Heterocyclic N, O, S, Se, Or Te Compound Containing Patents (Class 430/600)
-
Patent number: 4713322Abstract: A photographic silver halide emulsion comprising a thioether compound having more than 2 sulfur atoms in alkyl chains substituted on benzene nuclei. The compounds are useful in enhancing silver halide crystal growth. A process for preparation of the emulsion is also described.Type: GrantFiled: December 29, 1986Date of Patent: December 15, 1987Assignee: Eastman Kodak CompanyInventors: Philip S. Bryan, Arthur H. Herz
-
Patent number: 4699873Abstract: A negative silver halide photographic light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer is disclosed. At least one of the silver halide emulsion layers or another hydrophilic colloidal layer of the material contains a hydrazine derivative and a compound represented by the formula:R.sub.1 --S--S--R.sub.2wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an aliphatic group, an aromatic group or a heterocyclic group, or when R.sub.1 and R.sub.2 are both aliphatic groups they may together form a ring. The material can rapidly form a superhigh contrast image using a stable processing solution.Type: GrantFiled: January 29, 1986Date of Patent: October 13, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiro Takahashi, Shigeo Hirano
-
Patent number: 4695534Abstract: A photographic silver halide emulsion comprising a thioether substituted pyridine compound having improved ripening properties. A process for preparation of the emulsion is also described.Type: GrantFiled: December 29, 1986Date of Patent: September 22, 1987Assignee: Eastman Kodak CompanyInventors: Philip S. Bryan, Arthur H. Herz
-
Patent number: 4689286Abstract: A color photographic recording material developable by heat treatment and comprising at least one binder layer, which contains photosensitive silver halide, optionally a substantially non-photosensitive silver salt and a color providing compound (dye releaser), can be improved in regard to the Dmin/max relation and in regard to sensitivity by addition of a compound corresponding to formula IR.sup.1 --S--CO--O--R.sup.2in which R.sup.1 and R.sup.2 independently of one another represent alkyl, alkenyl, cycloalkyl, aralkyl or aryl.Type: GrantFiled: April 7, 1986Date of Patent: August 25, 1987Assignee: Agfa Gevaert AktiengesellschaftInventors: Karl-Wilhelm Schranz, Gunther Schenk, Hans hlschlager
-
Patent number: 4686167Abstract: Disclosed are novel compounds of the formula: ##STR1## wherein: X=--NR.sub.5 R.sub.6, or --OR.sub.7 ;R.sub.1 and R.sub.2 are independently hydrogen, substituted or unsubstituted alkyl, haloalkyl, hydroxyalkyl alkoxyalkyl, alkylaminoalkyl or arylalkyl having up to 18 carbons; cycloalkyl; phenyl or naphthyl; alkylphenyl, cyanophenyl, halophenyl or alkoxyphenyl substituents.R.sub.3 is hydrogen, benzyl, alkoxybenzyl, halobenzyl or alkylbenzyl, provided that if neither R.sub.1 nor R.sub.2 is hydrogen, then R.sub.3 is hydrogen.R.sub.4 is a divalent aromatic group which is substituted or unsubstituted.R.sub.5, R.sub.6, and R.sub.7 are independently hydrogen, alkyl, hydroxyalkyl, haloalkyl, alkoxyalkyl, alkylaminoalkyl, acylaminoalkyl, aminoalkyl or phenylalkyl having up to 12 carbons; a cycloalkyl substituent; phenyl or naphthyl; an alkylphenyl, cyanophenyl, halophenyl or alkoxyphenyl substituent.Furthermore, either R.sub.1 and R.sub.3 or R.sub.1 and R.sub.Type: GrantFiled: September 26, 1985Date of Patent: August 11, 1987Assignee: Anitec Image CorporationInventors: Bruce M. Resnick, Allan J. Wexler
-
Patent number: 4684604Abstract: Photographic elements and processes are described which employ a compound containing a hydrazide moiety attached by a linking group, comprising an acidic group or an active methylene group adjacent to an acidic group, to a heteroatom of a moiety containing a photographically useful group comprising a photographic dye or precursor thereof or a photographic reagent; wherein:(a) the hydrazide moiety is capable of being oxidized to an azo group by an oxidized developing agent,(b) the azo group formation causes the release of the photographically useful group, and(c) the released photographically useful group does not contain the linking group or the nitrogen atoms of the hydrazide moiety.Type: GrantFiled: April 24, 1986Date of Patent: August 4, 1987Assignee: Eastman Kodak CompanyInventor: John W. Harder
-
Patent number: 4681836Abstract: A silver halide photographic material having at least one silver halide emulsion layer which contains silver halide grains containing from 1.times.10.sup.-8 to 8.times.10.sup.-6 mole of a rhodium salt per mole of silver, and containing in said emulsion layer or another hydrophilic colloidal layer a compound represented by formula (I)R.sup.1 -NHNH-G-R.sup.2 (I)wherein R.sup.1 represents an aliphatic group or an aromatic group; R.sup.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted imino group; is exposed to imagewise pattern of light and then development-processed with a developer containing 0.15 mole/liter or more of sulfite ion and having a pH adjusted to from 9.5 to 12.Type: GrantFiled: November 20, 1986Date of Patent: July 21, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuaki Inoue, Yoshio Inagaki, Kimitaka Kameoka
-
Patent number: 4677053Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide photographic emulsion containing at least one infrared sensitizing dye represented by following general formula (I) ##STR1## and at least one compound represented by following general formula (II) ##STR2## wherein R, R.sub.1 R.sub.2, V, Z, X, m, n, p, A, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and W are defined in the specification.Type: GrantFiled: April 16, 1984Date of Patent: June 30, 1987Assignee: Yuji MiharaInventors: Yuji Mihara, Toshinao Ukai
-
Patent number: 4650746Abstract: This invention relates to a photographic element comprising a support, and coated on the support at least one negative-working photographic emulsion comprising radiation-sensitive silver halide grains capable of forming a surface latent image and a binder, and in the support or in a remaining hydrophilic colloid layer coated on the support in an amount sufficient to increase contrast, a hydrazine compound of the formula ##STR1## wherein R.sup.1 is a phenyl nucleus having a Hammet sigma value-derived electron withdrawing characteristic of less than +0.30.Type: GrantFiled: July 12, 1979Date of Patent: March 17, 1987Assignee: Eastman Kodak CompanyInventors: Joseph M. Simson, Harold E. Jordan
-
Patent number: 4634660Abstract: In the presence of a novel antifoggant represented by the general formula (I), a silver halide photographic material which has at least one light-sensitive silver halide emulsion layer on a support is development-processed. The developing solution is one containing both dihydroxybenzenes and 3-pyrazolidones, a developing solution containing both dihydroxybenzenes and aminophenoles, or a developing solution containing a primary aromatic amine developer to suppress markedly fog generation at much reduced sacrifice of sensitivity: ##STR1## wherein M represents a hydrogen atom, an alkali metal atom, NH.sub.4 or a mercapto group-protecting moiety which can be split-off in the presence of an alkali; n represents 1, 2 or 3; R.sup.1 represents a hydrogen atom or --COOR.sup.2 ; and R.sup.2 represents a hydrogen atom, an alkali metal atom, NH.sub.4, or an unsubstituted or substituted alkyl, aryl or aralkyl group.Type: GrantFiled: May 10, 1985Date of Patent: January 6, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Mifune, Koki Nakamura, Shoji Ishiguro
-
Patent number: 4619884Abstract: Photographic elements and assemblages are described which employ nondiffusible N',N'-diaromatic carbocyclic--or diaromatic heterocyclic--sulfonohydrazide compounds which are capable of releasing photographically useful groups in an imagewise manner as a function of silver halide development.Type: GrantFiled: July 29, 1985Date of Patent: October 28, 1986Assignee: Eastman Kodak CompanyInventor: Stephen P. Singer
-
Patent number: 4607006Abstract: A silver halide photographic light-sensitive material is described containing at least one electron-donative, silver halide-adsorptive compound represented by the following general formula (A) or (B), which is not a spectral sensitizing agent for silver halide or a nucleating agent:D--L--X (A)D--X (B)wherein D represents an electron donative atomic group comprising an aromatic ring or hetero ring, which may be unsubstituted or substituted with at least one substituent; L represents a linkage group containing at least one of C, N, S or O; and X represents a group which is adsorptive with a silver halide-adsorptive group containing at least one of C, N, S, O or Se, said N being optionally quarternized.Type: GrantFiled: October 9, 1984Date of Patent: August 19, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeo Hirano, Yasuhisa Sano, Haruo Takei, Tsutomu Miyasaka, Shinsaku Fujita
-
Patent number: 4607004Abstract: A silver halide color photographic light-sensitive material is disclosed, comprising a support having provided thereon light-sensitive silver halide emulsion layers, wherein on the outside of the light-sensitive silver halide emulsion layer positioned farthest from the support, a layer containing silver halide fine grains of about 0.2.mu. or less in average grain size is provided, and in the silver halide color photographic light-sensitive material at least one compound represented by the following general formula (I) is present: ##STR1## wherein M represents a hydrogen atom, an alkali metal or a quaternary ammonium group, X represents COOM' or SO.sub.3 M' (wherein M' represents a hydrogen atom, an alkali metal or a quaternary ammonium group), n represents 1 or 2, R.sub.1 represents a group capable of substituting on the phenyl group, and m represents 0, 1 or 2.Type: GrantFiled: December 17, 1984Date of Patent: August 19, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinpei Ikenoue, Haruhiko Iwano, Hiroyuki Mifune, Morio Yagihara
-
Patent number: 4604339Abstract: A method of developing silver halide photographic material which contains a light-sensitive silver halide emulsion and an internally-fogged silver halide emulsion, in which the internally-fogged emulsion has internal fogging nuclei at a depth of 0.02.mu. or more below the surface of the grains is disclosed. The photographic material is developed in the presence of at least one compound selected from the group consisting of tetraazaindenes containing at least one mercapto group, purines containing at least one mercapto group, triazaindenes containing at least one mercapto group and pentaazaindenes containing at least one mercapto group, to increase photographic speed, contrast and maximum density as well as remove uneven stain.Type: GrantFiled: November 30, 1983Date of Patent: August 5, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadao Sugimoto, Hideo Ikeda, Hiroyuki Mifune, Koki Nakamura
-
Patent number: 4588672Abstract: There is described a photographic system wherein development of an exposed photosensitive element with an aqueous alkaline photographic developing composition is effected in the presence of a compound which releases a quaternary in alkaline environment. Photographic products and processes utilizing such compounds are also disclosed.Type: GrantFiled: August 8, 1985Date of Patent: May 13, 1986Assignee: Polaroid CorporationInventor: John M. Dolphin
-
Patent number: 4581328Abstract: An internal latent image core/shell silver halide photographic emulsion containing core/shell silver halide grains is disclosed, the grains comprising a silver halide core which is doped with a metal ion or chemically sensitized or is both doped with a metal ion and chemically sensitized, and a silver halide shell which covers at least a sensitivity speck of the core, wherein both added iodine ion and a polymer having a specific repeating unit described in the specification are present on the surface of the core/shell silver halide grains. The emulsion has a high sensitivity even without chemical sensitization of the surface of core/shell silver halide grains.Type: GrantFiled: November 16, 1984Date of Patent: April 8, 1986Assignee: Fuji Photo Film Co., Ltd.Inventor: Junichi Matsuyama
-
Patent number: 4576905Abstract: Compounds containing an aromatic ring portion fused with a tellurazolium or derivative tellurazole, tellurazoline (including tellurazolinylidene), or tellurazolinium ring portion are disclosed together with processes and intermediates for their preparation. With properly selected pendant groups these tellurazolium and derivative compounds can be usefully employed as dyes, antifoggants or stabilizers, nucleating agents, latent image keeping addenda, or speed or contrast altering addenda in silver halide photographic systems.Type: GrantFiled: October 12, 1984Date of Patent: March 18, 1986Assignee: Eastman Kodak CompanyInventors: Wolfgang H. H. Gunther, Ronald E. Leone, Rosemary Przyklek
-
Patent number: 4560638Abstract: An unballasted arylhydrazide is disclosed the aryl moiety of which is substituted with a group of the formula ##STR1## where one of X and X' represents --NH--, the other represents a divalent chalcogen, and R represents an aliphatic or aromatic residue. The arylhydrazides, when applied to halftone imaging in conjunction with silver halide emulsions, photographic elements, and imaging processes, produce images of improved dot quality and low levels of pepper fog.Type: GrantFiled: October 9, 1984Date of Patent: December 24, 1985Assignee: Eastman Kodak CompanyInventors: James C. Loblaw, Barbara B. Lussier
-
Patent number: 4555480Abstract: A silver halide photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein the light-sensitive silver halide emulsion layer or other layer is a hydrophilic colloid layer containing a polyoxyethylene surface active agent represented by general formula (I) or (II) described below, and a nitron compound selected from nitron, an inorganic acid salt thereof and an organic acid salt thereof. ##STR1## wherein R.sub.1, R.sub.2, R.sub.6 and R.sub.8, which may be the same or different, each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a halogen atom, a substituted or unsubstituted acyl group, a substituted or unsubstituted amido group, a substituted or unsubstituted sulfonamido group, a substituted or unsubstituted carbamoyl group or a substituted or unsubstituted sulfamoyl group; R.sub.5 and R.sub.Type: GrantFiled: October 4, 1984Date of Patent: November 26, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeki Yokoyama, Koki Nakamura, Jyounichi Kouda, Nobuhisa Sekiguchi
-
Patent number: 4554245Abstract: A color reversal photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer, an organic compound and colloid grains of a metal or metal sulfide or silver halide grains the surface of which is previously fogged. The silver halide emulsion layer includes fine grains of silver halide particles having a particle size of 0.3.mu. or less. The fine grain particles are present in the emulsion in an amount in the range of about 30% to about 95% based on the total number of silver halide grains in the emulsion. The silver halide emulsion also includes coarse grains having a particle size of more than 0.3.mu.. The organic compound has a solubility product constant of 10.sup.-14 or less when forming a salt with a silver ion.Type: GrantFiled: January 30, 1984Date of Patent: November 19, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuhiro Hayashi, Naoyasu Deguchi, Hiroyuki Yamagami, Kensuke Goda, Kazunori Hasebe
-
Patent number: 4551419Abstract: A silver halide photographic material which contains a light-sensitive silver halide emulsion and an internally fogged silver halide emulsion is development-processed in the presence of at least one compound selected from the group consisting of compounds represented by the general formulae (I) and (II) and at least one azaindene having a mercapto group to exhibit high photographic speed, high contrast and high maximum image density:R.sub.1 --(R.sub.3).sub.l X}.sub.n R.sub.3 '--R.sub.2 (I)wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an aryl group, an aryl group, or a heterocyclic group; R.sub.3 and R.sub.3 ' each represents an alkylene group, an arylene group, a heterocyclic group; X presents ##STR1## R.sub.4 represents a hydrogen atom or --R.sub.5 --Y}.sub.m R.sub.5 '--R.sub.6 ; R.sub.5 and R.sub.5 ' have the same meanings as R.sub.3 and R.sub.3 '; R.sub.6 has the same meaning as R.sub.1 and R.sub.2 ; Y represents ##STR2## R.sub.7 has the same meaning as R.sub.1 and R.sub.Type: GrantFiled: February 10, 1984Date of Patent: November 5, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadao Sugimoto, Hideo Ikeda, Koki Nakamura
-
Patent number: 4551421Abstract: A silver halide photographic material is disclosed. The material is comprised of a support base having positioned thereon a silver halide emulsion layer and a surface protective layer. The emulsion layer contains a photosensitive silver halide emulsion, an internally fogged silver halide emulsion and a compound represented by the general formula (I):R.sub.1 [(R.sub.3).sub.l X].sub.n R.sub.3 '--R.sub.2wherein the substituents within the general formula (I) are defined within the specification. The photographic material is capable of providing an image having a high maximum density at a high speed and a high contrast. The material can be processed without requiring any specific additives in a short developing period using low-temperature processing. The material also possesses high-temperature quick processing aptitude.Type: GrantFiled: February 13, 1984Date of Patent: November 5, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadao Sugimoto, Hideo Ikeda, Koki Nakamura
-
Patent number: 4544628Abstract: A silver halide photographic emulsion is disclosed which includes a sensitizing dye represented by general formula (I) and a compound represented by general formula (II): ##STR1## The substituents within the general formulae are defined within the specification. The emulsion can be used to prepare a photographic material which has high green-sensitivity which is obtained without expanding the wavelength region of spectral sensitivity in the green sensitive region. Further, the resulting material has these improved results and does not show substantial change of its photographic properties such as sensitivity and amount of fogging during storage.Type: GrantFiled: February 2, 1984Date of Patent: October 1, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Yuji Mihara, Satoshi Nagaoka, Masaki Okazaki
-
Patent number: 4542094Abstract: A novel silver halide emulsion is disclosed. This silver halide emulsion comprises in combination (a) silver halide made of silver chlorobromide or silver chlorobromoiodide, (b) a hydroxytetrazaindene compound and (c) a nitrogen-containing heterocyclic compound having at least one mercapto group, the grains of said silver halide having such a size distribution that the variation co-efficient is not more than 0.15.Type: GrantFiled: October 21, 1983Date of Patent: September 17, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kunihiro Koshizuka, Syoji Matsuzaka, Takaaki Kojima
-
Patent number: 4528264Abstract: A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer and a high molecular compound having a repeating unit containing a residue of benzotriazoles. The repeating unit may be represented by the general formula (I) ##STR1## wherein R.sup.1 represents a hydrogen atom or a lower alkyl group, L represents a divalent bonding group, and X represents a monovalent group of benzotriazoles. Improved antifogging agent effects are obtained by utilizing the high molecular compound of applicants' invention in connection with silver halide photographic light-sensitive materials.Type: GrantFiled: November 16, 1983Date of Patent: July 9, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Shoji Ishiguro, Hiroyuki Mifune, Yoshiharu Fuseya, Tetsuro Kojima
-
Patent number: 4521508Abstract: A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer and a protective layer. The material contains a photosensitive silver halide emulsion and inside fogged silver halide emulsion as well as a disulfide compound. The disulfide compound is a compound represented by the general formula (I):A--S--S--B (I)wherein A and B independently represent an alkyl group, an aralkyl group, an aryl group, a heterocyclic group or ##STR1## wherein R represents an alkyl group, an aryl group, an aralkyl group, a heterocyclic group or an amino group. The material can form images having high contrast and a high maximum density. Further, the material has high sensitivity to light and can be developed at a low temperature in a reduced amount of time.Type: GrantFiled: November 7, 1983Date of Patent: June 4, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadao Sugimoto, Hideo Ikeda, Hiroyuki Mifune, Koki Nakamura
-
Patent number: 4514492Abstract: Desensitization defects due to nonferrous metal contamination of a silver halide film sensitized by a cysteine-thiazolidine moiety are decreased by incorporating a chelating agent such as quinaldic or picolinic acid into one or more layers of the film.Type: GrantFiled: December 15, 1983Date of Patent: April 30, 1985Assignee: E. I. Du Pont de Nemours and CompanyInventors: Raymond J. LeStrange, John H. Bayless, Jr., Allan R. Schoenberg
-
Patent number: 4510229Abstract: A lithographic photosensitive material which comprises a support having thereon at least one silver halide emulsion layer and that, contains as a lithographic development accelerating agent a compound represented by the following general formula (I) in its silver halide emulsion layer or another hydrophilic colloidal layer: ##STR1## wherein R.sub.1 to R.sub.5 may be the same or different, and they each represent hydrogen, a halogen atom, an alkyl group, an alkoxy group, an aryl group, ##STR2## (wherein R.sub.6 and R.sub.7 each represents hydrogen or an alkyl group, or they may combine with each other to form a 5- or 6-membered nitrogen containing saturated hetero ring), --NH--CO--R.sub.8 or --NHSO.sub.2 --R.sub.9 (wherein R.sub.8 and R.sub.9 each represents an alkyl group, an aryl group or an aralkyl group), or R.sub.3 and R.sub.4, or R.sub.4 and R.sub.5 may combine with each other to form a benzene ring and that, it is necessary to said compound that at least one of substituents R.sub.1, R.sub.3 and R.sub.Type: GrantFiled: March 19, 1984Date of Patent: April 9, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Yutaka Oka, Naomi Saeki, Yoshiharu Fuseya
-
Patent number: 4485169Abstract: The fading of latent images in photographic films or the like containing at least a silver halide emulsion layer is greatly diminished by the addition of a compound of the general formulae ##STR1## to the emulsion layer or another hydrophilic colloid layer. The substituents R.sub.1 to R.sub.4 are defined within.Type: GrantFiled: March 8, 1983Date of Patent: November 27, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Shoji Ishiguro, Tetsuro Kojima, Akio Mitsui
-
Patent number: 4481359Abstract: From the complex reaction mixture of cysteine and glutaraldehyde a low molecular weight polymer is recovered for use as an additive to silver halide emulsions and developers to increase speed. Iron and nickel complexes of the purified low molecular weight polymer are similarly useful for silver halide emulsions.Type: GrantFiled: January 4, 1982Date of Patent: November 6, 1984Assignee: E. I. Du Pont de Nemours and CompanyInventors: Jacob Beutel, Raymond J. LeStrange
-
Patent number: 4478928Abstract: The use of sulfinic acid radical substituted arylhydrazides in producing images in silver halide photographic elements is disclosed. The sulfinic acid radical substituted arylhydrazide can be incorporated in photographic silver halide, emulsions, and photographic elements. The sulfinic acid radical substituent is capable of activating the arylhydrazides, particularly for use at a lower alkaline pH. In negative working surface latent image forming emulsions the sulfinic acid radical substituted arylhydrazides permit higher speed or contrast to be achieved. In direct positive internal latent image forming emulsions increased nucleation activity and reduced rereversal can be achieved.Type: GrantFiled: May 11, 1983Date of Patent: October 23, 1984Assignee: Eastman Kodak CompanyInventors: Thomas C. Hess, Karl E. Wiegers
-
Patent number: 4471044Abstract: The use of thioamido and alkynyl substituted heterocyclic ammonium salts in producing images in silver halide photographic elements is disclosed. The thioamido and alkynyl substituted heterocyclic ammonium salts can be incorporated in photographic silver halide emulsions. The thioamido substituent is capable of promoting adsorption of these salts to silver halide grain surfaces. In negative working surface latent image forming emulsions the thioamido and alkynyl substituted heterocyclic ammonium salts permit higher speeds to be achieved. In direct positive internal latent image forming emulsions nucleation activity and improved incubation stability can be achieved.Type: GrantFiled: June 13, 1983Date of Patent: September 11, 1984Assignee: Eastman Kodak CompanyInventors: Richard L. Parton, Wilbur S. Gaugh, Karl E. Wiegers
-
Patent number: 4469783Abstract: A silver halide photographic emulsion is described, which has halogen composition comprises at least 60 mole % of silver chloride, 40 mole % or less of silver bromide, and 5 mole % or less of silver bromide. Grain formation is performed in the presence of a silver halide solvent selected from the group consisting of tetrasubstituted thioureas and organic thioethers, and from 10.sup.-8 to 10.sup.-5 mole of a water-soluble iridium compound per mole of silver halide. This photographic emulsion exhibits high sensitivity and provides high contrast even by flash exposure. Thus, it is useful for the production of light-sensitive materials to be used in the production of printing plates in accordance with photographic engraving.Type: GrantFiled: June 3, 1983Date of Patent: September 4, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Kenichi Kuwabara, Satoshi Kubota, Hiroyuki Mifune
-
Patent number: 4467029Abstract: A silver halide light-sensitive photographic material comprises a support and a Lippmann emulsion layer on the support containing a silver halide and at least one compound of the following formula in a quantity of at least 3.5.times.10.sup.-3 mole per mole of the silver halide of the Lippmann emulsion layer: ##STR1## wherein Z represents an atomic group necessary to form a heterocyclic ring; Y is a hydrogen atom or --S--R.sub.1 group; R and R.sub.1 are each a hydrogen atom, an alkali-metal atom, ammonium or an alkyl group; X and X.sub.1 are each a divalent organic group; m and m.sub.1 are each 0 or 1; and n is an integer of up to 3, provided if n is 0, Y is --S--R.sub.1 group.The silver halide light-sensitive photographic material is developed in a developer containing at least 0.6 mole per liter of sulfurous ions.Type: GrantFiled: March 8, 1983Date of Patent: August 21, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Toshikazu Nishide, Akio Kobayashi, Tamio Kitahata
-
Patent number: 4451555Abstract: The present invention deals with novel antifogging compounds and their use in a method of photographic reproduction comprising developing a photographic material having at least one exposed silver halide emulsion layer in the presence of a 1-phenyl-5-mercaptotetrazole compound wherein the phenyl group bears a substituent comprising at least one thioether function.Type: GrantFiled: November 25, 1981Date of Patent: May 29, 1984Assignee: AGFA-GEVAERT, N.V.Inventors: Robert J. Pollet, Antoon L. Vandenberghe, Roger A. Spriet
-
Patent number: 4451557Abstract: Photographic silver halide emulsions show increased speed and reduced latent image fading when a compound of the following structure is incorporated: ##STR1## wherein: X is --O--, --S--, --Se--, or ##STR2## Y.sup.1 and Y.sup.2 individually represent hydrogen or an aromatic nucleus or together represent the atoms completing a fused aromatic nucleus;Z is ##STR3## R is hydrogen or lower alkyl of from 1 to 5 carbon atoms; and R.sup.1 is hydrogen or methyl.Type: GrantFiled: February 14, 1983Date of Patent: May 29, 1984Assignee: Eastman Kodak CompanyInventors: Roger Lok, John P. Freeman, William N. Baum
-
Patent number: 4448878Abstract: A silver halide photographic light-sensitive material is disclosed. The material contains at least one member of the compounds represented by the general formula: ##STR1## (wherein the symbols are the same as described in the appended claims). In this silver halide photographic light-sensitive material, variations in photographic performance are prevented during the storage thereof and, further, the occurrence of fog is prevented without causing a reduction in sensitivity.Type: GrantFiled: November 12, 1982Date of Patent: May 15, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Kiyohiko Yamamuro, Shigeo Hirano, Yasuo Iwasa
-
Patent number: 4444875Abstract: Herein are disclosed a light-sensitive silver halide photographic material comprising a support and, coated thereon, a hydrophilic colloid layer or layers including a silver halide emulsion layer, at least one of said hydrophilic colloid layer or layers containing a 1H-tetrazolium compound, and an image-forming method which comprises processing a light-sensitive silver halide photographic material mentioned above.The light-sensitive silver halide photographic material and the image-forming method according to the present invention can provide a high contrast silver image and a clear dot quality.Type: GrantFiled: March 25, 1983Date of Patent: April 24, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Toshiharu Nagashima, Takeshi Habu
-
Patent number: 4442202Abstract: A post-activation type dry image forming material comprising (I) a silver salt component reducible to free silver upon light exposure and including silver iodide; (II) a redox reactive composition capable of making a visual change by a redox reaction of said composition, said reaction being initiated by heating in the presence of free silver; (III) an oxidizing agent for free silver which has an oxidizing capacity for free silver but is rendered photosensitive by heating and which, upon light exposure after said heating, is suppressed with respect to the oxidizing capacity for free silver and capable of catalytically promoting the redox reaction of said composition; and (IV) a photoreactive oxidizing agent, upon light exposure, capable of returning the reduced oxidizing agent for free silver to the original state.Type: GrantFiled: February 28, 1983Date of Patent: April 10, 1984Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Tetsuo Shiga, Takeo Kimura, Yoshinobu Ito, Kageyasu Akashi, Minoru Akiyama, Takeki Matsui
-
Patent number: 4431731Abstract: An internal latent image silver halide emulsion is disclosed comprising core/shell silver halide particles having a chemically sensitized surface which are composed of a core of silver halide doped with metal ions and/or subjected to chemical sensitization and a shell which covers said core as far as to do at least the sensitive sites of said core and a binder, wherein said silver halide emulsions contain a polymer containing a repeating unit represented by the following general formula (I) in an amount of 2 mg to 1000 mg per mole of silver as the weight of said repeating units in said polymer: ##STR1## wherein R.sup.1 represents a hydrogen atom or an alkyl group and Q represents a group selected from the group consisting of the following (1)-(4): ##STR2## wherein q represents an integer of 2 to 4, ##STR3## wherein R.sup.2 and R.sup.3 each represents a hydrogen atom or an alkyl group, ##STR4## wherein Z.sup.Type: GrantFiled: February 17, 1982Date of Patent: February 14, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadao Sugimoto, Ichizo Toya, Shigeharu Urabe, Shinji Sakaguchi
-
Patent number: 4431730Abstract: A process for the preparation of an internal latent image type silver halide emulsion containing silver halide grains comprising a central core of silver halide doped with metal ions, chemically sensitized or a combination thereof and an outer shell of silver halide covering at least light-sensitive sites of the central core characterized in that the surface of the silver halide grains are chemically sensitized in the presence of a polymer containing the repeating unit represented by general formula (I) ##STR1## wherein symbols R.sup.1 and Q are defined in the specification.Type: GrantFiled: February 17, 1982Date of Patent: February 14, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeharu Urabe, Shinji Sakaguchi, Ichizo Toya, Tadao Sugimoto
-
Patent number: 4426445Abstract: A silver halide photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer. The material contains at least one compound selected from the group consisting of a compound represented by the following general formula (I) and a compound represented by the following general formula (II) in at least one layer of the silver halide emulsion layer and other hydrophilic colloid layers thereof; ##STR1## wherein R represents an alkyl group having 1 to 6 carbon atoms which may be substituted, an aryl group having 6 to 11 carbon atoms which may be substituted, or an aralkyl group having 7 to 12 carbon atoms which may be substituted; A represents a .sigma. bond or a divalent connecting group which links R and the nitrogen atom; R.sub.1 and R.sub.2 are independently hydrogen, an alkyl group having 1 to 6 carbon atoms which may be substituted, or an aralkyl group having 7 to 11 carbon atoms which may be substituted, or when A represents a .sigma. bond, R.sub.Type: GrantFiled: March 31, 1983Date of Patent: January 17, 1984Assignee: Fuji Photo Film, Co., Ltd.Inventors: Junji Minamizono, Mitunori Hirano, Yoshiro Kawashima, Tadashi Ogawa
-
Patent number: 4419443Abstract: A silver halide photographic light-sensitive material is described comprising a support having thereon at least one silver halide emulsion layer wherein the silver halide emulsion has been chemically ripened in the presence of at least one compound containing at unit represented by the formula ##STR1## wherein M represents hydrogen, an alkali metal atom, or NH.sub.4. The silver halide photographic light-sensitive material shows high sensitivity without an accompanying increase in fog.Type: GrantFiled: November 10, 1981Date of Patent: December 6, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Mifune, Yoshiharu Fuseya, Shinpei Ikenoue
-
Patent number: 4411985Abstract: Stabilizer precursors which comprise triarylphosphines and triarylphosphoranes and which, upon being heated to a temperature above about 100.degree. C., release a phosphorous compound silver halide stabilizer that is useful in a heat stabilizable photographic silver halide material comprising photographic silver halide. A stabilized image is produced in the photographic material following exposure and development by heating the material to processing temperature. The triarylphosphines and triarylphosphoranes are useful in a dry physical development photographic material and process. Alternatively, the triarylphosphines and triarylphosphoranes are useful in a dry chemical photographic material and process.Type: GrantFiled: September 17, 1981Date of Patent: October 25, 1983Assignee: Eastman Kodak CompanyInventors: Lawrence R. Morrow, John Thatcher
-
Patent number: 4407935Abstract: The compounds of the formula ##STR1## in which R is amino, cyclic amino, aryloxy or a group of the formula ##STR2## in which L is a radical of the formula .dbd.N-Z, with Z being alkyl or cycloalkyl, or is a heterocyclic radical, aryleneoxy or oxyaryleneoxy and R' and R" are hydrogen, alkyl or halogen, and x and y are 0, 1, 2 or 3, are suitable development accelerators for the development of exposed photographic materials containing silver halide. They accelerate the reduction of the exposed silver salt to silver and thus enhance the sensitivity of the photographic material.Type: GrantFiled: January 15, 1982Date of Patent: October 4, 1983Assignee: Ciba-Geigy AGInventors: Mario Fryberg, David G. Leppard
-
Patent number: 4396711Abstract: Derivatives of thiazolidine are used in photographic silver halide emulsions to increase their speed 40% or more with little or no increase in emulsion fog. Lower silver halide coating weights are thus possible.Type: GrantFiled: March 29, 1982Date of Patent: August 2, 1983Assignee: E. I. Du Pont de Nemours and CompanyInventor: Joseph D. Overman
-
Patent number: 4396712Abstract: A novel dry image forming material comprising in one or more layers on a support (a) a non-photosensitive organic silver salt oxidizing agent, (b) a reducing agent for silver ions, (c) a silver halide component or a silver halide-forming component, (d) a toning agent and (e) a lipophilic binder, characterized by the inclusion of a specific 2-(2'-hydroxyphenyl)benzotriazole compound having bulky tert-butyl or tert-amyl groups at its ortho- and para-positions relative to the hydroxyl group in a layer containing the component (a). The dry image forming material of the present invention has high storage stability prior to use for image formation.Type: GrantFiled: May 29, 1981Date of Patent: August 2, 1983Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Shozo Kinoshita, Muneaki Kimura, Tetsuo Shiga
-
Patent number: 4378426Abstract: Photographic silver halide emulsions show increased speed and reduced latent image fading when a compound of the following structure is incorporated: ##STR1## wherein: X is -O-, -S-, -Se-, or ##STR2## Y represents the atoms completing a fused aromatic nucleus; Z is ##STR3## R is hydrogen or lower alkyl of from 1 to 5 carbon atoms.Type: GrantFiled: November 12, 1981Date of Patent: March 29, 1983Assignee: Eastman Kodak CompanyInventors: Roger Lok, John P. Freeman, William N. Baum
-
Patent number: T103803Abstract: Photographic silver halide emulsions show increased speed and reduced latent image fading when a compound of the following structure is incorporated: ##STR1## wherein: X is --O--, --S--, --Se--, or ##STR2## Y represents the atoms completing a fused aromatic nucleus; Z is ##STR3## and R is hydrogen or lower alkyl of from 1 to 5 carbon atoms.Type: GrantFiled: August 16, 1982Date of Patent: January 3, 1984Inventors: Roger Lok, John P. Freeman, William N. Baum
-
Patent number: T104802Abstract: A photographically useful alkynyl compound is disclosed which is nonionic under aqueous alkaline photographic processing conditions. The alkynyl compound is comprised of an alkynyl group attached to a methylene group through a divalent chalcogen or an imino group. The methylene group is activated by an electron withdrawing substituent. The alkynyl compounds are useful in direct positive internal latent image forming emulsions as nucleating agents and in negative working surface latent image emulsions to increase speed and/or contrast.Type: GrantFiled: February 21, 1984Date of Patent: November 6, 1984Inventor: Richard L. Parton