Methine Linked Six-membered Heterocyclic Rings Patents (Class 430/582)
-
Patent number: 7303851Abstract: Disclosed is a silver halide photographic light-sensitive material wherein a silver halide emulsion layer and/or a hydrophilic colloid layer contains at least one hydrazine derivative, and a silver halide emulsion is spectrally sensitized with a particular dye, and which contains a benzotriazol compound. There is provided a silver halide photographic light-sensitive material that exhibits superior residual color property and can provide stable photographic performance even after a long term running with a reduced silver amount.Type: GrantFiled: September 29, 2003Date of Patent: December 4, 2007Assignee: Fujifilm CorporationInventors: Mitsunori Hirano, Kunio Ishigaki, Tokuju Oikawa
-
Patent number: 7291449Abstract: Disclosed is a silver halide photographic material which comprises at least one methine dye represented by the following formula (I): wherein Y represents a furan ring or a pyrrole ring, and Y may further be condensed with other 5- or 6-membered carbocyclic ring or heterocyclic ring, or may have a substituent; the bond between two carbon atoms in which Y is condensed may be a single bond or a double bond; Z represents an atomic group necessary to form a 5- or 6-membered nitrogen-containing heterocyclic ring, and Z may further be condensed with other 5- or 6-membered carbocyclic ring or heterocyclic ring; R represents a substituted or unsubstituted alkyl group, aryl group, or heterocyclic group; D represents a group necessary to form a methine dye; L1 and L2 each represents a methine group; p represents 0 or 1; M represents a counter ion; and m represents a number of 0 or higher necessary to neutralize the charge in the molecule.Type: GrantFiled: August 17, 2001Date of Patent: November 6, 2007Assignee: Fujifilm CorporationInventors: Tetsuo Nakamura, Takanori Hioki, Katsuhisa Ohzeki, Naoyuki Hanaki
-
Patent number: 7172856Abstract: A silver halide photographic light-sensitive material having high sensitivity and having a desired spectral sensitivity distribution. A silver halide photographic light-sensitive material comprising at least one multichromophore dye compound having at least two dye chromophores connected by covalent bonding or coordinate bonding, at least two of the dye chromophores forming a dye chromophore group and the light absorption of the dye chromophore group differing from the sum of individual light absorptions of respective dye chromophores constituting said dye chromophore group.Type: GrantFiled: July 22, 2002Date of Patent: February 6, 2007Assignee: Fuji Photo Film Co., Ltd.Inventors: Takanori Hioki, Hiroo Takizawa, Katsuhiro Yamashita
-
Patent number: 7052827Abstract: A silver halide photographic material including at least one methine dye represented by the following general formula (I) and at least one coupler represented by the following general formula (XX): wherein X1 and X2 each represents an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, or a nitrogen atom; Y1 represents a furan, pyrrole or thiophene ring which may be condensed with another 5- or 6-membered carbon ring or heterocycle or may have a substituent group; Y2 represents an atomic group necessary for forming a benzene ring or a 5- or 6-membered unsaturated heterocycle, which may be further condensed with another 5- or 6-membered carbon ring or heterocycle or may have a substituent group; a bond between two carbon atoms by which Y1 and Y2 are each condensed with the carbon ring or the heterocycle may be a single bond or a double bond; R1 and R2 each represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; L1, L2 and L3 each represents a methine group; n1 represents 0 oType: GrantFiled: August 27, 2004Date of Patent: May 30, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsuo Nakamura
-
Patent number: 6881528Abstract: An electrophotographic photoreceptor with excellent wear resistance and high durability, and an image formation method having a high toner transferring efficiency and capable of providing images with high quality. The image formation method features a developing step of forming a toner image by developing an electrostatic latent image formed on the surface of a latent image carrier by a developer containing at least a toner, a transferring step of forming a transferred image by transferring the toner image formed on the surface of the latent image carrier to the surface of an object recording medium, and a fixing step of fixing the toner image transferred on the surface of the object recording medium. The latent image carrier has a surface layer containing a cross-linked resin having charge transporting property, and the toner is a toner containing at least a binder resin of mainly a crystalline resin and a coloring agent.Type: GrantFiled: February 20, 2002Date of Patent: April 19, 2005Assignee: Fuji Xerox, Co., Ltd.Inventors: Katsumi Daimon, Takashi Imai, Katsumi Nukada, Wataru Yamada
-
Patent number: 6838231Abstract: A process for producing a spectrally sensitized silver halide photographic emulsion having high sensitivity. A process for producing a silver halide photographic emulsion comprising as a sensitizing dye at least one connection dye having two or more chromophores connected through a covalent bond, the process comprising adding said connection dye to a silver halide photographic emulsion and allowing at least one chromophore out of a plurality of chromophores in the molecule of the connection dye to change in the adsorption strength to a silver halide grain; and a process for producing a silver halide photographic emulsion comprising a silver halide grain having adsorbed on the surface thereof a sensitizing dye in multiple layers, the process comprising adding one or a plural of sensitizing dye(s) to said silver halide emulsion and allowing at least one sensitizing dye out of added sensitizing dyes to change in the adsorption strength to a silver halide grain.Type: GrantFiled: October 15, 2002Date of Patent: January 4, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsumi Kobayashi, Takeshi Suzumoto, Takanori Hioki
-
Patent number: 6828087Abstract: A silver halide photographic material comprising at least one methine dye of formula (I) and at least one coupler of formula (X): wherein X1 and X2 each represents O, S, Se, Te, N or C; Y1 represents a furan, pyrrole or thiophene ring which may be condensed and substituted with the specific ring; Y2 represents an atomic group necessary for forming a benzene ring or a 5- or 6-membered unsaturated heterocycle; R1 and R2 each represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; L1, L2 and L3 each represents a methine group; n1 represents 0 or 1; M1 represents a counter ion; and m1 represents a number of 0 or more necessary for neutralizing a charge in a molecule; wherein Z1 and Z2 each represents —C(Q3)═ or —N═; Q1 and Q3 each represents a hydrogen atom or a monovalent substituent group; Q2 represents a hydrogen atom or a coupling release group.Type: GrantFiled: September 23, 2002Date of Patent: December 7, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsuo Nakamura
-
Patent number: 6828088Abstract: Disclosed is a silver halide photographic light-sensitive material comprising at least one silver halide emulsion layer on a support, wherein 40 mol % or more of silver halide contained in the silver halide emulsion layer is silver bromide and the silver halide contains 1×10−6 mole or more per mole of silver of a metal complex containing one or more cyanide ligands, and the silver halide photographic light-sensitive material has a characteristic curve drawn in orthogonal coordinates of logarithm of light exposure (x-axis) and optical density (y-axis) using equal unit lengths for the both axes, on which gamma is 4.0 or more for the optical density range of 0.1-1.5. There is provided a silver halide photographic light-sensitive material showing high contrast and high sensitivity.Type: GrantFiled: November 26, 2002Date of Patent: December 7, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Tokuju Oikawa
-
Patent number: 6815153Abstract: This invention relates to a silver halide photographic element comprising a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein said photographic element has an ISO speed rating of 800 or greater and has an integrated RMS green granularity equal to or less than 11.2.Type: GrantFiled: January 17, 2003Date of Patent: November 9, 2004Assignee: Eastman Kodak CompanyInventors: James A. Friday, Roger A. Weiss, Anabisdally I. Bodden
-
Patent number: 6770433Abstract: A high-sensitive silver halide photographic light-sensitive material is provided. A silver halide photographic light-sensitive material comprising a dye having a plurality of dye chromophores, which contains at least one dye where at least one of the dye chromophores is a methine dye chromophore containing a basic nucleus comprising a monocyclic heterocyclic ring.Type: GrantFiled: January 11, 2002Date of Patent: August 3, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Takanori Hioki
-
Patent number: 6759186Abstract: A silver halide photographic material is disclosed, comprising at least one silver halide emulsion layer provided on a support, the emulsion layer comprising a silver halide emulsion containing at least two sensitizing dyes represented by the following general formula (I): wherein X represents an oxygen atom, sulfur atom, selenium atom or NR′; R and R′ each represent a substituted or unsubstituted alkyl, aryl or heterocyclic group; D represents a group required to form a methine dye; M represents a counter ion; and m represents a number of not smaller than 0 required to neutralize the electric charge in the molecule.Type: GrantFiled: January 30, 2002Date of Patent: July 6, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuo Nakamura, Kimiyasu Morimura, Takanori Hioki
-
Publication number: 20040126721Abstract: Disclosed is a silver halide photographic light-sensitive material wherein a silver halide emulsion layer and/or a hydrophilic colloid layer contains at least one hydrazine derivative, and a silver halide emulsion is spectrally sensitized with a particular dye, and which contains a benzotriazol compound. There is provided a silver halide photographic light-sensitive material that exhibits superior residual color property and can provide stable photographic performance even after a long term running with a reduced silver amount.Type: ApplicationFiled: September 29, 2003Publication date: July 1, 2004Inventors: Mitsunori Hirano, Kunio Ishigaki, Tokuju Oikawa
-
Publication number: 20040115570Abstract: An image-forming method comprising:Type: ApplicationFiled: December 27, 2002Publication date: June 17, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Akito Yokozawa, Tatsuya Ishizaka, Katsuyuki Takada, Yoshiro Ochiai, Tetsuo Nakamura
-
Patent number: 6750002Abstract: A process for preparing a concentrated photographic spectral sensitizing dye-water composition which comprises adding an anionic sensitizing dye to an aqueous medium in the substantial absence of organic solvent, and agitating the combined dye and aqueous medium, wherein the anionic dye forms a liquid-crystalline dye phase in the aqueous medium and the agitation is performed in the presence of a nonionic surfactant having an HLB of less than 12 and an aqueous solubility at 25° C. of greater than 10 ppm, which nonionic surfactant is in the aqueous medium at a level of from 10 to 1000 ppm. In a specific embodiment of the invention, where the viscosity (at 0.1 s−1 shear rate) of the dye-water composition in the absence of the nonionic surfactant would be greater than 100 cp and especially where such viscosity would be greater than 500 cp, the surfactant is preferably present at a level sufficient to substantially reduce air entrainment during agitation of the dye-water composition.Type: GrantFiled: January 28, 2002Date of Patent: June 15, 2004Assignee: Eastman Kodak CompanyInventors: James E. Novak, Jeffrey S. Baugher, Dirk J. Hasberg, Lloyd A. Lobo
-
Patent number: 6720134Abstract: A silver halide photographic emulsion comprising grains, wherein 70% or more of the total projected area of the grains is occupied by silver halide grains each meeting requirements (a) to (d) below (a) the grain is composed of a tabular silver halide host grain having two mutually parallel main planes and aspect ratio of 2 or more, and a silver halide protrusion portion epitaxially junctioned on the surface of the host grain; (b) the silver bromide contents of both the host grain and the protrusion portion are 70 mol % or more; (c) the percentage of the silver amount in the protrusion is 12% or less of the silver amount in the host grain; and (d) the grain has a shallow electron-trapping zone.Type: GrantFiled: January 14, 2002Date of Patent: April 13, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasushi Miyamoto, Toshihiro Nishikawa, Nobuyuki Haraguchi, Hideo Ikeda, Takayoshi Mori
-
Patent number: 6686142Abstract: A chemically and spectrally-sensitized emulsion has been described, wherein said emulsion comprising (100) cubic silver halide grains with an average edge length of from 0.2 up to 1.5 &mgr;m, has been spectrally sensitized by addition at least three trimethine dyes: a main spectral sensitizer added in an amount of at least 85 mole % of all spectral sensitizers added, followed by adding a second spectral sensitizer in an amount of not more than 10 mole % and a third spectral sensitizer in an amount of at most 1 mole % wherein at least said main spectral sensitizer has two benzoxazole rings in its chemical structure, at least said third spectral sensitizer has two benzimidazole rings in its chemical structure and wherein the said second spectral sensitizer has a structure more sterically hindered than the structure of the other spectral sensitizers. A light-sensitive silver halide photographic film material coated with such emulsion and a radiographic screen/film combination has been described.Type: GrantFiled: March 4, 2002Date of Patent: February 3, 2004Assignee: Agfa-GevaertInventors: Kathy Elst, Paul Callant
-
Patent number: 6582894Abstract: A silver halide photographic emulsion is disclosed, comprising a silver halide grain having a spectral absorption maximum wavelength of less than 500 nm and a light absorption intensity of 60 or more or having a spectral absorption maximum wavelength of 500 nm or more and a light absorption intensity of 100 or more, wherein assuming that a maximum value of the spectral absorption factor of said emulsion by a sensitizing dye is Amax, the distance between the shortest wavelength showing 80% of Amax and the longest wavelength showing 80% of Amax is 20 nm or more and the distance between the shortest wavelength showing 50% of Amax and the longest wavelength showing 50% of Amax is 120 nm or less.Type: GrantFiled: March 10, 2000Date of Patent: June 24, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Takanori Hioki, Katsuhiro Yamashita, Katsumi Kobayashi, Takashi Katoh
-
Patent number: 6558893Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith a combination of two or more dyes comprising: (a) a first dye which is a cyanine dye of formula Ia and has a net charge of zero or −1 wherein the substituents are as defined in the specification; (b) a second dye which has at least one substituent that has a positive charge, and is a cyanine dye a merocyanine dye, arylidene dye, complex cyanine dye, complex merocyanine dye, homopolar cyanine dye, hemicyanine dye, styryl dye, hemioxonol dye, oxonol dye, anthraquinone dye, triphenylmethane dye, azo dye type, azomethines, or a coumarin dye, with the proviso that if the second dye is a cyanine dye, it is of formula IIa: wherein the substituents are as defined in the specification; and wherein (c) the wavelength of maximum light absorption, in nanometers (nm), of the first dye and the waveleType: GrantFiled: November 17, 2000Date of Patent: May 6, 2003Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, Andrei Andrievsky, Thomas L. Penner, William J. Harrison
-
Patent number: 6503697Abstract: A black-and-white silver halide photographic material has been disclosed, coated on a support with at least one light-sensitive emulsion layer, comprising a spectrally sensitized prefogged direct-positive silver halide emulsion, providing peak absorption in the wavelength range from 600 nm up to 700 nm, wherein said emulsion comprises a binder and core-shell emulsion crystals having silver bromide in a total amount of at least 80 mole %, characterized in that said emulsion is spectrally sensitized with a combination of a desensitizing dye having an absorption maximum wavelength in a range from 600 nm up to 700 nm, if present as a sole dye in said emulsion, and at least one azacyanine dye having an absorption maximum at a more hypsochromic wavelength.Type: GrantFiled: June 2, 2001Date of Patent: January 7, 2003Assignee: Agfa-GevaertInventors: Kris Viaene, Paul Callant
-
Patent number: 6465166Abstract: Compounds represented by formula (I) and silver halide photographic materials comprising these compounds: wherein Q1 represents a methine or polymethine group necessary for completing the compound as a methine dye; Z1 represents atoms necessary to complete a 5- or 6-membered nitrogen-containing heterocyclic ring, provided that Z1 may be condensed with a ring; L1 and L2 each represent a methine group; p1 represents 0 or 1; L represents a divalent linking group and Ar represents an aromatic group, provided that L or Ar contains at least one proton dissociative group as a substituent group or a part of the linkage or aromatic group and the proton dissociative group has a pKa value of from 3 to 12; M1 represents a counter ion for charge balance; and m1 represents a number of counter ions required for neutralizing charges on the molecule, and ranges from 0 to 10.Type: GrantFiled: November 22, 2000Date of Patent: October 15, 2002Assignee: Fuji Photo Film. Co., Ltd.Inventors: Katsumi Kobayashi, Takanori Hioki
-
Patent number: 6458524Abstract: A silver halide photographic light-sensitive material is described, comprising at least one compound represented by the following formula (I): wherein Z1 and Z2 each represents oxygen atom, sulfur atom, selenium atom, tellurium atom or a >NR group, R represents an alkyl group, an aryl group or a heterocyclic group, L1, L2 and L3 each represents a methine group, n1 represents 0 1, 2 or 3, V1, V2, V3, V4, W1, W2, W3 and W4 each represents hydrogen atom or a substituent, provided that two substituents may be combined with each other to form a condensed ring on the condition that assuming the sum total of &pgr; values of the substituents V1 to V4 is &pgr;v and the sum total of &pgr; values of the substituents W1 to W4 is &pgr;w, either one of &pgr;v and &pgr;w is 0.Type: GrantFiled: August 23, 2000Date of Patent: October 1, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuo Nakamura, Kimiyasu Morimura
-
Patent number: 6329133Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith a combination of two or more dyes wherein (b) (a) a dye having at least one substituent that has a negative charge is present, a dye having at least one substituent that has a positive charge is present, wherein at least one of the dyes is further substituted with at least one hydrogen bonding donor substituent. In a preferred embodiment, at least one of the dyes is substituted with at least two hydrogen bonding donor substituents. In another preferred embodiment a silver halide photographic material comprises at least one silver halide emulsion comprising silver halide grains having associated therewith a dye substituted with at least one guanidinium, amidinium, or imine of urea substituent.Type: GrantFiled: September 13, 1999Date of Patent: December 11, 2001Assignee: Eastman Kodak CompanyInventors: Andrei Andrievsky, Richard L. Parton, Thomas L. Penner, William J. Harrison
-
Patent number: 6143452Abstract: An electrophotographic photoreceptor characterized in comprising a resin layer containing a hardenable siloxane-based resin having a partial structure described below: ##STR1## wherein X represents a charge transportability providing group, which is a group bonding to Y in the formula via a carbon atom constituting said providing group, and Y represents at least a bivalent atom or group, excluding adjacent bonding atoms.Type: GrantFiled: September 14, 1999Date of Patent: November 7, 2000Assignee: Konica CorporationInventors: Tomoo Sakimura, Akihiko Itami, Kazumasa Watanabe, Shingo Fujimoto, Toyoko Shibata, Tomoko Sakimura
-
Patent number: 6117603Abstract: An electrostatographic imaging member includinga supporting substrate having an electrically conductive outer surface andat least one layer having an exposed imaging surface, the layer including a continuous matrix comprising a film forming polymer and a surface energy lowering liquid polysiloxane represented by the formula: ##STR1## wherein x and y are independently selected integers between about 5 and about 500,n is a number between 0 and 10, andR.sub.1 is selected from the group consisting of: ##STR2## wherein z is number between about 1 and about 30,R.sub.2 and R.sub.3 are independently selected from alkylene groups containing from 1 to 10 carbon atoms, andR.sub.4 is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms.Type: GrantFiled: July 28, 1999Date of Patent: September 12, 2000Assignee: Xerox CorporationInventors: Robert C. U. Yu, Richard L. Post, Satchidanand Mishra, Donald C. VonHoene, Anthony M. Horgan, Bing R. Hsieh, Edward F. Grabowski, Kathleen M. Carmichael, Huoy-Jen Yuh, John S. Chambers
-
Patent number: 6066426Abstract: An organic photoreceptor that includes:(a) a charge transport compound having the formula ##STR1## where n is an integer between 2 and 6, inclusive; R.sup.1 and R.sup.2, independently, are an alkyl group, a cycloalkyl group, or an aryl group, or R.sup.1 and R.sup.2 combine with the nitrogen atom to form a ring;Y is a bond, a carbon atom, a --CR.sup.3 group, an aryl group, a cycloalkyl group, or a cyclosiloxyl group;R.sup.3 is hydrogen, an alkyl group, or an aryl group; andX is a linking group having the formula --(CH.sub.2).sub.m -- where m is an integer between 4 and 10, inclusive, and one or more of the methylene groups is optionally replaced by an oxygen atom, a carbonyl group, or an ester group;(b) a charge generating compound; and(c) an electroconductive substrate.Type: GrantFiled: October 14, 1998Date of Patent: May 23, 2000Assignee: Imation Corp.Inventors: Andrew W. Mott, David J. Owen, Nusrallah Jubran, Martin D. Attwood, Richard A. Barcock, Richard J. Ellis, Rachel J. Hobson, David R. McGill
-
Patent number: 6066425Abstract: Electrophotographic charge generating elements comprise a solid electrolyte layer having improved image discrimination and layer adhesion. The solid electrolyte layer includes a complex of a silsesquioxane and a charge carrier, and is adhered to an underlying photoconductor layer using a primer layer that includes specific addition polymers. This primer layer has a resistivity of at least 10.sup.10 ohms/square and contains substantially no free ACTIVE moieties as defined herein. Such groups, when present in the primer layer, appear to reduce image discrimination.Type: GrantFiled: December 30, 1998Date of Patent: May 23, 2000Assignee: Eastman Kodak CompanyInventors: Wayne T. Ferrar, Louis J. Sorriero, J. Robin Cowdery, David S. Weiss
-
Patent number: 6057089Abstract: A silver halide photographic light-sensitive material having at least one silver halide emulsion layer formed on a support, wherein silver halide grains in the emulsion layer are reduction-sensitized and contain at least one compound represented by formula (I) below. ##STR1## In formula (I), R is an alkyl group represented as follows. ##STR2## Each of R.sub.a, R.sub.b, R.sub.c, ad R.sub.d represents an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, or an amino group, each of Q.sub.a, Q.sub.b, Q.sub.c, and Q.sub.d represents a methylene group, and each of r, s, t, and u represents an integer from 1 to 10.Each of L.sub.1 and L.sub.2 represents a methine group. p1 represents 0 or 1. Z.sub.1 represents atom groups required to neutralize a 5- or 6-membered nitrogen-containing heterocyclic ring. M.sub.1 represents a charge-balancing counterion, and m.sub.1 represents a number from 0 to 10 required to form electric charge of a molecule.Type: GrantFiled: January 16, 1997Date of Patent: May 2, 2000Assignee: Fuji Photo Film Co., Ltd.Inventors: Jun Matsumoto, Takanori Hioki, Tetsuo Nakamura
-
Patent number: 6040099Abstract: An electrophotographic photosensitive member according to the present invention includes: a photosensitive layer formed on an electroconductive support member thereof, wherein a surface layer of the photosensitive member contains a silicon denatured polycarbonate copolymer and a silicon-type graft polymer. An electrophotographic photosensitive apparatus according to the present invention includes: an electrophotographic photosensitive member, the surface layer of which contains a silicon denatured polycarbonate copolymer and a silicon-type graft polymer; a latent image forming unit for forming an electrostatic latent image on the electrophotographic photosensitive member; a developing unit for forming a toner image by developing the electrophotographic photosensitive member, on which the electrostatic image has been formed, with a toner; and, optimally, a cleaning unit for cleaning the electrophotographic photosensitive member.Type: GrantFiled: January 11, 1996Date of Patent: March 21, 2000Assignee: Canon Kabushiki KaishaInventors: Nobuyuki Hanami, Junichi Kishi, Yoichi Kawamorita, Takao Soma
-
Patent number: 6027848Abstract: An electrophotographic imaging member including a supporting substrate; an optional charge blocking layer; an optional adhesive layer; a charge generating layer and at least two charge transport layers, each charge transport layer including a charge transporting polymer (a) including a backbone containing charge transporting moieties in the backbone, the moieties having a chemical structure different from the chemical structure of charge transporting moieties in the charge transport polymer of any charge transport layer lying closer to the charge generating layer, and (b) having a higher ionization potential than the charge transport polymer in any charge transport layer lying closer to the charge generating layer. This imaging member may be employed in an electrophotographic imaging process, particularly in high sensitivity infrared photoreceptors which are compatible with liquid ink development processes.Type: GrantFiled: January 21, 1997Date of Patent: February 22, 2000Assignee: Xerox CorporationInventors: Damodar M. Pai, William W. Limburg
-
Patent number: 6017665Abstract: Charge generation layers and charge transport layers which are prepared by coating a substrate with a coating solution prepared by mixing:(A) a binder;(B) a charge generation material or a charge transport material; and(C) an organosilanc of the formula:R.sub.x Si(OR').sub.4-xwherein:R is ##STR1## R' is H- or C.sub.1-4 -alkyl; and x is an integer of 1 to 3,in a suitable solvent, exhibit enhanced adhesion to the substrate, and organic photoconductive imaging receptors which contain such a charge generation layer and/or charge transport layer exhibit improved lifetimes.Type: GrantFiled: February 26, 1998Date of Patent: January 25, 2000Assignee: Mitsubishi Chemical AmericaInventors: Guerry L. Grune, Richard R. Harris
-
Patent number: 5981161Abstract: A silver halide photographic light sensitive material is diclosed, comprising a support having a silver halide emulsion layer containing cubic silver halide grains containing iodide of 0.1 to 1.0 mol % and an iridium salt of 1.times.10.sup.-8 to 1.times.10.sup.Type: GrantFiled: June 20, 1997Date of Patent: November 9, 1999Assignee: Konica CorporationInventor: Yuji Hosoi
-
Patent number: 5976743Abstract: An electrophotographic photoreceptor having a charge transporting layer excellent in the abrasion resistance, stain resistance (toner releasability) and corona resistance, having a long life and also having excellent processability. An electrophotographic photoreceptor comprising a conductive substrate having thereon a charge generating layer containing a photoconductive material in a transparent resin cured product and at least one charge transporting layer containing a charge transporting material in a transparent resin cured product in this order, wherein the transparent resin cured product in the outermost layer of said at least one charge transporting layer is a cured product of silicone resin and contains a linear polysiloxanediol in an amount of 1 to 100 parts per 100 parts by weight of all silicone solids contents exclusive of the polysiloxanediol.Type: GrantFiled: January 28, 1998Date of Patent: November 2, 1999Assignee: Matsushita Electric Works, Ltd.Inventors: Takeyuki Yamaki, Minoru Inoue
-
Patent number: 5958665Abstract: A sultone compound represented by formula (I) or (I'), a quaternary salt compound represented by formula (II) or (II'), a methine compound represented by formula (III) or (III'), production processes thereof and a silver halide photographic light-sensitive material comprising a quaternary salt compound represented by formula (II) or (II') and/or a methine compound represented by formula (III) or (III') are disclosed.Type: GrantFiled: October 3, 1997Date of Patent: September 28, 1999Assignee: Fuji Photo Film Co., Ltd.Inventors: Takanori Hioki, Tetsuya Watanabe
-
Patent number: 5763152Abstract: A silver halide photographic light-sensitive material is disclosed. The material comprises a substrate provided thereon with at least one silver halide emulsion layer comprising at least one compound represented by the following Formula (I): ##STR1## wherein Ra and Rb each represents a hydrogen atom, an alkyl group having at least two carbon atoms or an aryl or heterocyclic group, provided that Ra and Rb do not simultaneously represent hydrogen atoms; La and Lb each represents a methylene group; L.sub.1 and L.sub.2 each represents a methine group; p.sub.1 represents 0 or 1; Z.sub.1 represents an atomic group required for forming a 5- or 6-membered nitrogen atom-containing heterocyclic ring; M.sub.1 represents a counterion required for balancing the electrical charge; m.sub.1 represents a numerical value of not less than 0 required for neutralizing the molecule; and Q represents a methine or polymethine group required for forming a methine dye.Type: GrantFiled: March 29, 1996Date of Patent: June 9, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Takanori Hioki, Mikio Ihama
-
Patent number: 5741632Abstract: A novel class of non-sensitizing infra-red dyes derived from heptamethine dyes with indolenine nuclei is disclosed. They are useful as filter-, acutance- or antihalation dyes for photographic elements based on silver halide or for photothermographic elements.Type: GrantFiled: December 9, 1996Date of Patent: April 21, 1998Assignee: Agfa-Gevaert, N.V.Inventor: Eric Kiekens
-
Patent number: 5578439Abstract: A silver halide photographic material is described, which contains the methine compound represented by the following formula (I): ##STR1## wherein Z.sup.1 represents a nonmetal atomic group necessary for completing a 5- or 6-membered heterocyclic ring which may be condensed; R.sup.1 represents an aliphatic or aromatic group which may be substituted; G.sup.1 represents a hydroxyl group, an amino group, an aliphatic or aromatic primary amino group, a hydroxyamino group, an alkoxyamino group, an acylamino group, or an aliphatic or aromatic sulfonamido group; G.sup.2 is a group substituted at the position adjacent to G and is a group represented by T.sup.2 --C(.dbd.T.sup.1)--; .dbd.T.sup.1 represents .dbd.O, .dbd.NH, .dbd.NOH, an alkoxyimino group, an aliphatic or aromatic imino group, an acylimino group, or an aliphatic or aromatic sulfonylimino group; T.sup.Type: GrantFiled: July 26, 1995Date of Patent: November 26, 1996Assignee: Fuji Photo Film Co., Ltd.Inventor: Yoshio Inagaki
-
Patent number: 5492802Abstract: A silver halide photographic element comprising a sensitizing dye of the formula: ##STR1## wherein: X1, X2, n, L, L2, R1 and R2 are as defined in the specification;Z1 represents Ar1-(L1) m, where Ar1 is a substituted or unsubstituted aromatic group, L1 is a linking group, m is 0 or 1, and the LOGP(A) of a molecule having a structure A corresponding to a portion of the dye ##STR2## is no more than 90% of LOGP(A'), where A' is the same as A except Z1 is replaced with unsubstituted phenyl, provided that L1 is not --CO-- when X1 or X2 is S or Se; andW1 is a counterion as needed to balance the charge of the molecule.Type: GrantFiled: May 20, 1994Date of Patent: February 20, 1996Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, David A. Stegman
-
Patent number: 5462851Abstract: A silver halide photographic material is disclosed which contains at least one methine dye represented by the following formula (I) or (II): ##STR1## wherein Z.sub.1 and Z.sub.2 each represents an atomic group for forming a five-membered or six-membered nitrogen-containing heterocyclic ring; R.sub.1, R.sub.2, R.sub.4 and R.sub.5 each represents an alkyl group; R.sub.3 and R.sub.6 each represents an alkyl group, an aryl group or a heterocyclic group; V.sub.1 to V.sub.12 each represents a hydrogen atom or a substituent; L.sub.1 to L.sub.10 each represents a methine group; M.sub.1 and M.sub.2 each represents an ion for neutralizing charge; m.sub.1 and m.sub.2 each represents a number of 0 or more which is required for neutralizing charge; and n.sub.1 and n.sub.2 each represents 0 or 1.Type: GrantFiled: September 16, 1993Date of Patent: October 31, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Takashi Kato, Tadashi Ikeda
-
Patent number: 5445928Abstract: A color photographic material comprising at least one cyan-coupling silver halide emulsion layer containing a red sensitizer, at least one magenta-coupling silver halide emulsion layer containing a green sensitizer and at least one yellow-coupling silver halide emulsion layer containing a blue sensitizer on a support, in which a silver halide emulsion is provided in a coupler-free layer sensitized with another spectral sensitizer (a gap sensitizer) of which the sensitization maximum lies between the sensitization maxima of the red- and green-sensitive layers or the green- and blue-sensitive layers, is distinguished by an extended gradation range towards the maximum densities and by distinctly improved detail reproduction in the region of high densities.Type: GrantFiled: January 6, 1994Date of Patent: August 29, 1995Assignee: Agfa-Gevaert AGInventors: Arno Schmuck, Edgar Draber, Michael Missfeldt
-
Patent number: 5437969Abstract: A color photographic silver halide material having at least one silver halide emulsion layer which is cyan coupling and contains a red sensitizer, at least one magenta coupling silver halide emulsion layer containing a green sensitizer and at least one yellow coupling silver halide emulsion layer containing a blue sensitizer on a support, in which the at least one blue sensitive halide emulsion layer contains a further spectral sensitizer (gap sensitizer) whose sensitization maximum lies between the sensitization maxima of the red and green sensitive silver halide emulsion layer and/or the at least one red sensitive silver halide emulsion layer contains an additional spectral sensitizer (gap sensitizer) whose sensitization maximum lies between the sensitization maxima of the green sensitive and the blue sensitive silver halide emulsion layer is distinguished by an increased range of gradations in the region of the maximum densities and a markedly improved detail reproduction in the region of high densities.Type: GrantFiled: January 6, 1994Date of Patent: August 1, 1995Assignee: Agfa-Gevaert AGInventors: Arno Schmuck, Edgar Draber, Michael Missfeldt
-
Patent number: 5418126Abstract: Spectral sensitizing dyes, and silver halide photographic elements incorporating them, which dyes have the formula: ##STR1## wherein: X1 and X2 each independently represent the atoms necessary to complete a 5- or 6-membered heterocyclic nucleus (preferably benzo-condensed), and X1 may be further substituted and X2 substituted or unsubstituted;n is a positive integer from 1 to 4,p and q each independently represents 0 or 1,each L independently represents a substituted or unsubstituted methine group,R1 and R2 each independently represents substituted or unsubstituted aryl or substituted or unsubstituted alkyl,Z1 represents a substituted or unsubstituted pyrrole or furan containing group;W1 is a counterion as needed to balance the charge of the molecule.Type: GrantFiled: January 19, 1994Date of Patent: May 23, 1995Assignee: Eastman Kodak CompanyInventors: David A. Stegman, Richard L. Parton, Steven G. Link, Pamela M. Ferguson
-
Patent number: 5403705Abstract: A light-sensitive silver halide photographic material is disclosed. The light-sensitive material comprises a support having thereon a silver halide emulsion layer, and the silver halide emulsion layer comprises silver halide grains having a silver chloride content of not less than 95 mol %. The emulsion is optically sensitized by addition of a dispersion of an optical sensitizer comprising a medium and particles of the dye dispersed in the medium. The ratio of silver to gelatin (Ag/Gel) in the emulsion at the time of addition of the dispersion of the dye is 2 to 8.5.Type: GrantFiled: September 28, 1993Date of Patent: April 4, 1995Assignee: Konica CorporationInventors: Shigeo Tanaka, Makoto Kaga, Tsuyoshi Ikeda
-
Patent number: 5397693Abstract: A silver halide photographic light-sensitive material contains a methine compound represented by the following formula: ##STR1## wherein Y.sup.1 is a group which is cleavable by a nucleophile; Z.sup.1 is --O--, --S--, or other; Z.sup.2 is --O--, --S--, --CR.sup.3 R.sup.4 (wherein each of R.sup.3 and R.sup.4 is alkyl or other), or other; A and B are each independently hydrogen, halogen, alkyl, aryl or a heterocyclic group; A and B may be linked to each other to form an unsaturated aliphatic ring, an aromatic ring or a heterocyclic ring; and Q.sup.1 is a methine or polymethine group which may have a heterocyclic group. A novel methine compound is also disclosed.Type: GrantFiled: April 8, 1993Date of Patent: March 14, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Ken Kawata, Tadashi Ikeda
-
Patent number: 5389500Abstract: Disclosed is a method for forming color photographic images which comprises printing of color images obtained by use of a color photographic light-sensitive material, having on a support, a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer onto a printing color photographic light-sensitive material having on a support, a yellow color forming layer, a magenta color forming layer and a cyan color forming layer, wherein the following requirements (A) and (B) are fulfilled,(A) wavelength .lambda..sub.B.sup.max to give the maximum value in spectral sensitivity distribution of a blue-sensitive silver halide emulsion layer is within the limits of 415 nm to 470 nm, and the sensitivity of the blue-sensitive emulsion layer at 480 nm is not more than 35% of the sensitivity at .lambda..sub.B.sup.Type: GrantFiled: October 19, 1993Date of Patent: February 14, 1995Assignee: Konica CorporationInventors: Hiroshi Shimazaki, Kuniaki Uezawa, Satoru Shimba, Yoshitaka Yamada
-
Patent number: 5336594Abstract: Disclosed is a silver halide photographic material containing at least one methine compound of formula (I) or (II): ##STR1## wherein A.sub.1 : ##STR2## and wherein Z.sub.1, Z.sub.2, Z.sub.3 and Z.sub.4 each is an atomic group of forming a 5- or 6-membered N-containing heterocyclic ring; R.sub.1, R.sub.2 and R.sub.4 each is an alkyl group; R.sub.3 is an alkyl, aryl or heterocyclic group; D.sub.1, D.sub.1a, D.sub.2 and D.sub.2a each is an atomic group of forming an acidic nucleus; V.sub.1 to V.sub.22 each is a hydrogen or a monovalent substituent; L.sub.1 to L.sub.12 each is a methine group; M.sub.1 and M.sub.2 each is a charge-neutralizing pair ion; m.sub.1 and m.sub.2 each is a number of 0 or more for neutralizing the charge in the molecule; n.sub.1, n.sub.2 and n.sub.4 each are 0 or 1; and n.sub.3 and n.sub.5 each is an integer of 0 or more. The material has a high sensitivity and storage stability.Type: GrantFiled: May 4, 1993Date of Patent: August 9, 1994Assignee: Fuji Photo Film Co., Ltd.Inventor: Takanori Hioki
-
Patent number: 5316904Abstract: Dyes and photographic elements containing them as silver halide sensitizing dyes, which dyes have the structure: ##STR1## wherein: X1 and X2 each independently represent the atoms necessary to complete a benzo-condensed 5- or 6-membered heterocyclic nucleus, which, in addition to being substituted by Z1 and Z2 respectively, may be further substituted or unsubstituted;n is a positive integer from 1 to 4,p and q each independently represents 0 or 1,each L independently represents a substituted or unsubstituted methine group,R1 and R2 each independently represents substituted or unsubstituted aryl or substituted or unsubstituted alkyl,Z1 represents a substituent which contains both an amide group and an aromatic ring which may be appended or fused to X1; andW1 is a counterion as needed to balance the charge of the molecule.Type: GrantFiled: November 19, 1992Date of Patent: May 31, 1994Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, David A. Stegman, Frederick J. Sauter
-
Patent number: 5244782Abstract: A silver halide photographic material composed of a support having thereon at least one silver halide emulsion layer containing substantially normal silver halide grains having a (111) plane and a (100) plane and capable of preferentially forming a latent image on the (100) plane; the (111) plane occupying at least about 40% of the surface of the grains or the (100) plane occupying more than about 60% of the surface of the grains; provided that when the (111) plane occupies at least about 40% of the surface of the grains, the grains are spectrally sensitized with (a) at least one spectral sensitizing dye selectively adsorbed more on the (100) plane than on the (111) plane, or (b) at least one spectral sensitizing dye selectively adsorbed more on the (111) plane than on the (100) plane.Type: GrantFiled: October 28, 1991Date of Patent: September 14, 1993Assignee: Fuji Photo Film Co. Ltd.Inventors: Hiroyuki Mifune, Shunji Takada
-
Patent number: 5149619Abstract: A silver halide photographic emulsion is disclosed, comprising a combination of at least one infrared sensitizing dye represented by formula (Ia) or (Ib) and at least one compound represented by formula (IIa) or (IIb): ##STR1## wherein each of the variables is as defined in the specification.Type: GrantFiled: September 5, 1991Date of Patent: September 22, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Yuji Mihara, Toshinao Ukai
-
Patent number: 5126235Abstract: A full color recording material comprising a support having thereon at least three silver halide photosensitive emulsion layers which contain respectively couplers which form yellow, magenta and cyan colorations and which are sensitive to light of different wavelength regions, at least two of the said layers being spectrally sensitized selectively to match laser light beams of wavelengths of at least 670 nm, wherein the at least two layers aforementioned contain at least one type of crosslinking type spectrally sensitizing dye.Type: GrantFiled: March 22, 1990Date of Patent: June 30, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Takanori Hioki
-
Patent number: 5112731Abstract: A silver halide photographic material is disclosed, which comprises a support having coated thereon at least one silver halide emulsion layer, wherein the emulsion layer comprises tabular grains of silver chloride, silver bromide, silver chlorobromide or silver chloroiodobromide having an iodide content of 1 mol % or less, which have an average aspect ratio of 3 or more and which have been spectrally sensitized with at least one spectral sensitizing dyes described below.Type: GrantFiled: August 30, 1990Date of Patent: May 12, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Nobuaki Miyasaka