Wood Patents (Class 48/111)
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Patent number: 11613705Abstract: A continuous system for gasification of a biomass feedstock comprising: a fuel conditioning zone, a gasification zone and a char cooling area.Type: GrantFiled: February 6, 2013Date of Patent: March 28, 2023Assignee: McGolden, LLCInventor: Michael McGolden
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Patent number: 11566191Abstract: A method and system for continuous production of contaminant free and size specific biochar using downdraft gasification of variable quality feedstock. The system and process of the present invention includes the transfer of biochar from a gasifier after gasification to a temperature-controlled cooling screw conveyor, into a drum magnet for ferrous metal removal into multiple diverters to separate and remove ungasified materials and non-ferrous metal contaminants, then transferred into a granulator for grinding and screening the biochar to a pre-selected size. By directly attaching a novel and continuous product treatment process to the biochar stream as it exits the gasifier, the particle size, moisture content, carbon content and yield of a contaminant free biochar product can be narrowly controlled and improved to meet strict product quality specifications required by specialty applications.Type: GrantFiled: December 22, 2021Date of Patent: January 31, 2023Assignee: ARIES CLEAN TECHNOLOGIES LLCInventors: Renus Kelfkens, Matthew Newman
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Patent number: 11242988Abstract: A multi-stage product gas generation system converts a carbonaceous material, such as municipal solid waste, into a product gas which may subsequently be converted into a liquid fuel or other material. One or more reactors containing bed material may be used to conduct reactions to effect the conversions. Unreacted inert feedstock contaminants present in the carbonaceous material may be separated from bed material using a portion of the product gas. A heat transfer medium collecting heat from a reaction in one stage may be applied as a reactant input in another, earlier stage.Type: GrantFiled: February 16, 2016Date of Patent: February 8, 2022Assignee: ThermoChem Recovery International, Inc.Inventors: Ravi Chandran, Daniel A. Burciaga, Daniel Michael Leo, Shawn Robert Freitas, Dave G. Newport, Justin Kevin Miller, Kaitlin Emily Harrington, Brian Christopher Attwood
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Patent number: 11091711Abstract: A separator system for treating a gas from a biomass gasification system, including: first and second cyclones, where the first cyclone includes an inlet for receiving a gas from a biomass gasification unit, the first cyclone being arranged for removing particulate matter from the gas from the biomass gasification unit in order to provide a first cleaner gas, piping arranged to lead the first cleaner gas to the second cyclone, where the second cyclone is arranged to remove particulate matter from the first cleaner gas in order to provide a second cleaner gas, a pipe arranged to lead the second cleaner gas to a special piping element, the latter including a burner, thereby providing a third cleaned gas, and a gas distribution unit arranged to lead the third cleaned gas to one or more tar reformer units. Also, a method of treating a gas from a biomass gasification system.Type: GrantFiled: August 22, 2017Date of Patent: August 17, 2021Assignee: HALDOR TOPSØE A/SInventors: Jørgen Madsen, Erik Gambarini, Erik Løgsted-Nielsen
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Patent number: 10627105Abstract: A ground supported single drum power boiler is described combining a refractory lined and insulated V-Cell floor; refractory lined and insulated combustion chamber; integrated fuel chutes configured to pre-dry wet solid fuel; top mounted fuel bin; internal chamber walls; configurable combustion air systems; and a back pass with after-burner ports and cross flow superheaters. The boiler can be configured in pre-assembled modules to minimize the field construction time and cost. An alternative embodiment is adaptable as a gasifier.Type: GrantFiled: February 27, 2017Date of Patent: April 21, 2020Inventors: Daniel R Higgins, Eugene Sullivan
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Patent number: 10059882Abstract: A method and apparatus for drying and pyrolyzing carbon-containing materials to produce valuable products including char, oil, gas and thermal energy. The present invention involves a method whereby carbon-containing material 1 is maintained in a heated region predominantly free of oxidizing gases to promote pyrolysis reactions, and the thermal energy required to drive the process is provided via the combustion of a proportion of the volatilized matter with an oxygen containing gas in the same chamber 3. The arrangement of the chamber 3 eliminates the need for any form of solid physical barrier between the concurrent pyrolysis and combustion reactions occurring in the process, and also avoids any requirement for external means of recirculating the gaseous volatilized matter. The present invention also relates to a method for improving the transfer of thermal energy from the combustion to pyrolysis zones via radiative and convective heat transfer mechanisms.Type: GrantFiled: August 29, 2013Date of Patent: August 28, 2018Assignee: EARTH SYSTEMS CONSULTING PTY LTDInventors: Philip John Sanderson, Adrian Lindsay Morphett
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Patent number: 9738841Abstract: A gasified gas production system of the present disclosure includes a gasification furnace which produces a gasified gas by gasifying a gasification raw material, a flow passage through which the gasified gas produced in the gasification furnace flows, a catalyst-holding unit which holds a catalyst which promotes reforming of tar included in the gasified gas inside the flow passage, and an oxidation agent supply unit which supplies an oxidation agent with a temperature of 200° C. to 900° C. to the catalyst.Type: GrantFiled: August 18, 2015Date of Patent: August 22, 2017Assignee: IHI CorporationInventor: Hiroaki Ohara
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Patent number: 9523053Abstract: A fuel gasification system including a gasification furnace including a fluidized bed formed by fluidizing reactant gas for gasifying fuel charged into gasification gas and flammable solid content, a combustion furnace for combustion of the flammable solid content into which the flammable solid content produced in the furnace is introduced together with bed material and that includes a fluidized bed formed by fluidizing reactant gas, a material separator such as hot cyclone that separates bed material from exhaust gas introduced from the combustion furnace, the separated bed material being fed through a downcomer to the gasification furnace, and a tar decomposing mechanism that heats the gasification gas produced in the furnace to decompose tar contained in the gasification gas.Type: GrantFiled: April 8, 2014Date of Patent: December 20, 2016Assignee: IHI CORPORATIONInventors: Takahiro Murakami, Koubun Kyo, Toshiyuki Suda
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Patent number: 9499753Abstract: The present invention relates to a gasification process and system, wherein a dryer integrated with a water-gas-shift catalyst is disposed in front of a gasifier.Type: GrantFiled: December 11, 2013Date of Patent: November 22, 2016Assignees: SK INNOVATION CO., LTD., SK ENERGY CO., LTD.Inventors: Jong Sung Park, Ji Sung Park, Cheon Seong Lee, Gyoo Tae Kim, Jae Wook Shin, Yong Jeon Kim
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Patent number: 9057031Abstract: A process for the co-gasification of carbonaceous solids (coal, coke) and biomass in which the biomass material is pyrolyzed to provide a biomass pyrolysis oil and biomass char or coke which are then mixed with the carbonaceous solid to form a slurry. This slurry is then heated if necessary to achieve a viscosity which can be processed conveniently in the gasifier. The heat required for pyrolyzing the biomass can conveniently be obtained from the heat exchanger used to cool the hot synthesis gas product emerging from the gasifier.Type: GrantFiled: September 29, 2009Date of Patent: June 16, 2015Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Ramesh Varadaraj, John L. Robbins, Michael Siskin
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Patent number: 9045706Abstract: A process is provided for producing syngas that is effective for use in downstream processes. The process for producing syngas includes operating a gasification apparatus in a start-up mode until the gasification apparatus and equipment downstream of the gasification apparatus are adequately warmed up to a first target temperature. Upon reaching a first target temperature, the process is then operated in a production mode to produce a second syngas with a higher CO/CO2 molar ratio. Operation in a start-up mode until reaching a first target temperature, provides a process that is effective for reducing fouling in downstream equipment and for providing a second syngas can be more effectively cooled and cleaned.Type: GrantFiled: May 13, 2014Date of Patent: June 2, 2015Assignee: INEOS BIO SAInventors: Ching-Whan Ko, Michael Sean Slape, Peter Simpson Bell, Kim Ocfemia
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Patent number: 9045704Abstract: A gasification reactor for producing crude gas, containing CO or H2, by gasification of ash-containing fuel with oxygen-containing gas, at temperatures above the melting temperature of the ash, has a reaction chamber formed by a membrane wall through which coolant flows, within a pressure container, is provided, with a narrowing transition channel into a gas cooling chamber, and spin-reducing, cooled bulkheads in the transition channel. The, wall that carries the bulkheads makes a transition, below the bulkheads, into a cylinder wall that is reduced in diameter, by way of a step having a corrugated surface. The cylinder wall, which is reduced in diameter, is enclosed by a further cylindrical wall, which is enlarged in diameter, which wall forms a second slag drip edge at its end, in the direction of gravity. The further cylindrical wall is disposed to be adjustable in its vertical position, with reference to the first drip edge.Type: GrantFiled: July 16, 2010Date of Patent: June 2, 2015Assignee: ThyssenKrupp Uhde GmbHInventors: Eberhard Kuske, Johannes Dostal, Reinald Schulze Eckel, Lothar Semrau
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Publication number: 20150135594Abstract: A gasification apparatus can produce hydrogen-containing gas from biomass with high thermal efficiency at low costs without severe trouble caused by tar generated by pyrolyzing the biomass, while maximizing the gasification rate of the tar. The gasification apparatus includes a biomass pyrolyzing zone for heating biomass in a non-oxidizing atmosphere, and a gas reforming zone for heating the resulting pyrolyzed gas in the presence of steam. A plurality of preheated granules and/or lumps is moved from the gas reforming zone to the biomass pyrolyzing zone, the apparatus reforms the gas generated by pyrolyzing the biomass and pyrolyzes the biomass, using the heat of the granules and/or lumps. The biomass pyrolyzing zone and the gas reforming zone is provided in a single vessel, and at least one partitioning plate is provided between the biomass pyrolyzing zone and the gas reforming zone.Type: ApplicationFiled: May 13, 2013Publication date: May 21, 2015Applicant: JAPAN BLUE ENERGY CO., LTD.Inventors: Naoki Dowaki, Kiyoshi Dowaki, Yasuie Takeda, Hiroshi Ikeda, Kousuke Suda, Fumie Kagaya, Hisashi Kamiuchi, Mitsuo Kameyama
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Patent number: 8999019Abstract: The present invention relates to a process and system for gasifying biomass or other carbonaceous feedstocks in an indirectly heated gasifier and provides a method for the elimination of condensable organic materials (tars) from the resulting product gas with an integrated tar removal step. More specifically, this tar removal step utilizes the circulating heat carrier to crack the organics and produce additional product gas. As a benefit of the above process, and because the heat carrier circulates through alternating steam and oxidizing zones in the process, deactivation of the cracking reactions is eliminated.Type: GrantFiled: October 23, 2006Date of Patent: April 7, 2015Assignee: Taylor Biomass Energy, LLCInventor: Mark A. Paisley
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Publication number: 20150075071Abstract: A biofuel gasification reactor for producing gases that are combustible in an internal combustion engine. The reactor includes a vessel with a loading port and cover, sized to receive biofuel of at least eight by twenty inches. A storage zone provides biofuel via gravity feed only to a plasma zone that oxidizes the biofuel into char and precursor gases. Air nozzles provide air to the plasma zone from a helical air preheater. A char zone receives the precursor gases and char. The precursor gases are substantially converted to effluent gases of hydrogen and carbon monoxide. A grating below the char zone holds the char until it is oxidized to ash. The grating covers the entire bottom of the char zone. The grating is disposed in a substantially fixed and immovable configuration during the operation of the reactor.Type: ApplicationFiled: September 13, 2013Publication date: March 19, 2015Inventor: Joseph T. Williams
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Publication number: 20150059245Abstract: Apparatuses, systems, mobile gasification systems, and methods for gasifying residual biomass are described. An example system may include a mobile gasification system configured to gasify feedstock generated from residual biomass to provide syngas. The mobile gasification system may be configured to generate electrical power using the syngas. The mobile gasification system may be configured to be installed in a transportable structure.Type: ApplicationFiled: September 4, 2014Publication date: March 5, 2015Inventors: Philip W. Appel, Thomas D. Weir, Jacob M. Culley, Timothy E. Farley, Daniel A. Howard, Sarah E. Love
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Publication number: 20150040565Abstract: The present application provides a reactor for: converting feedstock material into gases; or disassociating or reforming a chemical compound; and/a a mixture to its constituent elements; and/to other chemical forms, and; finally a heating device. The reactor comprises a heating device for discharging an ionized gas into the reactor, a feedstock feeder for injecting the feedstock material into the reactor, and a shell forming a chamber that encloses a portion of the heating device and a portion of the feedstock feeder. The application also provides a method for converting hydrocarbon material into synthetic gases. The method comprises: providing the hydrocarbon material to a burner inserted into a reactor, a second step of supplying ionized gases into the reactor, and a third step of subjecting the burner to a flame of the ionized gases such that molecules of the hydrocarbon material are dissociated to forming synthetic gas.Type: ApplicationFiled: November 29, 2012Publication date: February 12, 2015Inventor: Lien Chiow Tan
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Publication number: 20150013224Abstract: A method and a device for producing synthesis gas from biomass, wherein the biomass is decomposed into pyrolysis coke and pyrolisis gas in at least one pyrolisis reactor, the pyrolysis coke is introduced into the fluidised bed of a synthesis gas reactor and the pyrolysis gas is used as fluidisation gas for the synthesis gas reactor.Type: ApplicationFiled: July 25, 2014Publication date: January 15, 2015Inventor: Karl-Heinz Tetzlaff
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Publication number: 20140318013Abstract: A method, apparatus, and system for a solar-driven chemical plant that may include a solar thermal receiver having a cavity with an inner wall, where the solar thermal receiver is aligned to absorb concentrated solar energy from one or more of 1) an array of heliostats, 2) solar concentrating dishes, and 3) any combination of the two. Some embodiments may include a solar-driven chemical reactor having multiple reactor tubes located inside the cavity of solar thermal receiver, wherein a chemical reaction driven by radiant heat occurs in the multiple reactor tubes, and wherein particles of biomass are gasified in the presence of a steam (H2O) carrier gas and methane (CH4) in a simultaneous steam reformation and steam biomass gasification reaction to produce reaction products that include hydrogen and carbon monoxide gas using the solar thermal energy from the absorbed concentrated solar energy in the multiple reactor tubes.Type: ApplicationFiled: July 8, 2014Publication date: October 30, 2014Inventors: Wayne W. Simmons, Christopher Perkins, Zoran Radojica Zovanovic
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Patent number: 8850715Abstract: What is described is a process and an installation for drying articles, in particular painted vehicle bodies, in which the articles are moved through a drying zone in which they are hardened in an inert-gas atmosphere. Inert gas is taken from the drying zone constantly or intermittently and is first of all conducted along a first face which is at a first temperature at which higher-boiling contaminants condense out. The condensate that forms in the process is discharged. After that, the inert gas which has been pre-cleaned in this way is conducted along at least one second face which is at a lower temperature than the first face. Lower-boiling contaminants are precipitated at this point. These condensates, too, are then discharged. This process and installation work more favorably, energy-wise, and with higher cleaning efficiency than known processes and installations of a similar type.Type: GrantFiled: September 4, 2007Date of Patent: October 7, 2014Assignee: Eisenmann AGInventors: Werner Swoboda, Andreas Keller
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Publication number: 20140290593Abstract: The invention relates to a reactor (1) for gasifying biomass, in particular wood, comprising a feeder chute (7) and an ash bed arranged beneath the feeder chute (7). According to the invention, a device is provided by means of which biomass adhering to the feeder chute (7) can be detached, and/or a heat exchanger is provided by means of which a product gas generated from the biomass gives oil heat to the biomass subsequently conveyed in the feeder chute (7) and to oxidation air. The invention further relates to a fine filter (29) for cleaning a product gas generated from biomass. According to the invention, the filter medium contains biomass. Furthermore, the invention relates to a method for gasifying biomass in a reactor (1), in particular a reactor (1) according to the invention, to form a product gas. According to the invention, biomass adhering to the feeder chute (7) is detached and/or heat is given off to biomass and to oxidation air by the product gas.Type: ApplicationFiled: May 24, 2012Publication date: October 2, 2014Applicant: REP RENEWABLE ENERGY PRODUCTS GMBHInventor: Franz Krammer
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Publication number: 20140259925Abstract: A gasification system including: a casing defining: a solid material inlet; a fixed bed drying zone proximal the solid material inlet; a fixed bed pyrolysis zone arranged below the drying zone along a gravity vector, distal the solid material inlet across the pyrolysis zone; a kinetic bed combustion zone surrounded by the pyrolysis zone; and a fluidization channel extending through the drying zone and pyrolysis zone and fluidly connected to the combustion zone, the fluidization channel defining a kinetic bed reduction zone fluidly isolated from and thermally connected to the pyrolysis zone and the drying zone by the fluidization channel.Type: ApplicationFiled: March 17, 2014Publication date: September 18, 2014Applicant: All Power Labs, Inc.Inventor: James Mason
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Publication number: 20140223824Abstract: An apparatus for one stage thermo-catalytic plasma gasification and vitrification of organic material comprising: a generally funnel-shaped reactor having an upper section and a lower section, the lower section comprising a first, wider portion connected by a frustoconical transition to a second, narrower portion, and being suitable to receive a catalyst bed, and the upper section having at least one gas exhaust port; a plurality of inlets for the material from a plurality of directions located at the upper part of the lower section for introducing material into the upper portion of the lower section; a gas inlet system disposed around the lower section to provide gas into the lower section through one or more intake ports in the lower section; and a plurality of plasma arc torches mounted in the lower section to heat the catalyst bed and material, along with a method for plasma treatment of biomass.Type: ApplicationFiled: February 12, 2013Publication date: August 14, 2014Applicant: Solena Fuels CoprorationInventors: Robert T. Do, Sylvain A. Motycka
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Publication number: 20140223822Abstract: A method and system for producing synthesis gas comprising CO, CO2, and H2 from a carbonaceous stream using an oxygen containing stream. A stream containing a carbonaceous material, and a stream containing oxygen are injected into a gasification reactor, where the carbonaceous stream is partially oxidised to obtain a raw synthesis gas. The raw synthesis gas is removed from the gasification reactor and directed into a quenching section wherein a liquid, preferably water, is injected in the form of a mist.Type: ApplicationFiled: February 4, 2014Publication date: August 14, 2014Applicant: Shell Oil CompanyInventors: Robert Erwin VAN DEN BERG, Franciscus Gerardus VAN DONGEN, Thomas Paul VON KOSSAK-GLOWCZEWSKI, Hendrik Jan VAN DER PLOEG, Pieter Lammert ZUIDEVELD
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Publication number: 20140196369Abstract: Embodiments are directed to a gasifier that electrodynamically agitates charged chemical species in a reaction region of a reaction vessel of a gasifier and related methods. In an embodiment, a gasifier includes a reaction vessel configured to gasify at least one hydrocarbon-containing feed material to synthesis gas. The reaction vessel includes an inlet(s) for receiving a gasification medium that reacts with the at least one hydrocarbon-containing feed material and an outlet for allowing the synthesis gas to exit from the reaction vessel, and a reaction region. The gasifier includes at least one electrode positioned to be in electrical communication with the reaction region, and a voltage source operatively coupled to the at least one electrode. The voltage source and the at least one electrode are cooperatively configured to generate a time varying electric field in the reaction region to effect electrodynamic mixing of charged chemical species therein during gasification.Type: ApplicationFiled: January 13, 2014Publication date: July 17, 2014Applicant: ClearSign Combustion CorporationInventor: Christopher A. Wiklof
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Publication number: 20140182490Abstract: Disclosed here are example gasifiers for gasification of solid carbon fuel. An example gasifier includes a vertical vessel that includes feeding means for introducing a fuel at a top and along a first vertical axis in the vessel. The example vessel also includes a pyrolysis zone for pyrolysis of the fuel, a combustion zone for burning pyrolysis gases from the pyrolysis zone, a reduction zone for gasifying carbonized fuel from the pyrolysis zone and an outlet for collecting gases produced in the reduction zone. In addition, the example vessel includes a horizontal plate fixedly mounted between the feeding means and the pyrolysis zone for receiving and retaining the fuel introduced into the vessel. Also, the example vessel includes a movable pusher mounted between the feeding means and the horizontal plate, the movable pusher to push the fuel retained on the horizontal plate into the pyrolysis zone and positioned or positionable above the horizontal plate.Type: ApplicationFiled: March 4, 2014Publication date: July 3, 2014Applicant: Xylowatt, S.A.Inventors: Frederic Bourgois, Alexandre Bacq, Johan Klein, Michael Haube
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Publication number: 20140102000Abstract: Gasifiers for the gasification of solid carbon-based fuels are disclosed herein. An example gasifier includes an inlet chamber for introducing fuel into the gasifier and a pyrolysis region for pyrolyzing the fuel introduced into the vessel. The pyrolysis region includes first means for admission of a pyrolysis agent. The example gasifier also includes a combustion region for incinerating pyrolysis gases originating from the pyrolysis region, where the combustion region includes second means for admission of a gasifying agent. Also, the example gasifier includes a reduction region for gasifying carbonized fuel originating from the pyrolysis region, an outlet for collecting gases originating from the reduction region, and a region for collecting and discharging ashes. In addition, the example gasifier includes active transfer means to actively transfer solid material from the pyrolysis region to the reduction region.Type: ApplicationFiled: December 23, 2013Publication date: April 17, 2014Inventors: Michael Haube, Johan Klein, Frederic Bourgois, Alexandre Bacq
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Publication number: 20140093447Abstract: Disclosed is an apparatus and method for capturing the hot humid gases from a gypsum board dryer and utilizing those gases in the production of a synthetic gas (referred to as “syngas”). The syngas produced can then be utilized within a gypsum board plant to reduce the amount of natural gas needed. The method utilizes the heated water vapor (H2O) and carbon dioxide (CO2) found within the flue gas of a board dryer. The H2O and CO2 are used in a gasification process to yield the syngas.Type: ApplicationFiled: September 30, 2013Publication date: April 3, 2014Inventor: John W. College
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Publication number: 20140083010Abstract: A process for producing fuel gas and for carrying out a metallurgical process includes providing first and second process stages. In the first process stage, biomass is reacted with an oxygen-containing gas so as to obtain a fuel gas containing at least one of carbon monoxide, hydrogen, carbon dioxide and steam. The fuel gas is cooled to a temperature in a range from 300 to 600° C. The cooled fuel gas is subjected to a solids separation. In the second process stage, the fuel gas after the solids separation is directly supplied to at least one burner of the metallurgical process, the temperature of the fuel gas being maintained above the condensation temperature of tar and within the range from 300 to 600° C. by supplying heat.Type: ApplicationFiled: March 29, 2012Publication date: March 27, 2014Applicant: OUTOTEC OYJInventors: Andreas Orth, Agnes Von Garnier
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Publication number: 20140069010Abstract: The present disclosure relates generally to novel biomass pyrolysis processes and systems that decrease entrainment of char and other contaminants with the pyrolysis vapors. In certain embodiments, the present disclosure provides methods and systems to prevent entrainment of particles of char and heat carrier with pyrolysis vapors leaving a reactor, while allowing rapid upgrading of the vapors by catalyst(s) that are held in a an upgrading reactor and protected from contact with the char.Type: ApplicationFiled: September 9, 2013Publication date: March 13, 2014Applicant: Phillips 66 CompanyInventors: Mark A. Hughes, Tie-Pan Shi, Richard D. Sadok, Samuel T. Jones, Johnathan T. Gorke, Natalie A. Rebacz, Liang Zhang, Martin L. Perkins
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Publication number: 20140053465Abstract: A gasification furnace for gasifying a biomass resource in a manner producing a low quantity of tar. The gasification furnace (10) is provided with a punching plate (11) partitioning the furnace interior into upper and lower spaces; a biomass resource supply port (10a) for supplying the biomass resource over the punching plate (11); a first oxidizer supply port (10c) and a second oxidizer supply port (10d) for supplying an oxidizer into the furnace; a first oxidizer supply path supplying the oxidizer from the first oxidizer supply port (10c) from above towards below the punching plate (11); a second oxidizer supply path distributing and supplying to a plurality of locations within a predetermined area in the vicinity of the punching plate (11) from the second oxidizer supply port (10d); and a dry distillation gas output (10b) for discharging dry distillation gas generated by the pyrolysis and partial oxidation of the biomass resource on the punching plate (11) to the outside.Type: ApplicationFiled: November 7, 2011Publication date: February 27, 2014Applicants: ZE ENERGY INC.Inventor: Yasuharu Matsushita
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Patent number: 8641991Abstract: The present invention is generally directed to methods and systems for processing biomass into usable products, wherein such methods and systems involve an integration into conventional refineries and/or conventional refinery processes. Such methods and systems provide for an enhanced ability to utilize biofuels efficiently, and they can, at least in some embodiments, be used in hybrid refineries alongside conventional refinery processes.Type: GrantFiled: August 30, 2007Date of Patent: February 4, 2014Assignee: Chevron U.S.A. Inc.Inventor: William L. Schinski
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Publication number: 20130291437Abstract: The present invention relates to a method and apparatus (10) for use in rarefying a syngas so as to improve a calorific value of the syngas through the reduction of a concentration of tar from the syngas. The apparatus (10) comprises a gasification/pyrolysis means (12) such as a kiln (11), for generation of a flow of syngas from a raw material, and a cracking means (14). The cracking means (14) comprising a body (42) having an insulated internal volume (44) adapted to hold a heated bed of char. The flow of syngas from the kiln (11) is directed through the cracking means (14) where it comes into contact with the heated bed of char. Heavy long-chained carbon based molecules within the syngas undergo a cracking reaction and are broken into constituent lighter carbon based molecules. The method and apparatus of the present invention provides a rarefied output flow of syngas having an improved calorific quality and a substantially reduced concentration of tar.Type: ApplicationFiled: May 13, 2011Publication date: November 7, 2013Applicant: ANSAC PTY LTDInventors: Michael Joseph Martella, Dongke Zhang
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Patent number: 8529644Abstract: Disclosed are a method and a corresponding apparatus for converting a biomass reactant into synthesis gas. The method includes the steps of (1) heating biomass in a first molten liquid bath at a first temperature, wherein the first temperature is at least about 100° C., but less than the decomposition temperature of the biomass, wherein gas comprising water is evaporated and air is pressed from the biomass, thereby yielding dried biomass with minimal air content. (2) Recapturing the moisture evaporated from the biomass in step 1 for use in the process gas. (3) Heating the dried biomass in a second molten liquid bath at a second temperature, wherein the second temperature is sufficiently high to cause flash pyrolysis of the dried biomass, thereby yielding product gases, tar, and char. (4) Inserting recaptured steam into the process gas, which may optionally include external natural gas or hydrogen gas or recycled syngas for mixing and reforming with tar and non-condensable gases.Type: GrantFiled: December 9, 2010Date of Patent: September 10, 2013Assignee: The United States of America as represented by the Secretary of AgricultureInventors: Mark A. Dietenberger, Mark H. Anderson
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Publication number: 20130212944Abstract: A zirconium-based mixed oxide or zirconium-based mixed hydroxide which is capable of (a) at least 90% v/v conversion of naphthalene at atmospheric pressure at a temperature in the range 600-700° C. using a residence time of about 0.3 seconds, and/or (b) providing an initial heat of adsorption of ammonia of greater than 150 kJ/mol when measured by ammonia flowing gas microcalorimetry. Also, a method for purifying gas produced from the gasification of carbonaceous materials, comprising the step of bringing the gas into contact with such mixed oxides or mixed hydroxides.Type: ApplicationFiled: August 22, 2011Publication date: August 22, 2013Applicants: VALTION TEKNILLINEN TUTKIMUSKESKUS, MAGNESIUM ELEKTRON LIMITEDInventors: Hazel Stephenson, Heather Bradshaw, Pekka Simell, Anu Solla, Ella Ronkkonen, Outi Krause
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Patent number: 8506917Abstract: In a circulating fluidized-bed gasification system, an ammonia-off gas 30 from an ammonia remover 25 is fed to a catalytic denitrator 15 with a flow rate regulated such that a molar ratio of the ammonia in the ammonia off-gas 30 from the ammonia recover 25 to nitrogen oxides in an exhaust gas 6 from a combustion furnace 1 is kept within a setting range, and a reminder of the ammonia off-gas 30 is fed to the combustion furnace 1.Type: GrantFiled: October 14, 2010Date of Patent: August 13, 2013Assignee: IHI CorporationInventors: Hiroaki Ohara, Koki Hamada
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Publication number: 20130199093Abstract: In various embodiments, the present invention provides a reaction chamber, including a catalyst, and a heating chamber configured to receive light. The heating chamber is positioned underneath at least a portion of the reaction chamber.Type: ApplicationFiled: February 7, 2013Publication date: August 8, 2013Applicant: Regents of the University of MinnesotaInventor: Regents of the University of Minnesota
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Publication number: 20130185999Abstract: A device for converting a fuel including solid components, known as a solid fuel, into a gaseous fuel, includes a pyrolysis zone (2) for pyrolyzing solid fuel, having pyrolysis elements that are capable of decomposing the solid fuel into a pyrolysis gas and into a solid pyrolysis residue, known as coke, and a combustion zone (3), which is distinct from the pyrolysis zone (2), for burning the pyrolysis gas and having combustion elements (31, 32, 33). The device also includes elements for circulating pyrolysis gas from the pyrolysis zone (2) to the combustion zone (3), which is surrounded by the pyrolysis zone (2).Type: ApplicationFiled: October 5, 2011Publication date: July 25, 2013Applicant: S3DInventors: Li Chen, Anthony Kerihuel, Luc Gerun
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Publication number: 20130133305Abstract: A system includes a gasifier having a first enclosure having a first inlet, a first outlet, and a first interior volume. The first inlet is configured to receive a first fuel feedstock into the first interior volume, and the first outlet is configured to output a first syngas away from the first interior volume. The system also includes a plasma gasifier disposed downstream from the first outlet and coupled to a waste stream produced by the gasifier from the first fuel feedstock.Type: ApplicationFiled: January 24, 2013Publication date: May 30, 2013Applicant: GENERAL ELECTRIC COMPANYInventor: General Electric Company
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Method and system for wasteless processing and complete utilization of municipal and domestic wastes
Patent number: 8419902Abstract: Proposed are a system and method for wasteless pyrolytic processing and complete utilization of municipal and domestic wastes. The wastes are sequentially passed through units of sorting, grinding, drying, accumulating, and sending to a pyrolysis reactor for pyrolytic treatment. The syngas produced in the pyrolysis is passed through dry cleaning, dust catching, a first wet cleaning with water, a second wet cleaning with alkali, and a floatation unit for separation of water which is purified to an extent sufficient for technical use. The purified syngas is also passed through an absorber and is then used as a working medium for a power generation unit such as a gas turbine co-generator that generates electricity. Solid products of the pyrolysis reaction, such as coke, are returned to the reactor for afterburning, and the heat of the reaction can be utilized in a dryer, or the like.Type: GrantFiled: May 19, 2009Date of Patent: April 16, 2013Assignee: Greenlight Energy Solutions, LLCInventors: Arkady Feerer, Marat Hasbulatovich Kulakov, Denis Zagorsky -
Patent number: 8398730Abstract: A method of producing substitute natural gas (SNG) includes providing a gasification reactor having a cavity defined at least partially by a first wall. The reactor also includes a first passage defined at least partially by at least a portion of the first wall and a second wall, wherein the first passage is in heat transfer communication with the first wall. The reactor further includes a second passage defined at least partially by at least a portion of the second wall and a third wall. The method also includes coupling the cavity in flow communication with the first and second passages. The method further includes producing a first synthetic gas (syngas) stream within the cavity. The method also includes channeling at least a portion of the first syngas stream to the first and second passages.Type: GrantFiled: July 23, 2008Date of Patent: March 19, 2013Assignee: General Electric CompanyInventors: Paul Steven Wallace, Arnaldo Frydman
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Patent number: 8372166Abstract: A controlled zone gasification reactor for a plasma assisted gasification reaction system is disclosed for converting fuel, such as, but not limited to, biomass, to syngas to replace petroleum based fuels used in power generation. The system may be a modular system housed within a frame facilitating relatively easy transportation. The system may include a reactor vessel with distinct reaction zones that facilitate greater control and a more efficient system. The system may include a syngas heater channeling syngas collected downstream of the carbon layer support and to the pyrolysis reaction zone. The system may also include a syngas separation chamber configured to produce clean syngas, thereby requiring less filtering. The system may further include an agitator drive assembly that prevents formation of burn channels with in the fuel.Type: GrantFiled: November 15, 2010Date of Patent: February 12, 2013Assignee: AdaptiveARC, Inc.Inventor: Christian H. A. Juvan
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Patent number: 8372167Abstract: A controlled zone gasification reactor with an agitator drive assembly for a plasma assisted gasification reaction system is disclosed for converting fuel, such as, but not limited to, biomass, to syngas to replace petroleum based fuels used in power generation. The agitator drive assembly that prevents formation of burn channels with in the fuel. The agitator drive assembly may include a syngas separation chamber configured to produce clean syngas, thereby requiring less filtering. The syngas separation chamber may feed syngas downstream to a syngas heater in a pyrolysis reaction zone in the reactor vessel.Type: GrantFiled: November 15, 2010Date of Patent: February 12, 2013Assignee: AdaptiveARC, Inc.Inventor: Christian H. A. Juvan
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Publication number: 20130019529Abstract: A method for producing synthesis gas, including: 1) pre-processing a biomass raw material; 2) pyrolyzing the biomass raw material to yield a pyrolysis gas and a carbon powder; 3) separating the pyrolysis gas from the carbon powder and a solid heat carrier; 4) separating the carbon powder away from the solid heat carrier via a solid-solid separator; 5) conveying the generated pyrolysis gas to a condensate tank for spray condensation, condensing a condensable part in the pyrolysis gas to generate biological fuel oil, pressurizing the generated biological fuel oil by a high pressure oil pump and feeding to a gasification furnace to be gasified; and 6) feeding one part of non-condensable pyrolysis gas to a combustion bed to combust with air, and conveying the other part of the non-condensable pyrolysis gas to the pyrolysis bed as a fluidizing medium.Type: ApplicationFiled: September 24, 2012Publication date: January 24, 2013Applicant: WUHAN KAIDI ENGINEERING TECHNOLOGY RESEARCH INSTITUTE CO., LTD.Inventor: WUHAN KAIDI ENG. TECH. RES. INS. CO., LTD.
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Patent number: 8317886Abstract: An apparatus and method for starved air gasification of solid organic materials, including biomass and other wastes, to convert the chemical energy stored in such materials to thermal energy or gaseous products that may be used in biochemical and/or chemical synthesis. Specifically, the system utilizes a gasifier having a “moving bed of ash” hearth wherein the feedstock is partially oxidized at a low temperature (less than 1500 degrees F.) in a square or rectangular chamber having a vaulted, tapered or flat roof.Type: GrantFiled: November 7, 2003Date of Patent: November 27, 2012Assignee: Nexterra Systems Corp.Inventors: Robert G. Graham, Jan Barynin, Kenneth M. Davison, Dave Berner
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Patent number: 8216345Abstract: A gasification system is disclosed having a combustion or reaction vessel, a scrubber housing, and a filter housing. A carbonaceous fuel is partially combusted in the reaction vessel to generate a combustible gas. An improved ash support and removal system reduces clogging and other problems in the reaction vessel. The combustible gas passes through the scrubber housing to remove matter such as tar and oil, and the scrubbed gas passes through a hybrid blower to the filter housing. Wood chips are used in the filter housing to provide a relatively clean, dry gas. Wastewater and other waste products from the scrubber housing and filter housing are captured and returned to the reaction vessel.Type: GrantFiled: April 10, 2008Date of Patent: July 10, 2012Assignee: Verde Reformation, Inc.Inventors: Jackie W. Rogers, Michael W. Rogers
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Patent number: 8206471Abstract: Efficient biomass conversion systems, methods and apparatus utilize a fast pyrolysis unit installed at a sawmill or similar location where substantial quantities of biomass are generated, with the biomass generated at the sawmill fed into the fast pyrolysis unit under pyrolytic reaction conditions, and with exhaust gases containing entrained matter resulting from the pyrolytic reactions being separated into constituent char and bio-fuel constituents.Type: GrantFiled: May 15, 2009Date of Patent: June 26, 2012Assignee: American Bio Energy Converting Corp.Inventor: Johnny M. Tharpe, Jr.
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Patent number: 8084656Abstract: The various embodiments of the present invention relate generally to the process of gasification and the production of synthesis gas. More particularly, the various embodiments of the present disclosure relate to the process of biomass gasification and the reduction or elimination of tars from the hydrocarbon-rich product gas derived from biomass gasification. The present invention comprises systems and methods for the reduction of tar from a synthesis gas derived from biomass gasification.Type: GrantFiled: October 9, 2008Date of Patent: December 27, 2011Assignee: Rentech, Inc.Inventor: Herman Feldmann
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Patent number: 8062392Abstract: The present invention discloses a system for biomass treatment which addresses the need to find economical solutions to transport biomass. In the present invention, small, distributed gasifiers convert the biomass into synthesis gas (“syngas”). The syngas is then transported via a pipeline network to a central fuel production facility.Type: GrantFiled: December 17, 2008Date of Patent: November 22, 2011Assignee: Texaco Inc.Inventors: Paul F. Bryan, Yunquan Liu, Curtis L. Krause
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Patent number: 7964026Abstract: A gasification system having a combustor vessel, an optional scrubber vessel, an optional fixer vessel, an optional cyclone vessel and an optional demister vessel. A wide variety of possibly moist solid or semi-solid carbonaceous fuels may be partially combusted in the combustor to generate a combustible gas and a mineral ash. An improved ash support and removal subsystem reduces clogging and other problems. The combustible gas is conveyed by optional heavy-duty blowers through the optional vessels to remove liquids and particulates and to undergo catalytic chemical reactions to provide a relatively clean, dry, highly-combustible hydrocarbon gas that captures a relatively high fraction of the potential heating value of the fuel. Internal gases, liquids and particulates from the vessels may be recycled inside the system to improve efficiency and prevent liquid waste. A portion of the internal liquids may also be extracted for other uses.Type: GrantFiled: July 17, 2006Date of Patent: June 21, 2011Assignee: Power Reclamation, Inc.Inventor: Michael W. Rogers