Geochemical, Geological, Or Geothermal Exploration Patents (Class 436/25)
  • Patent number: 11536102
    Abstract: In an embodiment, a sample conditioning system includes a first valve subsystem, a controller, and a signal generator. The first valve subsystem includes a first electrically activated valve and a first timed switch in electrical communication with the first electrically activated valve, where the first timed switch is configured with a first time duration. The controller is configured to receive drilling data from a data source and, responsive to the drilling data satisfying a trigger associated with a timed sequence, cause the signal generator to apply a signal to at least the first timed switch. The signal causes the first timed switch to close for at least the first time duration and power the first electrically activated valve, the powered first electrically activated valve switching to allow air from a first air line to pass therethrough to a sample line.
    Type: Grant
    Filed: October 13, 2020
    Date of Patent: December 27, 2022
    Assignee: Reservoir Group Inc.
    Inventor: Isaac David Cobb
  • Patent number: 11487030
    Abstract: Disclosed are methods and systems for detecting and predicting events of increased seismic activity (i.e. earthquake activity). The methods include providing data catalogs, constructing magnitude versus time coordinate graphs, identifying energy levels of the graphs, and identifying further the obliquity angles of maximum and minimum energy levels and average increments between minimum and maximum energy levels. The methods also comprise constructing time arrows using the identified information, identifying energy centers via the time arrows, and analyzing variability throughout the seismic structure to predict a future event. Also disclosed are methods for predicting events based on attenuation wedge and energy parallelogram analysis.
    Type: Grant
    Filed: May 18, 2020
    Date of Patent: November 1, 2022
    Inventor: Vadim Kukharev
  • Patent number: 11268371
    Abstract: Methods of and systems for determining depths of provenance of drill cuttings contained in a drilling fluid received from a wellbore, the drilling fluid containing drill cuttings of different sizes that arrive at surface at different recorded times, the drill cuttings originating from different formation layers at different depth along the wellbore.
    Type: Grant
    Filed: October 23, 2017
    Date of Patent: March 8, 2022
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventor: Paul Simon Hammond
  • Patent number: 10976261
    Abstract: A method of detecting a mineral or metal in ground includes capturing an image of a target region of the ground and processing the image to determine a location of a candidate rock or plant of interest that is known to be usable for the detection of a mineral or element of interest. Once located, electromagnetic radiation, such as a laser, is directed to the candidate rock or plant to create a light signature, such as by vaporization. The method analyzes the light signature for the presence of the mineral or metal in the target region and determines if the light signature indicates the mineral or metal is present in the ground. The light signature can be analyzed with a spectroscope to detect the mineral or element as an indication of the present of the mineral or element in the ground around or below the candidate rock or plant.
    Type: Grant
    Filed: December 12, 2019
    Date of Patent: April 13, 2021
    Inventor: Peter Wilk
  • Patent number: 10927671
    Abstract: An automated or robotic mud-logger having a slurry sampler to collect a slurry sample online from a drilling fluid circuit contemporaneous with drilling of a borehole, the slurry sample including drilling fluid and rock cuttings. A liquid separator removes drilling fluid from the slurry sample and discharges a sample of the rock cuttings. A spectrometer performs elemental analysis of the sample of the rock cuttings substantially in real time with collection of the slurry sample.
    Type: Grant
    Filed: January 21, 2019
    Date of Patent: February 23, 2021
    Assignee: DIVERSIFIED WELL LOGGING, LLC
    Inventors: David Tonner, Aaron Swanson, Simon Hughes
  • Patent number: 10705237
    Abstract: Disclosed is a method for characterizing the evolution of a subsurface volume over time. The method comprises providing a first and second surveys of the reservoir with a first and second sets of seismic traces, performing an inversion to obtain estimates of changes having occurred between said first time and said second time in terms of at least one model parameter; wherein the subsurface volume is divided into regions according to a high order discrete classification attributed in accordance with the region's geologic characteristics, and said inversion is constrained per region of subsurface volume. The regions of subsurface volume may be geological layers.
    Type: Grant
    Filed: July 10, 2015
    Date of Patent: July 7, 2020
    Assignee: Total S.A.
    Inventors: Pierre Daniel Thore, Jonathan Anthony Edgar
  • Patent number: 10260030
    Abstract: A disposable, single-use wipe that can be used deodorize, disinfect, and/or sterilize an object. A holder may be used to create or energize one or more treatment agent in a wipe to improve its efficacy. A wipe includes a flexible membrane or cloth-like element that may apply, distribute, and/or remove a treatment agent to, over, or from a surface of the object. An enhanced treatment agent, such as peracetic acid, may be applied to the surface subsequent to being formed in the wipe as a result of installation of the wipe onto a holder, or otherwise activating the wipe. A holder may include a rechargeable reservoir to contain and apply a synergistic treatment agent to the wipe to create the enhanced treatment agent.
    Type: Grant
    Filed: January 24, 2018
    Date of Patent: April 16, 2019
    Inventor: Ashok V. Joshi
  • Patent number: 10222338
    Abstract: A method of detecting a mineral or metal in soil causes at least a portion of a plant to burn to produce a light signature. The method also analyzes the light signature for the presence of the mineral or metal in the plant and determines if the light signature indicates the mineral or metal is present in the plant.
    Type: Grant
    Filed: April 10, 2018
    Date of Patent: March 5, 2019
    Inventor: Peter Wilk
  • Patent number: 9995698
    Abstract: Disclosed is a method and system for integrating measurements from known laboratory techniques of fluid extraction (Dean Stark, Retort, Rock-Eval), which conducted independently by multiple disciplines and which have been so far treated as independent evaluations. In using these results, particularly Dean Stark and Retort, the oil industry has shown specific preferences between these two methods, with some groups advocating the validity of one method over the other, and others showing the opposite. Forums and discussions have been organized by the technical community to debate the benefits and drawbacks of each of these and to define which is the more suitable for reservoir characterization. Commercial laboratories have specialized in one method or the other based on their perceived validity. Both methods are correct, but each measure an incomplete assessment of the properties needed, and that together they provide considerable more information than when considered independently.
    Type: Grant
    Filed: October 20, 2016
    Date of Patent: June 12, 2018
    Assignee: W.D. Gonten Laboratories LLC
    Inventors: Roberto Suarez-Rivera, William D. Von Gonten, Kelly Vaughn, Ryan Zak
  • Patent number: 9664601
    Abstract: Method for determining volatile thio-ether compounds in offensive odorous sediment including: pre-treating a sediment sample, extracting volatile thio-ether compounds, separating and purifying the extraction supernatant in a solid phase extraction column, eluting with ethyl acetate, and finally collecting the eluent, which is then concentrated and used for determination by gas chromatography.
    Type: Grant
    Filed: April 12, 2016
    Date of Patent: May 30, 2017
    Assignee: Nanjing Institute of Geography & Limnology, Chinese Academy of Sciences
    Inventors: Xiaozhi Gu, Kaining Chen, Shuyun Sun, Miao Liu, Jia Kang, Yadong Wang
  • Patent number: 9500590
    Abstract: The present invention relates to an assay for the determination of a microorganism including a lysing chamber having triangular shaped metallic structures wherein the apexes of two triangles are arranged in alignment and forming a reactive zone for placement of the microorganism and lysing by microwave energy for exposing and isolating a target polynucleotide sequence. The isolated target polynucleotide sequence is introduced to an assay system for contact with polynucleotides which are complimentary to the isolated target polynucleotide sequence. Fluorophore-labeled capture polynucleotides are added for hybridizing to any bound target polynucleotide. Bound target polynucleotides are detected by metal enhanced fluorescence.
    Type: Grant
    Filed: December 1, 2011
    Date of Patent: November 22, 2016
    Assignee: UNIVERSITY OF MARYLAND, BALTIMORE COUNTY
    Inventor: Chris D. Geddes
  • Patent number: 9341558
    Abstract: The system for measuring permeation properties of concrete and porous materials includes a chamber having an upper plate, a lower plate, and a plurality of support members, the chamber being configured for holding a specimen. A plurality of supply tubes and a plurality of discharge tubes are in fluid communication with the chamber. A gas flow measurement assembly is in fluid communication with the chamber, the gas flow measurement assembly having a first pressure gauge and a gas flow meter. A water flow measurement assembly is in fluid communication with the chamber, the water flow measurement assembly having a second pressure gauge and a water flow meter. A gas cylinder is in fluid communication with the one of the plurality of supply tubes. The system may be used to measure gas permeability, water permeability, porosity, and absorption of concrete and other porous materials.
    Type: Grant
    Filed: August 25, 2015
    Date of Patent: May 17, 2016
    Assignee: KING SAUD UNIVERSITY
    Inventor: Mohammad Iqbal Khan
  • Patent number: 9170250
    Abstract: Detecting a spin probe in an oilfield fluid may indicate or determine the amount of the particular chemicals within an oilfield fluid. The detection of the spin probe may also indicate at least one property of the oilfield fluid, such as but not limited to pH, dielectric constant, rotational freedom of the spin probe, at least one chemical, the concentration of at least one chemical, residue of at least one chemical in the fluid, the speciation of coupled chemistry between the spin probe and the chemical, and combinations thereof. In one non-limiting embodiment, the spin probe may be attached to at least one chemical. The oilfield fluid may be or include, but is not limited to, a drilling fluid, a completion fluid, a production fluid, a servicing fluid, and combinations thereof.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: October 27, 2015
    Assignee: BAKER HUGHES INCORPORATED
    Inventors: Marc N. Lehmann, Matthew Hilfiger
  • Patent number: 9033800
    Abstract: A gaming machine with more gaming excitement is provided. The gaming machine includes: a cabinet; an upper image display panel which is provided on the cabinet and displays an effect image concerning a game; a lamp body unit which includes a lamp body which is a formed object and a sensor configured to detect the player's gesture with respect to the lamp body and is provided at a position different from the upper image display panel when viewed from the front surface of the cabinet; and a controller used to start the game, and the controller detects the player's gesture by the sensor at a timing corresponding to the state of the game and displays an effect image corresponding to the detected player's gesture on the upper image display panel.
    Type: Grant
    Filed: April 18, 2013
    Date of Patent: May 19, 2015
    Assignees: UNIVERSAL ENTERTAINMENT CORPORATION, ARUZE GAMING AMERICA, INC.
    Inventors: Masumi Fujisawa, Kenta Kitamura, Kenji Enokido, Keita Shimura, Kou Kobayashi, Hiroki Nakamura
  • Patent number: 9029156
    Abstract: The subject matter of the present disclosure is directed to developing a method of measuring the amount of producible oil and the producible oil saturation in shale-oil reservoirs using sample source rock. Further, the physical and chemical properties and amounts of producible oil in shale-oil reservoir samples may be determined. First and second solvents are applied to a sample source rock to extract petroleum from the sample source rock. The extracted source rock, the twice-extracted source rock, and the first and second extracted petroleum may be analyzed to determine the characteristics and properties of the reservoir rock.
    Type: Grant
    Filed: May 9, 2013
    Date of Patent: May 12, 2015
    Assignee: Weatherford Technology Holdings, LLC
    Inventors: Alan S. Kornacki, Patricia M. O'Neal, Kathryn E. Washburn, Kevin L. Kmiec
  • Patent number: 9029155
    Abstract: The present disclosure relates to apparatuses and methods to detect a fluid contamination level of a fluid sample. The method may comprise providing a fluid sample downhole from a subterranean formation, applying a reactant to the fluid sample to create a combined fluid, observing the combined fluid, and determining if contaminants are present within the fluid sample based upon the observing the combined fluid.
    Type: Grant
    Filed: May 21, 2010
    Date of Patent: May 12, 2015
    Assignee: Schlumberger Technology Corporation
    Inventors: Andrew E. Pomerantz, Oliver C. Mullins
  • Publication number: 20150087071
    Abstract: Method and apparatus for determining the relative content of a first rock species and of a second rock species in a rock sample extracted from a wellbore. The method comprises adding a reactant to the rock sample, measuring a first information (PT1) relative to a first amount of compound produced at a first instant (T1) and a second information (PT2) relative to a second amount of compound produced at a second instant (T2). The method also comprises calculating the relative content of the first species in the rock sample from the first information (PT1) and calculating the relative content of the second species in the rock sample from the second information PT2). The method comprises determining a corrected amount (Cv) of compound generated by the reaction of the second species with the reactant at the first instant (T1), and calculating the relative content of the first species in the rock sample and the relative content of the second species in the rock sample based on the corrected amount (Cv).
    Type: Application
    Filed: December 14, 2012
    Publication date: March 26, 2015
    Applicant: Geoservices Equipements
    Inventors: Farouk Kimour, Eric Villard, Pawel Kasprzykowski
  • Patent number: 8962336
    Abstract: Disclosed are a soil diagnosis method for diagnosing soil using a cycle activity indicator which is calculated using the following factors (I) to (III): (I) the ammonia reduction rate in target soil; (II) the activity of forming phosphoric acid from phytic acid in the target soil; and (III) the activity of forming potassium from compost in the target soil, and (IV) the soil bacteria count in the soil; and a soil quality control method; and a soil improvement method.
    Type: Grant
    Filed: March 19, 2010
    Date of Patent: February 24, 2015
    Assignee: The Ritsumeikan Trust
    Inventors: Kenzo Kubota, Hiroyuki Ishimori, Yoshiki Matsumiya, Ryoichi Fukagawa, Motoki Kubo, Nobuyuki Kadokura, Akio Kanemori
  • Publication number: 20140377872
    Abstract: The invention is a method of predicting the amount and the composition of fluids produced by mineral reactions operating within a sedimentary basin and trapped with hydrocarbons in reservoirs. Geological data characteristic of the basin are acquired and a representation of the basin by a grid is constructed. The evolution of a depth of burial (z), a temperature (T), a pore pressure (P), a volume (V) and a porosity ? at successive ages (ti) representative of the geological history of the basin is then calculated for at least one set of cells of the grid, using a basin model and the geological data. A mineralogical or chemical rock composition is determined in each cell of the set of cells from the geological data of the basin. The amount and the composition of fluids of mineral origin is determined within the set of cells using a geochemical model and an equation of state, from the parameters, the composition and a thermodynamic database.
    Type: Application
    Filed: June 19, 2014
    Publication date: December 25, 2014
    Inventors: Etienne BROSSE, Jean-Luc RUDKIEWICZ, Teddy PARRA, Xavier GUICHET
  • Patent number: 8912000
    Abstract: Methods and apparatus for obtaining a mass spectrum of a sample and determining a concentration of a component of the sample by utilizing a model of chemical and electron ionization and the obtained mass spectrum.
    Type: Grant
    Filed: July 17, 2009
    Date of Patent: December 16, 2014
    Assignee: Schlumberger Technology Corporation
    Inventors: Pierre J. Daniel, Julian J. Pop, Reza Taherian, Bruno Drochon
  • Patent number: 8845415
    Abstract: In various embodiments, players around the casino may predict cards to be dealt in a game of blackjack.
    Type: Grant
    Filed: July 6, 2012
    Date of Patent: September 30, 2014
    Assignee: CFPH, LLC
    Inventors: Howard W. Lutnick, Dean P. Alderucci, Geoffrey M. Gelman, Kevin Burman
  • Patent number: 8691582
    Abstract: A method for in situ monitoring within a specified environment. The method includes locating a housing in a well, wherein a set of pumps and a plurality of test beds are inserted. Each of the set of pumps are controlled by signals from the control system to push water from each pump into one of the plurality of separate test beds where, after flowing through each of the test beds, effluent flows into an effluent storage device.
    Type: Grant
    Filed: November 19, 2012
    Date of Patent: April 8, 2014
    Assignee: Arizona Board of Regents
    Inventor: Rolf U. Halden
  • Patent number: 8536536
    Abstract: The present invention comprises a method and a system of collection and analysis for in situ determination of concentrations of minerals in granular material originating from a shaft under excavation, in a continuous, non-intrusive manner in real time. According to the present invention granular material collected passes to a granular material collector, subsequently entering a reading module which determines the concentration of different materials by spectroscopic methods. The granular material collected comes from drilling dust which rises along a boring tool of an excavating bit. The concentration data of different minerals in the granular material being analysed at a given moment may be processed and transmitted to establish and/or correct logistic and operational procedures such as, for example, in an excavation or in an overall process wherein it is set.
    Type: Grant
    Filed: November 3, 2009
    Date of Patent: September 17, 2013
    Assignee: Ingenieros Matematicos Consultores Asociados, S.A.
    Inventors: Mario Manuel Durán Toro, Ronald Romeo Guzman Venegas
  • Patent number: 8518702
    Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.
    Type: Grant
    Filed: January 19, 2011
    Date of Patent: August 27, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Li Jiang, Oliver C. Mullins, Gale H. Gustavson, Christopher Harrison, Bhavani Raghuraman, Ronald E. G. Van Hal, Jimmy Lawrence, Kosta Ladavac, Albert Ballard Andrews, Timothy Gareth John Jones, Rogerio Tadeu Ramos
  • Patent number: 8492153
    Abstract: A method for calculating the volume of various predetermined organic end-members in samples of rock at various depths in oil reservoir rock is utilized to produce one or more graphic displays that are use to interpret the data to identify, e.g., tar mats, in order to improve the efficient production of hydrocarbons from the well. Data is collected from the samples by known pyrolysis and compositional modeling methods; additional data is obtained by elemental analysis to determine weight percentages of C, H, N, S and O in the selected end-members and characterization of physical properties of representative samples of the reservoir rock, e.g., from core samples; the data is then processed in accordance with the method to provide a series of data points used to produce the graphic displays for visual interpretation.
    Type: Grant
    Filed: February 15, 2008
    Date of Patent: July 23, 2013
    Assignee: Saudi Arabian Oil Company
    Inventors: Peter J. Jones, Henry I. Halpern
  • Patent number: 8486702
    Abstract: A traceable treatment composition for treating a subterranean formation having multiple zones penetrated by a well bore comprising a homogenous blend of a tracking composition and a resin composition. The tracking composition comprises a substantially non-radioactive tracking material selected from the group consisting of a metal salt. The metal portion of the metal salt may be selected from the group consisting of gold, silver, lithium, molybdenum, and vanadium.
    Type: Grant
    Filed: June 27, 2012
    Date of Patent: July 16, 2013
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philip D. Nguyen, Jimmie D. Weaver, Johnny A. Barton
  • Publication number: 20130122595
    Abstract: Apparatus and systems, as well as methods, may operate to draw a formation fluid sample into a sampling port included in a down hole tool or tool body, to vaporize some part of the fluid sample to substantially fill an injection port with a gas phase, to differentiate gas components in the gas phase to provide differentiated gas components along a concentration gradient in a receiving section, to detect the differentiated gas components with a detector, and to determine a fingerprint of the differentiated gas components. A reaction section and a vacuum section may be used for waste consumption and/or absorption.
    Type: Application
    Filed: January 10, 2013
    Publication date: May 16, 2013
    Applicant: Halliburton Energy Services, Inc.
    Inventor: Halliburton Energy Services, Inc.
  • Patent number: 8388435
    Abstract: A method of playing a wagering game comprises receiving a wager, and generating a randomly selected first outcome of a first wagering game, the first outcome comprising a first plurality of symbols arranged in a first matrix. The method further comprises generating a randomly selected second outcome of a second wagering game, the second outcome comprising a second plurality of symbols arranged in a second matrix, and simultaneously displaying the first outcome and the second outcome on at least one display. The method further comprises detecting an occurrence of a triggering event, in response to the triggering event, copying a first special symbol occurring in the first outcome into the second outcome to yield a modified second outcome, and evaluating the first outcome and the modified second outcome for winning combinations of symbols.
    Type: Grant
    Filed: May 28, 2009
    Date of Patent: March 5, 2013
    Assignee: WMS Gaming Inc.
    Inventors: Peter R. Anderson, Allon G. Englman, Benjamin T. Gomez, Joel R. Jaffe, Daniel P. Louie
  • Patent number: 8361804
    Abstract: Disclosed herein is an indicator precursor composition for determining the hardness of a wellbore fluid filtrate, where the composition includes a colorimetric indicator and a buffer, where the buffer may include a salt of a weak acid and a strong base, and where the indicator precursor may be a dry solid. Also disclosed is a method for determining the hardness of a wellbore fluid filtrate.
    Type: Grant
    Filed: September 21, 2009
    Date of Patent: January 29, 2013
    Assignee: M-I L.L.C.
    Inventors: Robert L. Horton, Bethicia B. Prasek
  • Patent number: 8354279
    Abstract: Compositions and methods for determining the source of treatment fluids being produced from a production formation having multiple zones by introducing a treatment composition having a tracking material into a zone in the subterranean formation, and detecting the tracking material in treatment composition that flows back from the subterranean formation.
    Type: Grant
    Filed: February 12, 2004
    Date of Patent: January 15, 2013
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philip D. Nguyen, Jimmie D. Weaver, Johnny A. Barton
  • Patent number: 8338182
    Abstract: A system for in situ monitoring within a specified environment includes a housing with an intake inserted into the environment. A plurality of pumps are included in the housing with a number of test beds, each being separately coupled to one of the number of pumps, where each of the number of test beds holds material and where each of the plurality of pumps operate to separately push fluid through a coupled test bed. An effluent storage device is disposed to receive effluent from the number of test beds.
    Type: Grant
    Filed: February 8, 2010
    Date of Patent: December 25, 2012
    Assignee: Arizona Board of Regents, a Body Corporate Acting for and on Behalf of Arizona State University
    Inventor: Rolf Ulrich Halden
  • Patent number: 8283174
    Abstract: A formation fluid sampling tool is provided with reactants which are carried downhole and which are combined in order to generate heat energy which is applied to the formation adjacent the borehole. By applying heat energy to the formation, the formation fluids are heated, thereby increasing mobility, and fluid sampling is expedited.
    Type: Grant
    Filed: January 7, 2011
    Date of Patent: October 9, 2012
    Assignee: Schlumberger Technology Corporation
    Inventors: Ronald E. G. Van Hal, Anthony Goodwin, Oliver C. Mullins, Peter S. Hegeman, Bhavani Raghuraman, Soraya S. Betancourt, Cosan Ayan, Ricardo Vasques, Francois Xavier Dubost, Christopher Scott Del Campo
  • Patent number: 8268146
    Abstract: A wellbore tool has an electrochemical sensor for measuring the amount of hydrogen sulphide or thiols in a fluid downhole in a wellbore. The sensor comprises a temperature- and pressure-resistant housing containing a flow path for the fluids. The fluids flow over one side of a gas permeable membrane the other side of the membrane being exposed to a chamber containing at least two electrodes and containing a reaction solution which together with the hydrogen sulphide or thiols create a redox reaction resulting in an electrical current dependent upon the amount of hydrogen sulphide or thiols in the fluid. Measurement is made by passing formation fluid along the flow path and repeatedly applying varying potential to one electrode and measuring the peak current flowing between that electrode and a second electrode.
    Type: Grant
    Filed: June 9, 2010
    Date of Patent: September 18, 2012
    Assignee: Schlumberger Technology Corporation
    Inventors: Li Jiang, Timothy Gareth John Jones, Jonathan Webster Brown, Andrew Gilbert
  • Patent number: 8246442
    Abstract: A game of chance is disclosed that looks like a multi-line gaming machine having a matrix of rows and columns of positions for displaying slot symbols or cards to a player. A player wagers to play one or more games but the actual pay lines are dynamically determined by events that occur during the course of game play, not before. Per the teaching of the invention a number of bonus pay lines and their routing are dynamically determined during the course of game play of slots or cards dependent on choices made by a player during game play.
    Type: Grant
    Filed: January 6, 2010
    Date of Patent: August 21, 2012
    Inventor: Robert P Barrie
  • Publication number: 20120149117
    Abstract: Methods and related apparatuses and mixtures are described for spectroscopic detection of hydrogen sulfide in a fluid, for example a formation fluid downhole. A reagent mixture is combined with the fluid. The reagent mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and a capping agent that limits growth of the insoluble metal sulfide species by electrosteric or steric stabilization. The particle growth is one of chemical reaction or significant aggregation, and the capping agent further functionalizes the reagent mixture to exhibit properties outside the natural characteristics of the metal sulfide species to allow for spectroscopic detection of the metal sulfide species. The combined mixture and fluid is then spectroscopically interrogated to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.
    Type: Application
    Filed: December 13, 2010
    Publication date: June 14, 2012
    Applicant: Schlumberger Technology Corporation
    Inventors: Jimmy Lawrence, Ronald van Hal, Jane Lam
  • Patent number: 8093056
    Abstract: A method and apparatus to determine the fractional amount of at least one constituent of a hydrocarbon mixture, comprising dissolving the hydrocarbon mixture in a substantially hydrogen free solvent to produce a diluted solution, the diluted solution having sufficient solvent to render a NMR property of the diluted solution to be predictably related to the constituent concentrations of the hydrocarbon mixture; making NMR measurements on the diluted solution; and determining the fractional amount of at least one constituent of the hydrocarbon mixture from the NMR measurements.
    Type: Grant
    Filed: June 29, 2007
    Date of Patent: January 10, 2012
    Assignee: Schlumberger Technology Corporation
    Inventor: Krishnamurthy Ganesan
  • Patent number: 8058071
    Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.
    Type: Grant
    Filed: January 19, 2011
    Date of Patent: November 15, 2011
    Assignee: Schlumberger Technology Corporation
    Inventors: Li Jiang, Oliver C. Mullins, Gale H. Gustavson, Christopher Harrison, Bhavani Raghuraman, Ronald E. G. Van Hal, Jimmy Lawrence, Kosta Ladavac, Albert Ballard Andrews, Timothy Gareth John Jones, Rogerio Tadeu Ramos
  • Patent number: 8037313
    Abstract: The invention relates generally to a method and arrangement for real-time betting with an off-line terminal, and especially to the technological field of keeping reliable time in the off-line terminal when handling, within a communications system comprising a distributed domain and a central domain, electronic records that contain predictions of the outcome of a certain incident. Within the distributed domain a multitude of electronic records that contain predictions of the outcome of the incident are generated and furnished with a cryptographically protected proof of a certain moment of the distributed domain's local time associated with the generation of the electronic record.
    Type: Grant
    Filed: December 28, 2004
    Date of Patent: October 11, 2011
    Assignee: Innoka Oy
    Inventors: Panu Hämäläinen, Marko Hännikäinen, Timo D. Hämäläinen
  • Publication number: 20110189778
    Abstract: Methods and apparatus for obtaining a mass spectrum of a sample and determining a concentration of a component of the sample by utilizing a model of chemical and electron ionization and the obtained mass spectrum.
    Type: Application
    Filed: July 17, 2009
    Publication date: August 4, 2011
    Inventors: Pierre J. Daniel, Julian J. Pop, Reza Teherian, Bruno Drochon
  • Patent number: 7959864
    Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.
    Type: Grant
    Filed: October 26, 2007
    Date of Patent: June 14, 2011
    Assignee: Schlumberger Technology Corporation
    Inventors: Li Jiang, Oliver C. Mullins, Gale H. Gustavson, Christopher Harrison, Bhavani Raghuraman, Ronald E. G. Van Hal, Jimmy Lawrence, Kosta Ladavac, A. Ballard Andrews, Timothy Gareth John Jones, Rogerio Tadeu Ramos
  • Publication number: 20110111507
    Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.
    Type: Application
    Filed: January 19, 2011
    Publication date: May 12, 2011
    Applicant: Schlumberger Technology Corporation
    Inventors: Li Jiang, Oliver C. Mullins, Gale H. Gustavson, Christopher Harrison, Bhavani Raghuraman, Ronald E.G. Van Hal, Jimmy Lawrence, Kosta Ladavac, A. Ballard Andrews, Timothy Gareth John Jones, Rogerio Tadeu Ramos
  • Publication number: 20110104809
    Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.
    Type: Application
    Filed: January 19, 2011
    Publication date: May 5, 2011
    Applicant: Schlumberger Technology Corporation
    Inventors: Li Jiang, Oliver C. Mullins, Gale H. Gustavson, Christopher Harrison, Bhavani Raghuraman, Ronald E.G. Van Hal, Jimmy Lawrence, Kosta Ladavac, A. Ballard Andrews, Timothy Gareth John Jones, Rogerio Tadeu Ramos
  • Patent number: 7896578
    Abstract: An apparatus and method for evaluating chemicals of interest in a subsurface bore hole, such as a groundwater sampling well. An absorbent member is attached to a flexible liner, and the liner is everted by fluid pressure down the borehole. The everted liner presses the absorbent member against the wall of the borehole. Any chemicals of interest are absorbed into the absorbent member from the media surrounding the borehole. The liner, with associated absorbent member thereon, is then extracted from the borehole. The absorbent member may then be subjected to any suitable laboratory analysis to evaluate the type, spatial distribution, and concentration of chemicals of interest, such as water contaminants occurring in the borehole.
    Type: Grant
    Filed: June 30, 2008
    Date of Patent: March 1, 2011
    Inventor: Carl Keller
  • Patent number: 7807467
    Abstract: A method is disclosed for predicting the High Frequency Reciprocating Rig (HFRR) wear scar diameter for a hydrocarbon mixture using an HFRR wear scar diameter prediction equation which predicts the HFRR wear scar diameter based on the mid-infrared spectroscopy test results for such hydrocarbon mixture. Such predicted HFRR wear scar diameter value can then be used to determine the necessity of adding a lubricity additive to a diesel material in order to produce a diesel product possessing adequate lubricity properties.
    Type: Grant
    Filed: October 17, 2006
    Date of Patent: October 5, 2010
    Assignee: ConocoPhillips Company
    Inventor: Enrico A. Lodrigueza
  • Patent number: 7803046
    Abstract: An gaming machine for and method of par-mutuel wagering that allows individuals to continuously place multiple casino and lottery styled pari-mutuel wagers on simulcast live and/or recorded pari-mutuel race events. The gaming machine includes a display screen to provide a graphic display of a plurality of pari-mutuel gaming options to a player, and a selection device operable by the player to select at least one of the pari-mutuel gaming options displayed on the screen, the selection device operable by the player to input a wager corresponding to the selected at least one pari-mutuel gaming option. The gaming machine has the ability to be linked to a network of gaming machines in pari-mutuel and/or other wagering venues.
    Type: Grant
    Filed: July 10, 2003
    Date of Patent: September 28, 2010
    Inventors: Kenneth A. Scott, Lawrence A. Krause
  • Publication number: 20100240135
    Abstract: The invention provides a method of testing sour natural gas by a) removing H2S from the gas stream, b) converting H2S to elemental sulfur, and c) recovering elemental sulfur. The invention also provides a substantially mobile system for testing sour natural gas including vehicles allowing the equipment to be operated on surfaces such as the flat beds of trailers. The system features equipment that may be mounted within one or more support structures situated on a mobile vehicle, such as, for instance the flat bed of a trailer. The one or more support structures hold each piece of equipment substantially fixed in place on the vehicles. Each surface such as the flat bed of a trailer may carry one, two or more pieces of equipment. The equipment may include, for instance, an air or oxygen compressor, a knockout vessel, a gas heater, an air heater, a cooler, a molten sulfur separator and a thermal oxidizer.
    Type: Application
    Filed: March 19, 2010
    Publication date: September 23, 2010
    Inventors: David M. Seeger, Bonnie S. Davis, Eric C. Klasson, Bryan J. Petrinec
  • Publication number: 20100055666
    Abstract: The present invention is directed to a waveguide sensor as well as to an evanescent field induced evanescent field induced sensor system for use in diagnostic housing and an integrated waveguide sensor comprising: a waveguide layer,—capture compounds applied on the upper surface of said waveguide layer for 5 specific bonding to target substances,—a cladding layer surface of said waveguide layer,—a filter which is transmitting for luminescent radiation while absorbs and/or reflects radiation of excitation radiation, wherein the filter is arranged below the lower 10 surface of said cladding layer, at least one detector for sensing luminescent radiation, wherein the detector is arranged below the lower surface of said filter, a substrate that is connected with the detector and comprises the electrical interface of said detector; wherein 15 between the upper surface of the waveguide layer and along at least a lower surface section of the housing a channel is formed for receiving a fluidic probe; and the luminesce
    Type: Application
    Filed: January 31, 2008
    Publication date: March 4, 2010
    Applicant: KONINKLIJKE PHILIPS ELECTRONICS N.V.
    Inventors: Reinhold Wimberger-Friedl, Nigel David Young, Pieter Jan Van Der Zaat
  • Patent number: 7669469
    Abstract: The present invention provides an apparatus and method for continuously monitoring the integrity of a pressurized well bore fluid sample collected downhole in an earth boring or well bore. The CDR continuous by measures the temperature and pressure for the down hole sample. Near infrared, mid infrared and visible light analysis is also performed on the small amount of sample to provide an on site analysis of sample properties and contamination level. The onsite analysis comprises determination of gas oil ratio, API gravity and various other parameters which can be estimated by a trained neural network or chemometric equation a flexural mechanical resonator is also provided to measure fluid density and viscosity from which additional parameters can be estimated by a trained neural network or chemometric equation. The sample tank is overpressured or supercharged to obviate adverse pressure drop or other effects of diverting a small sample to the CDR.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: March 2, 2010
    Assignee: Baker Hughes Incorporated
    Inventors: Michael Shammai, Francisco G. Sanchez, James T. Cernosek, Rocco DiFoggio
  • Publication number: 20100015714
    Abstract: A soil sample of fixed volume is mixed with a drying agent (MgSO4) and then acetone. The liquid is filtered off and a sample is applied to the sensing surface of an attenuated total reflectance (ATR) device in an IR spectrometer. After evaporation of the acetone, absorption is measured in a C-H stretch region (e.g. 2950 cm?1) to provide a value indicative of the amount of oil in the sample.
    Type: Application
    Filed: December 5, 2005
    Publication date: January 21, 2010
    Inventors: Selwayan Saini, John Stephen Setford, Julian Lawrence Ritchie, Vincent Paul Knight, Markus Michael Malecha
  • Patent number: 7642094
    Abstract: Provided is a method of measuring a biodegradation rate of a non-natural organic compound in the presence of a biodegradation medium, characterized by including: measuring a concentration of a radioactive carbon isotope 14C in a biodegradation medium; and measuring a biodegradation rate of a non-natural organic compound from a difference between the concentration of 14C in the biodegradation medium and a concentration of 14C in modern carbon. Further, a metal such as iron in the medium can be used as an internal standard. According to the method, a biodegradation rate of a non-natural organic compound can be measured safely, simply, rapidly, and accurately without providing any special measures against radiation.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: January 5, 2010
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Hironori Tashiro, Shinji Ito