Methine Linked Six-membered Heterocyclic Rings Patents (Class 430/582)
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Patent number: 5091298Abstract: Dyes according to formulas (I), (II), (III), (IV), and (V) below are described. The dyes are useful as low-staining sensitizing dyes for photographic materials. ##STR1## Z.sub.1, Z.sub.2, Z.sub.3, R.sub.1, R.sub.2, L, D, G, X, n, P, and q are defined herein.Type: GrantFiled: July 19, 1990Date of Patent: February 25, 1992Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, Steven G. Link, David A. Stegman, John D. Mee
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Patent number: 5035986Abstract: A silver halide color photographic material comprising photographic constituent layers containing at least one light-sensitive silver halide emulsion layer and at least one light-insensitive layer on a reflective support, wherein at least one of the photographic constituent layers comprises at least one dye represented by formula (I), at least one of the light-sensitive silver halide emulsion layers comprises silver halide grains substantially comprising silver chloride and the reflective support comprises 3.0 g/m.sup.2 or more of titanium oxide: ##STR1## wherein R.sub.1 and R.sub.2 each represents an alkyl group, an aryl group, a cyano group, --COOR.sub.5, --CONR.sub.5 R.sub.6, --COR.sub.7, --SO.sub.2 R.sub.7, --SOR.sub.7, --SO.sub.2 NR.sub.5 R.sub.6, --OR.sub.5, --NR.sub.5 R.sub.6, --NR.sub.6 COR.sub.7, --NR.sub.5 CONR.sub.5 R.sub.6 or --NR.sub.6 SO.sub.2 R.sub.7 in which R.sub.5 and R.sub.6 each represents a hydrogen atom, an alkyl group or an aryl group, R.sub.Type: GrantFiled: January 30, 1989Date of Patent: July 30, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Sakai, Shigeru Ohno
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Patent number: 5024928Abstract: A silver halide multilayer color reversal photographic material having improved color reproducibility comprises, in a blue-sensitive silver halide emulsion layer, the combination of a monomethine cyanine spectral sensitizing dye and a thiazole quaternary salt having attached to a quaternary nitrogen atom thereof an alkenyl group having a double bond in the .beta.-position.Type: GrantFiled: July 17, 1989Date of Patent: June 18, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: Marco Loiacono, Giuseppe Loviglio
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Patent number: 4945036Abstract: A silver halide photosensitive material is described, comprising two or more monodisperse silver halide emulsions of different average grain size on a support, wherein at least one of the said monodisperse silver halide emulsions has an average grain size of at least 0.7 .mu.m, and at least one of the silver halide emulsions has a smaller average grain size than the other, the average grain size of the silver halide emulsion as a whole being within the range of from 0.33 to 0.54 .mu.m, with a coated silver weight of from 2.3 to 3.8 g/m.sup.2, and which contains a sensitizing dye represented by formula (I) ##STR1## wherein Z and Z.sub.1 each represents a group of non-metallic atoms forming a thiazole nucleus, a benzothiazole nucleus, or a benzoxazole nucleus; R.sub.0 represents an alkyl group having from 1 to 6 carbon atoms, an allyl group, or an aralkyl group; R and R.sub.1 each represents an alkyl group or an aryl group; L, L.sub.1, and L.sub.Type: GrantFiled: May 31, 1989Date of Patent: July 31, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoki Arai, Kazuo Kagawa
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Patent number: 4935337Abstract: There is provided a silver halide photographic material wherein a hydrophilic colloid layer is dyed with a new water-soluble dye that will not adversely affect the photographic characteristics of the silver halide emulsion layer. The silver halide photographic material exhibits excellent performance in that the dye is photochemically inactive such that not allow the sensitivity to lower, the latent image to fade, or the image to fog, and the decoloring or dissolving of the dye proceed rapidly in a photographic processing step, leaving no detrimental color on the processed photographic material.Type: GrantFiled: October 20, 1988Date of Patent: June 19, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeru Kuwashima, Yoshihiro Jimbo, Keiichi Adachi
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Patent number: 4830958Abstract: A photographic material having an excellent rapid processability, a high sensitivity and a less sensitivity variation due to a change of standing of the silver halide emulsion in the course of preparation of the light-sensitive material, and its preparation process are disclosed. The silver halide photographic light-sensitive material comprises a support bearing at least one silver halide emulsion layer thereon, and at least one silver halide emulsion layer contains highly chloride-containing silver halide grains having a silver chloride content of not less than 90 mol %, a water-soluble bromide of from 0.05 mol % to 2 mol % per mol of silver halide and a high boiling organic solvent having a dielectric constant of not higher than 6.0.Type: GrantFiled: January 25, 1988Date of Patent: May 16, 1989Assignee: Konica CorporationInventors: Mitsuhiro Okumura, Keiji Ohbayashi, Shigeo Tanaka
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Patent number: 4814264Abstract: A silver halide light-sensitive material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer comprising silver halide grains and a binder, at least about 50 wt % of said silver halide grains comprising a silver halide grain matrix having thereon from about 10 to 10,000 protrusions per square micrometer of grain matrix surface, said individual protrusions having an average projected area diameter of up to about 0.15 .mu.m, and a halogen composition of said protrusions differing from that of the grain matrix; said silver halide emulsion being chemically sensitized with at least one compound selected from the group consisting of a sulfur compound, a selenium compound, a reducing compound and a noble metal compound; and said silver halide emulsion being spectrally sensitized with a methine dye.Type: GrantFiled: December 17, 1987Date of Patent: March 21, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiichiro Kishida, Minoru Sato
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Patent number: 4800154Abstract: A silver halide photographic emulsion comprising at least one spectral sensitizing dye having the following general formula (I):Dye--J.sup.1 --CONH--J.sup.2 --NHNHG--R (I)wherein Dye represents a dye residue capable of becoming a spectral sensitizing dye; J.sup.1 represents a substituted or unsubstituted alkylene group, a substituted or unsubstituted arylene group, a substituted or unsubstituted aralkylene group, or a substituted or unsubstituted alkarylene group; J.sup.2 represents a substituted or unsubstituted arylene group; R represents hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or a substituted or unsubstituted iminomethylene group.Type: GrantFiled: October 16, 1986Date of Patent: January 24, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaki Okazaki, Haruo Takei
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Patent number: 4713321Abstract: A process for preparing a silver halide photographic emulsion to be used for a photographic material is provided. Therein, additives such as dyes, sensitizers, auxiliary agents to be used upon gold sensitization, and so on are utilized within a period from at the silver halide grain forming time to just before the emulsion coating, and oxidizing agents are added at the time when the functions of the additives become substantially needless to result in conversion of the additives to those having no bad influences on photographic characteristics of the emulsion prepared, or to those having such chemical structures as to facilitate their removal with a washing treatment or the like.Silver halide emulsions prepared by the described process are also disclosed.Type: GrantFiled: February 14, 1986Date of Patent: December 15, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Mifune, Tadao Shishido, Yoshiaki Suzuki
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Patent number: 4576905Abstract: Compounds containing an aromatic ring portion fused with a tellurazolium or derivative tellurazole, tellurazoline (including tellurazolinylidene), or tellurazolinium ring portion are disclosed together with processes and intermediates for their preparation. With properly selected pendant groups these tellurazolium and derivative compounds can be usefully employed as dyes, antifoggants or stabilizers, nucleating agents, latent image keeping addenda, or speed or contrast altering addenda in silver halide photographic systems.Type: GrantFiled: October 12, 1984Date of Patent: March 18, 1986Assignee: Eastman Kodak CompanyInventors: Wolfgang H. H. Gunther, Ronald E. Leone, Rosemary Przyklek
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Patent number: 4375508Abstract: Photographic silver halide compositions and elements are provided which are spectrally sensitized with new methine dyes. The dyes are prepared from new intermediate compounds which have an acetylenically unsaturated hydrocarbon chain terminated with a nucleophilic group, the acetylenically unsaturated hydrocarbon chain being bonded to a nitrogen atom in a heterocyclic ring system of the type used in cyanine dyes. The new intermediates also provide alternative synthetic routes to known dyes.Type: GrantFiled: October 15, 1981Date of Patent: March 1, 1983Assignee: Eastman Kodak CompanyInventor: Yasushi S. Yamamoto
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Patent number: 4334001Abstract: A photoconductive composition comprising a photoconductive substance and at least one spectral sensitizer selected from azacyanines represented by formula (I), (II), (III), (IV) or (V) ##STR1## and a photosensitive member containing such a spectral sensitizer.Type: GrantFiled: December 8, 1980Date of Patent: June 8, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Horie, Hideo Sato
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Patent number: 4283488Abstract: Photo-sensitive silver halide compositions and elements are spectrally sensitized with new mathine dyes having a trialkylsilylalkyl group attached to a nitrogen atom in a heterocyclic nucleus of the dye.Type: GrantFiled: August 22, 1980Date of Patent: August 11, 1981Assignee: Eastman Kodak CompanyInventor: Earl J. VanLare
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Patent number: 4273862Abstract: Direct-positive silver halide photographic sensitive materials of high sensitivity and capable of forming a high-contrast image are obtained by incorporating anion-type cyanine dyes having a polarographic oxidation halfwave potential not less positive than +0.4 V in externally fogged direct-positive silver halide emulsions containing not less than 70 mole-% of bromide. Additional incorporation of a development accelerator such as 2-mercaptoimidazoline improves developability.Type: GrantFiled: September 24, 1979Date of Patent: June 16, 1981Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Akio Yoshida, Seigo Ebato
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Patent number: 4259439Abstract: A high-contrast direct positive prefogged silver halide emulsion free from coror stain, which contains at least one new dimethinecyanine dye wherein the 3-position of a pyrazolo[1,5-a]pyridine nucleus is bonded through a dimethine chain to the 1-, 2-, 3- or 4-position of a cyanine hetero ring nucleus, provided that where the bonding is in the 4-position said cyanine nucleus is a quinoline nucleus or a pyridine nucleus and where the bonding is in the 1- or 3-position said cyanine nucleus is an isoquinoline nucleus, said dimethyinecyanine dye being present in an amount sufficient to sensitize said emulsion.Type: GrantFiled: October 17, 1978Date of Patent: March 31, 1981Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Akira Tanaka, Akio Yoshida, Kozo Haino