Resin Or Synthetic Polymer Containing Patents (Class 430/627)
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Patent number: 5478714Abstract: A silver halide photographic emulsion contains tabular silver halide grains having an aspect ratio of 2 or more in an amount of 70% or more of a total projected area of all grains. A variation coefficient of the grain size distribution of all silver halide grains is 20% or less, a signal having at least two peaks is present in a diffraction angle range of less than 1.5 degree at a maximum peak height.times.0.13 of a (420) X-ray diffraction signal obtained using the K.sub..alpha. line of Cu, and a peak interval thereof is 0.1 degree or more in terms of the diffraction angle.Type: GrantFiled: March 2, 1994Date of Patent: December 26, 1995Assignee: Fuji Photo Film, Co., Ltd.Inventors: Sadanobu Shuto, Hideo Ikeda, Takefumi Hara
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Patent number: 5476762Abstract: A silver halide photographic light-sensitive material comprises a support and provided thereon, a photographic component layer comprising a silver halide emulsion layer, the material being processed in 10 seconds to less than 45 seconds, wherein the photographic component layer comprises polymer latex of a polymer containing in its chemical structure a unit derived from a monomer having a solubility in water of 25.degree. C. of 0.000 to 0.025% by weight and the pH of the surface on the silver halide emulsion layer side of the material is not more than 6.0.Type: GrantFiled: December 13, 1994Date of Patent: December 19, 1995Assignee: Konica CorporationInventor: Toshiyuki Marui
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Patent number: 5468598Abstract: A process for preparing a stable, solid particle dispersion of a substantially water-insoluble compound useful in imaging, comprises the steps of:(a) forming a coarse aqueous slurry of solid particles of said compound and a hydrophobic, water-soluble or water-dispersible polymer in an amount of 0.1 to 100% by weight based on the weight of said compound; and(b) milling said slurry for time sufficient to provide particles of the desired average particle size;wherein the polymer is an uncharged or weakly anionically charged water-soluble or water-dispersible homopolymer or copolymer in which at least 10 mole % of the repeat units contain an uncharged pendant group that terminates in (a) a CH.sub.3 unit, (b) a ring containing at least two contiguous CH.sub.2 units, or (c) an aromatic group.The resulting dispersion has dispersed solid particles of said compound having the desired small particle size and is stable toward particle agglomeration, particle growth and needle growth.Type: GrantFiled: April 18, 1994Date of Patent: November 21, 1995Assignee: Eastman Kodak CompanyInventors: David D. Miller, Mary C. Brick, Mridula Nair
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Patent number: 5462846Abstract: Disclosed is a silver halide color photographic material having at least one non-coloring layer. The layer contains (i) at least one water-insoluble polymer having a number average molecular weight of less than 2000, which is obtained obtained by polymerizing at least one monomer having an aromatic group, and optionally contains (ii) at least one UV absorbent selected from 2-(2'-hydroxyphenyl)benzotriazoles, benzophenones and triazines and (iii) at least one high boiling point organic solvent having a refractive index of 1.50 or less. The photographic material has high light fastness.Type: GrantFiled: November 22, 1994Date of Patent: October 31, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Yoneyama
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Patent number: 5455152Abstract: An ultraviolet absorbing monomer of formula (A): ##STR1## wherein: R.sub.4 and R.sub.5 are, independently, a substituted or unsubstituted alkylene with or without intervening oxygen, sulfur or nitrogen atoms; R.sub.6 is H or a substituted or unsubstituted methyl; and the benzo ring, the hydroxy substituted phenyl ring and the phenyl ring of the styryl group may be further substituted or unsubstituted. A method of making such monomers and photographic elements containing UV absorbing polymers formed from such monomers are also provided.Type: GrantFiled: September 27, 1994Date of Patent: October 3, 1995Assignee: Eastman Kodak CompanyInventor: Lal C. Vishwakarma
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Patent number: 5455154Abstract: A photographic silver halide material which has at least one light-sensitive layer and contains in at least one layer a compound corresponding to formula (I) in a quantity of at least 10 mg/m.sup.2 : ##STR1## wherein k stands for 50 to 99% by weight,l stands for 0 to 49% by weight,m stands for 1 to 40% by weight,j stands for 0 to 49% by weight,M denotes a comonomer incorporated by polymerisation,M.sub.1 denotes ##STR2## M.sub.2 denotes ##STR3## R.sub.1 and R.sub.2 denote hydrogen or alkyl, R.sub.3 denotes an acidic group, andB denotes a chemical bond or a bridging member and which is hardened with a rapid or an instant hardener,is distinguished by improved wet scratch resistance and stability in storage.Type: GrantFiled: May 23, 1994Date of Patent: October 3, 1995Assignee: Agfa Gevaert, AGInventors: Gunter Helling, Jean-Marie Dewanckele
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Patent number: 5453352Abstract: A silver halide photographic light-sensitive material is disclosed, which comprises a support and provided thereon, a hydrophilic colloid layer comprising a silver halide emulsion layer wherein the hydrophilic colloid layer contains a compound having a solubility of not less than 1 g based on 100 g of water of 25.degree. C.Type: GrantFiled: February 2, 1995Date of Patent: September 26, 1995Assignee: Konica CorporationInventor: Noriki Tachibana
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Patent number: 5447832Abstract: An imaging element comprising a support, at least one light-sensitive layer and at least one coalesced layer of film-forming colloidal polymeric particles and non-film-forming colloidal polymeric particles.Type: GrantFiled: March 31, 1994Date of Patent: September 5, 1995Assignee: Eastman Kodak CompanyInventors: Yongcai Wang, Charles C. Anderson
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Patent number: 5445931Abstract: A silver halide photographic material comprising, on a support, at least one silver halide emulsion layer, which has at least one hydrophilic colloid layer (including the silver halide emulsion layer) containing a water-soluble polymer comprising a COOH-containing monomer or a salt thereof which is water-insoluble at a pH.ltoreq.6 and water-soluble at a pH.gtoreq.10. The photographic material is well processed by ultra-rapid processing system, displaying an excellent drying property.Type: GrantFiled: August 3, 1994Date of Patent: August 29, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Junichi Yamanouchi, Yutaka Tamura, Yasuyuki Takagi
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Patent number: 5441865Abstract: This invention describes the use of gelatin-grafted-polymer particles as peptizers for the preparation of silver halide photographic emulsions, whereby the gelatin-grafted-polymer particles remain attached to the AgX crystals after preparation of the emulsions. In an embodiment of this invention, the core polymer particles are loaded with photographically useful agents. When the photographic agent is a dye-forming coupler, multicolor mixed-packet systems can be constructed using the packet emulsions prepared in the manner of this invention.Type: GrantFiled: January 7, 1993Date of Patent: August 15, 1995Assignee: Eastman Kodak CompanyInventors: John D. Lewis, Mark A. Whitson, Thomas J. Dannhauser, Tienteh Chen, Pranab Bagchi
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Patent number: 5437970Abstract: There is disclosed a silver halide color photographic material and a method for forming an image utilizing the same. The photographic material has, on a reflective support, photographic constitutional layers comprising photosensitive silver halide emulsion layers and non-photosensitive hydrophilic colloid layers, and comprises a reflective support covered the surface to be emulsion-coated with a composition of a polyester resin and a white pigment; and a non-photosensitive hydrophilic colloid layer containing a dispersion of solid fine particles of a compound represented by the following formula (Sa); with the total amount of gelatin contained in the photographic constitutional layers being limited; and with the silver halide emulsion being a high-silver-chloride emulsion:D-(X).sub.y formula (Sa)wherein D represents a compound having a chromophore; X represents a dissociable proton or a group having a dissociable proton.Type: GrantFiled: December 16, 1993Date of Patent: August 1, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Akiko Shono
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Patent number: 5427899Abstract: A two-phase acidic aqueous composition for use as a neutralization layer is generally comprised of a water soluble aqueous phase and a water insoluble particle phase. The particle phase generally comprises a copolymer having recurring units of an organic acid monomer and an organic ester monomer. The aqueous phase comprises a water soluble polymer having recurring units of at least an organic acid monomer. The organic acid monomers selected for the aqueous phase polymer are capable of interacting with the particle phase polymers such that the particle phase polymers are brought into stabilizing, intimate association with the aqueous phase.Type: GrantFiled: January 31, 1994Date of Patent: June 27, 1995Assignee: Polaroid CorporationInventors: David W. Avison, Agota F. Fehervari, David A. Johnson, Diana R. Koretsky
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Patent number: 5426019Abstract: Yellowing, dye fade and thermal pinking of a processed color photographic element is improved by incorporating into the photographic element a non-color forming, oil-soluble, monomeric or oligomeric organic compound having a glass transition temperature between 0.degree. and 150.degree. C. Preferred organic compounds include rosin derivatives, natural resins and oil-soluble sucrose esters, etc. In a particularly preferred embodiment, the above-noted properties are improved by incorporating into the photographic element an oil-soluble rosin derivative, such as abietic acid.Type: GrantFiled: December 30, 1993Date of Patent: June 20, 1995Assignee: Eastman Kodak CompanyInventor: Krishnan Chari
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Patent number: 5420004Abstract: An internal latent image type positive silver halide emulsion has improved sensitivity reduction in low illuminance exposures. A color diffusion transfer light-sensitive material incorporates the emulsion and has reduced sensitivity reduction. The internal latent image type positive silver halide emulsion is prepared using a polymer having a repetitive unit derived from an ethylenically unsaturated monomer having at least one thioether structure on a side chain as a deflocculating agent to form silver halide grains and subjecting the grain surfaces to a chemical sensitization in the presence of a polymer having a repetitive unit represented by the following Formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a substituted or unsubstituted alkyl group and Q represents a group selected from the group consisting of groups represented by the following Formula (1) to Formula (4): ##STR2## wherein q represents an integer of 2 to 4; ##STR3## wherein R.sup.2 and R.sup.Type: GrantFiled: August 10, 1993Date of Patent: May 30, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Munehisa Fujita, Toru Sano
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Patent number: 5415993Abstract: A photographic emulsion containing: a photosensitive silver halide; a light-insensitive, reducible silver source; a reducing agent for the light-insensitive, reducible silver source; and a binder consisting essentially of poly(vinyl butyral) having a poly(vinyl alcohol) content of about 17.5 to 21.0 wt. % and at least one solvent selected from the group consisting of: toluene, methyl ethyl ketone, acetone, tetrahydrofuran, and 1,4-dioxane. Additionally, a process for coating a substrate involving applying at least one layer of a molten thermoreversible organogel layer; causing it to gel; and removing residual solvent.Type: GrantFiled: February 17, 1994Date of Patent: May 16, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kenneth L. Hanzalik, George H. Crawford, Jr., Sharon M. Rozzi, David J. Scanlan
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Patent number: 5411849Abstract: A silver halide photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a silver halide emulsion comprising silver halide grains, which is prepared by a process comprising(i) forming the silver halide emulsion by mixing a silver salt and a halide salt in a dispersion medium,(ii) subjecting the emulsion formed to washing to remove water-soluble salts, and then(iii) carrying out chemical sensitization of the emulsion wherein in (ii), the washing is carried out by coagulating the emulsion by a gelatin coagulant selected from of a modified gelatin or a polymeric coagulant represented by the following formula [I]; and in (iii), iodide-containing silver halide fine grains are added at a time during the course of the chemical sensitization, ##STR1##Type: GrantFiled: December 6, 1993Date of Patent: May 2, 1995Assignee: Konica CorporationInventor: Takuji Hasegawa
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Patent number: 5407792Abstract: The present invention relates to photosensitive silver halide recording material with reduced pressure sensitivity. The occurrence of pressure marks can be minimized by protective layers with suitable additives. Other properties of the recording material, such as sensitivity, contrast, and clarity, are not affected adversely. Recording materials with protective layers containing polyolefin oxidates are largely insensitive to pressure marks and have low haze, high sensitivity, and high contrast. The invention's recording materials can be used in all fields of photographic and radiographic image production, especially in reproducing color images in steps preliminary to printing and in recording x-ray images for medical diagnostics.Type: GrantFiled: March 30, 1994Date of Patent: April 18, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Reinhold Ruger
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Patent number: 5405738Abstract: A silver halide photographic light-sensitive material has at least one silver halide emulsion layer on a support. The silver halide emulsion layer contains a silver halide emulsion in which 50% or more of the projected area or the number of all silver halide grains are occupied by substantially perfect cubic silver halide grains, which are silver bromochloroiodide or silver bromoiodide grains having a silver iodide content of 0.5 mol % or more and a silver chloride content of 3 mol % or less and are spectrally sensitized with sensitizing dyes.Type: GrantFiled: June 8, 1993Date of Patent: April 11, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Mitsuhiro Uchida
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Patent number: 5399480Abstract: The invention describes silver halide packet emulsion grains or crystals that are conventionally precipitated using gelatin of a given isoelectric pH, surrounded by a layer of gelatin-grafted-polymer particles wherein the grafted gelatin has a different isoelectric pH and the said gelatin-grafted-polymer particles are optionally chemically bonded to the gelatin surrounding the silver halide microcrystals. Such packet emulsions can form the basis for a mixed-packet color photographic system.Type: GrantFiled: September 14, 1993Date of Patent: March 21, 1995Assignee: Eastman Kodak CompanyInventors: Mark A. Whitson, John D. Lewis, Tienteh Chen, Thomas J. Dannhauser, Pranab Bagchi
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Patent number: 5393648Abstract: There is disclosed a silver halide photographic material containing a dispersion of a hydrophobic compound and a water-insoluble and organic solvent-soluble polymer as defined herein. The hydrophobic compound may be a dye which is photochemically inactive during storage but readily decolored and eluted in photographic processing.Type: GrantFiled: August 11, 1993Date of Patent: February 28, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Satoru Toda, Tomokazu Yasuda, Koji Tamoto
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Patent number: 5385819Abstract: A process for preparing a thin tabular grain silver halide emulsion comprised of silver halide grains which have a halide content of at least 50 mole percent bromide, wherein tabular grains of less than 0.15 micrometers in thickness and having an aspect ratio of greater than 8 account for greater than 50 percent of the total grain projected area, comprises the steps of nucleating the silver halide grains with a gelatino-peptizer or with the use of certain synthetic polymers that serve as effective nucleation peptizers and then growing the silver halide grains with the use of either a gelatino-peptizer or certain synthetic polymers that serve as effective growth peptizers.Type: GrantFiled: December 22, 1993Date of Patent: January 31, 1995Assignee: Eastman Kodak CompanyInventors: Wayne A. Bowman, Roger A. Weiss, Gerald W. Klein, John E. Keevert, Jr., Shane C. Weber
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Patent number: 5380642Abstract: A process for preparing a thin tabular grain silver halide emulsion comprised of silver halide grains which have a halide content of at least 50 mole percent bromide, wherein tabular grains of less than 0.15 micrometers in thickness and having an aspect ratio of greater than 8 account for greater than 50 percent of the total grain projected area, comprises the steps of nucleating the silver halide grains with a gelatino-peptizer or with the use of certain synthetic polymers that serve as effective nucleation peptizers and then growing the silver halide grains with the use of either a gelatino-peptizer or certain synthetic polymers that serve as effective growth peptizers.Type: GrantFiled: December 22, 1993Date of Patent: January 10, 1995Assignee: Eastman Kodak CompanyInventors: Michael R. Roberts, Wai K. Lam, Wayne A. Bowman, John E. Keevert, Jr., Byron H. Rubin
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Patent number: 5380637Abstract: A silver halide photographic material is disclosed in which a matting agent contained in a coating solution is prevented from settling in solution and peeling off during processing. The silver halide photographic material contains at least one light-sensitive emulsion and at least one surface protective layer on a support. The surface protective layer contains a polymer latex having an average particle size of up to 2 .mu.m and a perticular precipitation amount as measured in a test coating solution or a crosslinked polymer latex having a hydrophilic group.Type: GrantFiled: October 19, 1993Date of Patent: January 10, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Yamashita, Jun Kawagoe, Ichizo Toya
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Patent number: 5376434Abstract: A photographic material and a preparing method thereof are disclosed, the material comprising a photographic print and a protective layer provided on an image layer of the photographic print by coating latex comprising a resin having a glass transition temperature of 30.degree. to 70.degree. C.Type: GrantFiled: July 21, 1993Date of Patent: December 27, 1994Assignee: Konica CorporationInventors: Takahiro Ogawa, Sota Kawakami, Hiroshi Watanabe
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Patent number: 5374509Abstract: A photographic element is provided which readily absorbs aqueous solution during processing and yet readily liberates the water during drying. The photographic element comprises a support; at least one layer coated on said support wherein said layer comprises:(a) hydrophilic colloid;(b) a branched polysaccharide;(c) a polyacrylamide; andat least one of either (d) or (e):(d) a mixture of polyvinylidene chloride and polyacrylate; or(e) a copolymer of vinylidene chloride and acrylate.Type: GrantFiled: May 4, 1994Date of Patent: December 20, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventor: Jose Valentini
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Patent number: 5370984Abstract: In a silver halide photographic light-sensitive material having at least one silver halide emulsion layer on a support, at least one of the silver halide emulsion layers contains a light-sensitive silver halide emulsion, in which tabular grains having an aspect ratio of 2 or more occupy 50% or more of a total projected area of silver halide grains, and a polymer represented by Formula (1) below in an amount of 10.sup.-3 to 10 g per mole of the silver halide. In Formula (1), A represents a repeating unit derived from an ethylenic unsaturated monomer having at least one basic nitrogen atom, and B represents a repeating unit, other than A, derived from an ethylenic unsaturated monomer. x and y each represents a percentage by weight. x represents 0.1 to 100, and y represents 0 to 99.9.Type: GrantFiled: April 20, 1993Date of Patent: December 6, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Shunji Takada, Junichi Yamanouchi
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Patent number: 5370981Abstract: Antistatically treated plastic formed articles, e.g. photographic film supports, that contain at least two layers on the surface to be antistatically treated, wherein a layer nearer to the plastic surface contains a preparation of a polythiophene that is built up from structural units of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of each other stand for hydrogen or a C.sub.1 -C.sub.4 -alkyl group or together form an optionally substituted C.sub.1 -C.sub.4 -alkylene group, preferably a methylene group optionally substituted by alkyl groups, a 1,2-ethylene group optionally substituted by C.sub.1 -C.sub.12 -alkyl or phenyl groups, a 1,3-propylene group or a 1,2-cyclohexylene group,and a polyanion, a farther layer contains a film-forming polymer and at least one of the two layers contains an alkoxysilane, are characterized, apart from excellent antistatic properties, by very good layer adhesion.Type: GrantFiled: March 24, 1993Date of Patent: December 6, 1994Assignee: Agfa-Gevaert AGInventors: Werner Krafft, Friedrich Jonas, Bavo Muys, Dirk Quintens
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Patent number: 5370983Abstract: A silver halide photographic material containing an oil-in-water type dispersion of a hydrophobic photographically useful substance is disclosed, in which the dispersion is prepared by emulsifying and dispersing a solution (A) of at least one water-insoluble and organic solvent-soluble polymer in a substantially water-immiscible organic solvent and a solution (B) of at least one hydrophobic photographically useful substance in a substantially water-immiscible organic solvent in an aqueous medium (C) either simultaneously or separately. The dispersion has improved stability with time, and the photographically useful substance in the dispersed particles exhibits improved stability to light or heat in the photographic material.Type: GrantFiled: April 30, 1993Date of Patent: December 6, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Akiko Shono, Osamu Takahashi
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Patent number: 5368984Abstract: A silver halide photographic light-sensitive material is disclosed. The material comprises a light-sensitive silver halide emulsion layer and containing both of a latex stabilized by gelatin and a redox compound from which a development inhibitor is released when the redox is oxidized in the emulsion layer or other non-light-sensitive hydrophilic colloidal layer. The silver halide photographic light-sensitive material is suitable for graphic arts plate-making use and is excellent in Ming-Gothic type reproduction, screen-image enlarging and screen-image reduction aptitudes, white-on-color letter quality, paste-up trace prevention, easy handling and stability.Type: GrantFiled: November 10, 1993Date of Patent: November 29, 1994Assignee: Konica CorporationInventor: Kazuhiro Yoshida
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Patent number: 5366842Abstract: The invention creates a selective oxygen barrier around individual coupler or other photographically active particles by surrounding each particle with a layer of water applicable oxygen barrier polymer such as polyvinyl alcohol (PVA), which will also act as a steric barrier to coalescence of the particles. Photographic products formed with such materials are more dye stable.Type: GrantFiled: July 23, 1993Date of Patent: November 22, 1994Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, James L. Edwards, Wendell F. Smith, Jr., Brian Thomas
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Patent number: 5362613Abstract: A cationic high-molecular weight compound is represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrogen atom or C.sub.1-6 lower alkyl group; L.sup.1 represents --COO-- or --CONH-- and L.sup.2 represents a divalent group; J represents a C.sub.1-20 alkylene group or C.sub.7-20 aralkylene group; R.sup.3, R.sup.4 and R.sup.5 may be the same or different and each represents a C.sub.1-20 alkyl group or C.sub.7-20 aralkyl group; X.sup.Type: GrantFiled: January 15, 1993Date of Patent: November 8, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Kentaro Shiratsuchi, Fumio Kawamoto
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Patent number: 5352571Abstract: A silver halide color photographic light-sensitive material capable of providing a dye image having improved spectral absorption characteristic as well as high color-forming property and excellent dye image fastness is disclosed. The light-sensitive material comprises at least one silver halide emulsion layer having a cyan color-forming property, wherein the silver halide emulsion layer having the cyan color-forming property contains at least one cyan coupler represented by the following formula (I) or (II) and at least one of a sparingly water-soluble homopolymer and/or copolymer: ##STR1## wherein Za and Zb each represents --C(R.sub.3).dbd. or --N.dbd., provided that one of Za and Zb is --N.dbd. and the other is --C(R.sub.3).dbd.; R.sub.1 and R.sub.2 each are an electron attractive group having a Hammett's substituent constant .sigma..sub.p of 0.2 or more and the sum of the .sigma..sub.p values of R.sub.1 and R.sub.2 is 0.65 or more; R.sub.Type: GrantFiled: November 27, 1992Date of Patent: October 4, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Makoto Suzuki, Hideaki Naruse, Takehiko Sato
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Patent number: 5330885Abstract: A silver halide photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein at least one hydrophilic colloidal layer containing said light-sensitive silver halide emulsion layer comprises the polymer latex stabilized by gelatin, and the outermost layer on the side containing said light-sensitive silver halide emulsion layer and/or the outermost layer on the other side comprises the anionic fluorine containing surfactant and/or cationic fluorine containing surfactant.Type: GrantFiled: February 4, 1993Date of Patent: July 19, 1994Assignee: Konica CorporationInventors: Yasuhiko Takamuki, Kazuhiro Yoshida, Takeo Arai
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Patent number: 5302501Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the swelling ratio of the entire hydrophilic colloid layers on the acid polymer-containing layer side of the support of the silver halide photographic material having a hydrophilic colloid layer containing at least one acid polymer (having a carboxyl group-containing monomer unit content of at least 15 mol % or an acid value of at least 1.5 meq/g) on at least one silver halide emulsion layer-coated side thereof is at least 200% in distilled water, said acid polymer being dissolved in water and added to said hydrophilic colloid layer, and the swollen thickness of the above entire hydrophilic colloid layers at the time of the completion of the rinsing stage is not more than 8 .mu.m when said silver halide photographic material is processed (the swelling ratio in distilled water is a value obtained by incubating the photographic material at 40.degree. C.Type: GrantFiled: October 26, 1992Date of Patent: April 12, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Yutaka Tamura, Yasuyuki Takagi, Junichi Yamanouchi
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Patent number: 5288598Abstract: Photographic elements containing at least one layer containing polymeric particles surrounded by a layer of colloidal inorganic particles and separate particles of colloidal silica.Type: GrantFiled: October 30, 1992Date of Patent: February 22, 1994Assignee: Eastman Kodak CompanyInventors: Melvin D. Sterman, Alfred B. Fant, Melvin M. Kestner, Dennis E. Smith, Gary W. Visconte
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Patent number: 5284733Abstract: A silver halide photographic material is disclosed. The photographic material comprises a support having coated thereon one or more hydrophilic colloidal layers, at least one of the hydrophilic colloidal layers being a negative working silver halide emulsion layer, wherein said silver halide emulsion layer or another hydrophilic colloidal layer contains a water-soluble polymer or copolymer having a quaternary ammonium salt in a repeating unit. The process for forming a high contrast negative image using the photographic material is also disclosed.Type: GrantFiled: October 1, 1991Date of Patent: February 8, 1994Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Yasuhiko Kojima, Naoki Obi, Yasuo Shigemitsu, Kiyoshi Suematsu
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Patent number: 5279931Abstract: This invention describes a process of coprecipitating a photographic material such as a dye-forming coupler inside a base ionizable polymeric particle. Preparation of such a dispersion is performed by providing a first flow comprising a solution of a surfactant in water containing a polymer ionizable by base, providing a second flow comprising a water miscible solvent, base, water, and the photographic material, then mixing the said first and said second flow and immediately neutralizing the mixed flow to precipitate the photographic material inside the polymer particles forming a fine particle colloidal dispersion of the photographic material. The polymer dispersions of the invention are characterized by high photographic activity and high dye-stability in some cases.Type: GrantFiled: April 26, 1991Date of Patent: January 18, 1994Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, Steven J. Sargeant, James T. Beck, Brian Thomas
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Patent number: 5275931Abstract: A silver halide light-sensitive material containing at least silver halide grains, a dispersion medium, an antifoggant, and a hardening agent, wherein said antifoggant is an antifoggant having a reactive substituent capable of reacting with a functional group of the dispersion medium to form a covalent bond after adsorption on the silver halide grains and/or an antifoggant previously covalently bonded to the dispersion medium. The antifoggant is immobilized in a light-sensitive material while exerting its antifogging activity and is not therefore dissolved into a developing solution.Type: GrantFiled: November 24, 1992Date of Patent: January 4, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsuo Saitou, Hisashi Okamura, Tadashi Ikeda
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Patent number: 5270160Abstract: A polyester film comprising a polyester whose dicarboxylic acid copolymerized component contains (i) an aromatic dicarboxylic acid having a metal sulfonate and/or a derivative thereof and (ii) a polyetherdicarboxylic acid represented by the following chemical formula (a) and having a mean molecular weight in the range of 600 to 20000 and/or a derivative thereof.R.sup.1 OOCCH.sub.2 --(O--R.sup.2).sub.n --OCH.sub.2 COOR.sup.3(a)Where, "R.sup.1 " and "R.sup.3 " are alkyl groups each having a carbon number of 1 to 8, "R.sup.2 " is alkylene group having a carbon number of 2 to 8 and "n" is a positive integer. The polyester film has excellent transparency, mechanical properties and dimensional stability such as those of a PET film and an excellent water absorption property such as that of a TAC film.Type: GrantFiled: December 23, 1992Date of Patent: December 14, 1993Assignee: Toray Industries, Inc.Inventors: Toshihiko Hiraoka, Kenji Tsunashima, Masaru Suzuki, Takashi Mimura, Hirokazu Kurome
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Patent number: 5268263Abstract: An improved coating composition is detailed which increases the range of differential pressure within which a photographic element can be coated on a slide bead coating apparatus. The improved composition comprises a novel combination of the polymer shown in Formula 1 and the surfactant shown in Formula 2. The substituents are described.Type: GrantFiled: February 22, 1993Date of Patent: December 7, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventors: Jose E. Valentini, Jose M. Rodriguez-Parada
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Patent number: 5264317Abstract: The invention creates a selective oxygen barrier around individual coupler or other photographically active particles by surrounding each particle with a layer of water applicable oxygen barrier polymer such as polyvinyl alcohol (PVA), which will also act as a steric barrier to coalescence of the particles. Photographic products formed with such materials are more dye stable.Type: GrantFiled: November 12, 1992Date of Patent: November 23, 1993Assignee: Eastman Kodak CompanyInventors: Pranab Bagchi, James L. Edwards, Wendell F. Smith, Jr., Brian Thomas
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Patent number: 5264338Abstract: A method of preparing a superfine grain emulsion with a grain size of 0.05 .mu.m or less is provided, which includes mixing aqueous solutions of a water-soluble silver salt and a water-soluble halide with vigorous stirring inside a closed mixing device furnished with an agitator, where the solutions are fed into the device simultaneously and continuously, in the presence of at least one of a high molecular compound and a substance capable of adsorbing to silver halide, each of which has a physical retardance value of at least 40 as determined by PAGI method, and immediately expelling the newly-formed grains from the mixing device. Another method includes mixing the aqueous solutions in a mixing device as described above, immediately expelling the newly-formed grains from the device, and mixing the expelled grains with at least one of the above-described high molecular compound and substance.Type: GrantFiled: September 30, 1992Date of Patent: November 23, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeharu Urabe, Shunichi Aida
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Patent number: 5264334Abstract: Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating and in which a polyalkoxysilane is incorporated in the imaging composition to provide enhanced adhesion are protected against undesirable width-wise curling by interposing a barrier layer between the support and the image-forming layer. The barrier layer, which is composed of poly(silicic acid) and a water-soluble hydroxyl-containing monomer or polymer that is compatible therewith prevents migration from the image-forming layer to the support of by-products of hydrolysis of the polyalkoxysilane which can cause width-wise curl and consequent jamming of processing equipment.Type: GrantFiled: February 22, 1993Date of Patent: November 23, 1993Assignee: Eastman Kodak CompanyInventors: Woiciech M. Przezdziecki, Jean Z. DeRuyter
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Patent number: 5256527Abstract: The invention provides stable dispersions of couplers and methods of their formation. The stable dispersions are formed by the use of a nonionic water soluble polymer in combination with an anionic surfactant having a sulfate or sulfonate head group and a hydrophobic group of 8 to 20 carbons. The preferred nonionic water soluble polymers are polyethyleneoxide and polyvinylpyrrolidene. It is preferred that the dispersions have a pH of between about 5 and 5.5.Type: GrantFiled: September 9, 1991Date of Patent: October 26, 1993Assignee: Eastman Kodak CompanyInventors: Krishnan Chari, James T. Beck
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Patent number: 5242787Abstract: Disclosed is silver halide photographic photosensitive material comprising a support, having thereon at least one silver halide photosensitive emulsion layer, wherein a polymer which can be represented by the following general formula (I) is included in at least one of the structural layers of the photographic photosensitive material: ##STR1## The term A represents a repeating unit obtained by polymerizing a monomer which has at least two polymerizable ethylenically unsaturated groups of which at least one is in a side chain; B represents a repeating monomer unit obtained by the polymerization of a monomer which has one polymerizable ethylenically unsaturated group; R.sup.1 represents a hydrogen atom or an alkyl group; R.sup.2 and R.sup.3 each represents a hydrogen atom or a methyl group; R.sup.4 represents a hydrogen atom or an organic group; L.sub.Type: GrantFiled: October 28, 1991Date of Patent: September 7, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Tomokazu Yasuda, Shunichi Aida
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Patent number: 5238795Abstract: A light-sensitive silver halide photographic material is disclosed. The light-sensitive material comprises a support and two photographic layers each being provided on both sides, side A and side B, of the support and comprising a silver halide emulsion layer and a hydrophilic colloid layer wherein the light-sensitive material satisfies the relationship between sensitivities sA, sB and sA' thereof represented by the following expressions I and II, and an organic substance remained in the photographic layers after processing is an amount of not more than 90% by weight of the organic substance contained in the photographic layers before processing of the light-sensitive material;I: sA/sA'>4.0II: sA/sB=1.Type: GrantFiled: July 26, 1991Date of Patent: August 24, 1993Assignee: Konica CorporationInventor: Iku Metoki
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Patent number: 5234807Abstract: The polymerization and copolymerization of photographically useful vinyl monomers can be effected by dissolving such monomers in an isotropic oil-in-water microemulsion or in an isotropic water-in-oil microemulsion, each comprising monomers or comonomers, surfactants and/or cosurfactants, water, and optionally electrolytes. The microemulsion may be characterized as transparent or nearly transparent to the eye at 1% (w/w) or greater monomer, ultrafine in particle (droplet) size (typically in the range of 30 to 900 .ANG. in diameter), and spontaneously formed upon combining all the components with moderate stirring. The polymerization process is subsequently initiated with free radical initiators or with ultraviolet light. The components are chosen so that photographically useful polymers or photographically useful latexes are obtained, and said polymers or latexes may be coated in a photographic element.Type: GrantFiled: November 21, 1991Date of Patent: August 10, 1993Assignee: Eastman Kodak CompanyInventors: John Texter, Tienteh Chen, Edward Schofield
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Patent number: 5229250Abstract: Amphoteric polymers prepared by polymerization of (a) acrylic acid, (b) N,N-dimethyl- or N,N-diethylaminoethyl methacrylate and, optionally, (c) esters of methacrylic or acrylic acid prepared by (i) emulsion polymerization of (b), (c) and the methyl ester of (a), followed by basic hydrolysis, or (ii) polymerization of (a), (b) and (c) in the presence of a strong acid, and photographic emulsions comprised of said polymers in which the molar ratio of (a) to (b) is at least 2 to 1 and a silver halide.Type: GrantFiled: August 16, 1991Date of Patent: July 20, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventor: Robert P. Foss
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Patent number: 5215879Abstract: A silver halide photographic emulsion containing silver halide twinned-crystal grains is prepared by the steps of (a) forming silver halide nuclear grains by mixing a water soluble silver salt and a water soluble halide, (b) forming silver halide seed-emulsion grains by carrying out ripening of the nuclear grains formed in (a), and (c) growing the seed-emulsion grains, wherein a water soluble polymer is introduced by (b), having the repetition unit represented by the following formula [P] in an amount of 10 to 100 mol % per each polymer molecule: ##STR1##Type: GrantFiled: February 10, 1992Date of Patent: June 1, 1993Assignee: Konica CorporationInventors: Tetuya Suzuki, Shin-ichi Yamamoto, Harumi Asakawa, Toshihiko Yagi, Noriki Tachibana
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Patent number: 5213959Abstract: A silver halide light-sensitive material containing at least silver halide grains, a dispersion medium, an antifoggant, and a hardening agent, wherein said antifoggant is an antifoggant having a reactive substituent capable of reacting with a functional group of the dispersion medium to form a covalent bond after adsorption on the silver halide grains and/or an antifoggant previously covalently bonded to the dispersion medium. The antifoggant is immobilized in a light-sensitive material while exerting its antifogging activity and is not therefore dissolved into a developing solution.Type: GrantFiled: June 20, 1991Date of Patent: May 25, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsuo Saitou, Hisashi Okamura, Tadashi Ikeda