Chemically Reacted Organic Oxidate (e.g., Esterified, Etc.) Patents (Class 44/310)
  • Patent number: 8900416
    Abstract: The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.
    Type: Grant
    Filed: February 22, 2010
    Date of Patent: December 2, 2014
    Assignee: University of Georgia Research Foundation, Inc.
    Inventors: Roger Norris Hilten, Keshav Das, James R. Kastner, Brian P. Bibens
  • Patent number: 8603199
    Abstract: This invention relates to a method and device to produce esterified, olefinated/esterified, or thermochemolytic reacted bio-oils as fuels. The olefinated/esterified product may be utilized as a biocrude for input to a refinery, either alone or in combination with petroleum crude oils. The bio-oil esterification reaction is catalyzed by addition of alcohol and acid catalyst. The olefination/esterification reaction is catalyzed by addition of resin acid or other heterogeneous catalyst to catalyze olefins added to previously etherified bio-oil; the olefins and alcohol may also be simultaneously combined and catalyzed by addition of resin acid or other heterogeneous catalyst to produce the olefinated/esterified product.
    Type: Grant
    Filed: October 1, 2010
    Date of Patent: December 10, 2013
    Assignee: Mississippi State University
    Inventors: Philip H. Steele, Charles U. Pittman, Jr., Leonard L. Ingram, Jr., Sanjeev Gajjela, Zhijun Zhang, Priyanka Bhattacharya
  • Patent number: 8192696
    Abstract: A system and process for continuous production of fatty acid methyl esters (FAME) from the fatty acid triglycerides of waste oil via transesterification in the presence of a reusable sugar-based catalyst. The system and process incorporates re-cycling and re-use of waste by-product streams to result in a near-zero emissions, with a 97% product yield mix consisting of almost pure biodiesel and a very small percentage of impurities including glycerol.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: June 5, 2012
    Inventors: Stephanie Marie Gurski, Anam Kazim, Hoi Ki Cheung, Amani Obeid
  • Patent number: 8152870
    Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, sequentially adding solvent sets to the algal biomass, and sequentially separating solid biomass fractions from liquid fractions to arrive at a liquid fraction comprising neutral lipids. The method also includes esterifying the neutral lipids, separating a water miscible fraction comprising glycerin from a water immiscible fraction comprising fuel esters, carotenoids, and omega-3 fatty acids. The method also includes obtaining a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.
    Type: Grant
    Filed: April 6, 2011
    Date of Patent: April 10, 2012
    Assignee: Heliae Development, LLC
    Inventor: Aniket Kale
  • Patent number: 8124572
    Abstract: The present invention is directed to methods and systems for processing triglyceride-containing, biologically-derived oils, wherein such processing comprises conversion of triglycerides to free fatty acids and the separation of these fatty acids by saturation type. Such separation by type enables the efficient preparation of both lubricants and transportation fuels from a common source using a single integrated method and/or system.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: February 28, 2012
    Assignee: Chevron U.S.A. Inc.
    Inventor: Stephen Joseph Miller
  • Publication number: 20100095581
    Abstract: A biodiesel reactor system includes a reactor recirculation line running from the reactor bottom to a headspace in the top of the reactor. A reactor recirculation pump is in the reactor recirculation line, and a reactor nozzle is positioned in at a reactor recirculation line discharge in the headspace. The reactor nozzle provides back pressure on the reactor recirculation pump to cause a controlled cavitation. The controlled cavitation provides mixing for the various reactants to produce biodiesel fuel.
    Type: Application
    Filed: October 22, 2009
    Publication date: April 22, 2010
    Applicant: Biodiesel Logic, Inc.
    Inventor: John West
  • Publication number: 20090158642
    Abstract: Disclosed is a MMT containing motor fuel additive composition which synergistically interacts with the MMT additive to reduce both fuel intake system deposit formation and combustion chamber deposit formation, thereby reducing engine ORI and maintaining desired engine performance.
    Type: Application
    Filed: March 5, 2009
    Publication date: June 25, 2009
    Applicant: POLAR MOLECULAR CORPORATION
    Inventors: Otis L. Nelson, JR., Mark L. Nelson, A. Richard Nelson, Chandra Prakash, Gilbert Chapelet
  • Publication number: 20090158643
    Abstract: Disclosed is a leaded motor fuel additive composition which synergistically interacts with the alkyl lead additive to reduce both fuel intake system deposit formation and combustion chamber deposit formation, thereby reducing engine ORI and maintaining desired engine performance.
    Type: Application
    Filed: March 5, 2009
    Publication date: June 25, 2009
    Applicant: POLAR MOLECULAR CORPORATION
    Inventors: Otis L. Nelson, JR., Mark L. Nelson, A. Richard Nelson, Chandra Prakash, Gilbert Chapelet
  • Publication number: 20080176130
    Abstract: Disclosed is a fuel composition for fuel cells with improved performance. In order to efficiently remove undesirable intermediates of a fuel cell that uses liquid oxygenated hydrocarbons as fuel thereof, polyoxometalate as an oxidation assistant is directly added to the fuel cell. Herein, polyoxometalate includes at least one redox reactive anion caused by dissolution of polyoxometalate in an organic medium containing solution and/or an aqueous solution. The intermediates generated during activating the fuel cell are efficiently oxidized and, additionally, carbon monoxide with the property of catalyst poisoning of electrode catalyst is eliminated, thereby accomplishing improvements in poisoning resistance of the catalyst and, in turn, performance of the fuel cell.
    Type: Application
    Filed: December 5, 2007
    Publication date: July 24, 2008
    Inventors: Won-Bae Kim, Min-Ho Seo, Sung-Mock Choi, Jea-Hong Kim
  • Publication number: 20020189156
    Abstract: An additive for hydrocarbon fuels such as propane, comprising active components including a hydrocarbon mixture in the range of approximately 60% to 76% by volume, and hydrotreated distillates in the range of approximately 10% to 16% by volume.
    Type: Application
    Filed: February 13, 2002
    Publication date: December 19, 2002
    Inventor: Lloyd R. Lack
  • Patent number: 5178640
    Abstract: Synthetic fuel and/or synthetic components for fuels are prepared from a mixture of aromatic polycarboxylic acids of suitable elementary composition, having a mean molecular weight of between 120 and 800 and an acidity of between 5 and 18 meq/g by partially decarboxylating them by heat treatment and subjecting the non-removed acidic functions to esterification with one or more alcohols or one or more olefins. This invention relates to a method for preparing a synthetic fuel and/or synthetic components for fuels, and the product obtained by said method.
    Type: Grant
    Filed: April 5, 1989
    Date of Patent: January 12, 1993
    Assignee: ENI-Ente Nazionale Idrocarburi
    Inventors: Ermanno Girardi, Riccardo Mansani