Abstract: A golf ball comprising a core and a cover, the core consisting of: a solid inner core layer formed from a first unfoamed thermoplastic composition TP1 and having a diameter of 1.10 inch or less and a center Shore C hardness (Hcenter) of 50 or less, one or more optional intermediate core layers, and an outer core layer formed from a second thermoplastic composition TP2 and having a thickness of 0.200 inches or greater and an outer surface Shore C hardness (Houter surface) of 70 or greater, wherein Houter surface>Hcenter, and Houter surface?Hcenter?40.

Abstract: A golf ball comprising a core and a cover, wherein the core consists of: a solid inner core layer formed from an unfoamed thermoplastic composition and having a diameter of 1.10 inch or less and a center Shore C hardness (Hcenter) of 50 or less, one or more optional intermediate core layers, and an outer core layer formed from an unfoamed thermoset composition and having a thickness of 0.200 inches or greater and an outer surface Shore C hardness (Houter surface) of 70 or greater, wherein Houter surface>Hcenter, and Houter surface?Hcenter?40.

Abstract: A method of recycling a multi-material inner part of a golf ball includes a variety of steps. The inner part and cover are separated from one another. The inner part is pulverized into pieces. The pieces are placed in a liquid to separate the pieces of one material from the pieces of the other materials. A ball designed for use in such a system is also disclosed.

Abstract: A rebound resilient golf ball having one or more core layers, a cover surrounding the core layer or layers, and optionally a mantle layer positioned between the cover and the core layer or layers. At least one of the layers of the golf ball includes a material whose resilience increases as the hardness of the material increases.

Abstract: Golf balls comprising a multi-layer core and a single-, dual-, or multi-layer cover are disclosed. The multi-layer core comprises a thermoplastic center and a thermoplastic outer core layer that are both soft relative to a hard, thermoset intermediate core layer.

Abstract: Multi-layer golf balls having a hard, high compression center, a relatively soft intermediate layer, and a stiff outer cover layer, are provided. The outer surface hardness of the intermediate layer is less than that of both the center and the outer cover layer.

Abstract: Golf balls consisting of a multi-layer core and a cover are disclosed. The multi-layer core comprises at least one intermediate core layer formed from a thermoset composition other than diene rubber.

Abstract: The present invention generally relates to golf balls and more particularly to golf balls having multi-layered cores comprising a thermoset rubber center, a thermoplastic intermediate core layer, and a thermoset rubber outer core layer. A cover layer is disposed about the multi-layered core. At least one of the center, intermediate core layer, and outer core layer comprises a polyalkenamer rubber. The polyalkenamer rubber may be blended with other rubbers such as polybutadiene, polyisoprene, ethylene propylene diene, and styrene-butadiene rubbers. The polyalkenamer rubber composition helps improve resiliency of the core and provides the ball with a comfortable and soft feel.

Abstract: A golf ball includes a single core formed from a substantially homogenous rubber composition, an inner cover disposed about the core, and an outer cover. The inner cover includes an ionomeric material and has a hardness of about 60 Shore D or greater. The outer cover layer is disposed about the inner cover layer, is formed from a castable polyurea or polyurethane, and has a material hardness of about 60 Shore D or less. The outer surface of the core has a trans content of about 12% or less and a hardness of about 71 to 88 Shore C, the geometric center of the core has a trans content of about 10% or less and a hardness of about 70 to 80 Shore C, and the core surface hardness is greater than the geometric center hardness by about 1 to 10 Shore C to define a shallow positive hardness gradient.

Abstract: A multi-layer golf ball includes a core having an outer surface, and intermediate layer surrounding the core, and a cover surrounding the intermediate layer. The intermediate layer defines a radially inward facing surface that is flush with the outer surface of the core, and the cover defines the outermost surface of ball. The outer surface of the core includes a plurality of polygonal land portions aligned on a common sphere. The outer surface of the core further defines a first plurality of annular grooves disposed about a first axis, a second plurality of annular grooves disposed about a second axis, and a third plurality of annular grooves disposed about a third axis. The first axis, the second axis, and the third axis are mutually orthogonal, and each groove respectively extends from the common sphere and is concave relative to the core.

Abstract: A multi-layer golf ball includes a core, an intermediate layer surrounding the core, and a cover layer surrounding the intermediate layer. The core defines an outer surface that includes a plurality of polygonal land potions substantially aligned on a common sphere, which has a diameter of between 22 mm and 32 mm. The intermediate layer has a radially inward-facing surface that is flush with the outer surface of the core, and has a radial thickness of between 4 mm and 9 mm. The outer surface of the core defines a first set of annular grooves disposed about a first axis, and a second set of annular grooves disposed about a second axis. Each of the first and second set of annular grooves extend radially inward from the common sphere, and the first axis and the second axis are orthogonal.

Abstract: A multi-layer golf ball includes a core, and intermediate layer, and a cover. The core has an outer surface that includes a plurality of depressions extending from a spherical land portion. Each depression has a maximum depth relative to the spherical land portion of between 0.15 mm and 2.0 mm. The intermediate layer surrounds the core and has a radially inward surface that is flush with the outer surface of the core. The cover layer surrounds the intermediate layer and defines an outermost portion of ball.

Abstract: A center of a golf ball is formed from a composition having a flexural modulus from 150-450 MPa, a maximum loss factor (tan ?) between ?20 and 0° C. of 0.08 or less, a rebound resilience of 55% or more, and a slab hardness ranging from 40-60 in Shore D hardness. The center composition includes, as a resin component, 30 to 70 mass % of (A) a modified polyester elastomer having a Shore A hardness of 95 or less; 70-30 mass % of (B) a binary ionomer resin having a Shore D hardness of 65 or more, a flexural modulus of 300 MPa or more, and a melt flow rate (190° C., 2.16 kg) of 1.0 g/10 min or more; and 0-50 mass % of (C) a thermoplastic resin other than (A) and (B) components (provided that a total content of (A), (B), and (C) components is 100 mass %).

Abstract: A golf ball comprising (a) a core; (b) at least one mantle layer adjacent to the core; (c) an inner cover layer adjacent to the mantle layer; and (d) an outer cover layer adjacent to the inner cover layer, wherein the inner cover layer has a material Shore D hardness that is at least 3 less than the material Shore D hardness of the outer cover layer, and the inner cover layer has a thickness of less than 0.050 in.

Abstract: A multi-layer golf ball includes a core, and intermediate layer, and a cover. The core has an outer surface that includes a plurality of protrusions extending from a spherical land portion. Each protrusion has a maximum height relative to the spherical land portion of between 0.15 mm and 2.0 mm. The intermediate layer surrounds the core and has a radially outward surface that is flush with the outer surface of the core. The cover layer surrounds the intermediate layer and defines an outermost portion of ball.

Abstract: A method of forming a golf ball includes forming a pair of thermoplastic hemispherical shells from an elastomer compound including an elastomer and first, second, and third free radical initiators, with the elastomer being pre-crosslinked to a first crosslinking density, then positioning a spherical component between the hemispherical shells and compression molding and curing the hemispherical shells to a second crosslinking density around the spherical component. The method uses three different crosslinking temperatures.

Abstract: Golf balls having a core comprising a polyalkenamer rubber composition are provided. The rubber composition may further include other rubbers such as, for example, polybutadiene, polyisoprene, ethylene propylene rubber, ethylene propylene diene rubber, and styrene-butadiene rubber. The rubber composition helps improve resiliency of the core and provides the ball with a comfortable and soft feel. In one version, a solid, single core having an outer surface and geometric center is provided, wherein the outer surface has a hardness greater than the hardness of the geometric center to define a positive hardness gradient of at least 10 Shore C. In a second version, a dual-core having an inner core and surrounding outer core layer is provided. The inner core has a positive hardness gradient, while the outer core has a zero; negative; or positive hardness gradient.

Abstract: A cured elastomer golf ball component is made by heating an elastomer compound containing an ethylenically unsaturated elastomer, an ethylenically unsaturated monomer, and first and second free radical initiators to a first crosslinking temperature T1 in a compression mold and partially crosslinking the elastomer, then heating to a second crosslinking temperature T2 and curing the elastomer component of the golf ball. Either: (i) the first initiator has a half-life of about 0.2-5 minutes at T1, the second initiator has a half-life of about 0.2-5 minutes at T2, and T2 is higher T1 by at least about 30° C.; or (ii) the second initiator's one-minute half-life temperature is at least about 30° C. higher than the first initiator's one-minute half-life temperature, T1 is within about 20° C. of the first initiator's one-minute half-life temperature, and T2 is within about 20° C. of the second initiator's one-minute half-life temperature.

Abstract: Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises a center and an outer core layer that are both soft relative to a hard intermediate core layer. The Shore C hardness of the outer surface of the center is preferably greater than the Shore C hardness of the geometric center of the center.

Abstract: An object of the present invention is to provide a golf ball showing a low spin rate on driver shots and a high spin rate on approach shots. The present invention provides a multi-piece golf ball comprising a center and n (n is a natural number of 3 or more) envelope layers covering the center, wherein material hardness of the envelop layers satisfies H1<H0<Hn?1; where the envelope layers formed in order from the center side are referred to as the first envelope layer, the second envelope layer, the third envelope layer, the fourth envelope layer, . . . the n?1th envelope layer and the nth envelope layer (the outmost layer), respectively and H0 is a material hardness (Shore D hardness) of the center, and H1, H2, H3, H4, . . . Hn?1 and Hn are material hardness (Shore D hardness) of the first envelope layer, the second envelope layer, the third envelope layer, the fourth envelope layer, . . .

Abstract: A golf ball includes a core and a three-layer cover disposed adjacent the core. The three-layer cover includes an inner cover, an intermediate cover, and an outer cover. The inner cover includes a non-ionomeric E/Y copolymer where E is an olefin and Y is a carboxylic acid. The inner cover has a hardness of about 45 to 68 Shore D. The outer cover includes a castable thermoset polyurethane and has a hardness of about 40 to 62 Shore D. The intermediate cover layer, disposed between the inner and outer cover layers, is formed from a polyamide composition, where the polyamide composition includes a transparent polyamide having a light transmission of about 50% or greater.

Abstract: Multi-layered golf balls containing a two or three-layered core assembly are provided. In one embodiment, the core assembly includes an inner core (center) comprising a thermoset composition, an intermediate core layer; and surrounding outer core layer. Preferably, the thermoplastic composition comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. A second thermoset composition such as polybutadiene rubber may be used to form the outer core layer. The core layers have different hardness levels. In another embodiment, a two-layered core structure is provided. For example, the inner core and/or outer core layer may be made of the plasticized thermoplastic composition. The core structure and resulting ball have relatively good resiliency at given compressions.

Abstract: Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises a zero or negative hardness gradient center that is hard relative to an intermediate core layer.

Abstract: An object of the present invention is to provide a golf ball showing a low spin rate on driver shots and a high spin rate on approach shots. The present invention provides a multi-piece golf ball comprising a center and n (n is a natural number of 3 or more) envelope layers covering the center, wherein material hardness of the envelop layers satisfies H2<H0<Hn?1; where the envelope layers formed in order from the center side are referred to as a first envelope layer, a second envelope layer, a third envelope layer, a fourth envelope layer, . . . an n?1th envelope layer and an nth envelope layer (the outmost layer), respectively and H0 is a material hardness (Shore D hardness) of the center, and H1, H2, H3, H4, . . . Hn?1 and Hn are material hardness (Shore D hardness) of the first envelope layer, the second envelope layer, the third envelope layer, the fourth envelope layer, . . .

Abstract: Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises a center and an outer core layer that are both soft relative to a hard intermediate core layer. The Shore C hardness of the outer surface of the center is preferably less than the Shore C hardness of the geometric center of the center.

Abstract: A high performance golf ball includes a resin inner core, a rubber outer core, and a cover. The resin inner core is made of a blend of highly neutralized polymers and a low flexural modulus ionomer, and may include a blend of different highly neutralized polymers. The layers of the ball have specified compression values and relationships. The cover is a single layer ionomer cover, and may be made from a blend of different grades of the ionomer. The ball as a whole has properties to maximize performance and aesthetic properties, such as backspin off the irons, feel, and sound.

Abstract: A golf ball is provided capable of having various characteristics based on having an aggregated layer core. The golf ball includes an inner core, an outer shell enclosing the inner core, and an intermediate core enclosing the inner core. The intermediate core includes sublayers thermoplastically fused together to form an aggregated intermediate core layer having overall characteristics formed as a combination of the sublayer characteristics. A method of forming a golf ball core having an aggregated layer core can include forming a first and second stack of nested cups, thermoplastically bonding each of the stacks to each other to form first and second aggregated cups, arranging the aggregated cups around a golf ball inner core, and bonding the aggregated cups to each other. In some configurations, the sublayers can include ultrathin sublayers less than 20 microns thick, and in some configurations, the sublayers can include injection molded sublayers.

Abstract: A golf ball includes an inner core layer formed from a thermoplastic material comprising a highly-neutralized ionomer comprising a copolymer of ethylene and an ?,?-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to fully-neutralize the acid groups of the copolymer by 80% or greater. The inner core has a geometric center hardness less than its surface hardness to define a positive hardness gradient. An outer core layer is formed over the inner core and is formed from a substantially homogenous thermoset composition. The outer core layer has an interior hardness substantially less than an outer surface hardness to define a steep positive hardness gradient. An inner cover layer and an outer cover layer are formed over the outer core layer.

Abstract: A high performance golf ball includes a resin inner core, a rubber outer core, and a cover. The resin inner core is made of a blend of highly neutralized polymers and a low flexural modulus ionomer, and may include a blend of different highly neutralized polymers. The inner core has a specified range of coefficients of restitution when measured at different velocities. The cover is a single layer ionomer cover, and may be made from a blend of different grades of the ionomer. The ball as a whole has properties to maximize performance and aesthetic properties, such as backspin off the irons, feel, and sound.

Abstract: A high performance golf ball includes a resin inner core, a rubber outer core, and a cover. The resin inner core is made of a blend of highly neutralized polymers and a low flexural modulus ionomer, and may include a blend of different highly neutralized polymers. The inner core and cover layer each has a specified hardness with a hardness relationship. The cover is a single layer ionomer cover, and may be made from a blend of different grades of the ionomer. The ball as a whole has properties to maximize performance and aesthetic properties, such as backspin off the irons, feel, and sound.

Abstract: Embodiments of the disclosed polymer composition comprise a first unsaturated polymer or polymer precursor, and an effective amount of a peptizer. The peptizer typically comprises a heteroaryl or a heterocyclic compound, other than morpholine as disclosed in assignee's prior applications. Disclosed polymer compositions are useful for making sports equipment, such as at least one layer of a golf ball, often a core. Because the compositions are useful for making golf balls, materials commonly known for making such golf balls can be used in combination with the polymer composition. A method for forming a golf ball also is disclosed. The method comprises providing disclosed compositions and then forming at least one component of a golf using the composition.

Abstract: The present invention is directed to golf balls having a diameter of greater than 1.68 inches and including at least one layer formed from an HNP composition.

Abstract: A multi-piece solid golf ball having a core, an envelope layer, an intermediate layer and a cover. The core is formed primarily of a thermoplastic resin and has a diameter of from 20 to 30 mm, the envelope layer is formed of a rubber composition containing primarily a rubber material and has a thickness of from 3 to 10 mm, the intermediate layer is formed of a resin composition containing primarily an ionomer, and the cover is formed of a resin composition containing primarily a urethane. Both the relationship among the specific gravities of the core, the envelope layer and the intermediate layer, and the relationship among the surface hardnesses of the core, the envelope layer, the intermediate layer and the cover are optimized.

Abstract: A high performance golf ball includes a resin inner core, a rubber outer core, and a cover. The resin inner core is made of a blend of highly neutralized polymers and a low flexural modulus ionomer, and may include a blend of different highly neutralized polymers. The inner core has a specified specific gravity. The cover is a single layer ionomer cover, and may be made from a blend of different grades of the ionomer. The ball as a whole has properties to maximize performance and aesthetic properties, such as backspin off the irons, feel, and sound.

Abstract: A thermoplastic multi-layer golf ball has a core center including a first thermoplastic material and having a diameter of from about 7 mm to about 20 mm and a surface Shore D hardness H1 of from about 30 to about 48; a core layer outward from the core center, the core layer including a second thermoplastic material and having a diameter of from about 25 mm to about 40 mm, a thickness of from about 7 mm to about 10 mm, a surface Shore D hardness H2 that is greater than H1, and a 10-130 kg compression deformation of from about 2.6 mm to about 3.2 mm; an inner cover layer outward from the core layer, the inner cover layer including a third thermoplastic material and having a surface Shore D hardness H3 of from about 55 to about 70; and an outer cover layer on the surface of the golf ball including a fourth thermoplastic material and having a surface Shore D hardness H4 of from about 44 to about 56 and a 10-130 kg compression deformation of from about 2.3 mm to about 3.2 mm.

Abstract: A thermoplastic multi-layer golf ball has a thermoplastic core center, a thermoplastic core layer, and an inner cover layer and outer cover layer each including a thermoplastic polyurethane. The core center has a diameter of about 5-20 mm and a first flexural modulus of ?about 8,000 psi. The core layer has a diameter of about 28-40 mm, a thickness of about 4-10 mm, a second flexural modulus of ?about 15,000 psi and greater than the first flexural modulus, a 10-130 kg compression deformation of about 2.6-4.0 mm, and a surface hardness greater than the core center's surface hardness. The outer cover layer has a 10-130 kg compression deformation of about 2.3-3.2 mm and a surface hardness that is less than that of the inner cover layer. The difference between the core center's specific gravity and the core layer's specific gravity is ?about 0.1 g/cm3.

Abstract: Golf balls containing a core having at least two layers made from a polyalkenamer rubber composition are provided. At least one layer is made from a relatively low modulus polyalkenamer rubber composition and at least one layer is made from a relatively high modulus polyalkenamer rubber composition. The rubber composition may further include other rubbers such as, for example, polybutadiene, polyisoprene, ethylene propylene rubber, ethylene propylene diene rubber, and styrene-butadiene rubber. The rubber composition helps improve resiliency of the core.

Abstract: An object of the present invention is to provide a golf ball which has an increased dry spin rate and wet spin rate on approach shots without sacrificing the processability into the cover. The present invention provides a golf ball cover material having shear loss moduli G1? (Pa), G2? (Pa), and G3? (Pa) that satisfy following equations when measured using a dynamic viscoelasticity measuring apparatus at following conditions. log G1??7.09??(1) log G2??7.17??(2) log G3??7.14??(3) G1? measuring conditions: shear mode, oscillation frequency: 10 Hz, temperature: 0° C., strain: 0.05%; G2? measuring conditions: shear mode, oscillation frequency: 10 Hz, temperature: ?30° C., strain: 0.05%; and G3? measuring conditions: shear mode, oscillation frequency: 10 Hz, temperature: 0° C., strain: 5%.

Abstract: A golf ball 2 includes a core 4, a mid layer 6, and a cover 8. The core 4 includes a center 10 and an envelope layer 12. The ratio (Do/De) of an amount of compressive deformation Do of the center 10 to an amount of compressive deformation De of the core 4 is equal to or greater than 1.5 but equal to or less than 2.5. The ratio (Do/Dc) of the amount of compressive deformation Do of the center 10 to an amount of compressive deformation Dc of the golf ball 2 is equal to or greater than 1.8. The diameter of the center 10 is equal to or less than 20 mm. The difference (He?Ho) between a surface hardness He of the core 4 and a central hardness Ho of the center 10 is equal to or less than 40.

Abstract: A multi-piece solid golf ball has a core, an envelope layer encasing the core, an intermediate layer encasing the envelope layer, and an outer layer which encases the envelope layer and has formed on a surface thereof a plurality of dimples. The core is made of an elastomer. The envelope layer is formed of an inner envelope layer and an outer envelope layer, and the intermediate layer is formed of an inner intermediate layer and an outer intermediate layer. Letting the average hardness of the core be expressed by the following formula: average core hardness (Shore D)=[core surface hardness (Shore D)+core center hardness (Shore D)]/2, the outer layer has a hardness (Shore D) which is higher than the average core hardness and each of the envelope layers and the intermediate layers is softer than the outer layer.

Abstract: A golf ball 2 includes a spherical core 4, a mid layer 6 outside the core 4, and a cover 8 outside the mid layer 6. The core 4 includes a spherical center 10 and an envelope layer 12 outside the center 10. At all points P included in a zone that extends over a distance range from equal to or greater than 1 mm to equal to or less than 15 mm from the central point of the core 4, the following mathematical formula is satisfied. ?5<H2?H1<5 In the mathematical formula, H1 indicates the JIS-C hardness at a point P1 located radially inward of each point P at a distance of 1 mm from the point P, and H2 indicates the JIS-C hardness at a point P2 located radially outward of each point P at a distance of 1 mm from the point P.

Abstract: A golf ball comprising a core comprising an inner core center and an outer core layer disposed over the inner core center. The inner core center has a deflection of greater than 0.210 inch under a load of 100 kilograms and the core has a deflection ranging from 0.120 inch to 0.090 inch under a load of 200 pounds. An inner mantle layer is disposed over the core, an outer mantle is disposed over the inner mantle layer, and a cover is disposed over the outer mantle.

Abstract: Golf balls consisting of a dual core and a dual cover are disclosed. The surface hardness of the outer core layer is greater than the material hardness of the inner cover layer, and is preferably 75 Shore C or greater.

Abstract: Multi-piece golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The outer core layer is preferably formed from a non-foamed thermoset composition such as polybutadiene rubber. Preferably, the specific gravity (density) of the foam inner core is less than the density of the outer core layer. The ball further includes a cover of at least one layer and may include at least one casing layer. The core structure and resulting ball have relatively good resiliency.

Abstract: Multi-piece golf balls having a solid core and cover are provided. The ball contains an inner core made of a foam composition and surrounding outer core layer. Preferably, foamed polyurethane is used to form the inner core and polybutadiene rubber is used to make the outer core. The specific gravity (density) of the inner core is preferably less than the density of the outer core. The outer surface of the inner core preferably has a non-uniform structure and includes projecting members. The ball preferably has a high Moment of Inertia (MOI). The ball includes a single or multi-layered cover surrounding the core structure.

Abstract: Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises a zero or positive hardness gradient center that is hard relative to an intermediate core layer. The overall core preferably has a zero hardness gradient, a negative hardness gradient, or a positive hardness gradient of up to 20 Shore C units.

Abstract: A golf ball is formed including a core and a cover. The cover includes a thermoplastic inner cover layer and having a hardness between 55 and 60 Shore D, an outer cover layer having a hardness between 55 and 60 Shore D, and a non-ionomeric thermosetting polyurethane or polyurea intermediate cover layer disposed between the inner and outer cover layers. The intermediate cover layer has a hardness greater than the inner cover layer hardness and the outer cover layer hardness. The inner cover is formed from a partially- or fully-neutralized ionomer and the outer cover layer is formed from a polyurethane, a polyurea, or a urethane-urea blend.

Abstract: Multi-layered golf ball core sub-assemblies and the resulting golf balls are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The intermediate and outer core layers are preferably formed from non-foamed thermoset compositions such as polybutadiene rubber. The core layers have different hardness and specific gravity levels. The core structure and resulting ball have relatively good resiliency.

Abstract: Multi-layered golf ball core sub-assemblies and the resulting golf balls are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The intermediate and outer core layers are preferably formed from non-foamed thermoset compositions such as polybutadiene rubber. The core layers have different hardness and specific gravity levels. The core assembly preferably has a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency.

Abstract: A golf ball includes four layers. The first, third, and fourth layers are made from thermoplastic materials and the second is made of a thermoset material. The third layer is the hardest and is at least 10 Shore D harder than the fourth layer. The flexural modulus of the third layer is greater than that of the first layer, and the flexural modulus of the first layer is greater than that of the fourth layer.