Air And Steam Injected Patents (Class 48/63)
  • Patent number: 4541840
    Abstract: The invention relates to a process and a device for the discharge of residues of ash-containing fuels occurring during gasification of coal. The hot mixture of residues and water is separated in a separating chamber, whereby the residues enter a lock vessel situated under the separating chamber. The hot water is recycled to the water bath situated under the gasification reactor. After the lock vessel has been filled with residue, the hot water in the separating chamber is cooled or replaced by cold water. The discharge of the residues is pressureless and is effected by a stream of water flowing through the separating chamber into the lock vessel. Separating chamber and lock vessel remain filled with water at all times.
    Type: Grant
    Filed: August 8, 1983
    Date of Patent: September 17, 1985
    Assignee: Ruhrchemie Aktiengesellschaft
    Inventors: Josef Hibbel, Ulrich Gerhardus, Volkmar Schmidt, Bernhard Lieder, Heinrich Scheve, Erwin Zerres
  • Patent number: 4533362
    Abstract: A cyclic char gasifier plant is described which, from a single gas expander, can produce two or more separated and differing product reacted gases by use of an exhaust divider valve at the expander discharge.
    Type: Grant
    Filed: July 5, 1984
    Date of Patent: August 6, 1985
    Inventor: Joseph C. Firey
  • Patent number: 4527997
    Abstract: Coal gasification apparatus wherein a combustible mixture is formed and burned, comprising a combustion supporting gas such as oxygen, and a coal slurry. The hot products of combustion which issue from the burner, are directed into the reaction chamber of a synthesis gas generator. To avoid deposition of slag and ash particles along the hot, exposed face of the burner, a dynamic fluid blanket or barrier is directed transversely of the burner face. The reaction chamber includes an elongated port in which the burner is registered. To shield the burner, a manifold depends from the reaction chamber wall adjacent to the burner face and projects a stream of coolant fluid transversely of the face.
    Type: Grant
    Filed: August 12, 1982
    Date of Patent: July 9, 1985
    Assignee: Texaco Inc.
    Inventor: Michael L. Espedal
  • Patent number: 4490157
    Abstract: A fluidized bed gasifier (10) for gasifying a first fuel (50) receives heat indirectly from a combusting fluidized bed (24) disposed at least partially within the gasifier fluidized bed (12). Fuel for the combusting bed (24) may be provided by removing a portion of the fluidized first fuel from the gasifier bed (12) and transporting (30,34) this removed portion into the combusting bed (12). Heat is transferred across the conductive walls of the combustor vessel (26). Product gas heating value is increased by separately removing (28) the products of combustion from the gasifier (10) and by recycling a portion of the product fuel gas (74) as the fluidizing gas (54) for the gasifier fluidized bed (12). A radiation shield (18) is also provided to reduce heat loss from the gasifier bed (12) and to remove elutriated material from the product fuel gas.
    Type: Grant
    Filed: January 10, 1983
    Date of Patent: December 25, 1984
    Assignee: Combustion Engineering, Inc.
    Inventor: John H. Fernandes
  • Patent number: 4482359
    Abstract: A combustible gas producer plant is described in which a finely divided inert particulate material fluidized bed is divided into a first, combustible-gas producing section and a second, heating section, to both of which sections fuel is fed. Heat transfer, by bed material migration, from the second to the first section sustains the reaction in the first section leading to the production of combustible gas. A diaphragm water wall divides and surrounds the volumes above bed sections and is part of a boiler generating steam used (optionally with added oxygen) to fluidize the first bed section. The steam is also used to fluidize the bed material at the boundary of the bed sections and prevent in-bed gas migration across that boundary. The second section of the bed is fluidized with air or an air/inert gas mixture. Fluidization is effected with sparge tubes and the plant may include evaporator, superheater and economizer sections for the boiler.
    Type: Grant
    Filed: July 20, 1982
    Date of Patent: November 13, 1984
    Assignee: The Energy Equipment Company Limited
    Inventor: Peter B. Caplin
  • Patent number: 4452611
    Abstract: A downdraft channel gasifier for the efficient conversion of biomass materials to usable heat energy, which includes at least two generally triangularly shaped air ducts positioned longitudinally across an enclosed housing defining a combustion chamber. The air ducts have sloping sides which downwardly converge towards one another to define at least one open-botton V-shaped channel, the sloping sides primarily supporting the biomass fuel which will be combusted to derive producer gas. The air ducts are hollow and are in fluid communication with a high pressure air source at one end, and with the gasification chamber through air jet openings near their apexes. The high pressure air exits out air jet openings along the top edges of the air ducts, providing primary air for gasification of the biomass in the channels. The producer gas passes down between the channels and horizontally to an exit.
    Type: Grant
    Filed: May 24, 1982
    Date of Patent: June 5, 1984
    Inventor: Clarence B. Richey
  • Patent number: 4435364
    Abstract: An apparatus for withdrawing agglomerated solids, e.g. ash, from a fluidized bed of finely divided solid hydrocarbonaceous material, e.g. coal, is described. Agglomeration is effected by a high temperature reaction between the inorganic constituents of the hydrocarbonaceous material in the fluidized bed environment. A venturi is utilized to serve as a passage for withdrawing the agglomerated solids from the fluidized bed. Spiral or other descending ridges are positioned on the interior surface of the constricted cylindrical opening of the venturi to permit variable and increased rates of agglomerate discharge with improved separation and classification of the solid materials.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: March 6, 1984
    Assignee: Institute of Gas Technology
    Inventor: Karl S. Vorres
  • Patent number: 4400181
    Abstract: Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature.
    Type: Grant
    Filed: January 28, 1982
    Date of Patent: August 23, 1983
    Assignee: Hydrocarbon Research, Inc.
    Inventors: George J. Snell, Paul H. Kydd
  • Patent number: 4385905
    Abstract: A system is disclosed for the conversion of solid carbonaceous fuels to combustible gases having a high energy content. The system utilizes a two-stage reaction system where a particulate fuel is entrained in a high velocity, hot gas stream emanating from a fixed-bed char reactor, the particulate fuel delivered to a gasification reactor by the hot gas stream while being rapidly heated (fast pyrolized). The gases produced are drawn a fixed distance through a bed of char at the bottom of the gasification reactor, after which they are withdrawn from the reactor and cooled. To promote methanation, the generated gases, after passing through the fixed bed of char in the gasification reactor, exit the reactor through a dip leg within the reactor filled with a catalyst which promotes methanation.
    Type: Grant
    Filed: July 20, 1981
    Date of Patent: May 31, 1983
    Assignee: Everett Metal Products, Inc.
    Inventor: Gordon H. Tucker
  • Patent number: 4377394
    Abstract: An apparatus in which a downflowing high pressure stream of hot raw synthesis gas from the reaction zone of a free flow partial oxidation gas generator at a temperature in the range of about 1800.degree. to 3000.degree. F. is passed through a first gas diversion and residue separation chamber contained in a first pressure vessel where the velocity of the gas stream is reduced, solid material and molten slag are separated by gravity from the gas stream, and the direction is diverted into a thermally insulated side transfer line. The hot gas stream is then passed through a thermally insulated gas-solids impingement separation means contained in a second pressure vessel where its direction and velocity is changed and additional residue is separated. The hot gas stream is then passed upwardly through a radiant cooler where additional solid matter is removed by gravity and the gas temperature is reduced to a temperature in the range of about 900.degree. to 1800.degree. F.
    Type: Grant
    Filed: July 28, 1980
    Date of Patent: March 22, 1983
    Assignee: Texaco Development Corporation
    Inventors: James R. Muenger, Edward T. Child, Albert Brent
  • Patent number: 4359326
    Abstract: A process and pressurized, gasification reactor apparatus for converting combustible carbon containing materials such as coal char and other carbonaceous solids or carbonaceous solids/heavy oil combinations to an intermediate heating value fuel gas. The gasification reactor includes an insulated fluidized bed reactor chamber, an upper reactor housing for a freely suspended bayonet bundle type heat exchanger for (a) superheating incoming saturated steam and (b) cooling outgoing high temperature product gas, and a lower reactor housing structure which includes a free-floating, conically-shaped perforated plenum chamber. The superheated steam and oxygen are premixed with the plenum chamber before being pressure directed into the fluidized bed reactor chamber for mixture and combustion with the incoming combustible carbon containing materials such as coal char. After reaction of the superheated steam, oxygen and coal char in the fluidized bed reactor at temperatures ranging from 900.degree. F. to 1750.degree. F.
    Type: Grant
    Filed: November 20, 1980
    Date of Patent: November 16, 1982
    Assignee: Hydrocarbon Research, Inc.
    Inventors: Franklin D. Hoffert, John D. Milligan, Jose M. Marina, Jose M. Fernandez
  • Patent number: 4352675
    Abstract: Disclosed is a reactor for gasifying coal including a vortex burner. Helical ribs are arranged in the inner combustion gas supplying conduit of the burner to impart a spiral trajectory to the gas and also the coal-water suspension which suspension is supplied in the annular space between the inner conduit and an outer concentric conduit. Means are provided for adjustably supporting the ribs inside the inner conduit. In addition, other rib supporting arrangements and also burner structure for supplying the coal-water slurry centrally are disclosed.
    Type: Grant
    Filed: November 30, 1979
    Date of Patent: October 5, 1982
    Assignee: Ruhrkohle Aktiengesellschaft
    Inventors: Jurgen Seipenbusch, Hans Dohren
  • Patent number: 4340397
    Abstract: A slagging gasifier for the gasification of coal and organic waste materials is disclosed The gasifier includes a vertical blast furnace having a hearth section at the bottom thereof. A slag tap hole is formed in hearth section and opens into a quenching vessel. A honeycomb structure is formed on the inner surface of said hearth section in the area surrounding said slag tap hole, and the inner wall of the hearth section. A plurality of tuyeres extend into the hearth section and feed the furnace with steam and oxygen so as to permit the oxidation of coal and organic waste materials fed into the furnace. As a result of the oxidation, gas and molten slag are formed in the furnace. The slag is collected in the hearth section and exits the hearth section via the tap hole.
    Type: Grant
    Filed: October 14, 1980
    Date of Patent: July 20, 1982
    Assignee: Brandenberg Energy Corporation
    Inventor: Helmut Schulz
  • Patent number: 4337066
    Abstract: Apparatus for thermally decomposing and gasifying either liquid or solid combustible material in a single reactor filled with working medium in a high active fluidization, said reactor being provided with two partitions, one of which is extended downwards up to the lower portion of the reactor, while the other is vertically extended at the lower and middle portions thereof substantially at a right angle to the first partition, whereby the reactor is divided into two sections, that is, thermal decomposition and gasification section and combustion and heating section, so that thermal decomposing and gasifying are performed by way of supplying the combustible raw material into the downwardly travelling working medium and at the same time supplying steam thereinto for generating and maintaining the high active fluidization of the working medium in the thermal decomposition and gasification section, while burning and heating are performed by way of supplying air or steam mixture gas of oxygen and steam into the up
    Type: Grant
    Filed: January 3, 1980
    Date of Patent: June 29, 1982
    Inventor: Daizo Kunii
  • Patent number: 4328006
    Abstract: An apparatus in which the hot raw synthesis gas stream leaving the reaction zone of a free flow partial oxidation gas generator at a temperature in the range of about 1800.degree. to 3000.degree. F. is passed through a first gas diversion and residue separation zone where the velocity of the gas stream is reduced and its direction is diverted into a side transfer line. Solid material and molten slag separate by gravity from the gas stream. The hot gas stream is then introduced into a second gas diversion and residue separation zone, which comprises a plurality of high temperature resistant, thermally insulated cyclones, where the direction and velocity is changed and additional residue is separated. About 0.5 to 20 vol. % of the hot gas stream may be passed through bottom outlets in said first and second gas diversion zones in order to prevent bridging.
    Type: Grant
    Filed: July 10, 1980
    Date of Patent: May 4, 1982
    Assignee: Texaco Development Corporation
    Inventors: James R. Muenger, Edward T. Child, Albert Brent
  • Patent number: 4323366
    Abstract: A pressure container forms a shaft gasifier for receiving coarse coal in the form of a coal bed. A burner extends through the pressure container into a chamber therein and produces at least one primary gas jet directed against the coal bed, thereby gasifying the coal and generating a product gas and forming liquid slag. The liquid slag collects in a slag bath tank having an overflow weir over which the collected slag flows and falls freely toward a cooling water bath beneath the chamber. A water jet nozzle directs at least one water jet against the liquid slag as it falls freely between the weir and the cooling water bath. This atomizes the liquid slag, thereby cooling the slag and generating steam. At least a part of the steam is supplied as process steam to the coarse coal.
    Type: Grant
    Filed: December 30, 1980
    Date of Patent: April 6, 1982
    Assignee: Voest-Alpine AG
    Inventor: Gernot Staudinger
  • Patent number: 4309194
    Abstract: Method and apparatus for removing ash formed within, and accumulated at the lower portion of, a fluidized bed coal gasification reactor vessel. A supplemental fluidizing gas, at a temperature substantially less than the average fluidized bed combustion operating temperature, is injected into the vessel and upwardly through the ash so as to form a discrete thermal interface region between the fluidized bed and the ash. The elevation of the interface region, which rises with ash accumulation, is monitored by a thermocouple and interrelated with a motor controlled outlet valve. When the interface rises above the temperature indicator, the valve opens to allow removal of some of the ash, and the valve is closed, or positioned at a minimum setting, when the interface drops to an elevation below that of the thermocouple.
    Type: Grant
    Filed: June 3, 1980
    Date of Patent: January 5, 1982
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Louis A. Salvador, Ronald E. Andermann, Lawrence K. Rath
  • Patent number: 4309195
    Abstract: Apparatus for effecting the conversion of solid fuels (including solid organic waste materials having a fuel valve) by high temperature gasification into clean-burning and uniform gaseous fuel called "producer gas." The apparatus comprises a two-section, stacked double-shell gasifier reactor defining sequentially descending, drying, distillation, oxidation and reduction reaction zones through which a continuously fed column of the solid fuel descends during its conversion to a gaseous fuel.
    Type: Grant
    Filed: June 2, 1980
    Date of Patent: January 5, 1982
    Assignee: Energy Recovery Research Group, Inc.
    Inventor: Franz Rotter
  • Patent number: 4300914
    Abstract: An integral gasifier including a pretreater section and a gasifier section separated by a distribution grid is defined by a single vessel. The pretreater section pretreats coal or other carbon-containing material to be gasified to prevent caking and agglomeration of the coal in the gasifier. The level of the coal bed of the pretreater section and thus the holding or residence time in said bed is selectively regulated by the amount of pretreated coal which is lifted up a lift pipe into the gasifier section. Thus, the holding time in the pretreater section can be varied according to the amount of pretreat necessary for the particular coal to be gasified.
    Type: Grant
    Filed: March 20, 1980
    Date of Patent: November 17, 1981
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Louis F. Rice
  • Patent number: 4289502
    Abstract: The hot raw synthesis gas stream leaving the reaction zone of a free flow partial oxidation gas generator at a temperature in the range of about 1800.degree. to 3000.degree. F. is passed through a first gas diversion and residue separation zone where the velocity of the gas stream is reduced and its direction is diverted into a side transfer line. Solid material and molten slag separate by gravity from the gas stream. The hot gas stream is then introduced into a second gas diversion and residue separation zone where additional residue is separated. About 0.5 to 20 vol. % of the hot gas stream may be passed through bottom outlets in said first and second gas diversion zones in order to prevent bridging. The hot gas stream from the second gas diversion zone is passed upwardly through a radiant cooler where additional solid matter is removed by gravity and the gas temperature is reduced to a temperature in the range of about 900.degree. to 1800.degree. F.
    Type: Grant
    Filed: November 29, 1979
    Date of Patent: September 15, 1981
    Assignee: Texaco Development Corporation
    Inventors: James R. Muenger, Edward T. Child, Albert Brent
  • Patent number: 4282009
    Abstract: PCT No. PCT/US79/00929 Sec. 371 Date Nov. 1, 1979 Sec. 102(e) date Nov. 1, 1979 PCT Filed Nov. 1, 1979 PCT Pub. No. WO81/01295 PCT Pub. Date May 14, 1981A rotating fluidized bed gasifier system especially useful in compound engines comprising an annular fluidization chamber containing a bed of carbon containing pulverulent solid materials. The chamber, which is defined by inner and outer spaced apart coaxial, cylindrical, perforated walls, rotates about the longitudinal axis of the cylinders. Steam enters the bed, which is maintained at about 1800.degree. F., through the outer perforated wall and fluidizes the particles. The steam reacts endothermically with the carbon to produce reaction product gas which exits the bed, together with unreacted steam, through the inner perforated wall. In a preferred form of the invention the bed is maintained at approximately 1800.degree. F. by combining a rotating fluidized bed combustor with the gasifier.
    Type: Grant
    Filed: November 1, 1979
    Date of Patent: August 4, 1981
    Assignee: Caterpillar Tractor Co.
    Inventors: William H. Belke, Alexander Goloff, George B. Grim
  • Patent number: 4282010
    Abstract: A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.
    Type: Grant
    Filed: July 17, 1979
    Date of Patent: August 4, 1981
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Peter Cherish, Louis A. Salvador
  • Patent number: 4272255
    Abstract: The apparatus of U.S. Pat. No. 3,988,123 is improved by constructing the heat recovery stage as a relatively elongated water-wall type of heat exchanger within a pressure shell, rather than of shell and tube type. The heat exchanger is advantageously formed from contiguous, externally finned, vertical tubes that are rigidly joined together to form a laterally closed, heat recovery chamber, the fin portion of one being welded along its tip to the tube portion of another adjoining such fin portion. The heat exchanger tubes preferably continue vertically throughout substantially the entire height of the gasification reaction i.e. combustion chamber of the first stage of the apparatus, completely eliminating the intermediate quench stage of the patented apparatus and serving to recover heat from the combustion stage as well as from the heat recovery stage by a heat exchange fluid, such as water, flowing through the tubes.
    Type: Grant
    Filed: July 19, 1979
    Date of Patent: June 9, 1981
    Assignee: Mountain Fuel Resources, Inc.
    Inventor: Ralph L. Coates
  • Patent number: 4229289
    Abstract: An apparatus and process for conduct of fluidized bed reactions having an improved grate wherein at least one substantially continuous open slot sufficiently wide for passage of heavy solid particles is provided for preferential removal of heavy particles from the fluidizing chamber. The apparatus and process is particularly useful in coal gasification applications.
    Type: Grant
    Filed: March 12, 1979
    Date of Patent: October 21, 1980
    Assignee: Institute of Gas Technology
    Inventor: John G. Victor
  • Patent number: 4218423
    Abstract: An assembly of a quench ring and dip tube is for use with a reactor vessel. It is particularly beneficial where the reactor generates large quantities of molten slag. The quench ring is mounted against the floor of the reactor vessel for cooling same, and there are a plurality of spray passages directing cooling water against the inside of the dip tube which surrounds the ring at the upper end, while extending into a bath of quench water.
    Type: Grant
    Filed: November 6, 1978
    Date of Patent: August 19, 1980
    Assignee: Texaco Inc.
    Inventors: Allen M. Robin, Americo R. Catena
  • Patent number: 4200438
    Abstract: Solid fuel is acted on by a gasifying medium in a fluidized bed W. The resulting gas enters a cyclone 20 having an outlet for solid particles connected to a gasification chamber 30 in which the particles are gasified by a separate stream of gasifying medium supplied by an injector 25.
    Type: Grant
    Filed: September 11, 1978
    Date of Patent: April 29, 1980
    Assignee: Projektierung Chemische Verfahrenstechnik GmbH
    Inventors: Walter Kaimann, Karl-Heinz Brachthauser
  • Patent number: 4187672
    Abstract: The invention is concerned with novel apparatus and process for converting crude carbon such as coal, carbonaceous wastes and the like into valuable chemical products and/or energy. A mass of solid crude carbonaceous fuel is fed into a high temperature liquid which acts as a solvent for carbon at a temperature sufficient to carbonize the mass and by which the carbon is separated from impurities. Volatile fractions are removed from the mass which acts as a distillation column. Air, or another oxygen source, is introduced into the reactor wherein it reacts with the carbon dissolved in the liquid therein, which may preferably be iron to form a hot fuel gas. The hot fuel gas is then used to produce useful energy, generally via a stepwise procedure.
    Type: Grant
    Filed: November 17, 1977
    Date of Patent: February 12, 1980
    Assignee: Rasor Associates, Inc.
    Inventor: Ned S. Rasor
  • Patent number: 4106999
    Abstract: Apparatus for continuously pyrolyzing, vaporizing or gasifying a particulated carbonaceous feed material in which preheated heat-containing bodies or pebbles are admixed with the feed material in a stratified manner to form a downwardly moving columnar reaction mass, with a remaining portion of the pebbles substantially devoid of any feed material disposed in a surrounding layer relative to the reaction mass. Gas is continuously passed transversely through the reaction mass and surrounding layer in a manner to sweep the gaseous pyrolysis reaction products out of the reaction chamber and wherein the layers of pebbles surrounding the reaction mass serve to effect a deposition of carbonaceous residue preventing encrustation and fouling of the reactor.
    Type: Grant
    Filed: November 7, 1977
    Date of Patent: August 15, 1978
    Assignee: Edward Koppelman
    Inventors: Edward Koppelman, Robert G. Murray
  • Patent number: 4098586
    Abstract: Symmetrical stepped grate/rabble arm combinations for use in a fixed bed coal gasifier are shown in which the stepped grates comprise step plates having in combination threwith means for controlling the rate of discharge of solids therefrom. The solids discharge controlling means described comprise adjustable mechanical dams at spaced locations along the step plate periphery together with means for the positioning thereof.
    Type: Grant
    Filed: August 1, 1977
    Date of Patent: July 4, 1978
    Assignee: General Electric Company
    Inventor: Donald E. Woodmansee
  • Patent number: 4095959
    Abstract: Coal gasification apparatus having a hydrogenation gasifier chamber for gasifying a portion of coal charge and a steam gasifier vessel for gasifying unconverted coal from the hydrogenation chamber with the chamber disposed above the vessel and a pressure lock interposed between the outlet of the chamber and the inlet of the vessel to permit unconverted coal to flow into the vessel and prevent gas generated therein from passing into the chamber. An oxygen inlet is provided at the lower end of the vessel for residual-oxidation of remaining coal. A heat exchanger is provided for heat exchange between hot gas leaving vessel and incoming steam. The chamber may be preceded by a steam-heated heating tank for preheating the coal under pressure and then suddenly decompressing the coal.
    Type: Grant
    Filed: February 14, 1977
    Date of Patent: June 20, 1978
    Assignee: Kraftwerk Union Aktiengesellschaft
    Inventors: Konrad Kunstle, Christian Koch, Kurt Reiter
  • Patent number: 4085578
    Abstract: A coal gasification power plant is described in which low BTU gas is generated and used to operate a gas tubine and accompanying equipment for the generation of power. This plant is equipped with means for enabling the intermittent operation of multiple fixed bed coal gasifier units thereof to simultaneously produce water gas (intermediate BTU gas) and low BTU gas (producer gas) as required to operate the gas turbine.
    Type: Grant
    Filed: March 14, 1977
    Date of Patent: April 25, 1978
    Assignee: General Electric Company
    Inventor: Paul H. Kydd
  • Patent number: 4069107
    Abstract: Apparatus and process for continuously pyrolyzing or gasifying a particulated carbonaceous feed material in which preheated heat-containing bodies or pebbles are admixed with the feed material in a stratified manner to form a downwardly moving columnar reaction mass, with a remaining portion of the pebbles substantially devoid of any feed material disposed in a surrounding layer relative to the reaction mass. Gas is continuously passed transversely through the reaction mass and surrounding layer in a manner to sweep the gaseous pyrolysis reaction products out of the reaction chamber, and wherein the layers of pebbles surrounding the reaction mass serve to effect a deposition of carbonaceous residue, preventing encrustation and fouling of the reactor system.
    Type: Grant
    Filed: May 3, 1976
    Date of Patent: January 17, 1978
    Assignee: Edward Koppelman
    Inventors: Edward Koppelman, Robert G. Murray
  • Patent number: 4059415
    Abstract: Apparatus for converting a combustible material such as a hydrocarbon or carbon fuel into a gaseous fuel containing H.sub.2 and/or CO by reaction with a heated mixture of O.sub.2 and H.sub.2 O prepared by decomposition of H.sub.2 O.sub.2, characterized by the provision of a venturi section located upstream of the entrance to a reaction chamber for increasing the velocity of the flow of the O.sub.2 --H.sub.2 O mixture and arrangement of the combustible feed line to add the combustible to the mixture at the venturi.
    Type: Grant
    Filed: May 27, 1976
    Date of Patent: November 22, 1977
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Katuaki Kosaka, Fumio Wagatsuma, Mithuo Shimomoto, Osamu Harada, Zene Ueno
  • Patent number: 4055484
    Abstract: In a fluid coking process, a gas containing coke particles is elutriated in a riser portion of a vessel to remove selectively the larger coke particles. The elutriated gas flows into a bed of solids positioned in the upper portion of the vessel.
    Type: Grant
    Filed: May 14, 1976
    Date of Patent: October 25, 1977
    Assignee: Exxon Research & Engineering Co.
    Inventors: Don E. Blaser, Byron V. Molstedt
  • Patent number: 4032305
    Abstract: The relatively small degree of backmixing of gas in a well-arranged fast fluidized bed is exploited to introduce heat into a fluidized bed reaction system wherein a fluidized bed treatment zone receiving heat and for the purpose of conducting an endothermic treatment of matter can have a gas atmosphere, such as relatively pure steam, that is maintained independently of and without admixture by any gas or gases that are associated with a step for introducing the heat. The treatment advantageously constitutes a treatment of a carbonaceous matter, such as coal or petroleum or municipal solid waste, with hot steam for purpose of gasifying or carbonizing or cracking the matter. The arrangement is also useful for a broad range of endothermic chemical or physical treatment of matter at high temperature.
    Type: Grant
    Filed: October 7, 1974
    Date of Patent: June 28, 1977
    Inventor: Arthur M. Squires
  • Patent number: 4023280
    Abstract: A fluidized bed of material retained in a vessel receives a high velocity gas stream through a venturi orifice and passage to assist in the agglomeration of ash particles. The particles form a semi-fixed bed within the passage upstream from the venturi orifice. The particular dimensions of the semi-fixed bed are dependent, in part, upon the orifice size of the venturi. An iris valve defining the orifice permits adjustment of the cross-sectional area of the orifice thereby controls the velocity of the gas stream through the venturi.
    Type: Grant
    Filed: May 12, 1976
    Date of Patent: May 17, 1977
    Assignee: Institute of Gas Technology
    Inventors: Frank C. Schora, John W. Loeding, Jitendra G. Patel
  • Patent number: 4022591
    Abstract: An apparatus for the continuous gasification of coal by partial combustion with a reactant gas is disclosed, wherein a vertical gasification reactor is provided with a reactant supply and ash removal assembly adapted to supply coal and reactant gases and to remove ash particles to and from the reactor via a constricted passageway in the reactor bottom. The assembly includes an ash quench chamber having means for supplying coal and reactant gases through the reactor disposed therein which opens opposite the constricted passageway a predetermined distance therefrom. The apparatus may be operated continuously without collecting by-product ash particles in the reactor and without superheating the reactant supply means.
    Type: Grant
    Filed: June 14, 1976
    Date of Patent: May 10, 1977
    Assignee: Shell Internationale Research Maatschappij B.V.
    Inventor: Gernot Staudinger
  • Patent number: 4014664
    Abstract: A reactor for the pressure gasification of coal by treatment with oxygen and steam and, if desired, additional gasifying agents, at elevated temperatures and pressures, includes a water-cooled jacket and a rotary grate for moving the material to be gasified and for distributing the gasifying agents introduced into the reactor. The rotary grate is made of at least two concentric parts each of which rotates independly of the other part.
    Type: Grant
    Filed: October 10, 1975
    Date of Patent: March 29, 1977
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Hans Kupfer, Paul Lange, Paul Rudolph
  • Patent number: 4011059
    Abstract: Stirrer construction adapted for both vertical and rotational movements is described for use in a fixed bed coal gasifier. Rabble arms projecting from a depending shaft are arranged as an upper and a lower set. The rabble arms in the lower set each present shear edges at and adjacent the tips thereof in order to be lowered into the ash zone, when desired, to break away the hard sintered masses that tend to develop along the wall there. Also, the lower set of rabble arms is designed for use in the combustion ("hot") zone to break up or loosen clinker formation with minimum damage to the ceramic liner in this portion of the gasifier. The rabble arms in the upper set are longer than the rabble arms in the lower set and extend closer to the wall of the gasifier being used both in order to center the stirrer shaft and to stir the upper regions of the coal bed.
    Type: Grant
    Filed: January 30, 1976
    Date of Patent: March 8, 1977
    Assignee: General Electric Company
    Inventors: John W. Daly, Kenneth A. Darrow
  • Patent number: 4002438
    Abstract: There is disclosed herein a method and an apparatus for converting organic materials into a high quality fuel product. The process involves introducing the organic materials into a stream heated to a temperature of about 1600.degree. - 2000.degree. F and comprised of a carrier gas and a hard, particulate material. The organic material is rapidly converted into a fuel product which is then separated from the stream. The process can be used to form either a liquid or gaseous fuel product.
    Type: Grant
    Filed: January 22, 1975
    Date of Patent: January 11, 1977
    Inventor: Joseph Fleming
  • Patent number: 3981690
    Abstract: A method and apparatus for gasifying coal wherein the gasification takes place in a spout fluid bed at a pressure of about 10 to 30 atmospheres and a temperature of about 1800.degree. to 2200.degree.F and wherein the configuration of the apparatus and the manner of introduction of gases for combustion and fluidization is such that agglomerated ash can be withdrawn from the bottom of the apparatus and gas containing very low dust loading is produced. The gasification reaction is self-sustaining through the burning of a stoichiometric amount of coal with air in the lower part of the apparatus to form the spout within the fluid bed. The method and apparatus are particularly suitable for gasifying coarse coal particles.
    Type: Grant
    Filed: January 15, 1975
    Date of Patent: September 21, 1976
    Assignee: The United States of America as represented by the United States Energy Research and Development Administration
    Inventors: Joseph L. P. Chen, David H. Archer
  • Patent number: 3970436
    Abstract: A steam generating system for a gas producer of the type including a combustion chamber and an annular water jacket surrounding the chamber is disclosed characterised in that the upper part of the jacket is of larger diameter than the lower part thereof, the lower part being heated through substantially direct contact with the combustion chamber and the upper part being insulated from the chamber preferably by means of a skin of fire bricks or the like; an open upwardly directed vent pipe communicating with the lower part of the jacket; and a steam exhaust line communicating with the upper part of the jacket. The system also includes a venturi arrangement for introducing the generated steam to the air blast as well as a safety valve in the steam line which is adapted to respond to temperature changes in the air blast.
    Type: Grant
    Filed: August 12, 1975
    Date of Patent: July 20, 1976
    Inventor: Gerald Sydney Victor Livemore
  • Patent number: 3957457
    Abstract: Granulated coals or cokes derived from coal, in sizes up to about 3/4 inch and containing ash matter with an initial deformation temperature above about 2,300.degree.F, are fed to a slow fluidized bed comprising relatively large particles of coke intermingled with roughly spherical ash agglomerates, maintained at about 2,050.degree.F to 2,650.degree.F, and supplied with a gasification medium, for example, steam mixed with oxygen or air. A fast fluidized bed of coke fines is superposed above the slow bed and is contiguous therewith. Gasification products are discharged together with relatively fine particles of coke, which are collected and returned to the fast bed. Ash agglomerates are withdrawn from the bottom of the slow bed via a standpipe leading to a mechanical grate. An oxidizing medium is introduced below the grate to consume coke particles that accompany the ash agglomerates entering the standpipe.
    Type: Grant
    Filed: October 7, 1974
    Date of Patent: May 18, 1976
    Inventor: Arthur M. Squires
  • Patent number: 3957458
    Abstract: Granulated coals or cokes derived from coal, in sizes up to about 3/4 inch and containing ash matter with an initial deformation temperature below about 2,300.degree.F, are fed to a slow fluidized bed comprising relatively large particles of coke intermingled with roughly spherical ash agglomerates, maintained at about 1,900.degree.F to about 2,450.degree.F, and supplied with a gasification medium, for example, steam mixed with oxygen or air. A fast fluidized bed of coke fines is superimposed above the slow bed and is contiguous therewith. Gasification products are discharged together with relatively fine particles of coke, which are collected and returned to the fast bed. Ash agglomerates are withdrawn from the bottom of the slow bed via a standpipe leading to a slagging grate. Combustion of coke fines in a forehearth beneath the slagging grate creates slagging temperatures therein and at the grate. Molten slag falls through a taphole and into a pool of water, from which slag frit and water are discharged.
    Type: Grant
    Filed: October 7, 1974
    Date of Patent: May 18, 1976
    Inventor: Arthur M. Squires
  • Patent number: 3951615
    Abstract: The gasification of solid fuels or mixtures of solid and liquid fuels takes place in a cylindrically-shaped pressure reactor vessel having feed jets at the top of the vessel for introducing the fuel and the gasification medium into the vessel. A ring-shaped chamber containing a bath of molten iron surrounds a gas discharge pipe within the lower portion of the vessel. A water bath is established below the lower rim of the discharge pipe in the vessel and pipe means passing through the side wall of the vessel at an elevation above the lower rim of the discharge pipe and below the ring-shaped chamber discharge the gases liberated within the vessel. Reactor means are provided for utilizing the residual heat of the gases passing from the vessel. In one embodiment, the reactor means comprise a fluidized bed chamber into which coal and steam are injected to utilize the residual heat of the gases.
    Type: Grant
    Filed: May 7, 1974
    Date of Patent: April 20, 1976
    Assignee: Dr. C. Otto & Comp. G.m.b.H.
    Inventors: Paul Gernhardt, Egon Haese, Wilhelm Dangullier
  • Patent number: 3937620
    Abstract: Coal is gasified under elevated pressures and temperatures in a reactor having a rotatably mounted grate and supply conduits for oxygen-containing and oxygen-free gasifying agents. The rotary grate contains an internal chamber adjacent to the bearing for the grate and one of the supply conduits is adapted to feed an oxygen-free fluid to this internal chamber. The uppermost portion of the rotary grate contains a substantially closed internal chamber which has a supply conduit for feeding an oxygen-free fluid thereto. A mixing chamber is positioned between the uppermost chamber and the chamber adjacent the bearing for the grate and is provided with passages which lead to the charge to be gasified. The mixing chamber communicates with the uppermost chamber as well as the chamber adjacent the bearing and also has a supply conduit for feeding gasifying agents containing free oxygen thereto.
    Type: Grant
    Filed: August 20, 1974
    Date of Patent: February 10, 1976
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Paul Rudolph, Hans Kupfer, Werner Schmidt
  • Patent number: 3935825
    Abstract: An improved apparatus for withdrawing agglomerated solids from a fluidizing chamber housing a main, fluidized bed of finely divided solids which comprises at least one withdrawal chamber having a width less than the fluidizing chamber and positioned below the fluidized bed. This withdrawal chamber has sufficient dimensions (width (or diameter when cylindrical) and depth) to contain a second fluidized or semi-fixed bed within said chamber when a high velocity gas stream is introduced into the bottom portion of the withdrawal chamber. This high velocity gas stream forms an inverted cone in the withdrawal chamber, wherein the walls of the cone are defined by the fluidized or semi-fixed bed within the withdrawal chamber. The velocity of the gas stream is adjusted to selectively remove high density agglomerates downward from the main fluidized bed without removing the fluidized solids in admixture therewith.
    Type: Grant
    Filed: February 24, 1975
    Date of Patent: February 3, 1976
    Assignee: Institute of Gas Technology
    Inventors: Charles W. Matthews, Jitendra G. Patel
  • Patent number: 3933445
    Abstract: An oxidizing gas is injected through a nozzle into a bed of carbonaceous particles in a downward direction at an angle of declination at least as great as the angle of repose of the bed particles and at a gas inlet velocity of about 50 to 500 feet per second to supply the gas needed to fluidize the bed of carbonaceous particles.
    Type: Grant
    Filed: October 15, 1973
    Date of Patent: January 20, 1976
    Assignee: Exxon Research and Engineering Company
    Inventors: David E. Mueller, William J. Metrailer
  • Patent number: 3930811
    Abstract: A reactor for the continuous gasification of coal under superatmospheric pressures and elevated temperatures with gaseous gasifying agents containing free oxygen and with oxygen-free gasifying agents such as steam and/or carbon dioxide is disclosed. The reactor includes a substantially conical rotary grate which is rotatably mounted in the lower portion of the reactor housing. The rotary grate feeds the gasifying agent and/or discharges the gasification residues. Notwithstanding the inside diameter of the reactor housing, the clearance a between the rotary grate and the housing is 100-200 millimeters, the height b of the annular rim of the rotary grate is 100-350 millimeters, and the vertical distance c from the rotary grate to the housing bottom is 100-350 millimeters.
    Type: Grant
    Filed: September 18, 1974
    Date of Patent: January 6, 1976
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Heinz Hiller, Paul Rudolph