Diverse Cover And Interior Patents (Class 473/377)
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Patent number: 6729975Abstract: A method of manufacturing a golf ball is disclosed. A cover is molded through use of either a thermoplastic resin having a group capable of reacting with an isocyanate group or a thermoplastic resin containing a compound having two or more groups capable of reacting with an isocyanate group. Subsequently, a polyisocyanate compound is caused to permeate into the surface layer of the cover to thereby cause the reaction between the polyisocyanate compound and the group(s) capable of reacting with the isocyanate group. As a result, a modified layer having excellent properties is formed at the surface of the cover formed from thermoplastic resin. In this case, a non-yellowing polyurethane resin is preferably used as the thermoplastic resin having a group capable of reacting with an isocyanate group, and 4,4-diphenylmethane diisocyanate (MDI) is preferably used as the polyisocyanate compound.Type: GrantFiled: May 3, 2002Date of Patent: May 4, 2004Assignee: Bridgestone Sports Co., Ltd.Inventors: Michio Inoue, Keisuke Ihara, Hirotaka Shimosaka, Yutaka Masutani, Atsuki Kasashima
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Patent number: 6723008Abstract: In a multi-piece solid golf ball comprising a solid core and a cover of two inner and outer layers enclosing the solid core, the solid core has a deflection of at least 1.Type: GrantFiled: July 18, 2001Date of Patent: April 20, 2004Assignee: Bridgestone Sports Co., Ltd.Inventors: Hiroshi Higuchi, Hirotaka Shimosaka, Yasushi Ichikawa, Rinya Takesue
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Patent number: 6716117Abstract: In a multi-piece solid golf ball comprising a solid core and a cover consisting of inner and outer layers, the cover inner layer is composed mainly of an ionomer resin, and the cover outer layer is composed mainly of another thermoplastic elastomer. A thermoplastic resin-base adhesive layer is interposed between the cover inner and outer layers, or a thermoplastic resin-base adhesive is blended in the inner and/or outer layer cover stock.Type: GrantFiled: November 7, 2001Date of Patent: April 6, 2004Assignee: Bridgestone Sports Co., Ltd.Inventors: Yasushi Ichikawa, Shunichi Kashiwagi, Rinya Takesue
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Patent number: 6713565Abstract: It has been unexpectedly discovered that cis-1,4-polybutadiene that is synthesized utilizing Zeigler-Natta catalyst systems has superior characteristics for utilization in solid golf ball cores if the polymerization is terminated utilizing a carboxylic acid of the structural formula RCOOH, wherein R represents an alkyl group containing from 1 to about 30 carbon atoms.Type: GrantFiled: June 17, 2002Date of Patent: March 30, 2004Assignee: The Goodyear Tire & Rubber CompanyInventors: Craig William Burkhart, Michael Lester Kerns, Kenneth Floyd Castner, Michael Joseph Rachita, Michael Paul Mallamaci
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Publication number: 20040058753Abstract: A golf ball is provided which changes color or other indicia after exposure to moisture to indicate that the ball may not have predictable flight characteristics which may result in loss of carry and roll. In one embodiment, a microencapsulated dye layer is formed immediately below the final gloss coat, with controlled dye release causing a stained look to the ball after significant exposure to moisture. In another embodiment, the dye or ink is provided in pelletized form for ease of manufacture. In other embodiments, a dye, ink, or chemical is compounded with other materials and introduced into or applied onto the golf balls composite materials in a solid, liquid, or gaseous form. In still other embodiments imprints on the ball are made with a water activated ink which either appears or disappears upon the exposure of the golf ball to moisture.Type: ApplicationFiled: September 23, 2003Publication date: March 25, 2004Applicant: Performance Indicator, LLCInventor: Robert T. Winskowicz
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Publication number: 20040058751Abstract: The present invention is directed to improved cover compositions for golf ball construction and the resulting low modulus golf balls produced utilizing the improved cover compositions. The novel golf ball cover compositions of the invention comprise a blend of a relatively low amount of at least one hard ionomeric resins and a relatively large amount (i.e. from about 75 to about 85-90 percent) of at least one soft ionomer resin. When the cover compositions of the invention are utilized to manufacture golf balls, the golf balls produced thereby, exhibit properties of improved playability at low swing speeds without substantial sacrifices in durability and/or distance characteristics when compared to known hard-soft ionomer blends.Type: ApplicationFiled: September 26, 2003Publication date: March 25, 2004Applicant: Callaway Golf CompanyInventors: Michael J. Sullivan, R. Dennis Nesbitt, Terence Melvin
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Patent number: 6710114Abstract: Golf balls having a portion or layer formed from a polymeric composite that preferably includes at least two polymers with distinct microstructures. In particular, the balls can include a polybutadiene having at least about 80 percent cis-isomer polybutadiene blended with a polybutadiene having at least about 50 percent trans-isomer polybutadiene. Methods of preparing such golf balls are also recited.Type: GrantFiled: August 8, 2001Date of Patent: March 23, 2004Assignee: Acushnet CompanyInventors: Laurent C. Bissonnette, Roman D. Halko, David A. Bulpett, Michael P. Mallamaci
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Patent number: 6705958Abstract: A golf ball includes a core, and a cover made from a cover material containing an ionomer resin and also barium sulfate and titanium dioxide added in a total amount ranging from 10 to 25 parts by mass on the basis of 100 parts by mass of the ionomer resin. A flexural amount of the core, measured by applying a load of 980 N thereto, is in a range of 4.0 to 5.5 mm. A ratio of a melt-flow rate to a specific gravity (melt-flow rate/specific gravity) of the cover material is in a range of 1.6 or more. A Shore D hardness of the cover is in a range of 55 to 65.Type: GrantFiled: June 14, 2002Date of Patent: March 16, 2004Assignee: Bridgestone Sports Co., Ltd.Inventors: Junji Hayashi, Yutaka Masutani, Hisashi Yamagishi
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Patent number: 6699957Abstract: Disclosed herein is a polyurethane elastomer comprising the reaction product of: A) at least one aliphatic diisocyanate monomer; B) at least one high molecular weight polyol; C) at least one low molecular weight diol comprising an aromatic moiety; and D) at least one saturated diol curing agent. These elastomers are useful as components of golf ball covers.Type: GrantFiled: February 1, 2002Date of Patent: March 2, 2004Assignee: Uniroyal Chemical Company, Inc.Inventors: Vincent J. Gajewski, Glen C. Proctor
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Publication number: 20040038753Abstract: The present invention provides a multi-piece solid golf ball, which is superior in flight distance, spin performance and shot feel.Type: ApplicationFiled: August 22, 2003Publication date: February 26, 2004Inventor: Akira Kato
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Patent number: 6692381Abstract: The present invention provides a solid golf ball having exceptional rebound characteristics and flight performance, as well as good shot feel. The present invention relates to a solid golf ball comprising at least one layer of a core, and at least one layer of a cover formed on the core, wherein at least one of the layers of the core is formed by vulcanizing and press-molding a rubber composition comprising (a) a base rubber comprising polybutadiene rubber containing a cis-1,4-bond of not less than 99%, (b) a co-crosslinking agent, and (c) an organic peroxide.Type: GrantFiled: March 25, 2002Date of Patent: February 17, 2004Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Seigou Sakagami, Akihiro Nakahara, Satoshi Mano
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Patent number: 6688991Abstract: A long distance, low initial spin golf ball is disclosed. The golf ball includes a high moment of inertia core assembly, which may comprise a low specific gravity core and an optional intermediate layer. This sub-assembly is encased within a high specific gravity cover with Shore D hardness in the range of about 40 to about 80. The core is preferably made from a highly neutralized thermoplastic polymer with its specific gravity reduced, and the cover preferably has high specific gravity fillers dispersed therein. The cover is preferably made from thermoset polyurethane or polyurea.Type: GrantFiled: October 29, 2002Date of Patent: February 10, 2004Assignee: Acushnet CompanyInventors: Michael J. Sullivan, Derek A. Ladd
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Patent number: 6676542Abstract: The present invention provides a multi-piece solid golf ball, which is superior in flight distance, spin performance, shot feel and scuff resistance. The present invention relates to a multi-piece solid golf ball comprising a core composed of a center and an intermediate layer formed on the center, and a cover formed on the core, wherein the center has a diameter of 10 to 20 mm and a central point hardness in JIS-A hardness of 30 to 90, the intermediate layer has a surface hardness in Shore D hardness of 50 to 70 the cover comprises polyurethane-based thermoplastic elastomer as a main component, and has a hardness in Shore D hardness of 40 to 60 and a thickness of 0.3 to 1.5 mm.Type: GrantFiled: January 9, 2003Date of Patent: January 13, 2004Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Akira Kato, Keiji Moriyama
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Patent number: 6672976Abstract: A golf ball includes a core and a multi-layer cover. The golf ball satisfies the following conditions (1) to (5): (1) the number of dimples is 360 to 492; (2) total volume enclosed by the dimples as expressed as a percentage of the volume of the golf ball, VR, is 0.715% to 0.825%; (3) total surface area of the dimples as expressed as a percentage of the surface area of the golf ball, SR, is not less than 70%; (4) value obtained through subtraction of the JIS C hardness of the surface portion of the core from the average JIS C hardness of the cover is 0 to 20; and (5) initial velocity is in excess of 77.7 m/s (255 ft/s).Type: GrantFiled: May 14, 2001Date of Patent: January 6, 2004Assignee: Bridgestone Sports Co., Ltd.Inventor: Hideo Watanabe
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Patent number: 6670422Abstract: A rubber composition comprising 100 parts by weight of a base rubber containing 5-30% by weight of syndiotactic-1,2-polybutadiene and at least 40% by weight of cis-1,4-polybutadiene, 5-10 parts by weight of an unsaturated carboxylic acid metal salt, up to 2 parts by weight of an inorganic filler, and 10-30% by weight based on the weight of the metal salt of an initiator can be molded and vulcanized into a rubber product having a specific gravity of less than 1 and is suitable for the manufacture of golf balls for practice over water.Type: GrantFiled: February 4, 2002Date of Patent: December 30, 2003Assignee: Bridgestone Sports Co., Ltd.Inventors: Hiroto Sasaki, Jun Shindo
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Publication number: 20030236137Abstract: A golf ball including a core, a cover, and, optionally, an intermediate layer disposed between the core and the cover, wherein at least one of the core, cover layer, or optional intermediate layer includes at least one dendritic macromolecule.Type: ApplicationFiled: June 6, 2003Publication date: December 25, 2003Inventors: William E. Morgan, Kevin M. Harris, Murali Rajagopalan, Shenshen Wu, Manjari Kuntimaddi
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Patent number: 6663509Abstract: The present invention is directed to a golf ball comprising a dual core, a triple core, a cellular core, a liquid core, or a wound core; an inner cover layer and an outer cover layer; and at least 50 parts by weight of a non-ionomeric polyolefin material disposed in an inner layer within the ball. The dual or triple cores comprise an interior spherical center component formed from a thermoset material, a thermoplastic material, or combinations thereof; a core layer disposed about the center component, formed from a thermoset material, a thermoplastic material, or combinations thereof; and an optional outer core layer that surrounds the core component. The inner cover layer is comprised of a high acid ionomer or ionomer blend. The outer cover layer is comprised of a soft, very low modulus ionomer or ionomer blend, or a non-ionomeric thermoplastic elastomer such as polyurethane, polyester or polyesteramide.Type: GrantFiled: August 13, 2002Date of Patent: December 16, 2003Assignee: Callaway Golf CompanyInventors: R. Dennis Nesbitt, Mark L. Binette, Michael J. Sullivan
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Patent number: 6664319Abstract: A golf ball is provided that includes a molded resilient inner core made of a rubber compound and a polymeric cover surrounding the inner core. The rubber compound is a halo-butyl rubber polymer and a carbon black filler in an amount of 80% to 100% by weight of the total rubber component.Type: GrantFiled: September 26, 2001Date of Patent: December 16, 2003Assignee: Waggle Pty LTDInventors: Virendra Kumar Bahl, Steven Joseph Fisher
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Patent number: 6656060Abstract: A golf ball includes a solid core and a cover of at least one layer; wherein each of a specific gravity of the solid core and a specific gravity of the cover is nearly equal to a value (S) of a relation expression given by S=W/[(&pgr;/6)×D3], where W is a weight of the golf ball and D is a diameter of the golf ball. The golf ball can enhance the durability to increase the carry of the ball with less variations in carry of the ball.Type: GrantFiled: August 15, 2001Date of Patent: December 2, 2003Assignee: Bridgestone Sports Co., Ltd.Inventors: Yutaka Masutani, Junji Hayashi, Hisashi Yamagishi
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Patent number: 6652393Abstract: A solid golf ball comprising a core and a cover layer is characterized in that the cover layer is formed by carrying out a crosslinking reaction on a rubber composition comprising 100 parts by weight of a base rubber which is composed mainly of a mixture of (A) a polybutadiene of at least 40% cis-1,4 structure with (B) a syndiotactic 1,2-polybutadiene, (C) at least 5 parts by weight of methacrylic acid, (D) at least 5 parts by weight of a metal oxide, and (E) at least 0.1 part by weight of a polymerization initiator.Type: GrantFiled: August 16, 2002Date of Patent: November 25, 2003Assignee: Bridgestone Sports Co., Ltd.Inventor: Hideo Watanabe
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Patent number: 6648778Abstract: The present invention is directed to a golf ball comprising a soft core and a hard cover to produce a resulting golf ball having a reduced spin rate. In this regard, a core is provided and metal particles, or other heavy weight filler materials, are included in the cover compositions. This results in a golf ball exhibiting enhanced perimeter weighting. Preferably, the particles are included in a relatively thick inner cover layer (or mantle) of a solid, three-piece multi-layered golf ball. In another preferred version, one or more patterns of weighting material are incorporated in the ball, and most preferably along the outer periphery of the ball so that the pattern is visible along the ball's exterior. The size and weight of the core is reduced in order to produce an overall golf ball which meets, or is less than, the 1.62 ounce maximum weight limitation specified by the United States Golf Association.Type: GrantFiled: July 11, 2001Date of Patent: November 18, 2003Assignee: Callaway Golf CompanyInventors: Michael J. Sullivan, R. Dennis Nesbitt
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Patent number: 6648779Abstract: The golf ball has a solid core and a cover surrounding the core. The solid core is formed of a rubber composition that has a co-crosslinking agent and preferably an organic sulfur compound blended therein, with a portion of the co-crosslinking agent and the organic sulfur compound being micro-encapsulated within a thermoplastic resin, and a remaining portion of the co-crosslinking agent being in a non-encapsulated state. This improves dispersibility of the co-crosslinking agent and the organic sulfur compound within the rubber composition, and enables adjustment of the crosslinking pattern of the rubber molecule main chains. Thus, resilience and durability of the golf ball are improved.Type: GrantFiled: November 5, 2001Date of Patent: November 18, 2003Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Masatoshi Yokota
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Patent number: 6645091Abstract: A golf ball comprising a center, a cover, and optionally, at least one intermediate layer disposed between the center and the cover, wherein at least one of the cover and the at least one intermediate layer is formed with a thermoplastic polyurethane composition comprising a reaction product of at least one polyol and at least one diisocyanate, and a curing agent consisting essentially of at least one diol having the formula: HOH2CH2C(OH2CH2C)nO—X—O(CH2CH2O)mCH2CH2OH; wherein n and m, each separately have a value of 0, 1, 2, or 3, X is o-phenylene, m-phenylene, p-phenylene, 1,2-cyclohexyl, 1,3-cyclohexyl, 1,4-cyclohexyl; and mixtures a thereof.Type: GrantFiled: January 10, 2001Date of Patent: November 11, 2003Assignee: Acushnet CompanyInventors: Shenshen Wu, Murali Rajagopalan
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Patent number: 6635716Abstract: A golf ball formed of a core and a cover, wherein the core has a diameter of at least about 1.50 inches and comprises a polybutadiene rubber composition comprising at least about 2.2 parts per hundred of a halogenated organosulfur compound, and wherein the cover has a thickness of less than about 0.1 inches and comprises a polyurethane composition.Type: GrantFiled: September 13, 2001Date of Patent: October 21, 2003Assignee: Acushnet CompanyInventors: Peter R. Voorheis, Murali Rajagopalan
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Patent number: 6634964Abstract: A golf ball comprising a core and a cover layer, wherein the core has an outer diameter of no greater than about 1.62 inches; the cover layer comprises an inner cover layer and an outer cover layer having a material hardness of less than about 60 Shore D; and at least one of the core or the cover comprises high-Mooney-viscosity rubber, high-Mooney-viscosity rubber regrind, or a mixture thereof.Type: GrantFiled: February 13, 2002Date of Patent: October 21, 2003Assignee: Acushnet CompanyInventors: Michael D Jordan, Jeffrey L. Dalton, Christopher Cavallaro
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Publication number: 20030195062Abstract: Golf balls having a core including a material formed from a controlled-isomer polybutadiene, a crosslinking agent, and a free-radical initiator, or a reaction product thereof, and a cover having a plurality of dimples disposed about the core, wherein the controlled-isomer polybutadiene includes at least about 10 percent to 80 percent trans-isomer and no more than about 5 percent vinyl-configuration polybutadiene and wherein the controlled-isomer polybutadiene has both an absolute molecular weight of at least about 250,000 and a polydispersity of no more than about 3 prior to crosslinking. In particular, golf balls having a compression below about 80 without significant loss of resilience can be advantageously prepared with such materials. Methods of preparing such golf balls are also recited.Type: ApplicationFiled: April 21, 2003Publication date: October 16, 2003Inventors: Laurent Bissonnette, David A. Bulpett, Derek A. Ladd
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Patent number: 6632149Abstract: The invention provides a multi-piece solid golf ball having improved flight performance, controllability and good shot feel at the time of hitting. The multi-piece solid gold ball has a core having at least one layer, an intermediate layer formed on the core, and a cover covering the intermediate layer. When thickness of the intermediate layer is represented as X (mm) and JIS-C hardness of the intermediate layer is represented as Y, then X is 0.3 to 1.5 mm, X and Y have a correlation represented 10X+55≦Y≦10X+75, and the JIS-C hardness of the cover is 70 to 93.Type: GrantFiled: March 9, 2001Date of Patent: October 14, 2003Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Kazunari Yoshida
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Publication number: 20030190976Abstract: Disclosed herein is a multi-layer golf ball having a core, an inner cover layer comprising an ionomer and having Shore D hardness of about 65 or less, and an outer cover layer comprising an ionomer and having a Shore D hardness of at least 60. The outer cover layer is harder than the inner cover layer. The core preferably comprises a high molecular weight polybutadiene that exhibits an ultra high Mooney viscosity. The sum of the thickness of the inner cover layer and the thickness of the outer cover layer is greater than 0.090 inches. A method of making the golf ball also is disclosed.Type: ApplicationFiled: February 27, 2003Publication date: October 9, 2003Inventors: Mark L. Binette, David M. Melanson, Michael J. Tzivanis
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Patent number: 6624221Abstract: A resin composition comprising, in admixture, (A) a specific thermoplastic resin component, (B) at least one wax component selected from among (b-1) a fatty acid having 20-80 carbon atoms and/or a derivative thereof and (b-2) an oxidized natural wax and/or derivative having a neutralization value of 60-190 mg KOH/g, and optionally, (C) a basic inorganic metal compound capable of neutralizing acid groups in the thermoplastic resin component (A) and/or the wax component (B) is improved in flow, moldability and heat resistance and thus suitable to form a layer of a golf ball which exhibits improved rebound and distance properties.Type: GrantFiled: May 30, 2001Date of Patent: September 23, 2003Assignee: Bridgestone Sports Co., Ltd.Inventors: Rinya Takesue, Yasushi Ichikawa
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Patent number: 6623382Abstract: A golf ball is provided which changes color or other indicia after exposure to moisture to indicate that the ball may not have predictable flight characteristics which may result in loss of carry and roll. In one embodiment, a microencapsulated dye layer is formed immediately below the final gloss coat, with controlled dye release causing a stained look to the ball after significant exposure to moisture. In another embodiment, the dye or ink is provided in pelletized form for ease of manufacture. In other embodiments, a dye, ink, or chemical is compounded with other materials and introduced into or applied onto the golf balls composite materials in a solid, liquid, or gaseous form. In still other embodiments imprints on the ball are made with a water activated ink which either appears or disappears upon the exposure of the golf ball to moisture.Type: GrantFiled: November 30, 2001Date of Patent: September 23, 2003Assignee: Performance Indicator, LLCInventor: Robert T. Winskowicz
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Publication number: 20030176241Abstract: The invention relates to a solid golf ball having a diameter of less than about 1.70 inches, including a core formed from a rubber base material having a resilience index of at least about 40 and an outer diameter of at least about 1.58 inches, and a cover disposed about the core formed of a material having a Shore D hardness of less than about 65.Type: ApplicationFiled: December 6, 2002Publication date: September 18, 2003Inventors: Christopher Cavallaro, Jeffrey L. Dalton, Michael D. Jordan, Herbert C. Boehm, Samuel A. Pasqua
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Patent number: 6620060Abstract: The present invention is a golf ball having a core, a cover and a lattice structure aerodynamic pattern. The core has a diameter of 1.53 inches to 1.55 inches, and a PGA compression of 60 to 75 points. The cover has a thickness of 0.060 inch to 0.090 inch. The cover has a Shore D hardness less than 58 as measured on the golf ball. The golf ball has a COR that is greater than 0.782 points at 143 feet per second.Type: GrantFiled: May 8, 2002Date of Patent: September 16, 2003Assignee: Callaway Golf CompanyInventors: Steven S. Ogg, Michael S. Yagley, David M. Bartels, Pijush K. Dewanjee, Geoffrey P. M. Goodman
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Patent number: 6620058Abstract: The present invention is directed towards a golf ball and a method of making a golf ball which comprises a center, at least one cover layer, and at least one wound layer of a tensioned material windings between the center and the cover. Such golf balls have a coefficient of restitution that is optimized for low swing speed players. Since these players usually swing the club at the ball at low swing speeds, and thus get less distance from the ball off the tee, greater ball resiliency tends to provide greater distance and velocity off the tee. Preferably, the golf ball has a core having a thin wound layer of thread. The wound layer of the present invention may be applied to golf balls having liquid or solid centers to achieve desired golf ball characteristics.Type: GrantFiled: December 12, 2000Date of Patent: September 16, 2003Assignee: Acushnet CompanyInventors: Roman D. Halko, Laurent Bissonnette
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Patent number: 6616548Abstract: The present invention provides a two-piece solid golf ball having long flight distance, high spin amount at approach shot and excellent controllability, while maintaining good shot feel. The present invention relates to a two-piece solid golf ball comprising a core and a cover covering the core, wherein a surface hardness in Shore D hardness of the core is higher than a center hardness in Shore D hardness of the core by 15 to 40, the cover is formed from a cover composition comprising a blend of ionomer resin and high rebound characteristics thermoplastic elastomer, the cover has a Shore D hardness of 40 to 60, and the cover hardness is lower than the surface hardness of the core by 1 to 20.Type: GrantFiled: October 5, 2001Date of Patent: September 9, 2003Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Akira Kato, Takashi Sasaki
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Patent number: 6613842Abstract: A golf ball comprising a core and a cover, the cover having a thickness of less than about 0.08 inches, the core having a compression of less than about 90 and is formed from a composition comprising a base rubber, a metal salt acrylate or diacrylate, an initiator, a highly-neutralized polymer, and at least one of a low modulus ionomer or an acid terpolymer of the formula: having a dynamic shear storage modulus at 23° C.Type: GrantFiled: October 23, 2001Date of Patent: September 2, 2003Assignee: Acushnet CompanyInventor: Murali Rajagopalan
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Publication number: 20030153403Abstract: The present invention provides a three-piece solid golf ball, of which flight distance is improved by accomplishing high launch angle and low spin amount in initial flight performance, while maintaining soft and good shot feel, when hit at low head speed. The present invention relates to a three-piece solid golf ball comprising a center, an intermediate layer and a cover having many dimples on the surface thereof, wherein hardness distribution of the center; hardness distribution between each layer and the contiguous layer in the golf ball; and a ratio of the golf ball surface area occupied by the dimple to the total surface area of the golf ball and the total of a periphery length of the dimple; are adjusted to specified ranges.Type: ApplicationFiled: October 23, 2002Publication date: August 14, 2003Inventors: Seiichiro Endo, Keiji Ohama
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Patent number: 6602152Abstract: A golf ball including a sold core and a cover is provided. A deformed amount of the solid core, measured by applying a load of 980 N thereto, is in a range of 4.0 to 6.0 mm. A JIS-C hardness of the cover is in a range of 75 to 95. A JIS-C hardness (Sh) of a surface of the core and a JIS-hardness (Ch) of a center portion of the core satisfy a relationship of 1.55×Ch−16≦Sh≦1.55×Ch−10. A JIS-C hardness (Vh) of the cover and a JIS-C hardness (Sh) of the surface of the core satisfy a relationship of 0.9×Vh−70≦Vh−Sh≦0.9×Vh−50. The hardnesses of the center portion of the core, the surface of the core, and the cover become higher in this order. With this configuration, the golf ball can exhibit a high carrying performance, a good controllability, a desirable very soft feeling of hitting, and an excellent durability against continuous hitting.Type: GrantFiled: December 3, 2001Date of Patent: August 5, 2003Assignee: Bridgestone Sports Co., Ltd.Inventors: Hisashi Yamagishi, Junji Hayashi, Yasumasa Shimizu
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Patent number: 6602151Abstract: The present invention provides a method of producing golf balls improved the adhesion between a ball body and a coated film on the ball body without the need of expensive and large scale facilities. The inventive method comprises the steps of: applying an adhesion enhancing agent containing a silyl component and a solvent to a surface of a ball body; drying the coated surface to form an adhesion enhancing layer having the silyl component; and applying a paint to the adhesion enhancing layer. The silyl component is capable of remaining 30 weight % or more after an elapse of one hour at a temperature of 25° C. The method is applicable to the batch operating process of manufacturing golf balls.Type: GrantFiled: June 2, 2000Date of Patent: August 5, 2003Assignees: Sumitomo Rubber Industries Limited, Wayaku Paint Co., Ltd.Inventors: Kiyoto Maruoka, Kaichiro Wayaku
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Publication number: 20030144081Abstract: A high CoR golf ball having predetermined moment of inertia is provided. A portion of the golf ball preferably contains substantially no filler, which contributes to the increased resilience of the ball. In accordance to one aspect of the invention, the portion with substantially no filler is an outer core of the ball. The innermost core should have a high specific gravity. Additionally, the outermost layers of the ball may have a low specific gravity. Preferably, the portion with substantially no filler is relatively larger than other portions of the ball.Type: ApplicationFiled: January 28, 2003Publication date: July 31, 2003Inventors: Michael J. Sullivan, Derek A. Ladd, Antonio U. Desimas
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Publication number: 20030139228Abstract: The present invention is directed towards a multi-layered golf ball, at least the inner cover having multiple layers formed by a sandwich injection molding process, wherein each multi-layered cover comprises an inner layer and an outer layer of a first material and an intermediate layer therebetween of a second material. The materials having different properties. An embodiment of the invention includes both covers being multi-layered formed by the sandwich injection molding process.Type: ApplicationFiled: January 23, 2002Publication date: July 24, 2003Inventors: Christopher Cavallaro, Michael D. Jordan
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Patent number: 6595872Abstract: The present invention is a golf ball that has a coefficient of restitution at 143 feet per second that is greater than 0.8015, and an USGA initial velocity less than 255.0 feet per second. The golf ball is preferably a solid three-piece golf ball with a thermosetting polyurethane cover, an ionomer blend intermediate layer and a polybutadiene core.Type: GrantFiled: May 20, 2002Date of Patent: July 22, 2003Assignee: Callaway Golf CompanyInventors: Michael S. Yagley, Steven S. Ogg, Pijush K. Dewanjee, David M. Bartels
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Patent number: 6595874Abstract: A golf ball comprising an inner core, an outer core, and a cover is disclosed. The outer core surrounds the inner core, and the cover encases the cores. The inner core is preferably a pre-formed selectively weighted symmetrical, but non-spherical insert, which may be made from either a high or low specific gravity material to control the moment of inertia and spin rate of the ball. The outer core is over-molded around the pre-formed insert to form a spherical core. Alternatively, the inner core insert has outer pockets defined thereon. These pockets are adapted to receive the outer core materials, which may have either a high specific gravity or a low specific gravity.Type: GrantFiled: March 29, 2001Date of Patent: July 22, 2003Assignee: Acushnet CompanyInventors: Michael J. Sullivan, Herbert C. Boehm
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Patent number: 6592471Abstract: In a golf ball comprising a solid core, a mantle, and a cover, the mantle is formed of a thermoplastic elastomer having a Shore D hardness of 30-52, the cover is formed of a thermoplastic resin loaded with a particulate inorganic filler, the solid core has a surface JIS C hardness 10-22 units greater than a center JIS C hardness, and the golf ball has an inertia moment of 82.5-85.5 kg·cm2. The ball is improved in durability and feel when hit with clubs of different types.Type: GrantFiled: September 8, 2000Date of Patent: July 15, 2003Assignee: Bridgestone Sports Co., Ltd.Inventors: Hideo Watanabe, Yasumasa Shimizu, Akira Kawata
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Publication number: 20030130064Abstract: The present invention provides a multi-piece solid golf ball, which is superior in flight distance, shot feel, controllability and scuff resistance. The present invention relates to a multi-piece solid golf ball comprising a core consisting of a center and an intermediate layer, and a cover having many dimples on the surface thereof, wherein the center has a diameter of 25 to 40 mm, and a surface hardness of the center is higher than a central point hardness of the center in Shore D hardness by not more than 7, the intermediate layer has a thickness of 0.5 to 8.0 mm, and a surface hardness in Shore D hardness of the intermediate layer is higher than the central point hardness of the center by 3 to 25, and a hardness in Shore D hardness of the cover is lower than the surface hardness of the intermediate layer by 0 to 15.Type: ApplicationFiled: August 1, 2002Publication date: July 10, 2003Inventors: Takashi Sasaki, Akira Kato, Satoshi Iwami
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Patent number: 6589124Abstract: The present invention provides a hollow golf ball having good shot feel at the time of hitting by making impact force small, while keeping excellent flight performance. Improved shot feel at the time of hitting by improving an impact absorption, while keeping excellent flight performance. The present invention relates to a hollow golf ball comprising: a hollow core composed of a hollow portion and one or more hollow core outer layers formed from a core composition comprising rubber component, resin component or the mixture thereof, and a cover formed on the hollow core, wherein, when a secondary natural frequency of the hollow golf ball is expressed as X and a deformation amount, when applying from an initial load of 10 kgf to a final load of 130 kgf on the hollow golf ball, is expressed as Y, a difference of X−Y is within the range of 0.1 to 1.5.Type: GrantFiled: October 29, 1998Date of Patent: July 8, 2003Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Kiyoto Maruoka, Akihiro Nakahara, Kazuo Hochi
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Patent number: 6586511Abstract: The present invention is directed to a golf ball and to a process for forming a golf ball having at least one layer, where the layer is formed of a saponified polymer/oxa acid blend, having from about 65 to about 99 parts of at least one saponified polymer and from about 35 to 1 parts of at least one oxa acid, based on 100 parts by weight of the saponified polymer/oxa acid blend. The layer may be foamed or unfoamed, and may form at least a portion of any of the cover, the core, or a mantle layer situated between the cover and the core.Type: GrantFiled: January 16, 2001Date of Patent: July 1, 2003Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Kevin M. Harris
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Publication number: 20030119606Abstract: The present invention provides a multi-piece solid golf ball having soft and good shot feel and excellent flight performance when hit by a golfer who swings a golf club at low head speed. The present invention relates to a multi-piece solid golf ball comprising a core, an intermediate layer and a cover having many dimples on the surface thereof, wherein hardness distribution of the core; hardness distribution between each layer and the contiguous layer in the golf ball; a ratio of a thickness of the cover to that of the intermediate layer; a ratio (X/D) of the total periphery length (X) to a diameter of the golf ball; and a ratio (VD/VG) of the total volume of the dimples (VD) to a volume of the phantom sphere (VG) assuming that the golf ball is a true sphere having no dimples on the surface thereof; are adjusted to specified ranges.Type: ApplicationFiled: October 31, 2002Publication date: June 26, 2003Inventors: Keiji Ohama, Takahiro Sajima, Seiichiro Endo
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Patent number: 6583229Abstract: The present invention provides a solid golf ball having exceptional rebound characteristics and flight performance, as well as good shot feel. The present invention relates to a solid golf ball comprising at least one layer of a core, and at least one layer of a cover formed on the core, wherein at least one of the layers of the core is formed by vulcanizing and press-molding a rubber composition comprising a base rubber, co-crosslinking agent, organic peroxide, filler and specific organic sulfur compound which contains substituent groups having a substituent constant of not less than 1.42.Type: GrantFiled: May 24, 2001Date of Patent: June 24, 2003Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Satoshi Mano, Masatoshi Yokota, Kiyoto Maruoka, Seigou Sakagami, Tetsuo Yamaguchi
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Patent number: 6575848Abstract: Golf balls having a core including a material formed from a controlled-isomer polybutadiene, a crosslinking agent, and a free-radical initiator, or a reaction product thereof, and a cover having a plurality of dimples disposed about the core, wherein the controlled-isomer polybutadiene includes at least about 10 percent to 80 percent trans-isomer and no more than about 5 percent vinyl-configuration polybutadiene and wherein the controlled-isomer polybutadiene has both an absolute molecular weight of at least about 250,000 and a polydispersity of no more than about 3 prior to crosslinking. In particular, golf balls having a compression below about 80 without significant loss of resilience can be advantageously prepared with such materials. Methods of preparing such golf balls are also recited.Type: GrantFiled: December 21, 2000Date of Patent: June 10, 2003Assignee: Acushnet CompanyInventors: Laurent Bissonnette, David A. Bulpett, Derek A. Ladd
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Patent number: 6575849Abstract: A golf ball includes a core and a cover made from a cover material mainly containing an ionomer resin and also an inorganic filler having a specific gravity of 3.50 or more in an amount of 10 to 25 parts by mass on the basis of 100 parts by mass of the ionomer resin. A flexural amount of the core, measured by applying a load of 980 N thereto, is in a range of 4.7 to 5.3 mm. A specific gravity of the cover material is in a range of 1.050 to 1.100, a thickness of the cover is in a range of 1.5 to 2.0 mm, and a Shore D hardness of the cover is in a range of 57 to 63. A weight of the golf ball is in a range of 45.0 to 46.0 g, and a flexural amount of the golf ball, measured by applying a load of 980 N thereto, is in a range of 3.7 to 4.3 mm. A weight (W) of the golf ball and an inertia moment (MI) thereof satisfy a relationship of 1.53×W+13.32≦MI≦1.61×W+11.02.Type: GrantFiled: August 15, 2001Date of Patent: June 10, 2003Assignee: Bridgestone Sports Co., Ltd.Inventors: Junji Hayashi, Yutaka Masutani, Hisashi Yamagishi