Abstract: Disclosed herein are unmixed fuel processors and methods for using the same. In one embodiment, an unmixed fuel processor comprises: an oxidation reactor comprising an oxidation portion and a gasifier, a CO2 acceptor reactor, and a regeneration reactor. The oxidation portion comprises an air inlet, effluent outlet, and an oxygen transfer material. The gasifier comprises a solid hydrocarbon fuel inlet, a solids outlet, and a syngas outlet. The CO2 acceptor reactor comprises a water inlet, a hydrogen outlet, and a CO2 sorbent, and is configured to receive syngas from the gasifier. The regeneration reactor comprises a water inlet and a CO2 stream outlet. The regeneration reactor is configured to receive spent CO2 adsorption material from the gasification reactor and to return regenerated CO2 adsorption material to the gasification reactor, and configured to receive oxidized oxygen transfer material from the oxidation reactor and to return reduced oxygen transfer material to the oxidation reactor.

Abstract: Solid waste resource recovery in space is effected by pyrolysis processing, to produce light gases as the main products (CH4, H2, CO2, CO, H2O, NH3) and a reactive carbon-rich char as the main byproduct. Significant amounts of liquid products are formed under less severe pyrolysis conditions, and are cracked almost completely to gases as the temperature is raised. A primary pyrolysis model for the composite mixture is based on an existing model for whole biomass materials, and an artificial neural network models the changes in gas composition with the severity of pyrolysis conditions.

Abstract: Solid waste resource recovery in space is effected by pyrolysis processing, to produce light gases as the main products (CH4, H2, CO2, CO, H2O, NH3) and a reactive carbon-rich char as the main byproduct. Significant amounts of liquid products are formed under less severe pyrolysis conditions, and are cracked almost completely to gases as the temperature is raised. A primary pyrolysis model for the composite mixture is based on an existing model for whole biomass materials, and an artificial neural network models the changes in gas composition with the severity of pyrolysis conditions.

Abstract: A new combustion chamber design for a quench gasifier. Electrical heating is used in the throat area of the combustion chamber to achieve temperatures up to 3500° F. to melt ash deposits and to increase carbon conversion (reduce soot production). Silicon carbide and/or silicon nitride refractory materials are used in the hot face of the throat to withstand high temperatures and high temperature shocks. The proposed design reduces the capital cost of a gasification plant by eliminating the need for soot recovery and recycle system. This design also reduces the operating cost of the gasification plant by decreasing the frequent refractory damages that have been experienced in the throat area of the existing quench gasifiers.

Abstract: A method of the gasification of coal using oxygen and steam is provided wherein the coal is gasified at a temperature of from 1000 to 2500° C. and a pressure of from 1 to 100 kg/cm2 using oxygen generated by electrolyzing water and steam having a temperature of from 300 to 600° C. attained by heat exchange heat with a high temperature gas generated by the coal gasification. In the method, a remarkably higher efficiency and low carbon dioxide emission is attained.

Abstract: An apparatus for burning coal to produce substantially pure hydrogen for use in fuel cells, together with “sequestration ready” carbon dioxide and a stream of oxygen depleted air for powering gas turbines. The apparatus includes two fluidized bed reactors and a third transfer line reactor. The first reactor is supplied with coal particles or “char” and fluidized with high temperature steam. The second reactor is fluidized with high temperature steam and the third reactor is fluidized by compressed air. Solids circulated among these three reactors include a mixture of materials containing coal, calcium compounds (present as CaO, CaCO3 and mixtures thereof) and iron compounds (present as FeO, Fe2O3 and mixtures thereof).

Abstract: An apparatus for treating wastes includes a fluidized bed reactor for partially combusting the wastes at a relatively low temperature, and a separate relatively high temperature reactor for separate gasification of gaseous material and char from the first gasification. This synthesis gas thus formed is cooled, subjected to a conversion operation in a converter to produce hydrogen.

Abstract: An apparatus which is capable of supporting a process for gasifying a variety of hydrocarbon-containing materials. The resulting hydrogen-containing gas is suitable for use in various combustion processes and for petrochemical processes. A hydrocarbon-containing material is mixed with natural gas (or other suitable hydrocarbon gas) under pressure. The suspended material and gas are then injected under pressure into an acceleration/gasification tube. Intense heat (provided by an external energy source) is applied to the mixture as it travels through this tube, resulting in the cracking of the hydrocarbon chains and the release of additional energy. The released bond energy, along with the addition of the external energy, rapidly expands the gas and causes the velocity of the moving mixture to rise sharply as it proceeds down the tube. The acceleration/gasification tube is connected to a diffuser, which is essentially an expansion nozzle with a series of heat exchangers to cool the rapidly expanding gas.

Abstract: Facility for producing synthesis gas from a solid feedstock including organic matter, said facility including means for circulating a heat-carrying solid providing the heat necessary for such production, and several stages including gasification means (Z1, Z3), intermediate separation means (Z2, Z4) for separating the effluents coming from each stage, and combustion means (Z5).

Abstract: A method of producing a H2 rich gas stream includes supplying an O2 rich gas, steam, and fuel to an inner reforming zone of a fuel processor that includes a partial oxidation catalyst and a steam reforming catalyst or a combined partial oxidation and stream reforming catalyst. The method also includes contacting the O2 rich gas, steam, and fuel with the partial oxidation catalyst and the steam reforming catalyst or the combined partial oxidation and stream reforming catalyst in the inner reforming zone to generate a hot reformate stream. The method still further includes cooling the hot reformate stream in a cooling zone to produce a cooled reformate stream. Additionally, the method includes removing sulfur-containing compounds from the cooled reformate stream by contacting the cooled reformate stream with a sulfur removal agent.

Abstract: An apparatus which is capable of supporting a process for gasifying a variety of hydrocarbon-containing materials. The resulting hydrogen-containing gas is suitable for use in various combustion processes and for petrochemical processes. A hydrocarbon-containing material is mixed with natural gas (or other suitable hydrocarbon gas) under pressure. The suspended material and gas are then injected under pressure into an acceleration/gasification tube. Intense heat (provided by an external energy source) is applied to the mixture as it travels through this tube, resulting in the cracking of the hydrocarbon chains and the release of additional energy. The released bond energy, along with the addition of the external energy, rapidly expands the gas and causes the velocity of the moving mixture to rise sharply as it proceeds down the tube. The acceleration/gasification tube is connected to a diffuser, which is essentially an expansion nozzle with a series of heat exchangers to cool the rapidly expanding gas.

Abstract: A combined, integral steam generator coal gasifier includes a vertically elongated, all welded, gas tight enclosure with a burner zone having a double pitch sloping furnace floor and a slag tap extending therethrough. Successive zones located above the burner zone are provided with appropriate tube materials for conveying synthesis gas produced by the coal gasification process. A multi-pass convection pass zone having upflow and downflow passes is located at an upper portion of the enclosure and contains a plurality of superheater (primary and secondary) as well as economizer heating surfaces which extract heat from the synthesis gas to produce steam. An ash remover is connected to the outlet of the convection pass zone to remove ash from the synthesis gas exiting from the convection pass zone. The slag tap located at the bottom of the burner zone communicates with a slag tank or a drag chain deasher for receiving and removing slag from the burner zone.

Abstract: A catalytic gasification process and system for producing medium grade BTU gas including a gasification reactor having an inner air gasification zone, an outer steam gasification zone, a synthetic coal reaction zone, and an upper lime treating zone. The process and system of the present invention further includes a synthetic coal heating vessel which provides superheated recycled synthetic coal to the gasification reactor and a limestone treating vessel which provides superheated air and CO.sub.2 to the gasification reactor. The novel process and system of the present invention provides for the production of a medium grade BTU gas and several commercially valuable by-products with virtually no solid or liquid waste products.

Abstract: A process is disclosed for generating burnable gas by gasifying water- and ballast-containing organic materials, be it coal or garbage. The drying, low temperature carbonization and gasification steps are carried out separately. The heat taken form cooled gasified gas is supplied to the endothermic drying low temperature in low temperature carbonation stages. The low temperature carbonization gas is burned in a melting chamber furnace with air and/or oxygen or oxygen-rich flue gas and the liquid slag is evacuated, whereas the low temperature carbonization coke is blown into the hot combustion gases that leave the melting reactions which take place and give carbon monoxide and hydrogen reduce the carbon is removed from the gasified gas, supplied to the melting chamber furnace and completely burned.

Abstract: A process and system for cooling a dust-laden raw or untreated gas from the gasification of a solid carbon-containing fuel in a pressurized reactor. The gas from the reactor is introduced into a quench pipe that has a cross-sectional area that is smaller than the cross-sectional area of the reactor, and to which is supplied a quenching medium for direct cooling. The gas emerging from the outlet end of the quench pipe is deflected essentially by 180.degree. and, counter to the flow of the gas in the quench pipe, is guided through a cooling section that surrounds the quench pipe and is incorporated in a water-steam circuit.

Abstract: A catalytic gasification system for producing medium grade BTU gas including a gasification reactor having an inner air gasification zone, an outer steam gasification zone, a synthetic coal reaction zone, and an upper lime treating zone. The system of the present invention further includes a synthetic coal heating vessel which provides superheated recycled synthetic coal to the gasification reactor and a limestone treating vessel which provides superheated air and CO.sub.2 to the gasification reactor. The system of the present invention provides for the production of a medium grade BTU gas and several commercially valuable by-products with virtually no solid or liquid waste products.

Abstract: A system and method for producing product gas using residual waste liquor is described with a gasifier reactor having a fluidized bed located therein. The gasifier reactor is heated to a predetermined temperature range with either an external heater or a second fluidized bed located at a position below the first fluidized bed. A heat exchanger may be positioned in the first fluidized bed and/or the second fluidized bed for indirectly heating the respective fluidized beds. Condensing heat exchanger means recovers heat from the product gas and condenses an acid gas therefrom for recycling the chemicals. A reagent is sprayed in the condensing heat exchanger means to clean the product gas. Pressurization allows the cleaned product gas to be directly fired in a turbine.

Abstract: Heat is recovered from the hot solids discharged from the combustion chamber of a fluidized bed reactor. Hot solid particles as a result of combustion are removed either in the form of ash, or particles separated from a gas stream, and are passed into indirect heat exchange relationship with water, producing hot water. The hot water is mixed with fuel or other solid material to simultaneously heat and moisten the solid material (e.g. to a moisture content of 15-50%). The heated and moistened solid material is then fed into the combustion chamber, along with fluidizing air, to establish a fluidized bed in which combustion takes place. The heat exchange may take place in a closed heat exchange vessel, and the cooled solid particles may be discharged from the vessel through a pressure reduction valve.

Abstract: A system for providing heated fluidized bed gasification of a residual waste liquor provides a bed of granular material and a source of liquor provided to the material bed. An injector is situated in the material bed and communicates with an air source, a fuel source and a steam source. Fuel and air are combusted in the injector and mixed with the steam which forms a combustion product and steam mixture which is in turn injected into the material bed. The combustion and mixing is separated from the bed material by being confined within the injector. The injector is a bubble cap having at least one hole or an injector made of a porous ceramic material.

Abstract: Apparatus is disclosed for the allothermic gasification of coal with steam. The gasifier is vertically arranged with heat exchange tubes in separate gasification and pyrolysis zones so that a heat exchange medium is used in both zones.

Abstract: A method for generating, from refuse or refuse in combination with coal, a fuel gas suited for public utility purposes wherein refuse and coal can be introduced into the process in any proportion one to the other. The method provides the steps of subjecting the refuse to allothermal low-temperature carbonization, if desired in combination with coal, burning the gasification residue, purifying the crude gas and conditioning the pure gas for public utility purposes.

Abstract: A process is disclosed for allothermic gasification of coal under pressure with water vapor in a gas generator containing heat-exchange tubes for a heat transfer medium. The hot heat transfer medium that enters the gas generator by the heat-exchange tubes is first introduced in the gasification zone, then in the pyrolysis zone. The coal to be gasified flows counter-currently through the gas generator, so that the current of cooled heat transfer medium is used for heating and pyrolyzing the coal, whereas the heat for gasification is taken from the current of the still hot heat transfer medium. Gas generators vertically or horizontally arranged with fitting designs are used for implementation of the process.

Abstract: Resonant tubes of a pulse combustor are immersed in a bed of solid particles in a reaction zone to provide indirect heat from the pulsating combustion gases to the solid particles of the bed. The bed is maintained in an agitated state by a gas or vapor flowing through the bed. Reactant materials are introduced into the agitated bed and undergo reaction at enhanced rates resulting from heat transfer coefficients at least about twice as high as those of steady flow combustors and an intense acoustic pressure level propagated from the pulsating combustor into the reaction zone. The apparatus is useful, for example, to steam reform heavy hydrocarbons and to gasify carbonaceous material, including biomass and black liquor to produce combustible gas at relatively low temperatures, with steam being usilized as the bed fluidizing medium. Black liquor gasification, utilizing sodium carbonate as bed solids, results in liquor energy and chemical content recovery without smelt production.

Abstract: Part of the synthesis gas produced by coal gasification in an allothermically heated fluidized bed reactor is burned after removal of dust and sulfur and serves as a source of energy to heat the reactor by indirect heat exchange and to produce the steam required for the gasification process. The flue gas exiting from the heat exchanger of the reactor can be used to perform work in expansion turbines. The rest of the synthesis gas is available for use in downstream processes, such as iron ore reduction, or can be burned and used to perform work in turbines to produce electric current. The result is a process that is environmentally safer and operates with a better yield than direct coal burning or autothermal coal gasification, but requires no outside source of energy, such as nuclear power, as prior art allothermal coal gasification processes do.

Abstract: An apparatus for gasifying pulverized coal, the apparatus comprising a housing with a granulated slag discharge opening in a bottom of the housing, and a producer gas outlet opening in a lower part of the housing; a layer of thermal insulation lining the housing; a pulverized coal burner having a discharge area in the top of the housing; a layer of heat-resistant lining located above the producer gas outlet opening; a steam injection inlet; and a plurality of ducts arranged between the heat-resistant lining and the thermal insulation and extending between the steam injection inlet to the discharge area, each of the ducts having an outlet opening arranged at a level of the discharge area and an inlet opening arranged above the steam injection means. Steam is injected into the housing and the producer gas is cooled with a plurality of cooling medium supply nozzles arranged in the housing.

Abstract: An apparatus for gasifying coal dust has a housing provided with an output fitting for the removal of generator gas and an output fitting for the removal of granulated slag. An overflow maintains a body of liquid in the bottom of the housing and a coal-dust burner in the housing forms a downwardly moving coal-dust flame in an upper reaction zone of the housing. An annular tube wall in the housing upper and lower ends where its tubes are bent apart and form radially throughgoing upper and lower openings and at the burner and therebelow but above the generator-gas output fitting. This tube wall is radially gastight between its upper and lower openings and radially inwardly delimits an axially extending annular passage that is outwardly defined by the housing. Steam is fed to the upwardly directed lances in the passage to create in the housing a toroidal annular current of moving gas and steam rising in the passage and descending in the zones between the flame and the tube wall.

Abstract: An apparatus is provided for converting coal to gas, liquid and solid products. The coal is subjected to a pyrolysis reaction at a temperature of at least about 260.degree. C. in the presence of a hydrogen-containing gas, and the resultant solid residue subjected to a gasification reaction with oxygen and steam at a temperature of at least about 482.degree. C. thereby generating the necessary hydrogen-containing gas for the pyrolysis reaction and producing a solid product. Heat generated in the exothermic gasification reaction is transferred to the pyrolysis reaction, so the apparatus does not require any external source of heat except for means (88) to control the temperature of the gases passing to the pyrolysis reaction chamber. The gaseous fraction generated in the pyrolysis reaction is cooled to produce liquid and gas products, preferably after having first been subjected to a Fischer-Tropsch reaction.

Abstract: The reactor for the gasification of the fuel in a fixed bed comprises a rotary distributor, which is disposed over the fixed bed and includes at least one outlet structure for the fuel. The outlet structure consists of a tube, which is formed at its lower end with two arcuate cutouts through which the fuel flows out approximately at right angles to the direction of movement of the tube. Each cutout lies in a plane which includes an angle of about 25.degree. to 50.degree. with the horizontal. The outlet end of the tube has preferably the same elevation on the leading and trailing sides of the tube.

Abstract: A steam supply system is provided for use in conjunction with both a superposed turbine driven by a steam boiler and a process chamber. The steam boiler operates at a pressure above that needed for consumption in the process chamber and uses highly purified water. The process chamber can use steam which has been generated from relatively low purity water and may be any steam consuming process, such as in one embodiment coal gasification, not requiring that the water be returned for re-use as steam. Energy remaining in the high purity steam after it leaves the superposed turbine is used in a condensing reboiler to heat the water into steam for the process chamber. The two fluids are kept essentially isolated from contact with each other in the condensing reboiler, and the high purity water is pumped back to the high pressure boiler in a closed loop system.

Abstract: An integrated gasifying apparatus for solid municipal waste, sewage sludge and coal utilizes a fluidized-bed gasifier from which the char enters a low-temperature fluid bed combustor and then a high-temperature fluid bed combuster. CaO is admitted to the gasifier to form part of the bed and calcined lime is carried out of the high temperature combustor. The product gases are separated to recover CO.sub.2 which is recirculated to the gasifier at least in part as a fluidizing gas.

Abstract: An apparatus is provided for converting coal to gas, liquid and solid products, which comprises a single vessel including a pyrolysis chamber (20) disposed in the upper part of the vessel, and a gasification chamber (29) disposed beneath the pyrolysis chamber in the lower part of the vessel. The coal is subjected to a pyrolysis reaction at a temperature of at least about 260.degree. C. in the presence of a hydrogen-containing gas, and the resultant solid residue subjected to a gasification reaction with oxygen and steam at a temperature of at least about 482.degree. C. thereby generating the necessary hydrogen-containing gas for the pyrolysis reaction and producing a solid product. Heat generated during the exothermic gasification reaction is also transferred from the gasification chamber to the pyrolysis chamber for the endothermic reaction therein by conduction through a common dividing wall (74) interconnecting the two chambers.

Abstract: Disclosed is a reactor for gasifying coal including a vortex burner. Helical ribs are arranged in the inner combustion gas supplying conduit of the burner to impart a spiral trajectory to the gas and also the coal-water suspension which suspension is supplied in the annular space between the inner conduit and an outer concentric conduit. Means may be provided for adjustably supporting the ribs inside the inner conduit. In addition, other rib supporting arrangements and also burner structure for supplying the coal-water slurry centrally are disclosed.

Abstract: A fluidized bed gasifier (10) for gasifying a first fuel (50) receives heat indirectly from a combusting fluidized bed (24) disposed at least partially within the gasifier fluidized bed (12). Fuel for the combusting bed (24) may be provided by removing a portion of the fluidized first fuel from the gasifier bed (12) and transporting (30,34) this removed portion into the combusting bed (12). Heat is transferred across the conductive walls of the combustor vessel (26). Product gas heating value is increased by separately removing (28) the products of combustion from the gasifier (10) and by recycling a portion of the product fuel gas (74) as the fluidizing gas (54) for the gasifier fluidized bed (12). A radiation shield (18) is also provided to reduce heat loss from the gasifier bed (12) and to remove elutriated material from the product fuel gas.

Abstract: A combustible gas producer plant is described in which a finely divided inert particulate material fluidized bed is divided into a first, combustible-gas producing section and a second, heating section, to both of which sections fuel is fed. Heat transfer, by bed material migration, from the second to the first section sustains the reaction in the first section leading to the production of combustible gas. A diaphragm water wall divides and surrounds the volumes above bed sections and is part of a boiler generating steam used (optionally with added oxygen) to fluidize the first bed section. The steam is also used to fluidize the bed material at the boundary of the bed sections and prevent in-bed gas migration across that boundary. The second section of the bed is fluidized with air or an air/inert gas mixture. Fluidization is effected with sparge tubes and the plant may include evaporator, superheater and economizer sections for the boiler.

Abstract: A sulfur-containing fuel is passed into a first fluidized bed (13) containing CaSO.sub.4 and CaO and an oxygen-transfer mediator (e.g. H.sub.2) whereby the fuel is converted to combustible gas (18), some CaSO.sub.4 being reduced to CaS and sulfur being fixed as CaS by reaction with CaO. Bed particles pass from the bottom layer of the first bed (13) into the bottom layer of the second bed (14) which is fluidized by air at conditions such that some, but not all of the CaS is selectively oxidized to CaSO.sub.4 with no liberation of sulfur moieties. Bed particles pass from the bottom layer of the second bed (14) to the bottom layer of a third bed (15) optionally after passage via a fourth bed (60, FIG. 2) between the second and third beds. In the third bed (15), particles are fluidized with air to convert CaS selectively to CaSO.sub.

Abstract: Processes and apparatus for storing solar energy in synthetic fuels are disclosed. The disclosed processes include the steps of introducing steam and carbonaceous material such as coal, lignite, peat, solid organic wastes, or heavy oils into a molten gasification medium such as one or more molten salts and supplying sufficient solar heat to the gasification medium to maintain it in the molten state at a temperature at which the carbonaceous material and steam react to produce a synthesis gas product including a synthetic fuel gas or gases. Disclosed processes include the step of adding solar absorptivity enhancing dopant material to the gasification medium. Disclosed processes include the step of supplying solar heat to the gasification medium by directing concentrated solar radiation onto the gasification medium, rather than directing the solar radiation onto a separate body of material for indirectly heating the gasification medium.

Abstract: The apparatus serves to continuously charge coarse-grained and fine-grained solid fuels by means of a rotary distributor onto a fixed bed of fuel. The fixed bed is disposed within a reactor for gasifying the fuels. Gasifying agents comprising oxygen, steam and/or carbon dioxide are passed through the fixed bed from below. Residual matter left after the gasification is withdrawn under the fixed bed as solid ash or liquid slag. Fine-grained fuel having a mean particle size up to 5 mm are placed onto the fixed bed as helical layers separately form more coarsely grained fuel having a mean particle size above 5 mm. The more coarsely grained fuel is deposited directly on fine-grained fuel which has just been deposited.The gasifier comprises a rotary distributor that includes at least one passage for the fine-grained fuel and at least one passage for the more coarsely grained fuel. The inlet of the passage for fine-grained fuel is disposed near the center of the rotary distributor.

Abstract: An apparatus in which a downflowing high pressure stream of hot raw synthesis gas from the reaction zone of a free flow partial oxidation gas generator at a temperature in the range of about 1800.degree. to 3000.degree. F. is passed through a first gas diversion and residue separation chamber contained in a first pressure vessel where the velocity of the gas stream is reduced, solid material and molten slag are separated by gravity from the gas stream, and the direction is diverted into a thermally insulated side transfer line. The hot gas stream is then passed through a thermally insulated gas-solids impingement separation means contained in a second pressure vessel where its direction and velocity is changed and additional residue is separated. The hot gas stream is then passed upwardly through a radiant cooler where additional solid matter is removed by gravity and the gas temperature is reduced to a temperature in the range of about 900.degree. to 1800.degree. F.

Abstract: Disclosed is a reactor for gasifying coal including a vortex burner. Helical ribs are arranged in the inner combustion gas supplying conduit of the burner to impart a spiral trajectory to the gas and also the coal-water suspension which suspension is supplied in the annular space between the inner conduit and an outer concentric conduit. Means are provided for adjustably supporting the ribs inside the inner conduit. In addition, other rib supporting arrangements and also burner structure for supplying the coal-water slurry centrally are disclosed.

Abstract: The present invention is directed to a coal-water slurry atomizer for use a high-pressure dryer employed in a pumping system utilized to feed coal into a pressurized coal gasifier. The slurry atomizer is provided with a venturi, constant area slurry injection conduit, and a plurality of tangentially disposed steam injection ports. Superheated steam is injected into the atomizer through these ports to provide a vortical flow of the steam, which, in turn, shears slurry emerging from the slurry injection conduit. The droplets of slurry are rapidly dispersed in the dryer through the venturi where the water is vaporized from the slurry by the steam prior to deleterious heating of the coal.

Abstract: An apparatus in which the hot raw synthesis gas stream leaving the reaction zone of a free flow partial oxidation gas generator at a temperature in the range of about 1800.degree. to 3000.degree. F. is passed through a first gas diversion and residue separation zone where the velocity of the gas stream is reduced and its direction is diverted into a side transfer line. Solid material and molten slag separate by gravity from the gas stream. The hot gas stream is then introduced into a second gas diversion and residue separation zone, which comprises a plurality of high temperature resistant, thermally insulated cyclones, where the direction and velocity is changed and additional residue is separated. About 0.5 to 20 vol. % of the hot gas stream may be passed through bottom outlets in said first and second gas diversion zones in order to prevent bridging.

Abstract: An arrangement for pressure gasification of fine-grain coal in which the exit of a reactor is followed by a waste heat boiler for cooling the generated gas. The waste heat boiler has a radiation section and downstream heat exchanger surfaces. The reactor is provided, furthermore, with cooling cubes which are studded and lined with refractory ramming mix. The radiant type heating surfaces are sized so that the gas temperature at the exit of the radiation section is situated below the ash sintering temperature of the coal being used. On gas sides, the radiation section is followed by a pressure vessel accommodating convection type heating surface banks which are swept by the generated gas. The radiation section may be in the form of two gas passages through which the gas flows successively. These gas passages are formed by the tube walls welded between each other in a gas-type manner.

Abstract: A pressure container forms a shaft gasifier for receiving coarse coal in the form of a coal bed. A burner extends through the pressure container into a chamber therein and produces at least one primary gas jet directed against the coal bed, thereby gasifying the coal and generating a product gas and forming liquid slag. The liquid slag collects in a slag bath tank having an overflow weir over which the collected slag flows and falls freely toward a cooling water bath beneath the chamber. A water jet nozzle directs at least one water jet against the liquid slag as it falls freely between the weir and the cooling water bath. This atomizes the liquid slag, thereby cooling the slag and generating steam. At least a part of the steam is supplied as process steam to the coarse coal.

Abstract: Gasification of coal by hydrogenation to produce CH.sub.4 hydrocarbons, and by steam to produce hydrogen. Forming a medium-grain and a small-grain fractions from coal. Hydrogenating the volatile and readily reactive components of part of the small-grain fraction to form hydrocarbons and coke. Mixing the coke with the other part of the small-grain fraction. Forming briquets from the mixture. Mixing the briquets with medium size coal fraction and steam gasifying to produce hydrogen. The hydrogentation is preferably carried out in a fluidized bed operation and the steam gasification in a fixed-bed operation.

Abstract: Process and apparatus are disclosed for recovering liquid and gaseous fuel from solid hydrocarbon-containing mineral material such as bitumen-containing mineral materials exemplified by tar sands or oil-bearing diatomites, without expensive pretreatment to separate the hydrocarbon containing material from material containing no hydrocarbon. The hydrocarbon-containing material is agglomerated into discrete pieces that are treated on a traveling grate such as a circular traveling grate and subjected to sequential treatments in which hot gases are passed upwardly or downwardly through a relatively deep permeable bed of the pieces on the grate, in several treating zones separated by transverse gas seals and sealed at the side edges by suitable gas seals. All, or essentially all, of the heat required is obtained in a coke burn-off zone from combustion of coke that remains in the material on the grate after the volatile hydrocarbons have been removed by distillation in an earlier distillation zone.

Abstract: The hot raw synthesis gas stream leaving the reaction zone of a free flow partial oxidation gas generator at a temperature in the range of about 1800.degree. to 3000.degree. F. is passed through a first gas diversion and residue separation zone where the velocity of the gas stream is reduced and its direction is diverted into a side transfer line. Solid material and molten slag separate by gravity from the gas stream. The hot gas stream is then introduced into a second gas diversion and residue separation zone where additional residue is separated. About 0.5 to 20 vol. % of the hot gas stream may be passed through bottom outlets in said first and second gas diversion zones in order to prevent bridging. The hot gas stream from the second gas diversion zone is passed upwardly through a radiant cooler where additional solid matter is removed by gravity and the gas temperature is reduced to a temperature in the range of about 900.degree. to 1800.degree. F.

Abstract: PCT No. PCT/US79/00929 Sec. 371 Date Nov. 1, 1979 Sec. 102(e) date Nov. 1, 1979 PCT Filed Nov. 1, 1979 PCT Pub. No. WO81/01295 PCT Pub. Date May 14, 1981A rotating fluidized bed gasifier system especially useful in compound engines comprising an annular fluidization chamber containing a bed of carbon containing pulverulent solid materials. The chamber, which is defined by inner and outer spaced apart coaxial, cylindrical, perforated walls, rotates about the longitudinal axis of the cylinders. Steam enters the bed, which is maintained at about 1800.degree. F., through the outer perforated wall and fluidizes the particles. The steam reacts endothermically with the carbon to produce reaction product gas which exits the bed, together with unreacted steam, through the inner perforated wall. In a preferred form of the invention the bed is maintained at approximately 1800.degree. F. by combining a rotating fluidized bed combustor with the gasifier.

Abstract: Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials. Incident solar radiation is focused from an array of heliostats onto a tower-mounted secondary mirror which redirects the focused solar radiation down through a window onto the surface of a vertically-moving bed of coal, or a fluidized bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called "synthesis gas", which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam at the rear surface of the secondary mirror.

Abstract: A conical reaction region in a pyrolysis device has an adjustable height, adjustable speed agitator in the vicinity of the grate and a second agitator stirring the incoming material. A feed auger stops short of the reaction chamber to produce a sealing region in which the incoming feed material effectively produces a gas tight seal preventing the exit of reaction products. A gas outlet flow rate sensor controls the air inflow rate and/or lower agitator speed. Temperature and other sensors may be used to further optimize the process.

Abstract: Solid fuel is acted on by a gasifying medium in a fluidized bed W. The resulting gas enters a cyclone 20 having an outlet for solid particles connected to a gasification chamber 30 in which the particles are gasified by a separate stream of gasifying medium supplied by an injector 25.