Hydrazone Containing Patents (Class 430/58.4)
Additional nitrogen attached indirectly to the hydrazone group by nonionic bonding (Class 430/58.45)
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Patent number: 11269263Abstract: A bischloroformate composition is represented by a formula (1) below, contains a plurality of Ar components, and has an average number of monomer units (m1), which is calculated by an expression (Numerical Expression 1) below, ranging from 1.0 to 1.99. The plurality of Ar components are each independently Ar1 or Ar2. The plurality of Ar components include at least one Ar1 and at least one Ar2. Ar1 is a group represented by a formula (2) below. Ar2 is a group represented by a formula (3) below. A molar composition ratio represented by Ar1/(Ar1+Ar2) ranges from 45 mol % to 99 mol %.Type: GrantFiled: December 16, 2016Date of Patent: March 8, 2022Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Kengo Hirata, Takaaki Hikosaka, Hironobu Morishita
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Patent number: 10954396Abstract: The present invention provides a nickel nanowires-containing paste having an adequately high thermal curing rate even under comparatively low temperature, which is excellent in functional properties such as an electrical conductivity, strength properties (in particular, a bending property), a water-resisting property, a salt water-resisting property and electromagnetic-wave shielding properties, from which a cured structure excellent in an electrical conductivity can be obtained even if it is stored for a long time. The present invention relates to a paste comprising nickel nanowires, an alkoxy-alkylated polyamide and a glycol.Type: GrantFiled: October 1, 2018Date of Patent: March 23, 2021Assignee: UNITIKA LTD.Inventors: Hirotaka Takeda, Chikako Yamada
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Patent number: 9243322Abstract: Methods for applying a coating to a substrate in rolled form, the substrate including a first edge face and a second edge face opposite the first edge face, the substrate further having a first major surface and a second major surface opposite the first major surface, the first and second major surfaces extending between the first edge face and the second edge face, the methods including applying a coating to at least one edge face and optionally at least a portion of one or both major surfaces of the substrate in rolled form. Articles in rolled form prepared according to the foregoing methods are also disclosed.Type: GrantFiled: October 26, 2012Date of Patent: January 26, 2016Assignee: 3M INNOVATIVE PROPERTIES COMPANYInventors: Bill H. Dodge, David K. Cinader, Jr., MaThazin Aung, Artin Margharian
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Patent number: 9184317Abstract: Photovoltaic cells, as well as related systems, methods, modules, and components, are disclosed.Type: GrantFiled: April 2, 2008Date of Patent: November 10, 2015Assignee: MERCK PATENT GMBHInventors: Christoph Brabec, Jens Hauch, Russell Gaudiana, Andrea Welte, Jin-An He, Eitan C. Zeira
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Patent number: 9052645Abstract: An intermediate transfer member that includes polyarylatecarbonate, an optional polysiloxane, and an optional conductive filler component.Type: GrantFiled: April 13, 2013Date of Patent: June 9, 2015Assignee: Xerox CorporationInventor: Jin Wu
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Publication number: 20150064614Abstract: A photoreceptor includes a substrate a charge generating layer disposed on the substrate and a charge transport layer disposed on the charge generating layer, the charge transport layer includes a hole transport molecule, a fluorinated diol, and a leveling agent, the charge transport layer is substantially free of a polymer binder and catalyst, and has a post-discharge voltage of less than about 10 volts.Type: ApplicationFiled: September 4, 2013Publication date: March 5, 2015Applicant: XEROX CORPORATIONInventors: Gregory McGuire, Sarah J. Vella, Adrien P. Cote, Yvan Gagnon, Brynn Dooley
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Patent number: 8609310Abstract: An electrophotographic photoreceptor has at least an electroconductive substrate, and a photosensitive layer formed on or above the electroconductive substrate, wherein an outermost layer of the photoreceptor is a cured membrane of a composition containing at least one compound (a) having in a single molecule thereof a charge transporting skeleton and a chain polymerizable functional group, and at least one thermopolymerizable or photopolymerizable silicone polymeric radical polymerization initiator (b).Type: GrantFiled: August 14, 2009Date of Patent: December 17, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Hitoshi Takimoto, Akira Hirano, Takatsugu Doi, Wataru Yamada, Katsumi Nukada
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Patent number: 8404413Abstract: Present embodiments are directed to the preparation of curl-free flexible imaging members used in electrostatography. More particularly, the embodiments pertain to a structurally simplified flexible electrophotographic imaging member, including the incorporation of a plasticizer or a blend of plasticizers in the imaging layer(s) to effect imaging layer(s) stress relieving outcome for curl control without the need of an anticurl back coating, and methods for making and using the imaging member.Type: GrantFiled: May 18, 2010Date of Patent: March 26, 2013Assignee: Xerox CorporationInventors: Robert C. U. Yu, Yuhua Tong
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Patent number: 8404411Abstract: An electrophotographic photoreceptor having high sensitivity and hardly affected by the transfer in an electrophotographic process is provided. The electrophotographic photoreceptor includes an undercoat layer containing metal oxide particles and a binder resin and a photosensitive layer disposed on the undercoat layer, wherein the metal oxide particles have a volume average particle diameter of 0.1 ?m or less and a 90% cumulative particle diameter of 0.3 ?m or less which are measured by a dynamic light-scattering method in a liquid of the undercoat layer dispersed in a solvent mixture of methanol and 1-propanol at a weight ratio of 7:3, and the photosensitive layer contains a binder resin having an ester bond.Type: GrantFiled: May 18, 2007Date of Patent: March 26, 2013Assignee: Mitsubishi Chemical CorporationInventors: Teruyuki Mitsumori, Kozo Ishio, Hiroe Fuchigami, Hiroaki Takamura, Yasunori Kawai
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Publication number: 20130022902Abstract: An electrophotographic photoreceptor including an electroconductive substrate; a charge generation layer located overlying the electroconductive substrate; a charge transport layer located overlying the charge generation layer; and an outermost layer located overlying the charge transport layer. The charge transport layer includes a positive hole transport material having the following formula (1): wherein each of R1 to R26 independently represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or an alkoxyl group having 1 to 4 carbon atoms, and a compound having the following formula (2): wherein each of R27 and R28 independently represents a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group.Type: ApplicationFiled: July 13, 2012Publication date: January 24, 2013Inventors: Keisuke Shimoyama, Hideo Nakamori, Noboru Toriu, Mitsuaki Hirose, Tomoharu Asano
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Patent number: 8211603Abstract: An electrophotographic imaging member includes a substrate, a photogenerating layer, and an optional overcoating layer, where the photogenerating layer includes a chemically functionalized carbon nanotube material.Type: GrantFiled: August 8, 2006Date of Patent: July 3, 2012Assignee: Xerox CorporationInventors: Timothy P. Bender, James D. Mayo
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Publication number: 20110195354Abstract: The present invention provides an electrophotographic photoreceptor including a photosensitive layer on a conductive substrate, an outermost layer of the electrophotographic photoreceptor including a cured film of a composition which includes at least one charge transporting compound (a) having a charge transporting skeleton and at least two structural units represented by R—O—CO—CR??CH—R? in the same molecule, and at least one polycarbonate resin; a ratio (IA/IC) of an absorption peak intensity (IA) resulting from stretching vibration of a carbonyl group originating from the structural unit represented by R—O—CO—CR??CH—R? of the charge transporting compound (a) to an absorption peak intensity (IC) resulting from stretching vibration of a carbonyl group originating from the polycarbonate resin in an IR absorption spectrum of the outermost layer being from about 0.5 to about 10, and a width at half maximum of the absorption peak of the absorption peak intensity (IA) being about 25 cm?1 or more.Type: ApplicationFiled: September 8, 2010Publication date: August 11, 2011Applicant: FUJI XEROX CO., LTD.Inventors: Katsumi NUKADA, Wataru YAMADA, Tsuyoshi MIYAMOTO, Kenya SONOBE, Takatsugu DOI
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Publication number: 20110091799Abstract: In an electrophotographic photoreceptor having a photosensitive layer on an electroconductive substrate, the photosensitive layer is a positive-charging laminate comprising at least a charge transport layer and a charge generating layer laminated in that order, with the charge generating layer containing at least a resin binder, a charge generating agent, a space filler and an electron transport agent, while the charge transport layer contains at least, as a resin binder, polystyrene and a hole transport agent, and mineral oil of the charge transport layer is in an amount of 1% by mass or less of an amount of polystyrene. Thus, a highly durable and economic positive-charging multilayer electrophotographic photoreceptor and a manufacturing method therefor may be achieved.Type: ApplicationFiled: May 28, 2009Publication date: April 21, 2011Inventors: Yoichi Nakamura, Seizo Kitagawa, Hiroshi Emori, Yasushi Tanaka, Hiroyuki Ichiyanagi
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Publication number: 20100233601Abstract: An electrophotographic photoreceptor has at least an electroconductive substrate, and a photosensitive layer formed on or above the electroconductive substrate, wherein an outermost layer of the photoreceptor is a cured membrane of a composition containing at least one compound (a) having in a single molecule thereof a charge transporting skeleton and a chain polymerizable functional group, and at least one thermopolymerizable or photopolymerizable silicone polymeric radical polymerization initiator (b).Type: ApplicationFiled: August 14, 2009Publication date: September 16, 2010Applicant: FUJI XEROX CO., LTD.Inventors: Hitoshi TAKIMOTO, Akira HIRANO, Takatsugu DOI, Wataru YAMADA, Katsumi NUKADA
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Patent number: 7674565Abstract: A photoconductive having an overcoat layer that includes a cured or substantially crosslinked product of at least a melamine-formaldehyde resin and a charge transport compound, and an optional phenol compound.Type: GrantFiled: July 25, 2006Date of Patent: March 9, 2010Assignee: Xerox CorporationInventors: Yu Qi, Nan-Xing Hu
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Patent number: 7635548Abstract: An electrophotographic imaging member includes a substrate, a photogenerating layer, and an optional overcoating layer, where the photogenerating layer includes a self-assembled carbon nanotube material having pendant charge transport materials.Type: GrantFiled: August 8, 2006Date of Patent: December 22, 2009Assignee: Xerox CorporationInventor: Timothy P. Bender
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Patent number: 7553592Abstract: An electrophotographic imaging member includes at least one layer including a hole transport material and a strong electron acceptor material, such as an electrophotographic imaging member including a substrate, a charge generating layer, a hole transport layer, and an optional overcoating layer, wherein at least one layer of the electrophotographic imaging member comprises a strong electron acceptor material.Type: GrantFiled: June 5, 2006Date of Patent: June 30, 2009Assignee: Xerox CorporationInventors: Hany Aziz, Gregory McGuire, Johann Junginger
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Patent number: 7547842Abstract: Disclosed herein is an organic electronic device comprising a charge transport layer comprising a host charge transport material and a guest charge transport material, wherein the guest material is not homogeneously distributed in the host material and is spatially doped within the host material. The charge transport layer may be either a hole or electron transport layer and is useful in a variety of organic electronic devices.Type: GrantFiled: October 17, 2007Date of Patent: June 16, 2009Inventor: Ying Wang
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Patent number: 7534541Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula: where n is an integer between 1 and 10, inclusive; R1 comprises a functional group selected from the group consisting of a reactive ring group, an ethylenically unsaturated group, a reactive polar group, a hydrazone group, and an azine group; R2, R3, R4, R5, and R6 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, a heterocyclic group, or a part of a ring group; X is a bond or a linking group; and Q is O, S, or NR where R is H, an alkyl group, an acyl group, an alkenyl group, an alkynyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound.Type: GrantFiled: January 27, 2005Date of Patent: May 19, 2009Assignee: Samsung Electronics Co., Ltd.Inventors: Maryte Daskeviciene, Vytautas Getautis, Tadeus Lozovski, Edmundas Montrimas
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Patent number: 7510809Abstract: An electrophotographic photoreceptor including a charge generating layer and a charge transfer layer accumulated on a support member, the charge transfer layer including at least two layers of a support side layer and a surface side layer, wherein the support side layer contains A mol/cm3 of charge mol/cm3 of charge transfer material having a dipolar moment of not more than 0.75 and inorganic particles having a number average primary particle diameter of 3-150 nm, wherein A and B satisfies relations of (1) and (2), 9.0×10?4>A>3.0×10?4??(1) 8.0×10?4>B>2.0×10?5??(2).Type: GrantFiled: November 21, 2005Date of Patent: March 31, 2009Assignee: Konica Minolta Business Technologies, Inc.Inventors: Chigusa Yamane, Keiichi Inagaki, Kunihiro Ogura
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Patent number: 7452641Abstract: Charge transport compounds are described that have a multiple number of hydrazone-bridged (N,N-disubstituted)arylamine groups connected by a central bridging group. Examples of charge transport compounds of this invention are those having the following generic formula: (R-Q)n-Y where R is an (N,N-disubstituted)arylamine group; Q comprises an aliphatic or aromatic hydrazone linking group; n is 2; and Y comprises a bridging group comprising an aryl group having the formula —Ar1-G-Ar2— where Ar1 and Ar2 are, each independently, an arylene group and G comprises a bond, O, S, —SO2—, an imine group, an alkylene group, or an aromatic group.Type: GrantFiled: January 31, 2005Date of Patent: November 18, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Hwan Koo Lee, Kam W. Law, Edita Jasiukaityte, Jolita Ostrauskaite, Juozas V. Grazulevicius, Jonas Sidaravicius
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Patent number: 7432028Abstract: This invention relates to a novel organophotoreceptor that includes: (a) a charge transport composition comprising molecules having the formula where n is an average of a distribution of integers generally between 2 and 50,000, and in which n is at least 2; R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; X comprises an (N,N-disubstituted)arylamine group; and Y is a bridging group; (b) a charge generating compound; and (c) an electrically conductive substrate over which the charge transport composition and the charge generating compound are located.Type: GrantFiled: February 4, 2004Date of Patent: October 7, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Vytautas Getautis, Tadas Malinauskas, Juozas V. Grazulevicius, Valentas Gaidelis, Vygintas Jankauskas, Zbigniew Tokarski, Nusrallah Jubran, Kam W. Law
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Patent number: 7427460Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Ar is an aryl group; X comprises a bond or a linking group; R1, R2, and R3 each comprise H, a carboxyl, an amino group, a halogen, an alkyl group, an acyl group, an alkoxy group, an alkylsulfanyl group, an alkenyl group, an alkynyl group, a heterocyclic group, an aromatic group, or a part of a ring group; R4 comprises H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; and R5, R6, R7, and R8 each comprise an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, a heterocyclic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: July 30, 2004Date of Patent: September 23, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Ruta Budreckiene, Gintaras Buika, Vygintas Jankauskas, Juozas V. Grazulevicius, Jonas Sidaravicius, Nusrallah Jubran, Zbigniew Tokarski
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Patent number: 7358014Abstract: A novel charge transport compound, a novel process using that novel compound and an organophotoreceptor includes: (a) a novel charge transport compound having the formula where R1 and R2 are selected so that R1 and R2 form, with the included nitrogen atom, a group selected from the group consisting of heterocyclic rings, aromatic rings, and dinaphthylamine; or R1 comprises an aryl group and R2 comprises a group selected from the group consisting of sulfolanyl, pyrrolyl, pyrazolyl, benzotriazolyl, stilbenyl, tetrazolyl, and group A, wherein group A is represented by the structure or R1 comprises hydrogen, alkyl group, aryl group and R2 comprises sulfonylphenyl. R3 is hydrogen, alkyl group, aryl group, a heterocyclic group or a hydrocarbon group; and Q is a 3-carbazole group; (b) a charge generating compound; and (c) an electrically conductive substrate.Type: GrantFiled: August 9, 2002Date of Patent: April 15, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Kam W. Law, Nusrallah Jubran, Zbigniew Tokarski, Alan R. Katritzky, Ritu Jain, Rexiat Maimait
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Patent number: 7358015Abstract: Plasticizers in a charge transfer layer to reduce surface cracking and crazing having a hydrocarbon chain, attached to a hindered phenol containing triazole or triazine moiety. Plasticizers found useful for this application can be used in a concentration (by weight of the charge transfer layer) in the order of magnitude of 10% to about 25%. The plasticizer additive may also be used in combination with other known plasticizers such as those containing a 2-ethylhexyl group.Type: GrantFiled: June 3, 2005Date of Patent: April 15, 2008Assignee: Lexmark International, Inc.Inventors: Mark Thomas Bellino, Catherine Mailhé Randolph, Kasturi Rangan Srinivasan
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Publication number: 20080038652Abstract: An electrophotographic imaging member includes a substrate, a photogenerating layer, and an optional overcoating layer, where the photogenerating layer includes a self-assembled carbon nanotube material having pendant charge transport materials.Type: ApplicationFiled: August 8, 2006Publication date: February 14, 2008Applicant: XEROX CORPORATIONInventor: Timothy P. BENDER
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Patent number: 7326506Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Z1 and Z2 comprise, each independently, a bond, a vinyl group, a —CR1?N—NR2— group, or a —CR3?N—N?CR4— group; Y1 and Y2 comprise, each independently, an aromatic group; X1 and X2 are, each independently, a linking group; W1 and W2 are, each independently, a —(CH2)n— group or a —(CH2)n-1—C(?O)— group, where n is an integer between 1 and 10, inclusive; Q1 and Q2 are, each independently, O, S, or NR; and R1, R2, R3, R4, R, R?, and R? comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an acyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: May 28, 2004Date of Patent: February 5, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Vytautas Getautis, Juozas V. Grazulevicius, Vygintas Jankauskas, Ingrida Paulauskaite, Jurate Simokaitiene, Albina Stanisauskaite, Valentas Gaidelis
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Publication number: 20080026308Abstract: A photoconductive having an overcoat layer that includes a cured or substantially crosslinked product of at least a melamine-formaldehyde resin and a charge transport compound, and an optional phenol compound.Type: ApplicationFiled: July 25, 2006Publication date: January 31, 2008Applicant: Xerox CorporationInventors: Yu Qi, Nan-Xing Hu
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Publication number: 20070281226Abstract: An electrophotographic imaging member includes at least one layer including a hole transport material and a strong electron acceptor material, such as an electro photographic imaging member including a substrate, a charge generating layer, a hole transport layer, and an optional overcoating layer, wherein at least one layer of the electrophotographic imaging member comprises a strong electron acceptor material.Type: ApplicationFiled: June 5, 2006Publication date: December 6, 2007Applicant: XEROX CORPORATIONInventors: Hany AZIZ, Gregory McGuire, Johann Junginger
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Patent number: 7300731Abstract: The present invention relates to new a charge transport layer that includes first charge transport material which is spatially doped with a second charge transport material. The charge transport layer may either be a hole or electron transport layer and is useful in organic electronic devices.Type: GrantFiled: August 10, 2004Date of Patent: November 27, 2007Assignee: E.I. du Pont de Nemours and CompanyInventor: Ying Wang
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Patent number: 7291428Abstract: An electrophotographic imaging member having a charge generating layer and a charge transport layer overlayed thereon is provided. The charge transport layer has a lower surface and an upper surface, wherein the lower surface is in contiguous contact with the charge generating layer. The charge transport layer comprises a film forming polymer binder and a charge transport compound molecularly dispersed or dissolved therein to form a solid solution. The concentration of the charge transport compound in the charge transport layer decreases from the lower surface to the upper surface. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improved wear resistance, excellent imaging member electrical performance, and improved copy print out quality.Type: GrantFiled: December 15, 2006Date of Patent: November 6, 2007Assignee: Xerox CorporationInventors: Satchidanand Mishra, Anthony M. Horgan, Robert C. U. Yu, Dasarao K. Murti, Suresh K. Ahuja
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Patent number: 7195850Abstract: A photoconductor having a charge generation layer and a charge transport layer, the charge transport layer having hydrazone or aryl amine charge transport molecules and also having as room light protective additives acetosol yellow 5GLS and tetraphenylcyclopentadienone or 9-fluorenone. Preferably the amount of the acetosol yellow is 2 to 4 percent by weight of the weight of the charge transfer layer and the ratio of weight between the acetosol yellow and the dienone or fluorenone is in the range of 1:1 to 1:3.Type: GrantFiled: March 17, 2004Date of Patent: March 27, 2007Assignee: Lexmark International, Inc.Inventor: Kasturi Rangan Srinivasan
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Patent number: 7153574Abstract: A composition includes a metal oxide particle, which can optionally be surface treated by a silane coupling agent, and an electron acceptor surface grafted to the metal oxide particle.Type: GrantFiled: July 16, 2004Date of Patent: December 26, 2006Assignees: Xerox Corporation, Fuji Xerox Co., Ltd.Inventors: Yu Qi, Nan-Xing Hu, Ah-Mee Hor, Hidemi Nukada, Hirofumi Nakamura
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Patent number: 7125633Abstract: An imaging member having a charge transport layer with multiple regions or layers is provided. The charge transport layer includes at least two charge transport layers coated from solutions of different components and concentrations, wherein the second (top) transport layer comprises a lower concentration of different charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the second (top) charge transport layer is a high mobility hole transport compound. The charge transport compound in each layer is dissolved or molecularly dispersed in an electrically inactive film forming polymer to form a solid solution. In such a construction, the resulting dual charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.Type: GrantFiled: December 12, 2003Date of Patent: October 24, 2006Assignee: Xerox CorporationInventors: Satchidanand Mishra, Houy Jen Yuh, Anthony M. Horgan, Markus R. Silvestri, Robert C. Yu, Yuh Tong, Dale Renfer, Kenny-tuan Dinh, Geoff Foley, Jack Yanus, Timothy Fuller
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Patent number: 7112391Abstract: Charge transport compounds are described that have a multiple number of hydrazone-bridged (N,N-disubstituted)arylamine groups connected by a central bridging group. Examples of charge transport compounds of this invention are those having the following generic formula: (R—Q)n-Y where R is an (N,N-disubstituted)arylamine group; Q comprises an aromatic hydrazone linking group; Y comprises a bridging group between R—Q—groups; and n is an integer between 2 and 6. An organic photoreceptor includes (a) that compound and (b) a charge generating compound; and (c) an electrically conductive substrate.Type: GrantFiled: November 22, 2004Date of Patent: September 26, 2006Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Hwan Koo Lee, Kam W. Law
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Patent number: 7083884Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1 and R2 are, independently, H, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 1 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C?O, O?S?O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; E is an epoxy group; and Z is a phenothiazine group, a phenoxazine group, a phenoxathiin group, a dibenzo(1,4)dioxin group, a thianthrene group, or a phenazine group; and (b) a charge generating compound.Type: GrantFiled: October 28, 2003Date of Patent: August 1, 2006Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Juozas V. Grazulevicius, Vytautas Getautis, Jolita Ostrauskaite, Jurate Simokaitiene, Edmundas Montrimas
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Patent number: 7037632Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where the formula is described in the especification; and ?(b) a charge generating compound.Type: GrantFiled: September 25, 2003Date of Patent: May 2, 2006Assignee: Samsung Electronics Co. Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Kam W. Law
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Patent number: 7033714Abstract: An imaging member having a charge transport layer is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein the upper or additional transport layer(s) comprise a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be the same or different from that included in the additional charge transport layers. The charge transport compound in one or more of the layers is dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.Type: GrantFiled: December 16, 2003Date of Patent: April 25, 2006Assignee: Xerox CorporationInventors: Anthony M. Horgan, Robert C Yu, Satchidanand Mishra, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
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Patent number: 7011917Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula ?where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, H, halogen, carboxyl, hydroxyl, thiol, cyano, nitro, aldehyde group, ketone group, an ether group, an ester group, a carbonyl group, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups can be optionally replaced by O, S, C?O, O?S?O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; Y comprises a bond, C, N, O, S, a branched or linear —(CH2)p— grType: GrantFiled: September 25, 2003Date of Patent: March 14, 2006Assignee: Samsung Electronics Co. Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Kam W. Law
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Patent number: 7005222Abstract: An imaging member having a charge transport layer with multiple regions is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein at least the top or uppermost transport layer comprises a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be of the same or different compounds from that included in the top or additional charge transport layer(s). The charge transport compound present in each layer may be dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.Type: GrantFiled: December 16, 2003Date of Patent: February 28, 2006Assignee: Xerox CorporationInventors: Anthony M. Horgan, Satchidanand Mishra, Robert C. Yu, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
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Patent number: 6946225Abstract: A multi-active electrophotographic charge generation element comprises a conductive support, a charge generation layer (CGL) disposed on the conductive support, and a charge transport layer (CTL) disposed on the charge generation layer. The charge generation layer (CGL) includes a charge-generation material comprising an aggregated or crystalline form of a first dye or pigment and a first polymeric binder. The charge transport layer (CTL) comprises at least one charge-transport agent, a second dye or pigment having absorption in a selected spectral region that at least partially overlaps the absorption of a dissolved non-aggregated or non-crystalline form of the first dye or pigment, and a second polymeric binder. The second dye or pigment in the charge transport layer absorbs radiation in the selected spectral region that is incident on the charge transport layer, thereby shielding the charge generation layer from that radiation and mitigating visible radiation-induced photofatigue.Type: GrantFiled: July 22, 2002Date of Patent: September 20, 2005Assignee: Eastman Kodak CompanyInventors: Albert V. Buettner, Dennis R. Fronheiser, Anne F. Lairmore, David S. Weiss, Jeffrey R. Murray, Marie B. O'Regan
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Patent number: 6905804Abstract: This invention relates to a novel organophotoreceptor that includes: (a) a charge transport material comprising a fluorenone hydrazone having a) at least two fluorenone alkylsulfonylphenylhydrazone groups, b) at least two fluorenone pyrrolylhydrazone groups, c) at least two fluorenone benzotriazolylhydrazone groups, d) at least two fluorenone sulfolanylhydrazone groups, e) at least two fluorenone pyrazolylhydrazone groups, f) at least two fluorenone naphthylhydrazone groups, g) at least two fluorenone tetrazolylhydrazone groups, h) at least two fluorenone stilbenylhydrazone groups, or i) at least two fluorenone (9H-fluoren-9-ylidene)benzylhydrazone groups. Some of these fluoreneones may be represented by the formula where n is an integer between 2 and 6, inclusive; R1 is hydrogen, an alkyl group, or an aryl group; R2 is an alkylsulfonylphenyl or one of its derivatives; X is a linking group.Type: GrantFiled: January 22, 2003Date of Patent: June 14, 2005Assignee: Samsung Electronics Co., Ltd.Inventors: Kam W. Law, Nusrallah Jubran, Zbigniew Tokarski, Alan R. Katritzky, Ritu Jain, Rexiat Maimait
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Patent number: 6887634Abstract: Charge transport compounds are described that have a multiple number of hydrazone-bridged (N,N-disubstituted)arylamine groups connected by a central bridging group. Examples of charge transport compounds of this invention are those having the following generic formula: (R-Q)n-Y where R is an (N,N-disubstituted)arylamine group; Q comprises an aromatic hydrazone linking group; Y comprises a bridging group between R-Q- groups; and n is an integer between 2 and 6. An organic photoreceptor includes (a) that compound and (b) a charge generating compound; and (c) an electrically conductive substrate.Type: GrantFiled: December 30, 2003Date of Patent: May 3, 2005Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Hwan Koo Lee, Kam W. Law
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Patent number: 6835514Abstract: Improved organophotoreceptor include: (a) a charge transport compound having the formula where R1 has a structure of: in which Ar is selected form the group consisting of; R4 is a hydrogen or an aromatic group and R2 and R3 are, independently, an (N,N-disubstituted) arylamine group; (b) a charge generating compound; and (c) an electrically conductive substrate. Additional improved charge transport compounds have the formula where R1 has a structure of and R2 is a julolidene group or a carbazole group.Type: GrantFiled: March 6, 2003Date of Patent: December 28, 2004Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Kam W. Law
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Patent number: 6787276Abstract: Charge transport layers comprise a charge transport compound and binder including styrene-acrylic resin. Dual layer photoconductors comprise a substrate, a charge transport layer as described, and a charge generation layer.Type: GrantFiled: June 20, 2002Date of Patent: September 7, 2004Assignee: Lexmark International, Inc.Inventors: David Glenn Black, Ronald Harold Levin, Dat Quoc Nguyen, Bradford Lee Taylor, Vincent Wen-Hwa Ting, Franklin Dilworth Zartman
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Publication number: 20040126685Abstract: An imaging member having a charge transport layer with multiple regions is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein at least the top or uppermost transport layer comprises a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be of the same or different compounds from that included in the top or additional charge transport layer(s). The charge transport compound present in each layer may be dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.Type: ApplicationFiled: December 16, 2003Publication date: July 1, 2004Applicant: Xerox CorporationInventors: Anthony M. Horgan, Satchidanand Mishra, Robert C.U. Yu, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
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Publication number: 20040126684Abstract: An imaging member having a charge transport layer is provided. The charge transport layer includes a plurality of charge transport layers coated from solutions of similar or different compositions or concentrations, wherein the upper or additional transport layer(s) comprise a lower concentration of charge transport compound than the first (bottom) charge transport layer. The charge transport compound included in the first (bottom) charge transport layer may either be the same or different from that included in the additional charge transport layers. The charge transport compound in one or more of the layers is dissolved or molecularly dispersed in an electrically inactive polymer material to form a solid solution. In such a construction, the resulting charge transport layer exhibits enhanced cracking suppression, improves wear resistance, provides excellent imaging member electrical performance, and delivers improved print quality.Type: ApplicationFiled: December 16, 2003Publication date: July 1, 2004Applicant: Xerox CorporationInventors: Anthony M. Horgan, Robert C.U. Yu, Satchidanand Mishra, Richard L. Post, Edward F. Grabowski, Kathleen M. Carmichael, John R. Lambie
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Patent number: 6749978Abstract: Charge transport compounds are described that have a multiple number of hydrazone-bridged heterocyclic groups (especially julolidine groups, carbazole groups, triarylamine groups and (N,N-disubstituted)arylamine groups such as dialkarylamine groups (e.g. dimethylphenylamine; methylethylphenylamine, dipropylphenylamine, ethylepropylphenylamine, ethylbutylnaphthylamine, etc.), alkyldiarylamine groups (e.g. methyldiphenylamino, ethyldiphenylamino, etc), and triarylamino groups (e.g., triphenyl amino, trinaphthylamino, etc)) connected by a central bridging group.Type: GrantFiled: May 30, 2003Date of Patent: June 15, 2004Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Kam Law, Vytautas Getautis, Jonas Sidaravicius, Osvaldas Paliulis, Valentas Gaidelis, Vygintas Jankauskas
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Patent number: 6670085Abstract: Charge transport compounds are described that have a multiple number of hydrazone-bridged heterocyclic groups (especially julolidine, carbazole and/or triarylmethane groups) connected by a central bridging group.Type: GrantFiled: September 24, 2001Date of Patent: December 30, 2003Assignee: Samsung Electronics Co. LtdInventors: Nusrallah Jubran, Hwan Koo Lee, Kam W. Law
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Publication number: 20030235770Abstract: Charge transport layers comprise a charge transport compound and binder including styrene-acrylic resin. Dual layer photoconductors comprise a substrate, a charge transport layer as described, and a charge generation layer.Type: ApplicationFiled: June 20, 2002Publication date: December 25, 2003Inventors: David Glenn Black, Ronald Harold Levin, Dat Quoc Nguyen, Bradford Lee Taylor, Vincent Wen-Hwa Ting, Franklin Dilworth Zartman