In Aqueous Solution Patents (Class 436/125)
  • Patent number: 8025779
    Abstract: A water quality analyzer comprises: sensor electrodes 1a, 1b made of different metals from each other, the electrodes in a liquid of inspecting object generating a sense voltage in proportion to the liquid's impurities concentration; an operational amplifier OP1 amplifying the sense voltage without inverting to provide for a CPU 3; a resistor R0 whose one end is connected to the electrode 1a; and a voltage divider 2 applying a voltage obtained by dividing the sense voltage by a prescribed division ratio to R0's another end. The CPU 3 calculates input signal from OP1 to obtain chlorine concentration and displays the calculated result on a LCD 4 in a measurement mode, and sets the division ratio of the divider 2 so that sense voltage across electrodes 1a, 1b soaked in a liquid including prescribed concentration chloride approximately agrees with a reference voltage of prescribed concentration in a sense-voltage calibration mode.
    Type: Grant
    Filed: November 10, 2004
    Date of Patent: September 27, 2011
    Assignees: Tanita Corporation, FIS Inc.
    Inventors: Kiyoshi Sagawa, Shinichi Harima, Kazuo Onaga, Junko Yanagitani, Osamu Inazawa
  • Publication number: 20110217788
    Abstract: The invention relates to a method of monitoring a concentration of a halogenated disinfectant in swimming pools or the like and a device for implementing the method. The method comprises: a liquid-injection step of injecting the liquid to be analyzed into the analysis chamber; a reagent-injection step of injecting a reagent into the analysis chamber; a measurement step of measuring the liquid/reagent mixture by colorimetry; a processing step of processing the measurement in relation to data; and a verification step of verifying the colorimetric measurement when the measurement corresponds to the reagent being bleached or to an absence of reaction color.
    Type: Application
    Filed: November 17, 2009
    Publication date: September 8, 2011
    Applicant: PACIFIC INDUSTRIE
    Inventor: Zbigniew Stadnicki
  • Patent number: 8008087
    Abstract: Low concentrations of silicon in an etchant solution are analyzed by adding a predetermined concentration of fluoride ions to a test solution comprising a predetermined volume of the etchant solution, and measuring the concentration of fluoride ions in the test solution. Reaction with silicon ions in the test solution reduces the concentration of fluoride ions, which are present in stoichiometric excess, so that the silicon concentration of the etchant solution can be calculated from the difference between the predetermined and measured concentrations of fluoride ions in the test solution. The method is especially suited for analysis of silicon nitride etchants comprising a high concentration of phosphoric acid.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: August 30, 2011
    Assignee: ECI Technology, Inc.
    Inventors: Eugene Shalyt, Julia Tyutina, Peter Bratin
  • Patent number: 7989211
    Abstract: This invention relates to the development of a new Raman enhancing reagent and a surface-enhanced Raman scattering (SERS) method for rapid and ultra-sensitive detection and identification of perchlorate (ClO4?) and other anions such as technetium (TcO4?), uranium and nitrate in environmental samples. The method involves the synthesis of controlled gold nanoparticles which are modified with amine functional groups such as 2-(dimethylamino)ethanethiol and N,N,N-trimethylaminethiol. These functionalized Au nanoparticles were found to be reactive with perchlorate and other anions and can be used to detect these anions by Raman spectroscopy at ultra low concentrations in complex environmental matrices. This invention overcomes the limitations of currently-available analytical techniques by offering an inexpensive, rapid, ultra-sensitive, and real-time identification and detection of perchlorate and other anions.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: August 2, 2011
    Assignee: UT-Battelle, LLC
    Inventors: Baohua Gu, Chuanmin Ruan, Wei Wang
  • Patent number: 7943389
    Abstract: Methods for determining chlorine demand in water are provided. One method comprises (a) providing a test water sample containing at least one contaminant and a source of chlorine and a source of bromide; (b) heating the test water sample for a suitable time and temperature sufficient to substantially oxidize the at least one contaminant in the test water sample; and (c) determining the content of residual chlorine present in the test water sample.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: May 17, 2011
    Assignee: Chemtura Corporation
    Inventor: Karen Rigsby
  • Patent number: 7939334
    Abstract: A process for simultaneous assay of chlorides and sulfides by low pressure ion exclusion chromatography is provided, and in said process an analytic apparatus comprising a sampling valve, a sampling loop, an ion exclusion column and an analytic detection flow path is used, and said process comprises the following steps: (1) in the analytic detection flow path, the mixture of developer R1 and developer R2 mixes with Eluent C and then enters into a reactor, and the mixing is continued under heating.
    Type: Grant
    Filed: January 28, 2010
    Date of Patent: May 10, 2011
    Assignee: Sichuan University
    Inventors: Xinshen Zhang, Lingyun Yu, Xiaoping Jiang
  • Patent number: 7901948
    Abstract: The invention relates to the use of molecular tweezers as sensitive materials in chemical sensors intended to detect or assay organic compounds in the vapour state, and in particular nitro compounds. These molecular tweezers correspond to the general formula (I): in which: MC1 and MC2 represent macrocycles; p and q are equal to 0 or 1; X and Y are optionally substituted C1 to C10 alkylene groups; while E represents an optionally substituted cyclic or heterocyclic spacer group; and in which MC1 and MC2 are positioned facing each other. Fields of application: detection of explosives, control and monitoring of atmospheric pollution and of the quality of ambient air in relatively confined spaces, and monitoring of industrial sites.
    Type: Grant
    Filed: February 1, 2006
    Date of Patent: March 8, 2011
    Assignee: Commissariat A l'Energie Atomique
    Inventors: Lionel Hairault, Pierre Montmeat, Eric Pasquinet, Jean-Michel Barbe, Stéphane Brandes, Franck Denat, Claude Gros, Roger Guilard
  • Patent number: 7858379
    Abstract: A method for determining the amount of a known iodine-containing organic compound in an aqueous solution. The method comprises electrochemically reducing the known iodine-containing organic compound in an aqueous medium to release iodide anions, chemically oxidizing the iodide anions to produce molecular iodine, and measuring the amount of molecular iodine. The known iodine-containing organic compound is preferably an aryl iodide, such as Iothalamate. Other preferred iodine-containing organic compounds include various glomerular filtration rate (GFR) marker compounds in plasma or urine samples, as useful in the measurement of GFR for an animal. The electrochemical reduction of the known iodine-containing organic compound is preferably performed in an electrochemical cell including a working electrode separated from a counter electrode by a cation exchange membrane. The working electrode most preferably includes bismuth and the counter electrode most preferably includes platinum.
    Type: Grant
    Filed: June 3, 2008
    Date of Patent: December 28, 2010
    Assignee: Lynntech, Inc.
    Inventor: Bikas Vaidya
  • Publication number: 20100216118
    Abstract: A method that uses an L-?-dipalmitoleoyl-phosphatidylcholine (DPPC) surfactant based device that reacts with a substance in a known manner, to detect a substance of interest or to extract a substance of interest from a material is provided. The principles of the present invention are particularly useful in detecting/measuring a substance that is harmful to a human, and also to extracting NACL from saltwater.
    Type: Application
    Filed: October 1, 2007
    Publication date: August 26, 2010
    Inventor: Mark L. Witten
  • Patent number: 7709265
    Abstract: Prior to adding detergent or chelant, the conductivity of water in a washing chamber is measured. The maximum concentration of hard water ions that could correspond to the measured conductivity is determined, i.e., it is assumed that all of the conductivity is from calcium and/or magnesium ions in the water even though other ions may in fact be contributing to the measured conductivity. Enough chelating agent is added to the chamber to sequester this maximum concentration of hard water ions and the conductivity is measured again. Using the two conductivity measurements, the actual concentration of hard water ions is determined. A chelant factor based on the actual concentration of hard water ions is then used to determine the amount of chelant to be added for subsequent wash cycles to sequester all of the hard water ions.
    Type: Grant
    Filed: March 24, 2005
    Date of Patent: May 4, 2010
    Assignee: JohnsonDiversey, Inc.
    Inventors: Wai Yin Cedric Chan, James W. Livingston, Patricia Anne Anderson
  • Publication number: 20100086910
    Abstract: A method for surface modification of single walled carbon nanotubes. In one embodiment, the method includes the steps of providing a detergent solution, adding a plurality of single walled carbon nanotubes into the detergent solution, performing a first sonication to disperse the single walled carbon nanotubes in the detergent solution, and performing a second sonication after the first sonication to make detergent encased single walled carbon nanotubes. At least one of the plurality of single walled carbon nanotubes is at least partially wrapped by one or more detergent molecules to make it a detergent encased single walled carbon nanotube. In one embodiment, the detergent comprises SDS, PSS or a combination of them.
    Type: Application
    Filed: November 17, 2006
    Publication date: April 8, 2010
    Applicant: Board of Trustees of the University of Arkansas
    Inventors: Wei Zhao, Chulho Song
  • Publication number: 20100059423
    Abstract: A liquid sample is analysed for a target chemical. A sample solution is added to a measurement cell of known volume and a reagent is incrementally added to the cell until a detectable change is observed. A reference compound, of a known concentration, that does not take part in the reaction between the target chemical and reagent, is added to the reagent and by measuring the concentration of the reference compound the amount of reagent used may be determined. A single mechanism introduces a sample, adds reagent mixes cleans and flushes the measurement cell which incorporates a longitudinal chamber having a number of fluid inlets for sample and reagent and an outlet for measured sample/reagent mixtures, a detector being located in or adjacent to said chamber between the inlets and said outlet and a piston movable in said chamber carrying a series of seals such that movement of the piston sequentially opens the inlets and expels the fluid.
    Type: Application
    Filed: November 23, 2007
    Publication date: March 11, 2010
    Applicant: Aqualysis Pty Ltd
    Inventors: Stephen Charles Davis, John David Petty, John Thomas Huberts
  • Publication number: 20100040913
    Abstract: The present invention provides an apparatus and method for determining deterioration of a fuel cell, the method including measuring in real time fluoride ion concentration or pH value of outflow water from a fuel cell stack during operation in a fuel cell vehicle, calculating a fluoride emission rate from the measured value and, if the calculated fluoride emission rate is out of a predetermined normal range, determining deterioration of an electrolyte membrane of the fuel cell stack.
    Type: Application
    Filed: January 28, 2009
    Publication date: February 18, 2010
    Applicants: HYUNDAI MOTOR COMPANY, INDUSTRY-ACADEMY COOPERATION FOUNDATION, SCNU
    Inventors: Ik Jae Son, Byung Ki Ahn, Tae Won Lim, Jong Hyun Lee, Kwon Pil Park, Ho Lee, Chang Won Jung, Seung Chan Oh, Jae Jun Ko, Young Min Kim, Sae Hoon Kim, Jong Jin Yoon, Se Joon Im
  • Patent number: 7648695
    Abstract: New chemotherapeutic medicaments and certain medical uses and methods for use of such chemotherapeutic medicaments for treatment of disease in human or animal tissue are described, wherein a primary active component of such medicaments is a halogenated xanthene or halogenated xanthene derivative. Preferably, the halogenated xanthene is Rose Bengal or a functional derivative of Rose Bengal. The halogenated xanthenes constitute a family of useful chemotherapeutic agents that afford selective, persistent accumulation in certain tissues.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: January 19, 2010
    Assignee: Provectus Pharmatech, Inc.
    Inventors: H. Craig Dees, Timothy C. Scott
  • Patent number: 7531360
    Abstract: A selective method of dechlorination treatment of circulating water containing disinfectant chlorine in the form of ClO?,HClO, ClO2 or chloramine, where an ascorbic acid aqueous solution is injected from a storage reservoir into the water flow, the mass flow rate of the injected ascorbic acid solution being regulated with respect to the mass flow rate of the chlorine in the circulating water to be treated, in such a way that the ratio (R) of the ascorbic acid and chlorine mass flow rates (R=D1/ D2) is between 2.5 and 4, preferably less than or equal to 3. The method can be used for treatment of water that feeds into a biological detector containing a disinfectant chlorine content that is incompatible with the survival of the biological species used in the detector. The disinfectant chlorine level in the circulating water after mixing is maintained at a value lower than or equal to 0.6 mg/l, and preferably lower than or equal to the detectable limit.
    Type: Grant
    Filed: June 27, 2006
    Date of Patent: May 12, 2009
    Assignee: Societe des Eaux de Marseille
    Inventors: Jean-Luc Boudenne, Bruno Coulomb, Gerard Lieutaud
  • Publication number: 20090047743
    Abstract: A kit for determining residual chlorine or chloramine amount of a sample; comprising: a means for containing a PVA solution as an indicator, and another means for containing a reducing indicator. Said reducing indicator would be oxidized by a reaction with residual chlorine or chloramine and said PVA indicator induces a dye by reaction with oxidized compound such as free iodine; wherein intensity of said dye would be changed depending upon the residual chlorine or chloramine amount of the sample.
    Type: Application
    Filed: September 7, 2008
    Publication date: February 19, 2009
    Inventors: Nooshin Mirkheshty, Sayyed Ali Alavi
  • Patent number: 7491546
    Abstract: Water soluble analytical agents for chlorine analysis of water are delivered into a sample from a support that is beneficially moved in the sample to assist delivery and mixing. Beneficially, an immediate photometric analysis of free chlorine is provided, and variability of measurements is reduced. Advantageously, the analysis is a touch-free chlorine analysis.
    Type: Grant
    Filed: September 27, 2004
    Date of Patent: February 17, 2009
    Assignee: Industrial Test Systems, Inc.
    Inventor: Ivars Jaunakais
  • Publication number: 20090017549
    Abstract: A method for determining the amount of a known iodine-containing organic compound in an aqueous solution. The method comprises electrochemically reducing the known iodine-containing organic compound in an aqueous medium to release iodide anions, chemically oxidizing the iodide anions to produce molecular iodine, and measuring the amount of molecular iodine. The known iodine-containing organic compound is preferably an aryl iodide, such as Iothalamate. Other preferred iodine-containing organic compounds include various glomerular filtration rate (GFR) marker compounds in plasma or urine samples, as useful in the measurement of GFR for an animal. The electrochemical reduction of the known iodine-containing organic compound is preferably performed in an electrochemical cell including a working electrode separated from a counter electrode by a cation exchange membrane. The working electrode most preferably includes bismuth and the counter electrode most preferably includes platinum.
    Type: Application
    Filed: June 3, 2008
    Publication date: January 15, 2009
    Applicant: LYNNTECH, INC.
    Inventor: Bikas Vaidya
  • Patent number: 7402299
    Abstract: New intracorporeal photodynamic medicaments and certain medical uses and methods for use of such photodynamic medicaments for treatment of disease in human or animal tissue are described, wherein a primary active component of such medicaments is a halogenated xanthene or halogenated xanthene derivative. In preferred embodiments, such medicaments are used for treatment of a variety of conditions affecting the skin and related organs, the mouth and digestive tract and related organs, the urinary and reproductive tracts and related organs, the respiratory tract and related organs, the circulatory system and related organs, the head and neck, the endocrine and lymphoreticular systems and related organs, various other tissues, such as connective tissues and various tissue surfaces exposed during surgery, as well as various tissues exhibiting microbial or parasitic infection.
    Type: Grant
    Filed: November 30, 2004
    Date of Patent: July 22, 2008
    Assignee: Provectus Pharmatech, Inc.
    Inventors: H. Craig Dees, Timothy C. Scott, Eric A. Wachter, Walter G. Fisher, John Smolik
  • Publication number: 20080171392
    Abstract: The present invention relates generally to kits, compositions and methods useful in the qualitative analysis of the presence of chemicals used and produced in the manufacture of illegal drugs. The compositions and methods may be useful for, among other things, qualitatively determining whether items of real or personal property or other chattels have been exposed to the manufacture of illegal drugs or whether such items have been contaminated by illegal drugs.
    Type: Application
    Filed: January 14, 2008
    Publication date: July 17, 2008
    Applicant: BOARD OF TRUSTEES OF THE UNIVERSITY OF ARKANSAS
    Inventor: J. Jennifer Wu
  • Patent number: 7396691
    Abstract: The present invention relates to a method for detecting and/or measuring the concentration of fluoride (F?) or hydrogen fluoride (HF) in a sample, comprising the steps consisting of bringing said sample, in aqueous solution, into contact with a silylated organic compound in order to obtain a measurement solution, with said silylated organic compound being desilylated when it is in the presence of hydrofluoric acid or a fluoride, with the silylated organic compound and the desilylated organic compound being able to be detected and/or measured separately from each other; and detecting and/or measuring, in said measurement solution, the appearance of the desilylated against compound or the disappearance of the silylated organic compound, which takes place if fluoride or hydrogen fluoride is present in the sample. The method enables the presence of hydrogen fluoride or of fluorine to be detected very easily and expediently at concentrations of 10?2 l of HF/106 l of air (10 ppb) or else of 0.
    Type: Grant
    Filed: May 14, 2004
    Date of Patent: July 8, 2008
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Eric Ezan, Marie-Astrid Sagot, Philippe Pradelles
  • Publication number: 20080153173
    Abstract: In a method for determining the concentration of organically bound halogens present in waste water, a pre-specified amount of waste water is withdrawn and converted into a measurement sample. A spectral measurement is subsequently carried out on the measurement sample, and the result of the spectral measurement is compared with reference measurements in order to determine the concentration of organically bound halogens. The organically bound halogens are enriched in the measurement sample by extraction or adsorption. Inorganically bound halogens are removed from the measurement sample. The comparison of the spectral measurement with reference measurements is carried out using chemometric methods.
    Type: Application
    Filed: February 24, 2006
    Publication date: June 26, 2008
    Inventor: Christian Buck
  • Publication number: 20080139964
    Abstract: Muscle cramps can be reduced or avoided by monitoring the concentration of salt in perspiration to indicate the degree of salt depletion. Based on the degree of salt depletion, a sufficient amount of rehydration beverage is consumed to normalize the salt level.
    Type: Application
    Filed: November 1, 2006
    Publication date: June 12, 2008
    Applicant: Stokely-Van Camp, Inc.
    Inventors: Robert Murray, John R. Stofan, Jeffrey J. Zachwieja, Craig A. Horswill, Myron C. Rapkin, Wayne W. Weber
  • Patent number: 7384623
    Abstract: High energy phototherapeutic agents or radiosensitizer agents comprised of a halogenated xanthene, or other related agents that exhibit a preference for concentration in biologically sensitive structures in diseased tissue, and methods of treating and imaging using such radiosensitizer agents in such diseased tissue are described herein.
    Type: Grant
    Filed: August 25, 1999
    Date of Patent: June 10, 2008
    Assignee: Provectus Pharmatech, Inc.
    Inventors: H. Craig Dees, Timothy Scott, John T. Smolik, Eric A. Wachter
  • Publication number: 20070224691
    Abstract: The present invention provides a composition for measuring residual chlorine concentration in the sample water, which is an aqueous solution comprising a specific benzidine compound, e.g., N,N?-bis(2-sulfoethyl)-3,3?-dimethylbenzidine disodium salt, and a surfactant, wherein the content of the surfactant is set to be 0.5% by weight or more and to be 0.5 weight-fold or more of the content of the benzidine compound, and the pH is adjusted to be in the acidic region. This composition can prevent the benzidine compound from crystallizing in the aqueous solution under the low temperature condition such as in winter season or the like.
    Type: Application
    Filed: February 26, 2007
    Publication date: September 27, 2007
    Inventor: Hiroyuki Mitsumoto
  • Patent number: 7273588
    Abstract: Methods for determining the amount of at least one metal analyte present in a liquid or gas sample of a halosilane supply (e.g., a chlorosilane supply) are disclosed herein. A sample of a halosilane supply is contacted and reacted with an aqueous hydrofluoric acid solution to produce a liquid reaction mixture. Liquid from the liquid reaction mixture is evaporated under controlled temperature and pressure conditions to near dryness. The nearly-dry residue is prepared for spectral analysis. The presence of a detectable amount of at least one metal analyte is determined for the sample.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: September 25, 2007
    Assignee: Air Liquide America L.P.
    Inventors: Daniel C. Cowles, David S. Bollinger
  • Patent number: 7198955
    Abstract: A method is disclosed whereby the concentration of a blood substitute, such as cross-linked hemoglobin, in a serum or plasma specimen is rapidly and accurately identified and quantified. The method further takes the measured concentration of the blood substitute and uses it to correct for its effect, if any, on a measured analyte concentration, e.g., serum/plasma total protein. Further, the method allows for the determination of the concentration of true hemoglobin in the presence of blood substitutes. The method is carried out in respect of samples contained in a primary or secondary labelled tube, or a pipette tip used to dispense serum or plasma in a blood analyzer.
    Type: Grant
    Filed: October 16, 1997
    Date of Patent: April 3, 2007
    Assignee: NIR Diagnostics Inc.
    Inventors: James Samsoondar, Duncan MacIntyre
  • Patent number: 7189571
    Abstract: An analytical technique for the accurate and precise measurement of trace water in chemical reagents, comprising the steps of combining a chemical reagent comprising ?5 ppm water, with hexafluoroacetone (HFA), to form a sample mixture comprising at least the chemical reagent and a water derivative of hexafluoroacetone; and measuring the concentration of the water derivative of hexafluoroacetone by gas chromatography.
    Type: Grant
    Filed: March 27, 2002
    Date of Patent: March 13, 2007
    Assignee: Advanced Technology Materials, Inc.
    Inventors: Alexander S. Borovik, Ziyun Wang, Chongying Xu, Thomas H. Baum
  • Patent number: 7182873
    Abstract: First, a primary fluoric ion concentration detection process is performed, and a primary calcium salt addition process is performed to add calcium salt in a first reaction tank, wherein the dosage of the calcium salt in the primary calcium salt addition process is determined according to the detected fluoric ion concentration. Thereupon, a secondary calcium salt addition process is performed to add calcium salt into the second reaction tank. Following that, a solid-liquid separation process is performed to separate calcium fluoride from the wastewater, and a secondary fluoric ion concentration detection process is performed upon the wastewater after the calcium fluoride is separated. Finally, the dosage of the calcium salt in the secondary calcium salt addition process is determined in a feed back control manner according to the detected fluoric ion concentration.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: February 27, 2007
    Assignee: Powerchip Semiconductor Corp.
    Inventors: Chen-Hung Hsien, Wen-Ta Huang
  • Patent number: 7074365
    Abstract: The invention herein provides for the detection of certain organic halogen-containing agents or toxicants such as sarin, chloropicrin, mustard gas, mustard chlorohydrin, phosgene, chlorine, soman, lewisite, diphosgene and others by, in one embodiment, first reacting the agents with superoxide free radical anion (.O{overscore (2)}) to produce light pulses which can be detected by a standard photon counter. The superoxide may be available from a dimethyl sulfoxide superoxide (.O{overscore (2)}) liquid solution, from lecithin coated beads charged with superoxide (.O{overscore (2)}) in a reaction vessel or from a quarternary ammonium ion exchange resin charged with superoxide anion (.O{overscore (2)}) in a reaction vessel.
    Type: Grant
    Filed: April 22, 2002
    Date of Patent: July 11, 2006
    Inventor: Antony R. Shoaf
  • Patent number: 6998271
    Abstract: A luminescent sensory material for the detection of the presence of organo-halogen compounds is described. This material is based on a platinum chromophore functionalized with pyridylacetylide ligands, as shown in Formulae I and II below. These complexes exhibit positive luminescence upon exposure to the vapors of organ-halogen compounds like CH2Cl2 or CHCl3 with high selectivity over non-chlorinated common organic vapors. Direct relationships between vapor concentration and luminescence intensity are established using thin films prepared from these complexes.
    Type: Grant
    Filed: June 3, 2002
    Date of Patent: February 14, 2006
    Assignees: The Hong Kong Polytechnic University, The University of Hong Kong
    Inventors: Kwok-Yin Wong, Chi-Ming Che, Wei Lu, Zhike He
  • Patent number: 6890758
    Abstract: The concentration of citrate complexing agent in an electroless cobalt or nickel plating bath is determined by titrating a sample of the electroless plating bath containing a small concentration of free fluoride ion with a standard lanthanum nitrate solution. During the titration, La3+ ion first reacts preferentially with the citrate complexing agent and then with fluoride ion, which reduces the free fluoride ion concentration. The endpoint for the titration is indicated by a substantial decrease in the free fluoride ion concentration, which is detected via a fluoride ion specific electrode (ISE). The method can be used for analysis of other complexing agents.
    Type: Grant
    Filed: June 13, 2003
    Date of Patent: May 10, 2005
    Assignee: ECI Technology, Inc.
    Inventors: Eugene Shalyt, Michael Pavlov, Peter Bratin, Alex Kogan, Michael James Perpich
  • Patent number: 6881583
    Abstract: A water chloramination control system compares the concentration of aqueous higher chloramines to aqueous ammonia to optimize the ratio of added ammonia to chlorine. Aqueous ammonia concentration is measured by conversion to monochloramine which concentration is determined spectroscopically. Higher chloramine concentration is measured by a reaction producing free iodine which concentration is also determined spectroscopically. The higher chloramine to ammonia ratio is used to control ammonia feed to the water. Problems associated with excess chlorine, or excess ammonia, are avoided.
    Type: Grant
    Filed: June 16, 2002
    Date of Patent: April 19, 2005
    Assignee: Applied Spectrometry Associates Inc.
    Inventor: Scott J. Kahle
  • Publication number: 20040219683
    Abstract: Methods of measuring free and total chlorine content in solutions are provided without lowering the pH of the solution to the acid range by modifying a solution containing chlorine and water to contain a proton donating compound and electrochemically measuring the concentration of the chlorine in the solution. An additional potassium iodide reagent is added when total chlorine content is measured. Stable aqueous reagent solutions useful in automated chlorine analyzers which contain sodium bicarbonate, a base, and water or borax, water, and acid are also described. Finally, apparatuses for detecting the level of chlorine in water samples utilizing an automated chlorine detector, a cartridge having a solid proton donating compound, and optionally a standpipe are discussed.
    Type: Application
    Filed: July 23, 2003
    Publication date: November 4, 2004
    Applicant: Severn Trent Water Purification Inc.
    Inventors: Robert M. Taylor, Dianne M. Rothstein
  • Patent number: 6777242
    Abstract: The present invention relates to a stable aqueous solution (A) comprising an azo dye, a borate buffer and one or more masking agents, wherein the azo dye changes its coloration or coloration intensity in the presence of chlorine dioxide. The present invention further relates to a process for manufacturing the aqueous azo-dye solution (A), and to its use for the determination of residual chlorine dioxide in water.
    Type: Grant
    Filed: September 8, 1999
    Date of Patent: August 17, 2004
    Assignee: Atofina
    Inventors: Jean-Pierre Gautier, Frédérick Mantisi
  • Patent number: 6753186
    Abstract: A water quality sampling system and method in which compact water impurity detector and monitoring units intended for domestic use are installed in a residential environment while detected values are electronically transmitted to a Central Monitoring Station (CMS), where customers can register and pay over the Internet. Using the impurity detector units, a portion of an incoming water stream is passed to an analyzer for detection of chlorine and various contaminants. The detector analyzes related data for determining the condition and extent of impurity in the water elements. This data is transmitted from a compact control box, known as the wall unit, that translates the data for output to the CMS, located in another geographic locale, via a common data acquisition network. This network can be the Internet or a cellular and/or satellite connection.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: June 22, 2004
    Assignee: eWaterTek Inc.
    Inventor: Harold I. Moskoff
  • Publication number: 20040110299
    Abstract: A sensor system for controlling humidity effects on sensor performance comprising one or more sensor devices, a moisture reservoir disposed adjacent to the sensor array, wherein the moisture reservoir comprises desiccant materials operable for reversibly exchanging moisture with a sampled atmosphere, and a hydrophobic semi-permeable membrane permeable to volatile organic compounds and impermeable to water. A probe device for sampling groundwater comprising a sensor array, a moisture reservoir disposed adjacent to the sensor array, wherein the moisture reservoir comprises desiccant materials operable for extracting moisture from a sampled atmosphere, a hydrophobic semi-permeable membrane, a groundwater entry assembly, a power source, an analyte trap, and communications electronics. Methods for sampling a subaqueous environment using a probe device.
    Type: Application
    Filed: December 10, 2002
    Publication date: June 10, 2004
    Inventor: Timothy Mark Sivavec
  • Patent number: 6689618
    Abstract: A single reagent system and a method to detect and measure oxidizing adulterants in bodily fluid being screened for drugs of abuse are disclosed. The system comprising a strip containing 0.05 to 0.2 micromole/25 sq. mm. of a benzidine derivative and is used to detect sodium hypochlorite (bleach), chlorine, hydrogen peroxide, sodium bromide, sodium iodide, sodium nitrite, and pyridinium chlorochromate adulterants in urine, sweat, saliva, blood or other bodily fluids during screening for drugs of abuse.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: February 10, 2004
    Inventor: Shuenn Tzong Chen
  • Publication number: 20040018631
    Abstract: A method for detecting the presence and/or amount of fluoride in a test sample which comprises contacting the test sample with a compound of Formula (1) or a salt thereof and evaluating any change in the spectral characteristics of the compound:
    Type: Application
    Filed: August 8, 2003
    Publication date: January 29, 2004
    Inventors: Christopher James Ward, Prakash Patel, Tony David James
  • Patent number: 6673226
    Abstract: The concentration of chloride ion in an acid copper electroplating bath is determined from the effect that chloride exerts on the copper electrodeposition rate in the presence of organic additives. A cyclic voltammetric stripping (CVS) rate parameter is measured, before and after standard addition of a plating bath sample, in an acid copper electrodeposition solution containing little or no chloride and at least one organic additive. Cross contamination and waste disposal issues associated with the reagents and reaction products involved in chloride titration analyses are avoided. The method may also be applied to analysis of other halides (bromide and iodide) and other solutions.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: January 6, 2004
    Assignee: ECI Technology
    Inventors: Alex Kogan, Eugene Shalyt, Peter Bratin, Michael Pavlov, Michael James Perpich
  • Publication number: 20030186451
    Abstract: This invention is in the field of toxicology and clinical diagnostics. More specifically, this invention provides a single dry chemistry, liquid chemistry, or lateral flow dry chemistry combination test device for use in the detection of adulteration by the addition of bromine(s) to a specimen submitted for Drugs of Abuse (DAU) testing and clinical diagnostic purposes in aqueous fluids, including urine, saliva, serum, blood, sweat extracts, and liquid homogenates of hair.
    Type: Application
    Filed: March 21, 2003
    Publication date: October 2, 2003
    Inventor: Jack V. Smith
  • Patent number: 6627450
    Abstract: Methods of measuring free and total chlorine content in solutions are provided without lowering the pH of the solution to the acid range by modifying a solution containing chlorine and water to contain a proton donating compound and electrochemically measuring the concentration of the chlorine in the solution. An additional potassium iodide reagent is added when total chlorine content is measured. Stable aqueous reagent solutions useful in automated chlorine analyzers which contain sodium bicarbonate, a base, and water or borax, water, and acid are also described. Finally, apparatuses for detecting the level of chlorine in water samples utilizing an automated chlorine detector, a cartridge having a solid proton donating compound, and optionally a standpipe are discussed.
    Type: Grant
    Filed: February 11, 2000
    Date of Patent: September 30, 2003
    Assignee: Severn Trent Water Purifications, Inc.
    Inventors: Robert M. Taylor, Dianne M. Phelan
  • Publication number: 20030175152
    Abstract: The present invention provides test carriers to determine the presence or amount of a given substance in a liquid sample. The present invention also provides apparatus and methods for analyzing liquid samples using these test carriers.
    Type: Application
    Filed: November 25, 2002
    Publication date: September 18, 2003
    Inventors: Myron C. Rapkin, Claude R. Gunter
  • Patent number: 6617168
    Abstract: The present invention provides an evaluation method and an evaluation system of free halogen concentration which eliminate the necessity of early exchanging or recycling of catalysts, as compared with a conventional method or system. In the present evaluation method of free halogen concentration, a main flow path of a sample liquid for evaluation and a sub-region that communicates with the main flow path are formed, a potential-measuring electrode is installed in the main path, while a reference electrode is installed in the sub-region at a position where free halogen in the sample liquid has been decomposed. Moreover, free halogen in the sample liquid is decomposed by a free-halogen decomposing substance in the sub-region, and the free halogen concentration is evaluated from the electric potential difference between the reference electrode and the potential-measuring electrode.
    Type: Grant
    Filed: January 6, 1999
    Date of Patent: September 9, 2003
    Assignee: Omega Co., Ltd.
    Inventors: Shinichi Nakamura, Kunihiko Fukutsuka, Yasushi Hanano
  • Publication number: 20030166296
    Abstract: A chemical sensing system senses a concentration of a chemical of interest in a fluid. A portion of the chemical of interest diffuses across a barrier into an electrolyte. The barrier can be one or more polymeric hollow fibers. Electrodes or other sensing devices are disposed within the electrolyte. The electrolyte is selected such that it undergoes regenerative chemical reaction as it is exposed to the chemical of interest and the electrodes. The concentration of the chemical of interest can be determined by measuring a property of the electrolyte, such as current flowing through the electrolyte.
    Type: Application
    Filed: March 1, 2002
    Publication date: September 4, 2003
    Inventors: Roxane F. Morrison, Wayne B. Wood
  • Publication number: 20030152486
    Abstract: An ion-exchange membrane has a mesh structure with microscopic pores in which water can infiltrate. When the ion-exchange membrane is incorporated in the sensor body, the one side of the membrane comes in contact with the sample solution and the other side thereof comes in contact with the internal solution. The water in the internal solution gradually migrates to the side of the sample flow path permeating through the membrane. When the sensor is used for extended periods of time, therefore, the sensor performance often decreases due to a decrease in the electric conductivity between the internal electrode and the ion-exchange membrane.
    Type: Application
    Filed: September 19, 2002
    Publication date: August 14, 2003
    Inventors: Kotaro Yamashita, Koichi Tayama, Noriko Yoshioka, Yasuhisa Shibata
  • Patent number: 6602717
    Abstract: Apparatus for eliminating halide ions such as chloride ions from aqueous solutions having a hollow cylindrical sample holding chamber (2), the front end of which has an orifice (3) and in the vicinity of which is disposed a filter plate (4) that extends over the cross section of the sample holding chamber (2) and is liquid-permeable and essentially impermeable for solids and is inserted in a fixed manner into the hollow cylinder; a plunger (6) which can move to and fro in the sample holding chamber (2) and has a plunger stem (7) attached thereto engages in the open rear end (5) of the sample holding chamber, and, in the sample holding chamber (2) between the filter plate (4) and the plunger (6) is disposed a freely movable bed (7) of an adsorbent reacting with halide ions and forming a sparingly soluble compound, which bed fills a part of the sample holding chamber (2). The adsorbent is preferably charged with silver nitrate as compound reactive with halide ions.
    Type: Grant
    Filed: July 24, 2001
    Date of Patent: August 5, 2003
    Assignee: Macherey-Nagel GmbH & Co. KG
    Inventors: Edmund Radmacher, Markus John, Dirk Reinhardt, Klaus Möller
  • Patent number: 6599747
    Abstract: A test for determining the bioavailable fraction of an organic pollutant present in soil comprises determining the fraction of the organic pollutant present in the soil which may be extracted by a cyclodextrin or derivative thereof.
    Type: Grant
    Filed: June 22, 2000
    Date of Patent: July 29, 2003
    Assignee: University of Lancaster
    Inventors: Brian John Reid, Kirk Taylor Semple, Kevin Christopher Jones
  • Patent number: 6589796
    Abstract: A iodine-measuring method for determining or detecting iodine concentration in a specimen, comprising a specimen-pretreating step of thermally digesting a specimen together with an oxidizing agent, and a subsequent reaction-measuring step of reacting the resultant with an arsenious acid reagent solution and an ammonium cerium sulfate reagent solution and measuring absorbance in the reaction solution, characterized in that the specimen-pretreating step is performed by heating and cooling treatment under an airtight condition.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: July 8, 2003
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Toshinori Ohashi, Mituo Yamaki, Minoru Irie
  • Patent number: RE42192
    Abstract: Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.
    Type: Grant
    Filed: June 19, 2009
    Date of Patent: March 1, 2011
    Assignee: The University of Wyoming Research Corporation
    Inventors: John F. Schabron, Joseph F. Rovani, Jr., Theresa M. Bomstad, Susan S. Sorini-Wong, Gregory K. Wong