Silver Compound Other Than Halide, Per Se, Or Composition For Thermographic Process Patents (Class 430/617)
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Patent number: 5587269Abstract: The present invention provides a thermal imaging process using (i) a donor element comprising on a support having a thickness of 3-10 .mu.m a donor layer comprising a binder, a thermotransferable reducing agent capable of reducing a silver source to metallic silver upon heating and particles protruding from the surface of said donor layer and (ii) a receiving element comprising on a support a receiving layer comprising a silver source capable of being reduced by means of heat in the presence of a reducing agent, said thermal imaging process comprising the steps ofbringing said donor layer of said donor element into face to face relationship with said receiving layer of said receiving element,image-wise heating a thus obtained assemblage, thereby causing image-wise transfer of an amount of said thermotransferable reducing agent to said receiving element in accordance with the amount of heat supplied by said thermal head andseparating said donor element from said receiving element.Type: GrantFiled: March 8, 1995Date of Patent: December 24, 1996Assignee: Afga-Gevaert N.V.Inventor: Geert Defieuw
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Patent number: 5582953Abstract: A direct thermal recording process wherein a direct thermal recording material is heated dot-wise and said direct thermal recording material comprises on a substrate an imaging layer containing uniformly distributed in a film-forming polymeric binder (i) one or more substantially light-insensitive organic silver salts being no double salts, said silver salt(s) being in thermal working relationship with (ii) an organic reducing agent therefor, characterized in that said reducing agent is a benzene compound the benzene nucleus of which is substituted by no more than two hydroxy groups which are present in 3,4-position on said nucleus and have in the 1-position of said nucleus a substituent linked to said nucleus by means of a carbonyl group.Type: GrantFiled: May 25, 1995Date of Patent: December 10, 1996Assignee: Agfa-Gevaert N.V.Inventors: Carlo Uyttendaele, Herman Uytterhoeven, Bartholomeus Horsten
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Patent number: 5569574Abstract: There are described heat-developable photosensitive image-recording materials which include a compound having at least one cyclic 1,3-sulfur-oxygen moiety. The compound is stable in the photographic processing composition but capable of undergoing cleavage in the presence of an imagewise distribution of silver ions and/or soluble silver complex made available as a function of development to liberate a reagent in an imagewise distribution corresponding to that of the silver ion and/or the soluble silver complex. The reagent includes a photographically useful group such as a complete dye or dye intermediate.Type: GrantFiled: November 13, 1995Date of Patent: October 29, 1996Assignee: Polaroid CorporationInventors: Peter Viski, David P. Waller
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Patent number: 5558983Abstract: N-acyl-hydrazine compounds are useful as contrast enhancers when used in combination with (i) hindered phenol developers, and (ii) trityl hydrazide and/or formyl-phenyl hydrazine co-developers, to produce ultra-high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.Type: GrantFiled: September 19, 1995Date of Patent: September 24, 1996Assignee: Minnesota Mining & Manufacturing CompanyInventors: Sharon M. Simpson, Lori S. Harring
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Patent number: 5558973Abstract: A heat-developable color light-sensitive material is described, which comprises, on a support, at least a light-sensitive silver halide, a non-diffusible dye-donating compound capable of releasing or forming a diffusible dye in correspondence or reverse correspondence with a reaction of reducing the silver halide to silver, and a binder, which contains a specific solid organic pigment in at least one layer of a light-sensitive silver halide emulsion layer and/or its adjacent layer(s) and which contains an alginic acid derivative in the same layer containing the solid organic pigment.Type: GrantFiled: January 31, 1995Date of Patent: September 24, 1996Assignee: Fuji Photo Film Co., Ltd.Inventor: Makoto Yamada
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Patent number: 5558972Abstract: The present invention discloses a thermal imaging process using (i) a donor element comprising on a support a donor layer containing a binder and a thermotransferable reducing agent capable of reducing a silver source to metallic silver upon heating and (ii) a receiving element comprising on a support in the order given a receiving layer and a curable layer, said receiving layer comprising a silver source capable of being reduced by means of heat in the presence of a reducing agent for said silver source and a binder, said thermal imaging process comprising the steps ofbringing said donor layer of said donor element into face to face relationship with said receiving layer of said receiving element,image-wise heating a thus obtained assemblage, thereby causing image-wise transfer of an amount of said thermotransferable reducing agent to said receiving element in accordance with the amount of heat supplied,separating said donor element from said receiving element,curing said release layer andoverall heating saiType: GrantFiled: May 25, 1995Date of Patent: September 24, 1996Assignee: Agfa-GevaertInventors: Marc Van Damme, Herman Uytterhoeven, Geert Defieuw
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Patent number: 5554482Abstract: A silver halide light-sensitive material is disclosed. The light-sensitive material comprises a support and two or more layers. Silver halide, a reducing agent, an ethylenically unsaturated polymerizable compound or a cross-linkable polymer and a base precursor are independently contained in at least one of the layers. A layer containing the base precursor further contains a specific polyvinyl alcohol. The first embodiment of the specific polyvinyl alcohol (I) has such a chemical structure that a terminal alkyl group having 4 or more carbon atoms is attached to a polyvinyl alcohol. The second embodiment of the specific polyvinyl alcohol (II) is a block copolymer consisting of a vinyl alcohol unit and a hydrophobic unit, which is more hydrophobic than the vinyl alcohol unit. The third embodiment is a mixture of two polyvinyl alcohols (III) and (IV). The polyvinyl alcohol (III) has a saponification degree of not less than 95%.Type: GrantFiled: April 25, 1995Date of Patent: September 10, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroaki Yokoya, Akihiro Endo
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Patent number: 5547821Abstract: Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating are provided with an electroconductive overcoat layer or an electroconductive backing layer or both an electroconductive overcoat layer and an electroconductive backing layer. Such electroconductive layers are comprised of electrically-conductive metal-containing particles dispersed in a polymeric binder in an amount sufficient to provide a surface resistivity of less than 5.times.10.sup.11 ohms/square.Type: GrantFiled: May 17, 1995Date of Patent: August 20, 1996Assignee: Eastman Kodak CompanyInventors: Sharon M. Melpolder, Charles C. Anderson, Peter J. Cowdery-Corvan, John F. DeCory
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Patent number: 5547810Abstract: An image forming method comprises the steps of (a) exposing a silver halide photographic light-sensitive material comprising a first support and provided thereon, a photographic component layer comprising a first binder, light sensitive silver halide and a sparingly water soluble metal compound; (b) superposing the exposed material on an image receiving material comprising a second support and provided thereon, an image receiving layer comprising a second binder and a compound represented by Formula (I), ##STR1## wherein A represents a cycloalkyl group, an aryl group or a heterocyclic ring; and M.sub.1 and M.sub.2 independently represent an alkali metal atom, an ammonium ion or a quaternary ammonium ion; (c) heating the superposed materials in the presence of water; and (d) separating the image receiving material from the exposed material to obtain an image on the image receiving layer of the image receiving material.Type: GrantFiled: August 29, 1995Date of Patent: August 20, 1996Assignee: Konica CorporationInventors: Hitoshi Morimoto, Kazuhiro Miyazawa, Masaru Tsuchiya
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Patent number: 5545505Abstract: Hydroxylamine, alkanolamine, and ammonium phthalamate compounds are useful as contrast enhancers when used in combination with (i) hindered phenol developers, and (ii) trityl hydrazide and/or formyl-phenyl hydrazine co-developers, to produce ultra-high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.Type: GrantFiled: September 19, 1995Date of Patent: August 13, 1996Assignee: Minnesota Mining and manufacturing CompanyInventor: Sharon M. Simpson
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Patent number: 5545507Abstract: Hydroxamic acid compounds are useful as contrast enhancers when used in combination with (i) hindered phenol developers, and (ii) trityl hydrazide and/or formyl-phenyl hydrazine co-developers, to produce ultra-high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.Type: GrantFiled: September 19, 1995Date of Patent: August 13, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Sharon M. Simpson, Francis H. Sansbury
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Patent number: 5545515Abstract: Acrylonitrile compounds are useful as co-developers when used in combination with hindered phenol developers to produce high contrast black-and-white photothermographic and thermographic elements.Acrylonitrile compounds are also useful as co-developers when used in combination with (i) hindered phenol developers, and (ii) trityl hydrazide and/or formyl-phenyl hydrazinc co-developers, to produce ultra-high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.Type: GrantFiled: September 19, 1995Date of Patent: August 13, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Thomas J. Murray, Sharon M. Simpson
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Patent number: 5543286Abstract: A dry process silver salt photosensitive material is disclosed which has a support and a photosensitive layer. The photosensitive layer contains at least a photosensitive silver halide or photosensitive silver halide forming component, an organic silver salt and a pyrrole compound. The photosensitive material has a broad latitude for heat development and can form images with a high contrast.Type: GrantFiled: November 10, 1994Date of Patent: August 6, 1996Assignee: Canon Kabushiki KaishaInventors: Kazunori Ueno, Tetsuro Fukui, Motokazu Kobayashi, Takehiko Ooi, Kenji Kagami, Masao Suzuki, Katsuya Nishino
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Patent number: 5541054Abstract: The present invention provides heat-developable, photothermographic elements comprising a support bearing at least one photosensitive, image-forming layer comprising:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible silver source;(c) a reducing agent for silver ions;(d) a binder; and(e) a spectrally sensitizing amount of a compound having the central nucleus: ##STR1## wherein: Z is S, O, Se or N--R.sup.3 ;R.sup.1 and R.sup.2 represent an alkyl group of from 1 to 20 carbon atoms other than carboxy-substituted alkyl, preferably an alkyl group of from 1 to 8 carbon atoms, and most preferably an ethyl group; andR.sup.3 is H or alkyl group;X and Y are thioalkyl groups of from 1 to 20 carbon atoms;n=0 to 4;m=0 to 4; the sum of n plus m equals at least 1;D.sup.1 to D.sup.7 each independently represents a methine group and adjacent methine groups selected from D.sup.2, D.sup.3, D.sup.4, D.sup.5 and D.sup.6 may form cyclic groups;p=0 or 1; andA.sup.- is an anion.Type: GrantFiled: April 20, 1995Date of Patent: July 30, 1996Assignee: Minnesota Mining & Manufacturing CompanyInventors: James R. Miller, Brian C. Willett, Doreen C. Lynch, Becky J. Kummeth
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Patent number: 5536622Abstract: Trityl hydrazides and formyl-phenyl hydrazines are useful as co-developers with hindered phenols in phothothermographic and thermographic elements. These co-developers have the formula:R.sup.1 --(C.dbd.O).sub.n --NHNH--R.sup.2R.sup.1 represents hydrogen and R.sup.2 represents an aryl or substituted aryl group; or,R.sup.1 represents hydrogen, alkyl and alkenyl groups of up to 20 carbon atoms; alkoxy, thioalkoxy, or amido groups of up to 20 carbon atoms; aryl, alkaryl, or aralkyl groups of up to 20 carbon atoms; aryloxy, thioaryloxy, or anilino groups of up to 20 carbon atoms; aliphatic or aromatic heterocyclic ring groups containing up to 6 ring atoms; carbocyclic ring groups comprising up to 6 ring carbon atoms; or fused ring or bridging groups comprising up to 14 ring atoms; and R.sup.2 represents a trityl group.Type: GrantFiled: August 28, 1995Date of Patent: July 16, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Sharon M. Simpson, Lori S. Harring
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Patent number: 5532121Abstract: Reduction of mottle and other surface anomalies in photothermographic and thermographic elements is reduced by the incorporation of a fluorinated polymer containing at least two different groups within the polymer chain derived from reactive monomers, the groups being: a fluorinated, ethylenically unsaturated monomer; and a polar, ethylenically unsaturated monomer.Type: GrantFiled: March 24, 1995Date of Patent: July 2, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Roger K. Yonkoski, Patricia M. Savu
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Patent number: 5521059Abstract: Ribonucleic acid (RNA) compounds have been found to function as antifoggants and post-processing print stabilizers in photothermographic elements.Type: GrantFiled: April 25, 1995Date of Patent: May 28, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Takuzo Ishida, Frank J. Manganiello, Kumars Sakizadeh
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Patent number: 5512411Abstract: Sulfonyl hydrazides are used as developers in phothothermographic and thermographic elements. The sulfonyl hydrazides have the formula:R.sup.1 --CO--NHNH--SO.sub.2 --R.sup.2wherein R.sup.1 and R.sup.Type: GrantFiled: August 21, 1995Date of Patent: April 30, 1996Assignee: Minnesota Mining & Manufacturing CompanyInventors: Doreen C. Lynch, Sharon M. Simpson, Paul G. Skoug
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Patent number: 5512185Abstract: Metal oxidizing agents (such as silver oxide or silver nitrate) are added to a solution of organic chemicals which comprise an unwanted level of organic reducing agents (either aqueous or organic solutions in which the metal oxidizing agent does not dissolve) and the metal oxidizing agent oxidizes at least some portion of said organic reducing agents. Because the metal oxidizing agent is insoluble in the solution, it is readily removed (e.g., by filtration or sedimentary techniques) to leave a solution with reduced amounts of reducing agents therein. This process is particularly useful for purifying phthalazine, behenic acid, and other toners, the component forming the counterion with silver ion in forming the light-insensitive silver source material and any other additives and raw materials which can be dissolved in a solvent medium in which the metal oxidizing agent is not highly soluble.Type: GrantFiled: July 31, 1995Date of Patent: April 30, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Roger A. Mader, Robert J. Ryther
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Patent number: 5510236Abstract: Improved photothermographic elements are spectrally sensitized with cyanine dyes that provide efficient sensitization together with excellent keeping stability and low dye stain. The photothermographic elements comprise a photosensitive silver halide, an organic silver salt, such as silver behenate, and a reducing agent. The cyanine dye utilized as a spectral sensitizer for the silver halide is an anionic cyanine dye comprising two thiazole nuclei each of which is substituted with an N-sulfoalkyl group wherein at least one of the thiazole nuclei is a 5,6-dihalobenzothiazole nucleus.Type: GrantFiled: May 12, 1995Date of Patent: April 23, 1996Assignee: Eastman Kodak CompanyInventor: Heidi E. Dankosh
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Patent number: 5508162Abstract: Improved photothermographic elements are spectrally sensitized with a combination of cyanine dyes that provides efficient sensitization together with excellent keeping stability and low dye stain. The photothermographic elements comprise a photosensitive silver halide, an organic silver salt, such as silver behenate, and a reducing agent. The dye combination utilized as a spectral sensitizer for the silver halide is a combination of a first cyanine dye containing two thiazole nuclei and a second cyanine dye containing a thiazole nucleus and an oxazole nucleus.Type: GrantFiled: May 12, 1995Date of Patent: April 16, 1996Assignee: Eastman Kodak CompanyInventor: Heidi E. Dankosh
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Patent number: 5503969Abstract: A heat-developable color light-sensitive material is described, which comprises a light-sensitive silver halide, a binder, a dye-donating compound and at least one compound represented by the following formula (I) on a support: ##STR1## wherein R.sub.1 represents an alkyl group having from 1 to 30 carbon atoms, an alkenyl group having from 2 to 30 carbon atoms, a cycloalkyl group having from 3 to 30 carbon atoms, or an aryl group having from 6 to 36 carbon atoms; R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each independently represents a hydrogen atom, an alkyl group having from 1 to 30 carbon atoms, or an alkenyl group having from 2 to 30 carbon atoms; m represents an integer of from 0 to 10; and n represents 0 or 1; with the proviso that, when m is an integer of from 1 to 10, n is 0; when n is 1, m is 0; when m is an integer of from 2 to 10, the plurality of R.sub.2 groups may be the same or different, and the plurality of R.sub.3 groups may be the same or different; R.sub.1 and R.sub.2, R.sub.2 and R.sub.Type: GrantFiled: March 28, 1995Date of Patent: April 2, 1996Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuki Uehara, Hiroo Takizawa
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Patent number: 5496695Abstract: Trityl hydrazides and formyl-phenyl hydrazines are useful as co-developers with hindered phenols in phothothermographic and thermographic elements. These co-developers have the formula:R.sup.1 --(C.dbd.O).sub.n --NHNH--R.sup.2R.sup.1 represents hydrogen and R.sup.2 represents an aryl or substituted aryl group; or,R.sup.1 represents hydrogen, alkyl and alkenyl groups of up to 20 carbon atoms; alkoxy, thioalkoxy, or amido groups of up to 20 carbon atoms; aryl, alkaryl, or aralkyl groups of up to 20 carbon atoms; aryloxy, thioaryloxy, or anilino groups of up to 20 carbon atoms; aliphatic or aromatic heterocyclic ring groups containing up to 6 ring atoms; carbocyclic ring groups comprising up to 6 ring carbon atoms; or fused ring or bridging groups comprising up to 14 ring atoms; and R.sup.2 represents a trityl group.Type: GrantFiled: January 6, 1995Date of Patent: March 5, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Sharon M. Simpson, Lori S. Harring
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Patent number: 5491059Abstract: Silver carboxylates which can serve as the silver source in a black-and-white thermographic or photothermographic element or as the oxidizing agent for a dye-based thermographic or photothermographic color-imaging construction can be represented by the general formula;R.sup.3 --X--(CH.sub.2 --CH.sub.2 --X).sub.n --L--CR.sup.1 R.sup.2 --COO.sup.-+ Agwherein:R.sup.1 and R.sup.2 are each independently hydrogen, halogen, alkyl, substituted alkyl, aromatic, or substituted aromatic;R.sup.3 is an alkyl group, an aryl group, or L--CR.sup.1 R.sup.2 --COO.sup.-+ Ag;L is a linking group that links CR.sup.1 R.sup.2 to X;X is selected from the group consisting of O, S, and NR.sup.4, wherein R.sup.4 is chosen from alkyl, substituted alkyl, aromatic, or substituted aromatic; andn is an integer from 0 to 12.Type: GrantFiled: October 31, 1994Date of Patent: February 13, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventor: David R. Whitcomb
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Patent number: 5482814Abstract: A heat developing photosensitive member including: a photosensitive layer containing at least an organic silver salt, a reducing agent and a photosensitive silver halide or a photosensitive silver halide forming agent; and a supporting member for supporting the photosensitive layer thereon, wherein merocyanine dye having a structure in which a thiazole nucleus or selenazole nucleus and hydantoin nucleus, thiohydantoin nucleus or selenohydantoin nucleus are combined with each other by a combining group having a methine group is contained in the photosensitive layer.Type: GrantFiled: July 15, 1994Date of Patent: January 9, 1996Assignee: Canon Kabushiki KaishaInventors: Takehiko Ooi, Tetsuro Fukui, Motokazu Kobayashi, Kazunori Ueno, Kenji Kagami, Masao Suzuki, Katsuya Nishino
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Patent number: 5480760Abstract: An aqueous-developable chromogenic photographic heat-transferable non-aqueous dye-diffusion-transfer photographic element is disclosed, wherein said element comprises radiation sensitive silver halide, a dye-providing compound that forms or releases a heat-transferable image dye upon reaction of said compound with the oxidation product of a primary amine developing agent, a hydrophilic binder, and a thermal solvent for facilitating non-aqueous diffusion transfer according to formula (I) ##STR1## wherein AH is a hydrogen bond donating group with an aqueous pK.sub.a for proton loss of greater than 6;L.sup.1 and L.sup.Type: GrantFiled: June 8, 1993Date of Patent: January 2, 1996Assignee: Eastman Kodak CompanyInventors: David S. Bailey, Albert J. Mura, Jr.
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Patent number: 5480761Abstract: An aqueous-developable chromogenic photographic heat-transferable non-aqueous dye-diffusion-transfer photographic element is disclosed, wherein said element comprises radiation sensitive silver halide, a dye-providing compound that forms or releases a heat-transferable image dye upon reaction of said compound with the oxidation product of a primary amine developing agent, a hydrophilic binder, and a thermal solvent for facilitating non-aqueous diffusion transfer according to formula (I) ##STR1## wherein AH is a hydrogen bond donating group with an aqueous pK.sub.a for proton loss of greater than 6;L.sup.1 and L.sup.Type: GrantFiled: June 8, 1993Date of Patent: January 2, 1996Assignee: Eastman Kodak CompanyInventors: David S. Bailey, Albert J. Mura, Jr.
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Patent number: 5468587Abstract: An aqueous-developable chromogenic photographic heat-transferable non-aqueous dye-diffusion-transfer photographic element is disclosed, wherein said element comprises radiation sensitive silver halide, a dye-providing compound that forms or releases a heat-transferable image dye upon reaction of said compound with the oxidation product of a primary amine developing agent, a hydrophilic binder, and a thermal solvent for facilitating non-aqueous diffusion transfer according to formula (I) ##STR1## wherein AH is a hydrogen bond donating group with an aqueous pK.sub.a value for proton loss of greater than 6;L.sup.1 and L.sup.Type: GrantFiled: June 8, 1993Date of Patent: November 21, 1995Assignee: Eastman Kodak CompanyInventors: David S. Bailey, Albert J. Mura, Jr., Shari L. Eiff
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Patent number: 5468603Abstract: A photothermographic or thermographic imaging element having uniform optical density is described which is useful in automated equipment. A polymeric fluorinated surfactant is present in a layer adjacent to the photothermographic or thermographic emulsion layer to provide uniform optical density. Optically transparent polymeric beads are present in at least one outermost layer of the imaging element to assist in the separation and sliding of the elements when subjected to a film feeding mechanism in automated equipment.Type: GrantFiled: November 16, 1994Date of Patent: November 21, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventor: Thomas J. Kub
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Patent number: 5464738Abstract: Sulfonyl hydrazides are used as developers in phothothermographic and thermographic elements. The sulfonyl hydrazides have the formula:R.sup.1 --CO--NHNH--SO.sub.2 --R.sup.2wherein R.sup.1 and R.sup.Type: GrantFiled: January 6, 1995Date of Patent: November 7, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Doreen C. Lynch, Sharon M. Simpson, Paul G. Skoug
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Patent number: 5445913Abstract: The invention is directed to a process for forming a chromogenic photographic heat-transferable non-aqueous dye-diffusion-transfer photographic element comprising the steps of: providing, separately, a melt comprising a spectrally dye-sensitized silver halide emulsion and a dry diffusion transfer facilitating thermal solvent; mixing said spectrally dye sensitized silver halide emulsion melt and said dry diffusion transfer facilitating thermal solvent with a mixing means to create a mixed melt; providing a coating substrate; coating said mixed melt on said substrate to form a coated photographic element, wherein said coating takes place less than about 10 minutes after mixing.The heat-transferable photographic element thus formed has improved photographic sensitivity and increased sensitometric uniformity.Type: GrantFiled: February 25, 1994Date of Patent: August 29, 1995Assignee: Eastman Kodak CompanyInventors: David S. Bailey, Richard L. Parton
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Patent number: 5443742Abstract: Metal oxidizing agents (such as silver oxide or silver nitrate) are added to a solution of organic chemicals which comprise an unwanted level of organic reducing agents (either aqueous or organic solutions in which the metal oxidizing agent does not dissolve) and the metal oxidizing agent oxidizes at least some portion of said organic reducing agents. Because the metal oxidizing agent is insoluble in the solution, it is readily removed (e.g., by filtration or sedimentary techniques) to leave a solution with reduced amounts of reducing agents therein. This process is particularly useful for purifying phthalazine, behenic acid, and other toners, the component forming the counterion with silver ion in forming the light-insensitive silver source material and any other additives and raw materials which can be dissolved in a solvent medium in which the metal oxidizing agent is not highly soluble.Type: GrantFiled: November 7, 1994Date of Patent: August 22, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Roger A. Mader, Robert J. Ryther
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Patent number: 5441866Abstract: Photothermographic elements of the photothermographic type may be sensitized to the infrared with sensitizing dyes of the formula: ##STR1## wherein: R.sup.1 represents a (CH.sub.2).sub.n --COO.sup.- group of from 1-20 carbon atoms, or an alkyl group of from 1 to 20 carbon atoms; andn is an integer from 1 to 20.Type: GrantFiled: January 26, 1995Date of Patent: August 15, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: James R. Miller, Sam Kalousdian, Brian C. Willett, John M. Winslow, Pu Zhou, Chaofeng Zou
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Patent number: 5436109Abstract: A process for forming an improved dye image in a heat-developable photographic dry dye-diffusion transfer element comprising the steps of:providing a heat-developable chromogenic photographic dry dye-diffusion transfer element comprising radiation sensitive silver halide, an organic silver salt, a heat-developable dye-forming compound wherein said compound forms or releases a heat-transferable dye upon reaction of said compound with the oxidation product of a reducing agent, a reducing agent, a hydrophilic binder, and a thermal solvent wherein said thermal solvent comprises a 3-hydroxy benzamide or a 4-hydroxy benzamide and has the structure I ##STR1## wherein (a) Z.sub.1, Z.sub.2, Z.sub.3, Z.sub.4, and Z.sub.5 are substituents, the Hammet sigma parameters of Z.sub.2, Z.sub.3, and Z.sub.4 sum to give a total, .SIGMA., of at least -0.28 and less than 1.Type: GrantFiled: December 29, 1993Date of Patent: July 25, 1995Assignee: Eastman Kodak CompanyInventors: David S. Bailey, Ronald H. White, John Texter
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Patent number: 5425993Abstract: Process for obtaining submicronic particles, for example, pigments in the presence of lipidic vesicles having a lamellar structure, starting with at least one precursor of said particles involves preparing a dispersion of vesicles starting with at least one lipid capable of forming the walls of the vesicles and an aqueous phase E intended to be encapsulated in the said vesicles, and optionally an aqueous phase D, intended to form a dispersion medium of the said vesicles, at least one precursor of the said vesicles being dissolved in phase E and/or D, before and/or during and/or after the preparation of the vesicular phase, at least one agent capable of transforming the said precursor(s) into sought after particles being reacted with it (them) after introduction into the preparation medium.Type: GrantFiled: February 19, 1993Date of Patent: June 20, 1995Assignee: L'OrealInventors: Jean-Luc Morancais, Alain Lety, Guy Vanlerbergue
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Patent number: 5424182Abstract: A heat-sensitive coating composition, and heat-sensitive material for thermal imaging containing the heat sensitive composition. The composition comprises a color-forming amount of a finely divided, solid, colorless noble metal salt of an organic acid; a color-developing amount of an organic reducing agent which at thermal copy and printing temperatures is capable of a color-forming reaction with the noble metal salt; an image toning agent; and a carrier composition in which the noble metal salt, organic reducing agent, and toning agent are distributed. The carrier composition requires no organic solvents and comprises one or more substantially water-soluble polymeric carrier materials and a solubility-enhancing amount of a dispersing agent. A protective, clarifying, radiation-cured overcoat is provided. Methods of forming the heat-sensitive composition and the overcoat are also disclosed.Type: GrantFiled: September 10, 1993Date of Patent: June 13, 1995Assignee: Labelon CorporationInventors: Barry L. Marginean, Sr., Simon R. Cuch, Clinton A. Whittaker, Mayur C. Patel
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Patent number: 5422234Abstract: Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating include an adhesive interlayer interposed between the imaging layer and a protective overcoat layer. The adhesive interlayer, which is comprised of a polymer having epoxy functionality, strongly bonds the overcoat layer to the imaging layer.Type: GrantFiled: March 16, 1994Date of Patent: June 6, 1995Assignee: Eastman Kodak CompanyInventors: Charles L. Bauer, Wayne A. Bowman
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Thermally processable imaging element including an adhesive interlayer comprising a polyalkoxysilane
Patent number: 5418120Abstract: Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating include an adhesive interlayer interposed between the imaging layer and a protective overcoat layer. The adhesive interlayer, which is comprised of a polyalkoxysilane, strongly bonds the overcoat layer to the imaging layer.Type: GrantFiled: March 16, 1994Date of Patent: May 23, 1995Assignee: Eastman Kodak CompanyInventors: Charles L. Bauer, Wayne A. Bowman -
Patent number: 5415993Abstract: A photographic emulsion containing: a photosensitive silver halide; a light-insensitive, reducible silver source; a reducing agent for the light-insensitive, reducible silver source; and a binder consisting essentially of poly(vinyl butyral) having a poly(vinyl alcohol) content of about 17.5 to 21.0 wt. % and at least one solvent selected from the group consisting of: toluene, methyl ethyl ketone, acetone, tetrahydrofuran, and 1,4-dioxane. Additionally, a process for coating a substrate involving applying at least one layer of a molten thermoreversible organogel layer; causing it to gel; and removing residual solvent.Type: GrantFiled: February 17, 1994Date of Patent: May 16, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kenneth L. Hanzalik, George H. Crawford, Jr., Sharon M. Rozzi, David J. Scanlan
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Patent number: 5401611Abstract: The present invention provides a heat mode recording material comprising on a support having a hydrophilic surface or being provided with a hydrophilic layer, a metallic layer and on top thereof a hydrophobic layer having a thickness of less than 50 nm and there is further provided a method for making a lithographic plate therewith.Type: GrantFiled: February 5, 1993Date of Patent: March 28, 1995Assignee: AGFA-Gevaert, N.V.Inventors: John W. Edwards, Sr., Luc Leenders, Yves Verburgh, Joan Vermeersch, Ronald Schuerwegen
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Patent number: 5393649Abstract: Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating include an adhesive interlayer interposed between the imaging layer and a protective overcoat layer. The adhesive interlayer, which is comprised of a polymer having pyrrolidone functionality, strongly bonds the overcoat layer to the imaging layer.Type: GrantFiled: March 16, 1994Date of Patent: February 28, 1995Assignee: Eastman Kodak CompanyInventors: Charles L. Bauer, Wayne A. Bowman
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Patent number: 5393654Abstract: A heptamethine cyanine dye in which both nitrogen atoms of the cyanine chromophore bear a carboxyalkyl substituent comprising an alkyl chain of at least five carbon atoms. The dyes are useful as sensitisers in photothermographic imaging materials.Type: GrantFiled: February 28, 1994Date of Patent: February 28, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Ronald W. Burrows, David B. Oliff, James B. Philip, Jr.
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Patent number: 5387498Abstract: Positive-acting photothermographic elements suitable for use in graphic arts and medical imaging comprising a photosensitive medium comprising a reducible silver source, a photo-acid generator, a binder and a reducing system for silver ion comprising a reducing agent for silver ion in which exposure of the element to actinic radiation causes the production of acidic species in the exposed regions which inhibit reduction of the silver source by the reducing system.Type: GrantFiled: January 24, 1994Date of Patent: February 7, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventor: Richard J. Ellis
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Patent number: 5384237Abstract: A thermal-dye-bleach construction comprising a dye in association with a thermal dye-bleaching agent of general formula I: ##STR1## wherein: each of R.sup.a and R.sup.b are individually selected from: hydrogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, an aryl group, and a heterocyclic group, and preferably, both R.sup.a and R.sup.b represent hydrogen;p is one or two, and when p is one, Z is a monovalent group selected from: an akyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, and a heterocyclic group, and when p is two, Z is a divalent group selected from: an alkylene group, an arylene group, an alkenylene group, an alkynylene group, an aralkylene group, a cycloalkene group, and a heterocyclic group; and,M.sup.+ is a cation which will not react with a carbanion generated from the thermal-carbanion-generating agent in such manner as to render the carbanion ineffective as a bleaching agent for the dye.Type: GrantFiled: January 25, 1994Date of Patent: January 24, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Dian E. Stevenson, Mark P. Kirk, Sylvia A. Farnum, William C. Frank, Randall H. Helland, Jonathan P., Kitchin, Roger A. Mader, Mark B. Mizen, Richard A. Newmark, William D. Ramsden, Kumars Sakizadeh, Terence D. Spawn, George V. Tiers
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Patent number: 5384238Abstract: Positive-acting photothermographic elements suitable for use at contact speeds comprising a base layer having at least two layers thereon, which layers define a photosensitive medium comprising a photocurable composition, a reducible silver source, and a reducing system for silver ion comprising one or more components including a compound capable of reducing silver ion to silver metal, such that the reducible silver source and at least one component of the reducing system for silver ion are present in separate layers, wherein exposure of the element to actinic radiation causes curing of the photocurable composition in the exposed area(s), said curing preventing the reducing system from interacting with the reducible silver source during thermal processing and in which the photocurable composition comprises a free radical curable resin and a photoinitiator therefor having an absorbance to radiation in the wavelength range of 340 to 440 nm, which photoinitiator upon exposure to said actinic radiation or duringType: GrantFiled: January 21, 1994Date of Patent: January 24, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Richard J. Ellis, Ranjan C. Patel, Robert J. D. Nairne
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Patent number: 5380644Abstract: A fluorinated polymer comprising at least three different groups within the polymer chain derived from reactive monomers, the monomers comprising:(a) a fluorinated, ethylenically unsaturated monomer;(b) a hydroxyl-containing, ethylenically unsaturated monomer; and(c) a polar, ethylenically unsaturated monomer.The fluorinated polymers provide a surfactant that is particularly useful in the coating of polymeric layers. The surfactants can reduce surface anomalies, such as mottle when used to coat photothermographic and thermographic elements from certain solvent systems. The present invention also provides photothermographic and thermographic elements comprising the foregoing fluorinated polymers.Type: GrantFiled: August 10, 1993Date of Patent: January 10, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Roger K. Yonkoski, Patricia M. Savu
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Patent number: 5374675Abstract: Thermoplastic molding materials contain, as essential components,A) from 30 to 99.995% by weight of a thermoplastic polymer,B) from 0.005 to 5% by weight of an inorganic subgroup metal saltandC) from 0 to 69.995% by weight of fibrous or particulate fillers or a mixture thereof.Type: GrantFiled: August 13, 1993Date of Patent: December 20, 1994Assignee: BASF AktiengesellschaftInventors: Christoph Plachetta, Karl Schlichting, Martin Welz, Theresa A. Bright
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Patent number: 5374514Abstract: A photothermographic material comprising photographic silver halide, a reducible silver source, a reducing agent for silver ion and a binder, and as an antifoggant and/or stabilizer, a compound of the formula (I): ##STR1## wherein R is a member selected form the group consisting of a hydrogen atom, an alkyl group, an aryl group and a heterocyclic group.Type: GrantFiled: December 17, 1993Date of Patent: December 20, 1994Inventors: Mark P. Kirk, Andrew W. Mott
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Patent number: 5370966Abstract: The invention discloses an aqueous-developable chromogenic photographic heat-transferable non-aqueous dye-diffusion-transfer photographic element comprising radiation sensitive silver halide, a dye-providing compound that forms or releases a heat-transferable, image dye upon reaction of said compound with the oxidation product of a primary amine developing agent, a hydrophilic binder, and a thermal solvent for facilitating non-aqueous diffusion transfer wherein said thermal solvent comprises a sugar group containing amphiphilic compound, said amphiphilic compound comprising from one to three independently constituted 3 to 22 carbon atom hydrophobic tail(s) with one or more attached hydrophilic mono or oligosaccaridic rings or chains such that the HLB value of the compound is less than about 13.Type: GrantFiled: November 29, 1993Date of Patent: December 6, 1994Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, David S. Bailey
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Patent number: 5360695Abstract: An aqueous developable chromogenic photographic dye-diffusion transfer element of two or more layers comprising a support, radiation sensitive silver halide, a dye-forming compound wherein said compound forms a heat transferable dye upon reaction of said compound with the oxidation product of a primary amine developing agent, a hydrophilic binder, and a solid particle thermal solvent dispersion, wherein said thermal solvent is a water-immiscible phenol derivative, has a melting point of between 50.degree. C. and about 200.degree. C., and is incorporated at 5 to 200% by weight of said hydrophilic binder, and where said thermal solvent dispersion contains a dispersing aid, is disclosed.Type: GrantFiled: January 26, 1993Date of Patent: November 1, 1994Assignee: Eastman Kodak CompanyInventor: John Texter