Abstract: A method for operating a reformer installation for providing hydrogen-containing gas, especially during a starting phase of energy generation using a fuel cell, includes feeding an incoming stream to and discharging an outgoing stream from, the reformer unit, branching-off at least one outflowing partial stream from the outgoing stream, and feeding-back the outflowing partial stream, as an inflowing partial stream, to the incoming stream, to at least partially form a circulating stream. The outflowing partial stream has a composition corresponding to a composition of the outgoing stream upon emerging from the reformer unit. A reformer installation includes at least one reformer unit having feed and discharge lines and a line connecting the discharge line to the feed line, at least partially forming a circulating stream. The method and installation provide a highly efficient production of hydrogen and especially short times required for starting the reformer installation.

Abstract: A distillate fuel steam reformer system in which a fuel feed stream is first separated into two process streams: an aliphatics-rich, sulfur-depleted gas stream, and an aromatics- and sulfur-rich liquid residue stream. The aliphatics-rich gas stream is desulfurized, mixed with steam, and converted in a reforming reactor to a hydrogen-rich product stream. The aromatics-rich residue stream is mixed with air and combusted to provide heat necessary for endothermic process operations. Reducing the amounts of sulfur and aromatic hydrocarbons directed to desulfurzation and reforming operations minimizes the size and weight of the overall apparatus. The process of the invention is well suited to the use of microchannel apparatuses for heat exchangers, reactors, and other system components, which may be assembled in slab configuration, further reducing system size and weight.

Abstract: An arrangement for generating a hydrogen-containing gas from a hydrocarbon-containing medium includes a multi-stage reforming unit that is connected to a multi-stage carbon monoxide removal unit by a heat-conducting separating medium. The stages of the reforming unit, in an ascending order relative to the gas flow direction in the reforming unit, are in a thermal contact with stages of the carbon monoxide removal unit, in a descending order relative to the gas flow direction in the carbon monoxide removal unit.

Abstract: Disclosed is a novel method for steam reforming, by which selectivity to carbon monoxide is high, which is free from various side reactions, which may be carried out at a lower temperature and at a lower pressure than the conventional methods, and which may be carried out even if a catalyst is not used. In the method of the present invention, direct current pulse discharge is performed in a mixed gas containing a gaseous chain hydrocarbon and water vapor so as to react the chain hydrocarbon and the water vapor, thereby generating hydrogen and carbon monoxide.

Abstract: A multi-stage shift reactor reduces a carbon monoxide content in a hydrogen-rich gas mixture stream flowing through the shift reactor in a flow direction. At least two catalyst carrier bodies have a honeycomb structure with passages through which the gas mixture stream can flow and are disposed in succession along the gas mixture stream flow direction. At least one heat exchanger is disposed between the at least two catalyst carrier bodies. Such a shift reactor is particularly suitable for the highly dynamic carbon monoxide conversion in a mobile fuel cell system. A method for reducing a carbon monoxide content in a hydrogen-rich gas mixture stream is also provided.

Abstract: A process for the production of synthesis gas from a hydrocarbon fuel and steam and/or oxygen gas wherein at least part of any steam requirement is provided by heat exchange against exhaust gas from a gas turbine driving an air separation unit supplying at least part of any oxygen requirement for the synthesis gas production. The process is particularly applicable when the synthesis gas is used to prepare a synfuel by methanol synthesis or a Fischer-Tropsch process.

Abstract: A gas generator for generating a hydrogen-rich carbon-monoxide-lean gas from a water-fuel mixture by catalytic steam reforming and/or from an oxygen-fuel mixture by partial oxidation includes at least one fuel reservoir vessel; a reforming reactor; a CO shift reactor; a gas purifying unit; and a line to feed water from a water reservoir vessel into the reformate gas stream fed to the CO shift reactor. The water reservoir vessel contains a water-methanol mixture having a mixing ratio effective to ensure adequate frost protection.

Abstract: A method for gasifying carbonaceous materials to fuel gases comprises the formation of an ultra-superheated steam (USS) composition substantially containing water vapor, carbon dioxide and highly reactive free radicals thereof, at a temperature of about 2400° F. (1316° C.) to about 5000° F. (2760° C.). The USS composition comprising a high temperature clear, colorless flame is contacted with a carbonaceous material for rapid gasification/reforming thereof. The need for significant superstoichiometric steam addition for temperature control. Methods for controlling a gasification/reforming system to enhance efficiency are described. A USS burner for a fluidized bed gasification/reforming reactor, and methods of construction, are described.

Abstract: Provided is a method and apparatus for producing hydrogen from an input gas stream containing carbon monoxide and steam that includes contacting the input gas stream with a catalyst. The catalyst contains an inorganic oxide support; a platinum group metal dispersed on the inorganic oxide support; and a methane suppressing dispersed on the inorganic oxide support. The methane suppressing component is selected from the group consisting of oxides of tin, oxides of gallium and combinations thereof. Also provided are preferred catalyst preparations.

Abstract: Process and reaction unit for isothermal shift conversion of a carbon monoxide containing feed gas, the process comprising the steps of

Abstract: An apparatus and a method of generating a carburizing atmosphere are provided which can stably generate a reformed gas containing carbon monoxide of high concentration that is suitably used as a carburizing atmosphere.

Abstract: A small apparatus for the production of mixtures of LPG vapor and air, also called synthetic natural gas, with properties that allow these mixtures to be used in place of natural gas in mostly temporary installations for residential and industrial or commercial installations. The entire apparatus is designed to produce synthetic natural gas without permanent presence of operating personnel. Noise, typically associated with the operation of venturi-type vapor/air mixing devices, is suppressed by a combination of an air-intake filter and a noise-reducing device to a level that make the apparatus suitable for installations close to residential developments. A second vapor/air mixing apparatus, identical to the main system, is installed on the same support frame, acting as a backup device for the main system in situations of equipment malfunctions or temporary system overload. Equipment malfunctions are reported to centralized monitoring stations by means of a telephone-based signaling device.

Abstract: A method and apparatus for processing a hydrocarbon fuel comprises: a primary fuel processing reactor for converting a feed stream to a first reformate stream comprising hydrogen; a first hydrogen separator located downstream of the primary fuel processing reactor and fluidly connected thereto for receiving the first reformate stream, the first separator comprising a first membrane for separating the first reformate stream into a first hydrogen-rich stream and a first retentate stream; and a secondary fuel processing reactor fluidly connected to the first separator for receiving and converting the first retentate stream to a second reformate stream comprising hydrogen. A fuel cell power generation system includes the present apparatus and a fuel cell stack fluidly connected thereto for receiving hydrogen-rich streams therefrom.

Abstract: A hydrocarbon reformer system including a first reactor configured to generate hydrogen-rich reformate by carrying out at least one of a non-catalytic thermal partial oxidation, a catalytic partial oxidation, a steam reforming, and any combinations thereof, a second reactor in fluid communication with the first reactor to receive the hydrogen-rich reformate, and having a catalyst for promoting a water gas shift reaction in the hydrogen-rich reformate, and a heat exchanger having a first mass of two-phase water therein and configured to exchange heat between the two-phase water and the hydrogen-rich reformate in the second reactor, the heat exchanger being in fluid communication with the first reactor so as to supply steam to the first reactor as a reactant is disclosed. The disclosed reformer includes an auxiliary reactor configured to generate heated water/steam and being in fluid communication with the heat exchanger of the second reactor to supply the heated water/steam to the heat exchanger.

Abstract: An autothermal reformer according to the principles of the present invention comprises a first stage that selectively receives a fuel flow, a first oxidant flow, and a steam flow. The first stage has a first portion of a catalyst bed. The fluids within the first stage are routed through the first portion of the catalyst bed and react. There is a second stage downstream from and communicating with the first stage. The second stage receives the fluids from the first stage and also selectively receives a second oxidant flow. The second oxidant flow and the fluids received from the first stage flow through a second portion of a catalyst bed and further react.

Abstract: A steam reformer that produces hydrogen gas from water and a carbon-containing feedstock, such as an alcohol or a hydrocarbon. The steam reformer includes a hydrogen-producing region, in which a mixed gas stream containing hydrogen gas and other gases is produced from water and a carbon-containing feedstock. The steam reformer includes a separation region, in which the mixed gas stream is separated into a hydrogen-rich stream containing at least substantially pure hydrogen gas, and a byproduct stream containing at least a substantial portion of the other gases. In some embodiments, the steam reformer is a vertically oriented fuel processor. In some embodiments, the separation region includes at least one hydrogen-selective membrane. In some embodiments, the steam reformer further includes a polishing region, in which the hydrogen-rich stream produced in the separation region is further purified. In some embodiments, the reformer includes an external metal or sealed ceramic shell.

Abstract: A reformer includes an evaporation portion for evaporating a raw material, a reforming portion for producing a reformed gas whose principal element is hydrogen from the raw materials, a CO reduction portion for reducing CO involved in the reformed gas, a circulating conduit portion having a storage tank for storing the raw material, a feeding device for feeding the raw material under pressure, a cooling device for cooling the CO reduction portion and a supply device for supplying the raw material to the evaporation portion. The supply device includes a conduit branched from the circulating conduit portion connected to the evaporation portion and a flow control device provided in the conduit.

Abstract: A method and apparatus for the generation or purification of hydrogen is described, and which includes an enclosure having inner and outer chambers which are substantially separated by a barrier, and which are substantially concentrically aligned; an evaporator coil positioned within the inner chamber for receiving a solution of methanol and water, and wherein the solution of methanol and water is heated to a predetermined temperature; a reformer coil positioned within the inner chamber and coupled in downstream fluid flowing relation relative to the evaporator coil, and which facilitates the decomposition of the heated methanol and water solution into hydrogen gas and other constituents; and a purifier assembly positioned within the inner chamber and coupled in downstream fluid flowing relation relative to the reformer coil, and which substantially separates the hydrogen gas from the other constituents.

Abstract: This invention relates to a method for providing controlled heat to a process utilizing a flameless distributed combustion.

Abstract: There is provided is a process for preparation of synthesis gas, i.e. mixtures containing dihydrogen and oxides of carbon, from feedstocks containing methane and/or higher hydrocarbons having from about 2 to about 12 carbon atoms by an initial catalytic treatment of feedstock to provide a methane-containing gaseous mixture substantially free of compounds having 2 or more carbon atoms, and reforming the gaseous mixture at elevated temperatures using nickel-containing catalytic materials that are unusually active under mild conditions of conversion and resistant to deactivation. The process consists fundamentally in converting the higher hydrocarbon compounds to form a methane-containing gaseous mixture substantially free of compounds having 2 or more carbon atoms in an initial conversion zone containing a catalyst while controlling temperatures within the initial conversion zone to temperatures in a range of temperature downward from about 500° C. to about 300° C.

Abstract: A reactor/purifier for generating pure hydrogen in a stack or array of pairs of alternatingly connected high and low pressure reactor chambers wherein a gas-porous turbulence-promoting screen structure washcoated with a steam-reforming catalyst is sandwiched between a planar hydrogen-selective palladium alloy membrane and a planar gas-impermeable heat-conducting metal plate within the high pressure reactor chamber of each high pressure reactor chamber; and wherein the catalyst-coated structure in each high pressure chamber is reacted with steam and hydrocarbon fuel, such as methane or syn/gas, and/or carbon monoxide at an appropriately controlled temperature of between about 200° C. to 650° C.

Abstract: In order to provide hydrogen as a transportation fuel, service stations are provided with apparatus for performing the hydrocarbon to hydrogen conversion. The hydrocarbon product applied to the hydrocarbon to hydrogen converter can be distributed to the service station as gasoline/diesel fuel or as a separate hydrocarbon including natural gas. The hydrogen can be stored in a storage facility at the service station and dispensed to users as required. This distribution system eliminates the need for hydrocarbon to hydrogen converters in the each fuel cell powered automobile. This distribution system also eliminates the need for a separate dedicated hydrogen distribution system. In addition, the distribution of hydrogen can co-exist with the distribution of gasoline and diesel fuels providing for a convenient transition period.

Abstract: A fuel gas-steam reformer assembly, preferably an autothermal reformer assembly, for use in a fuel cell power plant, includes a mixing station for intermixing a relatively high molecular weight fuel and an air-steam stream so as to form a homogeneous fuel-air-steam mixture for admission into a catalyst bed. The catalyst bed can include catalyzed alumina pellets, or a monolith such as a foam or honeycomb body which is preferably formed from a high temperature material such as a steel alloy, or from a ceramic material. The air-steam stream is fed into a manifold in the mixing station. The mixing station also comprises a plurality of tubes which open into the catalyst bed, and which pass through the manifold. The tubes extend through the manifold and include tangential openings which interconnect the interior of the tubes with the manifold. The openings have axes which are tangential to the circumference of each of the tubes.

Abstract: A miniature vaporizer for effectively vaporizing a process fluid (e.g., a liquid media) in small energy system applications, such as systems employing chemical reformers and fuel cells. The vaporizer of the present invention can employ a heating medium, such as a hot exhaust generated by a power system, as the heating source for generating steam or for evaporating a fluid (e.g., liquid chemicals or fuels). The vaporizer of the invention can optionally be configured to vaporize water thereby functioning as a miniature steam generator, to evaporate a process fluid thereby functioning as a miniature evaporator or heat exchanger, or to evaporate a process fluid and mix the fluid with another medium. This evaporator/mixer configuration can be used in reformer plants where a liquid chemical or fuel (e.g., gasoline, diesel, methanol, etc.) needs to be first evaporated and mixed with steam prior to the introduction of the resultant mixture to a converter (e.g., reformor or fuel cell).

Abstract: A fuel processing system is disclosed. The system includes a steam reformer adapted to produce hydrogen from a feedstock consisting of water and at least one of an alcohol and a hydrocarbon feedstock. The feedstock is exposed to one or more reformation regions including a reformation catalyst and to a membrane region including at least one hydrogen-selective membrane.

Abstract: A compact fuel processor for converting a hydro-carbonaceous fuel into hydrogen and carbon dioxide comprising in series a hydrocarbon converstion zone (5) for converting the hydro-carbonaceous fuel into a product gas comprising carbon monoxide and hydrogen, a water-gas shift reaction zone (6) containing a catalyst suitable for the water-gas shift conversion reaction, an auxiliary water-gas shift reaction zone (7) containing a catalyst suitable for the water-gas shift conversion reaction, and a carbon monoxide removal zone (8). The invention further relates to a fuel cell system comprising such a fuel processor and a fuel cell and to the use of such a fuel processor or such a fuel cell system.

Abstract: A process and system for producing synthesis gas by a SPOC™ enhanced catalytic partial oxidation process is disclosed. A reaction in which H2S is partially oxidized to elemental sulfur and water takes place instead of a secondary reaction in which a portion of the light hydrocarbon feed is combusted to form CO2 and water. An increase in yield and selectivity for CO and H2 products results, and readily recoverable elemental sulfur is also produced.

Abstract: A fuel processor apparatus comprising a catalytic tubular reactor is heated using an infrared radiant burner to provide the endothermic heat of reaction needed to reform a mixture of hydrocarbon and steam for the production of a hydrogen-rich gas stream. The hydrogen-rich gas stream is further purified using a sequence of catalytic steps that is fed to a fuel cell whereupon a portion of the hydrogen contained in the gas stream is consumed for the production of electricity by electrochemical reaction with oxygen. An unused portion of the purified hydrogen-rich gas stream exits the fuel cell stack and is combusted in the infrared radiant burner. A fuel cell control system rapidly responds to a variable fuel cell electric demand by adjusting the feed of hydrocarbon to the catalytic tubular reactor to maintain the surface temperature of the infrared radiant burner within defined limits.

Abstract: A reformer is disposed in the flow path of a reactant fluid. The reformer includes an electrically heatable heater unit of honeycomb structure, in the upstream of the flow path of a reactant fluid, and a catalyst unit of honeycomb structure capable of generating hydrogen from a reactant fluid containing an organic compound or carbon monoxide, by catalysis, in the downstream of the above heater unit. The heater unit and catalyst unit satisfy the following relationship: Cell density of the heater unit≦Cell density of the catalyst unit. The reformer improve efficiency for production of hydrogen and reduce CO as the by-product.

Abstract: A housing containing two or more individual operating components called modules is disclosed. The modules themselves are independently contained in one or more vessels with attendant connectivity structures such as pipes, tubes, wires and the like. Each such vessel or device is configured to conduct at least one unit reaction or operation necessary or desired for generating or purifying a hydrogen enriched product gas formed from a hydrocarbon feed stock. Any vessel or zone in which such a unit operation is conducted, and is separately housed with respect at least one other vessel or zone for conducting a unit operation, is considered a module.

Abstract: A reactor for autothermal reforming of hydrocarbons that allows a reduction of excess-air factor &phgr; during the reforming without resulting in a reduced conversion of the hydrocarbons in an end region of the reaction zone. The reactor includes at least one reaction zone in which is arranged at least one catalyst structure for the reformation so that the educts involved in the reformation are converted while flowing through the reaction zone. A heating device is included for heating the end region of the reaction zone to accelerate the conversion of the hydrocarbons.

Abstract: A reformer includes two or more catalyst units in the flow path, capable of generating hydrogen from a reactant fluid containing an organic compound or carbon monoxide, by catalysis. In the reformer, at least two of the catalyst units satisfy the following relationship: Heat capacity of the upstream-side catalyst unit≦Heat capacity of the downstream-side catalyst unit. The reformer is improved in the relationship between these catalyst units with respect to heat capacity. This improvement leads to improvement of the reformer in safety, heating characteristics during the start-up period, efficiency of hydrogen production and reduction in production of CO as the coproduct.

Abstract: A process for an endothermic reaction includes the steps of carrying out an exothermic reaction in which a fuel is combusted to generate heat for transfer to a feedstock subject to an endothermic reaction, the waste heat from the exothermic and endothermic reactions being transferred to at least three fluid streams within a single heat recovery zone downstream of the endothermic and exothermic reactions, the apparatus therefor being contained within a single vessel.

Abstract: A reformer that includes a housing including a tubular member and an end plate member hermetically joined to the tubular member. The housing defines within it a first fluid flow path and a second fluid flow path in a heat exchanging relationship with each other. A reforming catalyst is disposed within the first fluid flow path. The tubular member has a tubular end, and the end plate member has an abutting rim that contacts with and extends along the tubular end of the tubular member and that is folded together over an entire circumference thereof to define a folded hermetic seam between the tubular member and the end plate member. The reformer can be low-priced and it manufacture is easy and efficient.

Abstract: A fuel processor for rapidly achieving operating temperature during startup. The fuel processor includes a reformer, a shift reactor, and a preferential oxidation reactor is provided for deriving hydrogen for use in creating electricity in a plurality of fuel cells. A first combustion heater system is coupled to at least one of the reformer, the shift reactor, and the preferential oxidation reactor to preheat the component during a rapid startup sequence. That is, the first combustion heater system is operable to produce thermal energy as a product of the combustion of air and fuel in the form of a first heated exhaust stream. This first heated exhaust stream is then used to heat the component directly or by using a heat exchanger type system. The first heated exhaust stream is also used by a second combustion device as a source of oxygen or diluent.

Abstract: A fuel processor for rapid start and operational control. The fuel processor includes a reformer, a shift reactor, and a preferential oxidation reactor for deriving hydrogen for use in creating electricity in a plurality of H2—O2 fuel cells. A heating and cooling mechanism is coupled to at least the shift reactor for controlling the critical temperature operation of the shift reactor without the need for a separate cooling loop. This heating and cooling mechanism produces or removes thermal energy as a product of the temperature of the combustion of air and fuel. Anode effluent and cathode effluent or air are used to control the temperature output of the heating mechanism. A vaporizer is provided that heats the PrOx reactor to operating temperature.

Abstract: In a reformer for a fuel cell equipped with a reforming unit 7 using a reaction system composed of a partial oxidation reaction and a steam reforming reaction as a reforming reaction, the reformer includes a vaporizing device 4 for vaporizing a raw fuel using a mixture of liquid hydrocarbon such as gasoline or alcohol and water and for supplying the vaporized fuel to the reforming unit 7. A spray nozzle 6 atomizes the raw fuel and supplies the atomized fuel to the reforming unit 7, and a blowing machine 9 supplies air to the reforming unit 7.

Abstract: A gasifier system includes a gasifier chamber, a plurality of nozzles or burners injecting and combusting a mixture including coal and oxygen within the gasifier chamber, and an ash bed disposed proximate a bottom of the gasifier chamber. Concurrent flow is generated within the gasifier such that gas and bi-products generated by the combustion of the mixture flow through the ash bed. The ash bed serves as a filter and reducing volume for the trace carbon not gasified during the combustion process. The hot gases exit the gasifier and enter a gas cooler and then a hot gas filter. Ash is unloaded from the gasifier chamber and is transferred into a quench tank, where ash settles and is removed to atmospheric conditions by a progressive pitched dewatering screw press. The dewatering screw press also serves as a seal to prevent excessive water escaping from the high pressure of gasifier operation.

Abstract: The present invention provides microcombustors, microreformers, and methods of steam reforming alcohols over a catalyst. The microcombustors can be manufactured with a very small size and can operate at very low temperature. Surprisingly superior results and properties obtained in methods of the present invention are also described.

Abstract: A hydrogen generating apparatus comprising a reformer, a heating section, a fuel supply section, a water supply section, a shift reactor with a shift catalyst layer, a first heat exchanger on the downstream side of the shift catalyst layer, and a temperature detector for the shift catalyst layer. The temperature of the downstream portion of the shift catalyst layer is raised by the action of the heat exchanger compared with the temperature of the same before the amount of the reformed gas is increased. And, the temperature of the downstream portion is lowered compared with the temperature of the same before the amount of the reformed gas is reduced when reducing the amount of the reformed gas. Accordingly, regardless whether the generation amount of hydrogen is large or small, the hydrogen generating apparatus can supply a constant concentration hydrogen gas while keeping the concentration of byproduct carbon monoxide low.

Abstract: A method of producing hydrogen by reforming a hydrocarbon or an aliphatic alcohol efficiently is disclosed together with an apparatus for implementing the method.

Abstract: A method for reforming a liquid hydrocarbon mixture, in which the hydrocarbon mixture is initially completely vaporized before it is contacted with the gaseous reactants and caused to undergo reaction. Usable as a reformer system in this context is a device which has at least two reforming chambers composed of a vaporization chamber and at least one reaction chamber, and in which a metering device for liquid hydrocarbons is provided in the region of the vaporization chamber, and an introducing device for gaseous reactants is provided in the region between at least two of the reforming chambers. The present invention allows liquid hydrocarbon mixtures to be reformed without the formation of unwanted residues such as tar or soot.

Abstract: Preferred embodiments of the present invention generate a synthesis gas with a molar ratio of hydrogen to carbon monoxide of approximately 2:1 required for Fischer-Tropsch synthesis. Additional hydrogen produced in the steam reforming of methane beyond the requirements for the Fischer-Tropsch reaction is separated from the product gases of the reformer by the use of a hydrogen permeable membrane. Air is passed over the outside of the tube. As the hydrogen contacts the air, it is combusted with oxygen in the air to form water and release the heat necessary to drive the steam reforming reaction.

Abstract: A steam reformer for producing H2 from a low pressure hydrocarbon gas (preferably propane) using an improved gaseous hydrocarbon fuel and steam delivery system comprising two coaxial tubes, an outer tube for delivery of steam which is gradually reduced in diameter to form a truncated conical tip for the outflow of steam around the end of an inner tube for the outflow of gaseous hydrocarbon. The outflow ends of both tubes are positioned in the same plane perpendicular to their axis. The outflow end of the second tube is preferably also gradually reduced in diameter in order to provide higher velocity of gaseous hydrocarbon to be mixed with the steam entering the reformer for optimized yield of hydrogen by optimizing the mixing of the steam and gaseous hydrocarbon in order to optimize the yield of hydrogen for the optimized generation of wattage for the same fuel-cell power generating system.

Abstract: An apparatus for steam reforming of hydrocarbons, the apparatus comprising a vessel defining a combustion chamber. The combustion chamber has a burner device for combustion of a fuel and a flue gas outlet for exhausting flue gas resulting from the combustion. A second chamber is integrally formed with the vessel. The second chamber comprises a first inlet conduit adapted for receiving water therein and an outlet conduit for exhausting steam. A reformer tube in the combustion chamber is filled with a catalyst and is connected to a second inlet conduit for having a steam and hydrocarbon mixture flow therethrough, and to a second outlet conduit for exhausting a process gas resulting from a steam reforming process in the reformer tube. The reformer tube is disposed in the combustion chamber so as to transfer heat from the combustion to the steam reforming process.

Abstract: An apparatus having at least two tubes (1, 2) which are arranged coaxially inside one another and project partially into the reactor is proposed for the production of synthesis gases by partial oxidation of carbon-containing fuels in a reactor without internals. The inner tube (2) has a device (8) for supplying the fuels and the outer tube (1) has a device (9) for supplying the combustion air. At the end, the tubes are conically tapered, so that a nozzle-like outlet opening (3) and an annular nozzle gap (4) are formed. To improve the resistance to wear, the tubes (1, 2) are in each case composed o two sections (1a, 1b) and (2a, 2b), the tube sections (1b, 2b) which extend into the reactor consisting of a high-melting metal alloy which is able to withstand high temperatures. The tube sections can be joined together in a positively and nonpositively locking manner by a screw thread or a flange structure (11, 12).

Abstract: An apparatus for carrying out a multi-step process of converting hydrocarbon fuel to a substantially pure hydrogen gas feed includes a plurality of modules stacked end-to-end along a common axis. Each module includes a shell having an interior space defining a passageway for the flow of gas from a first end of the shell to a second end of the shell opposite the first end, and a processing core being contained within the interior space for effecting a chemical, thermal, or physical change to a gas stream passing axially through the module. The multi-step process includes: providing a fuel processor having a plurality of modules stacked end-to-end along a common axis; and feeding the hydrocarbon fuel successively through each of the modules in an axial direction through the tubular reactor to produce the hydrogen rich gas.

Abstract: A hydrogen production apparatus for generating hydrogen comprises a first input for mixing a stream of liquid water with a stream of feed gas to produce a feed gas-water mixture stream and a heating mechanism for heating the feed gas-water mixture stream to a temperature sufficient to evaporate the water in the feed gas-water mixture stream to steam to produce a humidified feed-gas stream. A second input is provided for mixing the humidified feed-gas stream with a hydrocarbon fuel to produce a reformer reactant mixture of fuel, oxidant, and steam. A steam-methane reforming component reacts the hydrocarbon fuel and the steam in the reformer reactant mixture in a steam-methane reforming reaction to reform the hydrocarbon fuel in the reformer reactant mixture and produce a hydrogen enriched reformer product gas.

Abstract: A method for gasifying carbonaceous materials to fuel gases comprises the formation of an ultra-superheated steam (USS) composition substantially containing water vapor, carbon dioxide and highly reactive free radicals thereof, at a temperature of about 2400° F. (1316° C.) to about 5000° F. (2760° C.). Rapid gasification of a carbonaceous material with USS is indicated by the production of USS in a clear, colorless flame, and its enthalpy obviates the need for super-stoichiometric steam input. In a related aspect of the invention, gasification output per pound of steam as well as CO and H2 concentrations are increased by adding a relatively small amount of an oxygen-containing material such as cellulose to the input elemental carbon material, or by adding a relatively small amount of elemental carbon material such as coal to an input oxygen-containing material such as cellulose. Methods for controlling a gasifier system to enhance gasification efficiency are described.

Abstract: An auto-oxidation and internal heating type reforming method and apparatus for hydrogen production are disclosed for use in a process in which a gaseous mixture of a hydrocarbon or an aliphatic alcohol with water vapor is fed into contact with a mass of a reforming catalyst to bring about a reforming reaction of the gaseous mixture to produce hydrogen, wherein a small amount of an oxidizing catalyst is admixed with the reforming catalyst in that mass; and a small amount of oxygen is admixed with the gaseous mixture, whereby a portion of the hydrocarbon or aliphatic alcohol is exothermally oxidized to generate a quantity of heat required to reform the gaseous mixture of the hydrocarbon or aliphatic alcohol with water vapor.