Additional Diverse Ring Hetero Atom In The Hetero Ring Patents (Class 430/77)
  • Patent number: 5707768
    Abstract: A diamine compound of the following formula (1): ##STR1## wherein R.sub.1 is a hydrogen atom, a lower alkyl group or a lower alkoxy group, each of A.sub.1, A.sub.2 and A.sub.3 which are independent of one another, is a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a group of the following formula (2): ##STR2## wherein R.sub.1 is as defined above, and X is a substituted or unsubstituted arylene group or a substituted or unsubstituted heterocyclic bivalent group.
    Type: Grant
    Filed: November 28, 1995
    Date of Patent: January 13, 1998
    Assignee: Hodogaya Chemical Co., Ltd.
    Inventors: Mitsutoshi Anzai, Atsushi Takesue, Takanobu Watanabe, Chieko Inayoshi
  • Patent number: 5639581
    Abstract: A charge transporting polymer represented by formula (I): ##STR1## wherein R represents a hydrogen atom, an alkyl group, an acyl group or --CONH--R' wherein R' represents an alkyl group or a substituted or unsubstituted aryl group; R.sub.1 and R.sub.2, which may be the same or different, each represent a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group, a halogen atom, or a substituted or unsubstituted aryl group; X represents a substituted or unsubstituted divalent aromatic group; y represents 0 or 1; m represents 0 or 1; n represents an integer of 1 to 5; and p represents an integer of 5 to 5000,a process for producing the same, and an organic electron device containing the same, such as an electrophotographic photoreceptor are disclosed. The charge transporting polymer is excellent in solubility, film-forming properties, mechanical strength, positive hole mobility, and stability to repeated use.
    Type: Grant
    Filed: October 17, 1995
    Date of Patent: June 17, 1997
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Masahiro Iwasaki, Akira Imai, Katsumi Nukada, Katsuhiro Sato
  • Patent number: 5622801
    Abstract: An electrophotographic photoreceptor comprising a conductive substrate having thereon a photosensitive layer, the photosensitive layer containing a hydroxymetal or hydroxysilicon phthalocyanine pigment represented by formula (I) as a charge generating material, the phthalocyanine pigment having been treated with an organometallic compound having a hydrolyzable functional group or a hydrolysis product thereof: ##STR1## wherein Me represents Al, Ga, In, Si, Ge or Sn; X represents H, Cl, Br or I; m represents an integer of from 1 to 4; and n represents 1 where Me is Al, Ga or In, or 2 where Me is Si, Ge or Sn.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: April 22, 1997
    Assignee: Fuji Xerox Co., Ltd
    Inventors: Hidemi Nukada, Takahiro Suzuki, Katsumi Nukada, Katsumi Daimon, Yasuo Sakaguchi
  • Patent number: 5604065
    Abstract: An electrophotographic photoconductor includes an electroconductive substrate, and a photoconductive layer formed thereon containing at least one tertiary amine compound of formula (I) as an effective component: ##STR1## wherein Ar.sup.1 and Ar.sup.3 each is an aryl group which may have a substituent; Ar.sup.2 is a bivalent group of a carbocyclic aromatic compound or a bivalent group of a heterocyclic compound; R.sup.1 is a hydrogen atom, an alkyl group which may have a substituent or an alkoxyl group which may have a substituent; and R.sup.2 is a hydrogen atom, an alkyl group which may have a substituent or an aryl group which may have a substituent. A novel triphenylamine compound for use in the electrophotographic photoconductor is provided.
    Type: Grant
    Filed: September 14, 1995
    Date of Patent: February 18, 1997
    Assignees: Ricoh Company, Ltd., Hodogaya Chemical Co., Ltd.
    Inventors: Tomoyuki Shimada, Masaomi Sasaki, Tamotsu Aruga, Masafumi Ohta, Mitsutoshi Anzai, Akihiro Imai
  • Patent number: 5576132
    Abstract: An electrophotographic photoconductor comprises an electroconductive substrate and a photoconductive layer formed thereon comprising as an effective component at least one pyrenylamine derivative of formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, W, j, k, l, m and n are specifically defined in the specification. Furthermore, a novel pyrenylamine derivative for use in the above electrophotographic photoconductor, an aldehyde compound, which is an intermediate for producing the pyrenylamine derivative, and methods of preparing the pyrenylamine derivative and the aldehyde compound are disclosed.
    Type: Grant
    Filed: April 24, 1995
    Date of Patent: November 19, 1996
    Assignee: Ricoh Company, Ltd.
    Inventors: Chiaki Tanaka, Masaomi Sasaki, Tamotsu Aruga, Tomoyuki Shimada, Hiroshi Adachi
  • Patent number: 5569749
    Abstract: An organic photoconductive material is represented by the following general formula [1]:A.sub.1 --N.dbd.N--B--N.dbd.N--A.sub.2 [1],wherein B is a divalent organic group bonded to nitrogen atoms forming azo groups, A.sub.1 and A.sub.2 are groups different from each other, A.sub.1 is represented by the following general formula [A1]: ##STR1## wherein X is an atomic group which is necessary for forming an aromatic hydrocarbon ring or an aromatic hetero-ring by condensation with the benzene ring, Y is a hydrogen atom, an alkyl group, an alkoxy group or a halogen atom, m is an integer of 1 to 4, R is an aromatic hydrocarbon ring group or an aromatic hetero-ring group and n is 1 or 2, and A.sub.2 is a group represented by one of the following general formulae [A2] and [A3]: ##STR2## wherein a.sub.1 is a group selected from R, --N.dbd.CH--R and ##STR3## R, X, Y, m and n are the same as those in the general formula [A1] and p is 0 or 1.
    Type: Grant
    Filed: January 18, 1996
    Date of Patent: October 29, 1996
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Hisao Kouno, Shyouichi Takahashi, Kazuhiro Higashide, Nakaji Komiyama, Osamu Suda, Masaru Hasegawa
  • Patent number: 5501930
    Abstract: An electrophotographic photoreceptor is herein disclosed which comprises a conductive support and a photosensitive layer formed on the conductive support, and the photosensitive layer contains an enamine derivative as a carrier transport material represented by the formula ##STR1## wherein Ar is an aryl group which may have a substituent, a heterocyclic group which may have a substituent, an aralkyl group which may have a substituent, or a heterocyclic substituted alkyl group; and n is 2, 3 or 4.The electrophotographic photoreceptor is excellent in sensitivity and durability.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: March 26, 1996
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Akihiro Kondo, Kiyofumi Morimoto, Kazuhiro Emoto
  • Patent number: 5498502
    Abstract: The present invention provides an electrographic printing photosensitive resin composition, which exhibits a good photosensitivity in a negative corona charging system and is useful for a laser platemaking system using semi-conductor laser light within a near infrared range as a light source.Disclosed is a negative charging type printing photosensitive resin composition comprising a phthalocyanine compound (a), a mercaptoarylimidazole (thiazole) compound (b) and, if necessary, a compound selected from the group consisting of a condensed polycyclic quinone compound, a bisazo compound, a cyanine compound, a quinacridone compound and a mixture thereof (d), said compounds being dispersed in a binder resin (c). A printing photosensitive resin plate using the photosensitive resin composition is also disclosed.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: March 12, 1996
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hisaichi Muramoto, Kazunori Kanda, Yutaka Kanoi
  • Patent number: 5403958
    Abstract: Disclosed is an electrophotographic member containing as a charge transport material a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative which is remarkably excellent in solubility in an organic solvent and/or a binder such as polycarbonate resin, etc., can show very excellent electrophotographic properties such as high sensitivity, low residual potential and high durability. Further, a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative usable as a charge transport material, and a process for producing the same are disclosed. Furthermore, a fluorine-containing diarylamine usable for producing the fluorine-containing N,N,N',N'-tetraarylbenzidine derivative, and a process for producing the same are disclosed.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: April 4, 1995
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Yoshii Morishita, Yasushi Sugimoto, Shigeru Hayashida, Hiroko Ishikawa, Yoshiaki Noda, Shigeru Murakami, Munehiro Sato, Yoshinori Saito, Naoji Kurata, Yoshio Sugita
  • Patent number: 5389480
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive substrate and a photosensitive layer formed thereon, wherein the photosensitive layer contains at least one member selected from the group consisting of compounds of the formula (I), (II), and (III) as defined in the specification.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: February 14, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hitoshi Ono, Atsuo Saita
  • Patent number: 5376486
    Abstract: The present invention provides an electrophotographic photoreceptor high in sensitivity and endurance and highly resistant against oxidizing action with ozone or the like which comprises an electrically conductive support and, provided thereon, a light-sensitive layer which contains at least one azo compound containing a coupler component represented by the following formula [I] or [II]: ##STR1## wherein X represents a heterocyclic or aromatic ring residue which may have a substituent fusing with the benzene ring, Y represents a linkage group, R.sup.1 -R.sup.4 each represents a hydrogen atom or an alkyl group and R.sup.5 represents a hydrogen atom or an alkyl, aralkyl or acyl group which may have a substituent; ##STR2## wherein X and Y are as defined above and R.sup.6 and R.sup.7 each represents a hydrogen atom or an alkyl group which may have a substituent.
    Type: Grant
    Filed: June 14, 1993
    Date of Patent: December 27, 1994
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Akira Itoh, Hideki Nagamura
  • Patent number: 5370953
    Abstract: The invention presents an electrophotosensitive material comprising a conductive substrate, a photosensitive layer formed on the conductive substrate, and, if necessary, a surface protective layer formed on the photosensitive layer, wherein an oxadiazole derivative expressed in a general formula (I): ##STR1## where R.sup.1 denotes an alkyl group, is contained as an electron transfer substance on the photosensitive layer and/or surface protective layer. This photosensitive material enhances the electron transfer capability, and hence the sensitivity is improved. At the same time, the residual potential of the photosensitive material is lowered, and the stability and durability against repeated exposures are enhanced.
    Type: Grant
    Filed: November 20, 1992
    Date of Patent: December 6, 1994
    Assignee: Mita Industrial Co., Ltd.
    Inventor: Kaname Nakatani
  • Patent number: 5370954
    Abstract: An electrophotographic photoconductor is composed of an electroconductive support and a photoconductive layer formed thereon which contains a charge generating material and a charge transporting material. The charge generating material is composed of a particular triasazo compound and a particular disazo compound. A photoconductive composition useful as a photoconductive material is also composed of the trisazo compound and the disazo compound.
    Type: Grant
    Filed: April 16, 1993
    Date of Patent: December 6, 1994
    Assignee: Ricoh Company, Ltd.
    Inventors: Katsuichi Ohta, Masaomi Sasaki, Mitsuru Hashimoto, Kazuya Ishida, Tomoyuki Shimada
  • Patent number: 5356742
    Abstract: An electrophotographic photoconductor is composed of an electroconductive substrate and a photoconductive layer formed thereon, the photoconductive layer includes a dipyrenylamine derivative of formula (I): ##STR1## wherein R represents an alkyl group with 1 to 12 carbon atoms, which may have a substituent, or an aryl group which may have a substituent. Novel dipyrenylamine derivatives of formula (I), in which R is --ph--(R.sup.4)n, wherein, ph is a phenyl group, R.sup.4 is hydrogen, an unsubstituted or substituted alkyl group having 1 to 12 carbon atoms, an unsubstituted or substituted alkoxyl group having 1 to 12 carbon atoms, n is an integer of 1 to 5, and when n is 2 to 5, R.sup.4 may be the same or different, which are for use in the photoconductive layer of the electrophotographic photoconductor, are synthesized.
    Type: Grant
    Filed: February 28, 1992
    Date of Patent: October 18, 1994
    Assignee: Ricoh Company, Ltd.
    Inventors: Tomoyuki Shimada, Masaomi Sasaki, Tamotsu Aruga, Hiroshi Adachi
  • Patent number: 5352834
    Abstract: Disclosed is an electrophotographic member containing as a charge transport material a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative which is remarkably excellent in solubility in an organic solvent and/or a binder such as polycarbonate resin, etc., can show very excellent electrophotographic properties such as high sensitivity, low residual potential and high durability. Further, a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative usable as a charge transport material, and a process for producing the same are disclosed. Furthermore, a fluorine-containing diarylamine usable for producing the fluorine-containing N,N,N',N'-tetraarylbenzidine derivative, and a process for producing the same are disclosed.
    Type: Grant
    Filed: June 8, 1992
    Date of Patent: October 4, 1994
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshii Morishita, Yasushi Sugimoto, Shigeru Hayashida, Hiroko Ishikawa, Yoshiaki Noda, Shigeru Murakami, Munehiro Sato, Yoshinori Saito, Naoji Kurata, Yoshio Sugita
  • Patent number: 5316881
    Abstract: The photoconductor for electrophotography comprises an electroconductive substrate and a photosensitive layer formed on the substrate. The photosensitive layer may be a monolayer or function-separated laminate type one which comprise a charge generating layer and a charge transporting layer laminated one on another. The charge generating layer contains a specified benzidine compound represented by general formula (I) below as the charge transporting substance. ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which are the same or different, each represent independently an aryl group, an alkylaryl group, an alkoxyaryl group or a halogenated aryl group provided that R.sub.1 and R.sub.2, or R.sub.3 and R.sub.4, or both combine and form a condensed aromatic group with the nitrogen atom to which they are bonded, respectively; R.sub.5 and R.sub.6 each represent independently a hydrogen atom, an alkyl group, an alkoxy group, or a halogen atom.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: May 31, 1994
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Yoichi Nakamura, Nobuyoshi Mori, Sumitaka Nogami
  • Patent number: 5308726
    Abstract: An electrophotographic photosensitive element is here disclosed which comprises a conductive substrate and at least a photosensitive layer formed on the conductive substrate, the electrophotographic photosensitive element being characterized in that the photosensitive layer contains, as a charge transport material, a compound represented by the formula (1), (2) or (3) ##STR1##
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: May 3, 1994
    Assignee: NEC Corporation
    Inventors: Akira Hirano, Eriko Tsuruoka
  • Patent number: 5300385
    Abstract: Certain chemical compounds, which are aromatic heterocyclic-substituted derivatives of 4H-thiopyran-1,1,-dioxide given by the formula (I) wherein Het is a substituted or unsubstituted heterocyclic ring system containing at least one 5-membered heterocyclic aromatic ring; and R is an alkyl, aralkyl, or cycloalkyl group of 1 to about 10 carbon atoms, or an aryl group of 6 to about 12 carbon atoms, or a substituted or unsubstituted heterocyclic ring system containing at least one 5-membered aromatic heterocyclic ring, are electron-transport agents. These compounds exhibit good speed and toe voltage properties in electrophotographic elements.
    Type: Grant
    Filed: November 16, 1992
    Date of Patent: April 5, 1994
    Assignee: Eastman Kodak Company
    Inventors: Michael R. Detty, John A. Sinicropi, J. Robin Cowdery, Ralph H. Young
  • Patent number: 5294512
    Abstract: The photoreceptor comprises a light-sensitive layer on a conductive support or a conductive layer. The light-sensitive layer containes a pyrene compounds.
    Type: Grant
    Filed: February 22, 1993
    Date of Patent: March 15, 1994
    Assignee: Konica Corporation
    Inventors: Tomoko Suzuki, Akira Kinoshita
  • Patent number: 5286589
    Abstract: An electrophotographic photosensitive member has a photosensitive layer on an electroconductive support. The photosensitive layer comprises a compound having a structure represented by the general formula (1) or (2) as a charge-generating material: ##STR1## wherein A.sub.1 and A.sub.3 are respectively an alkyl radical, an aralkyl radical, an aromatic radical or a heterocyclic radical which may have a substituent; A.sub.2 is hydrogen atom, or an alkyl radical, an aralkyl radical, an aromatic radical, or a heterocyclic radical which may have a substituent; A.sub.1 and A.sub.2 may be the same with or different from each other; A.sub.1 and A.sub.2 may be linked together to form a ring; and n is an integer of 1, 2, or 3.
    Type: Grant
    Filed: November 12, 1992
    Date of Patent: February 15, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shintetsu Go, Kazushi Iuchi, Toshie Miyaji, Hajime Miyazaki, Hideyuki Takai, Masakazu Matsumoto
  • Patent number: 5275899
    Abstract: Photoconductive compositions useful in the fabrication of digital, laser-imaged offset printing plates. The compositions comprise a mixture of (a) an infrared-sensitive organic photoconductor sensitive to light in the wavelength range of 700-9090 nm; (b) a visible light-sensitive organic photoconductor sensitive to light in the wavelength range of 400-700 nm; (c) an ultraviolet-sensitive organic photoconductor sensitive to light in the wavelength range of 300-400 nm; and (d) a binder.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: January 4, 1994
    Assignee: Sun Chemical Corporation
    Inventors: Ken-ichi Shimazu, Jayanti S. Patel, Nishith V. Merchant
  • Patent number: 5268246
    Abstract: An electrophotographic photoconductor is composed of an electroconductive support and a photoconductive layer formed thereon comprising a novel pyrene-ring-containing olefin compound having formula [I]: ##STR1## wherein R.sup.1 and R.sup.2 each represent hydrogen or an alkyl group which may have a substituent; Y is an aliphatic hydrocarbon group which may have a substituent, a cyclic hydrocarbon group which may have a substituent, or an aromatic group which may have a substituent; n is an integer of 0 or 1, and m is an integer of 1 to 3, provided that when n is 0, m is 1, R.sup.1 is hydrogen, and Y is an aromatic group with a substituent ##STR2## R.sup.5 and R.sup.3 each represent hydrogen, and Y and R.sup.1 may be bonded to form a ring, a method of synthesizing the pyrene-ring-containing olefin compound and an intermediate therefor are disclosed.
    Type: Grant
    Filed: April 9, 1991
    Date of Patent: December 7, 1993
    Assignee: Ricoh Company, Ltd.
    Inventors: Tamotsu Aruga, Masaomi Sasaki, Tomoyuki Shimada, Hiroshi Adachi
  • Patent number: 5266430
    Abstract: A photoconductor for electrophotography comprises an electroconductive substrate and a photosensitive layer formed on the substrate. The photosensitive layer includes a novel bisazo compound as a charge generating substance therein. The bisazo compound is represented by the following general formula: ##STR1## wherein, A stands for a coupler residue.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: November 30, 1993
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Masami Kuroda, Masayo Amano, Noboru Furusho
  • Patent number: 5194355
    Abstract: An electrophotographic photosensitive member has an electroconductive support and a photosensitive layer. The photosensitive layer contains a compound represented by the general formula (1) below:Ar--(--N.dbd.N--Cp).sub.i (1).
    Type: Grant
    Filed: March 13, 1992
    Date of Patent: March 16, 1993
    Assignee: Canon Kabushiki Kaisha
    Inventors: Satomi Ohmura, Toshihiro Kikuchi
  • Patent number: 5178981
    Abstract: A photoconductor for electrophotography includes an electroconductive substrate; and a photosensitive layer formed on the substrate. The photosensitive layer includes a charge generating substance consisting essentially of at least one polycyclic compound represent by general formula (I) and at least one azo compound represented by general formula (II). ##STR1## wherein X is selected from the group consisting of a hydrogen atom, a halogen atom and a cyano group and n is an integer of 0 to 4; ##STR2## wherein R is selected from the group consisting of a hydrogen atom, a halogen atom and a substituted or unsubstituted alkyl group and alkoxy group, Z1 is selected from the group consisting of a substituted or unsubstituted alkyl group, aryl group and aromatic heterocyclic group, Z.sub.2 is selected from the group consisting of a hydrogen atom, a cyano group, a carbomoyl group, a carboxyl group, an ester group and an acyl group, each of Z.sub.3 and Z.sub.
    Type: Grant
    Filed: February 27, 1991
    Date of Patent: January 12, 1993
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Yoshimasa Hattori, Yoshinobu Sugata, Masami Kuroda, Noboru Furusho
  • Patent number: 5168025
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive support and a photosensitive layer formed thereon, wherein said photosensitive layer contains an arylamine compound of the formula (I): ##STR1## wherein each of Ar.sup.1 and Ar.sup.2 which may be the same or different, is an arylene group which may have substituents, each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 which may be the same or different, is an alkyl group which may have substituents, an aryl group which may have substituents, or a heterocyclic group which may have substituents, provided that R.sup.1 may, together with R.sup.2 or Ar.sup.1, form a ring containing the adjacent nitrogen atom, and R.sup.3 may, together with R.sup.4 or Ar.sup.2, form a ring containing the adjacent nitrogen atom, each of R.sup.5, R.sup.6, R.sup.7 and R.sup.
    Type: Grant
    Filed: September 11, 1991
    Date of Patent: December 1, 1992
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hitoshi Ono, Atsuo Saita
  • Patent number: 5160487
    Abstract: Disclosed is an electrophotographic member containing as a charge transport material a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative which is remarkably excellent in solubility in an organic solvent and/or a binder such as polycarbonate resin, etc., can show very excellent electrophotographic properties such as high sensitivity, low residual potential and high durability. Further, a fluorine-containing N,N,N',N'-tetraarylbenzidine derivative usable as a charge transport material, and a process for producing the same are disclosed. Furthermore, a fluorine-containing diarylamine usable for producing the fluorine-containing N,N,N',N'-tetraarylbenzidine derivative, and a process for producing the same are disclosed.
    Type: Grant
    Filed: September 4, 1991
    Date of Patent: November 3, 1992
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshii Morishita, Yasushi Sugimoto, Shigeru Hayashida, Hiroko Ishikawa, Yoshiaki Noda, Shigeru Murakami, Munehiro Sato, Yoshinori Saito, Naoji Kurata, Yoshio Sugita
  • Patent number: 5158848
    Abstract: A photoconductor for electrophotography comprises a substrate and a photosensitive layer formed thereon and including a novel hydrazone compound as a charge transporting substance. The hydrazone compound is represented by the following general formula: ##STR1## Wherein, A is selected from the residual group consisting of an aromatic residual group, a condensed polycyclic residual group, and a heterocyclic residual group, which groups may be or not may be substituted, R.sub.1 is selected from the atom or group consisting of any one of a hydrogen atom, a halogen atom, an alkyl group, an acyl group or a dialkylamino group, and each of R.sub.2 and R.sub.3 is selected from the group consisting of an alkyl group, an aryl group, an alkenyl group, an aralkyl group and a thenyl group, which groups may be or not may be substituted.
    Type: Grant
    Filed: January 15, 1991
    Date of Patent: October 27, 1992
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Masami Kuroda, Yoshinobu Sugata, Noboru Furusho
  • Patent number: 5141831
    Abstract: The present invention provides an electro-photographic photoreceptor which is high in sensitivity and endurance which comprises an electroconductive support and, provided thereon, a photosensitive layer which contains a compound represented by the following formula [I]: ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom or an alkyl, aralkyl or aryl group which may have substituent: X represents ##STR2## in which R.sup.3 and R.sup.4 each represents an alkyl, aralkyl or aryl group which may have substituent and R.sup.5 and R.sup.6 each represents a hydrogen atom or an alkyl, aralkyl or aryl group which may have substituent and R.sup.5 and R.sup.6 may link to each other to form a ring; and Z represents a group of atoms necessary for forming a saturated 5-8 membered ring together with two carbon atoms of the indoline ring.
    Type: Grant
    Filed: August 10, 1990
    Date of Patent: August 25, 1992
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Akira Itoh, Hideki Nagamura, Hideya Arisue
  • Patent number: 5139909
    Abstract: A photoconductive imaging member comprised of an unsymmetrical perinone and a charge transport layer.
    Type: Grant
    Filed: July 31, 1990
    Date of Patent: August 18, 1992
    Assignee: Xerox Corporation
    Inventors: Peter M. Kazmaier, Ah-Mee Hor, Cheng K. Hsiao
  • Patent number: 5137795
    Abstract: An electrophotographic recording material which comprises an electrically conductive support having thereon a photoconductive layer, characterized in that said layer contains one or more hydrazone compounds corresponding to a following general formula (I) to (II): ##STR1## wherein: R represents a homocyclic or heterocyclic group with aromatic character, including such group substituted with one or more non-ionic substituents, each of R.sup.1 and R.sup.2 (same or different) represents a C.sub.1 -C.sub.6 alkyl group,R.sup.3 represents hydrogen or a N,N-substituted --CH.dbd.hydrazono group,Z represents the atoms necessary to close an adjacent aromatic nucleus, or aromatic ring system substituted with a N,N-substituted --CH.dbd.hydrazono group, andX is a bivalent homocyclic or heterocyclic aromatic group.
    Type: Grant
    Filed: April 9, 1991
    Date of Patent: August 11, 1992
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Marcel J. Monbaliu, David R. Terrell, Stefaan K. De Meutter
  • Patent number: 5132189
    Abstract: A photoconductor for electrophotography includes an electroconductive substrate and a photosensitive layer formed on the substrate. The photosensitive layer includes a novel azo compound as a charge generating substance therein. One example of the azo compound is represented by general formula: ##STR1## wherein A stands for a coupler residue, and each of R.sub.1 and R.sub.2 is one of a hydrogen atom, a halogen atom, an alkyl group and an alkoxy group.
    Type: Grant
    Filed: September 4, 1990
    Date of Patent: July 21, 1992
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Masami Kuroda, Masayo Amano, Noboru Furusho
  • Patent number: 5112759
    Abstract: An electrophotographic photosensitive member comprises an electroconductive support and a photosensitive layer laid on the electroconductive support, the photosensitive layer containing a compound represented by the following general formula (1): ##STR1## wherein R in a substituted or unsubstituted aromatic group or heterocyclic group; X is substituted or unsubstituted benzenediyl, 2,3-pyridinediyl, 3,4-pyridinediyl or 2,3-pyrazinediyl; Y is an oxygen atom, a sulfur atom or a dicyanomethylene group, Z is an oxygen atom, a sulfur atom, a dicyanomethylene group or ##STR2## m is an integer of 1 2 or 3; and n is an integer of 0 or 1.
    Type: Grant
    Filed: March 30, 1990
    Date of Patent: May 12, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akihiro Senoo, Kazushi Iuchi, Hajime Miyazaki, Shintetsu Go, Toshie Miyaji
  • Patent number: 5106712
    Abstract: A novel electrophotographic photoreceptor is provided comprising on an electrically conductive support a layer containing a charge carrier-transporting compound and a charge carrier-generating compound or a charge carrier-transporting compound-containing layer and a charge-generating compound-containing layer, characterized in that as said charge carrier-generating compound there is contained a novel bisazo compound represented by the general formula (1-A), (1-B) or (1-C):Cp--N.dbd.N--Ar.sup.1 --C.tbd.C--.sub.n Ar.sup.2 --N.dbd.N--Cp (1-A)wherein Ar.sup.1 and Ar.sup.2 each represents an arylene group, divalent condensed polycyclic aromatic group or divalent heterocyclic aromatic group; Cp represents a coupler residue; and n represents an integer 2 or 3;Cp--N.dbd.N--Ar.sup.1 --C.tbd.C--Ar.sup.2 --C.tbd.C--Ar.sup.3 --C.tbd.C--Ar.sup.4 --N.dbd.N--Cp (1-B)wherein Ar.sup.1, Ar.sup.2, Ar.sup.3 and Ar.sup.
    Type: Grant
    Filed: July 6, 1990
    Date of Patent: April 21, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsugi Kitatani, Naonori Makino, Satoshi Hoshi
  • Patent number: 5100750
    Abstract: A photoconductor for electrophotography comprises a novel organic compound as a charge transporting substance. The organic compounds is represented by the following general formula: ##STR1## wherein, each of R.sub.1 to R.sub.4 stands for a hydrogen atom, a halogen atom, an alkoxy group, or an alkyl group, an aryl group, an alkenyl group, an aralkyl group, a thienyl group, each of which may have a substituent(s).
    Type: Grant
    Filed: April 6, 1989
    Date of Patent: March 31, 1992
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Masami Kuroda, Youichi Nakamura, Noboru Furusho
  • Patent number: 5089365
    Abstract: A photosensitive member for electrophotography have a photosensitive layer 20 provided on an electroconductive substrate 1 and, containing a compound selected from among derivatives of thiophene, diphenylthiophene or oxadiazole. When the surface of the photosensitive member was positively charged and then irradiated with white light, the half decay exposure amount with which the surface potential is decreased to half is 5 to 10 lux.multidot.sec. The photosensitive member is capable of being used in semiconductor laser printers.
    Type: Grant
    Filed: June 6, 1989
    Date of Patent: February 18, 1992
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Masami Kuroda, Youichi Nakamura, Noboru Furusho
  • Patent number: 5079118
    Abstract: A photosensitive member for electrophotography, comprising an electroconductive substrate and a photosensitive layer disposed thereon, wherein the photosensitive layer comprises a pyrene compound represented by the following general formula (I): ##STR1## wherein Ar.sub.1 and Ar.sub.2 respectively denote and aromatic hydrocarbon group capable of having a substituent, or an aromatic heterocyclic group capable of having a substituent.
    Type: Grant
    Filed: January 19, 1990
    Date of Patent: January 7, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Toshihiro Kikuchi, Tetsuro Kanemaru, Akihiro Senoo, Ryoji Yashiro
  • Patent number: 5077164
    Abstract: The present invention relates to a photosensitive member with a photosensitive layer on or over an electrically conductive substrate, in which the photosensitive layer comprises at least one of azo pigments selected from the group consisting of azo pigments represented by the following general formulas [I], [II] and [III]. ##STR1## in which Z.sub.1 is a residual group of a condensed ring excluding the benzene ring and the carbonyl group in the formula [I]; Z.sub.2 is a residual group of a condensed ring excluding the naphthalene ring and the carbonyl group in the formula [II]; Z.sub.1 and Z.sub.2 may have a substituent respectively; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent independently a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, a hydroxy group or a nitro group; Ar.sub.1, Ar.sub.2, Ar.sub.3, Ar.sub.4 and Ar.sub.5 represent independently an arylene group which may have a substituent; Ar.sub.
    Type: Grant
    Filed: June 20, 1990
    Date of Patent: December 31, 1991
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventors: Hideaki Ueda, Takamasa Ueda, Masakazu Takata
  • Patent number: 5071993
    Abstract: Compounds of the formula ##STR1## in which R.sup.1 and R.sup.3 independently of one another are C.sub.1 -C.sub.8 alkyl, cyclopentyl, cyclohexyl, C.sub.7 -C.sub.9 aralkyl, phenyl or a group of the formula--C.sub.m H.sub.2m+1-q (X).sub.q (II)in which m is a number from 0-10 and q is 1 or 2, with q=1 in the case of m=0, R.sup.2 and R.sup.4 independently of one another are each a group of the formula II or, in the case that R.sup.1 and R.sup.3 are each a group of the formula II, R.sup.2 and R.sup.4 independently of one another can also be C.sub.1 -C.sub.8 alkyl, cyclopentyl, cyclohexyl, C.sub.7 -C.sub.9 aralkyl or phenyl, R.sup.5 and R.sup.6 independently of one another are hydrogen, methyl, ethyl or together are trimethylene or tetramethylene, and X is a group of the formula ##STR2## in which the general symbols are as defined in claim 1, are suitable as fluorescent brighteners especially for photographic recording materials and for synthetic polymers.
    Type: Grant
    Filed: September 12, 1989
    Date of Patent: December 10, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: David G. Leppard, Eric Vieira
  • Patent number: 5055367
    Abstract: Disclosed is an imaging member which comprises a conductive substrate and a photogenerating layer containing a compound selected from the group consisting of: ##STR1## and mixtures thereof, wherein Cp represents a coupler group.
    Type: Grant
    Filed: May 31, 1990
    Date of Patent: October 8, 1991
    Assignee: Xerox Corporation
    Inventor: Kock-Yee Law
  • Patent number: 5041349
    Abstract: This invention provides an electrophotographic photoreceptor which is high in durability and high in sensitivity. This photoreceptor comprises an electroconductive support and, provided thereon, a photosensitive layer containing an azo pigment represented by the following formula [I] or [II]: ##STR1## wherein A represents a hydrogen atom, an alkyl group, a phenyl group or a heterocyclic ring group, m and n each represents 0 or 1, X represents a hydrogen atom, a lower alkyl group, a cyano group or a halogen atom and Cp represents a coupler residue, or ##STR2## wherein Z represents an alkyl group, a phenyl group or a heterocyclic ring group, X represents a hydrogen atom, a lower alkyl group, a cyano group or a halogen atom and Cp represents a coupler residue.
    Type: Grant
    Filed: July 31, 1990
    Date of Patent: August 20, 1991
    Assignee: Mitsubishi Paper Mills, Limited
    Inventors: Kazuhiro Emoto, Kozo Haino, Akira Itoh, Makoto Okaji
  • Patent number: 5034294
    Abstract: An electrophotographic photosensitive member has a photosensitive layer on an electroconductive support. The photosensitive layer comprises a compound represented by the general formula (1) or (2) having in the molecule thereof an electron-donating portion and an electron-accepting portion: ##STR1## where D is an electron-donating aromatic group or an electron-donating heterocyclic group; A is an electron-accepting aromatic group or an electron-accepting heterocyclic group; B is a hydrogen atom, or an aromatic or heterocyclic group which may form a ring together with A or D; m is an integer of 1, 2 or 3; and n is an integer of 0 or 1.
    Type: Grant
    Filed: February 7, 1990
    Date of Patent: July 23, 1991
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shintetsu Go, Kazushi Iuchi, Hajime Miyazaki, Hideyuki Takai, Masakazu Matsumoto
  • Patent number: 5028708
    Abstract: This invention provides azamethine compounds represented by the formula (I): ##STR1## (wherein X represents ##STR2## Y represents C.dbd.O, C.dbd.C(CN).sub.2 or SO.sub.2 ; R.sub.1 to R.sub.4 represent independently a hydrogen atom, an alkyl group which may be substituted, an alkoxyl group which may be substituted, a halogen atom, a nitro group, a cyano group, a hydroxyl group, an amino group which may be substituted, --A--R or ##STR3## R.sub.5 and R.sub.6 represent independently a hydrogen atom, an alkyl group which may be substituted, an aryl group which may be substituted or a cyclohexyl group; R.sub.5 and R.sub.6 may be combined to form a ring or may form a ring with a hetero atom; R.sub.7 and R.sub.
    Type: Grant
    Filed: April 8, 1988
    Date of Patent: July 2, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takeshi Hioki, Kiyoteru Kojima, Jun Tomioka
  • Patent number: 5019474
    Abstract: A novel electrophotographic photoreceptor is provided comprising on an electrically conductive support a layer containing a charge-transporting compound and a charge-generating compound or a charge-transporting compound-containing layer and a charge-generating compound-containing layer, characterized in that as said electric charge-generating compound there is contained a tetrakisazo compound represented by the general formula (1): ##STR1## wherein Ar.sup.1, Ar.sup.2, Ar.sup.3, Ar.sup.4, Ar.sup.5, Ar.sup.6 and Ar.sup.7 each represents an arylene group, divalent condensed polycyclic aromatic group or divalent heterocyclic aromatic group; and Cp represents a coupler residue.
    Type: Grant
    Filed: April 4, 1990
    Date of Patent: May 28, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naonori Makino, Shigeru Ohno, Satoshi Hoshi, Katsuji Kitatani
  • Patent number: 5013623
    Abstract: Disclosed is an electrophotographic photoreceptor which is high is sensitivity and high in endurance and which contains in photosensitive layer a novel stilbene compound represented by the following formulas [I], [II], or [III]: ##STR1##
    Type: Grant
    Filed: January 3, 1990
    Date of Patent: May 7, 1991
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Akira Itoh, Kozo Haino, Makoto Okaji, Kazuhiro Emoto, Tatsuya Kodera
  • Patent number: 4999269
    Abstract: This invention provides an electrophotographic photoreceptor which is high in durability and high in sensitivity. This photoreceptor comprises an electroconductive support and, provided thereon, a photosensitive layer containing an azo pigment represented by the following formula [I] or [II]: ##STR1## wherein A represents a hydrogen atom, an alkyl group, a phenyl group or a heterocyclic ring group, m and n each represents 0 or 1, X represents a hydrogen atom, a lower alkyl group, a cyano group or a halogen atom and Cp represents a coupler residue, or ##STR2## wherein Z represents an alkyl group, a phenyl group or a heterocyclic ring group, X represents a hydrogen atom, a lower alkyl group, a cyano group or a halogen atom and Cp represents a coupler residue.
    Type: Grant
    Filed: July 31, 1990
    Date of Patent: March 12, 1991
    Assignee: Mitsubishi Paper Mills, Limited
    Inventors: Kazuhiro Emoto, Kozo Haino, Akira Itoh, Makoto Okaji
  • Patent number: 4994338
    Abstract: An electrophotographic photosensitive material includes a photosensitive layer which is formed on a conductive support body and which contains an azo pigment expressed by Formula (1) described below, wherein at least one Cp in the Formula (1) is a coupler residue expressed by Formula (2) described below.Ar--N.dbd.N--CP).sub.n (1)wherein Ar is an aromatic hydrocarbon or aromatic heterocyclic group, Cp is a coupler reside having a phenolic hydroxyl group, and n is an integer of 1, 2, 3 or 4. ##STR1## wherein R.sub.1 and R.sub.2 each is a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, a halomethyl group, a cyano group or a nitro group.
    Type: Grant
    Filed: May 23, 1989
    Date of Patent: February 19, 1991
    Assignee: Canon Kabushiki Kaisha
    Inventor: Hideyuki Takai
  • Patent number: 4988593
    Abstract: An electrophotographic photosensitive member having a photosensitive layer is formed on a support and contains an azo pigment expressed by a general formula [I] or [II]: ##STR1## where A, B.sub.1 and B.sub.2 are aromatic hydrocarbon nucleus groups or heterocyclic groups which may be optionally linked by coupler groups, A is an univalent group, B.sub.1 is an univalent, bivalent or trivalent group, and B.sub.2 is a bivalent or trivalent group; X is a residue necessary for forming a polycyclic aromatic nucleus or a heterocycle by condensation with a benzene nucleus; R is a halogen atom, an alkyl group or an alkoxy group; n.sub.1 is an integer from 1 to 3; and n.sub.2 is an integer from 1 to 3. This photosensitive layer may be composed of a charge generation layer containing the above azo pigment and a charge transport layer.
    Type: Grant
    Filed: September 20, 1989
    Date of Patent: January 29, 1991
    Assignee: Canon Kabushiki Kaisha
    Inventor: Hideyuki Takai
  • Patent number: 4977051
    Abstract: An electrophotographic photoreceptor is disclosed, which comprises an electrically conductive support having thereon a layer which contains a charge carrier transporting compound and a charge carrier generating compound, or a layer which contains charge carrier transporting compound and a layer which contains a charge generating compound, wherein at least one type of tris-azo compound represented by formula (I) is included as a charge carrier generating compound: ##STR1## wherein Ar.sub.1, Ar.sub.2, Ar.sub.3, Ar.sub.4 and A are as defined in the specification.
    Type: Grant
    Filed: November 8, 1989
    Date of Patent: December 11, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeru Ohno, Katsuji Kitatani, Naonori Makino, Satoshi Hoshi, Hideo Sato
  • Patent number: RE35475
    Abstract: A photosensitive member for electrophotography have a photosensitive layer 20 provided on an electroconductive substrate 1 and, containing a compound selected from among derivatives of thiophene, diphenylthiophene or oxadiazole. When the surface of the photosensitive member was positively charged and then irradiated with white light, the half decay exposure amount with which the surface potential is decreased to half is 5 to 10 lux.cndot.sec. The photosensitive member is capable of being used in semiconductor laser printers.
    Type: Grant
    Filed: February 17, 1994
    Date of Patent: March 11, 1997
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Masami Kuroda, Youichi Nakamura, Noboru Furusho