Heavy Metal Or Aluminum Sulfonate Salt Or Complex Patents (Class 44/365)
  • Patent number: 12031099
    Abstract: An additive composition for a marine fuel or a heating oil comprising a stabilized colloidal dispersion of catalytic metal particles, a neutral or overbased alkaline earth metal detergent and a carrier fluid miscible with a marine fuel oil, a heavy fuel oil, a marine distillate fuel, and/or a residual fuel oil. Also provided are marine fuel and/or heating oil compositions having the additive composition described above and associated methods and uses.
    Type: Grant
    Filed: November 4, 2022
    Date of Patent: July 9, 2024
    Assignee: Infineum International Limited
    Inventors: Andrea Pastorino, Charlotte Carlisle, Amy J. Challinor
  • Patent number: 11685871
    Abstract: The present disclosure relates to a method of reducing regeneration frequency of a diesel particulate filter in a vehicle combusting diesel fuel. The method includes combusting a diesel fuel in a vehicle engine having a diesel particulate filter and wherein the diesel particulate filter requires regeneration thereof. The diesel fuel has less than about 50 ppmw of sulfur and one or more select additives to reduce a measured frequency of regeneration of the diesel particulate filter.
    Type: Grant
    Filed: April 25, 2022
    Date of Patent: June 27, 2023
    Assignee: Afton Chemical Corporation
    Inventors: Julienne Galante-Fox, Timothy J. Whalen, Daniel Taylor
  • Publication number: 20140000156
    Abstract: Provided in a fuel additive for heavy oil, made using a composition comprising: an oil-soluble metallic compound containing any one metal selected from calcium, barium, manganese, and iron; alcohol; hydrotreated light distillate; paraffin (kerosene); mineral oil; and a nonionic surfactant. The fuel additive for heavy oil, when added in a small amount to a heavy oil, can lower the kinematic viscosity and the flash point of the heavy oil, minimize the occurrence of a residual carbon fraction, dust, a sulfur fraction, or the like, increase the caloric value of the heavy oil, and improve the combustion efficiency during the combustion of the heavy oil.
    Type: Application
    Filed: March 2, 2012
    Publication date: January 2, 2014
    Inventor: Young Seo Lee
  • Patent number: 8287607
    Abstract: A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methyisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: October 16, 2012
    Inventors: Robert Wilfred Carroll, Noel Carroll, William F. Carroll, Michael Carroll
  • Patent number: 8211190
    Abstract: This invention relates to fuel oil, especially middle distillate fuel oil, compositions comprising middle distillate fuel oil and incorporated therein an incorporated therein an additive composition comprising (a) at least one fuel-soluble or fuel-dispersible neutral alkaline earth metal compound and/or at least one fuel-soluble or fuel-dispersible neutral alkali metal compound, and (b) at least one fuel-soluble or fuel-dispersible transition metal compound, characterized in that the fuel oil composition contains at most 0.05 mass % of sulfur, the total metal content derived from (a) and (b) in the fuel oil composition is at most 50 ppm by mass, and the mass proportion of (a) to (b), based on metal content, is in the range of from 1:99 to 99:1.
    Type: Grant
    Filed: April 20, 2005
    Date of Patent: July 3, 2012
    Assignee: Infineum International Limited
    Inventors: Rinaldo Caprotti, Brid Dilworth, Carlo S. Fava, Philip Collier
  • Patent number: 8147568
    Abstract: A diesel fuel composition containing metallic additives that are stabilized against phase separation. The diesel fuel contains a colloidally dispersed or solubilized metal catalyst compound, which can be used for diesel particulate trap regeneration and, as a stabilizer, 5-1,000 ppm (weight) of an oil-soluble or oil-dispersible organic compound having a lipophilic hydrocarbyl chain having attached directly thereto at least two contiguous polar head functional groups, i.e., the functional groups are separated by no more than three carbon atoms. The diesel fuel composition is particularly suitable for use with diesel engines fitted with a particulate trap for emissions control.
    Type: Grant
    Filed: September 1, 2004
    Date of Patent: April 3, 2012
    Assignee: Infineum International Limited
    Inventors: Rinaldo Caprotti, Russell M. Thompson
  • Patent number: 7524338
    Abstract: An additive composition for fuels such as diesel oil and fuel oil, used respectively for diesel engines and boilers of various types, containing a metal oxidation catalyst, in which the metal is iron, cerium, calcium, or their binary or ternary mixtures, an organic nitrate and a dispersing agent. The additive composition is able to reduce the formation of particulate emitted by diesel engines and boilers.
    Type: Grant
    Filed: August 1, 2001
    Date of Patent: April 28, 2009
    Inventor: Cesare Pedrazzini
  • Patent number: 7524340
    Abstract: A catalyst and method for improving combustion efficiency in boilers, engines, and other equipment by adding to fossil and other fuels a fuel additive that contains an oil-soluble iron compound and an over-based magnesium compound and for which the median particle size of the additive is less than about 0.01 micrometers.
    Type: Grant
    Filed: April 28, 2003
    Date of Patent: April 28, 2009
    Inventor: Walter R. May
  • Patent number: 7503944
    Abstract: A method of improving the combustion of a fuel by adding a catalyst or combustion enhancer at an extremely low concentration, preferably in the range of 1 part catalyst per 200 million parts fuel to 1 part catalyst per 6 trillion parts fuel. The catalyst or combustion enhancer may be selected from a wide range of soluble compounds. The method may comprise the steps of an initial mixing of the catalyst or enhancer with a suitable solvent and then subsequent dilution steps using solvents or fuel. Suitable solvents include water, MTBE, methylketone, methylisobutylketone, butanol, isopropyl alcohol and other hydrophilic/oleophilic compounds.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: March 17, 2009
    Inventors: Robert W. Carroll, Noel Carroll, William F. Carroll, Michael Carroll
  • Patent number: 7332001
    Abstract: A method of enhancing the operation of diesel fuel combustion systems in a combustion system includes supplying a fuel and additive that includes a manganese compound to a diesel fuel combustion system. The fuel is then combusted in the combustion chamber to produce at least one byproduct including the manganese compound. The manganese compound is supplied in an amount effective to complex with the combustion byproduct. The diesel fuel combustion system operation is enhanced by improving the attributes of lubricating oil loaded with the combustion byproduct soot particles.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: February 19, 2008
    Assignee: Afton Chemical Corporation
    Inventors: Gregory H. Guinther, Mark T. Devlin, Joseph W. Roos, David M. Human
  • Patent number: 7306634
    Abstract: A fuel additive iron salt composition effective in improving the operation of diesel engine particulate traps when added to a diesel fuel so as to provide 1-25 ppm iron in the fuel which comprises an oil soluble or oil dispersible neutral or overbased iron salt of an acidic organic compound, 50-99 mole % of the total iron present in the composition being in the ferric form, the balance being the ferrous form.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: December 11, 2007
    Assignee: Infineum International Limited
    Inventors: Rinaldo Caprotti, Robert J. Pilling
  • Publication number: 20040211112
    Abstract: A fuel composition, and a method and an apparatus for combusting it in a two-stroke engine, in which molybdenum introduced from the fuel will interact with alkaline earth metal originating from a detergent or other co-ingredient of the fuel in the combustion products to increase detergency without increasing the level of alkaline earth metal or compounds present in the fuel or combustion products thereof. In this manner, the engine operates more cleanly and efficiently without increasing the risk of harmful alkaline earth materials and compounds thereof blocking and poisoning catalysts, sensors and/or automotive on-board diagnostic devices, and it can lead to improved durability of exhaust after treatment systems.
    Type: Application
    Filed: March 29, 2004
    Publication date: October 28, 2004
    Inventors: Nicholas P. Clague, Michael A. Haynes, Peter Growcott
  • Publication number: 20040118032
    Abstract: The present invention relates to the reduction or inhibition of corrosion in an atmospheric burner unit by adding to a combustion system an effective amount of manganese, or a manganese precursor source, or derivative. The system may further include a catalyst package that may be composed of one or more individual organometallic compounds of Li, Na, K, Mg, Ca, Sr, Ba, Mo, Fe, Co, Pt, Ce, and combinations, mixtures or precursors thereof. The manganese component of the catalyst package of the present invention reduces or eliminates the poisoning of the combustion system, whereby improved combustion and reduced emissions result. In addition, this invention inhibits both high- and low-temperature corrosion that occurs on the hot surfaces of burner furnace walls and tubes, and on cooler surfaces of the burner unit exhaust stack.
    Type: Application
    Filed: December 18, 2002
    Publication date: June 24, 2004
    Inventors: Allen A. Aradi, Michael Wayne Adams, Stephen Alan Factor
  • Publication number: 20040074140
    Abstract: A method of enhancing the operation of an emission after treatment system in a combustion system includes supplying a fuel and additive that includes a manganese compound to a combustion system. The fuel is then combusted in the combustion chamber to produce at least one byproduct including the manganese compound. The manganese compound is supplied in an amount effective to complex with the combustion byproduct. The combustion system may include a catalyzed, or alternatively, a continuously regenerating technology, diesel particulate filter.
    Type: Application
    Filed: October 16, 2002
    Publication date: April 22, 2004
    Inventors: Gregory H. Guinther, Joseph W. Roos, David M. Human, Scott D. Schwab
  • Publication number: 20040035045
    Abstract: A fuels additive metallic salt composition effective in improving the operation of diesel engine particulate traps when added to a diesel fuel so as to provide 1-25 ppm metal in the fuel which comprises an oil soluble or oil dispersible overbased metal salt of an acidic organic compound, said salt composition containing 5-85 wt. % of a stoichiometric excess of metal over that required to neutralize the anionic portion of the salt, the metal being selected from the group consisting of Ca, Fe, Mg, Sr, Na, Ti, Zr, Mn, Zn and Ce.
    Type: Application
    Filed: May 19, 2003
    Publication date: February 26, 2004
    Inventors: Rinaldo Caprotti, Robert J. Pilling
  • Publication number: 20040031192
    Abstract: An additive for fuels such as diesel oil and fuel oil, used respectively for diesel engines and boilers of various types, is described, comprising a metal oxidation catalyst, an organic nitrate and a dispersing agent in suitable ratios, able to improve combustion efficiency in such a way as to reduce the formation of particulate by as much as 90%.
    Type: Application
    Filed: May 22, 2003
    Publication date: February 19, 2004
    Inventor: Cesare Pedrazzini
  • Patent number: 6652608
    Abstract: A fuel composition of the present invention exhibits minimized hydrolysis and increased fuel stability, even after extended storage at 65° F. for 6-9 months. The composition, which is preferably not strongly alkaline (3.0 to 10.5), is more preferably weakly alkaline to mildly acidic (4.5 to 8.5) and most preferably slightly acidic (6.3 to 6.8), includes a lower dialkyl carbonate, a combustion improving amount of at least one high heating combustible compound containing at least one element selected from the group consisting of aluminum, boron, bromine, bismuth, beryllium, calcium, cesium, chromium, cobalt, copper, francium, gallium, germanium, iodine, iron, indium, lithium, magnesium, manganese, molybdenum, nickel, niobium, nitrogen, phosphorus, potassium, palladium, rubidium, sodium, tin, zinc, praseodymium, rhenium, silicon, vanadium, or mixture, and a hydrocarbon base fuel.
    Type: Grant
    Filed: December 8, 1997
    Date of Patent: November 25, 2003
    Inventor: William C. Orr
  • Publication number: 20030196371
    Abstract: A method of reducing smoke and particulate emissions from an exhaust gas from a spark-ignited reciprocating engine by adding a fuel additive which contains an oil-soluble iron compound and an over-based magnesium compound to liquid petroleum fuel.
    Type: Application
    Filed: April 17, 2003
    Publication date: October 23, 2003
    Inventor: Walter R. May
  • Publication number: 20030192232
    Abstract: A catalyst and method for improving combustion efficiency in boilers, engines, and other equipment by adding to fossil and other fuels a fuel additive that contains an oil-soluble iron compound and an over-based magnesium compound and for which the median particle size of the additive is less than about 0.01 micrometers.
    Type: Application
    Filed: April 28, 2003
    Publication date: October 16, 2003
    Inventor: Walter R. May
  • Publication number: 20030182848
    Abstract: A diesel fuel composition which improves the performance of diesel engine particulate exhaust traps comprising a diesel fuel containing a combination of 1-25 ppm of metal in the form of a metal salt additive and 100 to 500 ppm of an oil soluble nitrogen containing ashless detergent additive.
    Type: Application
    Filed: March 10, 2003
    Publication date: October 2, 2003
    Inventors: Philip E. Collier, Rinaldo Caprotti
  • Patent number: 6488725
    Abstract: The present invention relates to the use of fuel additives in the regeneration of particulate filter traps, e.g. diesel particulate filter traps. The invention further relates to fuel additives suitable for use in such a process.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: December 3, 2002
    Assignee: The Associated Octel Company Limited
    Inventors: Matthew William Vincent, Paul Joseph Richards, Stephen Leonard Cook
  • Patent number: 6096104
    Abstract: Compositions including at least three metals (M1, M2, M3) are disclosed. The first metal (M1) is at least one metal selected from the iron group or the manganese group, and is preferably selected from iron, manganese, cobalt and nickel. The second metal (M2) is at least one metal selected from the rare earth group and is preferably selected from cerium, lanthanum, neodymium and praseodymiium. The third metal (M3) is selected from the group of alkaline or alkaline-earth metals, and is preferably selected from barium, strontium, calcium and lithium. The weight ratio (R) of metal (M3) to metal (M2) is greater than 0.15, and preferably greater than 1.5.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: August 1, 2000
    Assignees: Total Raffinage Distribution S.A., Gamlen Industries S.A.
    Inventors: Corinne Van den Neste, Jean Peyrot, Guy Brisset, Gerard Briard
  • Patent number: 6056792
    Abstract: A process of improving the oxidation of carbonaceous products derived from the combustion of fuel and improving combustion of a fuel is described. The process comprises adding to the fuel before combustion thereof a composition comprising at least an organo-metallic complex of a Group I or Group II metal characterized in that the concentration of the complex in the fuel before combustion is 30 ppm or less.
    Type: Grant
    Filed: February 13, 1998
    Date of Patent: May 2, 2000
    Assignee: The Associated Octel Company Limited
    Inventors: Donald Barr, Stephen L. Cook, Paul J. Richards, Maurice W. Rush