Hydrogen, Per Se Patents (Class 436/144)
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Patent number: 11626330Abstract: A film forming method includes: a first measurement process of measuring a substrate on which a pattern including recesses is formed using infrared spectroscopy; a film formation process of forming a film on the substrate after the first measurement process; a second measurement process of measuring the substrate using infrared spectroscopy after the film formation process; and an extraction process of extracting difference data between measurement data obtained in the first measurement process and measurement data obtained in the second measurement process.Type: GrantFiled: June 10, 2021Date of Patent: April 11, 2023Assignee: Tokyo Electron LimitedInventors: Yuji Otsuki, Munehito Kagaya, Yusuke Suzuki
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Patent number: 11624721Abstract: According to one embodiment, a hydrogen sensor is disclosed. The hydrogen sensor includes a capacitor, a gas detector, a heater, and a determiner. The capacitor includes a deformable member that deforms by absorbing or adsorbing hydrogen and varies a capacitance value corresponding to a deformation of the deformable member. The gas detector detects gas based on a capacitance value of the capacitor. The heater heats the deformable member. The determiner determines whether gas detected by the gas detector contains a substance other than hydrogen or not, wherein the gas detector detects the gas during a heating period during which the heater heats the deformable member.Type: GrantFiled: March 13, 2019Date of Patent: April 11, 2023Assignee: KABUSHIKI KAISHA TOSHIBAInventor: Hiroaki Yamazaki
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Patent number: 10036298Abstract: The invention is directed to a method for determining the state of aging of a catalytic converter (2). The disclosed method functions in a non-contacting manner as resonances formed when the catalytic converter (2) located in a housing is excited with high-frequency electromagnetic waves are analyzed.Type: GrantFiled: May 8, 2015Date of Patent: July 31, 2018Assignee: UMICORE AG & CO. KGInventors: Gregor Beulertz, Martin Votsmeier, Ralf Moos
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Patent number: 9803285Abstract: A method of electroless atomic layer deposition is described. The method electrolessly generates a layer of sacrificial material on a surface of a first material. The method adds doses of a solution of a second material to the substrate. The method performs a galvanic exchange reaction to oxidize away the layer of the sacrificial material and deposit a layer of the second material on the surface of the first material. The method can be repeated for a plurality of iterations in order to deposit a desired thickness of the second material on the surface of the first material.Type: GrantFiled: February 25, 2014Date of Patent: October 31, 2017Assignee: National Technology & Engineering Solutions of Sandia, LLCInventors: David Bruce Robinson, Patrick J. Cappillino, Leah B. Sheridan, John L. Stickney, David M. Benson
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Patent number: 9379301Abstract: A plurality of first cup-shaped members and a plurality of second cup-shaped members are placed alternately in repetition to form a pipe having an inner through-hole. At this point, neither the first cup-shaped members nor the second cup-shaped members are sintered yet. Then, the resultant pipe is sintered to obtain a pipe-shaped thermal power generation device. While the pipe is sintered, a pressure is applied to the pipe along a longitudinal direction of the pipe in a direction in which the pipe is compressed.Type: GrantFiled: November 27, 2013Date of Patent: June 28, 2016Assignee: Panasonic CorporationInventors: Akihiro Sakai, Tsutomu Kanno, Kohei Takahashi, Hiromasa Tamaki, Yuka Yamada
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Patent number: 8999723Abstract: A reliable, low cost device for determining when dangerous levels of hydrogen gas have been generated in a transformer is disclosed. The hydrogen indicator is defined by a module assembly that threads into either the headspace or into the oil-filled body of a transformer. The module has an open interior that contains a film that incorporates a hydrogen-sensitive chemochromic indicator. The indicator film is visible through a lens. When the film has been exposed to hydrogen, chemical changes in the chemochromic indicator cause the film to change color—the color change is immediately visible through the lens.Type: GrantFiled: April 16, 2014Date of Patent: April 7, 2015Assignee: Serveron CorporationInventor: Steven Mahoney
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Publication number: 20140364384Abstract: The present invention relates to the detection of markers in exhaled breath, wherein the detection of the presence or absence of the marker(s) in exhaled breath is used to assess various clinical data, including patient adherence in taking the medication and patient enzymatic (metabolic) competence in metabolizing the medication. An embodiment of the invention comprises a parent therapeutic agent labeled with a marker, where upon metabolism (e.g., via enzymatic action) of the therapeutic agent, the marker becomes volatile or semi-volatile and is present in the breath. In certain related embodiments, the marker contain a deuterium label, which is also present in the breath upon metabolism of the therapeutic agent. In another embodiment of the invention, the therapeutic agent is associated with a taggant (that may be either labeled or unlabeled with deuterium), which in turn will generate a marker in the breath that is easily measurable.Type: ApplicationFiled: April 23, 2014Publication date: December 11, 2014Applicant: University of Florida Research Foundation, Inc.Inventors: Richard J. Melker, Donn Michael Dennis, Christopher D. Batich, Mark S. Gold
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Publication number: 20140287514Abstract: The present invention includes a sensing device and method detecting the presence of a chemical analyte, comprising: a surface; a continuous or discontinuous terbium(III)-triphenylphosphine oxide coordination polymer layer deposited on the surface, wherein the polymer layer is porous; and a luminescence detector, wherein one or more analytes that interact with the polymer layer luminesce at distinct wavelengths unique to each analyte.Type: ApplicationFiled: March 17, 2014Publication date: September 25, 2014Inventors: Simon M. Humphrey, Bradley J. Holliday
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Publication number: 20140273262Abstract: Provided is a catalytic combustion typed gas sensor of detecting a combustible gas having a concentration equal to or more than a predetermined value based on a raised electric resistance. Herein, combustion heat generated when a combustible gas contacts to a catalytic metal (or detection element) heated by passing electric current therethrough raises a temperature and electric resistance of the catalytic metal. The electric current is made to pass through the catalytic metal such that the temperature of the catalytic metal becomes a standby temperature which is calculated by subtracting the raised temperature portion from a desorption temperature. The combustion heat is generated when the combustible gas contacts to the catalytic metal. Note the catalytic metal adsorbs a silicone compound via a silicon (Si) poisoning process and then desorbs the resulting adsorbed silicone compound at the desorption temperature. The desorption temperature is set in the range over 350° C. to 600° C.Type: ApplicationFiled: May 29, 2014Publication date: September 18, 2014Applicant: Honda Motor Co., Ltd.Inventors: Kazuhiro OKAJIMA, Hidetoshi OISHI, Shunji TSUKABAYASHI, Akihiro SUZUKI, Nobuaki MURAKAMI, Satoshi MORIMOTO, Hiroshi KODA, Takashi MATSUMOTO
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Publication number: 20140273261Abstract: A sensor assembly is disclosed for sensing a status condition of a liquid-filled electrical equipment such as a transformer. The sensor assembly can include a light source; a first hydrogen detection section, the first hydrogen detection section being optically coupled to the light source for receiving light from the light source, wherein the first hydrogen detection section has a first hydrogen sensitive layer that changes an optical response with respect to the received light depending on whether an amount of hydrogen at the first hydrogen sensitive layer is above or below a first threshold; and a first output section optically coupled to the first hydrogen detection section for receiving light having interacted with the first hydrogen sensitive layer such that the received light depends on the optical response of the first hydrogen sensitive layer.Type: ApplicationFiled: March 18, 2014Publication date: September 18, 2014Applicant: ABB RESEARCH LTDInventors: Barbara PANELLA, Jacobus Lodevicus Martinus Van Mechelen, Robin Gremaud, Pierre Lorin
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Patent number: 8778694Abstract: Provided herein are batch methods and devices for enriching trace quantities of impurities in gaseous mixtures, such as hydrogen fuel. The methods and devices rely on concentrating impurities using hydrogen transport membranes wherein the time period for concentrating the sample is calculated on the basis of optimized membrane characteristics, comprising its thickness and permeance, with optimization of temperature, and wherein the enrichment of trace impurities is proportional to the pressure ratio Phi/Plo and the volume ratio V1/V2, with following detection of the impurities using commonly-available detection methods.Type: GrantFiled: July 13, 2010Date of Patent: July 15, 2014Assignee: Uchicago Argonne, LLCInventors: Shabbir Ahmed, Sheldon H. D. Lee, Romesh Kumar, Dionissios D. Papadias
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Patent number: 8758691Abstract: A hydrogen sensor using a hydrogen-absorbing alloy containing an Mg—Ni-based alloy and a Zr—Ti-based alloy includes a substrate (2), a hydrogen reaction layer (3) formed on the substrate (2) and containing the Mg—Ni-based alloy and the Zr—Ti-based alloy, and a first catalyst layer (4) formed on the hydrogen reaction layer (3) and capable of accelerating hydrogenation of the Mg—Ni-based alloy.Type: GrantFiled: February 21, 2011Date of Patent: June 24, 2014Assignee: Kabushiki Kaisha AtsumitecInventors: Naoki Uchiyama, Tomomi Kanai, Kazumi Harada
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Publication number: 20140154811Abstract: Technologies are generally described for gas filtration and detection devices. Example devices may include a graphene membrane and a sensing device. The graphene membrane may be perforated with a plurality of discrete pores having a size-selective to enable one or more molecules to pass through the pores. A sensing device may be attached to a supporting permeable substrate and coupled with the graphene membrane. A fluid mixture including two or more molecules may be exposed to the graphene membrane. Molecules having a smaller diameter than the discrete pores may be directed through the graphene pores, and may be detected by the sensing device. Molecules having a larger size than the discrete pores may be prevented from crossing the graphene membrane. The sensing device may be configured to identify a presence of a selected molecule within the mixture without interference from contaminating factors.Type: ApplicationFiled: November 30, 2012Publication date: June 5, 2014Inventors: Angele Sjong, Kraig Anderson, Gary L. Duerksen, Seth Adrian Miller
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Patent number: 8734723Abstract: A gas sensor cell using a liquid crystal composite material is provided. The gas sensor cell has recovery capability and can be reused. Upon gas adsorption, the liquid crystal composite material has visually detectable color changes and changes in electrical properties to facilitate the measurement of gas concentration from low to high.Type: GrantFiled: August 30, 2013Date of Patent: May 27, 2014Assignee: Industrial Technology Research InstituteInventors: Chin-Kai Chang, Hui-Lung Kuo
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Patent number: 8691590Abstract: A hydrogen storage material analyzer along with its analysis and activation methods, the hydrogen storage material analyzer including a H2 absorption-desorption cycling tester, a temperature-programmed desorption spectrometer, a specimen holder and a temperature-controlled furnace.Type: GrantFiled: March 2, 2011Date of Patent: April 8, 2014Assignee: Yuan Ze UniversityInventors: Chia-Chieh Shen, Tsong-Pyng Perng, Hsueh-Chih Li
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Patent number: 8646310Abstract: A gas sensor includes a catalyst layer and a pipe-shaped thermoelectric power generation device. The pipe-shaped thermoelectric power generation device includes an internal through-hole along the axial direction of the pipe-shaped thermoelectric power generation device, a plurality of first cup-shaped components each made of metal, a plurality of second cup-shaped components each made of thermoelectric material, and first and second electrodes disposed at the ends of the pipe-shaped power generation device. The plurality of the first cup-shaped components and the plurality of the plurality of second cup-shaped components are arranged alternately and repeatedly along the axial direction. The catalyst layer is arranged on the internal surface of the internal through-hole. A method for detecting or measuring gas by using the gas sensor includes supplying a fluid containing the gas into the internal through-hole of the gas sensor, and detecting voltage between the first and second electrodes.Type: GrantFiled: January 10, 2012Date of Patent: February 11, 2014Assignee: Panasonic CorporationInventors: Kohei Takahashi, Tsutomu Kanno, Akihiro Sakai, Atsushi Omote, Yuka Yamada
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Patent number: 8623662Abstract: Methods, processes and compositions are provided for a visual or chemochromic hydrogen-detector with variable or tunable reversible color change. The working temperature range for the hydrogen detector is from minus 100° C. to plus 500° C. A hydrogen-sensitive pigment, including, but not limited to, oxides, hydroxides and polyoxo-compounds of tungsten, molybdenum, vanadium, chromium and combinations thereof, is combined with nano-sized metal activator particles and preferably, coated on a porous or woven substrate. In the presence of hydrogen, the composition rapidly changes its color from white or light-gray or light-tan to dark gray, navy-blue or black depending on the exposure time and hydrogen concentration in the medium. After hydrogen exposure ceases, the original color of the hydrogen-sensitive pigment is restored, and the visual hydrogen detector can be used repeatedly.Type: GrantFiled: September 14, 2012Date of Patent: January 7, 2014Assignee: University of Central Florida Research Foundation, Inc.Inventor: Nazim Z. Muradov
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Publication number: 20130210160Abstract: The invention relates to a device and to a method for the detection of hydrogen in a gas mixture, wherein the device comprises a catalyst unit which is connected to a source and a supply device for CO and/or CO2, respectively, or comprises these and wherein the catalyst unit is connected to a flame ionization detector by a feed line, such that the gas mixture, especially containing an inert carrier gas after passing through the catalyst unit is conducted to the FID. The FID is operated with hydrogen as fuel gas.Type: ApplicationFiled: April 26, 2011Publication date: August 15, 2013Applicant: Carl Von Ossietzky Universitaet OldenburgInventors: Frank Roessner, Stefan Schoenen
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Patent number: 8435448Abstract: An assembly and method for gas analysis. The assembly comprises a catalyst compartment for catalytically reacting a component of a gas sample, producing one or more gas species as products. A product compartment receives the gas species, and a sensing element within the compartment senses the amount of one or more of the gas species. This amount is compared to the amount of the same gas species present in a reference compartment containing a non-catalyzed gas sample, providing the amount of the gas species produced by catalysis. Using this value, the content of the gas component in the gas sample is calculated based upon the stoichiometry of the catalyzed reaction. In preferred embodiments, the gas for analysis is a process gas for fuel production, and the catalyst is a high temperature shift catalyst that catalyzes the reaction of carbon monoxide and water into hydrogen and carbon dioxide.Type: GrantFiled: April 8, 2010Date of Patent: May 7, 2013Assignee: The Regents of the University of CaliforniaInventors: Chan Seung Park, Colin E. Hackett, Joseph M. Norbeck
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Patent number: 8409869Abstract: A hydrogen sensor comprises a substrate having a surface coated with a hydrogen absorbing material and a temperature sensitive luminophore such that when the temperature sensitive luminophore is excited, it generates a fluorescent light, the luminescence of which is changed by an exothermic heat resulting from the adsorption of hydrogen through the hydrogen absorbing material. A hydrogen detecting system and a method of detecting hydrogen using the hydrogen sensor are also disclosed.Type: GrantFiled: March 30, 2011Date of Patent: April 2, 2013Assignee: National Tsing Hua UniversityInventors: Hirotaka Sakaue, Chih-Yung Huang
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Patent number: 8383412Abstract: Sensors and switches for detecting hydrogen include an electrically-insulating support; a first and second electrode; and a palladium structure alone or in combination with an organic insulating film. The palladium structures of the sensors are deposited on and contact a first electrode and a portion of the palladium structure extends to and contacts the second electrode to create a conductive path. The palladium structures of the switches are deposited on and contact a first electrode and a portion of the palladium structures extend to and contact an organic insulating film deposited on the second electrode. Upon exposure of the switch to hydrogen, portions of the palladium structure extend through the film and contact the second electrode to create a conductive path. Methods of detecting hydrogen and methods of fabricating a sensor for detecting an analyte of interest are also provided.Type: GrantFiled: October 30, 2009Date of Patent: February 26, 2013Assignee: University of Louisville Research Foundation, Inc.Inventors: Francis P. Zamborini, Radhika Dasari
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Publication number: 20130005045Abstract: A chemochromic sensor for detecting a combustible gas, such as hydrogen, includes a chemochromic pigment mechanically mixed with a polymer and molded into a rigid or pliable shape. In a preferred embodiment, the chemochromic detector is within the material which is molded into a manufactured part, said part becoming the detector itself. The detector is robust and easily modifiable for a variety of applications and environmental conditions, such as atmospheres of inert gas, hydrogen gas, or mixtures of gases, or in environments that have variable temperature, including high temperatures such as above 100° C. and low temperatures such as below ?196° C.Type: ApplicationFiled: September 12, 2012Publication date: January 3, 2013Applicants: SpaceInventors: Janine E. Captain, Luke B. Roberson, Martha K. Williams, Trent M. Smith, LaNetra Clayton Tate
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Publication number: 20120329168Abstract: A drug detection apparatus for identifying whether a gas sample contains an acidic gas includes a reactor having a gas inlet, a detection reagent containing an oxidant and a reductant, and a catalyst triggering a chemical adsorption with the oxidant and the reductant. A drug detection method applied to a drug detection apparatus is also disclosed. The drug detection apparatus and method can detect the acidic gases from drugs immediately, sensitively and selectively, thereby improving the efficiency of suspect inspection of drug smuggling in airports.Type: ApplicationFiled: June 15, 2012Publication date: December 27, 2012Inventors: Po-Tsang LIN, Shu-Liang LIAW
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Patent number: 8293178Abstract: A chemochromic sensor for detecting a combustible gas, such as hydrogen, includes a chemochromic pigment mechanically mixed with a polymer and formed into a rigid or pliable material. In a preferred embodiment, the chemochromic detector includes aerogel material. The detector is robust and easily modifiable for a variety of applications and environmental conditions, such as atmospheres of inert gas, hydrogen gas, or mixtures of gases, or in environments that have variable temperature, including high temperatures such as above 100° C. and low temperatures such as below ?196° C.Type: GrantFiled: November 6, 2007Date of Patent: October 23, 2012Assignee: The United States of America as Represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Luke B. Roberson, Janine E. Captain, Martha K. Williams, Trent M. Smith, LaNetra Clayton Tate
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Publication number: 20120225009Abstract: A hydrogen storage material analyzer along with its analysis and activation methods, the hydrogen storage material analyzer including a H2 absorption-desorption cycling tester, a temperature-programmed desorption spectrometer, a specimen holder and a temperature-controlled furnace. With this hydrogen storage material analyzer, a complete set of instruments can be used to implement simultaneously cyclic hydrogenation-dehydrogenation test and thermodynamic desorption analyses, thus improving the working efficiency and analysis accuracy.Type: ApplicationFiled: March 2, 2011Publication date: September 6, 2012Applicant: YUAN ZE UNIVERSITYInventors: Chia-Chieh Shen, Perng Tsong-Pyng, Hsueh-Chih Li
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Patent number: 8257978Abstract: Provided are novel technical means for obtaining useful knowledge in practical application of antioxidation action of dissolved hydrogen and in practical application of active oxygen scavenging action in water. Based on the temporal profile of the difference between the dissolved oxygen amount measured with forcibly dissolving hydrogen and the dissolved oxygen amount measured with blowing any other gas than hydrogen, the reaction between dissolved hydrogen and dissolved oxygen is quantitatively evaluated. Based on the temporal profile of the difference between the dissolved oxygen amount measured with making a photosensitizing dye contained in water and with forcibly dissolving hydrogen therein, and the dissolved oxygen amount measured without making a photosensitizing dye contained in water and with forcibly dissolving hydrogen therein, the reaction between dissolved hydrogen and dissolved oxygen is quantitatively evaluated.Type: GrantFiled: March 4, 2009Date of Patent: September 4, 2012Assignees: Eureka-Lab Inc., Seiji KatayamaInventors: Seiji Katayama, Yumiko Katayama
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Patent number: 8168438Abstract: The presently-disclosed subject matter provides sensors and methods for detecting hydrogen by determining the conductivity of a chemiresistant film upon exposure to hydrogen, including for example chemiresistant films comprised of alkylamine-, alkylthiolate-, and/or surfactant-coated metal alloy nanoparticles.Type: GrantFiled: July 26, 2008Date of Patent: May 1, 2012Assignee: University of Louisville Research Foundation, Inc.Inventors: Francis P. Zamborini, Francisco J. Ibanez
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Publication number: 20120045844Abstract: Methods and apparatus relating to very large scale FET arrays for analyte measurements. ChemFET (e.g., ISFET) arrays may be fabricated using conventional CMOS processing techniques based on improved FET pixel and array designs that increase measurement sensitivity and accuracy, and at the same time facilitate significantly small pixel sizes and dense arrays. Improved array control techniques provide for rapid data acquisition from large and dense arrays. Such arrays may be employed to detect a presence and/or concentration changes of various analyte types in a wide variety of chemical and/or biological processes. In one example, chemFET arrays facilitate DNA sequencing techniques based on monitoring changes in hydrogen ion concentration (pH), changes in other analyte concentration, and/or binding events associated with chemical processes relating to DNA synthesis.Type: ApplicationFiled: September 26, 2011Publication date: February 23, 2012Applicant: Life Technologies CorporationInventors: Jonathan ROTHBERG, Wolfgang Hinz, Kim Johnson, James Bustillo
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Publication number: 20120040469Abstract: A hydrogen sensor comprises a substrate having a surface coated with a hydrogen absorbing material and a temperature sensitive luminophore such that when the temperature sensitive luminophore is excited, it generates a fluorescent light, the luminescence of which is changed by an exothermic heat resulting from the adsorption of hydrogen through the hydrogen absorbing material. A hydrogen detecting system and a method of detecting hydrogen using the hydrogen sensor are also disclosed.Type: ApplicationFiled: March 30, 2011Publication date: February 16, 2012Inventors: Hirotaka Sakaue, Chih-Yung Huang
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Patent number: 8113035Abstract: Disclosed is a method for detecting hydrogen in steel. According to the method, hydrogen contained in steel is transferred into and preferably concentrated in at least one second material. Representative second materials include metals such as vanadium, niobium, tantalum, and their alloys. Upon transfer to the second material, the hydrogen is detected and preferably quantitatively determined. The data obtained with the method enables conclusions to be drawn about the presence of hydrogen in steel. Preferably, the concentration of hydrogen in steel is quantitatively determined from information obtained about the presence of hydrogen in the second material.Type: GrantFiled: April 25, 2007Date of Patent: February 14, 2012Inventors: Reiner Kirchheim, Peter-Joachim Wilbrandt, Jurgen Gegner
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Patent number: 8084265Abstract: Methods and Pd/V2O5 devices for hydrogen detection are disclosed. An exemplary method of preparing an improved sensor for chemochromic detection of hydrogen gas over a wide response range exhibits stability during repeated coloring/bleaching cycles upon exposure and removal of hydrogen gas. The method may include providing a substrate. The method may also include depositing a V205 layer that functions as a H2 insertion host in a Pd/V205 hydrogen sensor to be formed on said substrate. The method may also include depositing a Pd layer onto said V205 layer; said Pd layer functioning as an optical modulator.Type: GrantFiled: March 31, 2008Date of Patent: December 27, 2011Assignee: Alliance for Sustianable Energy, LLCInventors: Ping Liu, C. Edwin Tracy, J. Roland Pitts, R. Davis Smith, II, Se-Hee Lee
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Publication number: 20110300637Abstract: A method for sensing hydrogen includes the use of a transduction device with a sensing layer, and means for measuring a mass and/or conductivity change caused by an interaction of a gas with the sensing layer to provide a measure of an amount of hydrogen in the gas. The sensing layer includes polyaniline nanofiber material.Type: ApplicationFiled: August 2, 2011Publication date: December 8, 2011Inventors: Shabnam Virji, Richard B. Kaner, Bruce H. Weiller
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Patent number: 8071389Abstract: The invention relates to a method of controlling a hydrogenation of a starting material in a hydrogenation reactor, in which the amount of hydrogen reacted in the hydrogenation is firstly determined, the ratio of the amount of hydrogen reacted to the amount of starting material fed in is then derived, this ratio is compared with a prescribed value and, finally, at least one process parameter is altered if the ratio of the amount of hydrogen reacted to the amount of starting material fed in deviates by a prescribed amount from the prescribed value.Type: GrantFiled: January 30, 2006Date of Patent: December 6, 2011Assignee: BASF AktiengesellschaftInventors: Alexander Weck, Markus Rösch, Gunther Windecker, Gunnar Heydrich, Rolf Pinkos, Olga Schubert, Klaus Harth
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Publication number: 20110244585Abstract: A device is disclosed for detecting at least one chemical compound comprising at least one carbon nanotube with several graphene layers, on which is grafted at least one molecule bearing group G1 capable of reacting with the chemical compound or a precursor of such a group G1. The uses and the method of making such a device is also disclosed.Type: ApplicationFiled: September 28, 2009Publication date: October 6, 2011Applicant: Commissariat a l'energie atomique et aux energies alternativesInventors: Martine Mayne-L'Hermite, Serge Palacin, Pascale Chenevier, Jérôme Chancolon, Aurélien Gohier
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Patent number: 8025843Abstract: The present invention has a hydrogen detection portion composed of a semiconductor and a hydrogen absorber provided at least a part of a surface thereof, and pairs of electrodes provided at the semiconductor so as to sandwich the place at which the hydrogen absorber is provided and so as not to be electrically connected to each other with the hydrogen absorber, wherein the presence of hydrogen can be detected by the change in resistance of the semiconductor in response to hydrogen absorption into the hydrogen absorber, the change in resistance being measured between said pairs of electrodes.Type: GrantFiled: April 22, 2005Date of Patent: September 27, 2011Assignees: Alps Electric Co., Ltd., Honda Motor Co., Ltd.Inventors: Yasuichi Ono, Toshiaki Konno
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Patent number: 8025844Abstract: A hydrogen sensor includes a thin film layer formed on a top surface of a planar optical transmission medium, and a catalyst layer formed on a top surface of the thin film layer. A first interface is created between the planar optical transmission medium and the thin film layer. A substrate is joined to a bottom surface of the planar optical transmission medium so that a second interface is created between the planar optical transmission medium and the substrate. On entering a first end portion of the planer optical transmission medium, light from a light source is spread by an entrance section, and the spread light is transmitted inside the planar optical transmission medium to a second end portion by being reflected by the first and second interfaces alternately. Light exiting from the second end portion is transmitted to an optical sensor by an exit light-collecting section.Type: GrantFiled: July 10, 2007Date of Patent: September 27, 2011Assignees: Kabushiki Kaisha Atsumitec, National Institute of Advanced Industrial Science and TechnologyInventors: Naoki Uchiyama, Naoki Matsuda, Kazuki Yoshimura, Kenji Kato
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Patent number: 8003055Abstract: Methods, processes and compositions are provided for a visual or chemochromic hydrogen-detector with variable or tunable reversible color change. The working temperature range for the hydrogen detector is from minus 100° C. to plus 500° C. A hydrogen-sensitive pigment, including, but not limited to, oxides, hydroxides and polyoxo-compounds of tungsten, molybdenum, vanadium, chromium and combinations thereof, is combined with nano-sized metal activator particles and preferably, coated on a porous or woven substrate. In the presence of hydrogen, the composition rapidly changes its color from white or light-gray or light-tan to dark gray, navy-blue or black depending on the exposure time and hydrogen concentration in the medium. After hydrogen exposure ceases, the original color of the hydrogen-sensitive pigment is restored, and the visual hydrogen detector can be used repeatedly.Type: GrantFiled: February 27, 2008Date of Patent: August 23, 2011Assignee: University of Central Florida Research Foundation, Inc.Inventor: Nazim Muradov
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Publication number: 20110171066Abstract: A chemochromic sensor for detecting a combustible gas, such as hydrogen, includes a chemochromic pigment mechanically mixed with a polymer and formed into a rigid or pliable material. In a preferred embodiment, the chemochromic detector includes aerogel material. The detector is robust and easily modifiable for a variety of applications and environmental conditions, such as atmospheres of inert gas, hydrogen gas, or mixtures of gases, or in environments that have variable temperature, including high temperatures such as above 100° C. and low temperatures such as below ?196° C.Type: ApplicationFiled: November 6, 2007Publication date: July 14, 2011Applicants: Space AdministrationInventors: Janine E. Captain, Luke B. Roberson, Martha K. Williams, Trent M. Smith, LaNetra Clayton Tate
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Patent number: 7977638Abstract: The present invention relates to optical sensor arrangements, especially sensors of the type that can be used in motor vehicles and which can detect hydrogen in a gaseous measured medium.Type: GrantFiled: November 16, 2007Date of Patent: July 12, 2011Assignee: Bayerische Motoren Werke AktiengesellschaftInventors: Robert Frodl, Thomas Tille
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Patent number: 7910373Abstract: An ultra-fast response, high sensitivity structure for optical detection of low concentrations of hydrogen gas, comprising: a substrate; a water-doped WO3 layer coated on the substrate; and a palladium layer coated on the water-doped WO3 layer.Type: GrantFiled: May 5, 2001Date of Patent: March 22, 2011Assignee: Alliance for Sustainable Energy, LLCInventors: Ping Liu, C. Edwin Tracy, J. Roland Pitts, Se-Hee Lee
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Patent number: 7829344Abstract: The present invention relates to a device and a method for the detection of hydrogen in a gas volume by means of an exothermal catalytic recombination of hydrogen and oxygen present in the gas volume into water. The amount of energy that is released during such an exothermal catalytic recombination is measured in the form of a temperature difference and is compared with a stored limit value. When a corresponding limit value is exceeded an appropriate signal is output.Type: GrantFiled: May 23, 2008Date of Patent: November 9, 2010Assignee: Hoppecke Batterien GmbH & Co. KGInventors: Heinrich Kesper, Eduardo Cattaneo, Bernhard Riegel
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Publication number: 20100255598Abstract: The present invention relates to the detection of markers in exhaled breath, wherein the detection of the presence or absence of the marker(s) in exhaled breath is used to assess various clinical data, including patient adherence in taking the medication and patient enzymatic (metabolic) competence in metabolizing the medication. An embodiment of the invention comprises a parent therapeutic agent labeled with a marker, where upon metabolism (e.g., via enzymatic action) of the therapeutic agent, the marker becomes volatile or semi-volatile and is present in the breath. In certain related embodiments, the marker contain a deuterium label, which is also present in the breath upon metabolism of the therapeutic agent. In another embodiment of the invention, the therapeutic agent is associated with a taggant (that may be either labeled or unlabeled with deuterium), which in turn will generate a marker in the breath that is easily measurable.Type: ApplicationFiled: February 22, 2008Publication date: October 7, 2010Inventors: Richard J. Melker, Donn Michael Dennis, Christopher D. Batich, Mark S. Gold
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Publication number: 20100209507Abstract: Disclosed is a method of treating small intestinal bacterial overgrowth (SIBO) or a SIBO-caused condition in a human subject. SIBO-caused conditions include irritable bowel syndrome, fibromyalgia, chronic pelvic pain syndrome, chronic fatigue syndrome, depression, impaired mentation, impaired memory, halitosis, tinnitus, sugar craving, autism, attention deficit/hyperactivity disorder, drug sensitivity, an autoimmune disease, and Crohn's disease. Also disclosed are a method of screening for the abnormally likely presence of SIBO in a human subject and a method of detecting SIBO in a human subject. A method of determining the relative severity of SIBO or a SIBO-caused condition in a human subject, in whom small intestinal bacterial overgrowth (SIBO) has been detected, is also disclosed.Type: ApplicationFiled: April 27, 2010Publication date: August 19, 2010Applicant: CEDARS-SINAI MEDICAL CENTERInventors: Henry C. Lin, Mark Pimentel
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Patent number: 7754491Abstract: An assembly and method for gas analysis. The assembly comprises a catalyst compartment for catalytically reacting a component of a gas sample, producing one or more gas species as products. A product compartment receives the gas species, and a sensing element within the compartment senses the amount of one or more of the gas species. This amount is compared to the amount of the same gas species present in a reference compartment containing a non-catalyzed gas sample, providing the amount of the gas species produced by catalysis. Using this value, the content of the gas component in the gas sample is calculated based upon the stoichiometry of the catalyzed reaction. In preferred embodiments, the gas for analysis is a process gas for fuel production, and the catalyst is a high temperature shift catalyst that catalyzes the reaction of carbon monoxide and water into hydrogen and carbon dioxide.Type: GrantFiled: December 9, 2005Date of Patent: July 13, 2010Assignee: The Regents of the University of Calif.Inventors: Chan Seung Park, Colin E. Hackett, Nora A. Hackett, legal representative, Joseph M. Norbeck
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Patent number: 7687030Abstract: A hydrogen gas visualization device comprises a hydrogen sensor having a thin film layer formed on the surface of a substrate and a catalyst layer formed on the surface of the thin film layer which, when contacted by hydrogen gas contained in an atmosphere, hydrogenates the thin film layer and thereby changes the optical reflectance of the thin film layer, and one or more sensor faces provided with the hydrogen sensor. The hydrogen gas visualization device visualizes, on the sensor faces, the distribution of hydrogen gas contained in the atmosphere contacting the hydrogen sensor and thereby visualizes the existence and flow of the hydrogen gas.Type: GrantFiled: October 16, 2006Date of Patent: March 30, 2010Assignee: Kabushiki Kaisha ATSUMITECInventors: Naoki Uchiyama, Hiroyuki Matsumoto
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Patent number: 7682832Abstract: Gas flow is controlled to a feed gas consuming device depending on whether a contaminant gas is present. In one embodiment, hydrogen gas flow from a hydrogen gas generator to a hydrogen consuming device, such as a fuel cell, gas chromatograph or a flame ionization detector, is terminated when there is chemical contaminant breakthrough in the hydrogen gas flow. The apparatus relates to the use of a sensor for detecting a predetermined concentration of a chemical contaminant such as ammonia. In one embodiment the apparatus terminates the gas flow when a concentration of ammonia in the gas flow corresponds to a breakthrough (e.g., approximately in the range of 2.0% or greater). The apparatus prevents the ammonia-contaminated hydrogen from disabling such a hydrogen consuming device that would have otherwise received the contaminated gas flow.Type: GrantFiled: April 1, 2008Date of Patent: March 23, 2010Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Jeffrey A. Schmidt, Franklin Earl Lynch, John S. Wilkes
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Patent number: 7628959Abstract: A hydrogen gas sensor and/or switch fabricated from arrays nanowires composed of metal or metal alloys that have stable metal hydride phases. The sensor and/or switch response times make it quite suitable for measuring the concentration of hydrogen in a flowing gas stream. The sensor and/or switch preferably operates by measuring the resistance of several metal nanowires arrayed in parallel in the presence of hydrogen gas. The nanowires preferably comprise gaps or break junctions that can function as a switch that closes in the presence of hydrogen gas. Consequently, the conductivity of the nanowires of the sensor and/or switch increases in the presence of hydrogen.Type: GrantFiled: March 6, 2007Date of Patent: December 8, 2009Assignee: The Regents of the University of CaliforniaInventors: Reginald Mark Penner, Erich C. Walter, Fred Favier
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Publication number: 20090181105Abstract: The objective of the present invention is to provide an antioxidation method and antioxidant-functioning water that can anticipate high benchmarks of safety on the antioxidation subject such as the human body and reduced environmental burden. An antioxidation method and antioxidant-functioning water that can transform or maintain an antioxidation subject, which is in an oxidation state due to a deficiency of electrons or needs to be protected from oxidation, into a reduced state where electrons are filled by promoting the breaking reaction of molecular hydrogen used as a substrate included in the hydrogen-dissolved water into a product of active hydrogen through a process employing a catalyst, which is a precious metal colloid or a hydrogen oxidation/reduction enzyme (except for those already existing in a living organism), on the hydrogen-dissolved water.Type: ApplicationFiled: March 4, 2009Publication date: July 16, 2009Applicant: MIZ CO., LTD.Inventors: Tomoyuki YANAGIHARA, Bunpei Satoh, Tatsuya Shudo
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Patent number: 7537737Abstract: An installation structure for a gas sensor capable of detecting gas concentration in a highly accurate manner is provided. The installation structure for a gas sensor which detects concentration of gas circulating inside an outlet-side piping comprises a through hole 18 in an inner wall of the outlet-side piping and the gas sensor comprises a gas inlet portion with one face open within the outlet-side piping 14, and the gas sensor is installed to the outlet-side piping in a condition where the gas inlet portion does not protrude from the inner wall of outlet-side piping.Type: GrantFiled: March 28, 2003Date of Patent: May 26, 2009Assignee: Honda Motor Co., Ltd.Inventors: Hiroyuki Abe, Akihiro Suzuki, Takashi Sasaki
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Patent number: 7521252Abstract: Methods for forming hydrogen sensing materials include forming a palladium alloy thin film having less than about 83 atomic percent of palladium, and annealing the palladium alloy thin film to relieve residual stress and increase atomic intermixing of the nanorystaline lattice, while maintaining a grain size close to the grain size of the nonannealed palladium alloy thin film. For example, the sensing material may include a palladium-gold alloy thin film having about 60 atomic percent of palladium and about 40 atomic percent of gold. The palladium-gold alloy thin film is then annealed at a temperature of about 200 degrees Celsius for 1 hour. Methods for detecting hydrogen containing gas in which the hydrogen sensing material is maintained in a single phase when exposed to the hydrogen containing gas, and optical hydrogen sensors are also disclosed.Type: GrantFiled: February 3, 2005Date of Patent: April 21, 2009Assignee: The Research Foundation of State University of New YorkInventors: Michael A. Carpenter, Zhouying Zhao