Including Manipulative Emulsification Step Patents (Class 430/569)
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Patent number: 6291153Abstract: A direct radiographic film is usefull for dental care. The film contains lower than normal amounts of silver 30-45 mg/dm2) and gelatino-vehicle 15-30 mg/dm2) in each silver halide emulsion unit but retains the ability to provide desired sensitometric results. The film comprises predominantly non-spectrally sensitized silver bromide tabular grains.Type: GrantFiled: June 27, 2000Date of Patent: September 18, 2001Assignee: Eastman Kodak CompanyInventor: Robert E. Dickerson
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Patent number: 6284449Abstract: A silver halide emulsion comprising silver halide grains is disclosed, in which at least 50% of total grain projected area is accounted for by silver halide regular crystal grains exhibiting a proportion of a (100) face per grain of not less than 50% and having an average iodide content of not more than 5 mol %; the silver halide grains having an internal high iodide phase having an average iodide content of not less than 7 mol % and accounting for 0.1 to 15% of the grain volume; the high iodide phase being in the region at a depth of from 7 to 27% from the (100) face, based on the distance between the center of a grain and the (100) face.Type: GrantFiled: December 15, 1999Date of Patent: September 4, 2001Assignee: Konica CorporationInventors: Tomoyuki Nakayama, Tadahiro Nagasawa, Rieko Ren
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Patent number: 6277550Abstract: A photosensitive silver halide emulsion has been disclosed, containing tabular silver halide grains present in a numerical amount of at least 50%, said tabular grains having an average aspect ratio of at least 1.2, an average equivalent circular grain diameter of at least 0.1 &mgr;m and an average grain thickness of less than 0.3 &mgr;m, characterized in that said grains further include an organic hole trapping dopant.Type: GrantFiled: November 5, 1999Date of Patent: August 21, 2001Assignee: Agfa-GevaertInventors: Kathy Elst, Johan Loccufier
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Patent number: 6277551Abstract: In a screen/film system offering a suitable method for radiological image formation the film material comprises a {111} tabular silver chlor(oiod)ide emulsion comprising a binder and silver chlor(oiod)ide crystals having at least 90 mole % of silver chloride, accounting for at least 50% of the total projective surface of said crystals, further having an average thickness of less than 0.3 &mgr;m, an average crystal diameter of more than 0.5 &mgr;m and an average aspect ratio more of than 2:1, wherein said tabular crystals have been spectrally sensitized with blue and/or green spectral sensitizers, characterized in that said crystals have been doped with at least one of a hexa-coordinated metal complex ion having at least 4 fluorine atoms according to the formula (I) as explained more in detail in the description and in the claims [ML6−nFn]m− (I).Type: GrantFiled: January 27, 2000Date of Patent: August 21, 2001Assignee: Agfa-GevaertInventor: Dirk Vandenbroucke
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Patent number: 6265145Abstract: A process for the preparation of a radiation-sensitive silver halide emulsion comprised of high chloride cubical silver halide grains containing from 0.05 to 3 mole percent iodide, based on total silver, where the iodide is incorporated in the grains in a controlled, non-uniform distribution forming a core containing at least 50 percent of total silver, an iodide free surface shell having a thickness of greater than 50 Å, and a sub-surface shell that contains a maximum iodide concentration is disclosed, the process comprising: (a) providing in a stirred reaction vessel a dispersing medium and host high chloride silver halide cubical grains comprising a speed enhancing amount of iodide, and (b) precipitating silver halide onto the host grains by introducing at least a silver salt solution into the dispersing medium at a rate such that the normalized molar addition rate, Rn, is above 3.Type: GrantFiled: December 30, 1999Date of Patent: July 24, 2001Assignee: Eastman Kodak CompanyInventors: Rajesh V. Mehta, Jerzy A. Budz, Jess B. Hendricks, III, Heinz E. Stapelfeldt, Seshadri Jagannathan, Ramesh Jagannathan
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Patent number: 6265144Abstract: A method of preparing a silver halide emulsion is disclosed, comprising the steps of forming a silver halide emulsion, subjecting the silver halide emulsion to chemical sensitization, and adding a sensitizing dye the silver halide emulsion, wherein the sensitizing dye exhibits an absorption maximum at a wavelength of not less than 730 nm, the pAg of the emulsion being adjusted to a range of from 7.50 to 8.25 after strating the chemical sensitization and before adding the sensitizing dye.Type: GrantFiled: December 22, 1999Date of Patent: July 24, 2001Assignee: Konica CorporationInventors: Masato Okuyama, Shigeo Tanaka
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Patent number: 6261758Abstract: The production of tabular silver bromide-iodide emulsions and silver bromide-chloride-iodide emulsions with an aspect ratio 32, an iodide content from 1 to 40 mol % and a chloride content from 0 to 20 mol %, by the process steps of (a) silver halide nucleus precipitation, and (b) at least one further precipitation of silver halide, wherein rein at least one aromatic five- or six-membered, heterocyclic compound, which is free from—SH—,—SSO2H— and—SSO2R groups, is added in an amount from 10−9 to 10−4 mol/mol silver during nucleus precipitation or during the precipitation of an inner zone of the silver halide grain which is different from the nucleus precipitate, results in an improved speed/grain size ratio and in an increased stability of a photographic material which contains an emulsion produced in this manner.Type: GrantFiled: July 14, 2000Date of Patent: July 17, 2001Assignee: Agfa-GevaertInventors: Ralf Wirowski, Hans-Ulrich Borst, Detlev Kapitza, Jörg Siegel, Peter Bergthaller, Heinrich Odenwälder
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Patent number: 6258522Abstract: The present invention relates to a light-sensitive emulsion, and a light-sensitive photographic material containing the same, comprising silver bromoiodide grains of a core shell structure comprising a) an inner core consisting essentially of silver bromide or silver bromoiodide, the silver iodide content of said inner core being within the range of 0 to 10 mole %, and b) a plurality of shells consisting essentially of silver bromide or silver bromoiodide, wherein a pure silver iodide phase representing from 0.1 to 5 mole % of the total silver halide grain content is interposed between two adjacent shells, and wherein at least one of said adjacent shells has a silver iodide content higher than 5 mole %.Type: GrantFiled: May 23, 2000Date of Patent: July 10, 2001Assignee: Ferrania S.p.A.Inventors: Mario Mariotti, Stefania Ghirardo, Giuseppe Rocca, Mauro Avidano, Alessandro Gunnella, Ezio Astengo
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Patent number: 6251577Abstract: A method for producing a silver halide photographic emulsion comprises a step of spectrally sensitizing a silver halide photographic emulsion material that contains tabular silver halide grains having an aspect ratio of 3 or more in an amount of 50% or more of the total projected area of all the silver halide grains, and a step of performing the spectral sensitization by the addition of a cyanine dye in an amount of 60% or more of the saturated covering amount of the silver halide grains, and the emulsion is produced in the presence of 400 to 2,500 ppm of calcium ions and/or 50 to 2,500 ppm of magnesium ions.Type: GrantFiled: March 12, 1999Date of Patent: June 26, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Mamoru Sakurazawa, Junichiro Hosokawa, Keiji Mihayashi
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Patent number: 6248507Abstract: A process for the preparation of a radiation-sensitive silver halide emulsion comprised of high chloride cubical host grains containing from 0.Type: GrantFiled: December 30, 1999Date of Patent: June 19, 2001Assignee: Eastman Kodak CompanyInventors: Jerzy A. Budz, Seshadri Jagannathan, Alan R. Sadler
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Patent number: 6242171Abstract: This invention concerns tabular photographic emulsions and their preparation. According to the invention, high bromide tabular emulsion is precipitated and then a non-sensitized fine grain emulsion comprising grains exhibiting {100} crystal faces is added, before sensitization. The resulting emulsion exhibits improved speed/fog performance.Type: GrantFiled: December 9, 1999Date of Patent: June 5, 2001Assignee: Eastman Kodak CompanyInventor: Luc R. Gourlaouen
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Patent number: 6242172Abstract: A radiation-sensitive emulsion is disclosed comprised of cubical silver halide grains containing from 0.05 to 3 mole percent iodide, based on total silver, and an iridium coordination complex dopant, wherein (i) the iodide is incorporated in the grains in a controlled, non-uniform distribution forming a core containing at least 50 percent of total silver, an iodide free surface shell having a thickness of greater than 50 Å, and a sub-surface shell that contains a maximum iodide concentration, and (ii) the iridium coordination complex dopant is incorporated into the sub-surface shell or into a region of the core extending up to 60% of the total silver into the grain from the sub-surface shell. Speed and reciprocity of iodochloride emulsions can be improved by localized addition of known in the art reciprocity-controlling iridium dopants in relation to high iodide region of the grain.Type: GrantFiled: December 30, 1999Date of Patent: June 5, 2001Assignee: Eastman Kodak CompanyInventors: Jerzy A. Budz, Eric L. Bell, Rajesh V. Mehta
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Patent number: 6235461Abstract: The present invention relates to a process for manufacturing a silver halide photographic element comprising the step of adding to a silver halide emulsion (1) an aryl compound having at least two hydroxyl groups and at least one additional substituent represented by a sulfonic group, an alkali metal sulfonate group, a hydroxyl group, a carboxy group or a hydroxymethyl group, and (2) a polyhydroxyalkyl derivative selected from the group consisting of non-hydrogenated polysaccharides having an average molecular weight higher than 10,000 and hydrogenated polysaccharides having an average molecular weight equal to or lower than 10,000. The use of such a combination to increase the speed to Dmin ratio of a silver halide photographic element and a silver halide element comprising such a combination is also claimed.Type: GrantFiled: June 7, 1999Date of Patent: May 22, 2001Assignee: Tulalip Consultoria Comercial Sociedade Unipessoal S.A.Inventors: Alain Dominique M. Sismondi, Marco Serafini
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Patent number: 6232057Abstract: An iodide ion releasing compound represented by the following Formula [1], wherein R1, R2 and R3 represent a hydrogen atom and substituents; EWG represents —CO2—, —OCO—, —SO2—, —SO2O—, —OSO2—, —CONR4—, —NR5CO—, —CSNR6—, —NR7CS—, —NR8—, —O—, —S—, —CO—, —COCO— and —NR9SO2—; L represents linking group and SOL represents aqueous soluble group; R4, R5, R6, R7, R8 and R9 represent a hydrogen atom and substituents; n and m represent an integer of 1-4.Type: GrantFiled: December 21, 1998Date of Patent: May 15, 2001Assignee: Konica CorporationInventors: Emiko Kataoka, Norio Miura
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Patent number: 6228573Abstract: A process for preparing an ultrathin high bromide {111} tabular grain silver halide emulsion in a reaction vessel comprising the steps of (a) forming in the presence of a dispersing medium a population of silver halide grain nuclei containing twin planes, and (b) growing the silver halide grain nuclei containing twin planes to form high bromide {111} tabular silver halide grains by the addition of silver and halide ions, WHEREIN the majority of the silver added during growth step (b) is added at a pBr of less than 2.6 and in the presence of a triaminopyrimidine grain growth modifier containing mutually independent 4, 5 and 6 ring position amino substituents, the 4 and 6 ring position substituents being hydroamino substituents. High bromide ultrathin {111} tabular grain emulsions prepared by the process of the invention provide thinner tabular grains than that obtained in the absence of the triaminopyrimidine grain growth modifier.Type: GrantFiled: December 15, 1999Date of Patent: May 8, 2001Assignee: Eastman Kodak CompanyInventors: John E. Keevert, Jr., Joe E. Maskasky, Michael G. Antoniades
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Patent number: 6225041Abstract: A silver halide photographic emulsion is disclosed, consisting essentially of tabular silver halide grains having an average aspect ratio of 3.0 or more, the tabular grains substantially having dislocation lines, a variation coefficient of grain size of said tabular grains being 20% or less and a variation coefficient of thickness of said tabular grains being 20% or less. There is also disclosed a photographic light sensitive material containing the tabular grains.Type: GrantFiled: June 20, 1997Date of Patent: May 1, 2001Assignee: Konica CorporationInventor: Hiroshi Takada
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Patent number: 6218098Abstract: A process for the preparation of a high chloride silver halide grain emulsion in which at least 50% of the projected area of the emulsion grains is accounted for by cubic grains, said process comprising: i) precipitating an intermediate emulsion containing high chloride cubic nuclei having an average edge length less than or equal to 0.07 &mgr;m, by adding to an external continuous reactor at least one silver salt aqueous solution, a chloride salt aqueous solution and a hydrophilic colloid aqueous solution, in conditions so that (Qgel*Tgel)/(Qag*CAg) is more than 100, wherein Qgel is the flow rate of the hydrophilic colloid aqueous solution, Tgel is the hydrophilic colloid content of the hydrophilic colloid solution (g/l), QAg is the flow rate of the silver salt aqueous solution, CAg is the silver concentration of the silver salt aqueous solution (mole/l) and is comprised between 0.01 and 5 moles/l, the average pCl in the external reactor being between 1.7 and 3.Type: GrantFiled: September 2, 1999Date of Patent: April 17, 2001Assignee: Eastman Kodak CompanyInventors: Pierre-Henri Jezequel, Christian S. Schmuckle
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Patent number: 6214532Abstract: Method of preparing a photosensitive element containing a silver halide emulsion with homogeneous and thin tabular crystals, comprising the steps of: (1) forming silver halide nuclei by simultaneously adding an aqueous silver salt and a halide salt solution to a reaction vessel (a), containing an aqueous solution of a protective colloid, (2) transfering the dispersion of silver halide nuclei formed in vessel (a) to a mixing chaiber (b) and diluting said dispersion, (3) growing in a growth chamber (c) said nuclei of the diluted dispersion by adding and mixing an aqueous silver salt and a halide salt solution and collecting the grown crystals in reaction vessel (a) which is a part of a closed circuitry together with the mixing and growth chambers (b) and (c), (4) transfering said silver halide crystal dispersion to mixing chamber (b) and diluting the dispersion, (5) further growing the silver halide crystals in growth chamber (c) and collecting the silver halide crystals in reaction vessel a), (6) concentType: GrantFiled: December 13, 1999Date of Patent: April 10, 2001Assignee: Agfa-GevaertInventor: Dirk Bollen
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Patent number: 6203971Abstract: A photographic silver halide emulsion is disclosed, comprising tabular grains: the tabular grains having a silver chloride content of at least 95 mole %, an aspect ratio of at least 2 and a distance between the main planes of 0.13 &mgr;m or less; wherein the tabular grains occupy at least 90%, based on total projected area, of the total silver halide grains in the emulsion and have a variation coefficient of 20% or less in the distance between the main planes; and a silver halide photographic material comprising a support having thereon the silver halide emulsion and a method of development-processing the silver halide photographic material are disclosed.Type: GrantFiled: September 29, 1999Date of Patent: March 20, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Katsuhisa Ohzeki
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Patent number: 6194133Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein said emulsion contains as a dopant a metal complex represented by the following formula (I) or (II): [MLXLI(4−x)]n (I) wherein M represents a metal or a metal ion, L represents an imidazole compound which is bonded to M, x represents 1, 2, 3 or 4, n represents an integer of from −6 to +5, and LI represents a chemical species bonded to M and LI(4−x) may be the same or different chemical species when x is 1 or 2; [MXnL(6−n)]m (II) wherein M represents a metal ion, L represents an imidazole compound, X represents a halogen ion, n represents 3, 4 or 5, and m represents −5, −4, −3, −2, −1, 0, +1 or +2.Type: GrantFiled: May 12, 1999Date of Patent: February 27, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Tadanobu Sato
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Patent number: 6194135Abstract: A negatively developing color photographic silver halide material having a support and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least 95 mol % of the silver halides of which consist of AgCl, and in which at least one silver halide emulsion layer exhibits solarization on analogue exposure, is distinguished on scanning exposure by elevated color density and on analogue exposure by contrast which is independent of exposure time.Type: GrantFiled: October 22, 1999Date of Patent: February 27, 2001Assignee: Agfa-Gevaert Naamloze VennootschapInventors: Cuong Ly, Stefan Amann, Jürgen Jung, Dieter Rockser
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Patent number: 6187525Abstract: A photographic recording element is disclosed containing in at least one dye image forming layer unit (a) a radiation-sensitive silver halide grains include tabular grains (1) having {111} major faces, (2) containing greater than 50 mole percent bromide, based on silver, and (3) accounting for greater than 50 percent total grain projected area, (b) a fragmentable electron donating sensitizer, (c) a water dispersible cationic starch peptizer, and (d) a one equivalent dye image providing coupler. Increased photographic speed is realized.Type: GrantFiled: December 17, 1998Date of Patent: February 13, 2001Assignee: Eastman Kodak CompanyInventors: Joe E. Maskasky, Kenneth J. Reed, Victor P. Scaccia, James A. Friday
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Patent number: 6183946Abstract: A silver halide emulsion is disclosed, which is a silver chlorobromide or silver chloroiodobromide emulsion having a silver chloride content of 90 mol % or more, wherein the silver halide grain in said emulsion has, in the vicinity of the grain surface, a silver bromide-rich phase containing an iridium compound and, the silver bromide-rich phase comprises an inner part region and an outer side part region, wherein the inner side part region has a higher iridium compound density than the outer side part region has.Type: GrantFiled: September 24, 1998Date of Patent: February 6, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Yoshiro Ochiai
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Patent number: 6171738Abstract: A method for preparing a silver halide emulsion is disclosed, wherein the method controls a mean intergrain distance in the process of growing silver halide grains contained in a silver halide emulsion, as defined below, over a period of from the start of growing silver halide grains to completion thereof: Mean intergrain distance=(Volume of the reaction mixture solution/number of grains in the reaction mixture solution)⅓.Type: GrantFiled: March 31, 1998Date of Patent: January 9, 2001Assignee: Konica CorporationInventors: Hiroshi Takada, Sadayasu Ishikawa, Satoshi Ito
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Patent number: 6165705Abstract: This invention comprises a photothermographic element comprising a support bearing an imaging layer comprising:a silver salt;a reducing agent;a binder; anda photosensitive material comprising silver iodide produced by dispersing a solid ionic conductor of the formula MAg.sub.4 I.sub.5 in an organic solvent, whereby the solid ionic conductor decomposes to produce silver iodide, and wherein M is a monovalent cation and said solid ionic conductor has an ionic conductivity of >0.001 ohm.sup.-1 cm.sup.-1 at 25.degree. C.Type: GrantFiled: December 18, 1998Date of Patent: December 26, 2000Assignee: Eastman Kodak CompanyInventors: Heidi E. Dankosh, Kathleen R. Gisser, Thomas N. Blanton, Dilip K. Chatterjee, Seshadri Jagannathan
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Patent number: 6159677Abstract: A monodispersed silver halide emulsion has an average silver iodide content of 1 to 20 mol %, an average equivalent sphere diameter of 0.1 to 0.6 .mu.m, and 60% or more of the total projected area of all the grains in the emulsion are occupied by tabular silver halide grains each having principal planes composed of {100} faces in an amount of 80% or more based on the total surface area of each grain.Type: GrantFiled: May 29, 1998Date of Patent: December 12, 2000Assignee: Fuji Photo Film, Co., Ltd.Inventor: Nobuyuki Haraguchi
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Patent number: 6153370Abstract: There is disclosed a light-sensitive silver halide photographic emulsion, which comprises light-sensitive silver halide grains mainly composed of (100) planes and (111) planes, at least one compound that is adsorbed selectively on the (100) planes of the silver halide grains, and at least one spectrally sensitizing dye. There is also disclosed a light-sensitive material using the emulsion. The emulsion is high in sensitivity and excellent in graininess.Type: GrantFiled: April 24, 1997Date of Patent: November 28, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoichi Maruyama, Kimiyasu Morimura, Nobuyuki Haraguchi, Hiroyuki Mifune, Tetsuro Kojima
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Patent number: 6150081Abstract: A tabular silver halide emulsion wherein the tabular grains account for more than 75% of the total grain projected area said emulsion comprising silver halide grains nucleated in the presence of nucleation peptizer and thereafter grown in the presence of growth peptizer, wherein at least one of the peptizers is substantially pure collagen like material prepared by genetic engineering, said peptizer having an amino acid sequence comprising more than 4 different amino acids. A process of preparing the AgX emulsion. A process of producing recombinant collagen like polypeptide comprising expression of a collagen like polypeptide encoding nucleic acid sequence by a microorganism to a degree exceeding 0.95 grammes/liter, said recombinant collagen being free of helix structure and preferably the expression occurring in a microorganism other than E. coli or Saccharomyces cerevisiae.Type: GrantFiled: December 23, 1998Date of Patent: November 21, 2000Assignee: Fuji Photo Film B.V.Inventors: George Valentino Van Heerde, Alexis Cornelus Van Rijn, Jan Bastiaan Bouwstra, Frederik Anton De Wolf, Andreas Mooibroek, Marc Willem Theodoor Werten, Richele Deodata Wind, Tanja Jacoba Van Den Bosch
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Patent number: 6143484Abstract: The present invention is a method for stabilizing a photographic coating melt. The photographic melt includes an aqueous medium and a dispersed liquid organic phase containing an ultraviolet ray absorbing compound, and an emulsion containing silver halide particles having an average equivalent circular diameter of from 0.03 to 0.10 microns. The photographically useful ultraviolet ray absorber compound is soluble in a liquid organic phase and substantially insoluble in water. The method includes the step of adding to the emulsion containing silver halide particles a sufficient amount of surfactant to passify surfaces of the silver halide particles. The present invention is also a method of preparing a photographic coating melt. A dispersion is prepared which includes an aqueous medium, a dispersed liquid organic phase and an ultraviolet ray absorber compound wherein the ultraviolet ray absorber compound is soluble in the dispersed liquid organic phase and substantially insoluble in water.Type: GrantFiled: May 6, 1999Date of Patent: November 7, 2000Assignee: Eastman Kodak CompanyInventors: Kurt M. Schroeder, Jayme D. Ribeiro, Gary L. Slater, Timothy J. Hubert
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Patent number: 6143483Abstract: There is disclosed a silver halide emulsion that comprises at least a dispersion medium and silver halide grains, wherein 60% or more of the total projected area of the silver halide grains is occupied by tabular grains having an epitaxial junction, which grains each have a {100} face as a main plane and an aspect ratio (diameter/thickness ratio) of from 2.Type: GrantFiled: September 9, 1997Date of Patent: November 7, 2000Assignee: Fuji Photo Film Co.Inventors: Hideo Ikeda, Mitsuo Saitou
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Patent number: 6136523Abstract: The present invention allows one to use a phase I reactor to make thinner silver halide grains. This is accomplished by introducing the halide salt solution and the silver salt solution as close as possible to each other above the mixer head. The reactor is essentially divided into a micro reaction zone and a bulk reaction zone, thus, emulating the effect of a phase II or two stage reactor.Type: GrantFiled: May 23, 1995Date of Patent: October 24, 2000Assignee: Eastman Kodak CompanyInventors: Pierre Henri Jezequel, Ramesh Jagannathan
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Patent number: 6136524Abstract: A light-sensitive silver halide photographic emulsion has been described, said emulsion comprising a colloidally stabilizing binder and {100} tabular silver halide grains containing at least 50 mole % of silver chloride, wherein at least 70% by number of all grains is provided by said tabular grains, exhibiting an average aspect ratio of at least 5 and an average equivalent circular grain diameter of at least 0.3 .mu.m, wherein said tabular grains have an average thickness of less than 0.25 .mu.m for at least 75% by number of all tabular grains.Type: GrantFiled: February 24, 1999Date of Patent: October 24, 2000Assignee: Agfa-Gevaert, N.V.Inventors: Peter Verrept, Ann Verbeeck, Frank Louwet
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Patent number: 6127110Abstract: A silver halide emulsion in which in silver halide tabular grains having dislocation lines in a peripheral portion of a grain, no reduction sensitization is essentially performed before introduction of dislocation lines is started and reduction sensitization is performed after introduction of dislocation lines is started and before grain formation is completed, or a silver halide emulsion in which grain formation is performed in a silver nucleus stabilizing ambience and reduction sensitization is performed in the silver nucleus stabilizing ambience, and a silver halide photographic light-sensitive material using this emulsion.Type: GrantFiled: November 30, 1998Date of Patent: October 3, 2000Assignee: Fuji Photo Film Co., Ltd.Inventor: Mitsuhiro Uchida
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Patent number: 6117624Abstract: An infrared sensitized photothermographic silver halide element comprising a support layer having on at least one surface thereof a photothermographic composition comprising a binder, a light insensitive silver source, a reducing agent for silver ion and infrared radiation sensitive preformed silver halide grains having number average particle size of <0.10 micron with at least 80% of all grains with .+-.0.05 microns of the average, in combination with an antihalation layer having an absorbance ratio of IR absorbance (before exposure)/visible absorbance (after processing) >30, and an IR absorbance of at least 0.3 within the range of 750-1400 and an optical density of less than 0.03 in the visible region.Type: GrantFiled: August 24, 1999Date of Patent: September 12, 2000Assignee: Eastman Kodak CompanyInventors: Steven M. Shor, James B. Philip, Jr.
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Patent number: 6114081Abstract: There is disclosed a silver halide photographic light-sensitive material comprising a support having thereon at least one of spectrally sensitized light-sensitive silver halide emulsion layers, wherein at least one of the silver halide emulsion layers contains at least two kinds of silver halide emulsions, at least one kind of the emulsions being one in which silver halide grains have been formed and grown in the presence of at least one of nitrogen-containing heterocyclic compounds that are capable of forming a complex with silver; and at least one kind of the emulsions being one in which silver halide grains have been formed and grown in the absence of nitrogen-containing heterocyclic compounds that are capable of forming a complex with silver, and wherein at least one of the said emulsion layers or another hydrophilic colloid layer contains at least one hydrazine derivative nucleating agent, and also at least one nucleating accelerator selected from a group consisting of amine derivatives, onium salts, disType: GrantFiled: September 17, 1999Date of Patent: September 5, 2000Assignee: Fuji Photo Film Co., Ltd.Inventor: Tokuju Oikawa
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Patent number: 6100019Abstract: A process is disclosed of conducting in a single reaction vessel selective site high chloride epitaxy deposition as a continuation of host high bromide {1111} tabular grain emulsion precipitation. A host tabular grain emulsion is precipitated accounting for 0.05 to 1.5 moles of silver per liter of dispersing medium. Any iodide at the major faces of the tabular grains is uniformly distributed and any iodide in a surface region of the grains amounts to less than 7 mole, based on silver in the surface region. Until epitaxy is formed, pH is held in the range of 3 to 8. Gelatino-peptizer in an amount of 1 to 40 grams per Ag mole is added to the emulsion. Chloride ion in a range of from 0.03 to 0.15 mole per liter is dispersed in the emulsion. pBr is held in the range of from 3.0 to 3.8 until epitaxy is formed. Iodide ion in a concentration of from 5.times.10.sup.-6 to 1.times.10.sup.-4 mole per square meter of grain surface area is uniformly adsorbed to the major surfaces of the tabular grains.Type: GrantFiled: April 15, 1999Date of Patent: August 8, 2000Assignee: Eastman Kodak CompanyInventors: Thomas B. Brust, Philip J. Dale, Mark R. Mis, Donald L. Black
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Patent number: 6100020Abstract: The present invention relates to a process for the manufacturing of a silver halide element comprising a silver halide emulsion-making step, a chemical or optical sensitization step, and a silver halide emulsion coating step, characterized in that the process comprises the step of adding to the silver halide emulsion, after the chemical or optical sensitization step and before the coating step, an aryl compound having at least two substituents each of these represented by an hydroxyl group and/or a sulfonic group in an amount of less than 0.03 moles per mole of silver. The aryl compound increases the speed to Dmin ratio when used in a silver halide element.Type: GrantFiled: November 2, 1999Date of Patent: August 8, 2000Assignee: Eastman Kodak CompanyInventor: Alain D. Sismondi
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Patent number: 6100021Abstract: Provided is an improved sensitization method for photographic element. The photographic element comprises a support with at least one hydrophilic colloid layer coated thereon. The hydrophilic colloid layer comprises silver halide grains which are chemically sensitized with at least one compound represented by Formula 1:(OCH).sub.2 R.sup.1 (LHSO.sub.3).sub.2 Formula 1and at least one selenium compound.In formula 1, R.sup.1 represents an alkyl of 1-8 carbons; and L represents and alkali metal. The selenium compound is chosen from a group consisting of R.sup.2 SeCN, (R.sup.3).sub.3 PSe and ((R.sup.4).sub.2 NCO).sub.2 Se wherein R.sup.2 represents an alkyl of 1 to 8 carbons, or an alkali metal atom; R.sup.3 independently represents an aryl of 6 to 10 carbons or an alkyl of 1 to 8 carbons; and R.sup.4 independently represents an aryl of 6 to 10 carbons or an alkyl of 1 to 8 carbons.Type: GrantFiled: December 15, 1998Date of Patent: August 8, 2000Assignee: Agfa-Gevaert N.V.Inventors: Dietrich Max Fabricius, Allan R. Schoenberg
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Patent number: 6096495Abstract: A method for preparing a silver halide emulsion is disclosed, comprising introducing a silver salt solution and a halide solution through separate introduction tubes, mixing the silver salt and halide solutions to react a silver salt and a halide to form silver halide grains and discharging a reaction mixture solution through a discharge tube by the use of a mixing apparatus in which the introduction tubes and the discharge conduit are linked together so that all center axes of the introduction and discharge tubes intersect at a single point, wherein the silver salt solution and the halide solution are independently introduced at a linear velocity of not less than 4.0 m/sec and a Reynolds number of not less than 3,000.Type: GrantFiled: July 10, 1998Date of Patent: August 1, 2000Assignee: Konica CorporationInventors: Shigetami Kasai, Hisatake Okada
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Patent number: 6087085Abstract: A method is disclosed for preparing an emulsion having grains rich in silver bromide in the presence of gelatin as a protective colloid in a reaction vessel wherein a yield of more than 250 g of precipitated silver nitrate per liter of reaction vessel mixture is attained, wherein at least 70% of a total projected area of all grains is provided by {111} tabular grains having an average aspect ratio of more than 2:1 and an average thickness of from 0.05 up to 0.30 .mu.Type: GrantFiled: October 9, 1998Date of Patent: July 11, 2000Assignee: Agfa-Gevaert, N.V.Inventor: Kathy Elst
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Patent number: 6083678Abstract: A method has been described for preparing a light-sensitive silver halide photographic emulsion comprising performing at least three distinct precipitation steps in an aqueous medium into a reaction vessel, followed by desalting by means of flocculation and washing or by means of ultrafiltration, said emulsion comprising a colloidally stabilizing binder and {100} tabular silver halide grains containing at least 50 mole % of silver chloride, wherein at least 60% by number of all grains is provided by said tabular grains, and wherein said tabular grains exhibit an average aspect ratio of at least 2, an average thickness of at most 0.25 .mu.m with a variation coefficient of at most 0.25, and an average equivalent circular crystal diameter of 0.3 .mu.m or more with a variation coefficient of at most 0.Type: GrantFiled: October 9, 1998Date of Patent: July 4, 2000Assignee: Agfa-Gevaert, N.V.Inventors: Peter Verrept, Jan Cuypers
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Patent number: 6083679Abstract: The invention relates to a method of forming an emulsion comprising providing a silver chloride emulsion, said emulsion comprising silver chloride grains having a grain volume of 0.001 .mu.m.sup.3 to 2.2 .mu.m.sup.3, adding chemical and spectral sensitizing materials, heating said emulsion to sensitize said grains, cooling said emulsion, and then bringing said emulsion into contact with iodide and bromide.Type: GrantFiled: January 19, 1999Date of Patent: July 4, 2000Assignee: Eastman Kodak CompanyInventors: Karen J. Klingman, Susan K. Mroczek
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Patent number: 6080535Abstract: A silver halide emulsion is disclosed, comprising a dispersing medium and silver halide grains, wherein at least 50% by number of the silver halide grains is accounted for by tabular silver halide grains containing silver iodide, the tabular grains each meeting the following requirement:I.sub.1 >I.sub.2wherein I.sub.1 is a silver iodide content of an outermost layer in the major face region and I.sub.2 is a silver iodide content of an outermost layer in the side-face region.Type: GrantFiled: September 16, 1998Date of Patent: June 27, 2000Assignee: Konica CorporationInventor: Toshiya Kondo
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Patent number: 6080537Abstract: A silver halide emulsion is disclosed, comprising a dispersing medium and silver halide grains having a variation coefficient of grain size distribution of not more than 20%, at least 50% of total grain projected area of the emulsion being accounted for by tabular grains an aspect ratio of at least 5, the tabular grains each having a surface region having an iodide content more than an average iodide content of the grains, the tabular grains having dislocation lines in a central region and a peripheral region of the major faces, the peripheral region having a silver chalcogenide nucleus-containing phase, the central region having silver nucleus-containing phase, and the peripheral region having at least 10 dislocation lines per grain.Type: GrantFiled: April 26, 1999Date of Patent: June 27, 2000Assignee: Konica CorporationInventors: Hideo Sugimoto, Sadayasu Ishikawa
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Patent number: 6080536Abstract: A method has been described of preparing a photosensitive emulsion comprising tabular silver halide grains rich in silver bromide, having {100} major faces and an aspect ratio more than 1.5, wherein at least 50% of the projected area of all grains is provided by said {100} tabular grains, said method comprising the step of running in a reaction vessel an aqueous silver salt solution and an aqueous alkali halide solution rich in alkali bromide, characterized in that before starting running said reaction vessel comprises in an aqueous solution of gelatin an amount of amino-modified polyvinyl alcohol as an aqueous soluble polymer.Type: GrantFiled: March 15, 1999Date of Patent: June 27, 2000Assignee: Agfa-Gevaert, N.V.Inventors: Kathy Elst, Eddy Michiels, Gunter Helling
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Patent number: 6074811Abstract: A silver halide emulsion is described, which comprises at least a dispersion medium and silver halide grains, wherein from 40 to 100% of the total projected area of the entire silver halide grains are occupied by tabular grains having a thickness of from 0.01 to 0.50 .mu.m, an aspect ratio (diameter/thickness) of from 1.6 to 500, and main planes of {100} faces, and the aspect ratio of a right angled parallelogram surrounded by edge sides of {100} face of the tabular grains or a right angled parallelogram formed by extending the edge sides (long side length/short side length) is from 1 to 8, and the tabular grains are tabular grains formed by the adsorption of compound A.sup.0 represented by formula (Z.sup.1), (Z.sup.2), (Z.sup.3) or (Z.sup.4) onto silver halide grains:B.sup.1 --S--B.sup.2 (Z.sup.1)B.sup.1 --S(O)--B.sup.2 (Z.sup.2)B.sup.1 --S(O.sub.2)--B.sup.2 (Z.sup.3)B.sup.1 --S.sup.+ (R.sup.0)--B.sup.2 .multidot.Y.sub.0.sup.-(Z.sup.4)wherein B.sup.Type: GrantFiled: January 19, 1999Date of Patent: June 13, 2000Assignee: Fuji Photo Film Co., Ltd.Inventor: Mitsuo Saitou
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Patent number: 6074812Abstract: A method for desalting and dewatering a silver halide emulsion comprising removing soluble salts from the silver halide emulsion by electrodialysis, wherein the electrodialysis is carried out by passing a feed stream of the emulsion between an anion-exchange membrane and a cation-exchange membrane while a direct current voltage is applied between the anion-exchange and cation-exchange membranes so that ions are removed from the feed stream and transferred to a waste stream on the sides of the anion-exchange and cation-exchange membranes opposite to the feed stream, wherein a soluble material is added to the waste stream at a higher concentration with respect to the feed stream so as to establish a concentration gradient between the waste stream and the feed stream which drives osmotic dewatering of the feed stream during electrodialysis.Type: GrantFiled: May 14, 1999Date of Patent: June 13, 2000Assignee: Eastman Kodak CompanyInventor: Krishnan Chari
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Patent number: 6057089Abstract: A silver halide photographic light-sensitive material having at least one silver halide emulsion layer formed on a support, wherein silver halide grains in the emulsion layer are reduction-sensitized and contain at least one compound represented by formula (I) below. ##STR1## In formula (I), R is an alkyl group represented as follows. ##STR2## Each of R.sub.a, R.sub.b, R.sub.c, ad R.sub.d represents an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, or an amino group, each of Q.sub.a, Q.sub.b, Q.sub.c, and Q.sub.d represents a methylene group, and each of r, s, t, and u represents an integer from 1 to 10.Each of L.sub.1 and L.sub.2 represents a methine group. p1 represents 0 or 1. Z.sub.1 represents atom groups required to neutralize a 5- or 6-membered nitrogen-containing heterocyclic ring. M.sub.1 represents a charge-balancing counterion, and m.sub.1 represents a number from 0 to 10 required to form electric charge of a molecule.Type: GrantFiled: January 16, 1997Date of Patent: May 2, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Jun Matsumoto, Takanori Hioki, Tetsuo Nakamura
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Patent number: 6048681Abstract: Disclosed is a silver halide photographic material having at least one silver halide emulsion layer containing a silver halide photographic emulsion, wherein the silver halide photographic emulsion comprises spectrally sensitized tabular silver halide grains having an average aspect ratio of from 8 to 100, and having light absorption strength by a sensitizing dye per unit surface area of the grain surface of 100 or more.Type: GrantFiled: October 22, 1998Date of Patent: April 11, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Takeshi Suzumoto, Shigeharu Urabe, Katsuhiro Yamashita
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Patent number: 6048683Abstract: A method is disclosed of manufacturing radiation-sensitive emulsions by a pulsed flow double-jet process in which high chloride silver halide grains are grown in the presence of a thioether ripening agent in the dispersing medium in the reaction vessel the silver halide grains exhibiting an average grain roundness coefficient n in the range of from 2 to less than 15.Type: GrantFiled: December 22, 1998Date of Patent: April 11, 2000Assignee: Eastman Kodak CompanyInventors: Rajesh V. Mehta, Ramesh Jagannathan, Y. Chea Chang