Radiation-conductive Composition Contains Hetero Ring Patents (Class 430/75)
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Patent number: 10224493Abstract: The invention relates to boron-containing compounds with bicyclic structural units and to electronic devices, in particular organic electroluminescent devices, containing said compounds.Type: GrantFiled: September 19, 2014Date of Patent: March 5, 2019Assignee: Merck Patent GmbHInventor: Philipp Stoessel
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Publication number: 20150024309Abstract: A support material for printing a support structure with an electrophotography-based additive manufacturing system, the support material including a composition having a charge control agent and a thermoplastic copolymer having aromatic groups, (meth)acrylate-based ester groups, carboxylic acid groups, and anhydride groups, with a high anhydride conversion. The composition is provided in a powder form having a controlled particle size, and the support material is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the support structure in a layer-by-layer manner, and is at least partially soluble in an aqueous solution.Type: ApplicationFiled: July 17, 2013Publication date: January 22, 2015Inventor: Trevor I. Martin
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Publication number: 20140255837Abstract: Provided is an electrophotographic photosensitive member excellent in suppression of image deletion and electric potential variation. The surface layer of the electrophotographic photosensitive member comprises a hole transporting substance. The hole transporting substance is one of a compound consisting of a carbon atom and a hydrogen atom, or a compound consisting of a carbon atom, a hydrogen atom, and an oxygen atom. The hole transporting substance comprises a conjugate structure containing 24 or more sp2 carbon atoms. The conjugate structure comprises a condensed polycyclic structure comprising 12 or more sp2 carbon atoms. A ratio of a number of sp2 carbon atoms is 55% or more based on a total number of carbon atoms in the hole transporting substance, and a ratio of a number of sp3 carbon atoms is 10% or more based on a total number of carbon atoms in the hole transporting substance.Type: ApplicationFiled: February 26, 2014Publication date: September 11, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Koichi Nakata, Shinji Takagi, Nobuo Kosaka, Koichi Suzuki
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Publication number: 20140178810Abstract: An image bearing member includes a substrate, and a photosensitive layer overlying the substrate, wherein an uppermost surface layer of the image bearing member has a hydrocarbon compound represented by the following Chemical Formula 1; and a three-dimensionally cross-linked polymer formed by polymerization reaction of a charge transport compound having three or more [tetrahydro-2H-pyran-2-yl)oxy]methyl groups linked with aromatic rings, wherein, in the polymerization reaction, part of the three or more [(tetrahydro-2H-pyran-2-yl)oxy]methyl groups is severed and detached from the charge transport compound, Ph1-Q1-Ph2-Q2-Ph3??Chemical Formula 1 where Q1 and Q2 independently represent methylene groups or ethylene groups, Ph1 and Ph3 independently represent phenyl groups with which one or two methyl groups are bonded, and Ph2 represents a phenylene group or a phenylene group having one methyl group.Type: ApplicationFiled: December 4, 2013Publication date: June 26, 2014Inventors: Kazukiyo NAGAI, Yuuji Tanaka, Tetsuro Suzuki, Yuusuke Koizuka
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Patent number: 8741515Abstract: Provided is an image holding member for an image forming apparatus including a support; and a photosensitive layer disposed on the support and containing a compound represented by the following formula (I): wherein in the formula (I), R1's each independently represent a substituted or unsubstituted, linear or branched alkyl group having from 1 to 8 carbon atoms; Ar's each independently represent a substituted or unsubstituted phenyl group, a substituted or unsubstituted monovalent polynuclear aromatic hydrocarbon group having two aromatic rings, a substituted or unsubstituted monovalent condensed aromatic hydrocarbon group having two or three aromatic rings, or a substituted or unsubstituted monovalent aromatic heterocyclic group; and n's each independently represent a number of from 0 to 7.Type: GrantFiled: May 11, 2012Date of Patent: June 3, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Hidekazu Hirose, Ryosaku Igarashi, Katsuhiro Sato
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Publication number: 20140080044Abstract: The present invention provides dual wavelength imaging compositions, processes for forming dual wavelength imaging compositions, methods for forming images using dual wavelength imaging compositions and substrate (e.g., paper web) treated (e.g., coated) on one or both sides with dual wavelength imaging compositions. Also provided is a dual wavelength imaging particulate comprising a matrix of polymer material and containing: one or more image-forming agents; a photo-oxidizing agent which is activated at a first wavelength of light to cause the one or more image-forming agents to form one or more images; and a reducing agent which is activated at a second wavelength of light to cause termination of the formation of the one or more images.Type: ApplicationFiled: November 18, 2013Publication date: March 20, 2014Applicant: INTERNATIONAL PAPER COMAPNYInventors: RICHARD C. WILLIAMS, RICHARD D. FABER, OLEG GRINEVICH, JOHN MALPERT, ALEXANDRE MEJIRITSKI, DOUGLAS C. NECKERS
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Publication number: 20130316279Abstract: A composition according to the present invention contains at least a triarylamine compound and at least one bicyclic compound selected from the group consisting of those of the general formulas [1] to [4], wherein the triaryl amine compound is dissolved in the at least one bicyclic compound where R1 each independently represents a hydrogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, a fluorine atom or a chlorine atom; A, B, C and F each independently represents either —CR22—, —O— or —NR2—; D and E each independently represents either —CR2? or —N?; G represents —CR22—; H represents —CR2?; and R2 represents a hydrogen atom, a methyl group or a halogen atom.Type: ApplicationFiled: March 27, 2013Publication date: November 28, 2013Applicant: Central Glass Company, LimitedInventors: Hideaki IMURA, Masamune Okamoto, Naoto Takada
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Patent number: 8481234Abstract: An image bearing member including an electroconductive substrate, a photosensitive layer provided overlying the electroconductive substrate, and a furan derivative represented by the following chemical structure 1, where Ar1 and Ar2 independently represent substituted or non-substituted aryl groups and R1 represents an alkylene group having one to six carbon atoms.Type: GrantFiled: September 7, 2011Date of Patent: July 9, 2013Assignee: Ricoh Company, Ltd.Inventors: Hongguo Li, Kazukiyo Nagai, Yoshiaki Kawasaki
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Patent number: 8475984Abstract: An image holding member for an image forming apparatus includes a support and a photosensitive layer disposed on the support and containing a compound represented by following formula (I), wherein R1s each independently represent a substituted or unsubstituted linear or branched alkyl group having from 1 to 8 carbon atoms; Ar's each independently represent a substituted or unsubstituted phenyl group, a substituted or unsubstituted monovalent polynuclear aromatic hydrocarbon group having two aromatic rings, a substituted or unsubstituted monovalent condensed aromatic hydrocarbon group having two or three aromatic rings, or a substituted or unsubstituted monovalent aromatic heterocyclic group; and n's each independently represent a number of from 0 to 7.Type: GrantFiled: May 8, 2012Date of Patent: July 2, 2013Assignee: Fuji Xerox Co., Ltd.Inventors: Hidekazu Hirose, Ryosaku Igarashi, Katsuhiro Sato
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Publication number: 20130164662Abstract: An image holding member for an image forming apparatus includes a support and a photosensitive layer disposed on the support and containing a compound represented by following formula (I), wherein R1s each independently represent a substituted or unsubstituted linear or branched alkyl group having from 1 to 8 carbon atoms; Ar's each independently represent a substituted or unsubstituted phenyl group, a substituted or unsubstituted monovalent polynuclear aromatic hydrocarbon group having two aromatic rings, a substituted or unsubstituted monovalent condensed aromatic hydrocarbon group having two or three aromatic rings, or a substituted or unsubstituted monovalent aromatic heterocyclic group; and n's each independently represent a number of from 0 to 7.Type: ApplicationFiled: May 8, 2012Publication date: June 27, 2013Applicant: FUJI XEROX CO., LTD.Inventors: Hidekazu HIROSE, Ryosaku IGARASHI, Katsuhiro SATO
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Patent number: 8247144Abstract: An object of the invention is to provide a photoreceptor for electrophotography which has a low residual potential in an initial stage, is inhibited from increasing in residual potential, is prevented from decreasing in charge potential, and undergoes little fatigue deterioration even upon repeated use. The invention relates to a photoreceptor for electrophotography which has a photosensitive layer containing a cyclic phenol sulfide represented by the following general formula (1): and one or more charge-transporting agents each having an arylamino group in the molecule, and which has excellent durability.Type: GrantFiled: January 24, 2008Date of Patent: August 21, 2012Assignee: Hodogaya Chemical Co., Ltd.Inventors: Makoto Koike, Katsumi Abe, Atsushi Takesue
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Patent number: 8227157Abstract: The present invention provides a single-layer electrophotographic photoreceptor provided with a single-layer photosensitive layer that adapts to an exposing source emitting a laser beam with wavelengths of from 400 nm to 450 nm inclusive and is laminated on a conductive substrate, the single-layer photosensitive layer comprising: an enamine-type compound that functions as both a charge generation material and a charge transport material and is represented by the following general formula (1); and a perylene-type compound that functions as both an electron-transport material and a sensitizer and is represented by the following general formula (2):Type: GrantFiled: June 17, 2009Date of Patent: July 24, 2012Assignee: Sharp Kabushiki KaishaInventors: Koichi Toriyama, Mami Adachi
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Patent number: 8216753Abstract: There is provided an electroactive material having Formula I wherein: Q is the same or different at each occurrence and can be O, S, Se, Te, NR, SO, SO2, or SiR3; R is the same or different at each occurrence and can be hydrogen, alkyl, aryl, alkenyl, or alkynyl; R1 through R8 are the same or different and can be hydrogen, alkyl, aryl, halogen, hydroxyl, aryloxy, alkoxy, alkenyl, alkynyl, amino, alkylthio, phosphino, silyl, —COR, —COOR, —PO3R2, —OPO3R2, or CN.Type: GrantFiled: December 12, 2008Date of Patent: July 10, 2012Assignee: E I du Pont de Nemours and CompanyInventor: Hong Meng
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Patent number: 8029955Abstract: Provide is an electrophotographic photoreceptor exhibiting excellent evenness of halftone images together with fine line reproduction, and an image forming method thereof, as to a photoreceptor in which an oxytitanium phthalocyanine pigment having a maximum diffraction peak at a Bragg angle (2?±0.2°) of 27.2° in CuK? X-ray diffraction. Also disclosed is an electrophotographic photoreceptor possessing a body having cylindrical conductive support provided thereon photosensitive layer containing oxytitanium phthalocyanine pigment having maximum diffraction peak at a Bragg angle (2?±0.2°) of 27.2° in CuK? X-ray diffraction, and flanges jointed at both ends of the body, wherein at least one of flanges is fitted with driving shaft having drive hole having at least 3 sides, and a ratio B/A of cross-sectional area B of engaging part of rotation shaft to rotate the electrophotographic photoreceptor with respect to cross-sectional area A of the drive hole is 0.890-0.998.Type: GrantFiled: January 29, 2009Date of Patent: October 4, 2011Assignee: Konica Minolta Business Technologies, Inc.Inventors: Eiichi Sakai, Yoshihiko Eto, Kimiyuki Itou, Akihiko Itami, Takeo Oshiba
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Patent number: 7794907Abstract: A hydrazone compound capable of realizing an electrophotographic photoreceptor having good electric properties such as good sensitivity and light responsibility, good electric and mechanical durability and good environment stability, is provided. The hydrazone compound is represented by the following general formula (1). The compound is contained in the charge transporting layer of the electrophotographic photoreceptor.Type: GrantFiled: September 7, 2005Date of Patent: September 14, 2010Assignee: Sharp Kabushiki KaishaInventors: Akihiro Kondoh, Takatsugu Obata
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Publication number: 20100190956Abstract: An intermediate transfer media, such as a belt, that includes a polyaniline viologen charge transfer complex.Type: ApplicationFiled: January 27, 2009Publication date: July 29, 2010Applicant: Xerox CorporationInventor: Jin Wu
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Patent number: 7642027Abstract: A charge transport composition is provided including a cyclo-aliphatic ether compound. One purpose of the cyclo-aliphatic ether compound is to improve the resistance to crazing, crystallization and etching of the charge transport layer. The charge transport composition may be coated along with a charge generation composition onto a conductive substrate to form a photoconductor. The charge transport composition may therefore be employed in a photoconductor located in a printer or a printer cartridge.Type: GrantFiled: September 27, 2006Date of Patent: January 5, 2010Assignee: Lexmark International, Inc.Inventors: James Alan Hartman, Ronald Harold Levin, Weimei Luo, Dat Quoc Nguyen, Tanya Yvonne Thames
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Publication number: 20090233198Abstract: A process for producing an overprint is provided that includes a step of preparing a printed material by printing on a printing substrate, a step of coating the printed material with a photocurable composition, and a step of photocuring the photocurable composition, the photocurable composition including (1) a bridged ring hydrocarbon group-containing cationically polymerizable compound and (2) a photo-acid generator. There is also provided an overprint produced by the process. Furthermore, there is provided a photocurable composition that includes (1) a bridged ring hydrocarbon group-containing cationically polymerizable compound and (2) a photo-acid generator.Type: ApplicationFiled: March 11, 2009Publication date: September 17, 2009Applicant: FUJIFILM CorporationInventor: Ryuki KAKINO
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Patent number: 7563548Abstract: An amine compound represented by the general formula (1), which is incorporated as a charge-transporting substance to a charge-transporting layer of an electrophotographic photoreceptor: (in which Ar1, Ar2 and Ar3 each represents an optionally-substituted aryl group, or an optionally-substituted monovalent heterocyclic ring residue. Ar4 represents an optionally-substituted arylene group, or an optionally-substituted bivalent heterocyclic ring residue. R1 represents an optionally-substituted alkyl group, an optionally-substituted aryl group, an optionally-substituted monovalent heterocyclic ring residue, or an optionally-substituted aralkyl group. R2 and R3 each represents a hydrogen atom, an optionally-substituted alkyl group, an optionally-substituted aryl group, an optionally-substituted monovalent heterocyclic ring residue, or an optionally-substituted aralkyl group. n represents an integer of 1 or 2.Type: GrantFiled: November 30, 2004Date of Patent: July 21, 2009Assignee: Sharp Kabushiki KaishaInventors: Akihiro Kondoh, Takatsugu Obata
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Patent number: 7534540Abstract: An improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where X and X? are, each independently, a linking group; Ar comprises an aromatic group; R1, R2, and R3 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; and E1 and E2 are, each independently, a reactive ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, imaging methods, and a polymeric charge transport material prepared from the charge transport material above are described.Type: GrantFiled: April 29, 2004Date of Patent: May 19, 2009Assignee: Samsung Electronics Co., Ltd.Inventors: Zbigniew Tokarski, Nusrallah Jubran, Vytautas Getautis, Vygintas Jankauskas, Tadas Malinauskas, Edmundas Montrimas
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Patent number: 7534541Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula: where n is an integer between 1 and 10, inclusive; R1 comprises a functional group selected from the group consisting of a reactive ring group, an ethylenically unsaturated group, a reactive polar group, a hydrazone group, and an azine group; R2, R3, R4, R5, and R6 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, a heterocyclic group, or a part of a ring group; X is a bond or a linking group; and Q is O, S, or NR where R is H, an alkyl group, an acyl group, an alkenyl group, an alkynyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound.Type: GrantFiled: January 27, 2005Date of Patent: May 19, 2009Assignee: Samsung Electronics Co., Ltd.Inventors: Maryte Daskeviciene, Vytautas Getautis, Tadeus Lozovski, Edmundas Montrimas
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Publication number: 20090047589Abstract: Disclosed is an electrophotographic photoreceptor which is excellent in wear resistance and electrical characteristics. Specifically disclosed is an electrophotographic photoreceptor containing a polyester resin in a photosensitive layer provided on an electroconductive substrate. The polyester resin is composed of a copolymer represented by the general formula 1 below, which has a viscosity average molecular weight (Mv) of 10,000-300,000 and contains a diphenyl ether 4,4?-dicarboxylic acid component and a bivalent phenol component. In the general formula 1, A represents a diphenyl ether 4,4?-dicarboxylic acid residue represented by the formula A below, and B represents a bivalent phenol residue represented by the formula B below. In the formula A, each of Ra1 and Ra2 independently represents a hydrogen atom or a monovalent substituent which may have a substituent, and each of n and m is independently an integer from 0 to 4.Type: ApplicationFiled: October 6, 2008Publication date: February 19, 2009Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Hiroyuki TAJIMA, Yuuta Kumano
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Publication number: 20090035678Abstract: The present invention discloses a mixed cyclic phenol sulfide which is a mixture of the cyclic phenol sulfide wherein m is 8 and the cyclic phenol sulfide wherein m is an integer other than 8, the cyclic phenol sulfide being represented by the following formula (1): wherein R is a straight or branched alkyl group having 1 to 6 carbon atoms, and m is an integer from 4 to 9; or a cyclic phenol sulfide of formula (1) wherein m is 8. The present invention also discloses a charge control agent which comprises the above sulfide(s) as the active ingredient; and a toner which comprises the charge control agent, a coloring agent and a binder resin. This charge control agent is particularly useful for color toners, and it speeds up charging risetime, and has a high charge amount and charging characteristics excellent in the environmental stability. Further, the charge control agent is safe since it does not have any problem with the waste regulations.Type: ApplicationFiled: September 29, 2008Publication date: February 5, 2009Applicant: HODOGAYA CHEMICAL CO., LTD.Inventors: Masateru Yasumura, Masami Ito, Naohiro Tarumoto, Yoshikazu Aoki, Masafumi Umekawa, Masaki Okubo, Hideyuki Otsuka, Jun Watanabe
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Patent number: 7479357Abstract: An organophotoreceptor that includes: (a) a charge transport material having the formula wherein A is selected from heterocyclic groups, naphthyl group, alkylsulfonylphenyl, stilbenyl or the group X, wherein X is represented by the formula B is selected from hydrogen, alkyl group, and an aryl group, with the proviso that when A is naphthyl, B is naphthyl; or where R1 is selected from the group consisting of N-pyrrolyl, N-pyrazolyl, N-tetrazolyl, N-indolyl, N-carbazolyl, N-triazolyl, N-imidazolyl, N-benzimidazolyl, N-indazolyl, and N-benzotriazolyl group, and R3 is a 9-fluorenone group. (b) a charge generating compound; and (c) an electrically conductive substrate.Type: GrantFiled: September 13, 2002Date of Patent: January 20, 2009Assignee: Samsung Electronics Co., Ltd.Inventors: Kam W. Law, Nusrallah Jubran, Zbigniew Tokarski, Alan R. Katritzky, Ritu Jain, Rexiat Maimait, Anatoliy V. Vakulenko
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Patent number: 7468231Abstract: An imaging member comprising a supporting substrate; a single layer photoreceptor for both charge generation and charge transport disposed on the supporting substrate, the single layer photoreceptor comprising a binder containing a polyhedral oligomeric silsesquioxane; a cross-linking agent; a charge component; an electron transport component; and a charge generating component.Type: GrantFiled: February 9, 2005Date of Patent: December 23, 2008Assignee: Xerox CorporationInventors: Liang-Bih Lin, Jin Wu, John S. Chambers, Francisco J. Lopez
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Patent number: 7378203Abstract: Improved charge transport material comprises the formula: where M comprises a metallocenyl group; Y comprises a functional group selected from the group consisting of a metallocenyl group, a hydrazone group, an azine group, a reactive ring group, an ethylenically unsaturated group, and combinations thereof; R1 and R2 comprise, each independently, H, an organic group, or an organometallic group; and X is a bond, O, S, an aminylene group, a sulfonyl group, an organic linking group, or a combination thereof.Type: GrantFiled: March 16, 2005Date of Patent: May 27, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Patrick Knoll, Vytautas Getautis, Tadas Malinauskas, Maryte Daskeviciene, Edmundas Montrimas, Jonas Sidaravicius
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Patent number: 7364825Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula: where E comprises a functional group selected from the group consisting of a reactive ring group, an ethylenically unsaturated group, a hydrazone group, and an azine group; R1, R2, and R3 comprise, each independently, H or an organic group; X is a bond or a linking group, with the proviso that when E comprises a reactive ring group, X is a linking group; and Y is a nitrogen-containing aromatic heterocyclic group; and (b) a charge generating compound.Type: GrantFiled: February 7, 2005Date of Patent: April 29, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Ramunas Lygaitis, Juozas V. Grazulevicius, Valentas Gaidelis, Vygintas Jankauskas
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Patent number: 7364823Abstract: An amine compound represented by the following general formula (1) is incorporated as a charge-transporting substance into a charge-transporting layer of an electrophotographic photoreceptor.Type: GrantFiled: March 30, 2005Date of Patent: April 29, 2008Assignee: Sharp Kabushiki KaishaInventors: Akihiro Kondoh, Takatsugu Obata
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Patent number: 7351508Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y comprises an aromatic group; V1 and V2 comprise, each independently, a vinyl containing group; and R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an acyl group, an ether group, an ester group, an alkenyl group, an alkynyl group, a heterocyclic group, an aromatic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, electrophotographic imaging methods, and charge transport materials are also described.Type: GrantFiled: October 12, 2004Date of Patent: April 1, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Juozas V. Grazulevicius, Gintaras Buika, Vygintas Jankauskas, Valentas Gaidelis, Ruta Budreckiene, Zbigniew Tokarski, Nusrallah Jubran
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Publication number: 20080076051Abstract: A charge transport composition is provided including a cyclo-aliphatic ether compound. One purpose of the cyclo-aliphatic ether compound is to improve the resistance to crazing, crystallization and etching of the charge transport layer. The charge transport composition may be coated along with a charge generation composition onto a conductive substrate to form a photoconductor. The charge transport composition may therefore be employed in a photoconductor located in a printer or a printer cartridge.Type: ApplicationFiled: September 27, 2006Publication date: March 27, 2008Inventors: James Alan Hartman, Ronald Harold Levin, Weimei Luo, Dat Quoc Nguyen, Tanya Yvonne Thames
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Patent number: 7348116Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y comprises an aromatic heterocyclic group; X is a bond or a linking group; E comprises a reactive ring group or a reactive functional group; and R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an acyl group, an ether group, an alkenyl group, an alkynyl group, a heterocyclic group, an aromatic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, electrophotographic imaging methods, and bridged charge transport materials derived form the charge transport material above are also described.Type: GrantFiled: September 3, 2004Date of Patent: March 25, 2008Assignee: Samsung Electronics, LtdInventors: Ausra Matoliukstyte, Valentas Gaidelis, Juozas V. Grazulevicius, Vygintas Jankauskas, Beata Klejevskaja, Nusrallah Jubran, Zbigniew Tokarski
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Patent number: 7320849Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y1 and Y2 are, each independently, an arylamine group; R1 and R2 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; X1 and X2, each independently, are bridging groups; E1 and E2 are, each independently, an epoxy group; and Z is a linking group comprising an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. The charge transport materials can be crosslinked to a polymeric bind, either directly or through a crosslinking agent. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: December 31, 2003Date of Patent: January 22, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Vytautas Getautis, Tadas Malinauskas, Vygintas Jankauskas, Valentas Gaidelis
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Patent number: 7297458Abstract: A photoconductive member containing a supporting substrate, a photogenerating layer, and a charge transport layer and wherein the photogenerating layer comprises a photogenerating component, and an electron transport component.Type: GrantFiled: June 29, 2004Date of Patent: November 20, 2007Assignee: Xerox CorporationInventors: Nancy L. Belknap, Andronique Ioannidis, Cindy C. Chen, Lanhui Zhang, James M. Duff, John F. Graham, Timothy P. Bender
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Patent number: 7261987Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y comprises an aromatic group; X is a —(CH2)n— group, where n is an integer between 1 and 10, inclusive, and one or more of the methylene groups is optionally replaced by another atom or group; Q1, Q2, and Q3 are, each independently, O, S, or NR; and R, R1, R2, and R3 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an amino group, an acyl group, an alkoxy group, an alkylsulfanyl group, an aromatic group, or a heterocyclic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: July 28, 2004Date of Patent: August 28, 2007Assignee: Samsung Electronics Co., LtdInventors: Nusrallah Jubran, Zbigniew Tokarski
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Patent number: 7220523Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1, R2, R3, R4, R5, and R6 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; X1 and X2 are, each independently, a —(CH2)n— group, where n is an integer between 1 and 10, inclusive; X3 is linking group; and Q1, Q2, Q3, Q4, Q5, and Q6 are, each independently, O, S, NR, NC(?O)R? where R and R? are, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: June 10, 2004Date of Patent: May 22, 2007Assignee: Samsung Electronics Co., Ltd.Inventors: Zbigniew Tokarski, Nusrallah Jubran, Ramunas Lygaitis, Juozas V. Grazulevicius, Edmundas Montrimas, Jonas Sidaravicius
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Patent number: 7183028Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1, R2, R3, and R4 are, independently, an alkyl group, an alkaryl group, an aryl group, or a part of a cyclic group; R5 is hydrogen, an alkyl group, an alkaryl group, an aryl group, or a heterocyclic group; X comprises an aromatic group, such as an aryl group or an aromatic heterocyclic group; Y is a linking group; and Z comprises an epoxy group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: December 30, 2003Date of Patent: February 27, 2007Assignee: Samsung Electronics Co., Ltd.Inventors: Zbigniew Tokarski, Nusrallah Jubran, Kam W. Law, Vytautas Getautis, Maryte Daskeviciene, Edmundas Montrimas, Janina Gavutiene
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Patent number: 7175956Abstract: The invention is to provide an organic photoconductive material capable of realizing electrophotographic photoreceptors of high reliability that have high charge potential, high sensitivity, good responsiveness to light and good durability, of which the characteristics do not lower even when they are driven at low temperatures or at high speed and even when they are exposed to light, and to provide an electrophotographic photoreceptor that comprises the material and an image-forming apparatus. An organic photoconductive material of the following general formula (1), for example, an enamine compound of the following structural formula (1-1) is produced.Type: GrantFiled: September 3, 2003Date of Patent: February 13, 2007Assignee: Sharp Kabushiki KaishaInventors: Takatsugu Obata, Akihiro Kondoh, Kazuya Ishida
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Patent number: 7169520Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, H, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C?O, O?S?O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; Y comprises a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic grType: GrantFiled: October 31, 2003Date of Patent: January 30, 2007Assignee: Samsung Electronics Co., LtdInventors: Nusrallah Jubran, Zbigniew Tokarski, Juozas V. Grazulevicius, Vytautas Getautis, Jolita Ostrauskaite, Jurate Simokaitiene, Vygintas Jankauskas
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Patent number: 7094510Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula X-Z-X? where X and X? are, each independently, a (9-fluorenylidene)malononitrile group, and Z is a linking group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: December 30, 2003Date of Patent: August 22, 2006Assignee: Samsung Electric Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Kam W. Law, Eric Morrison, Vytautas Getautis, Vygintas Jankauskas
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Patent number: 7090953Abstract: This invention relates to a novel organophotoreceptor that comprises an electrically conductive substrate and photoconductive element on the electrically conductive substrate, the photoconductive element having a) a charge transport compound having the formula R1 is an aromatic group, an alkyl group, an alkenyl group, or a heterocyclic group; R2 comprises an (N,N-disubstituted)arylamine group; R3 comprises an epoxy group; R4 is H, an aromatic group, an alkyl group, an alkenyl group, or a heterocyclic group; and X is a first linking group; and (b) a charge generating compound. The epoxy group can be reacted with a functional group within the polymer to form a polymeric charge transport compound either directly or through a crosslinking agent. Corresponding electrophotographic apparatuses and imaging methods are also described.Type: GrantFiled: February 4, 2004Date of Patent: August 15, 2006Assignee: Samsung Electronics Co., Ltd.Inventors: Vytautas Getautis, Maryte Daskeviciene, Tadas Malinauskas, Edmundas Montrimas, Jonas Sidaravicius, Zbigniew Tokarski, Nusrallah Jubran, Kam W. Law
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Patent number: 7067566Abstract: Triazine ring based polymers for photoinduced liquid crystal alignment introduces photoactive groups for inducing, reinforcing, improving and preserving liquid crystal alignment, for example photoreactor such as cinnamate, coumarin, chalcone and maleimide, as a chain to have at least one photoactive group. One of the photoactive groups can experience Fries rearrangement which induces liquid crystal alignment, and other groups can experience photodimerization, photoisomerization, photocrosslinkng or photodegradation to reinforce, change or preserve the generated alignment.Type: GrantFiled: November 11, 2002Date of Patent: June 27, 2006Assignee: LG Cable Ltd.Inventors: Dongcheon Shin, Jinyool Kim, Kyusoon Park, Taemin Kim
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Patent number: 7029812Abstract: This invention relates to a novel organophotoreceptor that comprises an electrically conductive substrate and photoconductive element on the electrically conductive substrate, the photoconductive element having a) a novel charge transport compound having the formula where X is a divalent hydrocarbon group of 1 to 30 carbon atoms, or a divalent hydrocarbon group of 1 to 30 carbon atoms where there is at least one substitution of a carbon atom by a heteroatom provided that no two heteroatoms may be adjacent within the backbone of an aliphatic divalent hydrocarbon radical, R1 is an aryl group or a heterocyclic group, R2 is a (N,N-disubstituted)arylamine group, and R3 is an epoxy group; and (b) a charge generating compound. The epoxy group can be reacted with a functional group within the polymer to form a polymeric charge transport compound either directly or through a crosslinking agent.Type: GrantFiled: August 5, 2003Date of Patent: April 18, 2006Assignee: Samsung Electronics Co., Ltd.Inventors: Zbigniew Tokarski, Nusrallah Jubran, Kam W. Law, Vytautas Getautis, Jonas V. Sidaravicius, Maryte Daskeviciene, Vygintas Jankauskas, Edmundas Montrimas, Valentas Gaidelis, Albina Stanisauskaite
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Patent number: 7014968Abstract: Improved organophotoreceptor comprises a photoconductive element comprising: (a) a charge transport material having the formula where Y1 and Y2 are, each independently, a bond, —CR1?N—NR2—, or —CR3?N—N?CR4— where R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; X1 and X2 are, each independently, a linking group; T1 and T2 are, each independently, a thiiranyl group, H, an alkyl group, an alkenyl group, or an aromatic group with the proviso that at least one of T1 and T2 is a thiiranyl group; and Ar comprises an aromatic group with the proviso that when both Y1 and Y2 are a bond and one of T1 and T2 is not a thiiranyl group, Ar comprises a bis[(N,N-disubstituted)amino]aromatic group or a bicarbazole group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: December 30, 2003Date of Patent: March 21, 2006Assignee: Samsung Electronics Co., Ltd.Inventors: Zbigniew Tokarski, Nusrallah Jubran, Vytautas Getautis, Osvaldas Paliulis, Edmundas Montrimas, Valentas Gaidelis
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Patent number: 7011918Abstract: This invention includes an organophotoreceptor having an electrically conductive substrate and photoconductive element on the electrically conductive substrate, the photoconductive element having a) a polymeric charge transport composition with the formula where Y1 and Y2 are, each independently, a bond, a —CR1?N—NR2— group, or a —CR3?N—N?CR4— group; R, R?, R?, R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, an aromatic group, or a part of a ring group; X1 and X2 are, each independently, a linking group; T2 comprises a thiiranyl group, H, an alkyl group, an alkenyl group, or an aromatic group; Ar comprises an aromatic group; Z is a bridging group; and n is a distribution of integers between 1 and 100,000 with an average value at least 2; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging processes are also described.Type: GrantFiled: February 27, 2004Date of Patent: March 14, 2006Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Kam W. Law
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Patent number: 6994941Abstract: An electrophotographic photosensitive member is provided having a support and a photosensitive layer provided on the support and containing at least one kind of charge-transporting material which has a specific structure with a molecular weight of from 1,500 to 4,000, and is held in a proportion of from 90% by weight to 100% by weight based on the total weight of the charge-transporting material.Type: GrantFiled: August 28, 2003Date of Patent: February 7, 2006Assignee: Canon Kabushiki KaishaInventors: Takakazu Tanaka, Itaru Takaya, Yuka Ishiduka, Harunobu Ogaki, Kenichi Kaku
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Patent number: 6991881Abstract: The present invention relates to an electrophotographic photosensitive member having a support and provided thereon a photosensitive layer. The photosensitive layer contains a high-molecular weight charge-transporting material having a specific repeating structural unit. The high-molecular weight charge-transporting material has a weight-average molecular weight Mw of 1,500 or more and an energy level of highest occupied molecular orbital, EHOMO, of from ?8.3 eV or more to ?8.0 eV or less as found by semiempirical molecular-orbital calculation. The present invention also relates to a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member.Type: GrantFiled: April 25, 2003Date of Patent: January 31, 2006Assignee: Canon Kabushiki KaishaInventors: Harunobu Ogaki, Akira Yoshida, Takakazu Tanaka, Itaru Takaya, Yuka Ishiduka
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Patent number: 6972147Abstract: A fluorescent article is disclosed comprising a polymer matrix comprising a polymer having in its backbone repeating units of a U.V. light absorbing moiety, or a moiety capable of being transformed by photo-Fries rearrangement into a U.V. light absorbing moiety, the matrix further comprising a fluorescent dye. The matrix affords surprisingly improved fluorescence protection as compared to prior fluorescent articles having only U.V. light absorbing additives.Type: GrantFiled: November 9, 2000Date of Patent: December 6, 2005Assignee: Avery Dennison CorporationInventors: Guang-Xue Wei, Drew J. Buoni, Kimberly A. Dockus
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Patent number: 6960418Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1, R2, R3, and R4 are, independently, an alkyl group, an alkaryl group, or an acyl group; Y is an alkyl group, alkaryl group, or aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where in is an integer between 1 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C?O, O?S?O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R,5 and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; and E is an epoxy group; and (b) a charge generating compound.Type: GrantFiled: October 23, 2003Date of Patent: November 1, 2005Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Vytautas Getautis, Osvaldas Paliulis, Valentas Gaidelis, Edmundas Montrimas
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Patent number: 6946227Abstract: A photoconductive imaging member containers of a supporting substrate, and thereover a single layer comprised of a mixture of a photogenerator component, a charge transport component, an electron transport component, and a polymer binder, and wherein the photogenerating component is a pigment.Type: GrantFiled: November 20, 2002Date of Patent: September 20, 2005Assignee: Xerox CorporationInventors: Liang-Bih Lin, Richard H. Nealey, Ah-Mee Hor, James M. Duff, Timothy P. Bender, Andrew R. Melnyk, Andronique Ioannidis, Harold F. Hammond, Linda L. Ferrarese, Cindy C. Chen, James M. Markovics, Kenny-Tuan T. Dinh
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Patent number: 6852458Abstract: An electrophotographic photoreceptor has excellent electrical properties and is stable even upon repeated use. An electrophotographic apparatus using the electrophotographic photoreceptor uses a compound having an excellent electron transporting ability in a photosensitive layer of the electrophotographic photoreceptor. An electrophotographic photoreceptor, in which a photosensitive layer is located on an electrically conductive substrate either directly or via an undercoat layer, contains a compound having a structure represented by the general formula (I). An electrophotographic apparatus contains the above-mentioned electrophotographic photoreceptor, and carries out a charging process through a positive charging process.Type: GrantFiled: February 4, 2003Date of Patent: February 8, 2005Assignee: Fuji Electric Imaging Device Co., Ltd.Inventors: Kenichi Ohkura, Yoshihiro Ueno, Masami Kuroda, Nobuyuki Sekine