or para position to X in the benzene ring;R is alkyl; ##STR2## or can be taken together with R and the nitrogen atom to which it is attached to form a heterocyclic ring unsubstituted or substituted with a carboxy group; andCAR is a carrier moiety which, as a function of oxidation under alkaline conditions, releases a diffusible dye, with the proviso that the compound contains at least one CAR group and, excepting when R and R.sup.2 form a heterocyclic group and X is --SO.sub.2 --, must contain at least one carboxy group.
    Type: Grant
    Filed: August 17, 1978
    Date of Patent: April 1, 1980
    Assignee: Eastman Kodak Company
    Inventors: Kenneth N. Kilminster, Colin Holstead