Development Inhibitor Releaser (dir) Patents (Class 430/957)
  • Patent number: 4824772
    Abstract: A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the material contains at least one compound represented by general formula (I) described below and at least one compound represented by general formula (II) described below.A--PDI (I)wherein A represents a group capable of releasing PDI upon reaction with an oxidation product of a developing agent; and PDI represents a group which forms a development inhibitor upon reaction with an oxidation product of a developing agent after being released from A; ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of being released upon coupling; Za, Zb and Zc each represents a methane group, a substituted methine group, .dbd.N-- or --N--, wherein one of the Za--Zb bond and the Zb--Zc bond is a double bond and the other is a single bond; wherein R.sub.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: April 25, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Keiji Mihayashi
  • Patent number: 4824759
    Abstract: A method for forming an image, which comprises heating a light-sensitive material in the presence of a compound capable of forming a 2-mercaptobenzazole ring by a ring closing reaction when heated.In accordance with the method of the present invention, development is stopped at an appropriate time of development whereby an image having a high maximum density and low fog is obtained.A heat-developable light-sensitive material containing the compound is also disclosed.
    Type: Grant
    Filed: February 7, 1986
    Date of Patent: April 25, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Hiroshi Kitaguchi, Masashi Takeuchi, Masaaki Tsukase, Masatoshi Kato
  • Patent number: 4818664
    Abstract: A process for processing a silver halide color photographic material which comprises processing, after color development, a silver halide color photographic material with a processing solution having a bleaching faculty using an aminopolycarboxylic acid ferric complex salt as an oxidizing agent, said color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and at least one compound releasing by the reaction with an oxidation product of a developing agent a group releasing or forming development inhibitor by the reaction with another molecule of an oxidation product of a developing agent.
    Type: Grant
    Filed: May 20, 1987
    Date of Patent: April 4, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Ueda, Keiji Mihayashi, Seiji Ichijima
  • Patent number: 4818670
    Abstract: A silver halide photographic material is disclosed, which has high image quality in addition to high sensitivity. The photographic material comprises a support and at least one silver halide light-sensitive emulsion layer containing a compound being capable of splitting off a diffusible development-inhibitor or a precursor thereof upon a reaction with an oxidized product of a color developing agent. At least one of the silver halide light-sensitive emulsion layer layer and a layer adjacent to the light-sensitive emulsion layer contains a silver halide emulsion comprising a silver halide grain having an internal fog nucleus.
    Type: Grant
    Filed: February 17, 1987
    Date of Patent: April 4, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshihiko Yagi, Hiroshi Shimazaki
  • Patent number: 4814261
    Abstract: A silver halide photographic material is disclosed. The photographic material comprises a support having provided thereon at least one light-sensitive silver halide emulsion layer, the silver halide emulsion layer or a layer adjacent to the emulsion layer comprising a compound represented by the following formula (I): ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3, which may be the same or different, each represents a hydrogen atom or a group cleaved by an alkali; R.sub.4 represents an electron attracting group having .sigma..rho. value of Hammett's substituent constant of 0.3 or more; R.sub.5 represents a group substitutable on the benzene ring; n represents 0 or 1; and DI represents a development restrainer or a precursor thereof; and when any two of R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are adjacent each other, each of the two groups may represent a divalent group and the two groups may be bonded to form a heterocyclic group.
    Type: Grant
    Filed: July 16, 1987
    Date of Patent: March 21, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Shigeo Hirano
  • Patent number: 4812389
    Abstract: A process for processing a DIR coupler-containing silver halide color photographic material for photographing use in a continuous manner with replenishment of a developer is disclosed in which said DIR coupler is a coupler which has in a coupling site a group that functions as a development inhibitor or a development inhibitor precursor upon being eliminated from the coupling active site by color development processing and that will be decomposed to a compound exerting substantially no influences on photographic properties after flowing into a color developing solution, said development inhibitor having a half-value period of 4 hours or shorter than that at a pH of 10.0, and in which the developing solution is replenished in an amount of 700 ml or less per m.sup.2 of developed light-sensitive materials.
    Type: Grant
    Filed: September 25, 1986
    Date of Patent: March 14, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kei Sakanoue, Seiji Ichijima, Shinzo Kishimoto
  • Patent number: 4806459
    Abstract: A color photographic material comprising a support having provided thereon a blue-sensitive silver halide emulsion layer containing at least one coupler capable of reacting with an oxidation product of an aromatic primary amine developing agent to form a yellow dye, at least one coupler capable of reacting with said oxidation product to form a cyan dye and not to produce a diffusible development inhibitor or a precursor thereof, and at least one compound capable of reacting with said oxidation product to produce a diffusible development inhibitor or a precursor thereof.
    Type: Grant
    Filed: May 6, 1987
    Date of Patent: February 21, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsumi Makino, Noboru Sasaki, Koji Takahashi
  • Patent number: 4804619
    Abstract: A silver halide color photographic material improved in image quality such as sharpness and graininess is disclosed. The silver halide color photographic material is comprises support having thereon photographic component layers comprising at least two silver halide emulsion layers, adjacently arranged to each other, having the same color sensitivity and different speed from each other. In this photographic material the highest speed layer among these emulsion layers contains a DIR compound capable of releasing a diffusible development inhibitor or a diffusible compound capable of releasing a development inhibitor, and the total thickness of the silver halide emulsion layers is within the range of from 1.5 .mu.m to 5 .mu.m, and the silver halide emulsion layers are allowed to have the interposition of a non-light-sensitive intermediate layer.
    Type: Grant
    Filed: October 23, 1987
    Date of Patent: February 14, 1989
    Assignee: Konica Corporation
    Inventors: Yoshitaka Yamada, Masao Iwamura
  • Patent number: 4801520
    Abstract: A direct positive color light-sensitive material comprising a support having provided thereon at least one photographic emulsion layer containing unfogged internal latent image type silver halide particles and a color image forming coupler, wherein said color image forming coupler itself is substantially nondiffusible and produces or releases a dye upon oxidation coupling with a color developing agent, and said light-sensitive material contains at least one development inhibitor-releasing type coupler selected from the group consisting of compounds represented by formulae (D-I) and (D-II)Coup--Z (D-I)Coup--TIME--Z (D-II)wherein Coup represents a coupler residual group; Z represents a diffusible development inhibitor or a precursor thereof; and TIME represents a timing group.
    Type: Grant
    Filed: July 17, 1987
    Date of Patent: January 31, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Inoue, Tatsuo Heki
  • Patent number: 4798784
    Abstract: A method for processing a silver halide color photographic material which comprises, after color development of an exposed silver halide color photographic material containing a hydrolyzable type DIR coupler, rapidly processing the developed silver halide color photographic material with a liquid having a bleaching ability and subsequently with a liquid having a bleach-fixing ability, to thereby form a color image.In accordance with the method for processing a silver halide color photographic material, desilveration is completed in a short period of time and color photographic images having excellent color reproducibility and fastness are obtained.
    Type: Grant
    Filed: November 26, 1986
    Date of Patent: January 17, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinzo Kishimoto, Toshihiro Nishikawa, Akira Abe, Junya Nakajima
  • Patent number: 4791049
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide photographic material contains at least one compound represented by the following general formula (I):A--Time).sub.t X (I)wherein A represents an oxidation reduction moiety comprising an atomic group which does not enable --Time).sub.t X to be released until the oxidation reduction moiety is oxidized during photographic development processing; Time represents a timing group which is connected to A through a sulfur atom, a nitrogen atom or an oxygen atom; t represents an integer of 0 or 1; and X represents a group represented by the following general formula (II): ##STR1## wherein R represents a straight chain or branched chain alkylene group, a straight chain or branched chain alkenylene group, a straight chain or branched chain aralkylene group or an arylene group; Z represents a polar substituent; Y represents ##STR2## R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.
    Type: Grant
    Filed: April 23, 1987
    Date of Patent: December 13, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Shigeo Hirano, Hideo Usui
  • Patent number: 4783396
    Abstract: The present invention provides silver halide photographic materials containing a havel compound, which when reduced, releases a photographically useful group as triggered off by the cleavage of the nitrogen-oxygen single bond in the compound and which is represented by the following general formula (I): ##STR1## wherein EAG represents a group which accepts an electron from a reducing substance; N and O each represents nitrogen atom and an oxygen atom, respectively; R.sup.1 and R.sup.2 each represents a substituent other than a hydrogen atom, and when R.sup.1 or R.sup.2 is bonded to --(Time).sub.t PUG, R.sup.1 or R.sup.2 is a mere bond or a substituent other than a hydrogen atom, and R.sup.1 and R.sup.
    Type: Grant
    Filed: October 30, 1986
    Date of Patent: November 8, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koki Nakamura, Sahigeru Nakamura
  • Patent number: 4782012
    Abstract: Photographic elements and processes are described which employ compounds capable of releasing, as a function of silver halide development, a deactivatable development inhibitor to provide a combination of desirable sensitometric results. The deactivatable development inhibitor has the structure: ##STR1## wherein X is alkylene of 1 to 3 carbon atoms;R is alkyl of 1 to 4 carbon atoms; andthe sum of the carbon atoms in X and R is 5 or less.
    Type: Grant
    Filed: July 17, 1987
    Date of Patent: November 1, 1988
    Assignee: Eastman Kodak Company
    Inventors: Roy C. DeSelms, Jon A. Kapecki
  • Patent number: 4775610
    Abstract: A method for the formation of a photographic image including a heating step, comprising heating a photographic material in the presence of at least one compound selected from those represented by formulae (I) and(II) ##STR1## wherein A represents a non-metallic atomic group forming a carbocyclic aromatic ring or a heterocyclic aromatic ring;X represents a nucleophilic group or a precursor thereof;Q represnts a hydrogen atom or a substituted or unsubstituted alkyl, cycloalkyl, or aryl group; andPUG represents a photographically useful group.
    Type: Grant
    Filed: May 27, 1986
    Date of Patent: October 4, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Kozo Sato, Masatoshi Kato
  • Patent number: 4772537
    Abstract: A silver halide photographic material which contains at least one blocked photographic reagent having in the molecule thereof at least one ##STR1## structure and capable of releasing a photogrpahically useful reagent by cleavage of the ##STR2## bond by a nucleophilic attack of a nucleophilic reagent on the structure and a subsequent intramolecular electron transfer reaction or an intramolecular nucleophilic reaction and which has at least one photosensitive silver halide emulsion layer. There is provided a photogrphic material which includes, in combination, a photographic reagent precursor capable of releasing a photographically useful reagent timely on photographic processing and a photosensitive silver halide emulsion layer.
    Type: Grant
    Filed: September 18, 1986
    Date of Patent: September 20, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Isamu Itoh, Mitsunori Ono
  • Patent number: 4772545
    Abstract: A silver halide photographic material in which a silver iodobromide emulsion having an iodide content of 2 mole % or more and an organometallic salt functioning as a development inhibitor are employed in combination, whereby an improvements in graininess and sharpness of a developed image are achieved and high photographic speed is retained.A process for producing silver images using the silver halide photographic material is also disclosed.
    Type: Grant
    Filed: July 22, 1986
    Date of Patent: September 20, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shingo Nishiyama, Kiyoshi Kawai
  • Patent number: 4770982
    Abstract: A silver halide photographic material is disclosed which contains a compound represented by formula (I)RED--L.sub.1).sub.v B--L.sub.2).sub.w PUG (I)wherein RED represents a group adapted to release the group (L.sub.1).sub.v B--L.sub.2).sub.w PUG upon oxidation: L.sub.1 represents a group adapted to release the group B--L.sub.2).sub.w PUG after cleavage from RED; B represents a group which, after cleavage of the bond with L.sub.1 or RED, releases the group (L.sub.2).sub.w PUG upon reaction with an oxidized developing agent; L.sub.2 represents a group which, after cleavage from B, releases PUG; PUG represents a photographically useful group; and v and w each represents 0 or 1.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: September 13, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Shigeo Hirano, Koki Nakamura, Keiji Mihayashi
  • Patent number: 4770990
    Abstract: A silver halide photographic material is disclosed. The material comprises a support and at least one silver halide emulsion layer formed thereon, in which said emulsion layer or other layer contains a compound represented by formula (I) ##STR1## wherein X represents an atomic group capable of releasing (Time).sub.t PUG by undergoing an oxidation-reduction reaction with CA.dbd.CR.sub.1 --CR.sub.2).sub.n C.sub.B ; C.sub.A and C.sub.B each represents a carbon atom; n represents an integer of 0, 1, 2, or 3; R.sub.1 and R.sub.2 each a hydrogen atom or a group substitutable for a hydrogen atom; EWG represents an electron withdrawing group having a Hammett's .sigma. para value greater than 0.3; --Time).sub.t PUG represents a group bonded to C.sub.B through an oxygen atom thereof; Time represents a timing group; t represents 0 or 1; and PUG represents a photographically useful group.
    Type: Grant
    Filed: April 14, 1986
    Date of Patent: September 13, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koki Nakamura, Shigeo Hirano, Osamu Takahashi
  • Patent number: 4762777
    Abstract: Photographically useful compounds, i.e. in the present context compounds which, under development conditions, chemically react imagewise, after imagewise exposure, to produce desired reaction products in imagewise distribution, may be incorporated in the layers of photographic recording materials in the form of aqueous dispersions of polyurea or polyurethane compounds containing recurring structural units corresponding to the following formula:Q(--Y).sub.n Iin which Q represents the residue of the photographically useful compound; the other symbos are as defined in the specification.
    Type: Grant
    Filed: October 20, 1987
    Date of Patent: August 9, 1988
    Assignee: Agfa-Gevaert AG
    Inventors: Guter Helling, Helmut Reiff, Friedrich-Wilhelm Kunitz
  • Patent number: 4762778
    Abstract: A silver halide color photographic light-sensitive material has a support and at least one silver halide emulsion layer. At least one of the silver halide emulsion layers has a group of substantially monodisperse core/shell type silver halide grains having a value of not greater than 0.15. This value is obtained by dividing a standard deviation value by the average grain size value. The substantially monodisperse core/shell-type silver halide grains have shells from 0.01 to 0.1 in thickness. The silver halide grains include a silver iodide in the core in an amount of less than 8 mole % and a silver iodide in the shell of from 0.1 mole % to 6 mole %. A development inhibitor releasing compound having a relative development inhibitability of not less than 1 is also present in the emulsion layer.
    Type: Grant
    Filed: June 10, 1987
    Date of Patent: August 9, 1988
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Katsumasa Yamazaki, Toshihiko Yagi, Kenji Michiue, Sohei Goto, Yoshiharu Mochizuki
  • Patent number: 4760016
    Abstract: A silver halide color photographic light sensitive material is disclosed, which is excellent in the resistance to the back contamination of the processing liquid. The color photographic material comprises a support having thereon photographic component layers containing at least one silver halide emulsion layer. The emulsion containing at least one emulsion layer of the photographic component layers is a surface latent image forming type silver chloride or silver chloro-brobromide emulsion. And at least one of the photographic component layers contains at least one compound selected from the compounds represented by the formula [I]:A-(TIME)n-Z [I]in which A is a coupler component capable of coupling with the oxidized product of a color developing agent, Z is a component capable of releasing from A upon the coupling reaction of A with the oxidized product of the color developing agent and inhibiting the development of the silver halide, and Z has at least one hydrophilic group.
    Type: Grant
    Filed: October 14, 1986
    Date of Patent: July 26, 1988
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shigeto Hirabayashi, Kaoru Matsunaga
  • Patent number: 4749644
    Abstract: In a light-sensitive direct posi silver halide color photographic material having photographic constituent layers comprising at least one silver halide emulsion layer containing latent image type silver halide grains not previously fogged, which is capable of giving a direct posi image by subjecting the whole surface to exposure or effecting surface development in the presence of a fogging agent, after image exposure, the improvement wherein said internal latent image type silver halide grains are composed of at least two groups of internal latent image type silver halide grains having average grain sizes different from each other, and at least one compound capable of releasing a development inhibiting substance or its precursor through the reaction with the oxidized product of a color developing agent is contained in at least one layer of said photographic constituent layers.
    Type: Grant
    Filed: June 18, 1986
    Date of Patent: June 7, 1988
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Yasuo Tosaka, Keiji Ogi, Atsushi Kamitakahara
  • Patent number: 4746600
    Abstract: Disclosed is a light-sensitive silver halide color photographic material in which a DIR compound capable of releasing a diffusible development inhibitor or precursor thereof by the reaction with an oxidized form of a color developing agent is employed in combination with a non-diffusible dye and which sastisfies Condition A and B recited in the specification.By using the color light-sensitive material according to the present invention, the sharpness, particularly the edge effect (including the fringe effect and the border effect) of a photographic image has been greatly improved.
    Type: Grant
    Filed: June 26, 1986
    Date of Patent: May 24, 1988
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Yoshikazu Watanabe, Hiroshi Shimazaki, Toshifumi Iijima, Yoshiro Shigetomi, Toshihiko Yagi
  • Patent number: 4743533
    Abstract: There is described a photographic system wherein development of an exposed photosensitive element with an aqueous alkaline photographic developing composition is effected in the presence of a compound represented by the formula ##STR1## wherein R is --OH, --OR.sub.4, --NH.sub.2 --NHR.sub.5 or --NR.sub.4 R.sub.6 ; R.sub.1 is hydrogen, --NH.sub.2, alkyl, substituted alkyl, aryl or substituted aryl; R.sub.2 and R.sub.3 each independently is hydrogen, alkyl, aralkyl or aryl; R.sub.4 is a protecting group which can be removed in the presence of a base; R.sub.5 is an activating group which can render the neighboring hydrogen atom acidic; R.sub.6 is an electron withdrawing group which is capable of stabilizing the negative charge on the nitrogen atom which is produced upon removal of R.sub.4 upon contact with alkali; and PHOTO is a photographically useful group.
    Type: Grant
    Filed: March 31, 1986
    Date of Patent: May 10, 1988
    Assignee: Polaroid Corporation
    Inventors: Roger A. Boggs, John B. Mahoney, Avinash C. Mehta, William C. Schwarzel, Lloyd D. Taylor
  • Patent number: 4741994
    Abstract: A silver halide color photographic material having improved granularity and sharpness is disclosed which comprises at least one coupler represented by formula (Ia), (Ib), or (Ic). ##STR1## wherein A represents a coupler residue which can split away from the coupler by A--X bond cleavage upon reaction with an oxidation product of a developing agent; X represents an oxygen atom, or a sulfur atom; R.sub.1 and R.sub.2 each represents an aliphatic group, an aromatic group, or a heterocyclic group; Y represents a substituent group; and n represents 0, 1, or 2, and when n is 2, the two Y's represent the same or different substituent groups, or two of substituents R.sub.1, R.sub.2 and Y represent divalent groups that combine with each other to form a ring structure.
    Type: Grant
    Filed: October 2, 1985
    Date of Patent: May 3, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Kohzaburoh Yamada, Hideo Usui
  • Patent number: 4740453
    Abstract: A silver halide photosensitive material is described, comprising a support and at least one silver halide emulsion layer, wherein said emulsion layer or another layer contains a compound represented by formula (I) ##STR1## wherein X represents an atomic group forming a redox center of benzene type having substituents by linking with C.sub.A and C.sub.B, and which does not enable Time-PUG to be released until the redox center is oxidized during development processing; EWG represents an electron withdrawing group having a Hammet's .sigma. para value exceeding 0.3; C.sub.A and C.sub.B each represents a carbon atom; R.sub.1 and R.sub.2 each represents a hydrogen atom or a suitable substituent; Time represents a timing group connecting to C.sub.B through a sulfur, nitrogen, or selenium atom thereof, t is an integer of 0 or 1, and when t=0, Time is a chemical bond; PUG represents a photographically useful group and connects to C.sub.
    Type: Grant
    Filed: December 24, 1985
    Date of Patent: April 26, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koki Nakamura, Shigeo Hirano, Tadashi Ikeda, Keiji Mihayashi, Mitsunori Ono, Toshiro Takahashi, Ken-ichi Kuwabara, Morio Yagihara, Isamu Itoh
  • Patent number: 4737451
    Abstract: A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, said color photographic material containing a compound capable of releasing a group upon reaction with an oxidation product of a developing agent, the resulting group is oxidized and undergoes a ring cleavage reaction whereby a photograhically useful group is cleaved.The compound used in the present invention is capable of releasing a photograhically useful group through at least a two-step reaction, and the amount of the photographically useful group released is controlled depending on a concentration of the oxidation product of a developing agent. The silver halide color photographic material containing the compound either provides a color image having good image qualities such as sharpness, graininess, and color reproducibility, etc., or exhibits high sensitivity.
    Type: Grant
    Filed: October 7, 1986
    Date of Patent: April 12, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Seiji Ichijima
  • Patent number: 4737442
    Abstract: A silver halide photographic material for use in the field of graphic arts and a process for forming a high-contrast negative image using the same, wherein the silver halide emulsion layer or another layer of the silver halide photographic material provided on the support contains at least one compound represented by the formula (I) and at least one blocked development restrainer compound represented by the formula (II): ##STR1##
    Type: Grant
    Filed: April 18, 1986
    Date of Patent: April 12, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Tetunori Matusita, Nobuaki Inoue
  • Patent number: 4734357
    Abstract: A silver halide color light-sensitive material is described, which is increased in sensitivity, is adapted to form an image of high contrast, or is accelerated in development by incorporating a small amount of a specific compound which imagewise releases a foggant or a development accelerator. This compound is represented by the formula: Coup-(TIME).sub.n -FA (wherein Coup represents a coupler radical capable of undergoing a coupling reaction with an oxidized product of an aromatic primary amine developing agent; TIME represents a timing group which is eliminated from Coup by the coupling reaction and, thereafter, releases FA; n is 0 or 1; and FA represents a group which is eliminated from Coup in the coupling reaction when n is 0, whereas FA is released from TIME when n is 1. The FA has adsorption properties with respect to silver halide grains and also has a substantial fogging action with respect to the silver halide grains).
    Type: Grant
    Filed: January 14, 1987
    Date of Patent: March 29, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Hidetoshi Kobayashi, Isamu Itoh
  • Patent number: 4734353
    Abstract: A method for processing a silver halide photographic light-sensitive material comprising a support having thereon a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent capable of releasing a photographically useful agent, which method comprises processing the photographic light-sensitive material in the presence of an oxime.According to this method for processing a silver halide photographic light-sensitive material, both stability of the photographic light-sensitive material during storage and release of a photographically useful agent during processing are achieved without undersirable side-reactions, and a high sensitivity/fog ratio is obtained.
    Type: Grant
    Filed: April 21, 1986
    Date of Patent: March 29, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsunori Ono, Isamu Itoh, Keiji Mihayashi
  • Patent number: 4729943
    Abstract: A reversal photographic element comprising at least two dye image-forming units, at least one unit comprising(1) a first silver halide emulsion layer spectrally sensitized to a given region of the spectrum with which is associated a dye image-forming chromogenic coupler and(2) a second silver halide emulsion layer spectrally sensitized to a different region of the spectrum than the first and containing an interimage effect-forming means such as a development inhibitor-releasing coupler, which forms either a colorless compound or a dye which does not substantially take part in the formation of the image.
    Type: Grant
    Filed: October 6, 1986
    Date of Patent: March 8, 1988
    Assignee: Eastman Kodak Company
    Inventors: Maurice Pfaff, Regis Thomas
  • Patent number: 4729936
    Abstract: An image forming process including a heating step is disclosed. The process comprises conducting said heating step in the presence of at least one compound represented by formula (I), (II), or (III). ##STR1## wherein R.sup.1 represents ##STR2## wherein R.sup.11 and R.sup.12 each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkyloxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group or a substituted or unsubstituted amino group; R.sup.11 and R.sup.
    Type: Grant
    Filed: May 27, 1986
    Date of Patent: March 8, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Kozo Sato, Masatoshi Kato
  • Patent number: 4725530
    Abstract: A silver halide color photographic material comprising a support and at least one red-sensitive emulsion layer, at least one green-sensitive emulsion layer and at least one blue-sensitive emulsion layer on the support, which contains at least one cyan dye forming coupler represented by the general formula (I) and at least one cyan dye forming coupler represented by the general formula (II): ##STR1## wherein R.sub.1 represents --CONR.sub.5 R.sub.6, --NHCORhd 5, --NHCOOR.sub.7, --NHSO.sub.2 R.sub.7, --NHCONR.sub.5 R.sub.6 or --NHSO.sub.2 NR.sub.5 R.sub.6, R.sub.2 represents a group which can be substituted in the naphthol ring, m represents 0 or an integer of 1 to 3, R.sub.3 represents a monovalent group, R.sub.4 represents an aromatic group, and X and Y each represents a hydrogen atom or a group capable of leaving through a coupling reaction with an oxidized product of aromatic primary amine developing agent; R.sub.5 and R.sub.
    Type: Grant
    Filed: October 17, 1986
    Date of Patent: February 16, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Toshihiro Nishikawa
  • Patent number: 4725529
    Abstract: There is disclosed a light-sensitive silver halide photographic material, having two or more light-sensitive silver halide emulsion layers different in color sensitivities on a support, at least two of the light-sensitive silver halide emulsion layers different in color sensitivities containing a DIR compound capable of releasing a developing inhibitor or developing inhibitor precursor through the reaction with the oxidized product of a developing agent, the developing inhibitor or developing inhibitor precursor released from the DIR compound being diffusive, wherein the following conditions A:DIR compounds are added and incorporated in the emulsion layers so that the developing inhibitor released from the DIR compound incorporated in one color-sensitive silver halide emulsion layer and the developing inhibitor released from the DIR compound incorporated in the other color-sensitive silver halide emulsion layer are reversed in developing inhibiting power when the DIR compounds to be incorporated in the respec
    Type: Grant
    Filed: April 21, 1986
    Date of Patent: February 16, 1988
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hiroshi Shimazaki, Eiichi Sakamoto, Satoshi Nakagawa, Hiroshi Inoie, Minoru Ishikawa
  • Patent number: 4708927
    Abstract: A novel photographic element is disclosed. The element comprises a light-sensitive element including a light-sensitive silver halide emulsion layer coated on a support, wherein said silver halide emulsion layer or other photographic layers contain at least one development inhibitor precursor represented by formula (I) ##STR1## wherein A represents a phenyl group or a 5- or 6-membered nitrogen-containing heterocyclic ring group; L represents a chemical bond or divalent linking group; p and q each represents an integer of 1 or 2; and n represents 0 or 1.
    Type: Grant
    Filed: April 10, 1986
    Date of Patent: November 24, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Hiroshi Kawamoto, Yoshio Sakakibara
  • Patent number: 4705744
    Abstract: Silver halide color photographic materials comprising a support having thereon at least one blue-sensitive silver halide emulsion layer comprising a yellow dye-forming coupler, at least one green-sensitive silver halide emulsion layer comprising a magenta dye-forming coupler, and at least one red-sensitive silver halide emulsion layer comprising a cyan dye-forming coupler, characterized in that the wavelength weight-averaged between 500 nm and 600 nm (.lambda..sub.G) of spectral sensitivity distribution of all green-sensitive layers is in the range of 520 nm to 580 nm, the wavelength weight-averaged between 500 nm and 600 nm (.lambda..sub.-R) of spectral sensitivity distribution of one or more donor layers which exert an interlayer effect to at least one red-sensitive emulsion layer comprising a cyan dye-forming coupler is located in the range of 500 nm to 560 nm, and the difference of (.lambda..sub.G -.lambda..sub.-R) is greater than 5 nm.
    Type: Grant
    Filed: July 5, 1985
    Date of Patent: November 10, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noboru Sasaki, Koji Takahashi
  • Patent number: 4702999
    Abstract: Disclosed are novel antifoggant precursors having the general formula (I) or (II) which are sufficiently stable in a wealkyl acidic medium, are markedly effective in restraining over-development fog and besides cause little loss of sensitivity: ##STR1## (wherein Y represents oxygen atom or ##STR2## X represents OR.sub.3 when Y is oxygen atom and R.sub.3 when Y is ##STR3## where R.sub.1 and R.sub.2 each represents hydrogen atom, alkyl group aryl group and R.sub.3 represents hydrogen atom, alkyl group or phenyl group; R.sub.4 -R.sub.6 each represent hydrogen atom, halogen atom, alkyl group, carboxyl group, alkoxycarbonyl group or phenyl group, R.sub.4 and R.sub.5 may form together a benzene ring; R.sub.7 represents hydrogen atom, alkyl group or phenyl group; and A represents a heterocyclic group of the mercapto antifoggant.) ##STR4## (wherein X, Y, R.sub.4 -R.sub.5 and A are the same as defined for the general formula (I) and R.sub.4 and R.sub.5 or R.sub.5 and R.sub.6 may form together a benzene ring.).
    Type: Grant
    Filed: February 24, 1986
    Date of Patent: October 27, 1987
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Minoru Ohashi, Satoshi Kaneko
  • Patent number: 4698297
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing a compound capable of releasing a group represented by the general formula (I) described below upon the reaction with the oxidation product of a developing agent: ##STR1## wherein W and Z each represents an oxygen atom, a sulfur atom or a group of ##STR2## X.sub.1, X.sub.2, X.sub.3, X.sub.4 and X.sub.5 each represents a hydrogen atom or an organic residue; PUG represents a photographically useful group; n represents 1 or 2; any two of X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5 and PUG each represents a divalent group and may be connected to each other to form a cyclic structure; and when n represents 2, two Z's, two X.sub.3 's and two X.sub.4 's may be the same or different.
    Type: Grant
    Filed: May 28, 1985
    Date of Patent: October 6, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Noboru Sasaki
  • Patent number: 4696887
    Abstract: A novel method for formation of an image comprising a heating step, comprising the heating carried out in the presence of a compound of general formula (I):X--SO.sub.2 (DI) (I)wherein X represents a reducing group capable of reducing a silver salt and capable of being oxidized by heating and in its oxidized state capable of releasing a compound represented by (DI)--SO.sub.2 NH.sub.2 by reaction with a nucleophilic agent; and (DI) represents a development inhibiting group capable of inhibiting the oxidation reduction reaction of the silver salt and a reducing aent.The compound of the formula (I) functions to inhibit development after a certain period of time from the beginning of heat development.The present method provides a stable image with reduced fog and image mottle.
    Type: Grant
    Filed: February 13, 1986
    Date of Patent: September 29, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Hiroshi Kitaguchi, Masashi Takeuchi, Masaaki Tsukase, Masatoshi Kato
  • Patent number: 4695525
    Abstract: A process of forming images by heat developing a heat developable light-sensitive material after imagewise exposure is described, comprising heating a heat developable light-sensitive material in the presence of a compound represented by general formula (I) ##STR1##
    Type: Grant
    Filed: February 12, 1986
    Date of Patent: September 22, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaaki Tsukase, Kozo Sato, Hiroshi Kitaguchi, Masashi Takeuchi, Masatoshi Kato
  • Patent number: 4690885
    Abstract: A silver halide photographic material which comprises a support having coated thereon a light-sensitive silver halide emulsion layer, wherein the photographic material contains at least one blocked photographic agent represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is bonded to a blocking moiety through a hetero atom, or a precursor thereof; R.sup.1, R.sup.2 and R.sup.3 each represents a hydrogen atom, or a substituent group; and Z represents atoms necessary to form a carbocyclic ring or a heterocyclic ring (except for a heterocyclic ring which contains an NH group at the position adjacent to the carbon atom to which R.sup.1 is attached). The blocked photographic agent is completely stable upon storage of the photographic material, and releases a photographic agent at a desired time upon processing. The blocked photographic agent also exhibits its function to a substantial degree over a wide range of pH.
    Type: Grant
    Filed: October 16, 1985
    Date of Patent: September 1, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Akihiko Ikegawa
  • Patent number: 4686175
    Abstract: A silver halide multilayered color photographic light-sensitive material is disclosed. The material is comprised of a support basde having thereon a green-sensitive emulsion layer having a maximum sensitivity of from 535 nm to 555 nm, a blue-sensitive emulsion layer having a maximum sensitivity in the range of 80 to 110 nm shorter than that of the green-sensitive layer and a red-sensitive layer having a maximum sensitivity in the range of 75 to 95 nm longer than that of the green-sensitive layer. The material also contains a compound capable of releasing a diffusible development inhibitor or its precursor by a coupling reaction with the oxidation product of a color developing agent. This compound is present within one of the emulsion layers or a light-insensitive layer adjacent to one of the silver halide emulsion layers. The material undergoes less changes in color reproducibility due to changes in color temperature of a light source upon photographing.
    Type: Grant
    Filed: October 18, 1985
    Date of Patent: August 11, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ogawa, Masaki Okazaki
  • Patent number: 4684604
    Abstract: Photographic elements and processes are described which employ a compound containing a hydrazide moiety attached by a linking group, comprising an acidic group or an active methylene group adjacent to an acidic group, to a heteroatom of a moiety containing a photographically useful group comprising a photographic dye or precursor thereof or a photographic reagent; wherein:(a) the hydrazide moiety is capable of being oxidized to an azo group by an oxidized developing agent,(b) the azo group formation causes the release of the photographically useful group, and(c) the released photographically useful group does not contain the linking group or the nitrogen atoms of the hydrazide moiety.
    Type: Grant
    Filed: April 24, 1986
    Date of Patent: August 4, 1987
    Assignee: Eastman Kodak Company
    Inventor: John W. Harder
  • Patent number: 4678739
    Abstract: A method for forming an image which has a step of heating an image-forming material in the presence of a compound represented by formula (I), whereby unevenness of image density and increase in fog due to fluctuation of development temperature, which have so far been caused in heat-developable photosensitive materials, can be prevented from occurring: ##STR1## wherein R represents a hydrogen atom, or a group selected from a class consisting of groups represented by formulae (A) to (C) ##STR2## wherein R.sup.11 and R.sup.12 each represents a substituted or unsubstituted alkyl group, a cycloalkyl group, a substituted or unsubstituted alkenyl group, an aralkyl group, a substituted or unsubstituted aryl group, a heterocyclic group, an alkyloxy group, an aryloxy group, an alkylthio group, an arylthio group, or a substituted or unsubstituted amino group, or R.sup.11 and R.sup.
    Type: Grant
    Filed: December 18, 1985
    Date of Patent: July 7, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Masashi Takeuchi, Kozo Sato, Masaaki Tsukase, Masatoshi Kato
  • Patent number: 4678735
    Abstract: A heat developable light-sensitive material containing a compound represented by general formula (I) described below in a light-sensitive layer or an image receiving layer thereof: ##STR1## wherein X represents an atomic group necessary to complete a benzene ring or a naphthalene ring; R represents a group convertible to a hydroxy group or a dissociation form thereof at the time of heat development; Y represents an atomic group necessary to complete a 5-membered or 6-membered heterocyclic group containing at least one nitrogen atom; Q represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group; TIME represents a timing group; and n represents 0 or a positive integer.
    Type: Grant
    Filed: September 10, 1985
    Date of Patent: July 7, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Masatoshi Kato, Kozo Sato, Masasi Takeuchi, Masaaki Tsukase
  • Patent number: 4659651
    Abstract: A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer having associated therewith at least one blocked photographic reagent represented by formula (I) or (II); ##STR1## wherein, A represents a moiety of a photographic reagent or a moiety of a precursor of a photographic reagent bonded to the ring containing Z through a hetero atom; Y.sup.1, and Y.sup.2 and Y.sup.3 each represents a hydrogen atom or a substituent, or Y.sup.1 and Y.sup.3 in formula (I) together form a ring; Z represents an atomic group necessary for forming a carbon ring or a heterocyclic ring; and n represents 1 or 2.The silver halide photographic material is stable under storage conditions.
    Type: Grant
    Filed: July 11, 1985
    Date of Patent: April 21, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Akihiko Ikegawa
  • Patent number: 4652516
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing a compound capable of releasing a group represented by the general formula (I) described below upon the reaction with the oxidation product of a developing agent: ##STR1## wherein W represents an oxygen atom, a sulfur atom or a group ##STR2## (wherein R represents a hydrogen atom or an organic residue); X represents an electron withdrawing substituent; Y represents a hydrogen atom or a substituent; PUG represents a photographically useful group or a precursor thereof; X and Y each represents a divalent group and may be connected to each other to form a cyclic structure; and when W represents the group ##STR3## and R represents an organic residue, R and X or R and Y each represents a divalent group and may be connected to each other to form a cyclic structure.
    Type: Grant
    Filed: May 24, 1985
    Date of Patent: March 24, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Shingo Sato, Mitsunori Ono, Noboru Sasaki
  • Patent number: 4639408
    Abstract: A process for forming an image comprising a heating step is described, wherein a photographic material is heated in the presence of a compound represented by formula (I) ##STR1## wherein X represents an atomic group completing a carbocyclic aromatic ring or a heterocyclic aromatic ring; R.sup.1 is selected from groups represented by formulae (A), (B), and (C) ##STR2## in which R.sup.11 and R.sup.12 each represents a substituted or unsubstituted alkyl group, a cycloalkyl group, a substituted or unsubstituted alkenyl group, an aralkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, an alkyloxy or aryloxy group, an alkylthio or arylthio group, or a substituted or unsubstituted amino group, or R.sup.11 and R.sup.12 together form a 5-membered or 6-membered ring; R.sup.2 represents a group selected from the groups represented by R.sup.11 ; R.sup.1 and R.sup.
    Type: Grant
    Filed: November 20, 1985
    Date of Patent: January 27, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Masatoshi Kato
  • Patent number: 4636456
    Abstract: A process for forming photographic image is disclosed, comprising photographically developing, in the presence of a polyalkylene oxide compound, a silver halide photographic light-sensitive material including at least one silver halide emulsion layer and containing in at least said emulsion layer or other hydrophilic layer a compound represented by formula (I). ##STR1## wherein: A and A' each represents a hydrogen atom or an alkalihydrolyzable group;R.sub.1, R.sub.2, and R.sub.3 each represents a group capable of substituting a hydrogen atom on the hydroquinone nucleus, with R.sub.2 and R.sub.3, A and R.sub.1, or A and R.sub.2 together form a ring; andX represents a group which shows a development-inhibiting effect after being released.
    Type: Grant
    Filed: May 7, 1985
    Date of Patent: January 13, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiro Takahashi, Koki Nakamura
  • Patent number: 4629683
    Abstract: A method of processing a photographic material which contains a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent capable of releasing a photographically useful agent by ring cleavage of a 4- to 7-membered ring containing at least one carbonyl group in the presence of a hydroxylamine, whereby both high stability of the photographic material upon storage and timely release of the photographically useful agent upon processing are achieved.
    Type: Grant
    Filed: April 20, 1984
    Date of Patent: December 16, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Isamu Itoh, Mitsunori Ono, Keiji Mihayashi, Seiji Ichijima, Hidetoshi Kobayashi