In Situ Testing Patents (Class 436/28)
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Patent number: 12116889Abstract: The disclosure presents processes to determine a first formation fluid-second formation fluid boundary from one side of the boundary utilizing a formation tester tool. For example, the formation tester can be utilized in a borehole to determine an engagement point with a subterranean formation and determine one or more, or a combination of, injectable fluids to inject into the subterranean formation. Sensors coupled to the formation tester can measure the rebound pressure of the injected fluids. In some aspects, the fluid density of the collected fluid can be measured. The measured pressure changes and other collected data, can be utilized to determine a first formation fluid-second formation fluid boundary parameter. Other characteristic parameters can also be determined such as wettability parameters, porosity parameters, and capillary effects parameters. The formation tester can collect a core sample and an analyzation of the core sample can be utilized to determine the characteristic parameters.Type: GrantFiled: July 5, 2022Date of Patent: October 15, 2024Assignee: Halliburton Energy Services, Inc.Inventors: Christopher Michael Jones, Mehdi Ali Pour Kallehbasti, Anthony Herman VanZuilekom, Darren George Gascooke
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Patent number: 11939865Abstract: A method for the identification of operational problems in wells that produce by gas-lift, including allowing the hydrodynamic evaluation of the well/lines set by injection of at least one alcohol in the gas-lift line, collecting samples at the well sampling point, and detecting alcohol passage and return by direct analysis of information about process variables provided by the well instrumentation.Type: GrantFiled: December 14, 2020Date of Patent: March 26, 2024Assignee: Petróleo Brasileiro S.A.—PetrobrasInventors: Alcino Resende De Almeida, Andre Leal Gaio, Danielle Aguiar De Araujo, Maria Aparecida De Melo, Hercilio De Angeli Honorato, Cicero Pereira De Carvalho Neto
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Patent number: 11459883Abstract: During pulse power drilling, the formation rock type is determined by analyzing organic and inorganic chemical reaction products. Plasma pulses interact with the solid rock of the formation to shift downhole chemical reactions. The formation type may act as a catalyst or an inhibitor to enhance or degrade reactions. The concentration of organic and inorganic chemical reaction products is determined by analyzing the reactions occurring at the drill bit. From the concentrations, the formation rock type is determined.Type: GrantFiled: August 28, 2020Date of Patent: October 4, 2022Assignee: Halliburton Energy Services, Inc.Inventor: Mathew Dennis Rowe
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Patent number: 11346217Abstract: A method for drilling may comprise disposing a bottom hole assembly into a first wellbore. The bottom hole assembly may include a pulse power drilling assembly having one or more electrodes disposed on a drill bit and a pulse-generating circuit. The method may further include activating the one or more electrodes by applying an amperage, a voltage, and a cycle rate to the one or more electrodes to form an arc and a spark, adjusting the arc and the spark based at least in part on a hydrodynamic energy balance and a thermal energy balance, identifying one or more chemical reaction products created from an interaction of the arc and the spark with a formation, and adjusting the amperage, the voltage, and the cycle rate based on the chemical reaction products and storing the adjusted amperage, voltage, and cycle rate.Type: GrantFiled: August 31, 2020Date of Patent: May 31, 2022Assignee: Halliburton Energy Services, Inc.Inventor: Mathew Dennis Rowe
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Patent number: 10677046Abstract: Various examples are provided for gas leakage detection from geologic storage sites. In one example, a system for detection of gas leakage from a geologic storage site includes permanent down-hole gauges (PDGs) disposed at different depths within a well and an evaluation system that can determine a three-dimensional (3D) location of the gas leakage from the geologic storage site and a leakage indicator. The 3D location and leakage indicator can be determined using pressure data provided by the PDGs. The geologic storage site can store, e.g., CO2, natural gas or other type of gas. In another example, a method for detecting gas leakage from a geologic storage site includes receiving pressure data provided by PDGs disposed within one or more wells associated with the geologic storage site, determining key performance indicators using the pressure data and determining a 3D location and a leakage indicator using the key performance indicators.Type: GrantFiled: April 5, 2016Date of Patent: June 9, 2020Assignee: West Virginia UniversityInventors: Shahab D. Mohaghegh, Seyed Alireza Haghighat
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Patent number: 10379100Abstract: A method for determining the asphaltene content of oil includes obtaining an oil sample, determining an optical spectrum of the oil sample and removing asphaltenes from the oil sample by precipitating asphaltenes using a first alkane precipitant. The method also includes determining an optical spectrum of maltenes of the oil sample and subtracting the optical spectrum of the maltenes of the oil sample from the optical spectrum of the oil sample to yield an optical spectrum of asphaltenes of the oil sample. The method further includes using the optical spectrum of asphaltenes of the oil sample to determine asphaltene content of the oil sample using a second alkane precipitant.Type: GrantFiled: April 7, 2015Date of Patent: August 13, 2019Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Farshid Mostowfi, Vincent Joseph Sieben
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Patent number: 9151738Abstract: Solvent extraction to quantify contamination of a sample by a hydrocarbon contaminant is performed by providing a defined quantity of the sample, providing a defined quantity of a siloxane solvent, mixing the defined quantity of the siloxane solvent and the defined quantity of the sample to extract the hydrocarbon contaminant from the sample to form a contaminant solution with the siloxane solvent, and separating the contaminant solution from the sample. A concentration of the hydrocarbon contaminant in the contaminant solution can be measured by vibrational spectroscopy. Siloxane solvents are CFC free, VOC exempt, odorless, colorless, low to moderately flammable, non-toxic, and safe for incidental skin contact. Some are even used in cosmetic products.Type: GrantFiled: May 21, 2013Date of Patent: October 6, 2015Assignee: Agilent Technologies, Inc.Inventors: Franklin Scott Higgins, John Arthur Seelenbinder
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Publication number: 20150087072Abstract: A soil analysis apparatus includes at least one sensor element for measuring a property of the soil; a blade assembly having at least one blade and being displaceable between a raised position and an excavation position, the at least one blade being operable to excavate the soil at a test location when the blade assembly is in the excavation position, the blade assembly being further operable to enter a sensor permitting configuration; and a first actuator operable to displace the at least one sensor element between an initial position and a sensing position along a sensor displacement path, the sensor element being proximate the soil at the test location when in the sensing position.Type: ApplicationFiled: September 24, 2014Publication date: March 26, 2015Applicant: The Royal Institution for the Advancement of Learning/McGill UniversityInventors: Viacheslav Adamchuk, Nandkishor Dhawale, Frédéric René-Laforest, Shiv Prasher, Antoine Pouliot
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Patent number: 8912000Abstract: Methods and apparatus for obtaining a mass spectrum of a sample and determining a concentration of a component of the sample by utilizing a model of chemical and electron ionization and the obtained mass spectrum.Type: GrantFiled: July 17, 2009Date of Patent: December 16, 2014Assignee: Schlumberger Technology CorporationInventors: Pierre J. Daniel, Julian J. Pop, Reza Taherian, Bruno Drochon
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Patent number: 8883508Abstract: In some embodiments, apparatus and systems, as well as methods, may operate to draw a formation fluid sample into a sampling port included in a down hole tool, to vaporize some part of the fluid sample to substantially fill an injection port with a gas phase, to differentiate gas components in the gas phase to provide differentiated gas components along a concentration gradient, to detect the differentiated gas components, and to determine a fingerprint of the differentiated gas components. Other apparatus, systems, and methods are disclosed.Type: GrantFiled: July 9, 2013Date of Patent: November 11, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Christopher M. Jones, Michael T. Pelletier
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Publication number: 20140249053Abstract: Methods of identifying geological materials of interest comprising (i) providing a nanoprobe composition comprising one or more nanoprobes; wherein the nanoprobe includes (a) at least one tag; and (b) at least one signal generator; (ii) introducing the nanoprobes to a geological material; and (iii) detecting the presence of a signal generated by the signal generator on association of the tag with a target. Nanoprobe compositions identify geological materials, systems include such nanoprobe compositions, and methods use such nanoprobe compositions for the evaluation of geological materials.Type: ApplicationFiled: July 5, 2012Publication date: September 4, 2014Inventors: Amelia C. Robinson, Robert J. Pottorf, Daniel S. Jones, Sebastien L. Dreyfus
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Patent number: 8825408Abstract: Methods and systems to characterize a fluid in a reservoir to determine if the fluid is in one of equilibrium or non-equilibrium in terms of one of gravity, solvency power, entropy effect or some combination thereof. The method includes acquiring tool data at each depth for each fluid sample of at least two fluid samples wherein each fluid sample is at a different depth and communicating the tool data to a processor. Determining formation properties of each fluid sample to obtain formation property data and determining fluid properties for each fluid sample to obtain fluid property data. Selecting a mathematical model based on one of gravity, solvency power or entropy, in view of a fluid property, using one of tool data, formation property data, fluid property data, known fluid reservoir data or some combination thereof, to predict if the fluid is in an equilibrium distribution or a non-equilibrium distribution.Type: GrantFiled: June 12, 2009Date of Patent: September 2, 2014Assignee: Schlumberger Technology CorporationInventors: Denise E Freed, Kentaro Indo, Oliver C Mullins, John Ratulowski, Julian Zuo
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Patent number: 8691582Abstract: A method for in situ monitoring within a specified environment. The method includes locating a housing in a well, wherein a set of pumps and a plurality of test beds are inserted. Each of the set of pumps are controlled by signals from the control system to push water from each pump into one of the plurality of separate test beds where, after flowing through each of the test beds, effluent flows into an effluent storage device.Type: GrantFiled: November 19, 2012Date of Patent: April 8, 2014Assignee: Arizona Board of RegentsInventor: Rolf U. Halden
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Publication number: 20140024073Abstract: A method and apparatus for observing a biological microelectromechanical systems response to a fluid including combining an activator and a fluid wherein the fluid comprises a component from a subterranean formation, exposing the combined activator and fluid to a sensor in a wellbore to observe a biological microelectromechanical systems response, and integrating data from the observing with petrophysical data. A method and apparatus for observing a biological microelectromechanical systems response to a fluid including a housing comprising a biological microelectromechanical observation material, a signal analyzer in communication with the material, and a fluid preparation device positioned to allow fluid to flow to the surface, wherein the fluid comprises a component from a subterranean formation.Type: ApplicationFiled: July 19, 2012Publication date: January 23, 2014Applicant: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: OLEG ZHDANEEV, BRADLEY KAANTA, HUA CHEN
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Publication number: 20130295677Abstract: In some embodiments, apparatus and systems, as well as methods, may operate to draw a formation fluid sample into a sampling port included in a down hole tool, to vaporize some part of the fluid sample to substantially fill an injection port with a gas phase, to differentiate gas components in the gas phase to provide differentiated gas components along a concentration gradient, to detect the differentiated gas components, and to determine a fingerprint of the differentiated gas components. Other apparatus, systems, and methods are disclosed.Type: ApplicationFiled: July 9, 2013Publication date: November 7, 2013Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Christopher M. Jones, Michael T. Pelletier
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Patent number: 8492162Abstract: An electronic system for tracking and monitoring articles to be subjected to a sterilization cycle is disclosed. The method uses a sterilization indicator and electronically links sterilization information with the articles subjected to the sterilization process. The indicator allows a sterilization cycle to be monitored without the need for a user to subjectively distinguish between color, quality or intensity of display patterns.Type: GrantFiled: February 19, 2010Date of Patent: July 23, 2013Assignee: 3M Innovative Properties CompanyInventors: Roland C. Kippenhan, Steven S. Kirckof, Philip A. Bolea, Richard M. Rumble, Rodney K. Hehenberger, Ramon T. Ignacio
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Patent number: 8492152Abstract: Apparatus and systems, as well as methods, may operate to draw a formation fluid sample into a sampling port included in a down hole tool or tool body, to vaporize some part of the fluid sample to substantially fill an injection port with a gas phase, to differentiate gas components in the gas phase to provide differentiated gas components along a concentration gradient in a receiving section, to detect the differentiated gas components with a detector, and to determine a fingerprint of the differentiated gas components. A reaction section and a vacuum section may be used for waste consumption and/or absorption.Type: GrantFiled: January 10, 2013Date of Patent: July 23, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Christopher M. Jones, Michael T. Pelletier
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Patent number: 8444937Abstract: A method and apparatus for near real-time in-situ soil solution measurements is presented. An outer sleeve is placed in soil where ionic concentrations of organic or inorganic species are to be measured. A porous section connects with the outer sleeve (the porous section initially loaded with distilled water) equilibrates with the solution present in soil pores to form a solution to be measured. The initial distilled water is displaced within the porous section by a removable plunger. After substantial equilibration of the solution to be measured within the apparatus, the plunger is removed and a removable probe replaced. The probe may be an Ion Selective Electrode, or a transflection dip probe. The probe then may be used under computer control for measurement of solution properties. The Ion Selective Electrode may measure nitrate (NO3?) concentrations. The transflection dip probe may be read with spectrometer with an input deuterium light source.Type: GrantFiled: March 28, 2011Date of Patent: May 21, 2013Assignee: The Regents of the University of CaliforniaInventors: Atac Tuli, Jan W. Hopmans, Tamir Kamai, Benjamin D. Shaw
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Patent number: 8426211Abstract: The present invention relates to a method of detecting soil nutrients or soil nutrients in soil from reflected light, and also includes systems for the measurement, calculation and transmission of data relating to or carrying out that method.Type: GrantFiled: February 8, 2010Date of Patent: April 23, 2013Assignee: Bowling Green State UniversityInventors: B. B. Maruthi Sridhar, Robert K. Vincent
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Publication number: 20130095517Abstract: A method for in situ monitoring within a specified environment. The method includes locating a housing in a well, wherein a set of pumps and a plurality of test beds are inserted. Each of the set of pumps are controlled by signals from the control system to push water from each pump into one of the plurality of separate test beds where, after flowing through each of the test beds, effluent flows into an effluent storage device.Type: ApplicationFiled: November 19, 2012Publication date: April 18, 2013Applicant: Arizona Board of Regents Acting for and on Behalf of Arizona State UniversityInventor: Rolf U. Halden
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Publication number: 20130071934Abstract: A method and system that characterizes hydrogen sulfide in petroleum fluid employs a tool that includes a fluid analyzer for performing fluid analysis (including optical density (OD) for measuring carbon dioxide concentration) of a live oil sample, and a storage chamber for an analytical reagent fluidly coupled to a measurement chamber. An emulsion from fluid of the sample and the reagent is produced into the measurement chamber. The reagent changes color due to pH changes arising from chemical reactions between components of the sample and the reagent in the measurement chamber. The tool includes an optical sensor system that measures OD of a water phase of the emulsion at one or more determined wavelengths. The pH of the water phase is derived from such OD measurements. The pH of the water phase and the carbon dioxide concentration in the sample is used to calculate hydrogen sulfide concentration in the sample.Type: ApplicationFiled: September 16, 2011Publication date: March 21, 2013Inventors: Kentaro Indo, Michael M. Toribio, Shu Pan
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Patent number: 8388435Abstract: A method of playing a wagering game comprises receiving a wager, and generating a randomly selected first outcome of a first wagering game, the first outcome comprising a first plurality of symbols arranged in a first matrix. The method further comprises generating a randomly selected second outcome of a second wagering game, the second outcome comprising a second plurality of symbols arranged in a second matrix, and simultaneously displaying the first outcome and the second outcome on at least one display. The method further comprises detecting an occurrence of a triggering event, in response to the triggering event, copying a first special symbol occurring in the first outcome into the second outcome to yield a modified second outcome, and evaluating the first outcome and the modified second outcome for winning combinations of symbols.Type: GrantFiled: May 28, 2009Date of Patent: March 5, 2013Assignee: WMS Gaming Inc.Inventors: Peter R. Anderson, Allon G. Englman, Benjamin T. Gomez, Joel R. Jaffe, Daniel P. Louie
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Patent number: 8367413Abstract: Apparatus and systems, as well as methods, may operate to draw a formation fluid sample into a sampling port included in a down hole tool or tool body, to vaporize some part of the fluid sample to substantially fill an injection port with a gas phase, to differentiate gas components in the gas phase to provide differentiated gas components along a concentration gradient in a receiving section, to detect the differentiated gas components with a detector, and to determine a fingerprint of the differentiated gas components. The receiving section may comprise a diffusion section. A reaction section and a vacuum section may be used for waste consumption and/or absorption.Type: GrantFiled: December 16, 2008Date of Patent: February 5, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Christopher M. Jones, Michael T. Pelletier
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Patent number: 8367353Abstract: The present invention relates to a method for improved diagnosis of dysplasias based on simultaneous detection of INK4a gene products and at least one marker for cell proliferation. Particularly the present invention provides a method for discriminating dysplastic cells over-expressing INK4a gene products from cells over-expressing INK4a gene products without being dysplastic by detection of a marker suitable for characterizing the proliferation properties of the respective cell. The characterization of the proliferation properties may comprise the detection of a marker or a set of markers characteristic for active cell proliferation and/or a marker or a set of markers characteristic for retarded or ceased cell proliferation. The method presented herein thus enables for a specific diagnosis of dysplasias in histological and cytological specimens.Type: GrantFiled: March 6, 2009Date of Patent: February 5, 2013Assignee: Roche MTM Laboratories AGInventors: Ruediger Ridder, Anja Reichert, Marcus Trunk-Gehmacher, Richard Batrla
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Patent number: 8367420Abstract: The present invention relates to a method of detecting soil nutrients or soil nutrients in soil from reflected light, and also includes systems for the measurement, calculation and transmission of data relating to or carrying out that method.Type: GrantFiled: February 8, 2010Date of Patent: February 5, 2013Assignee: Bowling Green State UniversityInventors: B. B. Maruthi Sridhar, Robert K. Vincent
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Patent number: 8338182Abstract: A system for in situ monitoring within a specified environment includes a housing with an intake inserted into the environment. A plurality of pumps are included in the housing with a number of test beds, each being separately coupled to one of the number of pumps, where each of the number of test beds holds material and where each of the plurality of pumps operate to separately push fluid through a coupled test bed. An effluent storage device is disposed to receive effluent from the number of test beds.Type: GrantFiled: February 8, 2010Date of Patent: December 25, 2012Assignee: Arizona Board of Regents, a Body Corporate Acting for and on Behalf of Arizona State UniversityInventor: Rolf Ulrich Halden
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Patent number: 8283174Abstract: A formation fluid sampling tool is provided with reactants which are carried downhole and which are combined in order to generate heat energy which is applied to the formation adjacent the borehole. By applying heat energy to the formation, the formation fluids are heated, thereby increasing mobility, and fluid sampling is expedited.Type: GrantFiled: January 7, 2011Date of Patent: October 9, 2012Assignee: Schlumberger Technology CorporationInventors: Ronald E. G. Van Hal, Anthony Goodwin, Oliver C. Mullins, Peter S. Hegeman, Bhavani Raghuraman, Soraya S. Betancourt, Cosan Ayan, Ricardo Vasques, Francois Xavier Dubost, Christopher Scott Del Campo
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Patent number: 8206993Abstract: The diffusion coefficients and relaxation times of mixtures of alkanes follow simple scaling laws based on the chain length of the constituents and the mean chain length of the mixture. These scaling laws are used to determine chain sizes in a mixture from the distribution of the diffusion coefficients. These scaling laws can be used to determine the mean chain lengths (or chain lengths) of a sample (alkanes or mixtures of alkanes) and therefore the constituents of the sample.Type: GrantFiled: March 29, 2010Date of Patent: June 26, 2012Assignee: Schlumberger Technology CorporationInventor: Denise Freed
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Patent number: 8206985Abstract: A method of determining the effect of a spill on a marine environment, in which physical and chemical sensors are arranged with living organisms (4, 6) fitted with instruments, at an appropriate distance and position from the object (1) which is to be monitored, wherein the response of the living organism (4, 6), measured online in real time, is compared with known patterns of response, and where upstream and downstream measurements are compared to determine whether a change in response may be caused by a spill from the object, the significance of the real time measurements being validated through sampling of the organisms on a regular basis or as required, in order to analyze the effects on the health of the organisms, biomarkers, for the purpose of assessing the significance of the environmental effect.Type: GrantFiled: January 23, 2007Date of Patent: June 26, 2012Assignee: Biota Guard ASInventors: Odd Kjetil Andersen, Steinar Sanni
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Publication number: 20120149117Abstract: Methods and related apparatuses and mixtures are described for spectroscopic detection of hydrogen sulfide in a fluid, for example a formation fluid downhole. A reagent mixture is combined with the fluid. The reagent mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and a capping agent that limits growth of the insoluble metal sulfide species by electrosteric or steric stabilization. The particle growth is one of chemical reaction or significant aggregation, and the capping agent further functionalizes the reagent mixture to exhibit properties outside the natural characteristics of the metal sulfide species to allow for spectroscopic detection of the metal sulfide species. The combined mixture and fluid is then spectroscopically interrogated to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.Type: ApplicationFiled: December 13, 2010Publication date: June 14, 2012Applicant: Schlumberger Technology CorporationInventors: Jimmy Lawrence, Ronald van Hal, Jane Lam
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Patent number: 8093056Abstract: A method and apparatus to determine the fractional amount of at least one constituent of a hydrocarbon mixture, comprising dissolving the hydrocarbon mixture in a substantially hydrogen free solvent to produce a diluted solution, the diluted solution having sufficient solvent to render a NMR property of the diluted solution to be predictably related to the constituent concentrations of the hydrocarbon mixture; making NMR measurements on the diluted solution; and determining the fractional amount of at least one constituent of the hydrocarbon mixture from the NMR measurements.Type: GrantFiled: June 29, 2007Date of Patent: January 10, 2012Assignee: Schlumberger Technology CorporationInventor: Krishnamurthy Ganesan
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Patent number: 8058071Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.Type: GrantFiled: January 19, 2011Date of Patent: November 15, 2011Assignee: Schlumberger Technology CorporationInventors: Li Jiang, Oliver C. Mullins, Gale H. Gustavson, Christopher Harrison, Bhavani Raghuraman, Ronald E. G. Van Hal, Jimmy Lawrence, Kosta Ladavac, Albert Ballard Andrews, Timothy Gareth John Jones, Rogerio Tadeu Ramos
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Publication number: 20110195445Abstract: A system for in situ monitoring within a specified environment includes a housing with an intake inserted into the environment. A plurality of pumps are included in the housing with a number of test beds, each being separately coupled to one of the number of pumps, where each of the number of test beds holds material and where each of the plurality of pumps operate to separately push fluid through a coupled test bed. An effluent storage device is disposed to receive effluent from the number of test beds.Type: ApplicationFiled: February 8, 2010Publication date: August 11, 2011Inventor: Rolf U. Halden
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Patent number: 7947503Abstract: A dust monitor is disclosed that is suitably deployed in dusty environments and capable of providing near real-time indications of exposure to airborne particulates. The monitor includes a filter and filter assembly made of materials that do not interfere with subsequent instrumental (such as spectrometric) analysis for detecting and/or quantitating an analyte. In some disclosed embodiments, the filter is made of nylon or other material that is readily subjected to thermal destruction prior to spectrometric analysis. The dust monitor also includes a humidity correction feature that permits the filter to be made of ashable organic materials even if those materials are not highly hydrophobic. Transport devices are provided for shipment of the filter and/or filter assembly to an analytical laboratory which prevent loss of particulate matter and which facilitate an accurate analysis procedure.Type: GrantFiled: June 14, 2006Date of Patent: May 24, 2011Assignee: The United States of America as represented by the Department of Health and Human ServicesInventor: Donald P. Tuchman
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Patent number: 7927883Abstract: A method and apparatus for near real-time in-situ soil solution measurements is presented. An outer sleeve is placed in soil where ionic concentrations of organic or inorganic species are to be measured. A porous section connects with the outer sleeve (the porous section initially loaded with distilled water) equilibrates with the solution present in soil pores to form a solution to be measured. The initial distilled water is displaced within the porous section by a removable plunger. After substantial equilibration of the solution to be measured within the apparatus, the plunger is removed and a removable probe replaced. The probe may be an Ion Selective Electrode, or a transflection dip probe. The probe then may be used under computer control for measurement of solution properties. The Ion Selective Electrode may measure nitrate (NO3?) concentrations. The transflection dip probe may be read with spectrometer with an input deuterium light source.Type: GrantFiled: November 10, 2008Date of Patent: April 19, 2011Assignee: The Regents of the University of CaliforniaInventors: Atac Tuli, Jan W. Hopmans, Tamir Kamai, Benjamin D. Shaw
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Patent number: 7875455Abstract: A method and system for evaluating status and response of a mineral-producing field (e.g., oil and/or gas) by monitoring selected chemical and physical properties in or adjacent to a wellsite headspace. Nanotechnology sensors and other sensors are provided for one or more underground (fluid) mineral-producing wellsites to determine presence/absence of each of two or more target molecules in the fluid, relative humidity, temperature and/or fluid pressure adjacent to the wellsite and flow direction and flow velocity for the fluid. A nanosensor measures an electrical parameter value and estimates a corresponding environmental parameter value, such as water content or hydrocarbon content. The system is small enough to be located down-hole in each mineral-producing horizon for the wellsite.Type: GrantFiled: July 12, 2006Date of Patent: January 25, 2011Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration (NASA)Inventors: Jing Li, Meyya Meyyappan
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Publication number: 20100255587Abstract: This invention relates to methods and apparatus for determination of ion concentrations, particularly in downhole water from hydrocarbon wells, aquifers etc. It is useful in a wide range of applications, including predicting the formation of scale and fingerprinting waters from different sources. More particularly, the invention relates to the use of ligands whose electronic configuration is altered by the binding of the scaling ions within a water sample. These alterations are detected electrochemically by applying varying potential to electrodes and measuring current flow as potential is varied, from which is derived the concentration of scaling ions in the fluid.Type: ApplicationFiled: June 22, 2010Publication date: October 7, 2010Applicant: Schlumberger Technology CorporationInventors: Li Jiang, Timothy Gareth John Jones, Andrew Meredith, Markus Pagels, Amilra Prasanna De Silva
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Patent number: 7674624Abstract: A preferred method for determining the flow fraction of a mixture of water, gas and oil in a hydrocarbon reservoir includes measuring pressure and density of the mixture over time, determining a function which approximates a relationship between the density and pressure measurements, calculating a derivative of the function over time, and determining flow fraction based, in part, on the derivative. Preferably, transient data points are eliminated and the remaining set of data points are weight averaged to improve signal to noise ratio. Bubble point pressure, bubble point density and molecular weight and density of the liquid portion of the mixture are also used in the determination.Type: GrantFiled: June 4, 2003Date of Patent: March 9, 2010Assignee: Schlumberger Technology CorporationInventors: Kenneth E. Stephenson, Lalitha Venkataramanan
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Patent number: 7659123Abstract: In general, the purpose of the probe system is to provide improved rapid field methods using re-designed direct push technology (DPT) and “push-pull testing” concepts to evaluate in situ chemical, biochemical, surfactant, adsorptive media, and leaching and fixation remediation technologies for hazardous subsurface contaminant(s). The probe system and methods described here when applied to a hazardous waste site being considered for in situ remediation of contaminants (organic or inorganic) by the listed treatment technologies will yield information that greatly reduces the uncertainty with regards to treatment effectiveness for the in situ soil, groundwater, and contaminant(s) conditions affecting dosage requirements and reaction rate(s) for various reactants.Type: GrantFiled: August 31, 2004Date of Patent: February 9, 2010Assignee: EnChem Engineering, Inc.Inventor: Raymond G. Ball
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Patent number: 7594971Abstract: A novel method of cleaning and disinfecting organically contaminated articles such as, for instance, medical instruments, wherein the cleaning cycle consists of two sections divided by removal and replenishing the cleaning liquid, in each section of which the temperature of the cleaning liquid is raised to and maintained at between 40° C. and 60° C. for a predetermined time and the pH-value is raised to between 8.5 and 12 by adding an alkaline cleaning agent. During the second section a low-molecular peroxide compound is added to the cleaning liquid after the cleaning agent.Type: GrantFiled: November 19, 2004Date of Patent: September 29, 2009Assignee: Miele & Cie KGInventors: Winfried Michels, Michael Pieper
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Patent number: 7588943Abstract: A method for quantitative monitoring of a gas injected into a reservoir and likely to react chemically with the injection medium includes injecting into a reservoir a mixture of the potentially reactive gas to be quantified with a low proportion of a tracer gas whose chemical inertness is total, and in determining the variation with time of the initial proportion of reactive gas that may have disappeared through conversion, by measuring the concentration variation of the tracer gas in the mixture. The tracer gas is preferably selected from the rare gas family and from isotopes thereof, unlikely to be contaminated by contact of the mixture with the injection medium, and which have physical properties such as solubility in water or diffusion coefficients as close as possible to the gas injected. The method is applicable to monitoring of the evolution and conversion of a reactive gas such as carbon dioxide or methane, injected into an underground reservoir for example.Type: GrantFiled: July 24, 2002Date of Patent: September 15, 2009Assignee: Institut Francais du PetroleInventors: Alain Prinzhofer, Alexandre Rojey
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Publication number: 20090004748Abstract: A method and apparatus to determine the fractional amount of at least one constituent of a hydrocarbon mixture, comprising dissolving the hydrocarbon mixture in a substantially hydrogen free solvent to produce a diluted solution, the diluted solution having sufficient solvent to render a NMR property of the diluted solution to be predictably related to the constituent concentrations of the hydrocarbon mixture; making NMR measurements on the diluted solution; and determining the fractional amount of at least one constituent of the hydrocarbon mixture from the NMR measurements.Type: ApplicationFiled: June 29, 2007Publication date: January 1, 2009Applicant: SCHLUMBERGER TECHNOLOGY CORPORATIONInventor: Krishnamurthy Ganesan
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Patent number: 7445934Abstract: A method and apparatus is described for estimating terminal purity or terminal contamination for a fluid during the withdrawal of the fluid from a subsurface formation. The apparatus and method provide for measuring refractive index of the fluid over a time period, fitting a curve through the refractive index measurements or data values derived therefrom and estimating a terminal refractive index or terminal value for the data values from the fitted to curve to estimate the terminal contamination or purity for the fluid.Type: GrantFiled: April 4, 2007Date of Patent: November 4, 2008Assignee: Baker Hughes IncorporatedInventors: Rocco DiFoggio, Angus Simpson
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Patent number: 7427504Abstract: A method for analyzing formation fluid in earth formation surrounding a borehole includes storing analytical reagent in a reagent container in a fluids analyzer in a formation tester and moving the formation tester, including the reagent, downhole. Reagent from the reagent container is injected into formation fluid in the flow-line to make a mixture of formation fluid and reagent. The mixture is moved through a spectral analyzer cell in the fluids analyzer to produce a time-series of optical density measurements at a plurality of wavelengths. A characteristic of formation fluid is determined by spectral analysis of the time-series of optical density measurements.Type: GrantFiled: September 22, 2003Date of Patent: September 23, 2008Assignee: Schlumber Technology CorporationInventors: Torleif Torgersen, Bhavani Raghuraman, Edward Harrigan, Oliver C. Mullins, Gale Gustavson, Philip Rabbito, Ricardo Reves Vasques
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Patent number: 7393689Abstract: The present invention provides a method and apparatus or system for determining an amount of coal tar that can enter, and subsequently be displaced from, a given type of soil for a range of depths of the soil. The method and apparatus also provide verification of the pressure at which coal tar can be displaced from a given type of soil. In particular, the method and apparatus simulate the hydrostatic pressure that a soil sample encounters in the subsurface of the ground. Accordingly, the method and apparatus provide a relationship between the concentration of coal tar in the soil and the pressure required to displace the coal tar from the soil, which allows for an estimation of the amount of coal tar that may be displaced at a particular location or site. Further, the method and apparatus are adaptable for use in the laboratory or the field.Type: GrantFiled: January 27, 2004Date of Patent: July 1, 2008Assignee: Lehigh UniversityInventors: Horace Keith Moo-Young, Derick Gerdts Brown, Andrew J. Coleman
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Patent number: 7223602Abstract: The invention provides a method of online and on-site tracer generation for tagging natural gas stored in underground storage fields wherein feedstock is drawn from a feedstock source. The feedstock undergoes initial analysis to determine hydrocarbon levels. The feedstock then undergoes reaction to produce tracers such as ethylene, propylene, acetylene hydrogen and carbon monoxide. The feedstock is then analyzed to determine post reaction tracer concentration. The feedstock including generated tracers is then introduced back into the feedstock stream. Tracer levels in the pre-reaction or initial analysis of feedstock are compared with tracer levels in the post-reaction feedstock and the rate of flow of feedstock through the system is adjusted to achieve a predetermined level of tracer concentration. The level of tracer concentration will then be used to identify the particular natural gas charge in a storage field.Type: GrantFiled: September 4, 2002Date of Patent: May 29, 2007Inventors: Dennis D. Coleman, Rodney R. Ruch, Shiaoguo Chen, Massoud Rostam-Abadi
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Patent number: 7221448Abstract: The invention relates to a sample cell with a glass body comprising a gas inlet and a gas outlet and at least one orifice, a plane glass window is fused into the orifice, the shape and size of the window corresponds to the shape and size of the orifice, the orifice is limited by a rim, the rim is wider than the thickness of the window, the rim of the window is fused with the rim of the orifice. The invention further relates to a method of producing the sample cell. The window is inserted into the orifice. The rim of the orifice is heated several times from the exterior in such a way that the glass melts and a fused joint is formed between the window and the rim of the orifice. The sample cell produced by the method has a particularly rigid joint between the window and the glass body. Therefore, this glass cell is able to withstand pressures above 10 bar and allows the passage of light without lens effects owing to its plane-parallel windows. The sample cell is used in a polarizer for inert gas.Type: GrantFiled: June 7, 2000Date of Patent: May 22, 2007Assignee: Forschungszentrum Julich GmbHInventors: Stephan Appelt, Giovanni D'Orsaneo, Nadim Joni Shah
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Patent number: 7098034Abstract: Methods, systems, and computer program products analyze asphalt samples for anti-stripping agents by: obtaining a sample comprising asphalt binder material; sensing a selected parameter associated with the sample (such as the acidity and/or alkalinity of the sample); and analyzing the sensed parameter to assess at least one of: (a) the presence of at least one anti-stripping agent in the sample; and (b) the level of at least one anti-stripping agent in the sample. The sample can be heated so that it emits exhaust gas and the exhaust gas (directly or indirectly) interrogated to determine its pH, or other constituents or properties, such as ammonia. Pre-defined mathematical relationships can be used to correlate the measured sensed data to the concentrations of the anti-stripping agent(s) in the sample undergoing analysis. The evaluation can be carried out in a generally automated rapid manner so that the test can be completed in about 10 minutes or less. Related devices and kits are also described.Type: GrantFiled: December 23, 2002Date of Patent: August 29, 2006Assignee: InstroTek, Inc.Inventors: Tianqing He, Ali Regimand, Peter D. Muse, Lawrence H. James
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Patent number: 7008793Abstract: The present invention is intended to take a sample of an emulsion circulating in a line. The emulsion is momentarily diverted from the main circulation line 1 thereof to a bypass line 2. By restoring circulation of the emulsion in main line 1, an emulsion sample still present in bypass line 2 is confined under pressure. The emulsion sample is then stabilized according to a well-known method. Since the size and the distribution of the drops no longer evolve with time, the sample can be observed and analyzed after sampling. The invention more particularly applies to the field of petroleum industry and it is notably intended to take a sample of a petroleum effluent in form of an emulsion at wellheads.Type: GrantFiled: October 9, 2001Date of Patent: March 7, 2006Assignee: Institut Francais du PetroleInventors: Gilbert Duriez, Aurélie Mouret, Christine Noïk, Gérard Papon
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Patent number: 6890762Abstract: A method of measuring the physical and chemical properties of tissue or cells and a device for the same is provided, with which the physical and chemical environment of the tissue or cells can be changed arbitrarily corresponding to experimental necessities. The device comprises a system 40 for keeping the physical and chemical environment surrounding the biological tissue or cells constant, a system 50 for arbitrarily changing the physical and chemical environment, observation systems 10 and 20 for observing the physical and chemical properties of the tissue or cells, and a system 30 for comparing the change of the physical and chemical properties of the tissue or cells before and after changing the physical and chemical environment. The observation system 10 is a potential measurement device for measuring the electrophysiological properties of the tissue or cells.Type: GrantFiled: January 24, 1997Date of Patent: May 10, 2005Assignee: Matsushita Technical Information Services Co., Ltd.Inventors: Hirokazu Sugihara, Yasushi Kobayashi, Hiroaki Oka, Ryuta Ogawa, Makoto Taketani