Diverse Cover And Interior Patents (Class 473/377)
  • Publication number: 20130012336
    Abstract: A golf ball 2 includes a spherical core 4, a mid layer 6 positioned outside the core 4, and a cover 8 positioned outside the mid layer 6. The core 4 includes a spherical center 10 and an envelope layer 12 positioned outside the center 10. The center 10 has a diameter of 1 mm or greater and 15 mm or less. The center 10 has a JIS-C hardness H1, at its central point, of 20 or greater and 50 or less. The difference (H4?H3) between the JIS-C hardness H4 of the core 4 at its surface and the JIS-C hardness H3 of the envelope layer 12 at its innermost portion is equal to or greater than 10. The cover 8 has a flexural modulus of 300 MPa or greater and 1000 MPa or less, and has a tensile modulus of 400 MPa or greater and 1500 MPa or less.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 10, 2013
    Inventors: Hirotaka NAKAMURA, Keiji OHAMA, Kazuhiko ISOAGAWA, Satoko OKABE
  • Publication number: 20120302373
    Abstract: The invention provides a golf ball which includes a core and a cover encasing the core, wherein the cover has a thickness of at least 1.3 mm but not more than 1.8 mm and a material hardness, expressed as the Shore D hardness, of not more than 58, the core has a deflection when compressed under a final load of 1,275 N (130 kgf) from an initial load state of 98 N (10 kgf) of at least 4.1 mm, the ball has a deflection when compressed under a final load of 1,275 N (130 kgf) from an initial load state of 98 N (10 kgf) of at least 3.8 mm, and the ratio of the core deflection to the ball deflection (core/ball) is at least 0.8 but not more than 1.2. The ball of the invention can be sufficiently deformed on shots with a driver, even when played by a low head speed golfer, allowing a good ball rebound to be obtained and thus resulting in an increased distance. The ball also has a good feel when played and a satisfactory durability.
    Type: Application
    Filed: May 27, 2011
    Publication date: November 29, 2012
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventors: Atsushi NANBA, Hiroshi HIGUCHI
  • Patent number: 8309639
    Abstract: The present invention is directed to a golf ball having at least one layer formed from a rubber composition comprising a base rubber, at least 0.05 parts by weight of a free radical initiator, per 100 parts of the base rubber, and at least 0.1 parts by weight of a benzoquinone, per 100 parts of the base rubber. The rubber composition may be present in any one or more of a core layer, a cover layer, or an intermediate layer.
    Type: Grant
    Filed: October 6, 2009
    Date of Patent: November 13, 2012
    Assignee: Acushnet Company
    Inventors: David A. Bulpett, Brian Comeau, Douglas S. Goguen
  • Publication number: 20120283041
    Abstract: The invention provides a golf ball having a core formed by vulcanizing a rubber composition and a cover composed primarily of a polyurethane material. The rubber composition of the core includes 100 parts by weight of a base rubber, from 10 to 40 parts by weight of an unsaturated carboxylic acid or a metal salt thereof, a peroxyketal (a) and a monophenol-type antioxidant (b), the weight ratio (a)/(b) of the peroxyketal to the monophenol-type antioxidant being from 5 to 50. The ball has an excellent discoloration resistance and an outstanding distance and feel on shots taken with a middle iron.
    Type: Application
    Filed: July 13, 2012
    Publication date: November 8, 2012
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventor: Akira KIMURA
  • Patent number: 8299146
    Abstract: Golf ball 2 has core 4, cover 6 and paint layer 12. The base polymer of the cover 6 includes a thermoplastic polyurethane elastomer. The cover 6 includes one or more kinds of ultraviolet ray absorbing agents. The paint layer 12 includes one or more kinds of ultraviolet ray absorbing agents. There are one or more kinds of ultraviolet ray absorbing agents (common ultraviolet ray absorbing agent) included in the cover 6 and the paint layer 12. The cover 6 includes the common ultraviolet ray absorbing agent in an amount of A parts by weight per 100 parts by weight of the base polymer, and the paint layer 12 includes the common ultraviolet ray absorbing agent in an amount of B parts by weight per 100 parts by weight of the resin component, with the ratio (A/B) being preferably 0.1 or greater and 10 or less. Preferably, the thermoplastic polyurethane elastomer is an MDI based polyurethane elastomer.
    Type: Grant
    Filed: August 12, 2008
    Date of Patent: October 30, 2012
    Assignee: SRI Sports Limited
    Inventors: Keiji Ohama, Hirotaka Nakamura
  • Patent number: 8288478
    Abstract: Golf balls containing at least one layer made from a thermoplastic polyurethane or polyurethane-urea that is the reaction product of a polyisocyanate with moisture-resistant polyol and a curing agent are provided. The moisture-resistant polyol may be prepared by dimerizing unsaturated aliphatic monocarboxylic acid or ester containing 10 to 60 carbon atoms followed by reacting it with a monomeric, oligomeric, or polymeric diol. In one preferred version, the moisture-resistant polyol is a branched polyester polyol containing 36 carbon atoms. The composition can be prepared using prepolymer or one-shot manufacturing techniques. The resulting golf ball has desirable playing performance properties including high resiliency, toughness, impact durability, moisture-resistance, and soft feel.
    Type: Grant
    Filed: February 25, 2010
    Date of Patent: October 16, 2012
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Derek A. Ladd, Michael J. Sullivan
  • Publication number: 20120238378
    Abstract: A golf ball has a cover and a core which is made as a single piece or of two or more parts (for example an inner core covered by an outer core or mantle layer). The ball has non-spherical aspects in at least some parts and may also have different specific gravities in different parts of the ball. The different shaped ball parts combined with the different specific gravities of the materials for different ball parts results in a differential between the moments of inertia of the different spin axes. The golf ball is spherical, but the inner layers are not necessarily completely spherical or symmetrical layers or parts.
    Type: Application
    Filed: March 16, 2012
    Publication date: September 20, 2012
    Applicant: AERO-X GOLF, INC.
    Inventors: David L. Felker, Douglas C. Winfield
  • Publication number: 20120231899
    Abstract: A golf ball is provided that includes a coating. The coating is designed to allow a golfer to modify or increase the tackiness of the coating. The coating changes tackiness when exposed to a soaking material. A method of determining a desirable length of soak is also disclosed.
    Type: Application
    Filed: March 11, 2011
    Publication date: September 13, 2012
    Applicant: NIKE, Inc.
    Inventor: Mark Alan
  • Publication number: 20120220393
    Abstract: A golf ball comprising a single layer core formed from a substantially homogenous formulation and comprising a geometric center and an outer surface, and a cover layer disposed thereabout. The single layer core has an inner core region disposed about the geometric center and an outer core region that is disposed about the inner core region and is adjacent the outer surface, the outer core region having a thickness of about 15 mm or less. The inner core region has a hardness that increases radially from the geometric center toward the outer core region in a plurality of increments of about 5 Shore C. The inner core region has a first hardness (IC1h) and the outer core region has a second hardness (OC2h) such that (OC2h)>(IC1h) and a hardness of the outer surface (OSh) is greater than a hardness of the geometric center (GCh), represented by the relationship (OSh)>(GCh).
    Type: Application
    Filed: May 2, 2012
    Publication date: August 30, 2012
    Inventors: Michael J. Sullivan, Brian Comeau, Douglas S. Goguen, David A. Bulpett
  • Publication number: 20120214615
    Abstract: A multilayer solid golf ball may include a core formed from a highly neutralized polymer and a cover surrounding the core. The ball may also include an enclosing layer disposed between the core and the cover, the enclosing layer having a thermal conductivity of 0.12 W/m-K or less.
    Type: Application
    Filed: February 24, 2012
    Publication date: August 23, 2012
    Applicant: NIKE, Inc.
    Inventors: Hideyuki Ishii, Yutaka Kabeshita, Hsin Cheng, Chien-Hsin Chou, Chen-Tai Liu
  • Patent number: 8242195
    Abstract: The invention provides a golf ball having a core formed by vulcanizing a rubber composition and a cover composed primarily of a polyurethane material. The rubber composition of the core includes 100 parts by weight of a base rubber, from 10 to 40 parts by weight of an unsaturated carboxylic acid or a metal salt thereof, a peroxyketal (a) and a monophenol-type antioxidant (b), the weight ratio (a)/(b) of the peroxyketal to the monophenol-type antioxidant being from 5 to 50. The ball has an excellent discoloration resistance and an outstanding distance and feel on shots taken with a middle iron.
    Type: Grant
    Filed: July 31, 2009
    Date of Patent: August 14, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventor: Akira Kimura
  • Patent number: 8227545
    Abstract: Disclosed embodiments involve a novel blend composition for use in sports equipment, particularly for use in golf ball manufacture. The composition comprises three components, (A), (B), and (C). Component (A) can be selected from polymer(s) comprising an ethylene moiety and one or more unsaturated carboxylic acid, sulfonic acid, or phosphoric acid groups. Component (B) is a compound having a formula (R2N)m—R?—(X(O)nORy)m and component (C) is a basic metal ion salt having the ability to neutralize some, or all of the acidic groups present in components (A) and (B). The blend composition can also comprise an additional polymer and/or the reaction product of one or more ionomers and component (B). In particular embodiments, the blend composition is used in golf balls, comprising a core; an outer cover layer; and 0-5 intermediate layers; wherein one or more of said core, outer cover, and/or intermediate layers, if present, includes the blend composition.
    Type: Grant
    Filed: June 24, 2010
    Date of Patent: July 24, 2012
    Assignee: Taylor Made Golf Company, Inc.
    Inventor: Hyun Jin Kim
  • Patent number: 8227553
    Abstract: The invention provides a rubber composition for golf balls which includes a base rubber, (B) a metal salt of an unsaturated carboxylic acid and/or an unsaturated carboxylic acid and zinc oxide, (C) an organic peroxide, and (D) from 0.1 to 5 parts by weight of a metal salt of a thiol having the general formula (R—S)nM (wherein R is a monovalent hydrocarbon group having from 12 to 30 carbons, exclusive of aromatic groups; n is an integer such as 1, 2 or 3; and M is a metal) per 100 parts by weight of the base rubber. The golf ball-forming rubber composition of the invention is suitable for pressure molding and has an excellent productivity because it does not lower the rate of vulcanization. The golf ball of the invention, which is formed using the composition, is endowed with an excellent rebound.
    Type: Grant
    Filed: July 14, 2010
    Date of Patent: July 24, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventor: Yuichiro Ozawa
  • Publication number: 20120165126
    Abstract: A golf ball 2 includes a core 4, a mid layer 6, and a cover 8. The core 4 includes a center 10 and an envelope layer 12. The ratio of the volume Ve of the core 4 to the volume of a phantom sphere of the golf ball 2 is equal to greater than 76%. The ratio (Co/Do) of an amount of compressive deformation Co of the center 10 to the diameter Do of the center 10 is equal to or greater than 0.085 but equal to or less than 0.130. The ratio (Ce/De) of an amount of compressive deformation Ce of the core 4 to the diameter De of the core 4 is equal to or greater than 0.015 but equal to or less than 0.020.
    Type: Application
    Filed: October 12, 2011
    Publication date: June 28, 2012
    Inventors: Takahiro SAJIMA, Yoshiko Matsuyama
  • Publication number: 20120165127
    Abstract: A golf ball 2 includes a core 4, a mid layer 6, and a cover 8. The core 4 includes a center 10 and an envelope layer 12. The ratio of the volume Ve of the core 4 to the volume of a phantom sphere of the golf ball 2 is equal to greater than 76%. The ratio (Co/Ce) of an amount of compressive deformation Co of the center 10 to an amount of compressive deformation Ce of the core 4 is greater than 2.0 but less than 3.0. The ratio (Vo/Ve) of the volume Vo of the center 10 to the volume Ve of the core 4 is equal to or greater than 0.01 but equal to or less than 0.13.
    Type: Application
    Filed: October 12, 2011
    Publication date: June 28, 2012
    Inventors: Takahiro SAJIMA, Yoshiko Matsuyama
  • Publication number: 20120165128
    Abstract: A golf ball 2 includes a core 4, amid layer 6, and a cover 8. The core 4 includes a center 10 and an envelope layer 12. The ratio (Do/De) of an amount of compressive deformation Do of the center 10 to an amount of compressive deformation De of the core 4 is equal to or greater than 1.5 but equal to or less than 2.5. The ratio (Do/Dc) of the amount of compressive deformation Do of the center 10 to an amount of compressive deformation Dc of the golf ball 2 is equal to or greater than 1.8. The diameter of the center 10 is equal to or less than 20 mm. The difference (He-Ho) between a surface hardness He of the core 4 and a central hardness Ho of the center 10 is equal to or less than 40.
    Type: Application
    Filed: November 4, 2011
    Publication date: June 28, 2012
    Inventors: Yoshiko Matsuyama, Takahiro Sajima, Keiji Ohama
  • Publication number: 20120157236
    Abstract: Golf balls containing a core comprising a blend of: a) about 1 to about 49 weight percent of a polybutadiene rubber having a relatively high Mooney viscosity, and b) about 51 to about 99 weight percent of a polyalkenamer rubber having a relatively low Mooney viscosity are provided. Single or multi-layered cores may be prepared. In addition, the golf ball includes a cover that may be single or multi-layered. The cover is preferably made of polyurethanes, polyureas, or blends thereof. The polyalkenamer/polybutadiene rubber composition helps provide the ball with high resiliency along with a soft feel.
    Type: Application
    Filed: December 20, 2010
    Publication date: June 21, 2012
    Inventors: Michael J. Sullivan, Mark L. Binette, Douglas S. Goguen, Brian Comeau, Robert Blink, David A. Bulpett
  • Publication number: 20120122612
    Abstract: A golf ball includes a core having a diameter, a first Shore D hardness and a compression; and a cover having a second Shore D hardness that is at least 5 points less than the first Shore D hardness. The cover includes an ionomer of an alternate copolymer, the alternate copolymer being formed from the reaction product of a copolymer of ethylene and maleic anhydride monomer in the presence of a suitable base, the maleic anhydride monomer being present in an amount of about 78 wt %.
    Type: Application
    Filed: November 12, 2010
    Publication date: May 17, 2012
    Inventors: Murali Rajagopalan, Michael J. Sullivan
  • Publication number: 20120115641
    Abstract: Disclosed herein are soft and stiff compositions, i.e., compositions which have a flexural modulus that is greater than the value that is expected based on the composition's hardness. The compositions preferably have a hardness/modulus relationship represented by the formula H?11.889 Ln(M)+42, where H is the hardness of the composition, in JIS-C, and M is the flexural modulus of the composition, in ksi; or a softness/stiffness relationship represented by the formula if M<56, then H?8.5218 Ln(M)+26.5 if M?56, then H?8.5218 Ln(M)+28.5, where H is the hardness of the composition, in Shore D, and M is the flexural modulus of the composition, in ksi.
    Type: Application
    Filed: December 31, 2010
    Publication date: May 10, 2012
    Inventors: Brian Comeau, David A. Bulpett, Micheal J. Sullivan, Mark L. Binette, Robert Blink, Murali Rajagopalan
  • Publication number: 20120115645
    Abstract: Disclosed herein are hard and flexible compositions, i.e., compositions which have a flexural modulus that is less than the value that is expected based on the composition's hardness. The compositions preferably have a hardness/modulus relationship represented by the formula H?11.889 Ln(M)+47, where H is the hardness of the composition, in JIS-C, and M is the flexural modulus of the composition, in ksi; or a softness/stiffness relationship represented by the formula if M<110, then H?8.5218 Ln(M)+32.5 if M?110, then H?72.5, where H is the hardness of the composition, in Shore D, and M is the flexural modulus of the composition, in ksi.
    Type: Application
    Filed: December 31, 2010
    Publication date: May 10, 2012
    Inventors: Brian Comeau, David A. Bulpett, Michael J. Sullivan, Mark L. Binette, Robert Blink
  • Publication number: 20120115647
    Abstract: Disclosed herein are soft and stiff compositions, i.e., compositions which have a flexural modulus that is greater than the value that is expected based on the composition's hardness. The compositions preferably have a hardness/modulus relationship represented by the formula H?11.889 Ln(M)+42, where H is the hardness of the composition, in JIS-C, and M is the flexural modulus of the composition, in ksi; or a softness/stiffness relationship represented by the formula if M<56, then H?8.5218 Ln(M)+26.5 if M?56, then H?8.5218 Ln(M)+28.5, where H is the hardness of the composition, in Shore D, and M is the flexural modulus of the composition, in ksi.
    Type: Application
    Filed: December 31, 2010
    Publication date: May 10, 2012
    Inventors: Michael J. Sullivan, David A. Bulpett, Brian Comeau, Mark L. Binette, Robert Blink
  • Publication number: 20120115648
    Abstract: A golf ball comprising a single layer core being formed from a substantially homogenous formulation, the inner core region has a first hardness (IC1h), the outer core region has a second hardness (OC2h), the intermediate core region has third and fourth hardnesses (IMC3h) and (IMC4h), respectively, such that the third hardness is less than the first and second hardnesses, represented by the relationships (IMC3h)<(IC1h) and (IMC3h)<(OC2h), and the fourth hardness is greater than the first and second hardnesses, represented by the relationships (IMC4h)>(IC1h) and (IMC4h)>(OC2h), and hardness of the outer surface (OSh) is greater than a hardness of the geometric center (GCh), represented by the relationship (OSh)>(GCh).
    Type: Application
    Filed: August 25, 2011
    Publication date: May 10, 2012
    Inventors: Michael J. Sullivan, Brian Comeau, Douglas S. Goguen, David A. Bulpett
  • Publication number: 20120100934
    Abstract: The invention relates to golf ball formulations formed from blends of linear and branched polybutadienes catalyzed with neodymium that have improved properties and processing characteristics. Golf ball components may be formed from the blends to provide high coefficient of restitution.
    Type: Application
    Filed: October 25, 2010
    Publication date: April 26, 2012
    Applicant: ACUSHNET COMPANY
    Inventors: Michael J. Sullivan, Brian Comeau, David A. Bulpett, Derek A. Ladd
  • Publication number: 20120100936
    Abstract: The invention is directed to a golf ball comprising a long-chain branched neodymium-catalyzed polybutadiene having a cis-1,4 content of at least about 96% and a solution viscosity of less than 165 mPa·s, wherein the overall golf ball comprises a COR of at least about 0.780 and an Atti compression of from about 25 to about 120. The invention is also directed to a golf ball comprising a core, a cover and optionally an intermediate layer disposed between the core and the cover; wherein at least one of said core, cover and intermediate layer comprises a polybutadiene composition comprising a long-chain branched neodymium-catalyzed polybutadiene having a cis-1,4 content of at least about 96% and a solution viscosity of less than 165 mPa·s.
    Type: Application
    Filed: October 25, 2010
    Publication date: April 26, 2012
    Inventors: Michael J. Sullivan, Brian Comeau, David A. Bulpett, Derek A. Ladd
  • Patent number: 8157675
    Abstract: A golf ball comprising a single layer core and a cover layer disposed about the single layer core, the single layer core being formed from a substantially homogenous formulation and comprising a geometric center and an outer surface, the single layer core further comprising an inner core region disposed about the geometric center, an outer core region adjacent the outer surface, and an intermediate core region disposed between the inner and outer core regions and extending radially from about 8 mm to about 18 mm from the geometric center. The single layer core has first, second and third hardnesses disposed within the inner core region, outer core region, intermediate core region, respectively, wherein the third hardness is greater than the first hardness and the second hardness, and a hardness of the outer surface is substantially the same as or lower than a hardness of the geometric center.
    Type: Grant
    Filed: May 16, 2011
    Date of Patent: April 17, 2012
    Assignee: Acushnet Company
    Inventors: Michael J. Sullivan, Brian Comeau, Douglas S. Goguen, David A. Bulpett
  • Publication number: 20120077621
    Abstract: This disclosure relates to four-piece golf balls having an outer cover layer made from a crosslinked thermoplastic polyurethane elastomer. The crosslinked thermoplastic polyurethane elastomer includes crosslinks located in the hard segments, where the crosslinks being the reaction product of unsaturated bonds located in the hard segments catalyzed by a free radical initiator. The crosslinks may be formed from an unsaturated diol as a chain extender. The unsaturated diol may be trimethylolpropane monoallylether (TMPME). The four-piece golf ball may include an inner core layer formed from a highly neutralized acid polymer composition. The four-piece golf ball may also include an outer core layer formed from a polybutadiene rubber. The golf ball may exhibit a high degree of scuff resistance.
    Type: Application
    Filed: July 28, 2011
    Publication date: March 29, 2012
    Applicant: NIKE, INC.
    Inventors: Hideyuki Ishii, Hsin Cheng, Chien-Hsin Chou, Chung-Yu Huang, Yasushi Ichikawa, Chen-Tai Liu
  • Publication number: 20120071273
    Abstract: A golf ball core that includes a center point having a first hardness value and/or first specific gravity value, and a surface having a second hardness value and/or second specific gravity value. The first hardness value, or first specific gravity value, is different from the second hardness value, or second specific gravity value, respectively.
    Type: Application
    Filed: November 8, 2011
    Publication date: March 22, 2012
    Inventors: Hyun Jin Kim, Hong Guk Jeon, Kelvin Tsugio Okamoto
  • Patent number: 8137211
    Abstract: A multilayer golf ball including a solid center having a center hardness, a plurality of laminates cut into a plurality of shapes formed around the center to create an inner ball, and a cover formed around the inner ball, wherein the plurality of layers can include at least a first layer having a hardness greater than the center hardness and a second layer having a hardness greater than the first layer hardness, and optionally a third layer disposed between the first and the second layers having a hardness greater than the first layer hardness.
    Type: Grant
    Filed: September 28, 2009
    Date of Patent: March 20, 2012
    Assignee: Acushnet Company
    Inventors: Jeffery L. Dalton, Herbert C. Boehm, Christopher Cavallaro
  • Publication number: 20120064998
    Abstract: A multi-layer ball includes a core made of a high energy material such as a highly neutralized polymer and a cover made of a deadening material. A specified relationship exists between the compression and coefficient of restitution of the core and of the ball. The initial velocity of the ball is higher than what would be expected based on the coefficient of restitution of the ball compared to prior balls. The use of the deadening material allows the coefficient of restitution of the ball to be relatively low, which can yield improved spinnability in the half wedge shots while maintaining driver distance.
    Type: Application
    Filed: August 4, 2011
    Publication date: March 15, 2012
    Applicant: NIKE, INC.
    Inventors: Hideyuki Ishii, Arthur Molinari
  • Patent number: 8128514
    Abstract: The invention is directed to a golf ball comprising a core and a cover, wherein the core has a geometric center having a hardness (Hg) and the core has an outer surface that is treated with a surface-softening material comprising at least one fatty acid and/or fatty acid salt plasticizer composition such that the outer surface has an extrapolated hardness (HE) and an actual hardness (HOS) wherein HE is derived from a five point extrapolation within three quarters of an outer core diameter and HOS is measured on the curved surface of the core, and the cover has a hardness (HC), wherein HC>HE>Hg>HOS.
    Type: Grant
    Filed: September 16, 2010
    Date of Patent: March 6, 2012
    Assignee: Acushnet Company
    Inventors: Michael J. Sullivan, Mark L. Binette, Brian Comeau
  • Publication number: 20120046124
    Abstract: Golf balls containing a composite layer comprising a substantially transparent polymeric matrix with at least one embedded decorative insert member (for example, charm or jewelry piece) are provided. The ball further includes a core that may comprise a reflective material such as white pigment. A cover structure comprising a second substantially transparent polymeric matrix surrounds the composite layer. The decorative insert can be seen through the layers. Various light-reflective fillers, color pigments, and dyes may be added to the layers to create different optical effects. The resulting ball has an aesthetically pleasing appearance while maintaining its good playing performance properties.
    Type: Application
    Filed: October 31, 2011
    Publication date: February 23, 2012
    Inventors: Michael J. Sullivan, William E. Morgan
  • Patent number: 8119712
    Abstract: Golf balls containing at least one layer made from a rubber composition comprising a benzenetrisamide nucleating agent are provided. The rubber composition preferably contains a free-radical initiator agent, cross-linking agent, and fillers along with the base rubber and nucleating agent. Golf balls of various constructions may be made including two-piece, three-piece, and four-piece balls. The composition is used preferably to form a golf ball core having improved resiliency, durability, toughness, and impact strength.
    Type: Grant
    Filed: July 10, 2009
    Date of Patent: February 21, 2012
    Assignee: Acushnet Company
    Inventors: Douglas S. Goguen, Brian Comeau, David A. Bulpett
  • Publication number: 20120015760
    Abstract: The invention provides a rubber composition for golf balls which includes a base rubber, (B) a metal salt of an unsaturated carboxylic acid and/or an unsaturated carboxylic acid and zinc oxide, (C) an organic peroxide, and (D) from 0.1 to 5 parts by weight of a metal salt of a thiol having the general formula (R—S)nM (wherein R is a monovalent hydrocarbon group having from 12 to 30 carbons, exclusive of aromatic groups; n is an integer such as 1, 2 or 3; and M is a metal) per 100 parts by weight of the base rubber. The golf ball-forming rubber composition of the invention is suitable for pressure molding and has an excellent productivity because it does not lower the rate of vulcanization. The golf ball of the invention, which is formed using the composition, is endowed with an excellent rebound.
    Type: Application
    Filed: July 14, 2010
    Publication date: January 19, 2012
    Applicant: BRIDGESTONE SPORTS CO., LTD.
    Inventor: Yuichiro OZAWA
  • Patent number: 8096899
    Abstract: Presently disclosed embodiments concern an isocyanate-modified composition which includes A) from about 65 to about 99 weight % (based on the total weight of the isocyanate-modified composition) of a base polymer having either hydroxyl groups or amine groups or mixtures thereof, and B) from about 1 to about 35 weight % (based on the total weight of the isocyanate-modified composition) of a blocked isocyanate. The presently disclosed embodiments also include a golf ball made from the isocyanate-modified composition, and a method of making a golf ball using the isocyanate-modified composition, such as by injection molding.
    Type: Grant
    Filed: December 17, 2008
    Date of Patent: January 17, 2012
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon, Jae S. Lee
  • Publication number: 20120010021
    Abstract: An object of the present invention is to provide a golf ball traveling a greater distance by improving the properties of the spherical core. The present invention provides a golf ball comprising a spherical core, and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing a base rubber, a co-crosslinking agent, a crosslinking initiator, a filler and a polynuclear aromatic organic sulfur compound or a derivative thereof, and the spherical core has a specific hardness distribution without decreasing hardness from a central point toward a surface of the spherical core in JIS-C hardness.
    Type: Application
    Filed: July 11, 2011
    Publication date: January 12, 2012
    Inventors: Kazuhisa Fushihara, Kazuhiko Isogawa
  • Publication number: 20120010024
    Abstract: A golf ball 2 includes a spherical core 4 and a cover 6 positioned outside the core 4. The golf ball 2 further has dimples 8 on a surface thereof. The core 4 is obtained by crosslinking a rubber composition. The difference between a hardness H(5.0) at a point that is located at a distance of 5 mm from the central point of the core 4, and a hardness Ho at the central point is equal to or greater than 6.0. The difference between a hardness H (12.5) at a point that is located at a distance of 12.5 mm from the central point, and the hardness H(5.0) is equal to or less than 4.0. The difference between a hardness Hs at the surface of the core 4 and the hardness H(12.5) is equal to or greater than 10.0. The difference between the hardness Hs and the hardness Ho is equal to or greater than 22.0. There is no zone in which a hardness decreases from the central point to the surface. The rubber composition of the core 4 includes 2-naphthalenethiol. A cross-sectional shape of each dimple 8 is a wave-like curve.
    Type: Application
    Filed: June 23, 2011
    Publication date: January 12, 2012
    Inventors: Hirotaka NAKAMURA, Kazuhiko ISOGAWA, Seiichiro ENDO, Hyoungchol KIM
  • Patent number: 8093337
    Abstract: Golf balls including cores formed from polybutadiene reaction products having a percent change in dynamic stiffness from 0° C. to ?50° C. of less than 130 percent where the reaction products include a resilient polymer component, a crosslinking material, a cis-to-trans catalyst, and a free radical source. The golf balls may be formed with polyurethane covers, covers formed from castable reactive liquid materials, among other materials. The golf balls may also include an intermediate layer.
    Type: Grant
    Filed: May 7, 2009
    Date of Patent: January 10, 2012
    Assignee: Acushnet Company
    Inventors: Shenshen Wu, Edmund A. Hebert, Laurent Bissonnette, David A. Bulpett, Murali Rajagopalan, Peter Voorheis, Mark N. Wrigley
  • Publication number: 20110319196
    Abstract: An object of the present invention is to provide a golf ball cover resin composition containing an ionomer resin with an excellent resilience and fluidity. Another object of the present invention is to provide a golf ball using an ionomer resin for a cover, with an excellent shot feeling, durability and resilience.
    Type: Application
    Filed: June 6, 2011
    Publication date: December 29, 2011
    Inventor: Takahiro SHIGEMITSU
  • Publication number: 20110312446
    Abstract: A golf ball having a reduced distance while maintaining the appearance of a normal high performance trajectory. The golf ball has a core, an inner cover layer, and a cover. The core has a diameter of from about 1.300 to 1.620 inches, while the ball has a weight from 1.30 to 1.620 ounces, a diameter from 1.670 to 1.800 inches and a maximum Coefficient of Restitution from about 0.600 to about 0.790 as measured at 125 ft/sec incoming ball velocity. The ball has a drag to weight ratio of greater than 2.4 at a Reynolds number of about 207,000 and a spin ratio of about 0.095.
    Type: Application
    Filed: April 7, 2011
    Publication date: December 22, 2011
    Inventors: Michael J. Sullivan, Steven Aoyama
  • Patent number: 8044136
    Abstract: Disclosed are golf balls comprising cores or intermediate layers prepared from thermoplastic compositions having coefficients of restitution equal to or greater than 0.83 and PGA compressions greater than 100. Also disclosed is a composition comprising or prepared from (a) at least one aliphatic, mono-functional organic acid having from 16 to 20 carbon atoms, wherein the organic acid is unsaturated and linear; (b) an ethylene acid copolymer consisting essentially of copolymerized comonomers of ethylene and from 18 to 24 weight % of copolymerized comonomers of at least one C3 to C8 ?,? ethylenically unsaturated carboxylic acid, based on the total weight of the ethylene acid copolymer, having a melt index from about 200 to about 600 g/10 minutes; wherein the combined acid moieties of (a) and (b) are nominally neutralized to a level from about 120% to about 200%; and optionally (c) filler.
    Type: Grant
    Filed: October 30, 2008
    Date of Patent: October 25, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: James R. De Garavilla
  • Publication number: 20110250991
    Abstract: A golf ball 2 includes a spherical core 4 and a cover 6 positioned outside the core 4. The core 4 is obtained by crosslinking a rubber composition including 2-naphthalenethiol. The difference between: a hardness H(5.0) at a point which is located at a distance of 5 mm from the central point of the core 4; and a hardness Ho at the central point is 6.0 or greater. The difference between: a hardness H(12.5) at a point which is located at a distance of 12.5 mm from the central point; and the hardness H(5.0) is 4.0 or less. The difference between a hardness Hs at the surface of the core 4 and the hardness H(12.5) is 10.0 or greater. The difference between the hardness Hs and the hardness Ho is 22.0 or greater. There is no zone in which a hardness decreases from the central point to the surface.
    Type: Application
    Filed: March 16, 2011
    Publication date: October 13, 2011
    Inventors: Kazuhiko ISOGAWA, Seiichiro Endo
  • Patent number: 8034861
    Abstract: Golf balls consisting of a core and a cover are disclosed. The core is a solid, single-layer core formed from a rubber composition comprising a catechol. The core has a positive hardness gradient such that the difference between the core's surface hardness and the core's center hardness is 25 Shore C units or greater and/or the core has a diameter of from 1.51 inches to 1.59 inches.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: October 11, 2011
    Assignee: Acushnet Company
    Inventors: Brian Comeau, David A. Bulpett, Douglas S. Goguen, Derek A. Ladd
  • Patent number: 8034863
    Abstract: Golf balls consisting of a core and a cover are disclosed. The core is a solid, single-layer core formed from a rubber composition comprising a resorcinol. The core has a positive hardness gradient such that the difference between the core's surface hardness and the core's center hardness is 25 Shore C units or greater and/or the core has a diameter of from 1.51 inches to 1.59 inches.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: October 11, 2011
    Assignee: Acushnet Company
    Inventors: Brian Comeau, David A. Bulpett, Douglas S. Goguen, Derek A. Ladd
  • Patent number: 8025594
    Abstract: A golf ball comprising a single layer core and a cover layer disposed about the single layer core, the single layer core being formed from a substantially homogenous formulation and comprising a geometric center and an outer surface wherein an inner core region is disposed about the geometric center, an outer core region is adjacent the outer surface, and an intermediate core region is disposed between the inner and outer core regions and extends from at least about 2 mm radially from the geometric center to at least about 2 mm from the outer surface.
    Type: Grant
    Filed: June 26, 2009
    Date of Patent: September 27, 2011
    Assignee: Acushnet Company
    Inventors: Michael J. Sullivan, Brian Comeau, Douglas S. Goguen, David A. Bulpett
  • Publication number: 20110230280
    Abstract: A golf ball comprising a single layer core and a cover layer disposed about the single layer core, the single layer core being formed from a substantially homogenous formulation and comprising a geometric center and an outer surface, the single layer core further comprising an inner core region disposed about the geometric center, an outer core region adjacent the outer surface, and an intermediate core region disposed between the inner and outer core regions and extending radially from about 8 mm to about 18 mm from the geometric center. The single layer core has first, second and third hardnesses disposed within the inner core region, outer core region, intermediate core region, respectively, wherein the third hardness is greater than the first hardness and the second hardness, and a hardness of the outer surface is substantially the same as or lower than a hardness of the geometric center.
    Type: Application
    Filed: May 27, 2011
    Publication date: September 22, 2011
    Inventors: Michael J. Sullivan, Brian Comeau, Douglas S. Goguen, David A. Bulpett
  • Publication number: 20110224023
    Abstract: A golf ball has moisture resistant layer comprising a blend of at least one ionomer and hydrophobic thermoplastic polyurethane. The moisture resistant layer may be part of the cover layer, for example an inner layer of a two-layer cover layer. The moisture resistant layer may be an intermediate layer between the core and the cover.
    Type: Application
    Filed: March 4, 2011
    Publication date: September 15, 2011
    Applicant: NIKE, INC.
    Inventor: Bradley C. Tutmark
  • Publication number: 20110218056
    Abstract: A golf ball including a core and a cover including a thermoplastic inner cover layer having a material hardness of 60 to 80 Shore D; a thermoset outer cover layer comprising a castable polyurea and having a material hardness of 20 to 60 Shore D; and a thermoset intermediate cover layer disposed between the inner and outer cover layers and having a hardness substantially the same as the inner cover layer hardness and greater than the outer cover layer hardness. The inner cover includes one or more high- or low-acid ionomers and, optionally, a maleic anhydride modified polyolefin. The intermediate layer is formed from a castable liquid polybutadiene rubber.
    Type: Application
    Filed: March 4, 2010
    Publication date: September 8, 2011
    Inventors: Michael J. Sullivan, William E. Morgan, Brian Comeau, Douglas S. Goguen, David A. Bulpett
  • Publication number: 20110218054
    Abstract: A multi-piece golf ball comprising at least one component made of an ethylene-propylene diene copolymer (EPDM) rubber is provided. The multi-piece golf ball includes a cover, preferably a dual-cover having inner and outer cover layers. The outer cover is preferably made of the EPDM rubber material. The golf ball further includes an inner core, preferably a dual-core containing a center and surrounding outer core layer. The center may be made of a polybutadiene rubber composition and the outer core layer may be made of an EPDM rubber composition. The resulting golf ball has high resiliency, a soft feel, and good weatherability.
    Type: Application
    Filed: April 11, 2011
    Publication date: September 8, 2011
    Inventors: Michael J. Sullivan, David A. Bulpett, Brian Comeau, Mark L. Binette, William E. Morgan, Dennis Britton
  • Publication number: 20110218057
    Abstract: A golf ball comprising a single layer core and a cover layer disposed about the single layer core, the single layer core being formed from a substantially homogenous formulation and comprising a geometric center and an outer surface, the single layer core further comprising an inner core region disposed about the geometric center, an outer core region adjacent the outer surface, and an intermediate core region disposed between the inner and outer core regions and extending radially from about 8 mm to about 18 mm from the geometric center. The single layer core has first, second and third hardnesses disposed within the inner core region, outer core region, intermediate core region, respectively, wherein the third hardness is greater than the first hardness and the second hardness, and a hardness of the outer surface is substantially the same as or lower than a hardness of the geometric center.
    Type: Application
    Filed: May 16, 2011
    Publication date: September 8, 2011
    Inventors: Michael J. Sullivan, Brian Comeau, Douglas S. Goguen, David A. Bulpett
  • Patent number: 8013101
    Abstract: Golf ball compositions, and components formed therefrom, including trifunctional materials, such as trifunctional isocyanates, polyols, and amines, that have improved performance and durability characteristics, e.g., improved heat resistance, improved resiliency, and dimensional stability.
    Type: Grant
    Filed: April 20, 2010
    Date of Patent: September 6, 2011
    Assignee: Acushnet Company
    Inventors: Shenshen Wu, Shawn Ricci