Development Inhibitor Releaser (dir) Patents (Class 430/957)
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Patent number: 4619884Abstract: Photographic elements and assemblages are described which employ nondiffusible N',N'-diaromatic carbocyclic--or diaromatic heterocyclic--sulfonohydrazide compounds which are capable of releasing photographically useful groups in an imagewise manner as a function of silver halide development.Type: GrantFiled: July 29, 1985Date of Patent: October 28, 1986Assignee: Eastman Kodak CompanyInventor: Stephen P. Singer
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Patent number: 4618571Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing a coupler which releases a compound after the coupling reaction with the oxidation product of a developing agent, the released compound being capable of releasing further a photographically useful group by an oxidation-reduction reaction with the oxidation product of another developing agent. The compound used in the present invention is chemically stable and can release a photographically useful group under control; therefore the silver halide color photographic light-sensitive material containing the compound has good stability during storage and high sensitivity and provides a color image having good image qualities such as sharpness, graininess, color reproducibility, etc.Type: GrantFiled: February 25, 1985Date of Patent: October 21, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Hideo Usui, Naoyasu Deguchi
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Patent number: 4618563Abstract: A silver halide photographic light-sensitive material is described, comprising a support having thereon a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent represented by formula (I) ##STR1## wherein A represents a photographically useful agent moiety, which may have a timing group; X.sup.1 and X.sup.2 each represents a carbonyl group, a sulfonyl group, or a sulfinyl group; Z represents an atomic group forming a 5-membered, 6-membered, or 7-membered ring; R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an acyl group, a sulfonyl group, or a heterocyclic group; R.sup.3 represents an alkyl group, an alkenyl group, a cycloalkyl group, a heterocyclic group, an aryl group, or an aralkyl group; m represents 0, 1, or 2; n represents 0 or 1; and the total of m+n is 1, 2, or 3.Type: GrantFiled: August 15, 1984Date of Patent: October 21, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsunori Ono, Isamu Itoh, Keiji Mihayashi
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Patent number: 4610957Abstract: A heat-developable light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion and an acid precursor having a structural moiety represented by the following formula (I) bonded to carbon atoms: ##STR1## The acid precursor is extremely stable at room temperature but when it is heated above a certain temperature, and the development proceeds to the desired appropriate condition, it releases an acid to neutralize a base, whereby the development is stopped. A heat-developable light-sensitive material containing the acid precursor provides color images having a high S/N ratio and a high image density.Type: GrantFiled: April 26, 1985Date of Patent: September 9, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Masatoshi Kato, Hiroshi Kitaguchi
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Patent number: 4609610Abstract: Photographic elements and assemblages are described which employ nondiffusible compounds which release photographically useful groups in an imagewise manner as the result of a .beta.-elimination reaction.Type: GrantFiled: August 1, 1985Date of Patent: September 2, 1986Assignee: Eastman Kodak CompanyInventors: Richard P. Dunlap, Thomas E. Gompf
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Patent number: 4599301Abstract: A silver halide color photographic material is described, comprising a support having thereon at least a cyan-color-forming red-sensitive emulsion layer, a magenta-color-forming green-sensitive emulsion layer, and a yellow-color-forming blue-sensitive emulsion layer; the weight-averaged wavelength (.lambda.) on the spectral sensitivity distribution determined by equi-energy spectrum of said red-sensitive emulsion layer being less than 640 nm; the longest wavelength in the wavelengths having the sensitivity of 1/2 of the maximum value of the above-described equi-energy spectrum being in a range of from 30 nm to 55 nm longer than the weight-averaged wavelength and the minimum wavelength thereof being in a range of from 30 nm to 55 nm shorter than the weight-averaged wavelength; in the above-described equi-energy spectrum, values A and B defined below satisfying the relation of A/B.gtoreq.0.Type: GrantFiled: August 8, 1985Date of Patent: July 8, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Yuichi Ohashi, Tadashi Ogawa
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Patent number: 4584257Abstract: A photographic element comprised of a support having provided thereon at least one silver halide emulsion layer, the element containing a development inhibitor precursor, is disclosed. The development inhibitor precursor is a compound represented by following general formula (I): ##STR1## wherein A represents an unsubstituted or substituted phenyl group or a 5-membered or 6-membered nitrogen-containing heterocyclic ring; Q represents a naphthalene skeleton; R.sup.1, R.sup.2, and R.sup.3, which may be the same or different, independently represent a hydrogen atom or a monovalent substituent; and n represents 1 or 2. The photographic element gives improved image quality particularly in the low Dmin area. The element can be processed over a wide range of different processing temperatures and has improved preservability.Type: GrantFiled: April 18, 1985Date of Patent: April 22, 1986Assignee: Fuji Photo Film Co., Ltd.Inventors: Hisashi Okamura, Yoshio Sakakibara
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Patent number: 4579816Abstract: Yellow DIR couplers corresponding to formula I below are capable of producing remarkably powerful inhibitory effects on remote layers while their action on the layer containing them is comparatively slight: ##STR1## In the above formula, R.sup.1 represents straight-chained or branched alkyl, optionally substituted aryl or --NR.sup.5 R.sup.6,R.sup.2, R.sup.5 represent H or alkyl with 1 or 2 carbon atoms,R.sup.3, R.sup.6 represent alkyl with 1 to 18 carbon atoms or optionally substituted aryl,R.sup.4 represents alkyl with 5 to 12 carbon atoms, andFu represents a substituted or unsubstituted furyl group.Type: GrantFiled: July 15, 1985Date of Patent: April 1, 1986Assignee: Agfa-Gevaert AktiengesellschaftInventors: Hans Ohlschlager, Ulrich Griesel, Heinrich Odenwalder
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Patent number: 4571378Abstract: Improved photographic recording materials containing at least one silver halide emulsion layer with comparatively high sensitivity and at least one silver halide emulsion layer with comparatively low sensitivity. Color couplers and DIR compounds of differing reactivities are associated with these layers.Type: GrantFiled: December 10, 1984Date of Patent: February 18, 1986Assignee: Agfa-Gevaert AktiengesellschaftInventors: Wolfgang Sauerteig, Erwin Ranz, Heinz Schutz
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Patent number: 4564587Abstract: Disclosed is a light-sensitive silver halide color photographic material comprising at least one light-sensitive layer, which is constituted of a plurality of silver halide emulsion layers having substantially the same color sensitiveness but being different in sensitivities and contains a dye image-forming coupler, provided by coating on a support, said material being constituted so as to satisfy at the same time the requirements that (a) said plurality of silver halide emulsion layers in said light-sensitive layer are provided by coating in the order from the support side a low sensitivity emulsion layer, medium sensitivity emulsion layer and high sensitivity emulsion layer, (b) a non-sensitive intermediate layer is provided by coating between said low sensitivity emulsion layer and said medium sensitivity emulsion layer, (c) the density of a dye image-forming coupler in said medium sensitivity emulsion layer is 10 to 60% of the density of a dye image forming coupler in said low sensitivity emulsion layer;Type: GrantFiled: July 10, 1984Date of Patent: January 14, 1986Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Yoshikazu Watanabe, Kenji Ito
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Patent number: 4562138Abstract: This invention relates to nitrogen containing heterocyclic compounds represented by the general formula ##STR1## wherein Z is non-metallic atoms necessary to form a tetrazole, a benzotriazole or a benzothiazole, either substituted or unsubstituted, n is either 1 or 2 and R is alkyl or phenyl. The above mentioned compounds can be suitably used in a photographic material as a development inhibitor precursor.Type: GrantFiled: August 21, 1984Date of Patent: December 31, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Morito Uemura, Kaoru Onodera
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Patent number: 4554243Abstract: A silver halide photographic light-sensitive material is described which comprises a support having thereon a light-sensitive silver halide emulsion layer, wherein the photographic light-sensitive material therein contains a blocked photographic agent capable of releasing a photographically useful agent and the blocked photographic agent has a carbonyl group or thiocarbonyl group to which a hydrogen atom or a carbon atom is directly bonded and is substituted with a photographically useful group which is capable of being released upon an intramolecular nucleophilic attack by the oxygen atom in the carbonyl group or the sulfur atom in the thiocarbonyl group.The precursor of photographic agent is completely stable during storage prior to use of the photographic light-sensitive material, and releases a photographic agent at a desired time upon the processing of the photographic light-sensitive material. The precursor also exhibits its function to a substantial degree in a relatively low pH range.Type: GrantFiled: May 25, 1984Date of Patent: November 19, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsunori Ono, Isamu Itoh
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Patent number: 4546073Abstract: Precursor compounds from which photographically-active compounds are released with a time delay correspond to the following general formula ##STR1## wherein A represents the residue of a compound which undergoes oxidative coupling;X represents --O--, --S-- or --NR.sup.1 --;Y represents a releasable group which may consist of or contain the residue of a photographically-active compound; andR represents a group for controlling the kinetics of release.Advantageous pictorial properties (inter-image effect, edge effect, modulation transfer function) are obtained with compounds according to the present invention if the photographically-active residue is the residue of a development inhibitor.Type: GrantFiled: May 16, 1984Date of Patent: October 8, 1985Assignee: Agfa-Gevaert AktiengesellschaftInventors: Peter Bergthaller, Heinrich Odenwalder, Reinhard Matejec
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Patent number: 4543317Abstract: There is described a photographic system wherein development of an exposed photosensitive element with an aqueous alkaline processing composition is effected in the presence of a compound which is a salt of a radical of a substituted phenylmercaptoazole complexed with a radical of a quaternary. The salts are either insoluble or have extremely low solubility in water and become soluble, and photographically active, in alkaline environment.Type: GrantFiled: December 19, 1984Date of Patent: September 24, 1985Assignee: Polaroid CorporationInventors: Avinash C. Mehta, Lloyd D. Taylor
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Patent number: 4528263Abstract: Disclosed is a light-sensitive silver halide color photographic material having at least one light-sensitive silver halide emulsion layer on a support, characterized in that said light-sensitive silver halide emulsion layer contains a cyan coupler represented by the formula [I] shown below, and said light-sensitive silver halide emulsion layer and/or a layer contiguous to said light-sensitive silver halide emulsion layer contains at least one of a timing DIR compound represented by the formula [II] shown below and a non-timing type DIR compound: ##STR1## wherein X, R.sub.1 and R.sub.2 are as defined in the specification; ##STR2## wherein Cp, TIME and Z are as defined in the specification.Type: GrantFiled: February 27, 1984Date of Patent: July 9, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Hiroshi Sugita, Yasuo Tsuda, Kenji Ito, Satoru Shimba
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Patent number: 4524130Abstract: A silver halide color photographic light-sensitive material is disclosed. The material is comprised of a support base having a plurality of silver halide emulsion layers positioned thereon. The material includes at least one silver halide emulsion layer having a particular sensitivity and color sensitivity, and a second silver halide emulsion layer having the same color sensitivity but having a greater sensitivity with respect to light, the second layer including a silver halide having a silver iodide content in the range of 9% by mol to 15% by mol. The material includes a DIR compound in a layer other than the second silver halide emulsion layer. The DIR compound releases a diffusible development inhibitor or precursor thereof by a coupling reaction. The resulting material has greatly improved granularity and sharpness.Type: GrantFiled: January 19, 1984Date of Patent: June 18, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuo Iwasa, Shingo Ishimaru
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Patent number: 4522917Abstract: A photographic silver halide light-sensitive material is disclosed. The material is comprised of a support and a photographic layer or layers on the support. The photographic layer contains at least one of the compounds represented by the general formula: A--OCH.sub.2 --Z (wherein A is a group capable of undergoing cleavage on application of alkali hydrolysis, and Z is a photographically useful group containing a nitrogen atom through which it is linked to the group A--OCH.sub.2 --). The compounds, i.e., photographically useful group precursors, as used herein are stable during the storage of the raw film and can release the photographically useful group at a controlled speed during development.Type: GrantFiled: November 18, 1983Date of Patent: June 11, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Keiji Mihayashi, Isamu Itoh
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Patent number: 4518685Abstract: A silver halide photographic light-sensitive material which comprises a support having thereon a light-sensitive silver halide emulsion layer, wherein the photographic light-sensitive material contains a blocked photographic agent therein represented by formula (I): ##STR1## wherein A represents a photographic agent moiety which is bonded to a blocking moiety through a hetero atom or a group which is bonded to a blocking moiety through a hetero atom and capable of releasing a photographic agent upon a subsequent reaction after the group is released; Y represents a hydrogen atom or a substituent; and Z represents an atomic group necessary to form a carbocyclic ring or a heterocyclic ring.The precursor of photographic agent is completely stable during the preservation of the photographic light-sensitive material and releases a photographic agent at a desired time upon the processing of the photographic light-sensitive material.Type: GrantFiled: April 17, 1984Date of Patent: May 21, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Morio Yagihara, Akihiko Ikegawa, Mitsunori Ono, Yuji Mihara
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Patent number: 4511644Abstract: A photographic element comprised of a support having provided thereon at least one silver halide emulsion layer, the element containing a development inhibitor precursor. The development inhibitor precursor is represented by the following general formula (I): ##STR1## wherein A represents an unsubstituted or substituted phenyl group or a 5-membered or 6-membered nitrogen-containing heterocyclic ring; R.sup.1 represents a hydrogen atom or a monovalent substituent; and R.sup.2 represents an organic ballasting group. The element is capable of providing color images having improved image quality particularly with respect to having a low density in the Dmin areas. The photographic element can be processed over a wide range of processing temperatures. Further, the element can be preserved for long periods of time without having a reduction in the density in the Dmax areas.Type: GrantFiled: December 9, 1983Date of Patent: April 16, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Hisashi Okamura, Shinji Sakaguchi, Osamu Takahashi, Ashita Murai
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Patent number: 4503139Abstract: There are described novel photographic products and processes which utilize compounds which release a photographic reagent in the presence of alkali. The compounds include an imidazole blocking group and cleave in alkali to release the photographic reagent. Also described are novel compounds.Type: GrantFiled: May 9, 1983Date of Patent: March 5, 1985Assignee: Polaroid CorporationInventors: James R. Bartels-Keith, Roger A. Boggs, Anthony J. Puttick, Nancy M. Sofen
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Patent number: 4500633Abstract: A silver halide photographic material having formed on a support two or more layers that have different light sensitivities but have substantially the same color sensitivity is disclosed. In the material, the layer having the highest light sensitivity contains only a compound of formula (I) as a DIR compound and at least one of the remaining layers contains at least one compound of formula (II) as a DIR compound:A--TIME--Z (I)A--Z (II)wherein A is a coupling component capable of reaction with the oxidized product of a color developing agent to release the group TIME--Z (wherein TIME represents a timing group and Z represents a development retarder). The photographic material has improved sharpness and granularity and wide latitude for exposure.Type: GrantFiled: February 15, 1983Date of Patent: February 19, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Hiroshi Menjo, Yoshikazu Watanabe
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Patent number: 4500636Abstract: A silver halide photographic light-sensitive material which comprises a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent, said blocked photographic agent being represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is attached to a blocking moiety through a hetero atom; Z represents a divalent linkage group; p represents 0 or 1; X and Y each represents a substituent: m represents an integer of 0 to 4: and n represents an integer of 0 to 5.Type: GrantFiled: January 27, 1984Date of Patent: February 19, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsunori Ono, Isamu Itoh, Keiji Mihayashi, Yukio Karino
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Patent number: 4500634Abstract: A silver halide color photographic material in which both a coupler capable of releasing a diffusible development restrainer by coupling and a polymer coupler latex are present to increase visual sharpness.Type: GrantFiled: August 24, 1983Date of Patent: February 19, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Kei Sakanoue, Morio Yagihara, Seigi Ichijima, Kimitoshi Nagao
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Patent number: 4499181Abstract: A photographic recording material. On a support are provided a silver emulsion halide layer and a photographic layer. The photographic layer contains an indole compound represented by the general formula (I): ##STR1## wherein PUG represents a photographically useful group, Ball represents an organic group which has enough molecular weight and/or disposition to render the compound non-diffusible during processing of the photographic recording material with an alkaline medium and wherein the Ball contains a nitrogen atom which is directly attached to the 5th or 6th position of the indole ring. R.sub.1 represents a halogen atom or a monovalent organic group. R.sub.2 represents a hydrogen atom or a low molecular group attached, through a carbon atom, to the 2nd position of the indole ring. "m" represents an integer of zero to 3.Type: GrantFiled: June 2, 1983Date of Patent: February 12, 1985Assignee: Konishiroku Photo Ind., Co., Ltd.Inventors: Kazumasa Watanabe, Hidetaka Deguchi, Shunji Suginaka
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Patent number: 4490459Abstract: The invention relates to multi-layered color photosensitive materials having a support, a red photosensitive silver halide emulsion layer containing a non-diffusible cyan coupler, a green photosensitive silver halide emulsion layer containing a non-diffusible yellow coupler and a blue photosensitive silver halide emulsion layer containing a non-diffusible magenta coupler coated on a support in the order recited and wherein the green photosensitive emulsion layer contains a compound capable of reacting with an oxidized color developing agent to release a development inhibiting substance.Type: GrantFiled: May 12, 1983Date of Patent: December 25, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Toshifumi Iijima, Kaoru Onodera, Wataru Fujimatsu
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Patent number: 4482629Abstract: There is disclosed a light-sensitive silver halide photographic material containing a compound represented by the formula (I): ##STR1## wherein G, R.sub.1, R.sub.2 and X have the same meanings as defined in the specification.The 1-naphthol coupler which is contained in the light-sensitive silver halide photographic material is high in reactivity with an oxidized product of a color forming developing agent and can efficiently impart imagewise photographic effects to light-sensitive silver halide photographic materials.Type: GrantFiled: March 16, 1983Date of Patent: November 13, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Satoshi Nakagawa, Hiroshi Sugita, Shuzi Kida, Morito Uemura, Ken-ichi Kishi
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Patent number: 4480028Abstract: Silver halide photographic material having at least one light sensitive silver halide emulsion layer, at least one non-light sensitive hydrophilic colloidal layer, and optionally a third type of layer, wherein at least one of said emulsion layers, colloid layers, or third type of layers has, in a single layer, both a magenta coupler of Formula I and a development inhibitor releasing compound having a development inhibitor radical of Formula II or III, said Formula is wherein R.sub.1 is selected from benzamido, anilino, and phenylureido, each having a sulfonamido group and R.sub.2 is selected from aryl and heterocyclic groups; said Formula II is ##STR1## wherein R.sub.3 is selected from hydrogen, halogen, acylamino, alkyl, benzothiazolinylidenamino and phenyl substituted alkoxy; said Formula III is ##STR2## wherein X is a group of non-metallic atoms necessary to complete, together with the C.dbd.N group, a five or six membered heterocyclic ring.Type: GrantFiled: January 28, 1983Date of Patent: October 30, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kazuo Kato, Yoshikazu Watanabe, Kenji Kumashiro, Satoru Shimba
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Patent number: 4477563Abstract: A silver halide color photographic light-sensitive material is described comprising a support having thereon a silver halide emulsion layer containing a coupler having, at the coupling active position, a group which provides a compound having a development inhibiting property when the group is released from the coupling device position of the coupler upon the color development reaction and which is decomposed to a compound which does not substantially influence the photographic properties when the compound diffuses into a color developing solution.The silver halide color photographic light-sensitive material containing a novel class of development inhibitor releasing couplers provides color images of good sharpness and improved color reproduction without causing contamination of the processing solution.Type: GrantFiled: August 25, 1983Date of Patent: October 16, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiji Ichijima, Kei Sakanoue, Hidetoshi Kobayashi, Keiichi Adachi
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Patent number: 4472493Abstract: A photographic element is disclosed which is comprised of a support having thereon a light-sensitive silver halide emulsion which is associated with a development inhibitor precursor. The precursor is represented by the general formula [I] ##STR1## the substituents within the general formula are defined within the specification. By utilizing the development inhibitor precursor of the invention the resulting photographic element provides images having high quality and excellent processing temperature characteristics.Type: GrantFiled: December 9, 1983Date of Patent: September 18, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Hisashi Okamura, Yukio Maekawa, Yukio Karino
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Patent number: 4464463Abstract: A silver halide color photographic light-sensitive material comprises a support having thereon a light-sensitive silver halide emulsion layer and a light-insensitive layer is disclosed. The material contains within the light-sensitive layer or the light-insensitive layer a compound capable of reacting with and fixing formaldehyde gas, said compound being represented by the general formula (I) or (II): ##STR1## The compound capable of reacting with and fixing formaldehyde gas is loaded into an ultraviolet ray absorbing polymer latex comprised of a polymer having a repeating unit derived from a monomer represented by the general formula (III): ##STR2## The substituents within the above formulae are defined within the specification.Type: GrantFiled: July 26, 1983Date of Patent: August 7, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuro Kojima, Hidetoshi Kobayashi
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Patent number: 4461826Abstract: There is disclosed a silver halide light-sensitive color photographic material which comprises a support and coated thereon a light-sensitive layer containing a compound which, upon reaction with an oxidized color developing agent, is capable of releasing a diffusible development inhibitor and a negative type light-sensitive silver halide emulsion containing light-sensitive silver halide crystals essentially consisting of mono-dispersed silver halide crystals of which size distribution satisfies the following relation:S/r.ltoreq.0.15whereinS=.sqroot..SIGMA.(r-r.sub.i).sup.2 n.sub.i.sup.2 /.SIGMA.n.sub.i andr=.SIGMA.n.sub.i r.sub.i /.SIGMA.n.sub.i in which r.sub.i represents the crystal size of individual silver halide crystals and n.sub.i represents the number of crystals.The light-sensitive color photographic material of the present invention provides an image of remarkably improved sharpness.Type: GrantFiled: July 12, 1982Date of Patent: July 24, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kiyoshi Yamashita, Toshifumi Iijima
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Patent number: 4459351Abstract: A redox release compound that is capable upon oxidation of releasing a silver ion complexing heterocyclic thio moiety enables reduction of the concentration of silver required in a photographic silver halide material comprising a combination of (i) photographic silver halide capable of forming a surface latent image, and (ii) a photographic silver halide capable of forming an internal latent image. The silver halide capable of forming an internal latent image preferably has lower photosensitivity than the silver halide capable of forming a surface latent image. The redox release compound preferably comprises a silver ion complexing 1,2,4-triazolium-3-thio moiety. An image is developed in such an exposed photographic silver halide element by means of a surface type silver halide developer.Type: GrantFiled: June 22, 1983Date of Patent: July 10, 1984Assignee: Eastman Kodak CompanyInventors: Anthony Adin, Henry W. Altland
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Patent number: 4450223Abstract: A photographic silver halide material comprising a compound which is capable of being reduced by a silver halide developing agent at a rate slower than that of image-wise developable silver halide and in reduced state is capable of releasing a photographically useful group, characterized in that said compound corresponds to the following formula: ##STR1## wherein: R.sup.10 and R.sup.20 (same or different)(1) represent an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group or an aralkyl group including said groups in substituted form,(2) represent an aryl group including a substituted aryl group, or(3) represent a heterocyclic ring residue including such residue in substituted form, orR.sup.10 and R.sup.20 are ringclosed, either R.sup.10 or R.sup.20 containing a ballasting group conferring diffusion resistance to the compound in hydrophilic colloid media when penetrated by an aqueous alkaline liquid;L.sup.1 and L.sup.2 (same or different) represent a ##STR2## --SO.sub.Type: GrantFiled: February 14, 1983Date of Patent: May 22, 1984Assignee: AGFA-Gevaert, N.V.Inventors: Raphael K. Van Poucke, Christian C. Van de Sande, Andree Verhecken
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Patent number: 4434225Abstract: Disclosed is a light-sensitive silver halide color photographic material having at least one light-sensitive silver halide emulsion layer on a support, characterized in that said light-sensitive silver halide emulsion layer contains a cyan coupler represented by the formula [I] shown below, and said light-sensitive silver halide emulsion layer and/or a layer contiguous to said light-sensitive silver halide emulsion layer contains at least one of a timing DIR compound represented by the formula [II] shown below and a non-timing type DIR compound: ##STR1## wherein X, R.sub.1 and R.sub.2 are as defined in the specification; ##STR2## wherein Cp, TIME and Z are as defined in the specification.Type: GrantFiled: February 22, 1983Date of Patent: February 28, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Hiroshi Sugita, Yasuo Tsuda, Kenji Ito, Satoru Shimba
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Patent number: 4431728Abstract: There is disclosed a silver halide photographic light-sensitive material which comprises a support, a combination of an unfogged surface latent image type silver halide photographic emulsion and a material which is non-diffusible under alkali conditions and which is capable of releasing a diffusible development inhibitor or a precursor thereof as a result of cross oxidation with an oxidized product of a photographic developing agent; and a combination of an internal latent image type silver halide photographic emulsion whose silver halide grains contain therein, prior to development, fog nuclei and a dye image-forming material which is initially non-diffusible under alkaline conditions but which is capable of releasing a diffusible dye or a precursor thereof as a result of being oxidized by the oxidized product of said photographic developing agent.Type: GrantFiled: June 9, 1982Date of Patent: February 14, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Takao Abe, Tatsuhiko Kobayashi
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Patent number: 4420554Abstract: There is disclosed a silver halide photosensitive material which contains in at least one of silver halide emulsion layers and colloid layers at least on antifoggant precursor compound represented by the general formula: ##STR1## wherein A, Z, R.sub.1 and R.sub.2 are the same as defined previously. This photosensitive material is stabilized against overdevelopment fogging.Type: GrantFiled: February 17, 1982Date of Patent: December 13, 1983Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Minoru Ohashi, Kiyoshi Futaki, Katsuaki Iwaosa
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Patent number: 4414308Abstract: In a silver halide color photographic photosensitive material, having a red, a green and a blue light-sensitive emulsion layer on a support, each emulsion containing a nondiffusible image forming coupler, improvement is attained by providing a layer structure in which at least one of the red, the green and the blue light-sensitive emulsion layer is separated into a high sensitivity silver halide emulsion layer and a low sensitivity silver halide emulsion layer, both layers having photosensitive regions in substantially the same spectral region, by an intermediate layer and incorporating at least one kind of DIR compounds represented by formula (I) defined in the specification in at least one layer of the high sensitivity silver halide emulsion layer, the low sensitivity silver halide emulsion and the intermediate layer.Type: GrantFiled: March 16, 1982Date of Patent: November 8, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventor: Fumio Hamada
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Patent number: 4410618Abstract: .alpha.-Ketoimidomethyl blocked photographic reagents are useful in photographic elements, film units and processes. The blocked photographic reagents have the structure: ##STR1## wherein J represents ##STR2## X represents the atoms to complete a 5- or 6-membered ring or ring system; R represents alkyl of 1 to 30 carbon atoms or aryl of 6 to 30 carbon atoms; andPR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the blocking group.Type: GrantFiled: June 11, 1982Date of Patent: October 18, 1983Assignee: Eastman Kodak CompanyInventors: James P. Vanmeter, Chin H. Chen
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Patent number: 4409323Abstract: A silver halide photographic material containing a coupler capable of releasing a photographically useful group in a controllable timing.Type: GrantFiled: February 13, 1981Date of Patent: October 11, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Ryosuke Sato, Yuji Hotta, Katsumi Matsuura
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Patent number: 4359521Abstract: Light-sensitive color photographic material which contains on a base in at least one silver halide emulsion layer or an interlayer which is assigned to this and does not contain silver halide, at least one DIR coupler of the formula ##STR1## in which R is alkyl having 1 to 18 carbons atoms or aryl, D is hydrogen, optionally substituted alkyl having 1 to 18 carbon atoms, cycloalkyl having 3 to 10 carbon atoms, alkenyl having 2 to 18 carbon atoms, cycloalkenyl having 5 to 10 carbon atoms, aralkyl having 7 to 18 carbon atoms, cyano or halogen and G is a optionally substituted aliphatic hydrocarbon radical having 1 to 18 carbon atoms, the sum of the carbon atoms in the substituents D and G being at least 5, L.sub.1 is hydrogen or alkyl having 1 to 5 carbon atoms, L.sub.Type: GrantFiled: December 19, 1979Date of Patent: November 16, 1982Assignee: Ciba-Geigy AGInventors: Mario Fryberg, Remon Hagen, John G. V. Scott
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Patent number: 4358525Abstract: Photographically useful compounds such as photographic reagents and photographic dyes are blocked with a grouping which, under alkaline conditions, is cleaved from the compound by an intramolecular nucleophilic displacement reaction. The compounds are resistant to unblocking under storage conditions, but are uniformly unblocked under conditions encountered during photographic processing.Type: GrantFiled: August 12, 1981Date of Patent: November 9, 1982Assignee: Eastman Kodak CompanyInventors: Jared B. Mooberry, William C. Archie, Jr.
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Patent number: 4358532Abstract: A photographic element containing a compound represented by formula (I) ##STR1## wherein G represents --OR.sup.1 or --NHR.sup.2, R.sup.1 represents hydrogen or a hydrolyzable moiety, R.sup.2 represents hydrogen or an alkyl group containing from 1 to 50 carbon atoms, Z represents a photographically useful group, A represents an atomic group forming an aromatic ring, Ball represents an organic immobilizing group on the aromatic ring, which cntains from 8 to 50 carbon atoms, m represents an integer of 1 or 2, X represents a divalent organic group, Nu represents a nucleophilic group, and n represents an integer of 1 or 2, and X with the nucleophilic group Nu is capable of forming a 5- to 12-membered ring by oxidation having an electrophilic center at the carbon atom substituted by the --NHSO.sub.2 Z group.Type: GrantFiled: July 15, 1981Date of Patent: November 9, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Koichi Koyama, Shinsaku Fujita
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Patent number: 4358533Abstract: A silver halide photographic material having a hydrophilic colloid layer comprising fine polymer particles loaded with a hydrophobic photographic addenda provided on a support wherein the polymer has repeating units formed from a nonionic hydrophobic monomer. The nonionic hydrophobic monomer has the formula ##STR1## R.sub.1 and R.sub.2 individually are a hydrogen atom or methyl group, R.sub.3 is a hydrogen atom, an alkyl or aryl group, and m and n are integers of from 2 to 100 individually.Type: GrantFiled: March 11, 1981Date of Patent: November 9, 1982Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Kouji Tokitou, Tsuneo Wada
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Patent number: 4355101Abstract: Novel compounds which are represented by the formula ##STR1## wherein X represents the nonmetallic atoms necessary to form a nucleus which completes a 5- or 6-membered heterocyclic moiety, R is a group which is cleavable in aqueous alkaline medium and R.sub.1 is either a group which has a pKa of from about 7 to about 14 which is ionizable to an anion and wherein the silver salt of the mercaptan resulting from cleavage of -SR is rendered more soluble in the pH range within which R.sub.1 is ionized to an anion than it is below that pH range or a precursor of such a group. The compounds are useful in photographic applications.Type: GrantFiled: January 5, 1981Date of Patent: October 19, 1982Assignee: Polaroid CorporationInventors: Avinash C. Mehta, George H. Nawn, Lloyd D. Taylor
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Patent number: 4355100Abstract: A color photographic material having a light-sensitive silver halide emulsion layer containing a DIR compound having an amino group and a DIR compound having no amino group.Type: GrantFiled: January 19, 1981Date of Patent: October 19, 1982Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Hiroshi Sugita, Shizuo Saito, Ryosuke Sato, Kiyoshi Yamashita
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Patent number: 4355092Abstract: There are disclosed novel compounds which are represented by the formula ##STR1## wherein X represents the nonmetallic atoms necessary to form a nucleus which completes a 5- or 6-membered heterocyclic moiety, R is H, an alkali metal or a group which is cleavable in aqueous alkaline medium and Z is H, alkyl having from 1 to 10 carbon atoms, aralkyl such as benzyl or phenethyl, phenyl or substituted phenyl. The compounds are useful in photographic applications.Type: GrantFiled: January 5, 1981Date of Patent: October 19, 1982Assignee: Polaroid CorporationInventors: Avinash C. Mehta, George H. Nawn, Lloyd D. Taylor
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Patent number: 4353979Abstract: A silver halide photographic material containing a solution of a 5-pyrazolone type magneta coupler and a high-boiling organic solvent of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represent an aliphatic or aromatic group with a carbon atom of R.sub.3 directly bonded to the phosphorus atom.Type: GrantFiled: July 16, 1980Date of Patent: October 12, 1982Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Sadatugu Terada, Hideaki Arai, Kenji Itoh, Hiroshi Sugita, Katsumi Matsuura, Thuneo Wada
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Patent number: 4345024Abstract: A photographic development inhibitor releasing compound of the formula (I): ##STR1## wherein X is an indazole residue which may be substituted and which is bonded to the benzene nucleus through the nitrogen atom at the 1-position or 2-position thereof; R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, are each hydrogen, an alkyl group, an aryl group, an alkylthio group, an arylthio group, a halogen atom, a hydroxy group, an alkoxy group, an aryloxy group, an acyl group, an alkoxycarbonyl group, an amido group, a sulfonamido group, a carbamoyl group, a sulfamoyl group, a heterocyclic residue or any of the groups described above for X; further R.sup.2 and R.sup.3 may combine with each other to form a ring; and R.sup.4 and R.sup.5, which may be the same or different, are each hydrogen or a group capable of being hydrolyzed in the presence of an alkali. The compound is very active and rapidly releases a development inhibiting agent upon oxidation.Type: GrantFiled: April 30, 1981Date of Patent: August 17, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeo Hirano, Kei Sakanoue
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Patent number: 4340664Abstract: Latexes suited for homogeneously incorporating compounds with a photographically useful group into photographic silver halide emulsion materials. The latex incorporates a copolymer comprising recurring units of a monomer with photographically useful group, and recurring units of surface active monomer, according to the general formula: ##STR1## wherein: R.sup.1 is hydrogen or methyl,n is 0 or 1 to 20,L is ##STR2## R.sup.2 is hydrogen or a hydrocarbon group, R.sup.3 is a monovalent chemical bond or a bivalent aliphatic hydrocarbon group or such group interrupted by the group --COO-- or --CONR--, andY is a sulpho, sulphato or phosphono group in acid or salt form, and at least one of the groups --(CH.sub.2).sub.n --, R.sup.2 and R.sup.3 is or comprises a hydrocarbon chain of at least 8 C-atoms.Type: GrantFiled: September 19, 1980Date of Patent: July 20, 1982Assignee: Agfa-Gevaert, N.V.Inventors: Marcel J. Monbaliu, Walter F. De Winter, Raphael K. Van Poucke
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Patent number: RE31893Abstract: A color photographic material having a light-sensitive silver halide emulsion layer containing a DIR compound having an amino group and a DIR compound having no amino group.Type: GrantFiled: July 14, 1983Date of Patent: May 21, 1985Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Hiroshi Sugita, Shizuo Saito, Ryosuke Sato, Kiyoshi Yamashita