Silver Compound Other Than Halide, Per Se, Or Composition For Thermographic Process Patents (Class 430/617)
  • Patent number: 6830879
    Abstract: Disclosed is a photothermographic material having a support, at least one photosensitive layer containing a silver halide and a reducing agent and a non-photosensitive layer containing aggregates of a dye, wherein a transmission absorption spectrum of the aggregates has a maximum absorption wavelength within the range of 600-750 nm. The photothermographic material is easy to handle and provide an image having sufficient definition without residual color after development. The photothermographic material is suitable for light exposure with a red laser.
    Type: Grant
    Filed: August 2, 2002
    Date of Patent: December 14, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ryo Suzuki, Keiichi Suzuki, Yoshiharu Yabuki
  • Publication number: 20040234910
    Abstract: The present invention provides a photothermographic material having an image forming layer including at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, on one surface of a support, and having at least one back layer and a back surface protective layer, on the other surface of the support, wherein a binder of the back surface protective layer contains a water-soluble polymer and a latex polymer having a glass transition temperature of −30° C. to 40° C.; and an image forming method using the same.
    Type: Application
    Filed: May 20, 2004
    Publication date: November 25, 2004
    Inventors: Hajime Nakagawa, Takayasu Yasuda
  • Publication number: 20040234909
    Abstract: The present invention provides a photothermographic material which includes at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, on a support, and contains (a) a first dye having an absorption maximum in a range of 370 nm to 420 nm and (b) a second dye satisfying the following conditions (1) and (2) in the CIELAB color space:
    Type: Application
    Filed: May 4, 2004
    Publication date: November 25, 2004
    Inventors: Rikio Inoue, Ryo Suzuki
  • Patent number: 6821720
    Abstract: A method of producing a thermal-developable photosensitive material is provided, which prevents mixing of materials between layers to ensure that the coating surface is in a good condition. In this method, liquids for forming a photosensitive layer, an intermediate layer and a protective layer are simultaneously applied in a multilayer form on a substrate to produce a thermal-developable photosensitive material. A pH of the intermediate layer coating liquid is adjusted within a range from 5 to 10 and a viscosity of the intermediate layer coating liquid is adjusted within a range from 20 to 150 mPa·s. Moreover, a pH buffering salt is added to the intermediate layer coating liquid.
    Type: Grant
    Filed: October 2, 2002
    Date of Patent: November 23, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Junpei Iwado
  • Publication number: 20040202972
    Abstract: The invention provides a photothermographic material comprising, on a surface of a substrate, a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, a halogen compound represented by the following formula (A), and a development accelerator.
    Type: Application
    Filed: April 7, 2004
    Publication date: October 14, 2004
    Inventor: Kouta Fukui
  • Patent number: 6794123
    Abstract: A preparation process for a first aqueous dispersion comprising an ex-situ photosensitive silver halide and a substantially light-insensitive silver salt of an organic carboxylic acid, comprising the steps of: separately preparing a second aqueous dispersion comprising the ex-situ photosensitive silver halide and a third aqueous dispersion comprising the substantially light-insensitive silver salt of an organic carboxylic acid; and mixing the second aqueous dispersion with the third aqueous dispersion to produce a mixture thereof, characterized in that the first aqueous dispersion thereby produced is substantially free of a water-soluble metal or ammonium salt of an aliphatic carboxylic acid with greater than 12 carbon atoms and the process further comprises a step selected from the group consisting of: increasing the pH of the second aqueous dispersion to a value of at least 8.0 prior to mixing with the third aqueous dispersion; increasing the pH of the third aqueous dispersion to a value of at least 8.
    Type: Grant
    Filed: August 22, 2001
    Date of Patent: September 21, 2004
    Assignee: AGFA-Gevaert
    Inventors: Herman Uytterhoeven, Luc Vissers
  • Patent number: 6783925
    Abstract: A thermally processed image forming material containing elsewhere on a support a reducing agent, a binder and non-photosensitive fatty silver salt grains was disclosed, in which (1) the non-photosensitive fatty acid silver salt grains are prepared by mixing and reacting a silver ion-containing solution, the solvent of which being water or a mixture of water and an organic solvent, with a solution of a fatty acid alkali metal salt, the solvent of which being water, an organic solvent, or a mixture of water and an organic solvent, in a closed mixing means, or (2) the non-photosensitive fatty acid silver salt grains are prepared by micro-dispersing the reaction mixture at an operating pressure of 1,800 kg/cm2 or above using a ultrahigh pressure dispersion apparatus. Such thermally processed image forming material is excellent in the coated surface quality, and can afford an image which is low in fog and high in Dmax (maximum density).
    Type: Grant
    Filed: July 14, 2000
    Date of Patent: August 31, 2004
    Assignee: Fuji Photo Film Co., LTD
    Inventor: Shoji Yasuda
  • Publication number: 20040157177
    Abstract: The present disclosure relates to aqueous dispersions of silver (carboxylate-azine toner) particles wherein the azine content of the particles is from about 0.01 to 10% by weight relative to silver carboxylate. The carboxylates are typically silver salts of long chain fatty acids and the azine toners are the compounds that function as development accelerators and toning agents such as phthalazine. These silver (carboxylate-azine) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.
    Type: Application
    Filed: December 23, 2003
    Publication date: August 12, 2004
    Inventors: Mark Lelental, Peter J. Ghyzel, John W. Boettcher, James L. Wakley, David A. Dickinson, Joe E. Maskasky, Roger L. Klaus, Victor P. Scaccia, Thomas Blanton
  • Patent number: 6764813
    Abstract: A photothermographic film and a method for making same is taught. The film includes a support, a photothermographic imaging layer coated on the support, and a complement film generally confining the photothermographic imaging layer between the support and the complement film. The complement film is applied to the photothermographic imaging layer prior to exposure of the photothermographic imaging layer. The complement film retains any volatile materials present in the photothermographic imaging layer generated when thermal energy is applied thereto to develop a latent image exposed on the photothermographic imaging layer.
    Type: Grant
    Filed: May 17, 2002
    Date of Patent: July 20, 2004
    Assignee: Eastman Kodak Company
    Inventors: Aparna V. Bhave, Karissa L. Eckert, Kenneth W. Metz, Lawrence B. Wallace, Mridula Nair, Thomas M. Smith, Barry M. Brown
  • Publication number: 20040137382
    Abstract: Thermally developable compositions such thermographic and photothermographic emulsions include certain triazine-thione compounds. These emulsions can be used in thermally developable materials such as thermographic and photothermographic materials to provide increased image density and shortened development time, and to allow development at lower temperatures. Such materials can have imaging layers on one or both sides of the support.
    Type: Application
    Filed: December 11, 2003
    Publication date: July 15, 2004
    Inventors: Doreen C. Lynch, Stacy M. Ulrich, Paul G. Skoug
  • Publication number: 20040137388
    Abstract: A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, said thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one 2-mercapto-benzothiazole compound represented by formula (I): 1
    Type: Application
    Filed: November 10, 2003
    Publication date: July 15, 2004
    Applicant: AGFA-GEVAERT
    Inventors: Ingrid Geuens, Johan Loccufier
  • Publication number: 20040137380
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: 1
    Type: Application
    Filed: January 9, 2003
    Publication date: July 15, 2004
    Applicant: Eastman Kodak Company
    Inventors: James H. Reynolds, Douglas R. Robello, David H. Levy
  • Patent number: 6759187
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein: the substituents are as defined in the application.
    Type: Grant
    Filed: July 11, 2000
    Date of Patent: July 6, 2004
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, Mark E. Irving, David H. Levy, Jared B. Mooberry, James J. Seifert, James H. Reynolds, Lyn M. Irving
  • Patent number: 6756192
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein: the substituents are as defined in the application.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: June 29, 2004
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, Mark E. Irving, David H. Levy, Jared B. Mooberry, James J. Seifert, James H. Reynolds, Lyn M. Irving
  • Patent number: 6749999
    Abstract: Disclosed is a photothermographic material comprising a support, a photosensitive layer containing a silver halide having a silver iodide content of 10 mol % or more and a reducing agent and a non-photosensitive layer provided on the support, wherein at least one of the photosensitive layer and the non-photosensitive layer contains a dye showing an absorption maximum in a wavelength range of 350 nm to 430 nm. The photothermographic material exhibits high image quality, superior color tone and superior image stability after development.
    Type: Grant
    Filed: November 13, 2002
    Date of Patent: June 15, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshiharu Yabuki, Katsutoshi Yamane, Ryo Suzuki, Rikio Inoue
  • Patent number: 6746831
    Abstract: Thermographic and photothermographic materials comprise a barrier layer to provide physical protection and to prevent migration of diffusible imaging components and by-products resulting from high temperature imaging and/or development The barrier layer comprises 15 to 100 weight % of a film-forming cellulose ether polymer. This barrier layer is capable of retarding diffusion of mobile chemicals such as fatty carboxylic acids, developers, and toners. This barrier layer can also include other film-forming polymers to provide a clear and scratch-resistant surface.
    Type: Grant
    Filed: January 27, 2003
    Date of Patent: June 8, 2004
    Assignee: Eastman Kodak Company
    Inventor: Bryan V. Hunt
  • Publication number: 20040101794
    Abstract: A photothermographic imaging material having a support; a photosensitive layer containing photosensitive silver halide particles on one face of the support; and a non-photosensitive layer provided on a side of the support where the photosensitive layer is provided. At least one of the photosensitive layer and the non-photosensitive layer contains an organic silver salt, a reducing agent, a compound represented by the Formula (1) and a compound represented by the Formula (2a).
    Type: Application
    Filed: October 15, 2003
    Publication date: May 27, 2004
    Applicant: Konica Minolta Holdings, Inc.
    Inventors: Yasushi Usagawa, Narito Goto, Takeshi Habu
  • Patent number: 6737230
    Abstract: The present invention relates to a thermal developing photographic element comprising a radiant energy absorbing material incorporated into said photothermal film.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: May 18, 2004
    Assignee: Eastman Kodak Company
    Inventors: Timothy W. Stoebe, Mark E. Irving, David H. Levy, Kevin W. Williams
  • Patent number: 6737227
    Abstract: Thermally developable compositions such thermographic and photothermographic emulsions include certain heterocyclic disulfide compounds and ascorbic acid or reductone reducing agents. These compositions can be used in thermally developable materials such as thermographic and photothermographic materials to provide increased image density and shortened development time, and to allow development at lower temperatures. Such materials can have imaging layers on one or both sides of the support.
    Type: Grant
    Filed: March 7, 2003
    Date of Patent: May 18, 2004
    Assignee: Eastman Kodak Company
    Inventors: Doreen C. Lynch, Stacy M. Ulrich
  • Publication number: 20040076913
    Abstract: A high silver iodide photographic emulsion is provides, which has a high sensitivity and a narrow size distribution, and is a photosensitive silver halide photographic emulsion having a silver iodide content of 90 mol % or more, wherein the average grain size (R) and the average crystallite size (r) of silver halide emulsion grains in the emulsion satisfy the relationship of 1≦R/r<2.
    Type: Application
    Filed: October 10, 2003
    Publication date: April 22, 2004
    Inventors: Satoshi Aiba, Tadaaki Tani, Toshio Tsukada
  • Publication number: 20040067454
    Abstract: Nonpolymeric fluorochemicals defined as by the following Structure I are useful in thermally developable materials.
    Type: Application
    Filed: October 4, 2002
    Publication date: April 8, 2004
    Applicant: Eastman Kodak Company
    Inventors: Kumars Sakizadeh, Gary E. LaBelle, Aparna V. Bhave
  • Patent number: 6686133
    Abstract: A photothermographic recording material comprising a support and a photo-addressable thermally developable element, the photo-addressable thermally developable element containing a mixture of a substantially light-insensitive silver salt of a monocarboxylic acid and a substantially light-insensitive compound exclusive of silver succinate represented by formula (I): AgOOC—R1—COOAg wherein R1 is a straight chain saturated or unsaturated hydrocarbon group with two or three carbon atoms, optionally substituted with one or more of ═O, ═S, ═CR2R3, an alkyl group, an aryl group, an amino group, a substituted amino group, a cycloalkyl group, a hydroxy group, a thiol group, an alkyl sulphone group, an aryl sulphone group, an alkoxy group, an acyloxy group, a thioalkyl group, a thioaryl, a carbamic ester group, a halogen atom or a —(C═O)R4 group; wherein if R1 is substituted with two substituents selected from the group consisting of alkyl, thioalkyl, substituted amino and alkox
    Type: Grant
    Filed: March 19, 2002
    Date of Patent: February 3, 2004
    Assignee: Agfa-Gevaert
    Inventor: Horst Friedel
  • Publication number: 20040009438
    Abstract: High-speed black-and-white photothermographic materials can be imaged in any suitable fashion using ultraviolet, visible, infrared, or X-radiation. They can have one or more thermally developable imaging layers on either or both sides of the support and can be imaged with or without a phosphor intensifying screen in an imaging assembly. The photothermographic emulsions and materials have a net Dmin less than 0.25, and require less than 1 erg/cm2 to achieve a density of 1.00 above net Dmin.
    Type: Application
    Filed: April 16, 2003
    Publication date: January 15, 2004
    Applicant: Eastman Kodak Company
    Inventors: Chaofeng Zou, Doreen C. Lynch
  • Publication number: 20030224307
    Abstract: A photothermographic material including a substrate carrying on one surface thereof an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for a silver ion, and a binder, wherein the photosensitive silver halide has a silver iodide content of 40 to 100 mol %, and an average particle size of 5 to 80 nm, and the photothermographic material contains a compound of the following general formula (1);
    Type: Application
    Filed: April 14, 2003
    Publication date: December 4, 2003
    Inventors: Seiichi Yamamoto, Eiichi Okutsu, Tomoyuki Ohzeki
  • Publication number: 20030219684
    Abstract: Disclosed is a photothermographic material comprising a support, a photosensitive layer containing a silver halide having a silver iodide content of 10 mol % or more and a reducing agent and a non-photosensitive layer provided on the support, wherein at least one of the photosensitive layer and the non-photosensitive layer contains a dye showing an absorption maximum in a wavelength range of 350 nm to 430 nm. The photothermographic material exhibits high image quality, superior color tone and superior image stability after development.
    Type: Application
    Filed: November 13, 2002
    Publication date: November 27, 2003
    Inventors: Yoshiharu Yabuki, Katsutoshi Yamane, Ryo Suzuki, Rikio Inoue
  • Patent number: 6649330
    Abstract: In accordance with one embodiment of the invention, a photographic element is described comprising a support bearing one or more hydrophilic colloid layers including at least one photographic silver halide emulsion layer, wherein sequestered silver ions are incorporated into at least one hydrophilic colloid layer in the form of a silver ion containing material which sequesters silver ions prior to photographic processing and releases silver ions upon exposure to photographic processing solutions. Method for preparing and processing such photographic element are also described. In accordance with particular embodiments of the invention, the silver ion containing material comprises a silver ion-exchanged zeolite material or an intercalation composition comprising a layered host material having silver ions inserted as guest ions between the layers of the host material.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: November 18, 2003
    Assignee: Eastman Kodak Company
    Inventors: Joseph F. Bringley, Kenneth J. Lushington, Tiecheng A. Qiao, James S. Honan
  • Publication number: 20030186176
    Abstract: A silver halide photosensitive material having a substrate, a heat-responsive-discolorable coloring layer and a photosensitive layer coated thereon and having a silver halide, dye-providing compound and a binder, the heat-responsive-discolorable coloring layer containing a heat-responsive-discolorable coloring composition, which is colored at a temperature lower than its discoloration initiation temperature (T) of 60 to 200° C.; which is substantially discolored at a temperature equal to or higher than T; and which does not recover its color once discolored, even when its temperature is lowered to a temperature lower than T again, and the heat-responsive-discolorable coloring composition containing a polymer having a glass transition temperature of 60 to 200° C.
    Type: Application
    Filed: October 25, 2002
    Publication date: October 2, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Jun Arakawa, Takahiro Ishizuka
  • Publication number: 20030170573
    Abstract: Disclosed is a photothermographic material comprising a support having disposed on a surface thereof, a non-photosensitive silver source, a photosensitive silver halide, and a reducing agent, and having disposed another surface thereof at least one non-photosensitive layer, wherein at least one of the non-photosensitive layers contains at least one type of gelatin having an isoelectric point of from 5.0 to 9.5; and a method for processing the photothermographic material.
    Type: Application
    Filed: December 23, 2002
    Publication date: September 11, 2003
    Inventor: Rikio Inoue
  • Patent number: 6599684
    Abstract: The present invention is directed to a photothermographic element comprising at least one imaging layer with a pyrrolotriazole coupler and a developing agent, or precursor thereof, the combination of which is capable of forming an image record in the infrared region of the light spectrum in response to a selected hue of visible light. This expedient leads to the formation of high quality images, especially when scanning photothermographic elements in which the silver halide, metallic silver, and/or any organic silver salts have not been removed. Also disclosed is a method for photothermographically forming a developed image comprising an infrared image record.
    Type: Grant
    Filed: August 13, 2001
    Date of Patent: July 29, 2003
    Assignee: Eastman Kodak Company
    Inventors: James H. Reynolds, Leif P. Olson, Wojciech K. Slusarek, David H. Levy
  • Publication number: 20030129550
    Abstract: Disclosed is a photothermographic material having a support, at least one photosensitive layer containing a silver halide and a reducing agent and a non-photosensitive layer containing aggregates of a dye, wherein a transmission absorption spectrum of the aggregates has a maximum absorption wavelength within the range of 600-750 nm. The photothermographic material is easy to handle and provide an image having sufficient definition without residual color after development. The photothermographic material is suitable for light exposure with a red laser.
    Type: Application
    Filed: August 2, 2002
    Publication date: July 10, 2003
    Inventors: Ryo Suzuki, Keiichi Suzuki, Yoshiharu Yabuki
  • Patent number: 6586170
    Abstract: A thermographic recording element having at least one image forming layer contains an organic silver salt, a reducing agent, and optionally, a photosensitive silver halide. The element further contains a substituted alkene derivative of specific structure and preferably a specific hydrazine derivative. The element can be processed in a fully dry basis to produce images having high Dmax and gradation and free of black pepper.
    Type: Grant
    Filed: April 28, 1998
    Date of Patent: July 1, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kohzaburoh Yamada, Toshiaki Kubo, Hiroyuki Suzuki
  • Publication number: 20030118952
    Abstract: The second silver halide photosensitive material comprises a substrate and at least one photosensitive silver halide emulsion layer formed thereon, the silver halide photosensitive material comprising at least two types of silver halide grains with different projected areas having photosensitivity in the same photosensitivity range; silver halide grains having a larger projected area having a refractive index n1 and an average thickness a, and silver halide grains having a smaller projected area having a refractive index n2 and an average thickness b; and the silver halide grains satisfying the conditions defined by the following equation (1):
    Type: Application
    Filed: May 23, 2002
    Publication date: June 26, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Kiyoteru Miyake, Masahiro Asami
  • Publication number: 20030108828
    Abstract: In the apparatus for liquid preparation, the silver halide emulsion contained in a dedicated pot is transferred as liquid by a mohno pump via a piping into a measuring tank. The silver halide emulsion transferred into the measuring tank is measured with a load cell and is melted by heating with a jacket while being stirred by a stirrer. Accordingly, even when a small amount is used as in the case of the silver halide emulsion used in the heat-developable photosensitive material, the time for heating the silver halide emulsion, within the time range from the liquid preparation of the silver halide emulsion to its utilization, can be made short to the utmost, and hence the time elapse in melt can be suppressed. Thus, the time elapse in melt, reagent loss, and mutual contamination in the liquid preparation of photographic reagents can be effectively prevented.
    Type: Application
    Filed: July 1, 2002
    Publication date: June 12, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Yasushi Sano, Yoshitsugu Moizumi, Kazuaki Miyashita
  • Patent number: 6576415
    Abstract: A process for producing an aqueous dispersion comprising: preparing a dispersion of photosensitive silver halide and a binder or a surfactant in an aqueous medium; and subsequently either (a) adding a first silver salt to the silver halide dispersion and then adding a second silver salt; or (b) adding the second silver salt to the silver halide dispersion and then adding the first silver salt, wherein the aqueous dispersion is substantially free of a water-soluble metal or ammonium salt of an aliphatic carboxylic acid with greater than 12 carbon atoms, the first silver salt is a substantially light-insensitive and substantially water-insoluble silver salt of an organic carboxylic acid, and the second silver salt has a water-solubility greater than 0.1 g in 1 L of water at 20° C.; an aqueous dispersion obtainable therewith; a photothermographic recording material prepared with the aqueous dispersion; and a process for preparing the photothermographic recording material.
    Type: Grant
    Filed: August 13, 2001
    Date of Patent: June 10, 2003
    Assignee: AGFA-Gevaert
    Inventors: Herman Uytterhoeven, Johan Loccufier, Yvan Gilliams
  • Publication number: 20030099898
    Abstract: The present invention provides a heat-developable photosensitive material having a substrate, an undercoat layer and a photosensitive layer containing silver behenate in this order, wherein an adhesive roll having an adhesive force of at least 35 hPa is brought into contact with one face or both faces of the photosensitive material before the photosensitive layer is formed, and a method of producing the same.
    Type: Application
    Filed: September 27, 2002
    Publication date: May 29, 2003
    Inventor: Yoshimitsu Ito
  • Publication number: 20030096188
    Abstract: A planographic printing plate material and a method of preparing a planographic printing plate are disclosed, the planographic printing plate material comprising a support and provided thereon, one or more structural layers containing light sensitive silver halide grains, organic silver salt grains, a reducing agent, a contrast-increasing agent and a physical developing nucleus.
    Type: Application
    Filed: March 12, 2002
    Publication date: May 22, 2003
    Inventor: Takeshi Sampei
  • Patent number: 6566042
    Abstract: A method for producing an image comprising a step for heat-developing after light exposure a photothermographic material containing elsewhere on a support a non-photosensitive organic acid silver salt, a photosensitive silver halide, a nucleation aid, a binder and at least one compound expressed by the formula (A) below, at a line speed of 140 cm/min or faster: [where R1, R2, R3, X1 and X2 independently represent a hydrogen atom, halogen atom or the like; at least either one of X1 and X2 is a group expressed as —NR4R5, where R4 and R5 independently represents a hydrogen atom, alkyl group or the like] is provided. The method for producing an image of the present invention is successful in raising Dmax (maximum density), suppressing increase in fog during a long-term storage, and suppressing dimensional instability of line width affected by the energy of exposure.
    Type: Grant
    Filed: November 22, 2000
    Date of Patent: May 20, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takahiro Goto, Minoru Sakai, Katsuyuki Watanabe
  • Patent number: 6558894
    Abstract: A photothermographic material comprising, on one surface of a support, at least one kind of photosensitive silver halide, a silver salt of an organic acid, a reducing agent for silver ions, and a binder, wherein (1) said material further comprises two or more kinds of organic polyhalogenated compounds, and (2) a melting point of a mixture which consists of the organic polyhalogenated compounds in the same content ratio as the content ratio of said compounds in the photothermographic material is in the range of from −10° C. to 50° C. relative to a heat development temperature for the photothermographic material. The photothermographic material of the present invention shows high sensitivity and superior storability before heat development, and the material can be used for medical images, photoengraving and the like.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: May 6, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kouta Fukui
  • Patent number: 6555309
    Abstract: In the case where multiple slide hopper is used for simultaneous multilayer bead coating of photosensitive material, streak defect is occasionally cause, particularly in the case of coating photothermographic material, especially when the outermost layer includes materials capable of increasing optical density such as toner it more frequently happens. It is found that streak defect is restrained when meniscus curvature of upper side bead becomes less than 7.2 mm−1. This condition can be kept by selecting a proper value of clearance between the web surface and the lip of the slide hopper, that is from 0.10 mm to 0.40 mm, and a proper value of pressure in a lower side of the bead, that is from −100 Pa to −700 Pa.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: April 29, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Akifumi Kato
  • Publication number: 20030073046
    Abstract: A method of producing a thermal-developable photosensitive material is provided, which prevents mixing of materials between layers to ensure that the coating surface is in a good condition. In this method, liquids for forming a photosensitive layer, an intermediate layer and a protective layer are simultaneously applied in a multilayer form on a substrate to produce a thermal-developable photosensitive material. A pH of the intermediate layer coating liquid is adjusted within a range from 5 to 10 and a viscosity of the intermediate layer coating liquid is adjusted within a range from 20 to 150 mPa·s. Moreover, a pH buffering salt is added to the intermediate layer coating liquid.
    Type: Application
    Filed: October 2, 2002
    Publication date: April 17, 2003
    Applicant: FUJI PHOTO FILM,CO., LTD.
    Inventor: Junpei Iwado
  • Patent number: 6548233
    Abstract: Aqueous-based thermally sensitive emulsions and imaging materials include two or more hindered phenol silver ion reducing agents in a non-crystalline reducing agent composition. Such compositions can be provided as evaporated dispersions and can be formulated in aqueous coating compositions to provide thermally developable materials such as thermographic and photothermographic materials.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: April 15, 2003
    Assignee: Eastman Kodak Company
    Inventors: John W. Boettcher, Paul L. Zengerle, Roger L. Klaus
  • Publication number: 20030054297
    Abstract: A silver halide photographic lightsensitive material comprises, on a support, at least one lightsensitive silver halide emulsion layer and at least one non-lightsensitive layer.
    Type: Application
    Filed: March 29, 2002
    Publication date: March 20, 2003
    Inventor: Junichiro Hosokawa
  • Patent number: 6534226
    Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: March 18, 2003
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owczarczyk, David T. Southby, Xiqiang Yang
  • Publication number: 20030049573
    Abstract: The problem of the present invention is to clear the packaging material and the presence/absence detecting method of the residual photothermographic image recording sheet, which are improved so that the concave section or the notched section provided on the bottom plate does not exercise a bad influence, caused by the exhalation of the organic solvent, on the recording sheet stacked on the lowermost position. Packaging material of the recording sheets, having a detecting means of the recording sheet, wherein there is provided the concave section or the notched section on a section where a part of a vacuum head comes into contact with a bottom plate located on a bottom section of the packaging material, and wherein there is arranged a filler formed with a soft material having air permeability and neither absorbs nor transmits organic solvent, in the concave section or the notched section.
    Type: Application
    Filed: September 6, 2002
    Publication date: March 13, 2003
    Applicant: KONICA CORPORATION
    Inventors: Katsunori Goi, Mamoru Umeki, Wataru Tachikawa
  • Publication number: 20030039927
    Abstract: A silver salt photothermographic dry imaging material comprising a support having thereon a photosensitive layer comprising silver aliphatic carboxylate grains and photosensitive silver halide grains, a reducing agent for silver ions, a binder and a cross-linking agent, wherein the photothermographic material has a silver coverage of 1.0 to 1.7 g/m2; the photosensitive silver halide grains have a mean grain size of 0.03 to 0.055 &mgr;m and a degree of grain size dispersity of not more than 30%; after the dry imaging material has been subjected to photothermographic processing at a temperature of 100 to 200° C. for 5 to 50 seconds, the photosensitive layer exhibits a thermal transition temperature of 46 to 200° C.
    Type: Application
    Filed: March 6, 2002
    Publication date: February 27, 2003
    Inventors: Keiko Maeda, Tetsuo Shima
  • Patent number: 6518007
    Abstract: This invention relates to a multicolor silver halide photographic element comprising a support and at least one high bromide silver halide emulsion layer comprising low fogging tabular silver halide grains, said element further comprising an antifoggant represented by the following Structure I: R1—SO2—C(R2)R3—(CO)m—(L)n—SG  I wherein R1 is an aliphatic or cyclic group, R2 and R3 are independently hydrogen or bromine as long as at least one of them is bromine, L is a divalent linking group, m and n are independently 0 or 1, and SG is a solubilizing group that has a pKa of 8 or less.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: February 11, 2003
    Assignee: Eastman Kodak Company
    Inventors: Kenneth J. Reed, George J. Burgmaier, John E. Keevert, Roger L. Klaus
  • Patent number: 6514684
    Abstract: Bisphenol-phosphorus compound complexes represented by the following general formula (1) are disclosed (R1 to R4 represent hydrogen atom or a group that can be a substituent on a benzene ring; L represents —S— group or a —CHR5— group where R5 represents hydrogen atom or an alkyl group; and R6 to R8 represent an alkyl group, an aryl group, a heterocyclic group etc.). The present invention provides reducing agents that can realize thermally processed image recording materials that can provide sufficient image density at a practical reaction temperature (specifically 100-140° C.) and within a practical reaction time (specifically 1-30 seconds), and can sufficiently suppress the coloration of white portions when the materials are stored in a dark place after the development.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: February 4, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Makoto Suzuki, Yasuhiro Yoshioka
  • Patent number: 6506546
    Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein PUG is a photographically useful group; LINK 1 and LINK 2 are linking groups; TIME is a timing group; T represents t independently selected substituted or unsubstituted alkyl or aryl groups, t is 0, 1, or 2 and if t is 2, the T groups can form a ring; HET is a heterocyclic group which optionally can form a ring with a T group; R12 is hydrogen, substituted or unsubstituted alkyl or substituted or unsubstituted aryl, or R12 can form a ring with a T group or with HET; 1 is 0 or 1; m is 0, 1, or 2; and n is 0 or 1.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: January 14, 2003
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owozarczyk, Xiqiang Yang, David T. Southby
  • Patent number: 6506548
    Abstract: This invention relates to a silver halide photographic element comprising at least one silver halide emulsion layer and further comprising an antifoggant represented by the following Structure I: wherein R1 is an aliphatic or cyclic group, R2 and R3 are independently hydrogen or bromine as long as at least one of them is bromine, L is a divalent linking group, m and n are independently 0 or 1, and SG is a solubilizing group that has a pKa of 8 or less.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: January 14, 2003
    Assignee: Eastman Kodak Company
    Inventors: Roger L. Klaus, George J. Burgmaier, Jon N. Eikenberry, Jerzy Z. Mydlarz, Nicholas E. Grzeskowiak
  • Publication number: 20030008251
    Abstract: Disclosed is a photothermographic material containing a non-photosensitive silver salt, a photosensitive silver halide and a binder on a support, which comprises a nucleating agent and a surfactant represented by the following formula (F):
    Type: Application
    Filed: September 26, 2001
    Publication date: January 9, 2003
    Inventor: Tetsuo Yamaguchi