Chemically Reacted Organic Oxidate (e.g., Esterified, Etc.) Patents (Class 44/310)
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Patent number: 8900416Abstract: The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.Type: GrantFiled: February 22, 2010Date of Patent: December 2, 2014Assignee: University of Georgia Research Foundation, Inc.Inventors: Roger Norris Hilten, Keshav Das, James R. Kastner, Brian P. Bibens
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Patent number: 8603199Abstract: This invention relates to a method and device to produce esterified, olefinated/esterified, or thermochemolytic reacted bio-oils as fuels. The olefinated/esterified product may be utilized as a biocrude for input to a refinery, either alone or in combination with petroleum crude oils. The bio-oil esterification reaction is catalyzed by addition of alcohol and acid catalyst. The olefination/esterification reaction is catalyzed by addition of resin acid or other heterogeneous catalyst to catalyze olefins added to previously etherified bio-oil; the olefins and alcohol may also be simultaneously combined and catalyzed by addition of resin acid or other heterogeneous catalyst to produce the olefinated/esterified product.Type: GrantFiled: October 1, 2010Date of Patent: December 10, 2013Assignee: Mississippi State UniversityInventors: Philip H. Steele, Charles U. Pittman, Jr., Leonard L. Ingram, Jr., Sanjeev Gajjela, Zhijun Zhang, Priyanka Bhattacharya
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Patent number: 8192696Abstract: A system and process for continuous production of fatty acid methyl esters (FAME) from the fatty acid triglycerides of waste oil via transesterification in the presence of a reusable sugar-based catalyst. The system and process incorporates re-cycling and re-use of waste by-product streams to result in a near-zero emissions, with a 97% product yield mix consisting of almost pure biodiesel and a very small percentage of impurities including glycerol.Type: GrantFiled: November 18, 2009Date of Patent: June 5, 2012Inventors: Stephanie Marie Gurski, Anam Kazim, Hoi Ki Cheung, Amani Obeid
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Patent number: 8152870Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, sequentially adding solvent sets to the algal biomass, and sequentially separating solid biomass fractions from liquid fractions to arrive at a liquid fraction comprising neutral lipids. The method also includes esterifying the neutral lipids, separating a water miscible fraction comprising glycerin from a water immiscible fraction comprising fuel esters, carotenoids, and omega-3 fatty acids. The method also includes obtaining a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.Type: GrantFiled: April 6, 2011Date of Patent: April 10, 2012Assignee: Heliae Development, LLCInventor: Aniket Kale
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Patent number: 8124572Abstract: The present invention is directed to methods and systems for processing triglyceride-containing, biologically-derived oils, wherein such processing comprises conversion of triglycerides to free fatty acids and the separation of these fatty acids by saturation type. Such separation by type enables the efficient preparation of both lubricants and transportation fuels from a common source using a single integrated method and/or system.Type: GrantFiled: September 27, 2007Date of Patent: February 28, 2012Assignee: Chevron U.S.A. Inc.Inventor: Stephen Joseph Miller
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Publication number: 20100095581Abstract: A biodiesel reactor system includes a reactor recirculation line running from the reactor bottom to a headspace in the top of the reactor. A reactor recirculation pump is in the reactor recirculation line, and a reactor nozzle is positioned in at a reactor recirculation line discharge in the headspace. The reactor nozzle provides back pressure on the reactor recirculation pump to cause a controlled cavitation. The controlled cavitation provides mixing for the various reactants to produce biodiesel fuel.Type: ApplicationFiled: October 22, 2009Publication date: April 22, 2010Applicant: Biodiesel Logic, Inc.Inventor: John West
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Publication number: 20090158642Abstract: Disclosed is a MMT containing motor fuel additive composition which synergistically interacts with the MMT additive to reduce both fuel intake system deposit formation and combustion chamber deposit formation, thereby reducing engine ORI and maintaining desired engine performance.Type: ApplicationFiled: March 5, 2009Publication date: June 25, 2009Applicant: POLAR MOLECULAR CORPORATIONInventors: Otis L. Nelson, JR., Mark L. Nelson, A. Richard Nelson, Chandra Prakash, Gilbert Chapelet
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Publication number: 20090158643Abstract: Disclosed is a leaded motor fuel additive composition which synergistically interacts with the alkyl lead additive to reduce both fuel intake system deposit formation and combustion chamber deposit formation, thereby reducing engine ORI and maintaining desired engine performance.Type: ApplicationFiled: March 5, 2009Publication date: June 25, 2009Applicant: POLAR MOLECULAR CORPORATIONInventors: Otis L. Nelson, JR., Mark L. Nelson, A. Richard Nelson, Chandra Prakash, Gilbert Chapelet
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Publication number: 20080176130Abstract: Disclosed is a fuel composition for fuel cells with improved performance. In order to efficiently remove undesirable intermediates of a fuel cell that uses liquid oxygenated hydrocarbons as fuel thereof, polyoxometalate as an oxidation assistant is directly added to the fuel cell. Herein, polyoxometalate includes at least one redox reactive anion caused by dissolution of polyoxometalate in an organic medium containing solution and/or an aqueous solution. The intermediates generated during activating the fuel cell are efficiently oxidized and, additionally, carbon monoxide with the property of catalyst poisoning of electrode catalyst is eliminated, thereby accomplishing improvements in poisoning resistance of the catalyst and, in turn, performance of the fuel cell.Type: ApplicationFiled: December 5, 2007Publication date: July 24, 2008Inventors: Won-Bae Kim, Min-Ho Seo, Sung-Mock Choi, Jea-Hong Kim
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Publication number: 20020189156Abstract: An additive for hydrocarbon fuels such as propane, comprising active components including a hydrocarbon mixture in the range of approximately 60% to 76% by volume, and hydrotreated distillates in the range of approximately 10% to 16% by volume.Type: ApplicationFiled: February 13, 2002Publication date: December 19, 2002Inventor: Lloyd R. Lack
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Patent number: 5178640Abstract: Synthetic fuel and/or synthetic components for fuels are prepared from a mixture of aromatic polycarboxylic acids of suitable elementary composition, having a mean molecular weight of between 120 and 800 and an acidity of between 5 and 18 meq/g by partially decarboxylating them by heat treatment and subjecting the non-removed acidic functions to esterification with one or more alcohols or one or more olefins. This invention relates to a method for preparing a synthetic fuel and/or synthetic components for fuels, and the product obtained by said method.Type: GrantFiled: April 5, 1989Date of Patent: January 12, 1993Assignee: ENI-Ente Nazionale IdrocarburiInventors: Ermanno Girardi, Riccardo Mansani