Apparatus For Converting Or Treating Hydrocarbon Gas Patents (Class 48/127.9)
  • Publication number: 20080120908
    Abstract: A hydrogen production microapparatus includes conversion catalysts. After organic/inorganic hydrocarbons are put into the hydrogen production microapparatus, the organic/inorganic hydrocarbons will be decomposed so as to produce hydrogen gas usable as fuels owing to the catalysis and conversion caused by the conversion catalysts.
    Type: Application
    Filed: October 25, 2007
    Publication date: May 29, 2008
    Inventor: Huang-Hsiang Wang
  • Patent number: 7377951
    Abstract: A steam-hydrocarbon reforming process generating a process gas containing a first amount of heat and a flue gas containing a second amount of heat includes: providing a water heater, a boiler feed water (BFW) preparation system, a boiler, and a BFW heater; feeding water to the water heater; feeding water to the BFW preparation system from the water heater; feeding a first stream of water to the boiler from the BFW preparation system; feeding a second stream of water from the BFW preparation system to the BFW heater; heating at least part of the second stream of water fed to the BFW heater with a first part of the first amount of heat; heating water in the boiler with a second part of the first amount of heat; generating steam at 5-60 psig in the boiler; and heating the BFW preparation system or another internal system with the steam.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: May 27, 2008
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Hoanh Nang Pham, Blaine Edward Herb, Geoffrey Colling Achilles
  • Patent number: 7374591
    Abstract: A method for starting a gas generating system serving to generate a hydrogenous gas used for operating a fuel cell. The gas generating system includes: devices for converting starting materials into the hydrogenous gas; devices for conditioning at least a portion of the starting materials; devices for purifying the hydrogenous gas by removing unwanted gas constituents, and; a starting burner. According to the method, in a first method step, at least one fuel is combusted inside the starting burner. The hot waste gases resulting from this combustion firstly heat the devices provided for conditioning at least a portion of the starting materials, and the residual heat of these waste gases subsequently heats at least one additional component. In parallel thereto, the devices for converting the starting materials are heated by an electric heating.
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: May 20, 2008
    Assignee: Daimler AG
    Inventors: Marc Sommer, Bernhard Vogel
  • Patent number: 7367996
    Abstract: A hydrocarbon fuel processing reactor for generating a hydrogen-enriched reformate from hydrocarbons is disclosed. A plurality of shells are arranged coaxially having a gap defined between each of the successive shells, thereby forming a plurality of coaxial zones. The shells are configured to permit heat transfer from one zone to another. Fluid streams for reactions within the reactor are preheated by heat transfer from adjacent zones.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: May 6, 2008
    Assignee: Nuvera Fuel Cells, Inc.
    Inventors: Lawrence G. Clawson, Mark R. Hagan, Chunming Frank Qi, William F. Northrop
  • Patent number: 7368194
    Abstract: A feedstock mixing apparatus for fuel processing systems, and fuel processing and fuel cell systems incorporating the same. A fuel processing system according to the present invention includes one or more fuel processors adapted to produce a product hydrogen stream from a feed stream containing water and a carbon-containing feedstock. The fuel processing system further includes a feedstock delivery system adapted to mix the components of the feed stream at a determined mix ratio and to deliver this feed stream to the fuel processor(s). The fuel processing system may also include one or more fuel cell stacks that are adapted to produce an electric current from the product hydrogen stream produced by the fuel processing system. When the fuel processing system includes at least one fuel cell stack, it may be referred to as a fuel cell system.
    Type: Grant
    Filed: May 6, 2005
    Date of Patent: May 6, 2008
    Assignee: IdaTech, LLC
    Inventors: Anthony J. Dickman, David J. Edlund, William A. Pledger
  • Patent number: 7357821
    Abstract: A system for converting fuel and air into reformate with a reformer which has a reaction space, a nozzle for supplying a fuel/air mixture to the reaction space, and a fuel feed for supplying fuel to the nozzle (14). The nozzle is a Venturi nozzle with an air inlet area and a diffusor area which extends downstream with respect to the air inlet area.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: April 15, 2008
    Assignee: Webasto AG
    Inventors: Felix Wolf, Bernd Mittmann, Christine Sallinger, Christian Hubbauer, Thomas Kerscher, Christian Baecker, Stefan Kunz, Marcus Neumueller, Florian Metz, Martin Wegner, Ingrid Lanzl, Peter Lamp
  • Patent number: 7357820
    Abstract: The invention relates to a system for converting fuel and air into reformate with a reformer which has a reaction space, a nozzle for supplying a fuel/air mixture to the reaction space, and a fuel feed for supplying fuel to the nozzle. In the invention, the air inlet area of the nozzle is provided with air guidance means which impart a swirl to the in-flowing air.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: April 15, 2008
    Assignee: Webasto AG
    Inventors: Felix Wolf, Bernd Mittmann, Christine Sallinger, Christian Hubbauer, Thomas Kerscher, Christian Baecker, Stefan Kunz, Marcus Neumueller, Florian Metz, Martin Wegner, Ingrid Lanzl, Peter Lamp
  • Patent number: 7354465
    Abstract: Devices for cooling and humidifying a reformate stream from a reforming reactor as well as related methods, modules and systems includes a heat exchanger and a sprayer. The heat exchanger has an inlet, an outlet, and a conduit between the inlet and the outlet. The heat exchanger is adapted to allow a flow of a first fluid (e.g. water) inside the conduit and to establish a heat exchange relationship between the first fluid and a second fluid (e.g. reformate from a reforming reactor) flowing outside the conduit. The sprayer is coupled to the outlet of the heat exchanger for spraying the first fluid exiting the heat exchanger into the second fluid.
    Type: Grant
    Filed: June 20, 2005
    Date of Patent: April 8, 2008
    Assignee: Nuvera Fuel Cells, Inc.
    Inventors: Jian Lian Zhao, William F. Northrop
  • Patent number: 7344572
    Abstract: A reforming apparatus that generates hydrogen from fuel includes a plurality of reactors each having an internal space and reacting fuel in the internal space, a heat insulating package that contains the plurality of reactors, and a heat insulator that supports the plurality of reactors to be separated from an inner wall of the heat insulating package.
    Type: Grant
    Filed: March 23, 2004
    Date of Patent: March 18, 2008
    Assignee: Casio Computer Co., Ltd.
    Inventor: Tadao Yamamoto
  • Patent number: 7341609
    Abstract: A reforming and hydrogen purification system operating with minimal pressure drop for producing free hydrogen from different hydrogen rich fuels includes a hydrogen reforming catalyst bed in a vessel in communication with a core unit containing a hydrogen permeable selective membrane. The vessel is located within an insulated enclosure which forms an air inlet passageway and an exhaust passageway on opposite sides of the vessel. Air and raffinate pass through a burner within the air inlet passageway, providing a heated flue gas to heat the catalyst to the reaction temperature needed to generate free hydrogen from the feedstock. The burner flue gas flows laterally over and along the length of the bed between the input and output ends of the bed. Hydrogen is recovered from the core for use by a hydrogen-consuming device such as a fuel cell. The remaining unrecovered hydrogen in the reformed gases is contained in raffinate and is used to supply process heat via the burner.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: March 11, 2008
    Assignee: Genesis Fueltech, Inc.
    Inventor: Peter David DeVries
  • Patent number: 7338644
    Abstract: A compact fuel processor for converting a hydro-carbonaceous fuel into hydrogen and carbon dioxide having in series a hydrocarbon conversion zone for converting the hydro-carbonaceous fuel into a product gas of carbon monoxide and hydrogen, a water-gas shift reaction zone containing a catalyst suitable for the water-gas shift conversion reaction, an auxiliary water-gas shift reaction zone containing a catalyst suitable for the water-gas shift conversion reaction, and a carbon monoxide removal zone. The invention further relates to a fuel cell system having such a fuel processor and a fuel cell and to the use of such a fuel processor or such a fuel cell system.
    Type: Grant
    Filed: April 12, 2001
    Date of Patent: March 4, 2008
    Assignee: Shell Oil Company
    Inventors: Eric Sevenhuijsen, Hendrik Martinus Wentinck
  • Patent number: 7338643
    Abstract: A reformate clean-up reactor. The reactor takes a reformate stream and passes it through multiple subreactors that are integrated into a common reactor housing to reduce reformate stream by-product concentration prior to use of the reformate in a fuel cell. The reactor includes a gas shift subreactor to promote the conversion of carbon monoxide to carbon dioxide, a gaseous diffusion membrane subreactor to provide a hydrogen-rich portion of the reformate stream, and a methanation subreactor to convert carbon monoxide into methane and water. In applications where space for a fuel cell system is limited, the integration of the clean—up devices into a common housing provides significant improvements in structural and volumetric efficiency. Moreover, in at least one embodiment of the present invention, the juxtaposition of the gaseous diffusion membrane and the gas shift reactor improves membrane robustness.
    Type: Grant
    Filed: March 17, 2003
    Date of Patent: March 4, 2008
    Assignee: General Motors Corporation
    Inventors: Ian Barrey Irons, Julia Margaret Rowe, Peter Geoffrey Gray, Peter Albert Walker
  • Patent number: 7332003
    Abstract: An apparatus for processing hydrocarbon fuel (e.g., gasoline, kerosene, jet fuel, diesel and heating oil) to generate hydrogen (H2), which can be used in fuel cells, includes a desulfurization reactor for removing sulfur from the fuel; a catalytic reactor for forming a reformate from the fuel; and, optionally, a separator for separating a light fraction of the fuel from a heavy fraction of the fuel. The fuel is first exposed to the desulfurization reactor and then, if present, to the separator. Finally, the fuel is exposed to the catalyst in the catalytic reactor; and the hydrogen gas generated there from is collected for use in the fuel cell.
    Type: Grant
    Filed: September 2, 2004
    Date of Patent: February 19, 2008
    Assignee: Aspen Products Group, Inc.
    Inventors: Zhijiang Li, Mark D. Fokema, Wendell E. Rhine
  • Patent number: 7329291
    Abstract: Process for production of synthesis gas comprising carbon monoxide, carbon dioxide and hydrogen by reforming of methanol including the steps of: (a) introducing methanol in liquid phase into a reactor containing a solid methanol reforming catalyst suspended in a liquid phase of methanol and water; (b) reacting the liquid phase of methanol and water in presence of the suspended catalyst at a pressure and temperature, where methanol is maintained in the liquid phase; and (c) withdrawing from the reactor a gas phase of synthesis gas being produced during reaction of the liquid methanol and water phase.
    Type: Grant
    Filed: November 17, 2004
    Date of Patent: February 12, 2008
    Assignee: Haldor Topsoe A/S
    Inventors: Poul Erik Højlund Nielsen, Jens Perregaard
  • Patent number: 7318845
    Abstract: A distillate fuel steam reformer system in which a fuel feed stream is first separated into two process streams: an aliphatics-rich, sulfur-depleted gas stream, and an aromatics- and sulfur-rich liquid residue stream. The aliphatics-rich gas stream is desulfurized, mixed with steam, and converted in a reforming reactor to a hydrogen-rich product stream. The aromatics-rich residue stream is mixed with air and combusted to provide heat necessary for endothermic process operations. Reducing the amounts of sulfur and aromatic hydrocarbons directed to desulfurzation and reforming operations minimizes the size and weight of the overall apparatus. The process of the invention is well suited to the use of microchannel apparatuses for heat exchangers, reactors, and other system components, which may be assembled in slab configuration, further reducing system size and weight.
    Type: Grant
    Filed: June 23, 2003
    Date of Patent: January 15, 2008
    Assignee: Applied Research Associates, Inc.
    Inventors: Aly H. Shaaban, Timothy J. Campbell
  • Patent number: 7316718
    Abstract: An arrangement for generating hydrogen gas utilizes differential pressure to transport fuel and spent fuel components without requiring an electrically powered fuel delivery pump.
    Type: Grant
    Filed: July 11, 2001
    Date of Patent: January 8, 2008
    Assignee: Millennium Cell, Inc.
    Inventors: Steven C. Amendola, Richard M. Mohring, Phillip J. Petillo, Keith A. Fennimore, Stephen C. Petillo
  • Publication number: 20070289215
    Abstract: A method and apparatus for reacting a hydrocarbon containing feed stream by steam methane reforming reactions to form a synthesis gas. The hydrocarbon containing feed is reacted within a reactor having stages in which the final stage from which a synthesis gas is discharged incorporates expensive high temperature materials such as oxide dispersed strengthened metals while upstream stages operate at a lower temperature allowing the use of more conventional high temperature alloys. Each of the reactor stages incorporate reactor elements having one or more separation zones to separate oxygen from an oxygen containing feed to support combustion of a fuel within adjacent combustion zones, thereby to generate heat to support the endothermic steam methane reforming reactions.
    Type: Application
    Filed: June 19, 2006
    Publication date: December 20, 2007
    Inventors: John William Hemmings, Leo Bonnell, Earl T. Robinson
  • Patent number: 7303598
    Abstract: Apparatus and process for reformulating liquid fuel. In one step of the process the fuel is fractionated into light and heavy fractionates. The light fractionate is then reformed in a steam reformer into a reformed fuel that is suitable for use in fuel cells or other energy-producing devices. The heavy fractionate is burned with a part of the resulting heat used in the reforming step. In one embodiment the light fractionate is desulfurized before entering the reforming step. In another embodiment the heavy fractionate is directed into a holding vessel for subsequent use as a fuel which is suitable for burning to produce heat or other energy.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: December 4, 2007
    Assignee: Altex Technologies
    Inventors: Mehdi Namazian, John T. Kelly
  • Patent number: 7299655
    Abstract: Disclosed are methods and systems for vaporization of liquefied natural gas (LNG) that employ a condensing gas stream to adjust the gross heating value (GHV) of the LNG such that, upon vaporization, a natural gas product is obtained that meets pipeline or other commercial specifications. The condensing gas can be air, nitrogen, or in embodiments, NGLs such as ethane, propane, or butane, or other combustible hydrocarbon such as dimethyl ether (DME) depending on a desired change in GHV. In some embodiments, the methods and systems employ an integrated air separation plant for generation of nitrogen used as a condensing gas, wherein a cool stream of a heat transfer medium, such as water, ethylene glycol, other common heat transfer fluids, or mixtures thereof, obtained by heat transfer during vaporization of the LNG is used to pre-cool an air feed to the air separation plant, or to cool other process streams associated therewith.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: November 27, 2007
    Assignee: BP Corporation North America Inc.
    Inventor: Patrick B. Ward
  • Patent number: 7300635
    Abstract: A catalytic reactor comprises a plurality of fluid-impermeable plates defining flow channels between them. Tight fitting within each flow channel is a sheet of corrugated material whose surfaces are coated with catalytic material. At each end of the flow channels are headers to supply gas mixtures to the flow channels, the headers communicating with adjacent channels being separate. The reactor enables different gas mixtures to be supplied to adjacent channels, which may be at different pressures, and the corresponding chemical reactions are also different. Where one of the reactions is endothermic while the other reaction is exothermic, heat is transferred through the wall of the tube separating the adjacent channels, from the exothermic reaction to the endothermic reaction.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: November 27, 2007
    Assignee: CompactGTL PLC
    Inventors: Michael Joseph Bowe, John William Stairmand, Ian Frederick Zimmerman, Jason Andrew Maude
  • Patent number: 7297169
    Abstract: The present invention is an apparatus arranged to maximize heat utilization for a hydrocarbon steam reforming process to produce synthesis gas. The apparatus comprises a refractory lined vessel with partition walls that divide the inside of the vessel into (1) a combustion chamber(s) containing one or more burners, and (2) convection chambers used as a means to remove combustion products from the combustion chamber through one or more openings at the opposite end of the burner end. The combustion chamber contains one or more reformer tubes in which a mixed-feed of hydrocarbon and steam flow co-current with combustion products and receive direct radiant heat from the combustion flame through the tube wall. The convection chambers contain a tube-in-tube device filled with catalyst in the annuli.
    Type: Grant
    Filed: December 24, 2003
    Date of Patent: November 20, 2007
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Hoanh Nang Pham, David Hon Sing Ying, Shoou-I Wang, Scott David Madara, Joel Charles MacMurray
  • Patent number: 7294157
    Abstract: A carbon monoxide converter whose catalyst temperatures can be precisely controlled even under a high load. The carbon monoxide converter includes shift catalyst beds arranged in tandem for conducting a shift reaction for converting CO and H2O to H2 and CO2. The shift catalyst beds are arranged in a gas flow direction such that they are shorter on the upstream side, on which a gas containing CO and H2O is introduced, and longer on the downstream side, on which a gas containing the produced H2 and CO2 is discharged. A heat exchanger is disposed upstream of each shift catalyst bed, and the temperatures of the shift catalyst beds are controlled during the shift reaction. A gas containing CO2 and H2O discharged from the carbon monoxide converter is introduced into a carbon-monoxide-oxidizing unit.
    Type: Grant
    Filed: February 24, 2005
    Date of Patent: November 13, 2007
    Assignee: Honda Motor Co., Ltd.
    Inventors: Masako Takayama, Hikaru Okada
  • Publication number: 20070238611
    Abstract: The carbon dioxide absorbent contains a lithium-containing oxide, an alkali halide, has a high carbon dioxide absorption capability, and sufficiently maintains the carbon dioxide absorption capability even in repeated used for absorption and desorption of carbon dioxide.
    Type: Application
    Filed: October 23, 2006
    Publication date: October 11, 2007
    Inventors: Toshihiro IMADA, Masahiro Kato, Kenji Essaki, Yasuhiro Kato, Yukishige Maezawa
  • Patent number: 7276214
    Abstract: A chemical reactor is disclosed and which has a core composed of a stack of metal plates that are diffusion bonded in face-to-face relationship. A plurality of reaction zones are located within the core, as are a plurality of catalyst receiving zones, and both the reaction zones and the catalyst receiving zones are defined by respective aligned apertures in the plates. A first channel arrangement is provided in some of the plates for transporting a first reactant to and between the reaction zones, portions of the first channel arrangement that interconnect the reaction zones being formed over at least a portion of their length as heat exchange channels. A second channel arrangement is provided in others of the plates and is arranged to deliver a second reactant to each of the reaction zones.
    Type: Grant
    Filed: January 3, 2003
    Date of Patent: October 2, 2007
    Assignee: Meggit (UK) Ltd.
    Inventors: Anthony Matthew Johnston, Brian Scott Haynes
  • Patent number: 7276095
    Abstract: A stand-alone fuel processor (10) for producing hydrogen from a hydrocarbon fuel for a fuel cell engine in a vehicle. The fuel processor (10) includes a primary reactor (14) that dissociates hydrogen and other by-products from the hydrocarbon fuel as a reformate gas. The reformate gas is applied to a WGS reactor (48) to convert carbon monoxide and water to hydrogen and carbon dioxide. The WGS reactor (14) may include an adsorbent for adsorbing carbon monoxide. The reformate gas from the WGS reactor (48) is then sent to a rapid-cycle PSA device (12) for adsorbing the undesirable by-products in the gas and generates a stream of pure hydrogen. A liquid water separator (70) separates water from the reformate gas before it is applied to the PSA device (12). The PSA device (12) uses a portion of the separated hydrogen as a desorbing gas to purify the adsorbent in the PSA device (12). The by-products of the reformate gas can be used as a fuel in a combustor (30) that generates heat for the primary reactor (14).
    Type: Grant
    Filed: March 14, 2003
    Date of Patent: October 2, 2007
    Assignee: General Motors Corporation
    Inventors: Craig S. Gittleman, John B. Ruhl, Yan Zhang, William H. Pettit
  • Patent number: 7273505
    Abstract: A hydrogen generator comprises therein a reformer, a Shifter, a material flow passage with first evaporator through which a material is supplied to the reformer, a reformed gas flow passage for leading the reformed gas derived from the reformer to the Shifter, a shifted gas flow passage through which a shifted gas derived from the Shifter is taken out, and second steam flow passage formed adjacent to the reformed gas flow passage to be located at upstream side of the Shifter. The second evaporator is provided within the second steam flow passage. A part of heat of the reformed gas is recovered as latent heat by the second evaporator. Thereby, temperature of the Shifter is controlled.
    Type: Grant
    Filed: April 9, 2004
    Date of Patent: September 25, 2007
    Assignee: Matsushita Electric Industrial Co., Ltd
    Inventors: Motohiro Suzuki, Tomonori Asou, Yuji Mukai, Kunihiro Ukai, Akira Maenishi, Yoshio Tamura
  • Patent number: 7271201
    Abstract: A method and a system for drying a biomass, wet pulverized coal or combinations thereof, using heat from a Fischer-Tropsch synthesis in a heat exchanger to heat a nitrogen gas, using a flue gas in a heater to heat the heated nitrogen gas to a higher temperature, passing the twice heated nitrogen gas through apparatus to pulverize the fuel source of coal, biomass or both, forming a gas/particulate stream, filtering the gas/particulate stream in a filter to remove dried fuel feed stocks and using a blower to form a first steam and nitrogen mixture for discharge, and a second steam and nitrogen mixture for mixing with additional dry nitrogen gas for introduction to the first step of the method, at the heat exchanger.
    Type: Grant
    Filed: August 7, 2006
    Date of Patent: September 18, 2007
    Assignee: Syntroleum Corporation
    Inventors: James Francis Leahy, Robert L. Freerks
  • Patent number: 7270689
    Abstract: A reformer for reacting a raw material gas to be reformed, with an oxidizing agent gas and a reforming agent gas in the presence of an oxidation catalyst and a reforming catalyst to obtain a hydrogen-containing gas, including: a set of catalyst layers consisting of an oxidation catalyst layer and a reforming catalyst layer, and two or more inlets for feeding the oxidizing agent gas to the oxidation catalyst and/or the reforming catalyst in plural stages. The reformer can produce a hydrogen-containing gas without forming a combustion region of a temperature of as high as one thousand and several hundreds centigrade and can be manufactured at a low cost.
    Type: Grant
    Filed: July 14, 2004
    Date of Patent: September 18, 2007
    Assignees: Toyo Engineering Corporation, K. E. M. Corporation
    Inventors: Hidetsugu Fujii, Fumitake Watanabe, Katsuya Uehara, Yukuo Katayama
  • Patent number: 7267699
    Abstract: A fuel processing system including a filter for reforming a hydrocarbon fuel and its operation is disclosed. The system includes a first chamber for receiving a hydrocarbon fuel and combining it with air or water; a reformer in fluid connection with and down stream of the first chamber, which receives the hydrocarbon fuel combined with either air or water to reform the fuel to a reformate stream, which contains a hydrogen rich atmosphere; a second chamber in fluid connection with the reformer which is capable of receiving the reformate stream from the reformer; a water inlet connected to the second chamber capable of introducing water to the reformate stream; and a filter in fluid connection with and down stream of the second chamber, which is capable of preventing a substantial portion of any solid particles contained in the reformate stream from passing therethrough.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: September 11, 2007
    Assignee: Nissan Motor Co., Ltd.
    Inventor: Motohisa Kamijo
  • Patent number: 7267804
    Abstract: The membrane reactor of the present invention generates a desired gas such as hydrogen produced by steam reforming liquid fuels. The membrane reactor provides thermal integration between the heating source and the reaction catalyst by heat conduction through a solid medium. A gas purification system extracts energy from the waste gases to heat the membrane reactor. This, in concert with other control mechanisms provided results in a more efficient gas purification process.
    Type: Grant
    Filed: February 27, 2002
    Date of Patent: September 11, 2007
    Inventor: Robert E. Buxbaum
  • Patent number: 7267697
    Abstract: A fuel reforming system includes an inlet device for a reactor having a housing defining a frustoconical interior region having an inlet opening and an outlet opening. A tube mixer having a helical divider may be optionally employed to transfer fluid into the inlet opening. A retention member is placed at each of the openings and a plurality of particles is contained within the frustoconical interior region between the retention members. An insulator placed between the outlet opening and the catalyst reaction surface minimizes temperature non-uniformities over the catalyst surface area, which preserves the catalyst contained within the reaction surface and prevents premature onset of the reaction prior to contact of a reactant mixture with the reaction surface. As a reactant fluid material passes through the inlet device it forms a homogenous reactant fluid material which then flows onto a catalytic reaction surface to form a reformate.
    Type: Grant
    Filed: September 15, 2003
    Date of Patent: September 11, 2007
    Assignee: General Motors Corporation
    Inventors: Michael Bart Viola, Changsoo Kim, Calvin K. Koch
  • Patent number: 7261749
    Abstract: An autothermal reformer is provided for a fuel cell system utilizing one volume and a plurality of inlets for both start-up and normal operation. In start-up mode, thermal combustion is employed for heating the catalyst reformation section of the reformer. Two inlets are used to feed air and fuel into the system, which are mixed and ignited in the common volume. Once the catalyst has reached light-off temperature, a second set of inlets provide air, steam and fuel into the common volume. The mixture then passes into the catalytic reformation system.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: August 28, 2007
    Assignee: General Motors Corporation
    Inventors: William H Pettit, Mohammed E. H. Sennoun, Gerald E Voecks
  • Publication number: 20070180767
    Abstract: A non-pyrophoric shift reaction catalyst includes an oxide carrier impregnated with platinum (Pt) and cerium (Ce). The non-pyrophoric shift reaction catalyst may be prepared by uniformly mixing a platinum precursor, a cerium precursor, and an oxide carrier in a dispersing medium to obtain a mixture; drying the mixture; and calcining the dried mixture. The shift reaction catalyst having a non-pyrophoric property has an excellent reaction activity even at a low temperature and can efficiently remove carbon monoxide in fuel.
    Type: Application
    Filed: November 29, 2006
    Publication date: August 9, 2007
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Hyun-chul Lee, Soon-ho Kim, Doo-hwan Lee, Yulia Potapova, Ok-young Lim, Eun-duck Park, Eun-yong Ko
  • Patent number: 7252692
    Abstract: A shell and tube reactor module for hydrogen production is provided.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: August 7, 2007
    Inventor: Min-Hon Rei
  • Publication number: 20070169412
    Abstract: Disclosed is an exemplary sulfided cobalt oxide catalyst that may be disposed on an alumina or other catalyst support, for use in destruction of tar compounds formed during gasification of biomass and fossil derived fuels. Most catalysts are rapidly deactivated by sulfur gases and/or alkali metals. Through experimentation, it has been demonstrated that the exemplary catalyst does not suffer deactivation caused by sulfur (as H2S), or sodium (as Na2CO3, Na2SO4, or NaCl).
    Type: Application
    Filed: January 26, 2007
    Publication date: July 26, 2007
    Inventors: Scott A. Sinquefield, Taishan Fan
  • Patent number: 7247293
    Abstract: A process for the producton of pure syngas (hydrogen and carbon dioxide) by fast gasification of liquid, muddy, or solid raw materials, either produced for the purpose or from industrial processes in which they can not be recycled, or fuels from wastes or biomass, which process is carried out in a modular reactor including a raw materials feeding area, a gasification area, a discharging area of the residues in powdery or vitrified form. The obtained syngas is sent to a purification and compression step.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: July 24, 2007
    Assignee: Nesi Plant S.A.
    Inventor: Vincenzo Sorace
  • Patent number: 7244281
    Abstract: A plasma fuel reformer assembly for producing reformate gas includes a fuel reformer having an air/fuel input assembly, an electrode assembly, and a soot trap positioned downstream of the electrode assembly. The electrode assembly includes a first electrode and a second electrode that is spaced apart from the first electrode. The fuel reformer further includes a reformer controller electrically coupled to the air/fuel input assembly. The reformer controller includes a processing unit electrically connected to a memory unit.
    Type: Grant
    Filed: October 24, 2003
    Date of Patent: July 17, 2007
    Assignee: Arvin Technologies, Inc.
    Inventors: Samuel N. Crane, Jr., William Taylor, III
  • Patent number: 7238215
    Abstract: In an integrated process for the production of synthesis gas, a partial oxidation unit and a steam methane reformer are used to convert natural gas or another fuel to first and second mixtures of at least carbon monoxide and hydrogen, only the first process consuming oxygen. Carbon dioxide derived from the second mixture is sent to the inlet of the first process to reduce the oxygen consumption. The first and optionally second mixtures may be used as synthesis gas for a process such as a Fischer Tropsch process.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: July 3, 2007
    Assignee: L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Pierre-Robert Gauthier, Christian Lacoste
  • Patent number: 7235218
    Abstract: A compact catalytic reactor comprises a stack of plates (72, 74, 75) to define a multiplicity of first and second flow channels arranged alternately in the stack; each flow channel in which a chemical reaction is to take place is defined by straight-through channels across at least one plate, each such straight-through channel containing a removable gas-permeable catalyst structure (80) incorporating a metal substrate. The first flow channels (76) are oriented in a direction that is perpendicular to that of the second flow channels (77), and between successive second flow channels in the stack the reactor defines at least three side-by-side first flow channels (76); and the reactor incorporates flow diversion means (80; 88) such that the first fluid must flow through at least three such first flow channels (76) in succession, in flowing from an inlet to an outlet. The overall flow paths can therefore be approximately co-current or counter-current.
    Type: Grant
    Filed: April 14, 2005
    Date of Patent: June 26, 2007
    Assignee: Compactgtl PLC
    Inventor: Michael Joseph Bowe
  • Patent number: 7232553
    Abstract: Disclosed is a plate type steam reformer comprising a plate type burner capable of heating a broad area of a reactor as a heat source, positioned on a bottom of the reformer; a reforming reactor requiring a relatively high temperature, positioned over the burner; a high temperature water gas shift reactor requiring a relatively moderate temperature, positioned over the reforming reactor; a low temperature water gas shift reactor requiring a relatively low temperature, positioned over the high temperature water gas shift reactor; and dividing plates positioned between the above three reactors and between the reforming reactor and the burner such that combustion exhaust gas produced in the burner supplies heat to the above reactors.
    Type: Grant
    Filed: May 2, 2002
    Date of Patent: June 19, 2007
    Assignees: Korea Gas Corporation, Korea Research Institute of Chemical Technology
    Inventors: Young-Sam Oh, Young-Soon Baek, Taek-Yong Song, Sang-Eon Park, Ki-Won Jun, Ri-Sang Choi
  • Patent number: 7232471
    Abstract: A hydrogen generator comprises a burner for generating a combustion gas, a reformer provided around the burner to generate a reformed gas containing hydrogen by a steam reforming reaction based on a feed material comprising a compound containing at least carbon and hydrogen and a steam, using heat transmission from a combustion gas generated by the burner, and an evaporator having an inner tube provided around the burner, an outer tube provided around the inner tube, and a bottom plate that closes a lower portion of a tubular space formed between the inner tube and the outer tube, the evaporator being configured to evaporate water supplied to the tubular space to generate a steam to be supplied to the reformer, wherein a water absorbing member having a water absorbing capability is provided in the tubular space.
    Type: Grant
    Filed: October 9, 2003
    Date of Patent: June 19, 2007
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yoshio Tamura, Yuji Mukai, Akira Maenishi, Tomonori Asou
  • Patent number: 7226490
    Abstract: An apparatus for converting hydrocarbon fuel to a hydrogen rich gas including a first heat exchanger for heating the hydrocarbon fuel, a first desulfurization reactor for reacting a heated hydrocarbon fuel to produce a substantially desulfurized hydrocarbon fuel, a manifold for mixing the substantially desulfurized hydrocarbon fuel with an oxygen containing gas to produce a fuel mixture, a second heat exchanger for heating the fuel mixture, an autothermal reactor including a catalyst for reacting the heated fuel mixture to produce a first hydrogen containing gaseous mixture, a second desulfurization reactor for producing a second hydrogen containing gaseous mixture that is substantially desulfurized, a water gas shift reactor for reacting the second hydrogen containing gaseous mixture to produce a third hydrogen containing gaseous mixture with a substantially decreased carbon monoxide content, and a selective oxidation reactor for reacting the third hydrogen containing gaseous mixture to produce the hydrogen
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: June 5, 2007
    Assignee: Texaco, Inc.
    Inventors: Vijay A. Deshpande, Curtis Krause
  • Patent number: 7223296
    Abstract: A hydrogen generation system may include a burner unit that generates combustion gas and a combustion gas passage through which the combustion gas generated by the burner unit flows. A reformer, having a reforming catalyst, generates a reformed gas containing hydrogen by steam reforming a feed material and steam using the heat from the combustion gas. An evaporator evaporates water into steam using the heat from the combustion gas, flowing through the combustion gas passage, and supplies the steam to the reformer. The combustion gas passage is arranged to cover at least a portion of an outer surface of the reformer, and the evaporator is arranged to cover at least a portion of an outer surface of the combustion gas passage.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: May 29, 2007
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Tomonori Asou, Akira Maenishi, Yutaka Yoshida, Kunihiro Ukai, Yuji Mukai
  • Patent number: 7223373
    Abstract: A catalytic reactor comprises a plurality of sheets defining flow channels between then. Within each flow channel is a foil of corrugated material whose surfaces are coated with catalytic material. The flow channels extend in transverse dire options, but the foils are shaped to cause the gas in those channels to flow at least partly in counter current to the gas flowing in the other channels. The reactor incorporates header chambers to supply gas mixtures to the flow channels, each header being in the form of a cap attached to the outside of the back and covering a face of the stack. Hence different gas mixtures are supplied to the different channels which may be at different pressures, and the corresponding chemical reactions are also different, and heat is transferred through the sheets separating the adjacent channels. When the catalyst in one set of flow channels becomes spent, it can be replaced by removing a header.
    Type: Grant
    Filed: September 23, 2002
    Date of Patent: May 29, 2007
    Assignee: Compactgtl PLC
    Inventor: Jason Andrew Maude
  • Patent number: 7220392
    Abstract: A fuel conversion reactor includes a shell-and-tube heat exchanger for controlling the temperature of a hot gaseous mixture produced by catalytic or non-catalytic reaction of a fuel with a gaseous fluid, and for controlling the temperature of the gaseous fluid and/or the fuel prior to the reaction. The reactor is either a catalytic or non-catalytic burner, or a fuel reformer for converting a fuel to hydrogen. A preferred reactor includes an outer shell having first and second ends and an inner surface, a primary inner shell extending into the outer shell, the primary inner shell defining a heat exchanging chamber and having primary and secondary ends, and a secondary inner shell having a first end located adjacent the secondary end of the primary inner shell. One or more outlet apertures are formed between the two inner shells for passage of the gaseous fluid out of the heat exchanging chamber.
    Type: Grant
    Filed: May 22, 2003
    Date of Patent: May 22, 2007
    Assignee: Dana Canada Corporation
    Inventors: Xiaoyang Rong, Brian E. Cheadle
  • Patent number: 7214251
    Abstract: The compact steam reformer of the present invention integrally comprises a housing; a reforming reactor having an upper mixing compartment for mixing natural gas and steam and a lower compartment for accommodating a catalyst bed; a natural gas feeding coiled pipe through which natural gas is introduced while being heated; a steam generating coiled pipe in which pure water is converted to steam by the exhaust; a metal fiber burner for heating the reforming reactor; a high-temperature converter for primarily removing carbon monoxide from a synthetic gas; a low-temperature converter for secondarily reducing the carbon monoxide level of the synthetic gas; and a heat exchanger, provided between the high-temperature converter and the low-temperature converter, for cooling the gas effluent from the high-temperature converter.
    Type: Grant
    Filed: April 23, 2002
    Date of Patent: May 8, 2007
    Assignees: Korea Gas Corporation, Kyungdong City Gas Co. Ltd., Korea Research Institute of Chemical Technology
    Inventors: Young-Sam Oh, Young-Soon Baek, Won-Ihl Cho, Taek-Yong Song, Jeong-Hwan Lee, Sang-Eon Park, Ki-Won Jun, Ri-Sang Choi
  • Patent number: 7201983
    Abstract: A hydrogen generation apparatus has a reformer of generating a reformed gas containing at least hydrogen and carbon monoxide by making a material containing an organic compound react with water; carbon-monoxide-removing means of including at least a shifter of reducing the carbon monoxide contained in the reformed gas generated by the reformer in accordance with a shift reaction; and material-humidifying means of humidifying the material by directly or indirectly using moisture contained in the reformed gas.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: April 10, 2007
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Kiyoshi Taguchi, Kunihiro Ukai, Hidenobu Wakita, Seiji Fujihara
  • Patent number: 7201883
    Abstract: A catalytic reactor comprises a plurality of sheets defining flow channels between them. Within each flow channel is a foil of corrugated material whose surfaces are coated with catalytic material. Flow channels for a first gas extend in oblique directions relative to the flow channels for a second gas. The reactor incorporates header chambers to supply gas mixtures to the flow channels, the headers communicating with adjacent channels being separate. The reactor enables different gas mixtures to be supplied to adjacent channels, which may be at different pressures, and the corresponding chemical reactions are also different. Where one of the reactions is endothermic while the other reaction is exothermic, heat is transferred through the sheets separating the endothermic reaction. When the catalyst in one set of flow channels becomes spent, it can be replaced by removing a header.
    Type: Grant
    Filed: September 12, 2002
    Date of Patent: April 10, 2007
    Assignee: Compactgtl PLC
    Inventors: Michael Joseph Bowe, Clive Derek Lee-Tuffnell
  • Patent number: 7195657
    Abstract: A hydrogen generation system comprises a reformer 1 that contains a reforming catalyst, an evaporator 4 that supplies steam to the reformer 1, a heater 3 that heats the reformer 1 and the evaporator 4, a material feed portion 5 that feeds a feed material containing hydrocarbon compound to the reformer 1 through the evaporator 4, and a water supply portion 6 that has a flow rate switch 6a and supplies water to the reformer 1 and the evaporator 4.
    Type: Grant
    Filed: March 25, 2003
    Date of Patent: March 27, 2007
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Kunihiro Ukai, Kiyoshi Taguchi, Hidenobu Wakita, Seiji Fujihara, Akira Maenishi
  • Patent number: 7195663
    Abstract: Hydrogen-producing fuel processing systems, hydrogen purification membranes, hydrogen purification devices, and fuel processing and fuel cell systems that include hydrogen purification devices. In some embodiments, the fuel processing systems and the hydrogen purification membranes include a metal membrane, which is at least substantially comprised of palladium or a palladium alloy. In some embodiments, the membrane contains trace amounts of carbon, silicon, and/or oxygen. In some embodiments, the membranes form part of a hydrogen purification device that includes an enclosure containing a separation assembly, which is adapted to receive a mixed gas stream containing hydrogen gas and to produce a stream that contains pure or at least substantially pure hydrogen gas therefrom. In some embodiments, the membrane(s) and/or purification device forms a portion of a fuel processor, and in some embodiments, the membrane(s) and/or purification device forms a portion of a fuel processing or fuel cell system.
    Type: Grant
    Filed: May 25, 2006
    Date of Patent: March 27, 2007
    Assignee: IdaTech, LLC
    Inventors: David J. Edlund, William A. Pledger, R. Todd Studebaker