Product Having Overlayer On Radiation-conductive Layer Patents (Class 430/66)
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Patent number: 8574798Abstract: The present invention provides an electrophotographic photoreceptor having at least a photosensitive layer and a surface layer provided at a surface of the photosensitive layer. The surface layer contains a first layer which is provided at the photosensitive layer side and has a refractive index of n1 and a second layer which is provided at the opposite side of the first layer to the photosensitive layer and has a refractive index of n2. The refractive index of the photosensitive layer, the refractive index of the first layer, the refractive index of the second layer, the film thickness of the first layer, an integer of 0 or more, and the wavelength of light with which the surface of the photoreceptor is irradiated when an electrostatic latent image is formed satisfy specific relationships.Type: GrantFiled: August 3, 2009Date of Patent: November 5, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Takeshi Iwanaga, Masayuki Nishikawa, Shigeru Yagi, Nobuyuki Torigoe
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Patent number: 8574799Abstract: This invention provides an electrophotographic photoreceptor having improved resistance to soiling by a human body-derived substance and a high image stability. The electrophotographic photoreceptor comprises an electroconductie substrate and a photosensitive layer provided on the substrate and is characterized in that the photosensitive layer contains, as a binder resin, a polycarbonate resin comprising constituent units represented by the following formula (A) and the following formula (B), wherein R1 to R4 represent a hydrogen atom, a methyl group or the like; and X represents an alkylene group or the like. 3 to 50% by weight of the total constituent units is accounted for by the constituent units of formula (A) and the intrinsic viscosity is 0.3 to 2 dl/g. [Chemical formula 1] (A)(B).Type: GrantFiled: May 16, 2007Date of Patent: November 5, 2013Assignee: Mitsubishi Gas Chemical Company, Inc.Inventor: Takahiro Adachi
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Publication number: 20130280647Abstract: This application discloses a photoreceptor comprising a surface layer that is comprised of an organic composition cured by neutral molecular hydrogen bombardment. Methods for forming a photoreceptor having a cured surface are disclosed.Type: ApplicationFiled: April 24, 2012Publication date: October 24, 2013Applicant: Xerox CorporationInventors: Yu LIU, Yiliang Wu, Nan-Xing Hu, Gregory M. McGuire, Richard A. Klenkler, Vladislav Skorokhod, Johann Junginger
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Patent number: 8557487Abstract: To provide an electrophotographic photoconductor including: a conductive substrate; a photosensitive layer; and a surface layer having grooves which do not intersect each other, the photosensitive layer and the surface layer being laid over the conductive substrate, wherein the grooves each have a width of 60 ?m to 100 ?m and a depth of 0.2 ?m to 2 ?m, wherein the standard deviation of the depths of the grooves is 1/10 or less of the average value of the depths of the grooves measured at any four places, and wherein the grooves are formed in a direction which diagonally crosses a main scanning direction and a sub-scanning direction of the electrophotographic photoconductor.Type: GrantFiled: September 28, 2010Date of Patent: October 15, 2013Assignee: Ricoh Company, Ltd.Inventors: Hidetoshi Kami, Kazuhiro Egawa
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Patent number: 8557488Abstract: An electrophotographic photosensitive member includes a support and a photosensitive layer. The electrophotographic photosensitive member includes a surface layer that contains a polymer produced by the polymerization of a compound having a chain-polymerizable functional group. The compound having a chain-polymerizable functional group is a compound represented by the following formula (1).Type: GrantFiled: May 22, 2012Date of Patent: October 15, 2013Assignee: Canon Kabushiki KaishaInventors: Hideaki Nagasaka, Masaki Nonaka, Masato Tanaka
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Patent number: 8557486Abstract: An organic photoreceptor having a photosensitive layer, an electric conductive support, and a protective layer is disclosed, in which the protective layer comprises a composition produced by reacting tin oxide particles an acryloyl or methacryloyl group on their surface with a compound having an acryloyl or methacryloyl group. A production method of the same, an image forming apparatus and a process cartridge using the same are also disclosed.Type: GrantFiled: November 18, 2009Date of Patent: October 15, 2013Assignee: Konica Minolta Business Technologies, Inc.Inventors: Takeshi Ishida, Hirofumi Hayata, Masahiko Kurachi, Toshiyuki Fujita, Seisuke Maeda, Seijiro Takahashi
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Patent number: 8546052Abstract: An electrophotographic photosensitive member having a surface layer containing a polymeric product obtained by polymerizing a specific adamantane compound, a process cartridge and an electrophotographic apparatus which have the electrophotographic photosensitive member, and a process for producing the electrophotographic photosensitive member.Type: GrantFiled: May 6, 2011Date of Patent: October 1, 2013Assignee: Canon Kabushiki KaishaInventors: Masaki Nonaka, Masato Tanaka
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Publication number: 20130252152Abstract: An electrophotographic photoreceptor includes a substrate and a photosensitive layer, wherein the electrophotographic photoreceptor has a surface layer containing fluorine resin particles, and the fluorine resin particles exposed on a surface satisfy the following Expression (1): 0.5?(A)/(B)??10??Expression (1) wherein, (A) represents a number of aggregated particles in which 5 to 20 fluorine resin particles are connected and aggregated, and (B) represents a total number of fluorine resin particles that are isolated without being aggregated and aggregated particles in which 2 to 4 fluorine resin particles are connected and aggregated.Type: ApplicationFiled: September 28, 2012Publication date: September 26, 2013Applicant: FUJI XEROX CO., LTD.Inventor: Yukimi KAWABATA
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Publication number: 20130252151Abstract: An electrophotographic photoreceptor includes a substrate; a photosensitive layer that is provided on the substrate; and a surface layer that is provided on the photosensitive layer, contains fluororesin particles, is a single layer having a thickness of 3 ?m or greater, and has a cross-section, taken along a thickness direction thereof, which satisfies specific expressions.Type: ApplicationFiled: September 21, 2012Publication date: September 26, 2013Applicant: FUJI XEROX CO., LTD.Inventor: Shinya YAMAMOTO
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Patent number: 8541151Abstract: The presently disclosed embodiments relate in general to electrophotographic imaging members which include a protective overcoat layer comprising specific low surface energy polycarbonates of excellent optical clarity and having a slippery and adhesive surface to impact toner image transfer efficiency to receiving papers and effect contact friction reduction by which imaging members abrasion/wear resistance is enhanced. The present embodiments also disclose a process for making and using these members.Type: GrantFiled: April 19, 2010Date of Patent: September 24, 2013Assignee: Xerox CorporationInventor: Robert C. U. Yu
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Publication number: 20130243483Abstract: In a photoreceptor including an electroconductive substrate; a photosensitive layer; and a protective layer, the protective layer includes a crosslinked resin having a residual group of a polycarboxylic acid compound and a group having the below-mentioned formula (10), and at least one of a compound having the below-mentioned formula (2) and a compound having the below-mentioned formula (3). wherein each of R5 and R6 independently represents a hydrogen atom, or a substituted or unsubstituted alkyl group having 1 to 3 carbon atoms. wherein each of R7 and R8 independently represents a hydrogen atom, or an alkyl group having 1 to 4 carbon atoms, and Z1 represents a vinylene group, a divalent aromatic hydrocarbon group having 6 to 14 carbon atoms, or a 2,5-thiophenediyl group.Type: ApplicationFiled: February 20, 2013Publication date: September 19, 2013Inventors: Mitsuaki HIROSE, Akihiro Sugino, Noboru Toriu, Keisuke Shimoyama, Tomoharu Asano
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Patent number: 8535862Abstract: An electrophotographic photoreceptor including a conductive substrate, a photosensitive layer located overlying the conductive substrate, and a hardened protective layer located overlying the photosensitive layer. The hardened protective layer comprises a hardened material of a hardenable composition comprising a radical-polymerizable compound (A) having a charge transport structure and a radical-polymerizable compound (B) having an adamantane skeleton.Type: GrantFiled: June 6, 2011Date of Patent: September 17, 2013Assignee: Ricoh Company, Ltd.Inventors: Takafumi Iwamoto, Naohiro Toda
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Patent number: 8535861Abstract: There is provided an image forming apparatus including electrophotographic photoreceptor, a charging unit, an electrostatic latent image forming unit, a developing unit, and a residual toner removing unit, the surface protective layer of the electrophotographic photoreceptor having a surface free energy of about 10 mN/m to about 30 mN/m, the toner in the developing unit includes silica, and the residual toner removing unit including a blade member including a base layer and an edge layer having a type A durometer hardness of from about HsA 75 to about HsA 90 at 23° C., the hardness of the edge layer being higher than the hardness of the base layer.Type: GrantFiled: September 9, 2009Date of Patent: September 17, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Daisuke Haruyama, Masahiro Iwasaki, Takayuki Yamashita
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Patent number: 8535863Abstract: A photoreceptor including an electroconductive substrate; a photosensitive layer located overlying the electroconductive substrate; and a crosslinked outermost layer located overlying the photosensitive layer and including a crosslinked material and a specific carbazole compound serving as a charge transport material. An image forming apparatus including the photoreceptor; a charger to charge the photoreceptor; an irradiator to irradiate the charged photoreceptor to form an electrostatic latent image thereon; a developing device to develop the electrostatic latent image with a developer including a toner to form a toner image on the photoreceptor; and a transferring device to transfer the toner image onto a recording material.Type: GrantFiled: August 11, 2011Date of Patent: September 17, 2013Assignee: Ricoh Company, Ltd.Inventors: Tomoharu Asano, Hiroshi Ikuno, Yasuhito Kuboshima, Yuuji Tanaka
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Patent number: 8524428Abstract: An electrophotographic photoreceptor includes: a conductive substrate; a photosensitive layer including a charge-generating layer containing a charge-generating material and a charge-transporting layer containing a charge-transporting material, the charge-transporting layer having a hole mobility of about 5.0×10?6 (cm2/V·sec) or less at an electric field of 2 V/cm; and an overcoat layer that is provided on the photosensitive layer and contains a cured material of a charge-transporting material, wherein relational expression (1) Ip(OCL)>Ip(CTL)>Ip(CGL) is satisfied wherein Ip(CGL) represents an ionization potential (eV) of the charge-generating material contained in the charge-generating layer; Ip(CTL) represents an ionization potential (eV) of the charge-transporting material contained in the charge-transporting layer; and Ip(OCL) represents an ionization potential (eV) of the charge-transporting material contained in the overcoat layer.Type: GrantFiled: September 3, 2010Date of Patent: September 3, 2013Assignee: Fuji Xerox Co., Ltd.Inventor: Hirofumi Nakamura
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Patent number: 8524433Abstract: An electrophotographic photoconductor includes a conductive substrate and an outermost surface layer formed on the conductive substrate and containing a binder resin and a copolymer derived from a reactive monomer having charge transport property and a reactive monomer having no charge transport property, the copolymer having a side chain with 4 or more carbon atoms in a constitutional unit derived from the reactive monomer having no charge transport property.Type: GrantFiled: November 2, 2010Date of Patent: September 3, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Takatsugu Doi, Wataru Yamada, Yuko Iwadate, Katsumi Nukada
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Patent number: 8524432Abstract: An electrophotographic photoreceptor includes a conductive substrate, and at least a photosensitive layer on the conductive substrate, a layer located at a surface of the photosensitive layer side of the electrophotographic photoreceptor contains fluorine containing resin particles and a fluoro graft polymer having a fluoroalkyl group having 1 to 7 carbon atoms, and an area for a polystyrene equivalent molecular weight of 700,000 or more is from about 5% to about 20% of the total area in a gel permeation chromatography (GPC) chart for the fluoro graft polymer.Type: GrantFiled: September 29, 2009Date of Patent: September 3, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Hidemi Nukada, Masaru Miura, Shinya Yamamoto, Isamu Ishiko, Tetsuya Ezumi
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Patent number: 8518617Abstract: The present invention provides an electrophotographic photoreceptor including at least an electroconductive substrate and a photosensitive layer provided on or above the electroconductive substrate, wherein an outermost layer of the electrophotographic photoreceptor is a layer composed of a cured film of a composition including at least one of compound having a chain-polymerizable functional group and a charge-transportable backbone in the molecule thereof, a polymerization initiator and a radical deactivator.Type: GrantFiled: September 8, 2010Date of Patent: August 27, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Tsuyoshi Miyamoto, Wataru Yamada, Takatsugu Doi, Kenya Sonobe, Katsumi Nukada
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Patent number: 8518618Abstract: To provide an electrophotographic photoconductor, containing: a conductive support; a photosensitive layer provided above the conductive support; and a hardened protective layer provided above the photosensitive layer, wherein the hardened protective layer contains a hardened product of a radical polymerizable compound containing an adamantane skeleton.Type: GrantFiled: June 29, 2011Date of Patent: August 27, 2013Assignee: Ricoh Company, Ltd.Inventors: Takafumi Iwamoto, Naohiro Toda, Yoshitaka Uenoyama, Hidetoshi Ono
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Patent number: 8512924Abstract: An electrophotographic photoreceptor, including an electroconductive substrate; a photosensitive layer; a crosslinked surface layer comprising ?-alumina and tin oxide, wherein a first one-dimensional data array obtained from measuring a concavo-convex shape of the surface of the photoreceptor is subjected to a wavelet conversion to be separated into 6 frequency components, the one-dimensional data array of the lowest frequency component is further thinned so as to have 1/40 data arrays to obtain a second one-dimensional data array, the second one-dimensional data array is further subjected to the wavelet conversion to be separated into additional 6 frequency components, and wherein when relationships between respective arithmetic average roughness (WRa) (y-axis) of the 12 frequency components and the frequency components (x-axis) are graphed, at least WRa (214 to 551 ?m) and WRa (26 to 106 ?m) have a folding point or a maximum point.Type: GrantFiled: February 2, 2011Date of Patent: August 20, 2013Assignee: Ricoh Company, Ltd.Inventors: Hidetoshi Kami, Kazuhiro Egawa, Yukio Fujiwara
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Patent number: 8512923Abstract: An electrophotographic photosensitive member is disclosed which has a change layer consisting of five or more a-SiC intermediate layers, provided between an a-Si photoconductive layer and an a-SiC surface layer. Where two layers contiguous to each other in which C/(Si+C) is from 0.35 to 0.65 are selected from among the a-SiC intermediate layers included in the change layer, the rate of increase between the C/(Si+C) of an a-SiC intermediate layer on the photoconductive layer side and the C/(Si+C) of an a-SiC intermediate layer on the surface layer side (i.e., the rate of increase between layers) is 19% or less.Type: GrantFiled: April 15, 2010Date of Patent: August 20, 2013Assignee: Canon Kabushiki KaishaInventors: Kazuto Hosoi, Jun Ohira
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Patent number: 8507163Abstract: A method of manufacturing an image bearing member including forming a charge generation layer overlying an electroconductive substrate, forming a charge transport layer overlying the charge generation layer, the charge transport layer including a charge transport material having a molecular weight of from 600 to 900 and a binder resin, and forming a protection layer overlying the charge transport layer by applying a liquid application containing a polymerizable compound having a charge transport structure, a polymerizable compound having no charge transport structure, a filler, a polycarboxylic acid compound, and cyclopentanone and curing the polymerizable compound having a charge transport structure, and the polymerizable compound having no charge transport structure.Type: GrantFiled: December 11, 2009Date of Patent: August 13, 2013Assignee: Ricoh Company, Ltd.Inventors: Nozomu Tamoto, Hideo Nakamori, Mitsuaki Hirose
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Patent number: 8507161Abstract: A photoconductor containing an optional supporting substrate layer, a photogenerating layer, a charge transport layer, and a top overcoat layer of a phenolic compound, a phosphite compound, an optional charge transport compound, an optional melamine resin, an optional acrylated polyol, and an optional catalyst.Type: GrantFiled: July 15, 2011Date of Patent: August 13, 2013Assignee: Xerox CorporationInventors: Jin Wu, Kenny-Tuan T. Dinh, Terry L. Street, Robert W. Hedrick, Linda L. Ferrarese, Brian P. Gilmartin
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Patent number: 8492059Abstract: An electrophotographic photoreceptor, includes: a conductive support; and a photosensitive layer provided on or above the conductive support, the photosensitive layer including an outermost surface layer at the farthest location from the conductive support, wherein the outermost surface layer contains: coated insulating inorganic particles obtained by subjecting insulating inorganic particles having a specific surface area of not more than about 300 m2/g to a coating treatment with an aromatic functional group-containing compound; and fluorine-containing organic particles.Type: GrantFiled: October 20, 2009Date of Patent: July 23, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Shigeto Hashiba, Kazuhiro Koseki, Kaori Iemura, Kenta Ide, Satoya Sugiura, Fuyuki Kano, Kazuyuki Nakamura
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Patent number: 8486595Abstract: An image bearing member including an electroconductive substrate, a photosensitive layer overlying the electroconductive substrate, and a protection layer overlying the photosensitive layer, the photosensitive layer containing a diamine compound represented by the chemical structure 1, more of the diamine compound being disposed on the photosensitive layer side than the surface side relative to the midpoint in a depth direction of the protection layer: where X represents a substituted or non-substituted arylene group, or a compound represented by a chemical structure 2: where R represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms, where A1, A2, A3, and A4 independently represent an alkyl group having 1 to 4 carbon atoms, a substituted or non-substituted aryl group, or —CH2(CH2)mZ, where Z represents a substituted or non-substituted aryl group, a substituted or non-substituted cycloalkyl group, and a substituted or non-substitutedType: GrantFiled: September 10, 2010Date of Patent: July 16, 2013Assignee: Ricoh Company, Ltd.Inventors: Nozomu Tamoto, Mitsuaki Hirose, Hideo Nakamori
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Patent number: 8481237Abstract: A photoconductor containing a photogenerating layer, and at least one charge transport layer, and an overcoat layer in contact with, and contiguous to the charge transport layer. The overcoat layer is comprised polyethylene-block-polyethylene glycol copolymer and a charge transport component.Type: GrantFiled: January 24, 2011Date of Patent: July 9, 2013Assignee: Xerox CorporationInventors: Jin Wu, Kenny-tuan T. Dinh, Lanhui Zhang, Marc J. Livecchi, Edward C. Savage, Lin Ma, David M. Skinner, Linda L. Ferrarese
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Patent number: 8481234Abstract: An image bearing member including an electroconductive substrate, a photosensitive layer provided overlying the electroconductive substrate, and a furan derivative represented by the following chemical structure 1, where Ar1 and Ar2 independently represent substituted or non-substituted aryl groups and R1 represents an alkylene group having one to six carbon atoms.Type: GrantFiled: September 7, 2011Date of Patent: July 9, 2013Assignee: Ricoh Company, Ltd.Inventors: Hongguo Li, Kazukiyo Nagai, Yoshiaki Kawasaki
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Patent number: 8475983Abstract: The presently disclosed embodiments are directed to imaging members used in electrostatography. More particularly, the embodiments pertain to electrophotographic imaging members which have an added-on protective overcoat layer formulated to comprise of a novel A-B diblock copolymer comprising two segmental blocks of a bisphenol polycarbonate and an organic acid terminal which provides chemical vapor contaminant resistive property. The overcoat layer may further be formulated to include small quantity of charge transport compound. The present embodiments provide superior copy printout quality.Type: GrantFiled: June 30, 2010Date of Patent: July 2, 2013Assignee: Xerox CorporationInventors: Robert C. U. Yu, Yuhua Tong
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Patent number: 8465892Abstract: Embodiments provide novel imaging members used in electrostatography. More particularly, there is provided flexible electrophotographic imaging members which exhibit an extended functional life. These imaging members include an improved protective overcoat layer comprising: (1) a polymer blend of a low surface energy copolymer and a chemically resistive copolymer, (2) a chemically resistive copolymer and a slip agent, and (3) a chemically resistive copolymer and the dispersion of a low surface energy Polyhedral Oligomeric Silsesquioxane (POSS) nanoparticles to effect surface contact friction reduction for enhancing wear resistance and for suppressing copy printout defect caused by chemical attack.Type: GrantFiled: March 18, 2011Date of Patent: June 18, 2013Assignee: Xerox CorporationInventor: Robert C. U. Yu
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Patent number: 8465891Abstract: An electrophotographic photosensitive member includes a photoconductive layer, an intermediate layer, and a surface layer. When Si+C atom density in the surface layer is represented by DS×1022 atoms/cm3, the DS is 6.60 or more, and when the maximal value of H/(Si+H) in a distribution of hydrogen quantity in the photoconductive layer in a layer thickness direction is represented by HPmax, the average value of the H/(Si+H) in the second photoconductive region is represented by HP2, the DS and the HP2 satisfy the following expression (1) and the DS and the HPmax satisfy the following expression (2). HP2?0.07×DS?0.38??Expression (1) HPmax?0.04×DS+0.Type: GrantFiled: November 11, 2010Date of Patent: June 18, 2013Assignee: Canon Kabushiki KaishaInventors: Tomohito Ozawa, Kazuyoshi Akiyama, Yuu Nishimura, Daisuke Tazawa
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Patent number: 8460452Abstract: An oxide material including gallium, zinc and oxygen, a ratio of the number of atoms of zinc to the number of atoms of gallium (number of atoms of zinc/number of atoms of gallium) being from about 0.01 to about 0.6 and a ratio of the number of atoms of oxygen to the sum of the number of atoms of gallium and the number of atoms of zinc (number of atoms of oxygen/(number of atoms of gallium+number of atoms of zinc)) being from about 1.0 to about 1.6, is disclosed. An electrophotographic photoreceptor including a layer which includes the oxide material is also disclosed. An electrophotographic photoreceptor including a substrate; and a photosensitive layer including gallium, oxygen and zinc is also disclosed.Type: GrantFiled: April 26, 2010Date of Patent: June 11, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Shigeru Yagi, Takeshi Iwanaga
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Patent number: 8455163Abstract: The present invention provides an electrophotographic photosensitive member including a conductive substrate, a photoconductive layer on the conductive substrate, and a surface layer made of hydrogenated amorphous silicon carbide on the photoconductive layer. A ratio (C/(Si+C)) in the surface layer is 0.61 to 0.75, both inclusive, an Si+C atom density in the surface layer is 6.60×1022 atoms/cm3 or more, and an arithmetic average roughness Ra of the surface layer is 0.029 ?m to 0.500 ?m, both inclusive.Type: GrantFiled: November 22, 2010Date of Patent: June 4, 2013Assignee: Canon Kabushiki KaishaInventors: Makoto Aoki, Hironori Owaki, Kazunari Ooyama
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Patent number: 8457528Abstract: An electrophotographic apparatus is provided including an electrophotographic photosensitive member which includes a surface protective layer; and an exposure device which irradiates a surface of the electrophotographic photosensitive member with an exposure beam so as to form an electrostatic latent image on the surface of the electrophotographic photosensitive member, wherein the surface protective layer includes a material having no structure to provide charge transporting performance and has a plurality of through holes penetrating from the side of the front surface of the surface protective layer to the side of the charge transport layer, and the thickness of the surface protective layer is from 0.1 ?m or more to 1.5 ?m or less, and wherein when the surface of the electrophotographic photosensitive member is irradiated with the exposure beam, two or more of the through holes are included in an exposure beam spot.Type: GrantFiled: August 27, 2010Date of Patent: June 4, 2013Assignee: Canon Kabushiki KaishaInventors: Atsushi Ochi, Harunobu Ogaki, Hiroki Uematsu, Yasuhiro Kawai, Koji Takahashi, Shio Murai
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Patent number: 8450036Abstract: An electrophotographic photoreceptor containing fluororesin particles in which the cross-section obtained by cutting a surface layer along the thickness direction satisfies the following (1) and (2): 0?A1?0.5×A2??(1): 0.7×A3?A2?1.2×A3??(2): wherein A1 represents the proportion (%) of the area of the fluororesin particles occupying a region designated as a first region; A2 represents the proportion (%) of the area of the fluororesin particles occupying a region designated as a second region; and A3 represents the proportion (%) of the area of the fluororesin particles occupying the entire cross-section with respect to the entire area of the cross-section.Type: GrantFiled: September 28, 2011Date of Patent: May 28, 2013Assignee: Fuji Xerox Co., Ltd.Inventor: Shinya Yamamoto
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Patent number: 8450037Abstract: A method for making a photoconductor for electrophotography can comprise depositing a charge generating layer on an electrode; depositing a charge transfer layer on the charge generating layer, where a plurality of charge transfer molecules are disposed within the charge transfer layer; depositing a film of non-conducting material onto the surface of the charge-transfer layer; heating the film and the surface to cause a subset of the charge transfer molecules to move into the non-conducting material, creating in the film a conducting sub-layer and an insulating sub-layer, where the insulating sub-layer is substantially free of charge transfer molecules.Type: GrantFiled: March 12, 2009Date of Patent: May 28, 2013Assignee: Hewlett-Packard Development Company, L.P.Inventors: Krzysztof Nauka, Xia Sheng, Hou T. Ng
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Patent number: 8445168Abstract: The present invention provides an electrophotographic photosensitive member including a photoconductive layer, an intermediate layer made of hydrogenated amorphous silicon carbide on the photoconductive layer, and a surface layer made of hydrogenated amorphous silicon carbide on the intermediate layer, wherein a ratio (C/(Si+C); C2) in the surface layer is 0.61 to 0.75, and a sum of atom density of silicon and carbon is 6.60×1022 atoms/cm3 or more, a ratio (C/(Si+C); C1) and a sum (D1) of atom density of silicon and carbon in the intermediate layer increase continuously from the photoconductive layer toward the surface layer without exceeding C2 and D2, and the intermediate layer has a continuous region in which C1 is 0.25 to C2 while D1 is 5.50×1022 to 6.45×1022 atoms/cm3, the region being 150 nm or larger in a layer thickness direction, and an electrophotographic apparatus equipped therewith.Type: GrantFiled: November 18, 2010Date of Patent: May 21, 2013Assignee: Canon Kabushiki KaishaInventors: Kazuyoshi Akiyama, Tomohito Ozawa, Daisuke Tazawa, Yuu Nishimura
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Patent number: 8440377Abstract: An electrophotographic photosensitive member includes a substrate, a photoconductive layer, an intermediate layer, and a surface layer sequentially formed. The intermediate layer contains silicon, carbon and hydrogen, and a distribution of a hydrogen ratio, which is a ratio of the number of hydrogen atoms to the number of silicon, carbon and hydrogen atoms, in the intermediate layer has a maximum region. A largest hydrogen atomic ratio in the intermediate layer is larger than a hydrogen atomic ratio in the surface layer, and the hydrogen atomic ratio in the surface layer is 0.30 to 0.45. A distribution of a carbon atomic ratio, which is a ratio of the number of carbon atoms to the number of silicon and carbon atoms, in the intermediate layer has a maximum and a minimum region. A carbon atomic ratio in the maximum region is 0.53 to 0.63, a carbon atomic ratio in the minimum region is 0.47 or more, and the maximum hydrogen region in the intermediate layer is partially superimposed on the minimum carbon region.Type: GrantFiled: November 18, 2010Date of Patent: May 14, 2013Assignee: Canon Kabushiki KaishaInventors: Tomohito Ozawa, Motoya Yamada, Kazuyoshi Akiyama, Daisuke Tazawa
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Patent number: 8420284Abstract: An electrophotographic photoreceptor, including an electroconductive substrate; a photosensitive layer, located overlying the electroconductive substrate; and an outermost layer comprising a convexity, wherein each of the outermost layer and the convexity includes a crosslinked body including a structural unit having a same charge transportable structure, and wherein the number of convexity having a height not less than ½×RzJIS is from 30 to 300 in a measurement length of 12 mm, wherein RzJIS is an average of ten-point mean roughness specified in JIS B0601 of 2001 and measured at least 4 random positions in an area the outermost layer is formed on, and wherein the height of the convexity is a distance from the deepest valley to a top of the convexity in the measurement length of 12 mm.Type: GrantFiled: December 18, 2009Date of Patent: April 16, 2013Assignee: Ricoh Company, Ltd.Inventors: Kohichi Ohshima, Hidetoshi Kami, Yukio Fujiwara, Kazuhiro Egawa
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Patent number: 8404416Abstract: The invention provides an electrophotographic photoreceptor having a surface protection layer that satisfies the following requirements: (1) including a crosslinked substance of at least one selected from a guanamine compound or a melamine compound, and at least one charge transporting material having at least one substituent selected from —OH, —OCH3, —NH2, —SH or —COOH; (2) including the at least one of a guanamine compound or a melamine compound in an amount of from about 0.1 to about 5% by weight; and (3) having a universal hardness of from about 180 to about 220 N/mm2 and a creep ratio of from about 5% to about 8%, the universal hardness and the creep ratio being obtained by performing a hardness test by pushing a Vickers quadrangular pyramid diamond indenter against the surface protection layer at a maximum load of 20 mN, in an environment of 25° C. and a relative humidity of 50%.Type: GrantFiled: November 30, 2009Date of Patent: March 26, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Daisuke Haruyama, Masahiro Iwasaki
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Patent number: 8404415Abstract: Disclosed is an electrophotographic photoreceptor including: an electroconductive substrate; a photosensitive layer arranged on or above the electroconductive substrate; and a surface layer arranged on or above the photosensitive layer, and containing about 90% or more by atom of gallium (Ga), oxygen (O) and hydrogen (H), and having an atomic number density of about 7.8×1022 cm?3 or more.Type: GrantFiled: August 18, 2009Date of Patent: March 26, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Takeshi Iwanaga, Shigeru Yagi, Nobuyuki Torigoe
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Patent number: 8404417Abstract: In the present invention, disclosed is an organic photoreceptor comprising a conductive support and provided thereon, a photosensitive layer and a protective layer provided on the photosensitive layer, the protective layer formed with alumina particles each comprising a reactive organic group. Also provided is an organic photoreceptor with which electrophotographic images having high durability together with high image quality can be obtained by improving a wear property of the organic photoreceptor up to the same level as that of an amorphous silicon photoreceptor, as well as by improving image flow and image blur which are easy to be generated at high temperature and high humidity.Type: GrantFiled: July 9, 2009Date of Patent: March 26, 2013Assignee: Konica Minolta Business Technologies, Inc.Inventors: Toshiyuki Fujita, Hirofumi Hayata, Takeshi Ishida, Masahiko Kurachi, Seisuke Maeda, Seijiro Takahashi
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Publication number: 20130059242Abstract: A photoreceptor including an electroconductive substrate; a photosensitive layer on the electroconductive substrate; and a protection layer on the photosensitive layer, wherein the protection layer includes a radical polymerizable compound having three or more radical polymerizable groups without a charge transportable group, a monofunctional radical polymerizable compound having a specific charge transportable group and a non-radical polymerizable compound having a specific charge transportable group.Type: ApplicationFiled: July 24, 2012Publication date: March 7, 2013Inventors: Tomoharu Asano, Hiroshi Ikuno, Akihiro Sugino, Hideo Nakamori, Mitsuaki Hirose
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Publication number: 20130052572Abstract: Provided is a compound represented by the following Formula (I): wherein in Formula (I), F represents a charge transporting skeleton, L represents a divalent linking group including a —(CH2)n—O— group, m represents an integer of from 1 to 8, and n represents an integer of from 3 to 6.Type: ApplicationFiled: March 5, 2012Publication date: February 28, 2013Applicant: FUJI XEROX CO., LTD.Inventors: Katsumi NUKADA, Wataru YAMADA, Tomoya SASAKI, Yuko IWADATE, Kenji KAJIWARA
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Publication number: 20130052577Abstract: A photoconductor that includes an optional anticurl layer, optional supporting substrate, an optional ground plane layer, an optional hole blocking layer, an optional ground strip segment, an optional adhesive layer, a photogenerating layer, and a charge transport layer that contains an acrylonitrile-butadiene-styrene polymer.Type: ApplicationFiled: August 22, 2011Publication date: February 28, 2013Applicant: XEROX CORPORATIONInventor: Jin WU
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Patent number: 8383305Abstract: An image forming apparatus including a latent image bearing member, a charging device, a latent electrostatic image formation device, a development device, a transfer device, and a lubricant supplying device, the latent image bearing member satisfying (I), (II) and (III): |(A1?B1)?(A2?B2)|?5.0??(I) B1?1 (atomic %)??(II) 1 (nm)?X?30 (nm)??(III), where, by XPS analysis, A1 and B1 represent oxygen and silicon atom content ratio in a cross-linked surface layer, respectively, A2 represents oxygen atom content ratio in a surface dug through a cross-linked surface layer along a direction perpendicular to the latent image bearing member surface, to an electroconductive substrate at depth point X where B1 decreases to not greater than B1×0.5, and B2 represents the silicone atom content ratio in the surface at X.Type: GrantFiled: July 23, 2010Date of Patent: February 26, 2013Assignee: Ricoh Company, Ltd.Inventors: Akihiro Sugino, Tomoharu Asano, Keisuke Shimoyama
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Patent number: 8377107Abstract: A method of forming a coating on a medical device having a controlled morphology is described. A medical device having a controlled morphology is described.Type: GrantFiled: February 28, 2011Date of Patent: February 19, 2013Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Lothar Walter Kleiner, Jessica Renee DesNoyer, Stephen Dirk Pacetti, Syed Faiyaz Ahmed Hossainy
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Patent number: 8377499Abstract: A method of forming a coating on a medical device having a controlled morphology is described.Type: GrantFiled: February 28, 2011Date of Patent: February 19, 2013Assignee: Abbott Cardiovascular Systems Inc.Inventors: Lothar Walter Kleiner, Jessica Renee DesNoyer, Stephen Dirk Pacetti, Syed Faiyaz Ahmed Hossainy, O. Mikael Trollsas, Michael Huy Ngo
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Patent number: 8372566Abstract: A imaging member, such as a photoreceptor, having an outermost layer that is a structured organic film (SOF) comprising a plurality of segments and a plurality of linkers including a first fluorinated segment and a second electroactive segment.Type: GrantFiled: September 27, 2011Date of Patent: February 12, 2013Assignee: Xerox CorporationInventors: Adrien P. Cote, Matthew A. Heuft
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Patent number: 8372568Abstract: The disclosed embodiments are directed to a method for removing photoreceptor coatings from a rigid substrate, wherein the photoreceptor coatings disposed over a substrate of an electrophotographic photoreceptor, in order to recover it for re-use in photoreceptor manufacturing. More specifically, the invention discloses a photoreceptor substrate recovery methodology that includes the creation of an inner release layer over the substrate and followed by subjecting the rejected or used electrophotographic photoreceptor to a step of soaking in a non-toxic and environmentally-friendly stripping solution that separates the coatings from the substrate.Type: GrantFiled: November 5, 2009Date of Patent: February 12, 2013Assignee: Xerox CorporationInventors: Robert C. U. Yu, Kent J. Evans, Yuhua Tong, Nancy L. Belknap, Helen R. Cherniack, Robert P. Altavela, Edward F. Grabowski
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Patent number: 8367285Abstract: Embodiments pertain to a novel imaging member, namely, an imaging member or photoreceptor comprising an overcoat layer which comprises light-absorbing material that improves print quality. The light-absorbing material reduces the intrinsic light shock suffered by conventional overcoat layers without negatively impacting electrical properties of the overcoat layer.Type: GrantFiled: November 6, 2009Date of Patent: February 5, 2013Assignee: Xerox CorporationInventors: Cuong Vong, Yvan Gagnon, Gregory McGuire