Substituted Or Unsubstituted Cyclopentadienyl Manganese Tricarbonyl, With An Organic Compound Having -c(=o)o- Not Bonded To Heavy Metal Or Aluminum Etc.) Patents (Class 44/360)
  • Patent number: 9200229
    Abstract: A non-aqueous lubricating composition containing a major amount of an oil of lubricating viscosity and a minor amount in the range of 0.02% to 5% by weight, of at least one compound having the structural formula (I): wherein m and n are each independently an integer in the range 1 to 6, R1 and R2 each independently represent a C1 to C10 hydrocarbyl or substituted hydrocarbyl group, and R3 represents a C10 to C26 hydrocarbyl group.
    Type: Grant
    Filed: May 17, 2013
    Date of Patent: December 1, 2015
    Assignee: CASTROL LIMITED
    Inventors: Samir Chahine, James Edward Moss
  • Patent number: 8870981
    Abstract: An additive composition for a fuel comprises: (i) a metal compound selected from an iron compound, a manganese compound, a calcium compound, a cerium compound and mixtures thereof; (ii) an organic compound selected from a bicyclic monoterpene, substituted bicyclic monoterpene, adamantane, propylene carbonate and mixtures thereof; and (iii) a stabilizer. The additive composition allows fuels which are prone to separation, for example blended fuels or fuels having a high content of asphaltenes, to be used successfully.
    Type: Grant
    Filed: November 14, 2012
    Date of Patent: October 28, 2014
    Assignee: Innospec Limited
    Inventors: Miltiades Papachristos, Ian Malcolm McRobbie, Deepak Kamran
  • Patent number: 8641791
    Abstract: The invention concerns a method for supplying iron, via the fuel, to the particulate trap of a diesel engine exhaust in a form suitable for promoting trap regeneration. The method involves the addition to the fuel of a defined colloid of iron oxide. Combustion of this colloid produces iron-containing compounds, especially iron oxides, which collect in association with carbonaceous particulate matter in the particulate trap, and function to promote the combustion of this matter. The colloid in particular shows a lower level of associated deposit formation on the fuel injectors than the iron additives of the prior art. The method is thus particularly suitable for modern engines showing increased susceptibility to fuel injector deposits. The colloid also shows a balance of properties providing excellent suitability for use as an additive in fuels, and especially in diesel engine on-board dosing devices.
    Type: Grant
    Filed: March 7, 2008
    Date of Patent: February 4, 2014
    Assignee: Infineum International Limited
    Inventor: Russell M. Thompson
  • Patent number: 8287607
    Abstract: A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methyisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: October 16, 2012
    Inventors: Robert Wilfred Carroll, Noel Carroll, William F. Carroll, Michael Carroll
  • Patent number: 7862628
    Abstract: A hydrocarbonaceous fuel additive, fuel composition, and method all lower both carbon particulate emissions and improve slag properties in combustion systems including, for instance, utility furnaces and boiler systems. The mixed metal catalyst may include a transition metal-containing compound, an alkali metal compound, and a magnesium-containing compound.
    Type: Grant
    Filed: August 14, 2007
    Date of Patent: January 4, 2011
    Assignee: Ethyl Petroleum Additives, Inc.
    Inventors: Stephen A. Factor, Joseph W. Roos, Allen A. Aradi
  • Patent number: 7572303
    Abstract: A fuel composition of the present invention exhibits minimized hydrolysis and increased fuel stability, even after extended storage at 65° F. for 6-9 months. The composition, which is preferably not strongly alkaline (3.0 to 10.5), is more preferably weakly alkaline to mildly acidic (4.5 to 8.5) and most preferably slightly acidic (6.3 to 6.8), includes a lower dialkyl carbonate, a combustion improving amount of at least one high heating combustible compound containing at least one element selected from the group consisting of aluminum, boron, bromine, bismuth, beryllium, calcium, cesium, chromium, cobalt, copper, francium, gallium, germanium, iodine, iron, indium, lithium, magnesium, manganese, molybdenum, nickel, niobium, nitrogen, phosphorus, potassium, palladium, rubidium, sodium, tin, zinc, praseodymium, rhenium, silicon, vanadium, or mixture, and a hydrocarbon base fuel.
    Type: Grant
    Filed: November 24, 2003
    Date of Patent: August 11, 2009
    Assignee: Octane International, Ltd.
    Inventor: William C. Orr
  • Patent number: 7553343
    Abstract: Deposits and soot formation in a direct injection gasoline engine are reduced by providing as fuel for the operation of said direct injection engine a fuel composition comprising a fuel-soluble cyclopentadienyl manganese tricarbonyl compound.
    Type: Grant
    Filed: December 12, 2000
    Date of Patent: June 30, 2009
    Assignee: Afton Chemical Intangibles, LLC
    Inventors: Allen A. Aradi, Joseph W. Roos, Herbert M. Scull, Michael W. Meffert
  • Patent number: 7410514
    Abstract: The invention relates to a liquid fuel composition of: 10-80 vol % of a first component which includes at least two aliphatic organic non-hydrocarbon compounds; 20-65 vol % of a second component including at least one hydrocarbon and having an aromatic content of less than 15 vol % of the total of the second component; 1-35 vol % of a third component, which includes an oxygenate; and 0.01 to 20 vol % water, wherein at least one compound in the fuel composition is miscible with both water and hydrocarbons to provide a single phase composition. Such fuels have been found to reduce undesirable emissions in the exhaust gases and enable the use of recycled compounds and water in the fuel.
    Type: Grant
    Filed: December 5, 2002
    Date of Patent: August 12, 2008
    Inventor: Greg Binions
  • Patent number: 7276094
    Abstract: A hydrocarbonaceous fuel additive, fuel composition, and method all lower both carbon particulate emissions and improve slag properties in combustion systems including, for instance, utility furnaces and boiler systems. The mixed metal catalyst may include a transition metal-containing compound, an alkali metal compound, and a magnesium-containing compound.
    Type: Grant
    Filed: November 25, 2003
    Date of Patent: October 2, 2007
    Assignee: Ethyl Petroleum Additives, Inc.
    Inventors: Stephen A. Factor, Joseph W. Roos, Allen A. Aradi
  • Patent number: 7041738
    Abstract: The present invention provides an additive for improving the cold flow properties of vegetable or animal fuel oil. The additive comprises A) a copolymer of ethylene and 8–21 mol % of at least one acrylic or vinyl ester having a C1–C18-alkyl radical and B) a comb polymer of at least one C8–C16-alkyl ester of an ethylenically unsaturated dicarboxylic acid and at least one C10–C20-olefin, wherein the sum Q Q = ? i ? w 1 ? i · n 1 ? i + ? j ? w 2 ? j · n 2 ? j ?of the molar averages of the carbon chain distributions in the alkyl side chains of the olefins (monomer 1) and the fatty alcohols (monomer 2) is from 23 to 27. In Q, w1 and w2 are the molar proportions of the individual chain lengths in the comb polymer from the different monomers 1 and 2, and n1 and n2 are the side chain carbon atom lengths, excluding comb polymer bonded carbon atoms of monomer 1, and the running variables i and j are the individual side chain lengths in the particular monomer groups.
    Type: Grant
    Filed: June 11, 2003
    Date of Patent: May 9, 2006
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Bettina Siggelkow, Martina Hess, Ulrike Neuhaus
  • Publication number: 20040237384
    Abstract: A fuel composition of the present invention exhibits minimized hydrolysis and increased fuel stability, even after extended storage at 65° F. for 6-9 months. The composition, which is preferably not strongly alkaline (3.0 to 10.5), is more preferably weakly alkaline to mildly acidic (4.5 to 8.5) and most preferably slightly acidic (6.3 to 6.8), includes a lower dialkyl carbonate, a combustion improving amount of at least one high heating combustible compound containing at least one element selected from the group consisting of aluminum, boron, bromine, bismuth, beryllium, calcium, cesium, chromium, cobalt, copper, francium, gallium, germanium, iodine, iron, indium, lithium, magnesium, manganese, molybdenum, nickel, niobium, nitrogen, phosphorus, potassium, palladium, rubidium, sodium, tin, zinc, praseodymium, rhenium, silicon, vanadium, or mixture, and a hydrocarbon base fuel.
    Type: Application
    Filed: November 24, 2003
    Publication date: December 2, 2004
    Inventor: William C. Orr
  • Publication number: 20040118032
    Abstract: The present invention relates to the reduction or inhibition of corrosion in an atmospheric burner unit by adding to a combustion system an effective amount of manganese, or a manganese precursor source, or derivative. The system may further include a catalyst package that may be composed of one or more individual organometallic compounds of Li, Na, K, Mg, Ca, Sr, Ba, Mo, Fe, Co, Pt, Ce, and combinations, mixtures or precursors thereof. The manganese component of the catalyst package of the present invention reduces or eliminates the poisoning of the combustion system, whereby improved combustion and reduced emissions result. In addition, this invention inhibits both high- and low-temperature corrosion that occurs on the hot surfaces of burner furnace walls and tubes, and on cooler surfaces of the burner unit exhaust stack.
    Type: Application
    Filed: December 18, 2002
    Publication date: June 24, 2004
    Inventors: Allen A. Aradi, Michael Wayne Adams, Stephen Alan Factor
  • Publication number: 20040107634
    Abstract: The invention relates to a liquid fuel composition comprising: 10-80 vol % of a first component comprising at least two aliphatic organic non-hydrocarbon compounds; 20-65 vol % of a second component comprising at least one hydrocarbon and having an aromatic content of less than 15 vol % of the total of the second component; 1-35 vol % of a third component, which comprises an oxygenate; and 0.01 to 20 vol % water, wherein at least one compound in the fuel composition is miscible with both water and hydrocarbons to provide a single phase composition. Such fuels have been found to reduce undesirable emissions in the exhaust gases and enable the use of recycled compounds and water in the fuel.
    Type: Application
    Filed: December 5, 2002
    Publication date: June 10, 2004
    Inventor: Greg Binions
  • Patent number: 6652608
    Abstract: A fuel composition of the present invention exhibits minimized hydrolysis and increased fuel stability, even after extended storage at 65° F. for 6-9 months. The composition, which is preferably not strongly alkaline (3.0 to 10.5), is more preferably weakly alkaline to mildly acidic (4.5 to 8.5) and most preferably slightly acidic (6.3 to 6.8), includes a lower dialkyl carbonate, a combustion improving amount of at least one high heating combustible compound containing at least one element selected from the group consisting of aluminum, boron, bromine, bismuth, beryllium, calcium, cesium, chromium, cobalt, copper, francium, gallium, germanium, iodine, iron, indium, lithium, magnesium, manganese, molybdenum, nickel, niobium, nitrogen, phosphorus, potassium, palladium, rubidium, sodium, tin, zinc, praseodymium, rhenium, silicon, vanadium, or mixture, and a hydrocarbon base fuel.
    Type: Grant
    Filed: December 8, 1997
    Date of Patent: November 25, 2003
    Inventor: William C. Orr
  • Patent number: 5944858
    Abstract: Hydrocarbonaceous fuels and additive compositions therefor which comprise: a) one or more fuel-soluble manganese carbonyl compounds; and b) one or more fuel-soluble alkali or alkaline earth metal-containing neutral or basic detergent salts. These compositions preferably contain, in addition to components a) and b) above, one or more of the following: c) one or more fuel-soluble ashless dispersants; d) at least one fuel-soluble demulsifying agent; e) at least one aliphatic or cycloaliphatic amine; and f) at least one metal deactivator. The compositions possess improved combustion characteristics (e.g., formation of less soot, smoke, carbonaceous products and/or noxious emissions), and form on combustion carbonaceous products of reduced acidity. The deposition of sludge on critical engine or burner parts or surfaces is reduced and the fuels have improved stability and demulsibility characteristics. And the fuel compositions can result in decreased fuel consumption in diesel engines.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: August 31, 1999
    Assignee: Ethyl Petroleum Additives, Ltd.
    Inventor: Graeme McRobert Wallace
  • Patent number: 5599357
    Abstract: Methods and compositions for reducing toxic compounds emissions and the maximum reactivity of exhaust products emitted by spark-ignition internal combustion engines. Gasoline having a minimum target octane number is formed by blending together base fuel blending components and at least one cyclopentadienyl manganese tricarbonyl compound in an amount equivalent to up to about 0.03 gram of manganese per gallon.
    Type: Grant
    Filed: May 4, 1995
    Date of Patent: February 4, 1997
    Assignee: Ehtyl Corporation
    Inventor: Thomas A. Leeper
  • Patent number: 5551957
    Abstract: The combination of a fuel-soluble succinimide detergent/dispersant, a fuel-soluble liquid carrier or induction aid therefor, and a fuel-soluble cyclopentadienyl manganese tricarbonyl compound can sharply reduce the formation or accumulation of engine deposits such as intake valve deposits in internal combustion engines. In fact, such compositions can function synergistically whereby the effectiveness of a highly effective succinimide-based deposit control additive can be improved by the addition thereto of the manganese compound, the latter not known to be a substance that reduces deposits.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: September 3, 1996
    Assignee: Ethyl Corporation
    Inventors: Lawrence J. Cunningham, Don P. Hollrah, Alexander M. Kulinowski
  • Patent number: 5515280
    Abstract: With an electronic control device for an internal combustion engine using an oxygenated compound mixed fuel, operating conditions of the engine are detected, and are utilized to determine fundamental control data for the engine, while the dielectric constant and the refractive index of an oxygenated compound mixed fuel supplied to the engine are detected, and the oxygenated compound content of the mixed fuel is calculated according to the dielectric constant thus detected. The refractive index, and the oxygenated compound content are utilized to estimate the distillation characteristic of the petroleum refined fuel in the mixed fuel. The fundamental control data are corrected by using first correction data determined from the oxygenated compound content and second correction data determined from the distillation characteristic.
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: May 7, 1996
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventor: Hiroyoshi Suzuki