Heterocyclic N, O, S, Se, Or Te Compound Containing Patents (Class 430/600)
  • Patent number: 4713322
    Abstract: A photographic silver halide emulsion comprising a thioether compound having more than 2 sulfur atoms in alkyl chains substituted on benzene nuclei. The compounds are useful in enhancing silver halide crystal growth. A process for preparation of the emulsion is also described.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: December 15, 1987
    Assignee: Eastman Kodak Company
    Inventors: Philip S. Bryan, Arthur H. Herz
  • Patent number: 4699873
    Abstract: A negative silver halide photographic light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer is disclosed. At least one of the silver halide emulsion layers or another hydrophilic colloidal layer of the material contains a hydrazine derivative and a compound represented by the formula:R.sub.1 --S--S--R.sub.2wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an aliphatic group, an aromatic group or a heterocyclic group, or when R.sub.1 and R.sub.2 are both aliphatic groups they may together form a ring. The material can rapidly form a superhigh contrast image using a stable processing solution.
    Type: Grant
    Filed: January 29, 1986
    Date of Patent: October 13, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiro Takahashi, Shigeo Hirano
  • Patent number: 4695534
    Abstract: A photographic silver halide emulsion comprising a thioether substituted pyridine compound having improved ripening properties. A process for preparation of the emulsion is also described.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: September 22, 1987
    Assignee: Eastman Kodak Company
    Inventors: Philip S. Bryan, Arthur H. Herz
  • Patent number: 4689286
    Abstract: A color photographic recording material developable by heat treatment and comprising at least one binder layer, which contains photosensitive silver halide, optionally a substantially non-photosensitive silver salt and a color providing compound (dye releaser), can be improved in regard to the Dmin/max relation and in regard to sensitivity by addition of a compound corresponding to formula IR.sup.1 --S--CO--O--R.sup.2in which R.sup.1 and R.sup.2 independently of one another represent alkyl, alkenyl, cycloalkyl, aralkyl or aryl.
    Type: Grant
    Filed: April 7, 1986
    Date of Patent: August 25, 1987
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Karl-Wilhelm Schranz, Gunther Schenk, Hans hlschlager
  • Patent number: 4686167
    Abstract: Disclosed are novel compounds of the formula: ##STR1## wherein: X=--NR.sub.5 R.sub.6, or --OR.sub.7 ;R.sub.1 and R.sub.2 are independently hydrogen, substituted or unsubstituted alkyl, haloalkyl, hydroxyalkyl alkoxyalkyl, alkylaminoalkyl or arylalkyl having up to 18 carbons; cycloalkyl; phenyl or naphthyl; alkylphenyl, cyanophenyl, halophenyl or alkoxyphenyl substituents.R.sub.3 is hydrogen, benzyl, alkoxybenzyl, halobenzyl or alkylbenzyl, provided that if neither R.sub.1 nor R.sub.2 is hydrogen, then R.sub.3 is hydrogen.R.sub.4 is a divalent aromatic group which is substituted or unsubstituted.R.sub.5, R.sub.6, and R.sub.7 are independently hydrogen, alkyl, hydroxyalkyl, haloalkyl, alkoxyalkyl, alkylaminoalkyl, acylaminoalkyl, aminoalkyl or phenylalkyl having up to 12 carbons; a cycloalkyl substituent; phenyl or naphthyl; an alkylphenyl, cyanophenyl, halophenyl or alkoxyphenyl substituent.Furthermore, either R.sub.1 and R.sub.3 or R.sub.1 and R.sub.
    Type: Grant
    Filed: September 26, 1985
    Date of Patent: August 11, 1987
    Assignee: Anitec Image Corporation
    Inventors: Bruce M. Resnick, Allan J. Wexler
  • Patent number: 4684604
    Abstract: Photographic elements and processes are described which employ a compound containing a hydrazide moiety attached by a linking group, comprising an acidic group or an active methylene group adjacent to an acidic group, to a heteroatom of a moiety containing a photographically useful group comprising a photographic dye or precursor thereof or a photographic reagent; wherein:(a) the hydrazide moiety is capable of being oxidized to an azo group by an oxidized developing agent,(b) the azo group formation causes the release of the photographically useful group, and(c) the released photographically useful group does not contain the linking group or the nitrogen atoms of the hydrazide moiety.
    Type: Grant
    Filed: April 24, 1986
    Date of Patent: August 4, 1987
    Assignee: Eastman Kodak Company
    Inventor: John W. Harder
  • Patent number: 4681836
    Abstract: A silver halide photographic material having at least one silver halide emulsion layer which contains silver halide grains containing from 1.times.10.sup.-8 to 8.times.10.sup.-6 mole of a rhodium salt per mole of silver, and containing in said emulsion layer or another hydrophilic colloidal layer a compound represented by formula (I)R.sup.1 -NHNH-G-R.sup.2 (I)wherein R.sup.1 represents an aliphatic group or an aromatic group; R.sup.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted imino group; is exposed to imagewise pattern of light and then development-processed with a developer containing 0.15 mole/liter or more of sulfite ion and having a pH adjusted to from 9.5 to 12.
    Type: Grant
    Filed: November 20, 1986
    Date of Patent: July 21, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Yoshio Inagaki, Kimitaka Kameoka
  • Patent number: 4677053
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide photographic emulsion containing at least one infrared sensitizing dye represented by following general formula (I) ##STR1## and at least one compound represented by following general formula (II) ##STR2## wherein R, R.sub.1 R.sub.2, V, Z, X, m, n, p, A, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and W are defined in the specification.
    Type: Grant
    Filed: April 16, 1984
    Date of Patent: June 30, 1987
    Assignee: Yuji Mihara
    Inventors: Yuji Mihara, Toshinao Ukai
  • Patent number: 4650746
    Abstract: This invention relates to a photographic element comprising a support, and coated on the support at least one negative-working photographic emulsion comprising radiation-sensitive silver halide grains capable of forming a surface latent image and a binder, and in the support or in a remaining hydrophilic colloid layer coated on the support in an amount sufficient to increase contrast, a hydrazine compound of the formula ##STR1## wherein R.sup.1 is a phenyl nucleus having a Hammet sigma value-derived electron withdrawing characteristic of less than +0.30.
    Type: Grant
    Filed: July 12, 1979
    Date of Patent: March 17, 1987
    Assignee: Eastman Kodak Company
    Inventors: Joseph M. Simson, Harold E. Jordan
  • Patent number: 4634660
    Abstract: In the presence of a novel antifoggant represented by the general formula (I), a silver halide photographic material which has at least one light-sensitive silver halide emulsion layer on a support is development-processed. The developing solution is one containing both dihydroxybenzenes and 3-pyrazolidones, a developing solution containing both dihydroxybenzenes and aminophenoles, or a developing solution containing a primary aromatic amine developer to suppress markedly fog generation at much reduced sacrifice of sensitivity: ##STR1## wherein M represents a hydrogen atom, an alkali metal atom, NH.sub.4 or a mercapto group-protecting moiety which can be split-off in the presence of an alkali; n represents 1, 2 or 3; R.sup.1 represents a hydrogen atom or --COOR.sup.2 ; and R.sup.2 represents a hydrogen atom, an alkali metal atom, NH.sub.4, or an unsubstituted or substituted alkyl, aryl or aralkyl group.
    Type: Grant
    Filed: May 10, 1985
    Date of Patent: January 6, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Koki Nakamura, Shoji Ishiguro
  • Patent number: 4619884
    Abstract: Photographic elements and assemblages are described which employ nondiffusible N',N'-diaromatic carbocyclic--or diaromatic heterocyclic--sulfonohydrazide compounds which are capable of releasing photographically useful groups in an imagewise manner as a function of silver halide development.
    Type: Grant
    Filed: July 29, 1985
    Date of Patent: October 28, 1986
    Assignee: Eastman Kodak Company
    Inventor: Stephen P. Singer
  • Patent number: 4607006
    Abstract: A silver halide photographic light-sensitive material is described containing at least one electron-donative, silver halide-adsorptive compound represented by the following general formula (A) or (B), which is not a spectral sensitizing agent for silver halide or a nucleating agent:D--L--X (A)D--X (B)wherein D represents an electron donative atomic group comprising an aromatic ring or hetero ring, which may be unsubstituted or substituted with at least one substituent; L represents a linkage group containing at least one of C, N, S or O; and X represents a group which is adsorptive with a silver halide-adsorptive group containing at least one of C, N, S, O or Se, said N being optionally quarternized.
    Type: Grant
    Filed: October 9, 1984
    Date of Patent: August 19, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeo Hirano, Yasuhisa Sano, Haruo Takei, Tsutomu Miyasaka, Shinsaku Fujita
  • Patent number: 4607004
    Abstract: A silver halide color photographic light-sensitive material is disclosed, comprising a support having provided thereon light-sensitive silver halide emulsion layers, wherein on the outside of the light-sensitive silver halide emulsion layer positioned farthest from the support, a layer containing silver halide fine grains of about 0.2.mu. or less in average grain size is provided, and in the silver halide color photographic light-sensitive material at least one compound represented by the following general formula (I) is present: ##STR1## wherein M represents a hydrogen atom, an alkali metal or a quaternary ammonium group, X represents COOM' or SO.sub.3 M' (wherein M' represents a hydrogen atom, an alkali metal or a quaternary ammonium group), n represents 1 or 2, R.sub.1 represents a group capable of substituting on the phenyl group, and m represents 0, 1 or 2.
    Type: Grant
    Filed: December 17, 1984
    Date of Patent: August 19, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinpei Ikenoue, Haruhiko Iwano, Hiroyuki Mifune, Morio Yagihara
  • Patent number: 4604339
    Abstract: A method of developing silver halide photographic material which contains a light-sensitive silver halide emulsion and an internally-fogged silver halide emulsion, in which the internally-fogged emulsion has internal fogging nuclei at a depth of 0.02.mu. or more below the surface of the grains is disclosed. The photographic material is developed in the presence of at least one compound selected from the group consisting of tetraazaindenes containing at least one mercapto group, purines containing at least one mercapto group, triazaindenes containing at least one mercapto group and pentaazaindenes containing at least one mercapto group, to increase photographic speed, contrast and maximum density as well as remove uneven stain.
    Type: Grant
    Filed: November 30, 1983
    Date of Patent: August 5, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadao Sugimoto, Hideo Ikeda, Hiroyuki Mifune, Koki Nakamura
  • Patent number: 4588672
    Abstract: There is described a photographic system wherein development of an exposed photosensitive element with an aqueous alkaline photographic developing composition is effected in the presence of a compound which releases a quaternary in alkaline environment. Photographic products and processes utilizing such compounds are also disclosed.
    Type: Grant
    Filed: August 8, 1985
    Date of Patent: May 13, 1986
    Assignee: Polaroid Corporation
    Inventor: John M. Dolphin
  • Patent number: 4581328
    Abstract: An internal latent image core/shell silver halide photographic emulsion containing core/shell silver halide grains is disclosed, the grains comprising a silver halide core which is doped with a metal ion or chemically sensitized or is both doped with a metal ion and chemically sensitized, and a silver halide shell which covers at least a sensitivity speck of the core, wherein both added iodine ion and a polymer having a specific repeating unit described in the specification are present on the surface of the core/shell silver halide grains. The emulsion has a high sensitivity even without chemical sensitization of the surface of core/shell silver halide grains.
    Type: Grant
    Filed: November 16, 1984
    Date of Patent: April 8, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Junichi Matsuyama
  • Patent number: 4576905
    Abstract: Compounds containing an aromatic ring portion fused with a tellurazolium or derivative tellurazole, tellurazoline (including tellurazolinylidene), or tellurazolinium ring portion are disclosed together with processes and intermediates for their preparation. With properly selected pendant groups these tellurazolium and derivative compounds can be usefully employed as dyes, antifoggants or stabilizers, nucleating agents, latent image keeping addenda, or speed or contrast altering addenda in silver halide photographic systems.
    Type: Grant
    Filed: October 12, 1984
    Date of Patent: March 18, 1986
    Assignee: Eastman Kodak Company
    Inventors: Wolfgang H. H. Gunther, Ronald E. Leone, Rosemary Przyklek
  • Patent number: 4560638
    Abstract: An unballasted arylhydrazide is disclosed the aryl moiety of which is substituted with a group of the formula ##STR1## where one of X and X' represents --NH--, the other represents a divalent chalcogen, and R represents an aliphatic or aromatic residue. The arylhydrazides, when applied to halftone imaging in conjunction with silver halide emulsions, photographic elements, and imaging processes, produce images of improved dot quality and low levels of pepper fog.
    Type: Grant
    Filed: October 9, 1984
    Date of Patent: December 24, 1985
    Assignee: Eastman Kodak Company
    Inventors: James C. Loblaw, Barbara B. Lussier
  • Patent number: 4555480
    Abstract: A silver halide photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein the light-sensitive silver halide emulsion layer or other layer is a hydrophilic colloid layer containing a polyoxyethylene surface active agent represented by general formula (I) or (II) described below, and a nitron compound selected from nitron, an inorganic acid salt thereof and an organic acid salt thereof. ##STR1## wherein R.sub.1, R.sub.2, R.sub.6 and R.sub.8, which may be the same or different, each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a halogen atom, a substituted or unsubstituted acyl group, a substituted or unsubstituted amido group, a substituted or unsubstituted sulfonamido group, a substituted or unsubstituted carbamoyl group or a substituted or unsubstituted sulfamoyl group; R.sub.5 and R.sub.
    Type: Grant
    Filed: October 4, 1984
    Date of Patent: November 26, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeki Yokoyama, Koki Nakamura, Jyounichi Kouda, Nobuhisa Sekiguchi
  • Patent number: 4554245
    Abstract: A color reversal photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer, an organic compound and colloid grains of a metal or metal sulfide or silver halide grains the surface of which is previously fogged. The silver halide emulsion layer includes fine grains of silver halide particles having a particle size of 0.3.mu. or less. The fine grain particles are present in the emulsion in an amount in the range of about 30% to about 95% based on the total number of silver halide grains in the emulsion. The silver halide emulsion also includes coarse grains having a particle size of more than 0.3.mu.. The organic compound has a solubility product constant of 10.sup.-14 or less when forming a salt with a silver ion.
    Type: Grant
    Filed: January 30, 1984
    Date of Patent: November 19, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuhiro Hayashi, Naoyasu Deguchi, Hiroyuki Yamagami, Kensuke Goda, Kazunori Hasebe
  • Patent number: 4551419
    Abstract: A silver halide photographic material which contains a light-sensitive silver halide emulsion and an internally fogged silver halide emulsion is development-processed in the presence of at least one compound selected from the group consisting of compounds represented by the general formulae (I) and (II) and at least one azaindene having a mercapto group to exhibit high photographic speed, high contrast and high maximum image density:R.sub.1 --(R.sub.3).sub.l X}.sub.n R.sub.3 '--R.sub.2 (I)wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an aryl group, an aryl group, or a heterocyclic group; R.sub.3 and R.sub.3 ' each represents an alkylene group, an arylene group, a heterocyclic group; X presents ##STR1## R.sub.4 represents a hydrogen atom or --R.sub.5 --Y}.sub.m R.sub.5 '--R.sub.6 ; R.sub.5 and R.sub.5 ' have the same meanings as R.sub.3 and R.sub.3 '; R.sub.6 has the same meaning as R.sub.1 and R.sub.2 ; Y represents ##STR2## R.sub.7 has the same meaning as R.sub.1 and R.sub.
    Type: Grant
    Filed: February 10, 1984
    Date of Patent: November 5, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadao Sugimoto, Hideo Ikeda, Koki Nakamura
  • Patent number: 4551421
    Abstract: A silver halide photographic material is disclosed. The material is comprised of a support base having positioned thereon a silver halide emulsion layer and a surface protective layer. The emulsion layer contains a photosensitive silver halide emulsion, an internally fogged silver halide emulsion and a compound represented by the general formula (I):R.sub.1 [(R.sub.3).sub.l X].sub.n R.sub.3 '--R.sub.2wherein the substituents within the general formula (I) are defined within the specification. The photographic material is capable of providing an image having a high maximum density at a high speed and a high contrast. The material can be processed without requiring any specific additives in a short developing period using low-temperature processing. The material also possesses high-temperature quick processing aptitude.
    Type: Grant
    Filed: February 13, 1984
    Date of Patent: November 5, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadao Sugimoto, Hideo Ikeda, Koki Nakamura
  • Patent number: 4544628
    Abstract: A silver halide photographic emulsion is disclosed which includes a sensitizing dye represented by general formula (I) and a compound represented by general formula (II): ##STR1## The substituents within the general formulae are defined within the specification. The emulsion can be used to prepare a photographic material which has high green-sensitivity which is obtained without expanding the wavelength region of spectral sensitivity in the green sensitive region. Further, the resulting material has these improved results and does not show substantial change of its photographic properties such as sensitivity and amount of fogging during storage.
    Type: Grant
    Filed: February 2, 1984
    Date of Patent: October 1, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yuji Mihara, Satoshi Nagaoka, Masaki Okazaki
  • Patent number: 4542094
    Abstract: A novel silver halide emulsion is disclosed. This silver halide emulsion comprises in combination (a) silver halide made of silver chlorobromide or silver chlorobromoiodide, (b) a hydroxytetrazaindene compound and (c) a nitrogen-containing heterocyclic compound having at least one mercapto group, the grains of said silver halide having such a size distribution that the variation co-efficient is not more than 0.15.
    Type: Grant
    Filed: October 21, 1983
    Date of Patent: September 17, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kunihiro Koshizuka, Syoji Matsuzaka, Takaaki Kojima
  • Patent number: 4528264
    Abstract: A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer and a high molecular compound having a repeating unit containing a residue of benzotriazoles. The repeating unit may be represented by the general formula (I) ##STR1## wherein R.sup.1 represents a hydrogen atom or a lower alkyl group, L represents a divalent bonding group, and X represents a monovalent group of benzotriazoles. Improved antifogging agent effects are obtained by utilizing the high molecular compound of applicants' invention in connection with silver halide photographic light-sensitive materials.
    Type: Grant
    Filed: November 16, 1983
    Date of Patent: July 9, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shoji Ishiguro, Hiroyuki Mifune, Yoshiharu Fuseya, Tetsuro Kojima
  • Patent number: 4521508
    Abstract: A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer and a protective layer. The material contains a photosensitive silver halide emulsion and inside fogged silver halide emulsion as well as a disulfide compound. The disulfide compound is a compound represented by the general formula (I):A--S--S--B (I)wherein A and B independently represent an alkyl group, an aralkyl group, an aryl group, a heterocyclic group or ##STR1## wherein R represents an alkyl group, an aryl group, an aralkyl group, a heterocyclic group or an amino group. The material can form images having high contrast and a high maximum density. Further, the material has high sensitivity to light and can be developed at a low temperature in a reduced amount of time.
    Type: Grant
    Filed: November 7, 1983
    Date of Patent: June 4, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadao Sugimoto, Hideo Ikeda, Hiroyuki Mifune, Koki Nakamura
  • Patent number: 4514492
    Abstract: Desensitization defects due to nonferrous metal contamination of a silver halide film sensitized by a cysteine-thiazolidine moiety are decreased by incorporating a chelating agent such as quinaldic or picolinic acid into one or more layers of the film.
    Type: Grant
    Filed: December 15, 1983
    Date of Patent: April 30, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Raymond J. LeStrange, John H. Bayless, Jr., Allan R. Schoenberg
  • Patent number: 4510229
    Abstract: A lithographic photosensitive material which comprises a support having thereon at least one silver halide emulsion layer and that, contains as a lithographic development accelerating agent a compound represented by the following general formula (I) in its silver halide emulsion layer or another hydrophilic colloidal layer: ##STR1## wherein R.sub.1 to R.sub.5 may be the same or different, and they each represent hydrogen, a halogen atom, an alkyl group, an alkoxy group, an aryl group, ##STR2## (wherein R.sub.6 and R.sub.7 each represents hydrogen or an alkyl group, or they may combine with each other to form a 5- or 6-membered nitrogen containing saturated hetero ring), --NH--CO--R.sub.8 or --NHSO.sub.2 --R.sub.9 (wherein R.sub.8 and R.sub.9 each represents an alkyl group, an aryl group or an aralkyl group), or R.sub.3 and R.sub.4, or R.sub.4 and R.sub.5 may combine with each other to form a benzene ring and that, it is necessary to said compound that at least one of substituents R.sub.1, R.sub.3 and R.sub.
    Type: Grant
    Filed: March 19, 1984
    Date of Patent: April 9, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yutaka Oka, Naomi Saeki, Yoshiharu Fuseya
  • Patent number: 4485169
    Abstract: The fading of latent images in photographic films or the like containing at least a silver halide emulsion layer is greatly diminished by the addition of a compound of the general formulae ##STR1## to the emulsion layer or another hydrophilic colloid layer. The substituents R.sub.1 to R.sub.4 are defined within.
    Type: Grant
    Filed: March 8, 1983
    Date of Patent: November 27, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shoji Ishiguro, Tetsuro Kojima, Akio Mitsui
  • Patent number: 4481359
    Abstract: From the complex reaction mixture of cysteine and glutaraldehyde a low molecular weight polymer is recovered for use as an additive to silver halide emulsions and developers to increase speed. Iron and nickel complexes of the purified low molecular weight polymer are similarly useful for silver halide emulsions.
    Type: Grant
    Filed: January 4, 1982
    Date of Patent: November 6, 1984
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Jacob Beutel, Raymond J. LeStrange
  • Patent number: 4478928
    Abstract: The use of sulfinic acid radical substituted arylhydrazides in producing images in silver halide photographic elements is disclosed. The sulfinic acid radical substituted arylhydrazide can be incorporated in photographic silver halide, emulsions, and photographic elements. The sulfinic acid radical substituent is capable of activating the arylhydrazides, particularly for use at a lower alkaline pH. In negative working surface latent image forming emulsions the sulfinic acid radical substituted arylhydrazides permit higher speed or contrast to be achieved. In direct positive internal latent image forming emulsions increased nucleation activity and reduced rereversal can be achieved.
    Type: Grant
    Filed: May 11, 1983
    Date of Patent: October 23, 1984
    Assignee: Eastman Kodak Company
    Inventors: Thomas C. Hess, Karl E. Wiegers
  • Patent number: 4471044
    Abstract: The use of thioamido and alkynyl substituted heterocyclic ammonium salts in producing images in silver halide photographic elements is disclosed. The thioamido and alkynyl substituted heterocyclic ammonium salts can be incorporated in photographic silver halide emulsions. The thioamido substituent is capable of promoting adsorption of these salts to silver halide grain surfaces. In negative working surface latent image forming emulsions the thioamido and alkynyl substituted heterocyclic ammonium salts permit higher speeds to be achieved. In direct positive internal latent image forming emulsions nucleation activity and improved incubation stability can be achieved.
    Type: Grant
    Filed: June 13, 1983
    Date of Patent: September 11, 1984
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Wilbur S. Gaugh, Karl E. Wiegers
  • Patent number: 4469783
    Abstract: A silver halide photographic emulsion is described, which has halogen composition comprises at least 60 mole % of silver chloride, 40 mole % or less of silver bromide, and 5 mole % or less of silver bromide. Grain formation is performed in the presence of a silver halide solvent selected from the group consisting of tetrasubstituted thioureas and organic thioethers, and from 10.sup.-8 to 10.sup.-5 mole of a water-soluble iridium compound per mole of silver halide. This photographic emulsion exhibits high sensitivity and provides high contrast even by flash exposure. Thus, it is useful for the production of light-sensitive materials to be used in the production of printing plates in accordance with photographic engraving.
    Type: Grant
    Filed: June 3, 1983
    Date of Patent: September 4, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kenichi Kuwabara, Satoshi Kubota, Hiroyuki Mifune
  • Patent number: 4467029
    Abstract: A silver halide light-sensitive photographic material comprises a support and a Lippmann emulsion layer on the support containing a silver halide and at least one compound of the following formula in a quantity of at least 3.5.times.10.sup.-3 mole per mole of the silver halide of the Lippmann emulsion layer: ##STR1## wherein Z represents an atomic group necessary to form a heterocyclic ring; Y is a hydrogen atom or --S--R.sub.1 group; R and R.sub.1 are each a hydrogen atom, an alkali-metal atom, ammonium or an alkyl group; X and X.sub.1 are each a divalent organic group; m and m.sub.1 are each 0 or 1; and n is an integer of up to 3, provided if n is 0, Y is --S--R.sub.1 group.The silver halide light-sensitive photographic material is developed in a developer containing at least 0.6 mole per liter of sulfurous ions.
    Type: Grant
    Filed: March 8, 1983
    Date of Patent: August 21, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshikazu Nishide, Akio Kobayashi, Tamio Kitahata
  • Patent number: 4451555
    Abstract: The present invention deals with novel antifogging compounds and their use in a method of photographic reproduction comprising developing a photographic material having at least one exposed silver halide emulsion layer in the presence of a 1-phenyl-5-mercaptotetrazole compound wherein the phenyl group bears a substituent comprising at least one thioether function.
    Type: Grant
    Filed: November 25, 1981
    Date of Patent: May 29, 1984
    Assignee: AGFA-GEVAERT, N.V.
    Inventors: Robert J. Pollet, Antoon L. Vandenberghe, Roger A. Spriet
  • Patent number: 4451557
    Abstract: Photographic silver halide emulsions show increased speed and reduced latent image fading when a compound of the following structure is incorporated: ##STR1## wherein: X is --O--, --S--, --Se--, or ##STR2## Y.sup.1 and Y.sup.2 individually represent hydrogen or an aromatic nucleus or together represent the atoms completing a fused aromatic nucleus;Z is ##STR3## R is hydrogen or lower alkyl of from 1 to 5 carbon atoms; and R.sup.1 is hydrogen or methyl.
    Type: Grant
    Filed: February 14, 1983
    Date of Patent: May 29, 1984
    Assignee: Eastman Kodak Company
    Inventors: Roger Lok, John P. Freeman, William N. Baum
  • Patent number: 4448878
    Abstract: A silver halide photographic light-sensitive material is disclosed. The material contains at least one member of the compounds represented by the general formula: ##STR1## (wherein the symbols are the same as described in the appended claims). In this silver halide photographic light-sensitive material, variations in photographic performance are prevented during the storage thereof and, further, the occurrence of fog is prevented without causing a reduction in sensitivity.
    Type: Grant
    Filed: November 12, 1982
    Date of Patent: May 15, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyohiko Yamamuro, Shigeo Hirano, Yasuo Iwasa
  • Patent number: 4444875
    Abstract: Herein are disclosed a light-sensitive silver halide photographic material comprising a support and, coated thereon, a hydrophilic colloid layer or layers including a silver halide emulsion layer, at least one of said hydrophilic colloid layer or layers containing a 1H-tetrazolium compound, and an image-forming method which comprises processing a light-sensitive silver halide photographic material mentioned above.The light-sensitive silver halide photographic material and the image-forming method according to the present invention can provide a high contrast silver image and a clear dot quality.
    Type: Grant
    Filed: March 25, 1983
    Date of Patent: April 24, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshiharu Nagashima, Takeshi Habu
  • Patent number: 4442202
    Abstract: A post-activation type dry image forming material comprising (I) a silver salt component reducible to free silver upon light exposure and including silver iodide; (II) a redox reactive composition capable of making a visual change by a redox reaction of said composition, said reaction being initiated by heating in the presence of free silver; (III) an oxidizing agent for free silver which has an oxidizing capacity for free silver but is rendered photosensitive by heating and which, upon light exposure after said heating, is suppressed with respect to the oxidizing capacity for free silver and capable of catalytically promoting the redox reaction of said composition; and (IV) a photoreactive oxidizing agent, upon light exposure, capable of returning the reduced oxidizing agent for free silver to the original state.
    Type: Grant
    Filed: February 28, 1983
    Date of Patent: April 10, 1984
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Tetsuo Shiga, Takeo Kimura, Yoshinobu Ito, Kageyasu Akashi, Minoru Akiyama, Takeki Matsui
  • Patent number: 4431731
    Abstract: An internal latent image silver halide emulsion is disclosed comprising core/shell silver halide particles having a chemically sensitized surface which are composed of a core of silver halide doped with metal ions and/or subjected to chemical sensitization and a shell which covers said core as far as to do at least the sensitive sites of said core and a binder, wherein said silver halide emulsions contain a polymer containing a repeating unit represented by the following general formula (I) in an amount of 2 mg to 1000 mg per mole of silver as the weight of said repeating units in said polymer: ##STR1## wherein R.sup.1 represents a hydrogen atom or an alkyl group and Q represents a group selected from the group consisting of the following (1)-(4): ##STR2## wherein q represents an integer of 2 to 4, ##STR3## wherein R.sup.2 and R.sup.3 each represents a hydrogen atom or an alkyl group, ##STR4## wherein Z.sup.
    Type: Grant
    Filed: February 17, 1982
    Date of Patent: February 14, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadao Sugimoto, Ichizo Toya, Shigeharu Urabe, Shinji Sakaguchi
  • Patent number: 4431730
    Abstract: A process for the preparation of an internal latent image type silver halide emulsion containing silver halide grains comprising a central core of silver halide doped with metal ions, chemically sensitized or a combination thereof and an outer shell of silver halide covering at least light-sensitive sites of the central core characterized in that the surface of the silver halide grains are chemically sensitized in the presence of a polymer containing the repeating unit represented by general formula (I) ##STR1## wherein symbols R.sup.1 and Q are defined in the specification.
    Type: Grant
    Filed: February 17, 1982
    Date of Patent: February 14, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeharu Urabe, Shinji Sakaguchi, Ichizo Toya, Tadao Sugimoto
  • Patent number: 4426445
    Abstract: A silver halide photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer. The material contains at least one compound selected from the group consisting of a compound represented by the following general formula (I) and a compound represented by the following general formula (II) in at least one layer of the silver halide emulsion layer and other hydrophilic colloid layers thereof; ##STR1## wherein R represents an alkyl group having 1 to 6 carbon atoms which may be substituted, an aryl group having 6 to 11 carbon atoms which may be substituted, or an aralkyl group having 7 to 12 carbon atoms which may be substituted; A represents a .sigma. bond or a divalent connecting group which links R and the nitrogen atom; R.sub.1 and R.sub.2 are independently hydrogen, an alkyl group having 1 to 6 carbon atoms which may be substituted, or an aralkyl group having 7 to 11 carbon atoms which may be substituted, or when A represents a .sigma. bond, R.sub.
    Type: Grant
    Filed: March 31, 1983
    Date of Patent: January 17, 1984
    Assignee: Fuji Photo Film, Co., Ltd.
    Inventors: Junji Minamizono, Mitunori Hirano, Yoshiro Kawashima, Tadashi Ogawa
  • Patent number: 4419443
    Abstract: A silver halide photographic light-sensitive material is described comprising a support having thereon at least one silver halide emulsion layer wherein the silver halide emulsion has been chemically ripened in the presence of at least one compound containing at unit represented by the formula ##STR1## wherein M represents hydrogen, an alkali metal atom, or NH.sub.4. The silver halide photographic light-sensitive material shows high sensitivity without an accompanying increase in fog.
    Type: Grant
    Filed: November 10, 1981
    Date of Patent: December 6, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Yoshiharu Fuseya, Shinpei Ikenoue
  • Patent number: 4411985
    Abstract: Stabilizer precursors which comprise triarylphosphines and triarylphosphoranes and which, upon being heated to a temperature above about 100.degree. C., release a phosphorous compound silver halide stabilizer that is useful in a heat stabilizable photographic silver halide material comprising photographic silver halide. A stabilized image is produced in the photographic material following exposure and development by heating the material to processing temperature. The triarylphosphines and triarylphosphoranes are useful in a dry physical development photographic material and process. Alternatively, the triarylphosphines and triarylphosphoranes are useful in a dry chemical photographic material and process.
    Type: Grant
    Filed: September 17, 1981
    Date of Patent: October 25, 1983
    Assignee: Eastman Kodak Company
    Inventors: Lawrence R. Morrow, John Thatcher
  • Patent number: 4407935
    Abstract: The compounds of the formula ##STR1## in which R is amino, cyclic amino, aryloxy or a group of the formula ##STR2## in which L is a radical of the formula .dbd.N-Z, with Z being alkyl or cycloalkyl, or is a heterocyclic radical, aryleneoxy or oxyaryleneoxy and R' and R" are hydrogen, alkyl or halogen, and x and y are 0, 1, 2 or 3, are suitable development accelerators for the development of exposed photographic materials containing silver halide. They accelerate the reduction of the exposed silver salt to silver and thus enhance the sensitivity of the photographic material.
    Type: Grant
    Filed: January 15, 1982
    Date of Patent: October 4, 1983
    Assignee: Ciba-Geigy AG
    Inventors: Mario Fryberg, David G. Leppard
  • Patent number: 4396711
    Abstract: Derivatives of thiazolidine are used in photographic silver halide emulsions to increase their speed 40% or more with little or no increase in emulsion fog. Lower silver halide coating weights are thus possible.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: August 2, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Joseph D. Overman
  • Patent number: 4396712
    Abstract: A novel dry image forming material comprising in one or more layers on a support (a) a non-photosensitive organic silver salt oxidizing agent, (b) a reducing agent for silver ions, (c) a silver halide component or a silver halide-forming component, (d) a toning agent and (e) a lipophilic binder, characterized by the inclusion of a specific 2-(2'-hydroxyphenyl)benzotriazole compound having bulky tert-butyl or tert-amyl groups at its ortho- and para-positions relative to the hydroxyl group in a layer containing the component (a). The dry image forming material of the present invention has high storage stability prior to use for image formation.
    Type: Grant
    Filed: May 29, 1981
    Date of Patent: August 2, 1983
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Shozo Kinoshita, Muneaki Kimura, Tetsuo Shiga
  • Patent number: 4378426
    Abstract: Photographic silver halide emulsions show increased speed and reduced latent image fading when a compound of the following structure is incorporated: ##STR1## wherein: X is -O-, -S-, -Se-, or ##STR2## Y represents the atoms completing a fused aromatic nucleus; Z is ##STR3## R is hydrogen or lower alkyl of from 1 to 5 carbon atoms.
    Type: Grant
    Filed: November 12, 1981
    Date of Patent: March 29, 1983
    Assignee: Eastman Kodak Company
    Inventors: Roger Lok, John P. Freeman, William N. Baum
  • Patent number: T103803
    Abstract: Photographic silver halide emulsions show increased speed and reduced latent image fading when a compound of the following structure is incorporated: ##STR1## wherein: X is --O--, --S--, --Se--, or ##STR2## Y represents the atoms completing a fused aromatic nucleus; Z is ##STR3## and R is hydrogen or lower alkyl of from 1 to 5 carbon atoms.
    Type: Grant
    Filed: August 16, 1982
    Date of Patent: January 3, 1984
    Inventors: Roger Lok, John P. Freeman, William N. Baum
  • Patent number: T104802
    Abstract: A photographically useful alkynyl compound is disclosed which is nonionic under aqueous alkaline photographic processing conditions. The alkynyl compound is comprised of an alkynyl group attached to a methylene group through a divalent chalcogen or an imino group. The methylene group is activated by an electron withdrawing substituent. The alkynyl compounds are useful in direct positive internal latent image forming emulsions as nucleating agents and in negative working surface latent image emulsions to increase speed and/or contrast.
    Type: Grant
    Filed: February 21, 1984
    Date of Patent: November 6, 1984
    Inventor: Richard L. Parton