Abstract: Provided is a charging roller that can achieve excellent image quality and prevent detachment of particles in its surface layer. A charging roller 1 comprises a shaft 2 and, on an outer circumferential side of the shaft 2, at least a base layer 3 and a surface layer 4, wherein the surface layer 4 contains a binder resin 41 and particles 42, and the particles 42 contain 50 mass % or more of a same component A as at least one selected from components constituting the binder resin 41, and a content of the particles in the surface layer is 30 parts to 120 parts by mass with respect to 100 parts by mass of the binder resin.
Abstract: There is provided an electrophotographic photoconductor in which at least an undercoat layer and a photosensitive layer are laminated in an order mentioned on a conductive support, wherein at least one of the undercoat layer and the photosensitive layer contains a compound represented by a formula A below: wherein Y in the above formula A is a group represented by: wherein R1 and R2 are each independently an alkyl group having 1 to 6 carbon atoms, m is an integer of 1 to 4, and X is each independently a group selected from a group 1 below: wherein R3 to R8 in the above group 1 are each independently an alkyl group having 1 to 6 carbon atoms.
Abstract: An electrophotographic photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3). The photosensitive layer (3) is a single-layer photosensitive layer. The photosensitive layer (3) contains at least a charge generating material, a hole transport material, an electron transport material, and a binder resin. The charge generating material includes a metal-free phthalocyanine. The hole transport material includes a triphenylamine derivative represented by general formula (1) shown below. The electron transport material includes a quinone derivative represented by general formula (2) shown below. In general formula (1), R1, R2, R3, m1, m2, k, p, and q are the same as those described in the description. In general formula (2), R4, R5, and R6 are the same as those described in the description.
Abstract: The present invention relates to phosphorescent organic light-emitting diodes (OLEDs) including a hole-transporting or a hole-transporting and an electron-blocking layer including an N,N,N?,N?-tetraaryl-phenylene-3,5-diamine or an N,N,N?,N?-tetraaryl-1,1?-biphenyl-3,3?-diamine matrix compound and to new N,N,N?,N?-tetraarylsubstituted m-arylene diamine compounds useful as hole-transporting and electron-blocking layer matrices in phosphorescent OLEDs.
Type:
Grant
Filed:
March 1, 2019
Date of Patent:
December 15, 2020
Assignee:
Novaled GmbH
Inventors:
Mike Zöllner, Jens Wutke, Martin Burkhardt
Abstract: Disclosed is a fluorine-containing composition containing a fluorine-containing compound represented by general formula (1) and a fluorine-based solvent.
Abstract: The present invention relates to phosphorescent organic light-emitting diodes (OLEDs) comprising a hole-transporting or a hole-transporting and an electron-blocking layer comprising an N,N,N?,N?-tetraaryl-phenylene-3,5-diamine or an N,N,N?,N?-tetraaryl-1,1?-biphenyl-3,3?-diamine matrix compound and to new N,N,N?,N?-tetraarylsubstituted m-arylene diamine compounds useful as hole-transporting and electron-blocking layer matrices in phosphorescent OLEDs.
Type:
Grant
Filed:
October 17, 2013
Date of Patent:
March 26, 2019
Assignee:
Novaled GmbH
Inventors:
Mike Zoellner, Jens Wutke, Martin Burkhardt
Abstract: In an electrophotographic photosensitive member including a support and a photosensitive layer formed on the support, a surface layer of the electrophotographic photosensitive member contains a cured product obtained by copolymerizing at least one compound (i) selected from the group consisting of a triphenylamine compound having a hydroxymethyl group and a benzidine compound having a hydroxymethyl group, and at least one compound (ii) selected from the group consisting of a compound represented by the following formula (1), a compound represented by the following formula (2), a compound represented by the following formula (3), and a compound represented by the following formula (4):
Abstract: In a negatively-chargeable laminate-type electrophotographic photoreceptor, a charge generation layer and another charge transport layer are arranged on a conductive substrate directly or via an intermediate layer. The charge transport layer contains at least a hole-transporting substance, an electron-transporting substance and a binder resin; the mass ratio (RPN) [% by mass] between mass (P) of the hole-transporting substance and mass (N) of the electron-transporting substance is represented by the following equation (1), and satisfies the following equation (2): RPN=(N/(P+N))×100??(1) 1?RPN?40??(2); and when a voltage of +6 kV is applied to the photoreceptor for 5 seconds via a resin sheet having a thickness of 50 ?m and a surface resistivity of 2×107 ?/cm2, the surface potential difference (?Vo) and half-tone potential difference (?Vh) between before and after the voltage application are both 15 V or less.
Abstract: An intermediate transfer member that includes a mixture of a polymer, a vinyl acetate crotonic acid copolymer, an optional conductive component, an optional fluoropolymer, and an optional polysiloxane.
Abstract: An electrophotographic photosensitive member includes a laminated body including a conductive support, a first intermediate layer on the conductive support, and a second intermediate layer on the first intermediate layer, the first intermediate layer containing a binder resin and a metal oxide particle whose surface have been treated with an organic compound, and the second intermediate layer containing a cured product having electron transportability, in which the laminated body satisfies the following expression (1): R—nV/R_0V?0.
Abstract: A photoreceptor includes a substrate a charge generating layer disposed on the substrate and a charge transport layer disposed on the charge generating layer, the charge transport layer includes a hole transport molecule, a fluorinated diol, and a leveling agent, the charge transport layer is substantially free of a polymer binder and catalyst, and has a post-discharge voltage of less than about 10 volts.
Type:
Application
Filed:
September 4, 2013
Publication date:
March 5, 2015
Applicant:
XEROX CORPORATION
Inventors:
Gregory McGuire, Sarah J. Vella, Adrien P. Cote, Yvan Gagnon, Brynn Dooley
Abstract: An electrophotographic photosensitive member that includes the outermost surface layer formed by curing a mixture of a charge transporting substance having a chain-polymerizable functional group and a urea compound represented by the following formula (1) or (2), and a process cartridge and an electrophotographic apparatus each including the electrophotographic photosensitive member.
Abstract: An electrophotographic photoreceptor includes a conductive support and a photosensitive layer and a surface protection layer that are sequentially laminated on the conductive support. The surface protection layer contains a binder resin and inorganic fine particles surface-treated with a hole transporting compound of the following General Formula 1. A?R1-Q1)k??[General Formula 1] A is a hole transporting group. Q1 is an acidic group. R1 is a substituted or non-substituted alkylene, alkenylene or arylene group. k is a positive integer of 1 or more. If k is an integer of 2 or more, each of R1 and Q1 are same or different.
Abstract: A photoreceptor for electrophotography includes a photosensitive layer provided on a conductive substrate that contains at least a resin binder, a charge transport material, and an additive. The photoreceptor exhibits high photoresponsivity, stable electrical properties regardless of repeated use thereof, and high durability. The resin binder contains a polycarbonate resin composed of a copolymer having structural units expressed by general formulae (1) and (2) below. The charge transport material contains at least one type of stilbene compound expressed by general formulae (3), (4), and (5) below. The additive contains at least one type of diester compound expressed by general formula (6) below.
Abstract: An electrophotographic photoreceptor including an electroconductive substrate, a charge generation layer located overlying the electroconductive substrate, a hole transport layer located on the charge generation layer, and a hole transport protective layer located on the hole transport layer. The hole transport protective layer includes a three-dimensionally crosslinked material obtained by irradiating a composition including at least a radically polymerizable hole transport compound with ultraviolet rays or electron beams so that the radically polymerizable hole transport compound causes chain polymerization. In addition, the protective layer includes a specific cyano-containing styryl aromatic compound or a specific cyano-containing distyryl aromatic compound.
Type:
Grant
Filed:
September 22, 2011
Date of Patent:
September 16, 2014
Assignee:
Ricoh Company, Ltd.
Inventors:
Kazukiyo Nagai, Tetsuro Suzuki, Hongguo Li
Abstract: An electrophotographic photoreceptor includes a conductive substrate, a photosensitive layer, and a surface layer that is provided on the photosensitive layer. The surface layer includes a cross-linked component which is a reaction product of compound A and compound B. The compound A is at least one compound selected from guanamine compounds and melamine compounds, and the compound B is a charge-transporting material. A structure derived from at least one compound selected from the guanamine compounds and the melamine compounds included in the surface layer amounts for 0.1% by weight to 5% by weight, and a structure derived from the charge-transporting material included in the surface layer amounts for 85% by weight or greater. Surface roughness Rz of the surface layer is from 0.1 ?m to 0.3 ?m, and the surface has at least one compound selected from fatty acid metal salt and fluorine resin particles.
Abstract: An electrophotographic photoreceptor includes a conductive substrate; and a single-layer photosensitive layer that is provided on the conductive substrate and includes a binder resin, at least one kind of charge generation material selected from hydroxygallium phthalocyanine pigments and chlorogallium phthalocyanine pigments, a hole transport material represented by Formula (1), and an electron transport material represented by Formula (2):
Abstract: An overcoat layer for an organic photoconductor drum of an electrophotographic image forming device is provided. The overcoat layer is prepared from a curable composition including a urethane methacrylate functional charge transport molecule, and a photoinitiator. The urethane acrylate functional charge transport molecule is a reaction product of hydroxyl functional charge transport molecule and a monomer having an isocyanate group and an acrylate group. This overcoat layer improves wear resistance of the organic photoconductor drum without negatively altering the electrophotographic properties, thus protecting the organic photoconductor drum from damage and extending its useful life.
Abstract: An electrophotographic photosensitive member includes a support and a photosensitive layer formed on the support. A surface layer of the electrophotographic photosensitive member contains a polymerized product of a composition that contains a charge transporting compound having a particular group (chain polymerizable functional group).
Abstract: The invention can provide an electrophotographic photoreceptor comprising a photosensitive layer containing a specific charge transport material and a specific copolymerized polycarbonate resin, and an image-forming apparatus and an electrophotographic cartridge which use the electrophotographic photoreceptor.
Abstract: An electrophotographic photoreceptor includes a conductive substrate; and a photosensitive layer on the conductive substrate, wherein a layer having an outermost surface of the photoreceptor contains a polymer that is formed by polymerizing a crosslinkable charge transport material having an aromatic group and a —CH2OH group, and the layer having the outermost surface satisfies the following Formula (1): (Peak 2)/(Peak 1)?0.05??(1) wherein Peak 1 represents a peak area of an absorption peak (from about 1550 cm?1 to about 1650 cm?1) of stretching vibration of an aromatic group, which is obtained when an infrared absorption spectrum of the layer having the outermost surface is measured, and Peak 2 represents a peak area of an absorption peak (from about 1670 cm?1 to about 1710 cm?1) of an aromatic aldehyde, which is obtained when the infrared absorption spectrum of the layer having the outermost surface is measured.
Abstract: There is provided an electrophotographic photoreceptor including a conductive substrate; an intermediate layer; a photosensitive layer; and a surface layer, in this order, the surface layer including two or more charge transporting materials each including a reactive substituent and respectively having mutually different ionization potentials, in an amount of 90% by weight or more relative to the total solid content of the surface layer, and the content ratio X of each of the two or more charge transporting materials satisfying the following Formula (1).
Abstract: To provide: a latent electrostatic image bearing member including one of a cured material obtained through radical polymerization of a radically polymerizable compound of component (A1), and a cured material obtained through radical polymerization of a radically polymerizable compound of component (A2) in the outermost layer, wherein the component (A1) includes two radically polymerizable groups and a substituted amino group which does not include a radically polymerizable group in a molecule, and the radically polymerizable group and the nearest substituted amino group which does not include an unsaturated bond in between are connected with two or more aromatic hydrocarbon compounds, and, the radically polymerizable compound of component (A2) includes a condensed polycyclic aromatic hydrocarbon formed by bonding a radically polymerizable group and a non-radically polymerizable substituted amine group through a condensed polycyclic aromatic hydrocarbon group; and an image forming apparatus, image forming meth
Abstract: An electrophotographic photosensitive member has a laminated body, and a hole transporting layer formed on the laminated body, wherein the laminated body is a laminated body having a conductive support, an electron transporting layer and a charge generating layer. When an impedance is measured by forming a circular-shaped gold electrode having a thickness of 300 nm and a diameter of 10 mm on a surface of the charge generating layer of the laminated body by sputtering, and applying an alternating electric field of 100 mV and 0.1 Hz between the conductive support and the gold electrode, the laminated body of the electrophotographic photosensitive member satisfies the following expression (1): R_opt/R_dark?0.
Abstract: An electrophotographic photoreceptor includes a conductive substrate; a single-layer photosensitive layer that is provided on the conductive substrate and includes a binder resin, a charge generation material, a hole transport material, and an electron transport material, wherein a half decay exposure during positive charging is less than or equal to 0.18 ?J/cm2, and a half decay exposure during negative charging is 2 to 12 times the half decay exposure during positive charging.
Abstract: An electrophotographic photoreceptor includes a conductive substrate, a photosensitive layer, and a surface layer that is provided on the photosensitive layer. The surface layer includes a cross-linked component which is a reaction product of compound A and compound B. The compound A is at least one compound selected from guanamine compounds and melamine compounds, and the compound B is a charge-transporting material. A structure derived from at least one compound selected from the guanamine compounds and the melamine compounds included in the surface layer amounts for 0.1% by weight to 5% by weight, and a structure derived from the charge-transporting material included in the surface layer amounts for 85% by weight or greater. Surface roughness Rz of the surface layer is from 0.1 ?m to 0.3 ?m, and the surface has at least one compound selected from fatty acid metal salt and fluorine resin particles.
Abstract: A photoconductor that includes a supporting substrate, an optional ground plane layer, an optional hole blocking layer, an optional adhesive layer, a photogenerating layer, and at least one charge transport layer, and where the charge transport layer contains a biaryl polycarbonate, or a mixture of a biaryl polycarbonate and a second polymer such as a polycarbonate.
Abstract: Improved electrophotographic imaging members which pertain to the incorporation of a fluoroketone into the charge transport layer to achieve a structurally simplified flexible electrophotographic imaging member that remains flat without the need for an anticurl back coating layer. The imaging member is both more slippery and has a reduced coefficient of friction, thus extending service life.
Abstract: An image bearing member including an electroconductive substrate, a photosensitive layer provided overlying the electroconductive substrate, and a furan derivative represented by the following chemical structure 1, where Ar1 and Ar2 independently represent substituted or non-substituted aryl groups and R1 represents an alkylene group having one to six carbon atoms.
Abstract: A photoconductor that includes an optional anticurl layer, optional supporting substrate, an optional ground plane layer, an optional hole blocking layer, an optional ground strip segment, an optional adhesive layer, a photogenerating layer, and a charge transport layer that contains an acrylonitrile-butadiene-styrene polymer.
Abstract: An electrophotographic photoconductor containing at least a charge generation material and a charge transport material on a conductive support, the electrophotographic photoconductor comprising a diamine compound represented by the formula (1), and also a polyarylate resin having a structural unit represented by the following formula (I).
Abstract: An electrophotographic photoreceptor including a conductive substrate and a photosensitive layer located overlying the conductive substrate. The photosensitive layer comprises a specific diamine compound.
Abstract: An electrophotographic photoreceptor comprising: a conductive substrate; a photosensitive layer formed on the conductive substrate; and an outermost surface layer that is a layer made of a cured material of a composition including at least one compound represented by the following formula (I) and at least one compound having charge transportability and an azo group: wherein in formula (I), F represents an n-valent organic group having a hole transporting property, R represents a hydrogen atom or an alkyl group, L represents a divalent organic group, n represents an integer of 1 or more, and j represents 0 or 1.
Abstract: A photoconductor that includes a supporting substrate, an optional ground plane layer, an optional hole blocking layer, an optional adhesive layer, a photogenerating layer, and at least one charge transport layer, and where the charge transport layer contains a polyalkylene glycol benzoate and a fluorinated polymer.
Type:
Grant
Filed:
May 26, 2010
Date of Patent:
September 18, 2012
Assignee:
Xerox Corporation
Inventors:
Jin Wu, Kenny-Tuan T Dinh, Linda L Ferrarese, Marc J Livecchi, Edward C Savage, Michael E Zak
Abstract: The presently disclosed embodiments are directed generally to an improved electrostatographic imaging member in which the overcoat layer comprises cross-linkable polyester resins. The overcoat layer not only provides wear resistance, but it also provides higher charge transport efficiency and therefore better photoelectrical properties. In addition, the polyesters can cross-link with a variety of resins and thus provide good adhesion as well.
Type:
Grant
Filed:
September 28, 2009
Date of Patent:
September 4, 2012
Assignee:
Xerox Corporation
Inventors:
Liang-Bih Lin, Brian P. Gilmartin, Emily K. Redman, Marc J. LiVecchi
Abstract: Embodiments provide novel imaging members used in electrostatography. More particularly, there is provided flexible electrophotographic imaging members which have improved imaging layer(s) formulated to comprise of a plasticizer in a material matrix of a solid solution comprising a charge transporting compound and a film forming polymer binder which is a novel A-B diblock copolymer or a binary polymer blend of a novel A-B diblock copolymer and a bisphenol polycarbonate. The flexible imaging members thus prepared have improved photoelectrical cyclic function stability, chemical resistive property, and are curl-free, and thus eliminate the need for an additional anticurl back coating layer.
Type:
Application
Filed:
February 24, 2011
Publication date:
August 30, 2012
Applicant:
XEROX CORPORATION
Inventors:
Robert C.U. Yu, Stephen T. Avery, Jimmy E. Kelly
Abstract: An image forming apparatus comprising an electrophotographic photoreceptor having a photosensitive layer on an electroconductive substrate, and a toner for developing an electrostatic charge image, wherein the photosensitive layer of the electrophotographic photoreceptor contains a phthalocyanine obtained via an acid paste step; the toner for developing an electrostatic charge image is a toner for developing an electrostatic charge image containing toner matrix particles formed in an aqueous medium; the toner has a volume median diameter (Dv50) of from 4.0 ?m to 7.0 ?m; and the relationship between the volume median diameter (Dv50) and the percentage in number (Dns) of toner particles having a particle diameter of from 2.00 ?m to 3.56 ?m satisfies the following formula (1): Dns?0.233 EXP(17.3/Dv50)??(1).
Abstract: There provides an electrophotographic photoreceptor using a novel amine compound which has an excellent effect of ozone resistance and can be used for providing an electrophotographic photoreceptor having no adverse effect on other characteristics, and an image forming apparatus including the photoreceptor. The aim is attained by an electrophotographic photoreceptor formed by stacking a single layer type photosensitive layer containing a charge generating material and a charge transporting material, or a layered photosensitive layer, in which a charge generation layer containing a charge generating material and a charge transporting layer containing a charge transporting material are stacked in this order, on a conductive substrate made of a conductive material, wherein the single layer type photosensitive layer or the charge transporting layer of the layered photosensitive layer contains a specific amine compound.
Abstract: A photoconductor that includes a supporting substrate, a ground plane layer, a hole blocking layer, an adhesive layer, a photogenerating layer, and at least one charge transport layer of a charge transporting polycarbonate or a mixture of a charge transporting polycarbonate and a second polymer such as a polycarbonate.
Abstract: An electrophotographic photoreceptor is provided that contains a conductive substrate, an undercoat layer, a charge generation layer, and a charge transport layer, wherein the under coat layer contains a binder resin and multiple inorganic pigments each having different average primary particle diameters in a total amount of from 75 to 86% by weight, the charge generation layer contains a binder resin and a titanyl phthalocyanine pigment having a specific X-ray diffraction spectrum in an amount of from 70 to 85% by weight, the charge transport layer comprises a specific distyryl compound, and the following formulae (2-1) to (2-3) are satisfied: 0.2?(D(F2)/D(G))?0.5??(2-1) 0.2?D(F1)??(2-2) D(F2)?D(F1)??(2-3) wherein D(F1) (?m) and D(F2) (?m) represent average primary particle diameters of the largest and smallest inorganic pigments, respectively, and D(G) (?m) represents an average primary particle diameter of the titanyl phthalocyanine pigment.
Type:
Grant
Filed:
June 23, 2009
Date of Patent:
May 15, 2012
Assignee:
Ricoh Company, Ltd.
Inventors:
Hiromi Tada, Nozomu Tamoto, Tomoyuki Shimada, Takafumi Iwamoto
Abstract: A photoconductor that includes a supporting substrate, an optional ground plane layer, an optional hole blocking layer, an optional adhesive layer, a photogenerating layer, and at least one charge transport layer, and where the charge transport layer contains a biaryl polycarbonate, or a mixture of a biaryl polycarbonate and a second polymer such as a polycarbonate.
Abstract: A photoconductor that includes a supporting substrate, an optional ground plane layer, an optional hole blocking layer, an optional adhesive layer, a photogenerating layer, and at least one charge transport layer, and where the charge transport layer contains a spirodilactam based polycarbonate.
Abstract: The present invention relates to a polyvinyl acetal resin having a specific repeating structural unit, an electrophotographic photosensitive member using the polyvinyl acetal resin, and a process cartridge and an electrophotographic apparatus each having the electrophotographic photosensitive member.
Abstract: A photoconductor that includes a backing layer, a supporting substrate thereover, a photogenerating layer, and at least one charge transport layer of at least one charge transport component, and wherein the backing layer is in contact with the supporting substrate on the reverse side thereof, and the outermost layer of the backing layer is comprised of a polyurethane comprised of a dendritic polyester polyol and a polyisocyanate.
Abstract: An electrophotographic photoreceptor comprising a conductive support and a photosensitive layer obtained by laminating at least a charge generation layer and a charge transport layer containing a charge transport material in this order on the conductive support, the photosensitive layer being provided with a surface protective layer on the surface thereof, wherein the protective layer contains at least filler particles which exhibit a dispersed state defined by Rf given by the following equations (1) and (2): Rf=(df×b3)/(dm×a3)??(1) 1.0×10?3?Rf?2.
Abstract: A photoconductor that includes a supporting substrate, an optional ground plane layer, an optional hole blocking layer, an optional adhesive layer, a photogenerating layer, and at least one charge transport layer, and where the charge transport layer contains a polyalkylene glycol benzoate and a fluorinated polymer.
Type:
Application
Filed:
May 26, 2010
Publication date:
December 1, 2011
Applicant:
XEROX CORPORATION
Inventors:
Jin Wu, Kenny-Tuan T. Dinh, Linda L. Ferrarese, Marc J. Livecchi, Edward C. Savage, Michael E. Zak
Abstract: A photoconductor that includes, for example, a backing layer, a supporting substrate, a photogenerating layer, and a charge transport layer, and where the outermost layer of the backing layer is comprised of a mixture of a glycoluril resin and a polyol resin.
Abstract: To provide: a latent electrostatic image bearing member including one of a cured material obtained through radical polymerization of a radically polymerizable compound of component (A1), and a cured material obtained through radical polymerization of a radically polymerizable compound of component (A2) in the outermost layer, wherein the component (A1) includes two radically polymerizable groups and a substituted amino group which does not include a radically polymerizable group in a molecule, and the radically polymerizable group and the nearest substituted amino group which does not include an unsaturated bond in between are connected with two or more aromatic hydrocarbon compounds, and, the radically polymerizable compound of component (A2) includes a condensed polycyclic aromatic hydrocarbon formed by bonding a radically polymerizable group and a non-radically polymerizable substituted amine group through a condensed polycyclic aromatic hydrocarbon group; and an image forming apparatus, image forming meth