Containig Triglycerides (e.g., Castor Oil, Corn Oil, Olive Oil, Lard, Etc.) Patents (Class 44/308)
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Patent number: 12173240Abstract: The present invention relates to a process for converting vegetable oils, animal fats, residual edible oils and carboxylic acids into renewable liquid fuels, such as bionaphtha, bioJET-A1 and renewable diesel, for use in a mixture with fossil fuels. The process consists of two steps: hydrotreating and hydrocracking. The effluent from the hydrotreatment step presents aromatics, olefins and compounds resulting from the polymerization of esters and acids in its composition. This fact occurs due to the use of partially reduced catalysts and without injection of sulfide agent and allows obtaining a bioJET-A1 with adequate quality for use in a mixture with fossil kerosene. At the same time, the process generates, in addition to products in the distillation range of naphtha, kerosene and diesel, high molecular weight linear paraffins (with up to 40 carbon atoms).Type: GrantFiled: August 20, 2021Date of Patent: December 24, 2024Assignee: Petróleo Brasileiro S.A. - PetrobrasInventors: Jefferson Roberto Gomes, Jose Luiz Zotin, Rodrigo Caetano Chistone, Anilza De Almeida Lyra Correa, Marcelo Edral Pacheco
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Patent number: 12037556Abstract: The invention discloses methods for manufacturing and using a diesel fuel composition comprising a cetane number improver, a fossil fuel component, and a hydrotreated renewable fuel component manufactured by hydrotreating and isomerising renewable raw material.Type: GrantFiled: October 31, 2022Date of Patent: July 16, 2024Assignee: NESTE OYJInventors: Ulla Kiiski, Markku Kuronen, Jenni Nortio
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Patent number: 11814587Abstract: A method for treating petroleum, petroleum fraction, or natural gas, the process comprising: adding a) a first component which is selected from material, particularly roots, of a plant of the genus Glycyrrhiza, and/or an arbuscular mycorrhizal fungi, and b) a second component which is selected from a plant material or -ingredient comprising plastids, algae and/or cyanobacteria, to the petroleum, petroleum fraction, or natural gas.Type: GrantFiled: December 22, 2017Date of Patent: November 14, 2023Inventor: Rainer Tesch
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Patent number: 11802257Abstract: Systems and methods to reduce pour point (PP) temperatures of fat-based compositions for use in transportation fuels. In one or more embodiments, methods and systems reduce the pour point of rendered fats using biologically-derived plant oils for effectively transporting the blended fat based compositions over long distances, thereby advantageously decreasing the heating and mixing requirements needed to maintain the compositional temperature above the pour point. In certain embodiments, the fat based composition comprises rendered animal fats, such as tallow in combination with distilled corn oil (DCO).Type: GrantFiled: January 31, 2023Date of Patent: October 31, 2023Assignee: MARATHON PETROLEUM COMPANY LPInventors: Daniel Z. Short, Nathan R. Klaus, David G. Teschel, Paul J. Dofton, Justin L. Womeldorff, Michelle Smith, Peg Broughton, Caleb S. Litchfield
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Patent number: 11603501Abstract: A method for producing a bio-jet fuel includes a reaction step of hydrogenating, isomerizing, and decomposing a crude oil obtained by a deoxygenation treatment of a raw oil containing a triglyceride and/or a free fatty acid, by using a hydrogenation catalyst and an isomerization catalyst in a hydrogen atmosphere under conditions of a reaction temperature of 180° C. to 350° C. and a pressure of 0.1 MPa to 30 MPa.Type: GrantFiled: May 17, 2019Date of Patent: March 14, 2023Assignees: HIBD LABORATORY ASSOCIATION, ENVIRONMENT ENERGY CO., LTD.Inventors: Kaoru Fujimoto, Yayoi Murakami, Shuji Noda
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Patent number: 11518950Abstract: Provided herein are biodiesel fuel mixtures having improved properties for reducing NOx emissions as well as total particular matter emissions, CO emissions, and total hydrocarbon emissions.Type: GrantFiled: October 26, 2021Date of Patent: December 6, 2022Assignee: HULL PARTNERS, LLCInventor: Patrick McDuff
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Patent number: 11262342Abstract: Methods, systems, and apparatus, including computer programs encoded on computer storage media, for molecular content analysis. One of the methods includes receiving molecular content data that indicates a molecular content of a portion of a batch of sludge; determining, by a machine learning module included in the system using the molecular content data and multiple parameters, a predicted value for a property of the portion of the batch of sludge; and providing the predicted value for the property of the portion of the batch of sludge.Type: GrantFiled: July 12, 2017Date of Patent: March 1, 2022Assignee: Accenture Global Solutions LimitedInventors: Corinna Lamberti, Katherine Goldklang, Robert Riley
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Patent number: 11261330Abstract: The invention relates to a composition comprising C10-C20 paraffins, wherein about 3 wt. % to about 30 wt. %, based on the total weight of the composition, are C10-C15 paraffins, and the C10-C20 paraffins are derived from a biological raw material. The invention also relates to a protective agent for a porous material, comprising said composition.Type: GrantFiled: May 16, 2017Date of Patent: March 1, 2022Assignee: NESTE CORPORATIONInventors: Virpi Rämö, Tomi Nyman, Tanja Eskola
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Patent number: 11203728Abstract: A multipurpose fuel composition is disclosed which contains a petroleum derived jet fuel component and a renewable jet fuel component, wherein the multipurpose fuel composition has a freezing point of ?40° C. or below, and an exemplary cetane number more than 40, preferably more than 45, more preferably more than 50.Type: GrantFiled: June 4, 2018Date of Patent: December 21, 2021Assignee: NESTE OYJInventors: Markku Kuronen, Ulla Kiiski, Jenni Nortio, Kati Sandberg
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Patent number: 11104859Abstract: Disclosed are compositions containing at least one of the following: (1) estolide polyethylene glycol diesters; (2) hydroxy derived estolide polyethylene glycol diesters; (3) unsaturated hydroxy derived estolide polyethylene glycol diesters; (4) estolide trimetholpropane diesters; (5) hydroxy derived estolide trimetholpropane diesters; (6) unsaturated hydroxy derived estolide trimetholpropane diesters; (7) estolide epoxide polyethylene glycol diesters; (8) estolide dihydroxide polyethylene glycol diesters; (9) mono-capped hydroxy derived estolide epoxide polyethylene glycol diesters; (10) mono-capped hydroxy derived estolide dihydroxide polyethylene glycol diesters; and mixtures thereof; and optionally a carrier. All the compounds can be used as a viscosity index improver thereby improving a lubricant's performance.Type: GrantFiled: August 12, 2019Date of Patent: August 31, 2021Assignee: The United States of America, as represented by the Secretary of AgricultureInventors: Terry Isbell, Steven C. Cermak, Benjamin A. Lowery
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Patent number: 11104857Abstract: A fuel composition for powering a combustion engine, the composition comprising: a liquid base fuel; and a (co)polymer obtainable by (co)polymerizing at least the following monomers: •at least one bicyclic (meth)acrylate ester •optionally at least one lower-alkyl (meth)acrylate, •optionally at least one aromatic vinyl monomer, and •optionally other ethylenically unsaturated monomers.Type: GrantFiled: May 19, 2016Date of Patent: August 31, 2021Assignee: Shell Oil CompanyInventors: Mark Lawrence Brewer, John Socrates Thomaides, John M. Morales, Qiwei He, Philip Nigel Threlfall-Holmes, Damien Christian Vadillo, Nicholas James Rounthwaite, Michael Timothy Philbin, Roger Francis Cracknell, Andrea Schuetze
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Patent number: 11001774Abstract: The present technology provides compositions that include at least about 98 weight percent (“wt %”) n-paraffins which, among other surprising features, may be suitable for use as a diesel fuel, an aviation fuel, a jet fuel blendstock, a blendstock to reduce the cloud point of a diesel fuel, a fuel for portable heaters, and/or as a charcoal lighter fluid. The composition includes at least about 98 wt % C7-C12 n-paraffins, where at least about 10 wt % of composition includes n-decane, at least about 20 wt % of the composition includes n-dodecane, and at least about 75 wt % of the composition includes even carbon number paraffins. The composition also includes less about 0.1 wt % oxygenates and less than about 0.1 wt % aromatics. The composition may be produced by a process that includes hydrotreating a biorenewable feedstock comprising at least one of palm kernel oil, coconut oil, babassu oil, microbial oil, or algal oil.Type: GrantFiled: February 25, 2019Date of Patent: May 11, 2021Assignee: REG SYNTHETIC FUELS, LLCInventors: Ramin Abhari, David A. Slade, H. Lynn Tomlinson, Erik Ashby, Nate Green, Caroline Golden
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Patent number: 11001775Abstract: A fuel composition for powering a combustion engine the composition comprising: a liquid base fuel; and a copolymer obtainable by copolymerizing at least the following monomers: —at least one bicyclic (meth)acrylate ester; —at least one fatty-alkyl (meth)acrylate; —optionally, and preferably, at least one aromatic vinyl monomer; and —optionally other ethylenically unsaturated monomers.Type: GrantFiled: May 19, 2016Date of Patent: May 11, 2021Assignee: Shell Oil CompanyInventors: Mark Lawrence Brewer, John Socrates Thomaides, John M. Morales, Qiwei He, Philip Nigel Threlfall-Holmes, Damien Christian Vadillo, Nicholas James Rounthwaite, Michael Timothy Philbin, Roger Francis Cracknell, Andrea Schuetze
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Patent number: 10889837Abstract: The present invention relates to using high oil corn to make a biochemical such as ethanol. More particularly, the invention relates to methods of making a biochemical using relatively low temperature saccharification followed by fermentation or simultaneous saccharification and fermentation of high oil corn.Type: GrantFiled: November 24, 2015Date of Patent: January 12, 2021Assignee: POET Research, Inc.Inventors: Stephen M. Lewis, John Kenneth Grearson, Neelakantam V. Narendranath, Francis Michael Swain, Brett Yerdon, Camille Kelly Nelson
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Patent number: 10865430Abstract: Provided is a device for producing ultra-low sulfur biodiesel. The device for producing ultra-low sulfur biodiesel is a two-stage processing device, comprising a two-stage purification unit, a two-stage enzyme reaction unit, a two-stage distillation unit, and a decompression rectification unit. The present invention is green and environment-friendly, effectively and completely removing sulfur-containing impurities from the raw material, eliminating the attack of a sulfur-containing group in the synthesis process on fatty acids, and providing sufficient conditions for obtaining ultra-low sulfur content methyl esters in the product section.Type: GrantFiled: May 29, 2018Date of Patent: December 15, 2020Inventors: Aijun Li, Hong Wang, Guangming Wen, Weiqing Chen, Hongpeng Li, Liyan Feng, Liguang Feng
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Patent number: 10865354Abstract: Marine gas oil compositions corresponding to fuels and/or fuel blending components are provided that can provide improved friction properties within an engine. Addition of lubricant base stock to a marine gas oil composition can reduce frictional losses within an engine during operation. The benefits in reduction of frictional losses can be observed based on the difference between the indicated mean effective pressure and the actual work delivered by an engine, where the difference corresponds to the frictional mean effective pressure.Type: GrantFiled: March 6, 2020Date of Patent: December 15, 2020Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Aditya S. Shetkar, Kenneth C. H. Kar, Scott K. Berkhous
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Patent number: 10829706Abstract: A method of manufacturing a cetane-boosting fuel additive includes reacting formaldehyde and 2-ethylhexanol at a mole ratio of 10:1 to 1:1, or 5:1 to 1.5:1, or 4:1 to 2:1, or 3.5:1 to 2.5:1 in the presence of a heterogeneous acid catalyst at a temperature of 300 to 375° K to obtain a cetane-boosting product mixture comprising H3C(CH2)3CH(CH2CH3)CH2(OCH2)nOH, H3C(CH2)3CH(CH2CH3)CH2(OCH2)nOCH2CH(CH2CH3)(CH2)3CH3, or a combination thereof, wherein n has an average value of 2.8 to 3.2, preferably an average value of 3.Type: GrantFiled: July 17, 2018Date of Patent: November 10, 2020Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Vijay Dinkar Bodas, Sultan Eid Al-Otaibi, Guillermo Leal, Mohammed Bismillah Ansari, Naif Mohammed Al Naddah Al-Otaibi
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Patent number: 10815431Abstract: Disclosed are a method and a system for producing bio-derived aromatic hydrocarbons from a renewable resource. More particularly, the disclosure provides for the co-location of a biomass reactor unit and an aromatization reactor unit to produce benzene from a renewable source such as plant mass. Hexane produced from cellulose in the biomass reactor unit can be converted to benzene in the aromatization reactor unit and hydrogen produced in the aromatization reactor unit can be used in the biomass reactor unit. Also described is the use of a mixture of bio-derived hexane produced from cellulose and naphtha in an aromatization process.Type: GrantFiled: August 16, 2019Date of Patent: October 27, 2020Assignee: Chevron Phillips Chemical Company LPInventor: Ryan W. Snell
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Patent number: 10767124Abstract: A process for recovery hydrogen and LPG from a gaseous separated hydroprocessed stream and a stripper gaseous stream and/or a fractionator gaseous stream by increasing the pressure of the stripper gaseous stream and/or the fractionator gaseous stream. Both streams or all three streams can be subjected to sponge absorption and hydrogen recovery in series.Type: GrantFiled: March 30, 2017Date of Patent: September 8, 2020Assignee: UOP LLCInventors: Kiran Ladkat, Neeraj Tiwari
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Patent number: 10450533Abstract: Methods and devices for economically producing a purified biodiesel product from feedstocks. Some embodiments of the methods comprise using at least one of a crude feedstock pretreatment process and a free fatty acid refining process prior to transesterification and the formation of crude biodiesel and glycerin. The crude biodiesel is then subjected to at least one biodiesel refining process which, in conjunction with feedstock pretreatment and free fatty acid refining produces a purified biodiesel product that meets multiple commercial specifications. A wide variety of feedstocks may be used to make biodiesel that otherwise would not meet the same commercial specifications, including corn oil, used cooking oil, poultry fats, fatty acid distillates, pennycress oil, and algal oils.Type: GrantFiled: March 26, 2018Date of Patent: October 22, 2019Assignee: Renewable Energy Group, Inc.Inventors: David A Slade, Cody J Ellens, Bradley N Albin, Derek J Winkel, Jared A Downey
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Patent number: 10428278Abstract: Disclosed are a method and a system for producing bio-derived aromatic hydrocarbons from a renewable resource. More particularly, the disclosure provides for the co-location of a biomass reactor unit and an aromatization reactor unit to produce benzene from a renewable source such as plant mass. Hexane produced from cellulose in the biomass reactor unit can be converted to benzene in the aromatization reactor unit and hydrogen produced in the aromatization reactor unit can be used in the biomass reactor unit. Also described is the use of a mixture of bio-derived hexane produced from cellulose and naphtha in an aromatization process.Type: GrantFiled: June 15, 2017Date of Patent: October 1, 2019Assignee: Chevron Phillips Chemical Company LPInventor: Ryan W. Snell
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Patent number: 10377953Abstract: The present disclosure relates to processes and systems that convert biomass to stable intermediate hydrocarbon products that having a greatly decreased oxygen content. This stabilized intermediate hydrocarbon product may be easily be stored for an extended period of time, further refined into liquid transportation fuels (either alone or mixed with petroleum-derived hydrocarbons), or blended with petroleum-derived blendstocks to produce a finished liquid transportation fuel.Type: GrantFiled: November 8, 2017Date of Patent: August 13, 2019Assignee: Phillips 66 CompanyInventors: Kening Gong, Liang Zhang, John R. Copeland, Reed J. Eisenhart
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Patent number: 10358611Abstract: An apparatus and process is disclosed for hydrocracking a hydrocarbon feed stream following hydrotreating the feed stream. A separator removes diesel and lower boiling materials in a hydrotreated stream before a hydrocracking reactor, so only liquid materials heavier than diesel are hydrocracked in a hydrocracking reactor. A vapor hydrotreated stream and the hydrocracked stream are separated and fractionated together.Type: GrantFiled: February 3, 2017Date of Patent: July 23, 2019Assignee: UOP LLCInventors: Gabriela M. Gonzalez Lippke, Simerjeet Singh, Richard K. Hoehn
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Patent number: 10323199Abstract: The present invention relates to a Fuel Supplement comprising of selected plant oils mixed in given proportions, which when added to fuels like petrol and diesel can reduce harmful emissions during combustion of fuel. It can significantly decrease the Sulphur content in fuels and thus protect the environment from harmful pollutants. It improves the fuel lubricity and engine performance. It also increases the flash point of Diesel.Type: GrantFiled: December 29, 2016Date of Patent: June 18, 2019Assignee: SSR PHARMA PRIVATE LTDInventors: Sandeep P. Agarwal, Surjan Singh Rauthan
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Patent number: 10308896Abstract: The present invention relates generally to methods for producing detergent compounds from waste plastic feedstocks. More specifically, the invention relates to methods for producing detergent intermediates, including alkylbenzenes, paraffins, olefins, oxo alcohols, and surfactant derivatives thereof from waste plastic feedstock.Type: GrantFiled: August 2, 2016Date of Patent: June 4, 2019Assignee: The Procter & Gamble CompanyInventors: Jeffrey John Scheibel, Phillip Kyle Vinson, Scott Leroy Cron, Thomas Earl Williams
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Patent number: 10221387Abstract: An integrated facility for the co-production of ethanol and biodiesel fuel is provided. Ethanol and corn oil, the primary product and a by-product from the ethanol plant, are utilized as feedstocks for a biodiesel plant operating within the same general facility as the corn ethanol plant. By-products of the biodiesel plant, principally crude liquid glycerol and gaseous ethanol or methanol, are recycled to various parts of the ethanol plant.Type: GrantFiled: August 26, 2014Date of Patent: March 5, 2019Assignee: Rayeman Elements, Inc.Inventors: Rachel Overheul, Brandon Awtrey, Daniel Johnson
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Patent number: 9957496Abstract: Provided are a method for regulating acid resistance of a microorganism by suppressing the expression of the fadD gene therein and a screening method for a microorganism having acid resistance by using the expression level of the fadD gene as an index. A method for regulating acid resistance of a microorganism, including suppressing the expression of fadD gene present in the microorganism.Type: GrantFiled: December 3, 2014Date of Patent: May 1, 2018Assignee: KABUSHIKI KAISHA YAKULT HONSHAInventors: Hoshitaka Matsumoto, Mika Miura, Mayumi Kiwaki, Tohru Iino
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Patent number: 9957464Abstract: Methods and devices for economically producing a purified biodiesel product from feedstocks. Some embodiments of the methods comprise using at least one of a crude feedstock pretreatment process and a free fatty acid refining process prior to transesterification and the formation of crude biodiesel and glycerin. The crude biodiesel is then subjected to at least one biodiesel refining process which, in conjunction with feedstock pretreatment and free fatty acid refining produces a purified biodiesel product that meets multiple commercial specifications. A wide variety of feedstocks may be used to make biodiesel that otherwise would not meet the same commercial specifications, including corn oil, used cooking oil, poultry fats, fatty acid distillates, pennycress oil, and algal oils.Type: GrantFiled: June 10, 2014Date of Patent: May 1, 2018Assignee: Renewable Energy Group, Inc.Inventors: David A Slade, Cody J Ellens, Bradley N Albin, Derek J Winkel, Jared A Downey
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Patent number: 9845432Abstract: The invention relates to a method for revamping a conventional refinery of mineral oils into a biorefinery, characterized by a production scheme which allows the treatment of raw materials of a biological origin (vegetable oils, animal fats, exhausted cooking oils) for the production of biofuels, prevalently high-quality biodiesel.Type: GrantFiled: September 4, 2012Date of Patent: December 19, 2017Assignee: ENI S.p.A.Inventors: Giacomo Fernando Rispoli, Claudia Prati, Andrea Amoroso, Paolo Pollesel
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Patent number: 9701594Abstract: The present invention relates to the hydrodeoxygenation of pyrolysis oils in the presence of an alcohol.Type: GrantFiled: August 30, 2011Date of Patent: July 11, 2017Assignee: Albemarle Europe SPRLInventors: Emanuel Hermanus Van Broekhoven, Ralph Klomp, Ruben Theodoor Pronk, Leendert Arie Gerritsen, Frans Lodewijk Plantenga, Edgar Evert Steenwinkel
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Patent number: 9644150Abstract: The amount of renewable hydrocarbons produced from biomass may be increased by pyrolyzing the biomass in a biomass conversion unit in the presence of hydrogen sulfide or a sulfiding agent. The formation of deposits of unwanted carbonaceous materials, such as coke, is reduced by the presence of the hydrogen sulfide or sulfiding agent.Type: GrantFiled: December 15, 2015Date of Patent: May 9, 2017Assignee: Inaeris Technologies, LLCInventors: Lorenz J. Bauer, Mitch Loescher
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Patent number: 9469818Abstract: The invention relates to a hydrocarbon composition, which can be used as a fuel and/or fuel oil, containing a petroleum component (A) and a component of a biological origin (B), wherein the component of a biological origin is present in a quantity of up to 75% by volume with respect to the total composition.Type: GrantFiled: November 10, 2014Date of Patent: October 18, 2016Assignees: ENI S.p.A., UOP LLCInventors: Franco Baldiraghi, Silvia Guanziroli, Giovanni Faraci, Luigina Maria Flora Sabatino, Terry Louise Marker, John Anthony Petri
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Patent number: 9434962Abstract: Disclosed is an integrated process comprising first and second biotechnical processes. The first process produces biofuel and/or starting material for biofuel and uses a microorganism capable of producing enzymes. The second process produces biofuel and/or starting material for biofuel. In the integrated process, the microorganisms are cultivated and biofuel and/or starting material for biofuel and enzymes are produced. The microorganism culture, supernatant or a protein enriched fraction or a dilution of the supernatant comprising catalytically active enzyme(s) are introduced into the first and/or into the second process, or feedstock for the process(es) is treated. The invention relates also to use of the produced enzymes in biofuel production process or in other applications as an enzyme preparation or a source of enzymes. The invention relates also to use of the produced lipids and alcohols as biofuel, a component of biofuel or a starting material for biofuel production.Type: GrantFiled: December 21, 2011Date of Patent: September 6, 2016Assignee: Neste OyjInventors: Perttu Koskinen, Reijo Tanner
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Patent number: 9273258Abstract: Methods are provided for producing a jet fuel composition from a feedstock including a natural oil. The methods include reacting the feedstock with a low-weight olefin in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product. The methods further include hydrogenating the metathesized product under conditions sufficient to form a jet fuel composition.Type: GrantFiled: December 8, 2014Date of Patent: March 1, 2016Assignee: Elevance Renewable Sciences, Inc.Inventors: Melvin L. Luetkens, Jr., Steven A. Cohen, Chander Balakrishnan
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Patent number: 9267086Abstract: The invention provides synergistic biofuel blends comprising a petroleum distillate and two or more fatty acid alkyl ester-containing biofuels. Methods for making synergistic biofuel blends are also provided.Type: GrantFiled: January 10, 2011Date of Patent: February 23, 2016Assignee: ExxonMobil Research and Engineering CompanyInventors: Lisa I-Ching Yeh, Donna I. Hoel, Paul P. Wells
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Patent number: 9260678Abstract: Process for the production of biocombustible or biofuel mixtures suitable for different conditions of use, starting from refined or raw vegetable oils, including those extracted from seaweed, and/or from used food oils and animal fats, each of which is pre-treated with specific treatments in order to yield a dried refined oil. The latter then undergoes transesterification with an excess of lower alcohols or bioalcohols, and a subsequent separation into a raw glycerine-based phase and a phase containing mixtures of fatty acid alkyl esters and the excess alcohols or bioalcohols.Type: GrantFiled: July 6, 2007Date of Patent: February 16, 2016Inventor: Nazzareno De Angelis
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Patent number: 9120991Abstract: High octane unleaded aviation fuel compositions having a CHN content of at least 97.2 wt %, less than 2.8 wt % of oxygen content, a T10 of at most 75° C., T40 of at least 75° C., a T50 of at most 105° C., a T90 of at most 135° C., a final boiling point of less than 210° C., an adjusted heat of combustion of at least 43.5 MJ/kg, a vapor pressure in the range of 38 to 49 kPa is provided.Type: GrantFiled: July 25, 2014Date of Patent: September 1, 2015Assignee: Shell Oil CompanyInventors: Timothy Michael Shea, Trevor James Davies, Michael Clifford Macknay, Hanane Belmokaddem Bennis
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Patent number: 9074191Abstract: The present invention provides a system and method for culturing a microalgae biofamily to produce lipids. The method includes growing a microalgae biofamily comprises multiple microalgae species in a liquid medium at a first stress level. A portion of the microalgae are exposed to a second stress level and harvested. Lipids are extracted from the harvested portion. Also disclosed is a system for culturing a microalgae biofamily that comprises an enclosed pond containing microalgae in growth medium and having a sloped bottom, at least one photobioreactor positioned above the pond, and a pump circulating the microalgae-containing growth medium between the pond and the at least one photobioreactor.Type: GrantFiled: December 30, 2010Date of Patent: July 7, 2015Inventor: Marcelo Gonzalez Machin
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Patent number: 9051525Abstract: Emissions of polynuclear aromatic hydrocarbons (PAHs) from diesel engines may be reduced by blending a renewable hydrocarbon distillate with a base diesel fuel. The base diesel may be a fossil diesel fuel, a Fischer-Tropsch diesel fuel as well as a hydroprocessed biodiesel fuel or a combination thereof. The renewable hydrocarbon distillate is a fraction from hydrotreated bio-oil having a boiling point between from about 320° F. to about 700° F.Type: GrantFiled: January 25, 2013Date of Patent: June 9, 2015Assignee: KiOR, Inc.Inventors: Jeffrey C. Trewella, Vicente Sanchez, Roger L. Leisenring, Jr.
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Patent number: 9045785Abstract: The present invention is directed to isolated microorganisms as well as strains and mutants thereof, biomasses, microbial oils, compositions, and cultures; methods of producing the microbial oils, biomasses, and mutants; and methods of using the isolated microorganisms, biomasses, and microbial oils.Type: GrantFiled: July 20, 2012Date of Patent: June 2, 2015Assignee: DSM IP Assets B.V.Inventors: Joseph W. Pfeifer, III, Jon Milton Hansen, Jose R. Garcia, Xiao Daniel Dong, Paul Warren Behrens, Kirk E. Apt
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Patent number: 9039790Abstract: Methods for making a fuel composition comprising contacting one or more components of a hydroprocessing feedstock, for example both a fatty acid- or triglyceride-containing component and a paraffin-rich component, with hydrogen under catalytic hydroprocessing conditions are disclosed. The methods are effective to upgrade the component(s) and provide a hydroprocessed biofuel. A representative method utilizes a single-stage process in which hydrogen-containing recycle gas is circulated through both a hydrodeoxygenation zone and a hydrocracking zone in series.Type: GrantFiled: December 15, 2010Date of Patent: May 26, 2015Assignee: UOP LLCInventor: Tom N. Kalnes
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Patent number: 9024096Abstract: A process for converting triacylglycerides-containing oils into crude oil precursors and/or distillate hydrocarbon fuels is disclosed. The process may include reacting a triacylglycerides-containing oil-carbon dioxide mixture at a temperature in the range from about 250° C. to about 525° C. and a pressure greater than about 75 bar to convert at least a portion of the triacylglycerides to a hydrocarbon or mixture of hydrocarbons comprising one or more of isoolefins, isoparaffins, cycloolefins, cycloparaffins, and aromatics.Type: GrantFiled: December 11, 2012Date of Patent: May 5, 2015Assignee: Lummus Technology Inc.Inventor: Marvin I. Greene
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Patent number: 8975457Abstract: Described herein are methods for producing fuels and solvents from fatty acid resources. In general, the pyrolysis products of fatty acids are extracted in order to remove residual fatty acids and produce very pure hydrocarbon compositions composed of alkanes and alkenes. The fatty acids removed from the extraction step can be further pyrolyzed to produce additional hydrocarbons or, in the alternative, the fatty acids can be isolated and used in other applications. Also disclosed herein are fuels and solvents produced by the methods described herein.Type: GrantFiled: February 24, 2011Date of Patent: March 10, 2015Assignee: The Governors of the University of AlbertaInventor: David Bressler
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Patent number: 8975459Abstract: A process for making a bio-naphtha and optionally bio-propane from a complex mixture of natural occurring fats & oils, wherein said complex mixture is subjected to a refining treatment for removing the major part of non-triglyceride and non-fatty acid components, thereby obtaining refined fats & oils; said refined fats & oils are transformed into linear or substantially linear paraffin's as the bio-naphtha by an hydrodeoxygenation or from said refined fats & oils are obtained fatty acids that are transformed into linear or substantially linear paraffin's as the bio-naphtha by hydrodeoxygenation or decarboxylation of the free fatty acids or from said refined fats & oils are obtained fatty acids soaps that are transformed into linear or substantially linear paraffin's as the bio-naphtha by decarboxylation of the soaps.Type: GrantFiled: December 3, 2013Date of Patent: March 10, 2015Assignee: Total Research & Technology FeluyInventors: Walter Vermeiren, Nicolas Van Gyseghem
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Patent number: 8957269Abstract: The invention relates to a method of producing olefinic monomers for the production of a polymer. The invention particularly relates to the production of tall oil-based biopolymers, such as polyolefins. In the stages of the method bio oil, with a content of over 50% of fatty acids of tall oil and no more than 25% of resin acids of tall oil, and hydrogen gas are fed into a catalyst bed (7); the oil is catalytically deoxygenated in the bed by hydrogen; the flow exiting the bed is cooled down and divided into a hydrocarbon-bearing liquid phase (10) and a gas phase; and the hydrocarbon-bearing liquid (13) is subjected to steam cracking (4) to provide a product containing polymerizing olefins. The deoxygenation in the bed can be followed by a catalytic cracking or, with a suitable catalyst, the deoxygenation and cracking can be simultaneous. The separated hydrogen-bearing gas phase can be circulated in the process.Type: GrantFiled: January 29, 2010Date of Patent: February 17, 2015Assignee: Stora Enso OyjInventors: Ali Harlin, Tapani Penttinen, Jari Räsänen, Olli Aaltonen
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Patent number: 8939758Abstract: Candle compositions are disclosed which include a high concentration of liquid oils, yet are solid due the incorporation of wax-monoesters; thereby enhancing the scope, quality and functionality of candles. The wax-monoesters may be obtained from natural plant based waxes, including rice bran wax. Candles based on the candle compositions and methods of making the compositions are also disclosed.Type: GrantFiled: July 19, 2010Date of Patent: January 27, 2015Assignee: Global Agritech, Inc.Inventor: Dharma R. Kodali
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Patent number: 8940949Abstract: A process for the conversion of biomass to hydrocarbon products such as transportation fuels, kerosene, diesel oil, fuel oil, chemical and refinery plant feeds. The instant process uses a hydrocarbon or synthesis gas co-feed and hot pressurized water to convert the biomass in a manner commonly referred to as hydrothermal liquefaction.Type: GrantFiled: September 24, 2012Date of Patent: January 27, 2015Inventor: Gary Peyton Miller
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Patent number: 8911514Abstract: Hydrotreating methods and hydrotreating systems are provided herein. In an embodiment, a hydrotreating method includes heating a petroleum-based diesel feed. The heated petroleum-based diesel feed is introduced to a hydrotreating process. An unheated carbonaceous feed is introduced to the hydrotreating process separate from the heated petroleum-based diesel feed. The heated petroleum-based diesel feed and the unheated carbonaceous feed are co-processed in the hydrotreating process. In an embodiment of a hydrotreating system, the hydrotreating system includes a hydrotreating unit, and a heating apparatus, with the heating apparatus heating petroleum-based diesel feed prior to introduction to the hydrotreating unit. The unheated carbonaceous feed source is in fluid communication with the hydrotreating unit for introducing an unheated carbonaceous feed to the hydrotreating unit separate from the petroleum-based diesel feed.Type: GrantFiled: December 15, 2011Date of Patent: December 16, 2014Assignee: UOP LLCInventors: Soumendra M. Banerjee, Richard K. Hoehn
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Patent number: 8911512Abstract: Disclosed is a method for determining properties of hydrocarbonaceous samples including a component prepared from: 1) the thermo-catalytic conversion of biomass, or 2) the pyrolytic conversion of biomass with subsequent upgrading. The determination of the property(ies) is by use of a near-infrared spectra based correlation.Type: GrantFiled: September 20, 2012Date of Patent: December 16, 2014Assignee: KiOR, Inc.Inventors: Jorge Gonzalez, Leslie May, Vicente Sanchez
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Patent number: 8911513Abstract: A system and method are disclosed for processing grease trap waste to produce brown grease oil. Heat to promote waste grease stratification is provided by combustion of brown grease itself. A portion of the brown grease, which would normally be transported to an end user, is retained in a separate holding vessel at the grease processing site. The brown grease within the holding vessel is thermally conditioned to adjust viscosity so that it may be drawn through one or more pumps to increase pressure for atomization in a boiler. The heat of the brown grease combustion is applied to grease trap waste in the containment vessel by heating tubes immersed in the grease trap waste in which a heat transfer medium circulates and gives up its heat to the grease trap waste to thereby promote stratification of the grease trap waste and production of the brown grease oil.Type: GrantFiled: August 4, 2010Date of Patent: December 16, 2014Assignee: Downey Ridge Environmental CompanyInventors: Ronald L. Crosier, James E. Hendrixon