S, Se, Or Te Or Compound Thereof Patents (Class 430/603)
  • Patent number: 5593821
    Abstract: Disclosed are a silver halide emulsion which comprises multi-layered silver halide grains each having a major face of {100}, having a total Cl content of 20 mol %/mol of Ag or more and having an aspect ratio of 2 or more and which has been sensitized by selenium and/or tellurium sensitization, and a silver halide photographic material comprising the emulsion. The emulsion has a high sensitivity and a low fog, while having a high covering power. The intergranular uniformity of the halide composition in the multi-layered silver halide grains in the emulsion is good. Rapid processing of the photographic material is possible.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 14, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takayoshi Oyamada
  • Patent number: 5593820
    Abstract: A silver halide emulsion is described, which contains tabular silver halide grains having {100} faces as the parallel two major planes, having an aspect ratio of 2 or more and having a mean silver chloride content of 50 mol % or more, in an amount of 50% or more of the total projected area of all the silver halide grains therein, and which is spectrally sensitized with a particular trimethine dye of formula (I). A photographic material having the emulsion has a high sensitivity and good storability and can be processed rapidly.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: January 14, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hideyuki Shirai
  • Patent number: 5578440
    Abstract: A silver halide photographic material having high sensitivity, reduced in fog and excellent in storage stability is described, which comprises a support having thereon at least one constituent layer containing at least one hydrazone compound having a methine dye residue or an adsorbing group to silver halide through a covalent bond or containing at least one metallocene compound having a methine dye residue through a covalent bond.
    Type: Grant
    Filed: November 14, 1995
    Date of Patent: November 26, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Tadashi Ikeda
  • Patent number: 5576170
    Abstract: A photographic element comprising a support having situated thereon a silver halide emulsion, the emulsion comprising an alkynylamine compound of the formula: wherein Z represents atoms necessary to complete a 5 to 10-membered heterocyclic ring system, R.sup.1 represents hydrogen or an alkyl of from 1 to 5 carbon atoms, and R.sup.2 represents hydrogen, or an alkyl, aryl, heteroaryl, carbocyclic or heterocyclic group; andat least one dihydroxy aryl compound represented by formula II or III: ##STR1## wherein R.sup.3 to R.sup.12 are independently selected from the group consisting of hydrogen, hydroxy, sulfonate, or an alkyl of from 1 to 5 carbon atoms, and wherein at least two of such groups represent a hydroxy group.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: November 19, 1996
    Assignee: Eastman Kodak Company
    Inventors: Jon N. Eikenberry, Robert E. Bernard
  • Patent number: 5576173
    Abstract: A silver halide photographic element comprising a silver halide emulsion layer sensitized with a sensitizing dye of formula (I) which provides a maximum sensitivity at greater than 700 nm and which emulsion layer has substantially no dye deaggregating compound therein: ##STR1## wherein: X.sub.1 and X.sub.2 are independently sulfur, selenium or oxygen provided that X.sub.1 and X.sub.2 are not both oxygen and either benzo ring may be substituted or unsubstituted;R.sub.1 and R.sub.2 each independently represent an alkyl, aryl or heterocyclic group provided that at least one of R.sub.1 or R.sub.2 has an acid or acid salt substituent;A is a counterion as needed to balance the charge.
    Type: Grant
    Filed: July 13, 1995
    Date of Patent: November 19, 1996
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Anthony Adin
  • Patent number: 5573899
    Abstract: A silver halide photographic material having at least one light-sensitive emulsion layer containing a silver halide emulsion on a support, in which at least one silver halide emulsion layer contains silver halide grains of silver chloride or silver chlorobromide having a silver chloride content of 90 mol % or more, the silver halide grains being tellurium-sensitized, and at least one of light-sensitive emulsion layers or non-light-sensitive emulsion layers on the support contains at least one specific compound represented by formula (I), (II) or (III) herein. The material has excellent rapid processability and a high sensitivity. It involves little photographic fluctuation before and after continuous processing thereof and little photographic fluctuation due to variation of the ambient humidity during exposure thereof. The image sharpness of the material may be noticeably improved without appreciably detracting from the sensitivity thereof.
    Type: Grant
    Filed: May 17, 1994
    Date of Patent: November 12, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Akira Kase
  • Patent number: 5573903
    Abstract: A silver halide photographic material having the improved storability and anti-stress property is disclosed, which comprises a support having provided thereon at least one light-sensitive silver halide emulsion layer containing a silver halide emulsion, wherein the silver halide emulsion is subjected to a chemical sensitization with a selenium compound, and the emulsion layer or another layer provided on the support contains at least one of the compounds represented by formulas (I), (II) and (III): ##STR1## wherein R.sub.11 to R.sub.16, R.sub.21 to R.sub.26, R.sub.1 and R.sub.2 are defined in the specification.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: November 12, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Yamashita, Tetsuro Kojima, Hiroyuki Mifune, Mikio Ihama, Hirotomo Sasaki
  • Patent number: 5573901
    Abstract: A silver halide photographic material having the improved storability and anti-stress property is disclosed, which comprises a support having provided thereon at least one light-sensitive silver halide emulsion layer containing a silver halide emulsion, wherein the silver halide emulsion is subjected to a chemical sensitization with a selenium compound, and the emulsion layer or another layer provided on the support contains at least one of the compounds represented by formulas (I), (II) and (III): ##STR1##
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: November 12, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Yamashita, Tetsuro Kojima, Hiroyuki Mifune, Mikio Ihama, Hirotomo Sasaki
  • Patent number: 5571664
    Abstract: A negatively developing color photographic silver halide material containing at least two blue-sensitive, yellow-coupling silver halide emulsion layers, at least two green-sensitive, magenta-coupling silver halide emulsion layers, at least two red-sensitive, cyan-coupling silver halide emulsion layers and a yellow filter layer on a transparent support, the layers of the same spectral sensitivity having different photographic sensitivities and the blue-sensitive layers being arranged further from the support than the yellow filter layer and the green-sensitive and red-sensitive layers being arranged nearer the support than the yellow filter layer, is distinguished by improved development kinetics if at least one of the green-sensitive layers of highest sensitivity and the red-sensitive layers of highest sensitivity contains a crown ether.
    Type: Grant
    Filed: September 8, 1995
    Date of Patent: November 5, 1996
    Assignee: Agfa-Gevaert AG
    Inventors: J org Siegel, Peter Hankofer, Hans-Ulrich Borst
  • Patent number: 5569576
    Abstract: A photographic material is disclosed containing on at least one side of the support at least one light-sensitive silver halide emulsion layer characterised in that the light-sensitive layer and/or at least one non-light sensitive layer in water-permeable relationship with the light-sensitive layer comprises at least one compound having the general formula (I)R[O--CH.sub.2 --CH.sub.2 --S--(LINK.sup.1 --S).sub.x --CH.sub.2 --CH.sub.2 --O--(LINK.sup.2)].sub.y --OR (I)wherein each of LINK.sup.1 and LINK.sup.2 which may be the same or different represents a divalent linking group; R represents H, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or an acyl group; x is 0, 1 or 2, and y varies from 2 to 20.
    Type: Grant
    Filed: February 27, 1995
    Date of Patent: October 29, 1996
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Jean-Marie Dewanckele, Geert Vercruysse, Ralf B uscher
  • Patent number: 5567571
    Abstract: A color photographic light-sensitive material comprises at least two silver halide emulsion layer groups having different color sensitivities on a support. Each group contains at least two silver halide emulsion layers to essentially the same spectral range and having different sensitivities. A highest-speed layer of these at least two silver halide emulsion layers contains a silver halide emulsion in which selenium-sensitized silver halide grains with an aspect ratio of 3 or more occupy 50% or more of a total projected area. A lowest-speed layer of the at least two silver halide emulsion layers contains a selenium-sensitized regular crystal silver halide emulsion. In development of this light-sensitive material, a method of continuously processing which comprises exposing said photographic light-sensitive material, subjecting said photographic light-sensitive material to a developing solution and replenishing a developer solution with not mre than 500 ml of developer replenishing solution per 1 m.sup.2.
    Type: Grant
    Filed: September 14, 1995
    Date of Patent: October 22, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshihiro Nishikawa
  • Patent number: 5565314
    Abstract: In a silver halide emulsion, tabular silver halide grains substantially consisting of silver bromoiodide, each having faces as two parallel major faces, an aspect ratio of 2 or more, and an average silver iodide content of 1 mol % or more, account for 50% or more of a total projected area of silver halide grains.
    Type: Grant
    Filed: September 26, 1994
    Date of Patent: October 15, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaharu Nakatsu, Hiroshi Takehara
  • Patent number: 5565315
    Abstract: Disclosed is a silver halide emulsion in which at least 50% of the total projected area of silver halide grains comprises tabular core/shell grains each having {100} planes as main planes and said silver halide grain substantially comprises silver chlorobromide with the halogen composition continuously being varied in the shell part.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: October 15, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Seiji Yamashita
  • Patent number: 5561033
    Abstract: A silver halide photographic light-sensitive material having at least one silver halide emulsion layer formed on a support, said emulsion layer containing tabular grains having an aspect ratio of 3 or more, which occupy at least 50% of the total projected area of all silver halide grains contained in the emulsion layer. The silver halide grains have been subjected to tellurium sensitization using at least butyl-diisopropylphosphinetelluride as a sensitizer, and also to other chemical sensitization.
    Type: Grant
    Filed: June 7, 1994
    Date of Patent: October 1, 1996
    Assignee: Fuji Photo Film, Co., Ltd.
    Inventors: Yasuo Kashi, Hirotomo Sasaki, Hiroyuki Mifune
  • Patent number: 5556741
    Abstract: There is disclosed a silver halide photosensitive material having at least one silver halide emulsion layer coated on a support, wherein silver halide grains in the emulsion layer are subjected to reduction sensitization and contain a radical scavenger, prior to the completion of a chemical sensitization. There is also disclosed a silver halide emulsion and a method of manufacturing the same. The said silver halide photosensitive material has a enhanced sensitivity, without causing high fog.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 17, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoichi Suga, Yoshio Ishii, Masakazu Morigaki
  • Patent number: 5556738
    Abstract: A silver halide photographic element with enhanced sensitivity and improved pressure resistance is disclosed, comprising a support having, on at least one side thereof, hydrophilic colloidal layers including a light-sensitive silver halide emulsion layer and a nonlight-sensitive hydrophilic colloidal layer, wherein the nonlight-sensitive layer contains organic material-aggregation particles; and gelatin contained in the total hydrophilic colloidal layers provided on one side of the support amounts to a range of 1.3 to 2.5 g per m.sup.2.
    Type: Grant
    Filed: July 13, 1995
    Date of Patent: September 17, 1996
    Assignee: Konica Corporation
    Inventors: Yasuhiko Takamuki, Ken Nagami
  • Patent number: 5550012
    Abstract: A silver halide emulsion contains silver halide grains in a dispersion medium. Tabular silver halide grains having a thickness of less than 0.5 .mu.m, a diameter of 0.3 .mu.m or more, an aspect ratio of 2 or more, and 10 or more dislocations per grain account for 50% or more of a projected area of all the silver halide grains. The grains are formed in the presence of at least one compound which can oxidize silver atoms.
    Type: Grant
    Filed: August 22, 1994
    Date of Patent: August 27, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoichi Suga
  • Patent number: 5547829
    Abstract: A silver halide photographic material comprises a silver halide emulsion layer provided on a support. The silver halide emulsion layer contains a selenium or tellurium compound represented by the formula (I): ##STR1## in which Ch is Se or Te; R.sup.1 is hydrogen, an aliphatic group, an aromatic group, a heterocyclic group, --OR.sup.11 or --NR.sup.12 R.sup.13 ; each of R.sup.11, R.sup.12 and R.sup.13 is hydrogen, an aliphatic group, an aromatic group or a heterocyclic group; and R.sup.2 is an aliphatic group, an aromatic group or a heterocyclic group.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: August 20, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Morio Yagihara, Hirotomo Sasaki, Hiroyuki Mifune, Shinji Kato
  • Patent number: 5547830
    Abstract: A silver halide photographic material comprising a support and at least one light-sensitive emulsion layer provided thereon, wherein the emulsion layer comprises a silver halide emulsion containing silver halide grains formed of silver chlorobromide, silver chloroiodide or silver chloroiodobromide each containing at least 90 mol % of silver chloride, or silver chloride, wherein 10.sup.-7 to 10.sup.-3 mol/mol of silver halide of an iron compound and 10.sup.-7 to 10.sup.-4 mol/mol of silver halide of a sulfur group compound are added to the silver halide grains until physical ripening of the grains is completed. The photographic material is particularly suitable in an image forming method involving exposing the photographic material to laser beams for a short period of time.
    Type: Grant
    Filed: January 31, 1995
    Date of Patent: August 20, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masahiro Asami
  • Patent number: 5541050
    Abstract: A silver halide color photographic light-sensitive material having at least one light-sensitive silver halide emulsion layer formed on a support containing light-sensitive silver halide grains which have been chemically sensitized by at least one of a selenium sensitizer, a gold sensitizer and a sulfur sensitizer and at least one of the layers of the material contains a compound represented by the following formula (I) and/or a compound represented by the following formula (II) in which A is a coupler residue or a redox group, L.sub.1 and L.sub.3 are divalent timing groups, L.sub.2 is a timing group with a valency of 3 or more, PUG is a photographically useful group, j and n are integers, each of 0 to 2, m is 1 or 2, s is 2 or a greater integer obtained by subtracting 1 from the valence of L.sub.2, L.sub.4 is --OCO-- group, and L.sub.5 is a group which releases PUG by electron transfer along a conjugated system.Formula (I)A'--(L.sub.1).sub.j --(L.sub.2).sub.m --[(L.sub.3).sub.n --PUG].sub.8Formula (II)A--L.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: July 30, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Mikio Ihama
  • Patent number: 5541047
    Abstract: A silver halide photographic light-sensitive material is disclosed, comprising tabular grains having an average aspect ratio of diameter to thickness of 2 or more, having an average overall iodide content of 2 mol % or less, and having a surface phase containing 3 to 20 mol % iodide on the average.
    Type: Grant
    Filed: December 12, 1994
    Date of Patent: July 30, 1996
    Assignee: Konica Corporation
    Inventors: Hiroshi Kashiwagi, Hideki Takiguchi
  • Patent number: 5541054
    Abstract: The present invention provides heat-developable, photothermographic elements comprising a support bearing at least one photosensitive, image-forming layer comprising:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible silver source;(c) a reducing agent for silver ions;(d) a binder; and(e) a spectrally sensitizing amount of a compound having the central nucleus: ##STR1## wherein: Z is S, O, Se or N--R.sup.3 ;R.sup.1 and R.sup.2 represent an alkyl group of from 1 to 20 carbon atoms other than carboxy-substituted alkyl, preferably an alkyl group of from 1 to 8 carbon atoms, and most preferably an ethyl group; andR.sup.3 is H or alkyl group;X and Y are thioalkyl groups of from 1 to 20 carbon atoms;n=0 to 4;m=0 to 4; the sum of n plus m equals at least 1;D.sup.1 to D.sup.7 each independently represents a methine group and adjacent methine groups selected from D.sup.2, D.sup.3, D.sup.4, D.sup.5 and D.sup.6 may form cyclic groups;p=0 or 1; andA.sup.- is an anion.
    Type: Grant
    Filed: April 20, 1995
    Date of Patent: July 30, 1996
    Assignee: Minnesota Mining & Manufacturing Company
    Inventors: James R. Miller, Brian C. Willett, Doreen C. Lynch, Becky J. Kummeth
  • Patent number: 5536632
    Abstract: A chemically and spectrally sensitized ultrathin tabular grain emulsion is disclosed including tabular grains (a) having {111} major faces, (b) containing greater than 70 mole percent bromide, based on silver, (c) accounting for greater than 90 percent of total grain projected area, (d) exhibiting an average equivalent circular diameter of at least 0.7 .mu.m, and (e) exhibiting an average thickness of less than 0.07 .mu.m.Improved sensitivity is observed when the surface chemical sensitization sites include silver halide protrusions of a face centered cubic crystal lattice structure forming epitaxial junctions with the tabular grains and having a higher overall solubility than at least that portion of the tabular grains forming epitaxial junctions with the protrusions and a sensitivity enhancing combination of dopants are contained in the silver halide grains including a first sensitivity enhancing dopant capable of providing shallow electron trapping sites and a second sensitivity enhancing selenium dopant.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: July 16, 1996
    Assignee: Eastman Kodak Company
    Inventors: Xin Wen, Richard L. Daubendiek, Donald L. Black, Joseph C. Deaton, Timothy R. Gersey, Joseph G. Lighthouse, Myra T. Olm, Robert D. Wilson
  • Patent number: 5534402
    Abstract: A direct-positive silver halide photographic material is disclosed, which comprises a support having thereon at least one prefogged light-sensitive silver halide emulsion layer, wherein said silver halide emulsion is an emulsion which has been previously fogged with a gold compound and a tellurium compound.
    Type: Grant
    Filed: December 13, 1994
    Date of Patent: July 9, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Kuno, Hiroyuki Mifune
  • Patent number: 5532120
    Abstract: A silver halide photographic material comprises a silver halide emulsion layer provided on a support. The silver halide emulsion layer contains a selenium compound represented by the formula (I), (IIa) or (IIb): ##STR1## in which each of R.sup.11 and R.sup.12 is hydrogen, an aliphatic group, an aromatic group, a heterocyclic group, --OR.sup.13 or --NR.sup.14 R.sup.15 ; each of R.sup.21 and R.sup.31 is an aliphatic group, an aromatic group, a heterocyclic group, --OR.sup.23 or --NR.sup.24 R.sup.25 ; each of R.sup.22 and R.sup.32 is an aliphatic group, an aromatic group or a heterocyclic group; each of R.sup.13, R.sup.14, R.sup.15, R.sup.23, R.sup.24 and R.sup.25 is hydrogen, an aliphatic group, an aromatic group or a heterocyclic group; and Ch is S, Se or Te.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: July 2, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Hirotomo Sasaki, Hiroyuki Mifune, Shinji Kato
  • Patent number: 5532119
    Abstract: Direct-positive photographic elements are comprised of a support and a silver halide emulsion layer containing core-shell silver halide grains comprising a chemically sensitized core and a chemically sensitized shell, wherein at least one of the core and the shell comprises a band of dopant and wherein the dopant is hexacyano ruthenium (II). Preferably, the shell of the core-shell grains is chemically sensitized with both a gold-containing chemical sensitizing agent and a sulfur-containing chemical sensitizing agent and the weight ratio of the gold-containing chemical sensitizing agent to the sulfur-containing chemical sensitizing agent is at least about two to one.
    Type: Grant
    Filed: March 25, 1993
    Date of Patent: July 2, 1996
    Assignee: Eastman Kodak Company
    Inventors: Robert A. Arcus, Alfred P. Marchetti
  • Patent number: 5525460
    Abstract: A silver halide photographic emulsion comprising silver halide grains which are formed while iodide ions are rapidly being generated from an iodide ion-releasing agent represented by Formula (I) below, and which are chemically sensitized with a selenium sensitizer. Formula (I)R--Iwhere R represents a monovalent organic residue which releases the iodine atom in the form of iodide ions upon reacting with a base and/or a nucleophilic reagent.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: June 11, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoichi Maruyama, Morio Yagihara, Hisashi Okamura, Hiroshi Kawamoto, Makoto Kikuchi
  • Patent number: 5518873
    Abstract: A silver halide light-sensitive emulsion and a silver halide light-sensitive material containing the same are disclosed, in which silver halide emulsion grains composed of an internal nucleus of silver bromide or silver iodobromide having a silver iodide content of not more than 1 mol % having provided thereon, in the order described, a first coating layer of silver iodobromide having a silver iodide content of from 2 to 20 mol % and a second coating layer of silver iodobromide or silver bromide a silver iodide content of which is lower than that of said first coat and is not more than 3 mol %, and are further composed of iodide phrases which are formed by halogen conversion with an iodide ion, by addition of silver iodide fine grains or by addition of a silver ion and an iodide ion at any stage during formation of 3 to 97% of the total amount of silver and after completion of the formation of the second coating layer.
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: May 21, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ryutaro Konishi, Hiroshi Tamaoki, Masayuki Kuramitu, Hideo Ikeda, Katsuro Nagaoka
  • Patent number: 5514534
    Abstract: Disclosed is a silver halide photographic light-sensitive material which comprises a support and at least one silver halide emulsion layer formed on the support. The emulsion layer contains at least one silver halide emulsion which is a tellurium-sensitized monodispersed emulsion.
    Type: Grant
    Filed: October 14, 1993
    Date of Patent: May 7, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasushi Nozawa, Hiroyuki Mifune, Hirotomo Sasaki
  • Patent number: 5514533
    Abstract: A silver halide photographic photosensitive material comprises a silver halide photographic emulsion layer and a compound represented by general formula (I): ##STR1## wherein V.sub.1 and V.sub.2 each represents a hydrogen atom, an alkyl group or an alkoxy group; at least one of V.sub.1 and V.sub.2 is an alkyl group or an alkoxy group; Z.sub.1 represents a group of atoms which is required to form a five- or six-membered nitrogen-containing heterocyclic ring; Z.sub.2 represents a group of atoms which is required to form a five- or six-membered nitrogen-containing heterocyclic ring; Z.sub.3 represents an oxygen atom, a sulfur atom or a selenium atom; R.sub.1 and R.sub.3 each represents an alkyl group; R.sub.2 represents an alkyl group, an aryl group or a heterocyclic group; L.sub.1, L.sub.2 and L.sub.3 each represents a methine group; M.sub.1 represents a charge neutralizing counter-ion; and m.sub.1 is a number having a value zero or above which is required to neutralize the charge within the molecule.
    Type: Grant
    Filed: October 4, 1994
    Date of Patent: May 7, 1996
    Assignee: Fuji Photo Film Co., LTD.
    Inventors: Takanori Hioki, Tetsuo Yoshida
  • Patent number: 5514535
    Abstract: Hydrophilic colloids, such as gelatin, which are employed in the manufacture of photographic elements are commonly treated with a hardening composition, among the most useful of which are hardening compositions containing vinyl sulfone hardening agents such as bis(vinylsulfonyl)methane. In accordance with this invention, a sulfate, such as sodium sulfate, is utilized as both an effective conductivity marker and an effective inhibitor of homopolymerization in such hardening compositions.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: May 7, 1996
    Assignee: Eastman Kodak Company
    Inventors: Lewis R. Hamilton, Peter A. Marr, Philip R. Martell, Kristine F. Ohman
  • Patent number: 5508156
    Abstract: There is disclosed a silver halide photographic light-sensitive material. The photographic material comprises a support having thereon at least a silver halide emulsion layer containing silver halide grains, which grains have a silver chloride content of 95 mol % or more and are subjected to selenium, tellurium or gold sensitization, wherein the photographic material further contains a specific dye, and wherein the photographic material preferably has the pH value of the coated film of no more than 6.5.
    Type: Grant
    Filed: November 29, 1994
    Date of Patent: April 16, 1996
    Assignee: Fuji Photo Film Co.
    Inventor: Hiroshi Kawai
  • Patent number: 5500333
    Abstract: The invention is generally accomplished by providing a method of finishing an emulsion comprising providing silver halide grains, adding to said emulsion in an amount between about 0.005 mmol/per mole of silver and 0.10 mmol/per mole of silver of the compound ##STR1## X=O, S, Se; R.sub.1 =alkyl or substituted alkyl or aryl or substituted aryl;Y.sub.1 and Y.sub.2 individually represent hydrogen, alkyl groups or an aromatic nucleus or together represent the atoms necessary to complete a cyclic structure containing carbon, oxygen, selenium, or nitrogen atoms necessary to complete a fused aromatic nucleus or an alicyclic structure. The invention also provides a photographic element comprising the silver halide emulsion. In a preferred embodiment, the R.sub.1 substituent is methyl or phenyl.
    Type: Grant
    Filed: December 16, 1993
    Date of Patent: March 19, 1996
    Assignee: Eastman Kodak Company
    Inventors: Jon N. Eikenberry, Roger Lok, Chung-Yuan Chen
  • Patent number: 5498511
    Abstract: A silver halide photographic material is disclosed, which comprises a support having thereon at least one silver halide emulsion layer, wherein the swelling amount of the hydrophilic colloid layers including the light-sensitive silver halide emulsion layer and a protective layer coated on at least one side of the support is not more than 10 .mu.m in thickness and at least 60% of the total projected area of the total silver halide grains in at least one silver halide emulsion layer includes tabular silver halide grains having a Cl.sup.- content of at least 20 mole %, a {100} plane as the major plane, a thickness of 0.35 .mu.m or less, and an aspect ratio (diameter/thickness) of at least 2, and further a developing process for developing the above silver halide photographic material with a developer containing ascorbic acid or the derivative thereof is disclosed.
    Type: Grant
    Filed: October 21, 1994
    Date of Patent: March 12, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Yamashita, Mitsuo Saitou, Tomoyuki Ozeki, Tatsuya Ishizaka
  • Patent number: 5494788
    Abstract: The invention relates to a method of sensitizing (111) high chloride tabular grains having {111} major faces comprising providing the high chloride tabular grains, and sensitizing using temperatures greater than 70.degree. C.
    Type: Grant
    Filed: September 29, 1994
    Date of Patent: February 27, 1996
    Assignee: Eastman Kodak Company
    Inventors: Yun C. Chang, Jerzy A. Budz
  • Patent number: 5489504
    Abstract: A silver halide photographic emulsion which is improved in photographic speed, fog and graininess is provided, comprising a dispersion medium and light-sensitive silver halide grains, wherein said silver halide grains are formed, in the presence of an oxidizing agent at a time during the course of forming said silver halide grains, by supplying an emulsion comprising silver halide fine grains formed in the presence of dispersion medium.
    Type: Grant
    Filed: June 14, 1993
    Date of Patent: February 6, 1996
    Assignee: Konica Corporation
    Inventor: Hiroshi Takada
  • Patent number: 5484690
    Abstract: A silver halide photographic material is disclosed, comprising a support having thereon one or more hydrophilic colloid layers, at least one of the hydrophilic colloid layers being a silver halide emulsion layer comprising silver halide grains with a silver chloride content of at least 90 mol %, wherein at least one hydrophilic colloid layer contains at least one compound selected from the compounds represented by formulae (I), (II) and (III); and at least one compound selected from the compounds represented by formulae (A), (B) and (C): ##STR1## wherein the substituents are as defined in the claims. The silver halide photographic material can be handled in an environment which can essentially be referred to as bright room.
    Type: Grant
    Filed: June 13, 1994
    Date of Patent: January 16, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takahiro Goto
  • Patent number: 5482823
    Abstract: A silver halide photographic emulsion is provided, wherein the silver halide emulsion contains silver halide grains having an average iodide content of less than 3 mol %, the silver halide grains comprising monodispersed core/shell type silver halide grains containing internally high iodide, the core/shell grains having two parallel twin planes and a substantially roundish hexahedral or tetradecahedral form.
    Type: Grant
    Filed: September 23, 1994
    Date of Patent: January 9, 1996
    Assignee: Konica Corporation
    Inventors: Yoshihiro Haga, Tetsuya Suzuki, Yasuo Taima
  • Patent number: 5482827
    Abstract: Light-sensitive silver halide photographic elements comprising a support bearing at least one gelatin-containing silver halide emulsion layer, wherein the silver halide emulsion is chemically sensitized with sulfur and gold in the presence of a sulfinic acid compound and the gelatin is hardened with a carbamoylpyridinium salt compound.
    Type: Grant
    Filed: January 3, 1995
    Date of Patent: January 9, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mauro Besio, Giuseppe Rocca
  • Patent number: 5478711
    Abstract: A photographic element comprising a support having located thereon at least one silver halide emulsion layer, the emulsion layer containing a development accelerator and a release compound that provides a non-imagewise distribution of a development inhibitor moiety. The release compound is characterized in that it comprises a blocking group from which the development inhibitor moiety is released.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: December 26, 1995
    Assignee: Eastman Kodak Company
    Inventors: Keath T. Chen, John V. Nelson, David A. Dickinson, Thomas R. Welter
  • Patent number: 5468602
    Abstract: A method for producing silver halide photographic light-sensitive material is disclosed. The method comprises the steps of (1) forming silver halide crystal nuclei, (2) growing the nuclei to form a silver halide emulsion, (3) chemically sensitizing the silver halide emulsion with a selenium compound, and (4) coating and drying the silver halide emulsion on a support, and a compound represented by formula I is added to the silver halide emulsion during the time between the moment of completion of the nuclei forming step and the moment of completion of the chemically sensitizing step. ##STR1## In the formula R.sub.1 is a hydrogen atom, a straight or branched alkyl group, a cycloalkyl group, an alkenyl group, an aralkyl group, an alkoxyl group, an aryl group, a heterocyclic group, a carbamoyl group, a thiocarbamoyl group or a sulfamoyl group; R.sub.2 and R.sub.
    Type: Grant
    Filed: November 2, 1994
    Date of Patent: November 21, 1995
    Assignee: Konica Corporation
    Inventor: Shigeaki Takahashi
  • Patent number: 5466571
    Abstract: A silver halide photographic light-sensitive material is disclosed which comprises a support and provided thereon, a light-sensitive silver halide emulsion layer containing silver halide grains, the silver halide grains are chemically sensitized by a selenium compound and spectrally sensitized by a dye represented by formula (S-1): ##STR1##
    Type: Grant
    Filed: April 12, 1995
    Date of Patent: November 14, 1995
    Assignee: Konica Corporation
    Inventors: Tsuyoshi Mitsuhashi, Nobuaki Kagawa
  • Patent number: 5464737
    Abstract: Post-processing stabilizers for photothermographic, silver imaging media are disclosed. The stabilizers are represented by the following general formulae: ##STR1## wherein: R.sup.1, R.sup.2, and R.sup.3 are independently H, halogen, an alkyl group, an alkoxy group, a thioalkyl group, a cycloalkyl group, a perhalogenated alkyl group, or taken together form a cycloaliphatic group.Compounds of formula (I) may be used as stabilizer precursors in photothermographic silver imaging media to provide post-processing stability without significantly adversely affecting desired properties of the photothermographic material.
    Type: Grant
    Filed: November 30, 1994
    Date of Patent: November 7, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kumars Sakizadeh, John T. Blair, David T. Ask
  • Patent number: 5462843
    Abstract: A silver halide material for colour photography, comprising a support, at least one blue-sensitive yellow-coupling silver halide emulsion layer, at least one green-sensitive, magenta-coupling silver halide emulsion layer, and at least one red-sensitive, cyan-coupling silver halide emulsion layer applied to the support and conventional intermediate and protective layers, the emulsion in at least one of the silver halide layers comprising not less than 80 mol-% AgCl and not more than 0.5 mol-% AgI, and the last-mentioned silver halide emulsion is doped with at least one compound of a metal in the groups (a) and (b), where (a) comprises rhodium, iridium, osmium, ruthenium, rhenium and cadmium and (b) comprises gold and platinum. The material has very good development kinetics.
    Type: Grant
    Filed: September 20, 1994
    Date of Patent: October 31, 1995
    Assignee: Agfa-Gevaert AG
    Inventors: Sieghart Klotzer, Bruno Mucke
  • Patent number: 5460932
    Abstract: A photographic element comprising a support having located thereon a first layer which does not contain colloidal silver and a second layer, the first layer containing a release compound that comprises a development inhibitor moiety and a blocking group from which the development inhibitor moiety is non-imagewise released, and the second layer containing a development accelerator.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: October 24, 1995
    Assignee: Eastman Kodak Company
    Inventors: Keath T. Chen, John V. Nelson, David A. Dickinson, Thomas R. Welter
  • Patent number: 5459027
    Abstract: Disclosed herein is a silver halide photographic light-sensitive material comprising at least one layer made of a silver halide emulsion comprising a dispersion medium and silver halide grains dispersed in the dispersion medium. Each of the silver halide grains contains a metal or metal ions other than silver. The emulsion has been chemically sensitized in the presence of a tellurium compound which has a pseudo-first order reaction rate constant k of 1.times.10.sup.-8 to 1.times.10.sup.-0 min.sup.-1. The metal is at least one polyvalent metal selected from the group consisting of Ir, Rh, Pd, Ru, Pt, Os, Fe, Ni and Co. The metal ions are ammonium salt, acetate, nitrate, sulfate, phosphate, hydroxide, or complex salt of the metal. Telluroketones or phosphinetellurides is used as the tellurium compound. It is desirable that the silver halide emulsion is a monodispersed emulsion having a variation coefficient of 22% or less.
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: October 17, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shunji Takada, Hiroyuki Mifune, Tetsuro Kojima
  • Patent number: 5459028
    Abstract: Heat-developable photographic recording materials comprising (a) at least one binder layer coated on a support, the binder layer containing at least one light-sensitive silver halide and a light-insensitive silver salt of a fatty acid; and in the binder layer or in another layer in reactive relationship to the binder layer (b) at least one reducing agent and (c) a stabilizer selected from the group of hexamethylene tetramine and salts thereof, triazaadamantane and salts thereof, and compounds that can be derived from hexamethylene tetramine by exchanging one or more --CH.sub.2 -- groups with --S--, --SO--, or --SO.sub.2 -- provide excellent stability during storage and can be manufactured easily and inexpensively and which presents minimal environmental or health risks.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: October 17, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Walter Ball
  • Patent number: 5449599
    Abstract: A silver halide light-sensitive photographic material for applications in the field of mammography is disclosed which has an improved diagnostic value by an enhanced sharpness. The silver halide crystals to be used in the said material show a fog level, a toe contrast and an overall contrast that is, like the image quality, substantially uneffected by the processing conditions. The coating amount of silver halide crystals in the emulsion layer can be reduced to such an amount that an archivability of from 10 to 20 years can be assured in normal storage conditions. The X-ray material is suitable for rapid processing, without loss in sensitivity, within processing cycles of 45 or 38 seconds, wherein hardener-free processing solutions can be used.
    Type: Grant
    Filed: January 21, 1994
    Date of Patent: September 12, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Luc J. Heremans
  • Patent number: 5447826
    Abstract: A photographic light-sensitive silver halide material is disclosed comprising a support and one or more hydrophylic colloid layers including at least one light-sensitive silver halide emulsion layer characterized in that in said emulsion layer is a gold and sulphur sensitized silver bromide or silver bromoiodide emulsion having cubic crystal habit and in that said emulsion and/or a hydrophylic colloid layer in water-permeable relationship therewith comprises a 3-pyrazolidinone compound.
    Type: Grant
    Filed: April 18, 1994
    Date of Patent: September 5, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Luc J. Heremans, Rudi A. Goedeweeck
  • Patent number: H1549
    Abstract: A silver halide photographic light-sensitive material comprising a support having thereon a silver halide grain emulsion layer is provided, wherein the silver halide emulsion is chemical-sensitized with a selenium compound; and, at a time during the course of chemical sensitization, silver iodide fine grains is further added to the emulsion. The silver halide emulsion comprises tabular grains having an aspect ration of 3 or more.
    Type: Grant
    Filed: July 25, 1994
    Date of Patent: June 4, 1996
    Inventor: Yorihiro Yamaya