S, Se, Or Te Or Compound Thereof Patents (Class 430/603)
  • Patent number: 5066573
    Abstract: A silver halide color photographic material is described, comprising a support having thereon at least one of a silver halide emulsion layer and other hydrophilic colloid layer, wherein the silver halide emulsion layer or a hydrophilic colloid layer contains at least one compound represented by formula (II): ##STR1## wherein R.sub.2 represents a hydrogen atom or a group that can be substituted, Y.sub.1 represents ##STR2## R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8, which may be the same or different, each represents a hydrogen atom or a group that can be substituted; X.sub.1 represents a divalent linking group containing a hetero atom connected to the carbon atom; m is 0 or 1; A represents a bleach accelerating agent moiety represented by ##STR3## wherein R.sub.9, L, X.sub.2 R.sub.10 B, l.sub.1 and L.sub.2 are defined in the specification.The compound represented by formula (II) is a bleach accelerating agent having an active group of adsorptive group.
    Type: Grant
    Filed: February 12, 1990
    Date of Patent: November 19, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetunori Matushita, Morio Yagihara, Kei Sakanoue
  • Patent number: 5059516
    Abstract: A silver halide photographic material that contains at least one compound represented by the general formula (2) shown below and at least one compound selected from the group consisting of the compounds represented by the general formulas (3) and (4) shown below: ##STR1## The constituents in the above formulas are clearly defined in the instant specification and claims.
    Type: Grant
    Filed: October 30, 1990
    Date of Patent: October 22, 1991
    Assignee: Konica Corporation
    Inventors: Kiyoshi Sato, Kouji Ono
  • Patent number: 5051336
    Abstract: A negative type silver halide photographic material is disclosed. The material comprises a support having provided thereon at least one silver halide emulsion layer containing silver halide grains sensitized with gold and sulfur sensitizers, the emulsion layer or at least one other hydrophilic colloid layer containing at least one high contrast-imparting hydrazine derivative and at least one compound represented by the following general formula (I): ##STR1## wherein Z represents N or C--X wherein X represents a substituted or unsubstituted alkyl or aryl group, Y represents a substituted or unsubstituted alkyl or aryl group, and M represents a hydrogen atom, a metallic atom, or ammonium which may be substituted.
    Type: Grant
    Filed: May 11, 1990
    Date of Patent: September 24, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Senzo Sasaoka, Tetsuo Yoshida
  • Patent number: 5041367
    Abstract: A photographic recording material is provided which has enhanced photographic properties, such as sharpness values without substantial decrease in photographic speed.
    Type: Grant
    Filed: March 5, 1990
    Date of Patent: August 20, 1991
    Assignee: Eastman Kodak Company
    Inventor: Henry J. Sniadoch
  • Patent number: 5037733
    Abstract: A silver halide photosensitive material comprising a support having thereon at least one silver halide emulsion layer containing silver halide grains. These silver halide grains are obtained by subjecting the surface of silver halide grains to halogen conversion. These silver halide grains are essentially silver iodide free silver chlorobromide. They have a plurality of internal layers of different halogen compositions and contain at least one bridged pentamethine cyanine dye compound represented by the general formula (I) or (I'): ##STR1## and one compound represented by general formula (II): ##STR2## The variables in the above formulas are defined in the instant specification.
    Type: Grant
    Filed: November 28, 1989
    Date of Patent: August 6, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kensuke Goda
  • Patent number: 5035989
    Abstract: A silver halide photographic material for reversal processing is disclosed, which comprises a support having provided thereon at least one hydrophilic colloidal layer, the hydrophilic colloidal layer being a light-sensitive silver halide emulsion layer, silver halide grains of the silver halide emulsion being of a core/shell structure comprising a core portion substantially composed of silver bromide and said shell portion substantially composed of silver bromoiodide.
    Type: Grant
    Filed: November 28, 1989
    Date of Patent: July 30, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shingo Nishiyama, Naomi Saeki
  • Patent number: 5028522
    Abstract: A silver halide photographic material is disclosed, which contains at least one compound represented by general formula (I) or general formula (II):Z--R-Se--R'--Z' (I)Z--R--Se--R" (II)where R and R' each individually represent bivalent groups composed of at least one of the following types of atoms carbon atoms, nitrogen atoms, oxygen atoms, sulfur atoms, and selenium atoms; Z and Z' each individually represent a hydroxyl group, an amino group, an ammonium group, a carboxylic acid group, a salt of a carboxylic acid group, a sulfonic acid group, a salt of a sulfonic acid group, an ether group, a thioether group, a selenoether group, a ureido group, a thioureido group, an oxycarbonylamino group, an acyl group, a sulfonyl group, a carbamoyl group, a carboxamido group, a sulfamoyl group a sulfonamido group, an acyloxy group, a sulfonyloxy group, an oxycarbonyl group, an oxysulfonyl group, or a heterocyclic group; and R" represents an alkyl group, an cycloalkyl group, an alkenyl group, an aralkyl group, or aryl gr
    Type: Grant
    Filed: November 14, 1989
    Date of Patent: July 2, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Hiroyuki Mifune
  • Patent number: 5015567
    Abstract: A silver halide photographic emulsion is subjected to sulfur or gold-sulfur sensitization in the presence of a combination of (1) at least one of an organic thioether compound or a tetrasubstituted thiourea and (2) a nitrogen-containing heterocyclic compound, to achieve the prevention of pressure desensitization and safelight aptitude deterioration.
    Type: Grant
    Filed: February 10, 1989
    Date of Patent: May 14, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shuzo Suga, Tadao Shishido, Hiroyuki Mifune, Yoshiro Kawashima
  • Patent number: 5009993
    Abstract: A direct positive photographic material comprising a support having provided thereon one or more hydrophilic colloid containing layers, wherein at least one of said hydrophilic colloid containing layers is an internal latent image type silver halide emulsion which has not been previously fogged and at least one of said emulsion layer or other hydrophilic colloid containing layer contains a colloidal metal or a colloidal water-insoluble metallic sulfide, selenide or telluride, and a method for forming a direct positive from the direct positive photographic material in which a light-sensitive material contains at least two layers containing colloidal silver.
    Type: Grant
    Filed: October 16, 1989
    Date of Patent: April 23, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Inoue, Tatsuo Heki
  • Patent number: 5004679
    Abstract: A silver halide photographic material is disclosed which comprises at least one silver halide emulsion layer on a support, wherein light-sensitive silver halide grains in the silver halide emulsion layer or layers are obtained by charging previously prepared silver halide particles having a fine size into a reaction vessel which allows nucleation and/or crystallization of the light-sensitive silver halide grains so that nucleation and/or crystallization are effected in the reaction vessel, and the light-sensitive silver halide grains are subjected to chemical ripening in the presence of a silver halide solvent. A process for the preparation of the silver halide photographic material is also disclosed.
    Type: Grant
    Filed: January 9, 1990
    Date of Patent: April 2, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shigeharu Urabe
  • Patent number: 5004680
    Abstract: A silver halide photographic light-sensitive material is disclosed which has a high speed with a low fog and is improved on the long-term preservability. The light-sensitive material comprises a support having thereon a photographic component layer including at least one silver halide emulsion layer, in which the silver halide emulsion layer comprises silver halide grains, each of which are comprised of two or more phases different in the silver iodide content, wherein the average silver iodide content of the grain is higher than the silver iodide content of the external phase of the grain, and to at least one layer included the photographic component layer is added elementary sulfur in a step of manufacturing process of the silver halide photographic light-sensitive material.
    Type: Grant
    Filed: June 1, 1989
    Date of Patent: April 2, 1991
    Assignee: Konica Corporation
    Inventors: Toshihiko Yagi, Kenji Kumashiro, Hideki Takiguchi
  • Patent number: 5001042
    Abstract: A method for forming an image which comprises developing an imagewise exposed silver halide color photographic material with a color developer containing at least one aromatic primary amine color developing agent, wherein said silver halide color photographic material contains a silver chlorobromide emulsion having an average silver bromide content of from 0.1 to 10 mol % and containing substantially no iodide in at least one layer thereof, at least said silver chlorobromide emulsion containing a gold compound, and said color developer contains from 3.5.times.10.sup.-2 to 1.5.times.10.sup.-1 mol/l of chloride ion and from 3.0.times.10.sup.-5 to 1.0.times.10.sup.-3 mol/l of bromide ion.
    Type: Grant
    Filed: October 3, 1989
    Date of Patent: March 19, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazunori Hasebe
  • Patent number: 4990440
    Abstract: The sensitivity/fog ratio can be improved by using photographic silver halide emulsions containing gelatine which has a cysteine content of less than 10 ppm and a gold number of .gtoreq.23 .mu.mol/g.
    Type: Grant
    Filed: August 4, 1989
    Date of Patent: February 5, 1991
    Assignee: Agfa-Gevaert Aktiengessellschaft
    Inventors: Franz Moll, Bruno Mucke, Walter Patzold, Klaus Wagner
  • Patent number: 4988603
    Abstract: A processing method for silver halide photographic material is disclosed, which stably provides images having high contrast and high dot quality with little degradation in sensitivity by rapid processing.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: January 29, 1991
    Assignee: Konica Corporation
    Inventors: Yasuhiko Takamuki, Takeshi Habu, Junichi Fukawa
  • Patent number: 4971890
    Abstract: A silver halide photographic material is disclosed, comprising a support having thereon at least one of silver halide photographic emulsion layers and other hydrophilic colloidal layers, wherein said photographic emulsion layers or other hydrophilic colloidal layers contain a hydrazine compound represented by formula (I): ##STR1## wherein at least one of A.sub.1 and A.sub.2 represents a hydrogen atom and the other represents a hydrogen atom, a sulfonyl group or an acyl group; R.sub.1 represents an aliphatic, group, an aromatic group, or a heterocyclic group; Y.sub.1 represents a divalent organic group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## wherein R.sub.2 represents an alkoxy group or an aryloxy group, ##STR3## or an iminomethylene group; Z.sub.1 represents a group suitable for making a nucleophilic attack on G.sub.1 to separate the G.sub.1 --L.sub.1 --Z.sub.1 from the rest of the molecule; and L.sub.
    Type: Grant
    Filed: May 9, 1989
    Date of Patent: November 20, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Kazunobu Katoh
  • Patent number: 4971899
    Abstract: Direct positive photographic films are disclosed having novel density enhancers of the formula ##STR1## wherein A is oxygen or sulfur, and B is selected from the group consisting of hydrogen, alkyl haloalkyl, hydroxyalkyl, alkylamino and alkoxy. Photographic materials coated with emulsions having these density enhancers display good optical density while maintaining high speed capability.
    Type: Grant
    Filed: May 5, 1989
    Date of Patent: November 20, 1990
    Assignee: Sun Chemical Corporation
    Inventors: Steven R. Gallo, John Abbruzzese, Adelberto Aguero
  • Patent number: 4971889
    Abstract: A silver halide photographic emulsion containing at least one compound represented by following formula (I):Dye--L--Hyd (I)wherein Dye represents a chromophore-containing dye residue shown by following formula (II); Hyd represents a hydrazine residue one of the two nitrogen atoms of which is substituted by a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an alkilydene group and L represents a divalent linkage group of bonding Dye and Hyd; ##STR1## wherein R and R.sub.1, which may be the same or different, each represents an alkyl group; Z and Z.sub.1, which may be the same or different, each represents an atomic group necessary for forming a 5- or 6-membered heterocyclic ring; Q represents an atomic group necessary for forming a 5- or 6-membered carbon ring or a 5- or 6-membered heterocyclic ring; A represents an oxygen atom or a sulfur atom; and n, d, and m each represents 0 or 1.
    Type: Grant
    Filed: September 1, 1989
    Date of Patent: November 20, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ikeda, Haruo Takei, Satoru Takimoto, Masaki Okazaki
  • Patent number: 4965184
    Abstract: Photographic, silver halide emulsions can be additionally sensitized without a deleterious increase in fog, by the addition of an alkali metal salt of 1-napthol-4-sulfonic acid. These emulsions are stable, and have good contrast and top density. The 1-napthol-4-sulfonic acid can be added conveniently from an aqueous solution and is totally compatible with conventional silver halide elements.
    Type: Grant
    Filed: February 23, 1989
    Date of Patent: October 23, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Raymond J. LeStrange
  • Patent number: 4963475
    Abstract: A method of processing an imagewise exposed light-sensitive silver halide photographic material. The material contains a silver halide emulsion layer containing silver halide grains which are sensitized with a monomethine dye. The material is processed with a developer solution containing an aromatic primary amine color developing agent in the presence of at least one hydroxylamine derivative and at least one nitrogen containing heterocyclic mercapto compound.
    Type: Grant
    Filed: March 28, 1989
    Date of Patent: October 16, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kazuhiro Murai, Keiji Ohbayashi, Kaoru Onodera
  • Patent number: 4962016
    Abstract: A silver halide photographic light-sensitive material which has an excellent gradation and an excellent pressure resistance. The photographic material comprising a support and, provided thereon, a photographic component layer including a silver halide emulsion layer in which the sewlling degree of said photographic component layer is not higher than 150 and said silver halide emulsion layer is added with elementary sulfur.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: October 9, 1990
    Assignee: Konica Corporation
    Inventors: Shigeo Chino, Mitsuhiro Okumura
  • Patent number: 4962015
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer containing at least one emulsion in which chemically sensitized silver halide grains are composed of tabular silver halide grains having a diameter of a circle corresponding to the projected area of at least 0.4 .mu.
    Type: Grant
    Filed: May 2, 1989
    Date of Patent: October 9, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shunichi Aida, Yoshinori Shibata
  • Patent number: 4960689
    Abstract: A silver halide color photographic light-sensitive material includes a support having thereon at least one silver halide emulsion layer, wherein the emulsion layer contains a silver halide emulsion which comprises silver halide grains consisting of at least 50 mol % of silver chloride and contains at least one of the compounds represented by formulas [I] to [III]: ##STR1## wherein Z represents alkyl (the number of carbon atoms is 1 to 18), aryl (the number of carbon atom is 6 to 18), or heterocyclic,Y represents an atom group required for forming heterocyclic or aryl (the number of carbon atoms of the aryl is 6 to 18),M represents metal cation, organic cation, or hydrogen atom, andn represents an integer from 2 to 10.
    Type: Grant
    Filed: June 2, 1988
    Date of Patent: October 2, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihiro Nishikawa, Shunji Takada, Kazunori Hasebe
  • Patent number: 4957849
    Abstract: A silver halide photographic material is disclosed, which comprises a support having provided thereon at least one silver halide emulsion layer and which contains a hydrazine derivative in the emulsion layer or other hydrophilic colloidal layer, the emulsion layer containing two kinds of monodispersed silver halide grains different from each other in mean grain size, and the smaller sized monodispersed silver halide grains being chemically sensitized.An image-forming method using this photographic material is also disclosed.
    Type: Grant
    Filed: March 14, 1989
    Date of Patent: September 18, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Senzo Sasaoka
  • Patent number: 4956260
    Abstract: A light-sensitive material comprising a light-sensitive layer provided on a support wherein the light-sensitive layer contains silver halide, a reducing agent, a polymerizable compound, and an additive compound selected from the group consisting of a 5- or 6-membered nitrogen containing heterocyclic compound, thiourea, a thiourea derivative, a thioether compound, polyethylene glycol and a polyethylene glycol derivative. Thermal image-forming methods utilizing the light-sensitive materials are also disclosed.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: September 11, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koichi Nakamura
  • Patent number: 4952490
    Abstract: A photographic light-sensitive material comprises a support having thereon at least one silver halide emulsion layer. At least 70% of a total number of silver halide grains contained in the emulsion layer are regular crystal grains not having a twinning plane. At least 50 mol% of the regular grains are silver chloride. The regular crystal grains have a (111) crystal plane on 30% or more of a total grain surface and are chemically sensitized in the presence of a gold compound or sulfur and gold compounds.
    Type: Grant
    Filed: March 1, 1988
    Date of Patent: August 28, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shunji Takada, Toshihiro Nishikawa, Kei Sakanoue, Akira Abe
  • Patent number: 4923794
    Abstract: A silver halide photographic material comprising silver halide emulsion including a telluroether compound of the formula (I):L.sub.1 --Te--L.sub.2 (I)wherein L.sub.1 and L.sub.2 each independently represents a substituted or unsubstituted aliphatic group which is substituted with at least one hydroxyl group, mercapto group, amino group, ether group, selenoether group, thioether group, ammonium group, sulfonyl group, carbamoyl group, carbonamido group, sulfamoyl group, sulfonamido group, acyloxy group, sulfonyloxy group, ureido group, thioureido group, thioamido group, oxysulfonyl group, oxycarbonylamino group, sulfonic acid group or salt thereof, phosphoric acid or salt thereof, phosphoric ester group, sulfinic acid group or a salt thereof, phosphino group or heterocyclic group.
    Type: Grant
    Filed: July 11, 1989
    Date of Patent: May 8, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hirotomo Sasaki, Tadao Shishido, Hiroyuki Mifune
  • Patent number: 4921784
    Abstract: A thiocyanate-containing silver halide emulsion, characterized in that a disc tablet of 2.5 mm in diameter formed of 10 mg of silver halide contained in the silver halide emulsion shows an absorbance of 0.015 or higher or thiocyanate ion at 2052 cm.sup.-1, measured by IR spectroscopy. The emulsion is high in sensitivity, small in loss of photographic sensitivity caused by pressure and small in fluctuations in results of photographic processings.
    Type: Grant
    Filed: July 16, 1986
    Date of Patent: May 1, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideo Ikeda, Ryoichi Nemori
  • Patent number: 4914002
    Abstract: A silver halide negative photographic material comprising a support having thereon at least one silver halide emulsion layer, at least one hydrophilic colloidal layer thereof containing (1) a hydrazine derivative, (2) a compound substantially having no absorption maximum in the visible light region represented by formula (I): ##STR1## wherein Z.sup.11, Z.sup.12, R.sup.11, R.sup.12 X and n are as defined in the specification, and (3) at least one compound represented by formula (II) or (III): ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and Q are as defined in the specification; and ##STR3## wherein R.sub.21, R.sub.22, R.sub.23, and R.sub.24, are as defined in the specification. The photographic material can be processed with a stable developer to provide an ultra-high contrast image without reduction in sensitivity, gamma or maximum density or the appearance of black pepper. The photographic material is excellent in pressure properties and anti-blocking properties.
    Type: Grant
    Filed: November 4, 1988
    Date of Patent: April 3, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Hisashi Okada, Shigeo Hirano, Kimitaka Kameoka, Tetsuo Yoshida, Morio Yagihara
  • Patent number: 4914016
    Abstract: A silver halide photographic light-sensitive material containing inorganic sulfur or elemental sulfur, and a processing method comprising a step for developing such photographic material with a color developer which contains an aromatic primary amine compound for not more than 60 seconds. Photographic image improved in contrast of the without degradation in sensitivity and fogging can be obtained by the photographic material and the processing method.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: April 3, 1990
    Assignee: Konica Corporation
    Inventors: Masanobu Miyoshi, Makoto Kajiwara, Shigeo Tanaka, Mitsuhiro Okumura
  • Patent number: 4906558
    Abstract: Color photographic silver halide material in which at least one layer contains a silver halide emulsion with 95 to 100 mol % of chloride which has been optimally ripened with a combination of at least one sulphur ripening body and at least one compound of the formula ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 denote, independently of one another, hydrogen or alkyl, and X.sup..crclbar. denotes an anion, combines excellent sensitivity with low fog and steep gradation, particularly in the threshold and shoulder region.
    Type: Grant
    Filed: October 14, 1988
    Date of Patent: March 6, 1990
    Assignee: AGFA-Gevaert Aktiengesellschaft
    Inventors: Bruno Mucke, Franz Moll
  • Patent number: 4897342
    Abstract: In a method of preparing a light-sensitive silver halide photographic emulsion, silver salt and halide are mixed in the presence of an iridium compound. The emulsion is then chemically ripened by an instable sulfur compound and a nitrogen-containing heterocyclic compound capable of forming a complex with silver.
    Type: Grant
    Filed: April 14, 1989
    Date of Patent: January 30, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Makoto Kajiwara, Masanobu Miyoshi, Kaoru Onodera
  • Patent number: 4897343
    Abstract: A spectrally sensitized silver halide photographic emulsion is disclosed, which comprises at least one alkali metal sulfite compound and at least one ascorbic acid compound.
    Type: Grant
    Filed: May 11, 1988
    Date of Patent: January 30, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ikeda, Haruo Takei, Shunichi Aida
  • Patent number: 4892809
    Abstract: A silver halide color photographic material having at least one silver halide emulsion layer on a base, in which the emulsion layer contains at least one kind of specific magenta coupler of a pyrazoloazole system and the silver halide emulsion is a silver chlorobromide emulsion or silver chloroiodobromide emulsion chemically sensitized in the presence of a nucleic acid or a decomposition product thereof prior to the completion of chemical sensitization by sulfur compounds. This color photographic material is improved in color reproduction and image stability, less liable to fogging that is formed during development, and less dependent on processing conditions.
    Type: Grant
    Filed: May 11, 1989
    Date of Patent: January 9, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yasuhito Momoki
  • Patent number: 4888273
    Abstract: Silver halide emulsions containing tabular silver halide grains are stabilized by the employment of a compound of the formula ##STR1## where R is --SO.sub.2 NH.sub.2, In a preferred embodiment an azaindene is also employed.
    Type: Grant
    Filed: February 26, 1988
    Date of Patent: December 19, 1989
    Assignee: Polaroid Corporation
    Inventors: Richard S. Himmelwright, Avinash C. Mehta, Lloyd D. Taylor
  • Patent number: 4865965
    Abstract: This invention is directed to a light sensitive silver halide emulsion comprising a cyclic ether compound having an acid function and to an element containing such emulsion and to a process for using same. The compound comprises, in the cyclic ring, at least two atoms from the group consisting of sulfur and selenium, each of which atoms being separated from one another by a chain of at least two carbon atoms. Such compound acts as a solvent and as a growth modifying agent for silver halide grains. Also described is a process for modifying the growth of silver halide grains.
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: September 12, 1989
    Assignee: Eastman Kodak Company
    Inventors: Gerard Friour, Arthur H. Herz, Christian Paris, Marcel Riveccie
  • Patent number: 4865947
    Abstract: A negative-type silver halide photographic material comprising a support and at least one light-sensitive silver halide emulsion layer on the support, wherein compounds represented by the general formulae (I) and (II) are incorporated in the light-sensitive silver halide emulsion layer or the hydrophilic colloid layer adjacent thereto. General Formula (I):R.sub.1 --NHNH--G--R.sub.2 (I)General Formula (II):Z.sub.0 --S--Z.sub.1 (II)wherein R.sub.1 is an aliphatic or aromatic group, R.sub.2 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group, and G is a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted imino group, and Z.sub.0 is an alkyl group, an aromatic group, or a heteroaromatic group, said group Z.sub.
    Type: Grant
    Filed: August 26, 1988
    Date of Patent: September 12, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kenichi Kuwabara, Yoshio Inagaki
  • Patent number: 4865962
    Abstract: A photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, characterized in that the emulsion layer contains silver chlorobromide prepared in such a manner that silver halide regular crystal grains, having no twinning crystal plane and containing 50 mol % or more of silver chloride, are used as host grains, an organic compound is adsorbed on a surface of each of the host grains, and sulfur-plus-gold sensitization is performed, either during or after halide conversion in the presence of a bromide.
    Type: Grant
    Filed: December 28, 1987
    Date of Patent: September 12, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunori Hasebe, Masahiro Asami, Naoto Ohshima, Keisuke Shiba, Toshihiro Nishikawa, Kei Sakanoue, Akira Abe
  • Patent number: 4863843
    Abstract: A silver halide photographic emulsion comprising as major constituent silver bromide with improved gradation, density and sensitivity and decreased fog is disclosed. This emulsion contains at least one of the compounds represented by the general formula ##STR1## wherein Z represents an aromatic radical, or of the oxidized derivatives thereof, and at least one of the compounds represented by the general formula ##STR2## wherein A represents a hydroxyl group, an amino group, ##STR3## R.sub.1 and R.sub.2 form a ring jointly with the carbon atom to which R.sub.1 and R.sub.2 are attached or one of R.sub.1 and R.sub.2 represents a hydrogen atom and the other represents a hydrogen atom, an alkyl group, an aryl group, or a hydroxyl group; n is 0 or an integer of 1 to 8, and M represents a hydrogen atom or an alkali metal.
    Type: Grant
    Filed: October 28, 1985
    Date of Patent: September 5, 1989
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Masao Okushima, Katsuaki Iwaosa, Susumu Baba, Tokitsugu Houjo
  • Patent number: 4863845
    Abstract: In an internal latent image type direct positive silver halide emulsion containing core/shell type silver halide grains wherein at least light-sensitive sites of the silver halide internal core which has been subjected to doping with metal ions or chemical sensitization, or both, is covered with a silver halide outer shell, the improvement wherein a photographic additive which is adsorbed on silver halide in said emulsion or interacts with silver ion, said additive being a compound which functions to change the crystal form or particle size of the silver halide grains in the case of the formation thereof or acts as a sensitizer or a sensitizing assistant in the case of chemically sensitizing the core particles but has a harmful influence on photographic properties if it remains after use of it, is deactivated by a deactivator prior to completion of the formation of said core/shell type silver halide grains or completion of surface chemical ripening of said grains.
    Type: Grant
    Filed: August 6, 1987
    Date of Patent: September 5, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ashita Murai, Hiroyuki Mifune, Tatsuo Heki
  • Patent number: 4863846
    Abstract: A silver halide photographic light-sensitive material is disclosed which is decreased in variation of light-sensitivity caused by a change in environmental humidity and a prolonged storage of the photographic material.
    Type: Grant
    Filed: June 21, 1988
    Date of Patent: September 5, 1989
    Assignee: Konica Corporation
    Inventors: Shigeo Tanaka, Mitsuhiro Okumura, Makoto Kajiwara, Masanobu Miyoshi
  • Patent number: 4863844
    Abstract: A silver halide light-sensitive photographic material which is excellent in the aptitude for rapid processing and highly sensitive and of which the sensitivity and gradation are stable against the change of the temperature at the time of exposure is disclosed. The silver-halide photographic material comprises a support and, provided thereon, a silver halide emulsion layer, wherein said silver halide emulsion layer contains silver chloro-halide grains containing not less than 90 mole % of silver chloride and having been chemically sensitized in the presence of a labile sulfur compound and a gold compound, and an organic compound of which solubility product (Ksp) with a silver ion is not more than 1.times.10.sup.11.0, said organic compound having been added to said silver halide emulsion layer during the period between after the formation of said silver halide grains and before the completion of the chemical sensitization thereof.
    Type: Grant
    Filed: November 17, 1987
    Date of Patent: September 5, 1989
    Assignee: Konica Corporation
    Inventors: Mitsuhiro Okumura, Keiji Ohbayashi, Shigeo Tanaka
  • Patent number: 4857450
    Abstract: High contrast negative acting silver halide emulsions suitable for laser scanning applications comprising a Group VIII metal compound and one or more spectrally sensitizing dyes of the formula ##STR1## The emulsions have good long term stability and good sensitivity.
    Type: Grant
    Filed: April 27, 1987
    Date of Patent: August 15, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Ronald W. Burrows, Keith A. Penfound, Bernard A. Lea
  • Patent number: 4853323
    Abstract: The present invention relates to a silver halide emulsion containing a thiocyanate and having a high sensitivity in particular to light of a low illuminance. According to the present invention, a silver halide emulsion is provided, wherein the IR absorbance at 2052 cm.sup.-1 due to thiocyanate ion contained in the silver halide grain of the emulsion is observed and a tricarboxylic acid or its salt is contained in the emulsion.
    Type: Grant
    Filed: October 15, 1986
    Date of Patent: August 1, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideo Ikeda, Shuzo Suga, Nobuaki Miyasaka
  • Patent number: 4845023
    Abstract: A silver halide photographic light-sensitive material comprising at least one layer of a silver halide emulsion on a support is improved in shelf stability by treating a chemically sensitized silver halide emulsion with an ion-exchange resin or a porous absorbent to remove residue of the chemical sensitizer during and/or after chemical sensitization.
    Type: Grant
    Filed: August 19, 1987
    Date of Patent: July 4, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Mifune
  • Patent number: 4840887
    Abstract: A silver halide photographic material is disclosed, which comprises a support having formed thereon at least one silver halide emulsion layer, wherein the silver halide photographic material contains, in the silver halide emulsion layer, other hydrophilic colloid layer(s), or both, a compound represented by formula (I) ##STR1## wherein EAG represents an electron accepting group, --SO.sub.2 -- represents a sulfonylene group; X represents an oxygen atom (--O--), a sulfur atom (--S--) or an atomic group (--N(R.sub.2)--) containing a nitrogen atom; the single bond between --SO.sub.2 and X being cleaved after EAG receives an electron, wherein R.sub.1 and R.sub.2 each represents a simple bond or a group other than a hydrogen atom; said R.sub.1, R.sub.2, EAG may be combined with each other to form a ring; (Time) represents a group capable of releasing a photographically useful group (PUG) upon the cleavage of the SO.sub.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: June 20, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koki Nakamura
  • Patent number: 4837136
    Abstract: A silver halide photographic material is described comprising a support having coated thereon at least one silver halide emulsion layer, wherein at least one of the silver halide emulsion layer and other hydrophilic colloid layer contains a nondiffusible photographically useful compound having a sulfo group and a group represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represents an aliphatic group having at least 2 carbon atoms and r represents 0 or 1.The compounds represented by the general formula (I) are photographically useful compounds which impart excellent photographic properties to silver halide photographic materials, including improved dispersibility.
    Type: Grant
    Filed: October 9, 1986
    Date of Patent: June 6, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Yasuhiro Shimada, Jun Arakawa
  • Patent number: 4830958
    Abstract: A photographic material having an excellent rapid processability, a high sensitivity and a less sensitivity variation due to a change of standing of the silver halide emulsion in the course of preparation of the light-sensitive material, and its preparation process are disclosed. The silver halide photographic light-sensitive material comprises a support bearing at least one silver halide emulsion layer thereon, and at least one silver halide emulsion layer contains highly chloride-containing silver halide grains having a silver chloride content of not less than 90 mol %, a water-soluble bromide of from 0.05 mol % to 2 mol % per mol of silver halide and a high boiling organic solvent having a dielectric constant of not higher than 6.0.
    Type: Grant
    Filed: January 25, 1988
    Date of Patent: May 16, 1989
    Assignee: Konica Corporation
    Inventors: Mitsuhiro Okumura, Keiji Ohbayashi, Shigeo Tanaka
  • Patent number: 4818671
    Abstract: A silver halide color photographic material improved in sensitivity, gradiation and maximum density when the material is treated with a rapid processing. The silver halide color photographic material comprises a support and photograhic component layers including at least one silver halide emulsion layer comprising (a) silver halide grains comprising not less than 80 mol % of silver chloride, (b) a gold compound in an amount of from 5.times.10.sup.-7 to 5.times.10.sup.-3 mol per mol of silver halide contained in said silver halide emulsion layer, (c) a sulfur sensitizer and (d) a spectral sensitizing dye represented by the following general formula [I]: ##STR1## wherein X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an aryl group or a hydroxy group, respectively; R.sub.1 and R.sub.2 are an alkyl group, respective;y X.sup..crclbar. is a counter anion and n is 0 or 1.
    Type: Grant
    Filed: July 29, 1987
    Date of Patent: April 4, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Keiji Ohbayashi, Mitsuhiro Okumura, Takaaki Kojima, Shigeo Tanaka
  • Patent number: 4814264
    Abstract: A silver halide light-sensitive material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer comprising silver halide grains and a binder, at least about 50 wt % of said silver halide grains comprising a silver halide grain matrix having thereon from about 10 to 10,000 protrusions per square micrometer of grain matrix surface, said individual protrusions having an average projected area diameter of up to about 0.15 .mu.m, and a halogen composition of said protrusions differing from that of the grain matrix; said silver halide emulsion being chemically sensitized with at least one compound selected from the group consisting of a sulfur compound, a selenium compound, a reducing compound and a noble metal compound; and said silver halide emulsion being spectrally sensitized with a methine dye.
    Type: Grant
    Filed: December 17, 1987
    Date of Patent: March 21, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiichiro Kishida, Minoru Sato
  • Patent number: H830
    Abstract: A novel silver halide color photographic material containing a desilvering accelerator releasing compound, which comprises at least one light-sensitive silver halide emulsion layer on a support, wherein at least one of said emulsion layer and a non-light sensitive hydrophilic layer(s) contains at least one compound represented by the formula (I)PWR--Time--.sub.t BA (I)wherein PWR represents a group which undergoes reduction to release (Time--.sub.t BA; BA represents a group which becomes a desilvering accelerator after being released; Time represents a group which releases BA through a reaction after being released from PWR as (Time--.sub.t BA; and t represents an integer of 0 or 1.
    Type: Grant
    Filed: May 2, 1988
    Date of Patent: October 2, 1990
    Inventors: Naoyasu Deguchi, Shinji Ueda, Koki Nakamura