Abstract: In a reforming reactor (31), a partial oxidation reaction is performed between a hydrocarbon fuel and air, and in a mixer (32), water is injected into hot gas heated by the partial oxidation reaction to vaporize the water, and the vaporized water is mixed with the hot gas. In a shift reactor (33), the vaporized water is made to undergo a shift reaction with the hot gas. In this way, a device for promoting vaporization of the water or a complex fuel injection device is not required.

Abstract: This invention is directed to a heat exchanged membrane reactor for electric power generation. More specifically, the invention comprises a membrane reactor system that employs catalytic or thermal steam reforming and a water gas shift reaction on one side of the membrane, and hydrogen combustion on the other side of the membrane. Heat of combustion is exchanged through the membrane to heat the hydrocarbon fuel and provide heat for the reforming reaction. In one embodiment, the hydrogen is combusted with compressed air to power a turbine to produce electricity. A carbon dioxide product stream is produced in inherently separated form and at pressure to facilitate injection of the CO2 into a well for the purpose of sequestering carbon from the earth's atmosphere.

Abstract: A chemical reactor includes a first reaction section which has a first flow path and causes a first reaction in the first flow path. A heating section heats the first reaction section. A second reaction section has a second flow path and causes a second reaction in the second flow path by heat of the heating section transmitted via the first reaction section.

Abstract: An apparatus which is capable of supporting a process for gasifying a variety of hydrocarbon-containing materials. The resulting hydrogen-containing gas is suitable for use in various combustion processes and for petrochemical processes. A hydrocarbon-containing material is mixed with natural gas (or other suitable hydrocarbon gas) under pressure. The suspended material and gas are then injected under pressure into an acceleration/gasification tube. Intense heat (provided by an external energy source) is applied to the mixture as it travels through this tube, resulting in the cracking of the hydrocarbon chains and the release of additional energy. The released bond energy, along with the addition of the external energy, rapidly expands the gas and causes the velocity of the moving mixture to rise sharply as it proceeds down the tube. The acceleration/gasification tube is connected to a diffuser, which is essentially an expansion nozzle with a series of heat exchangers to cool the rapidly expanding gas.

Abstract: A dual-chamber, aqueous-chemistry-based portable reactor for reducing water via any of numerous possible exothermic reactions to produce both heat and hydrogen gas. In one embodiment, aluminum metal is contained within a lower reaction chamber, an aqueous, sodium-hydroxide solution is contained in an upper chamber, and the aqueous, sodium-hydroxide solution is fed by gravity into the lower reaction chamber to vigorously react with the aluminum metal to produce both heat and hydrogen gas. A static feedback-control tube returns the aqueous, sodium-hydroxide solution back from the second chamber to the first chamber in the event that excessive hydrogen-gas pressure builds up in the second chamber, providing feedback-control of the rate of the reduction of water in the second chamber by a combination of gas pressure and hydrostatic pressure.

Abstract: An apparatus for carrying out a multi-step process of converting hydrocarbon fuel to a substantially pure hydrogen gas feed includes a plurality of reaction zones arranged in an insulated, box-shaped, compact fuel processor. The multi-step process includes preheating the hydrocarbon fuel utilizing integration with the inherent exothermic processes utilized with the fuel processor, reacting the preheated hydrocarbon fuel to form the hydrogen rich gas, and purifying the hydrogen rich gas to produce a gas that is suitable for consumption in a fuel cell.

Abstract: Method and apparatus for steam reforming a sulfur-containing hydrocarbon fuel, such as a diesel hydrocarbon fuel. The apparatus includes a desulphurization unit, a pre-reformer, and a steam reforming unit. A carbon dioxide fixing material is present in the steam reforming catalyst bed to fix carbon dioxide that is produced by the reforming reaction. The carbon dioxide fixing material is an alkaline earth oxide, a doped alkaline earth oxide or a mixture thereof. The fixing of carbon dioxide within the steam reforming catalyst bed creates an equilibrium shift in the steam reforming reaction to produce more hydrogen and less carbon monoxide. Carbon dioxide fixed in the catalyst bed can be released by heating the carbon dioxide fixing material or catalyst bed to a temperature in excess of the steam reforming temperature. Fuel processors having multiple catalyst beds and methods and apparatus for generating electricity utilizing such fuel processors in conjunction with a fuel cell are also disclosed.

Abstract: A method of producing a H2 rich gas stream includes supplying an O2 rich gas, steam, and fuel to an inner reforming zone of a fuel processor that includes a partial oxidation catalyst and a steam reforming catalyst or a combined partial oxidation and stream reforming catalyst. The method also includes contacting the O2 rich gas, steam, and fuel with the partial oxidation catalyst and the steam reforming catalyst or the combined partial oxidation and stream reforming catalyst in the inner reforming zone to generate a hot reformate stream. The method still further includes cooling the hot reformate stream in a cooling zone to produce a cooled reformate stream. Additionally, the method includes removing sulfur-containing compounds from the cooled reformate stream by contacting the cooled reformate stream with a sulfur removal agent.

Abstract: A hydrogen generation apparatus includes controls for delivering a feedstock to a reactor and a water gas step membrane reactor operating at a lower temperature than the reactor so as to efficiently produce purified hydrogen and manage heat within the apparatus. Catalytic combustion of feedstock in the presence of a combustible gas based on a computer controller facilitates operation. Flat plate heat exchangers in various configurations are contemplated as a reactor, water gas step membrane reactor, and purifier. Catalytic burning of feedstock in the presence of a combustible gas enhances apparatus efficiency.

Abstract: A hydrogen-rich reformate gas generator, such as a mini-CPO (catalytic partial oxidizer) (36), provides warm, dry, hydrogen-containing reformate gas to a hydrogen desulfurizer (17) which provides desulfurized reformate gas to a major reformer (14) (such as a CPO) which, after processing in a water-gas shift reactor (26) and preferential CO oxidizer (27) produces hydrogen-containing reformate in a line (31) for use, for instance, as fuel for a fuel cell power plant. The expensive prior art hydrogen blower (30) is thereby eliminated, thus reducing parasitic power losses in the power plant. The drier reformate provided by the mini-CPO to the hydrogen desulfurizer favors hydrogen sulfide adsorption on zinc oxide and helps to reduce sulfur to the parts per billion level.

Abstract: A heat exchanger (60) for a fuel processing system (10) that produces a hydrogen reformate gas. The heat exchanger (60) includes a catalyst for converting carbon monoxide to carbon dioxide. The heat exchanger (60) can be any suitable heat exchanger, such as a tube and fin type heat exchanger, that is able to cool the reformate gas and includes a suitable surface on which the catalyst can be coated. In one embodiment, the heat exchanger (60) is part of a WGS reactor assembly (48). The WGS reactor assembly (48) includes a first stage WGS adiabatic reactor (52) followed by the catalyzed heat exchanger (60) and a second stage WGS adiabatic reactor (68). Also, in one embodiment, both the first stage and the second stage WGS reactors (52, 68) are medium temperature reactors. By catalyzing the heat exchanger (60) in the WGS reactor assembly (48), the assembly (48) can be smaller than what is currently known in the art.

Abstract: A hydrogen generating apparatus having a fuel feeding part, a water feeding part for fuel reforming, an oxidant gas feeding part, a reforming catalyst body, a heating part for the reforming catalyst, a CO shifting catalyst body and a CO purification catalyst body is provided wherein the reforming catalyst body, the CO shifting catalyst body and the CO purification catalyst body are sequentially ordered from the fuel feeding part toward the downstream side, and wherein a shifting catalyst of the shifting catalyst body contains as one component at least a platinum group-type catalyst.

Abstract: The present invention relates to a method for oil gasification. In particular, the present invention relates to a method for oil gasification while reducing wastewater and costly purification systems. The method comprises providing feedstock and water to an oil gasification system; receiving flash gas from the oil gasification system at a flash gas condensing section; extracting vapor generated by the flash gas condensing section; returning water produced by the extracting step to the flash gas condensing section; outputting dry flash gas produced by the extracting step; receiving spent wash water at a syngas cooling section from a syngas washing section; and outputting washed syngas from the syngas washing section.

Abstract: A fuel gas reformer assemblage for use in a fuel cell power plant is formed from a composite plate assembly which includes spaced-apart divider plates with interposed columns of individual gas passages. The reformer assemblage is constructed from a series of repeating sub-assemblies, each of which includes a core of separate regenerator/heat exchanger gas passages. The core in each sub-assembly is sandwiched between a pair of reformer gas passage skins, which complete the sub-assembly. Adjacent reformer gas/regenerator/reformer gas passage sub-assemblies in the composite plate assembly are separated from each other by burner gas passages. The burner gas stream and the process gas stream flow in opposite directions through the assemblage. A varying heat transfer fin density population is disposed in the burner gas passage so as to control the peak burner wall temperatures encountered during operation of the assemblage. The burner wall peak temperature is preferably no greater than about 1,700° F.

Abstract: A compact endothermic catalytic reaction apparatus for converting hydrocarbon feedstock and methanol to useful gases, such as hydrogen and carbon monoxide, comprising a tubular endothermic catalytic reactor, a radiant combustion chamber and an annular convection section. Thus tubular endothermic catalytic reactor receives radiant energy from a metal fiber burner that is disposed within the radiant combustion chamber. Combustion products from the radiant chamber enter an annular convection section wherein heat is transferred by forced convection to the tubular endothermic catalytic reactor. The combination of radiant and convective heat transfer results in a compact design of high thermal efficiency.

Abstract: A fuel gas reformer assemblage for use in a fuel cell power plant is formed from a composite plate assembly which includes spaced-apart divider plates with interposed monolithic open cell sponge-like members which form gas passages. The monolithic members have a lattice of internal open cells which are both laterally and longitudinally interconnected so as to provide for a diffuse gas flow. The entire surface area of the monolithic components is wash coated with a porous alumina layer, and selected areas of the wash coat are also catalyzed. The reformer assemblage is constructed from a series of repeating sub-assemblies, each of which includes a core of separate regenerator/heat exchanger gas passages. The core in each sub-assembly is sandwiched between a pair of reformer gas passage skins, which complete the subassembly. Adjacent reformer gas/regenerator/reformer gas passage sub-assemblies in the composite plate assembly are separated from each other by burner gas passages.

Abstract: A compact endothermic reaction apparatus employing metallic reaction tubes in a close-pack arrangement using offset nozzle tubes and an air distribution plate for introducing fuel and air into a combustion chamber to produce long and thin flames thereby to avoid excessive localized heating of the reaction tubes and provide high reaction tube life expectancy. Also, excessive localized heating of the reaction tubes at the inlet ends of exhaust tubes is eliminated and provision is made for preventing buckling of individual reaction tubes that may be subjected to higher than average reaction tube temperatures.

Abstract: A reformer furnace having a cylindrical shell with an open outlet end in bottom of the shell, and a burner surrounded by a wall spaced apart the burner arranged within the shell and spaced apart from inner wall surface of the shell, thereby defining a reformer chamber between the burner wall and inner surface of the shell and a combustion chamber within the wall surrounding the burner. One or more reformer tubes, having an outer tube with a closed end and an open ended inner tube are arranged vertically within the reformer chamber, so that a hot flue gas from the burner circulates with an upward flow in the combustion chamber and a downward flow in the reformer chamber.

Abstract: A fuel gas reformer assemblage for use in a fuel cell power plant is formed from a composite plate assembly which includes spaced-apart divider plates with interposed columns of individual gas passages. The reformer assemblage is constructed from a series of repeating sub-assemblies, each of which includes a core of separate regenerator/heat exchanger gas passages. The core in each sub-assembly is sandwiched between a pair of reformer gas passage skins, which complete the sub-assembly. Adjacent reformer gas/regenerator/reformer gas passage sub-assemblies in the composite plate assembly are separated from each other by burner gas passages. The regenerator/heat exchanger gas passages and the reformer gas passages in each sub-assembly are connected by gas flow return manifolds which form a part of each sub-assembly.

Abstract: A steam reformer for converting a reactor fuel into a product gas includes a segmented catalyst bed. The steam reformer side walls have a thermal coefficient of expansion which is greater than the thermal coefficient of expansion of the catalyst. By forming low volume catalyst bed segments in the hotter portions of the catalyst bed, slumping and subsequent damage of the catalyst pellets is minimized. The catalyst bed is divided into segments whose volumes are inversely proportional to the temperatures of the various zones in the reformer. The segments are formed by utilizing sequential catalyst support assemblies which include perforated catalyst support members that are differentially spaced apart from each other by support assembly legs having varying lengths. Catalyst support assemblies with shorter length legs are used in the hotter zones of the reformer, and support assemblies with progressively longer length legs are used in the cooler zones of the reformer.

Abstract: A number of embodiments of reformers for reforming fuel for a fuel cell that includes an elongated catalyst bed with fuel to be reformed being delivered at one end of the bed and extracted from the other end of the bed. Heat is applied to a greater extent at the inlet end of the catalyst bed than the outlet end to prevent the formation of carbon monoxide in the products delivered from the outlet. In all embodiments, the catalyst bed has a spiral configuration and the fuel is heated before it is delivered to the catalyst bed. In some embodiments the same heat sources are employed for heating both the fuel and the catalyst bed.

Abstract: A hydrogen producing apparatus for producing hydrogen on an industrial scale by steam reforming reactions and separating hydrogen using a hydrogen-permeable membrane, including nested outer (14), intermediate (18) and inner (20) cylinders, a combustion burner (44) disposed toward the inner hollow chamber of the inner cylinder (20), a catalyst layer (A) in the annulus (30) between the intermediate (18) and inner (20) cylinders, hydrogen-permeable tubes (32) disposed in the catalyst layer (A-30), and sweep gas supply tubes (34) in the hydrogen-permeable tubes (32). The raw material gas is fed to the catalyst layer (A) and is converted into hydrogen at a high temperature produced by the burner (44), the produced hydrogen permeates the hydrogen-permeable tubes (32) which selectively separate and collect the hydrogen, and the permeated hydrogen flows with the sweep gas out of the apparatus through the outlet (52) for the sweep tubes (34).

Abstract: A number of embodiments of reformers for reforming fuel for a fuel cell that includes an elongated catalyst bed with fuel to be reformed being delivered at one end of the bed and extracted from the other end of the bed. Heat is applied to a greater extent at the inlet end of the catalyst bed than the outlet end to prevent the formation of carbon monoxide in the products delivered from the outlet. In all embodiments, the catalyst bed has a spiral configuration and the fuel is heated before it is delivered to the catalyst bed. In some embodiments the same heat sources are employed for heating both the fuel and the catalyst bed.

Abstract: Process, and apparatus, for the production of hydrogen and carbon monoxide in a reactor, preferably one containing a bed of a particulate solids catalyst, or catalyst and solids diluent, by contacting and reacting within the reaction zone a low molecular weight hydrocarbon feed, steam and oxygen, or a low molecular weight hydrocarbon feed and oxygen, at high temperature. An oxygen stream preheated to high temperature is fed via a nozzle inlet, or inlets, into the reactor, while the hydrocarbon and steam, or hydrocarbon, is fed via a different nozzle inlet, or inlets, into the reactor. Preferred oxygen nozzle designs are constituted of nickel-chromium-iron alloys, especially Inconel 600, and Inconel alloys of the 600 series generally. The oxygen nozzle is comprised of a tubular body with inlet, and outlets of special design, which renders the nozzle especially useful in the intensely hot oxygen environment.

Abstract: A compact endothermic reaction apparatus employing metallic reaction tubes in a close-pack arrangement using offset nozzle tubes and an air distribution plate for introducing fuel and air into a combustion chamber to produce long and thin flames thereby to avoid excessive localized heating of the reaction tubes and provide high reaction tube life expectancy. Also, excessive localized heating of the reaction tubes at the inlet ends of exhaust tubes is eliminated and provision is made for preventing buckling of individual reaction tubes that may be subjected to higher than average reaction tube temperatures.

Abstract: The integrated apparatus includes within a single vessel a plurality of components for processing fuel in a fuel cell plant. Along with the gas reformer is an air preheater for the burner and a plenum for supplying the shift converter. The shift converter is also in the vessel with upstream steam and fuel heat exchangers. The shift converter heat exchanger is also included.

Abstract: The fuel gas reformer of a fuel cell power plant is provided with burner gas flow baffles which are annular in configuration, and which are concentric with the axis of the burner tube. The annular burner gas flow baffles form annular burner gas flow passages. The reformer has a plurality of annular arrays of catalyst filled tubes disposed in concentric rings about the burner tube. Each of the adjacent catalyst tube rings is separated from the next filled tube ring by one of the annular baffles. Burner gases are deflected downwardly and outwardly by the reformer housing top piece onto the catalyst filled tube rings. The baffles prevent inward flow of the burner gases and direct the burner gases uniformly downwardly along the catalyst filled tubes. Each ring of catalyst filled tubes is thus properly heated so as to enhance reforming of the fuel gas reactant.

Abstract: Hydrogen gas is generated in a fluidized bed reactor by reacting gases namely steam and a hydrocarbon gas such as methane or natural gas in a fluidized bed of particulate catalytic material. The catalytic material is fluidized by injecting the mixture of the reacting gases at the bottom of the bed. Hydrogen generated within the bed is removed via a selectively permeable membrane that extends through the bed and through a freeboard area above the bed. The reaction is endothermic and therefore heat to maintain the bed at the desired temperature is added as required. Preferably a separator separates particulate catalytic material entrained in the gases in the freeboard area and delivers the particulate material separated from the gas back into the bed.

Abstract: Resonant tubes of a pulse combustor are immersed in a bed of solid particles in a reaction zone to provide indirect heat from the pulsating combustion gases to the solid particles of the bed. The bed is maintained in an agitated state by a gas or vapor flowing through the bed. Reactant materials are introduced into the agitated bed and undergo reaction at enhanced rates resulting from heat transfer coefficients at least about twice as high as those of steady flow combustors and an intense acoustic pressure level propagated from the pulsating combustor into the reaction zone. The apparatus is useful, for example, to steam reform heavy hydrocarbons and to gasify carbonaceous material, including biomass and black liquor to produce combustible gas at relatively low temperatures, with steam being utilized as the bed fluidizing medium. Black liquor gasification, utilizing sodium carbonate as bed solids, results in liquor energy and chemical content recovery without smelt production.

Abstract: A gas fired reformer includes a plurality of bayonet type reformers, each having a vertical outlet tube posted on a common outlet header. Three outlet header continuation members pass downwardly through the reformer shell to a ground support, at least one of these being a reformer gas outlet line.

Abstract: A seal plate within a gas fixed reformer divides an upper plenum and a lower plenum to force combustion products along the heat exchange surface of the reactors. The seal plate has a sealed horizontal central portion and a vertical perpendicular portion extending to the bottom of the shell. The entire seal plate is exposed to gas in the discharge plenum, whereby differential expansion of various seal plate portions is avoided.

Abstract: A reforming apparatus for hydrocarbon includes a first annular passage forming an outside stock gas passage filled with a catalyst. A second annular passage is arranged just inside of the first annular passage and in concentric relationship therewith to form an outside reformed gas passage. A third annular passage is arranged just inside of the second annular passage, and is connected thereto via a third communicating portion, for forming an inside reformed gas passage. A fourth annular passage is arranged just inside of the third annular passage and is connected between the first and third annular passages by first and second communicating portions, respectively, for forming an inside stock passage filled with the catalyst for reforming the stock gas. A first combustion gas passage is formed just inside of the fourth annular passage and a second combustion gas passage is formed just outside of the first annular passage, for heating the fourth and first annular passages, respectively.

Abstract: An apparatus for catalytic reaction containing a heating chamber having a hearth, side wall(s) and a roof, and an inlet and outlet for a heat source gas; a substantially vertically mounted concentric double cylindrical tubular reactor mounted in said roof and protruding into the space within said heating chamber; a gas-permeable dividing means which divides the space within the heating chamber into an upper convection heat transfer space and a lower radiant heat transfer space is useful in steam reforming and similar processes.

Abstract: A reformer assembly includes fuel introduction plates, combustion chamber plates and reforming chamber plates. The fuel introduction plate includes a first plate member and a first masking frame on the periphery of the first plate member. The combustion chamber plate includes a second plate member and a second masking frame on the periphery of the second plate member, and combustion catalyst is placed in the combustion chamber plate. The reforming chamber plate includes a third plate member and a third masking frame on the periphery of the third plate member, and reforming catalyst is placed in the reforming chamber plate. The first masking frame has a fuel feeding port. The second plate member has a number of dispersion holes and the second masking frame has air feeding and exhaust gas discharging ports. The third masking frame has raw material gas feeding and reformed gas discharging ports. These plates are stacked to define a multi-layer unit.

Abstract: Main units which includes a reforming reactor and a combustor, both piled together having a heat conductive, partition wall therebetween, are located in a manner such that the combustor sides thereof face each other, with an auxiliary unit for supplying fuel to each combustor being put between the main units. Raw material gas to be reformed is supplied to the reforming reactor through a passage formed in each unit, and then discharged through another passage formed in each unit. Fuel is supplied to the auxiliary unit through yet another passage formed in the main unit, so that it may flow uniformly dispersing in the combustor via the auxiliary unit.

Abstract: A convective reformer device is provided which is useful for partially reforming a feed mixture of hydrocarbons and steam. The device includes an outer shell enclosure and a tubular inner core assembly and is specifically adapted to support heat exchange between a heating fluid, which may be an effluent from downstream, and the hydrocarbon-steam feed mixture. The convective reformer is used in a system and process for the steam reformation of hydrocarbons, in which the partially reformed effluent from the convective reformer is further reformed in a steam reforming furnace, or an auto-thermal reformer, or a steam reforming furnace followed by an auto-thermal reformer. The fully reformed effluent from the steam reformer, or auto-thermal reformer, is directed back to the convective reformer to supply the heat of reaction for the partial reformation of the feed mixture.

Abstract: A fuel reforming apparatus includes a reaction tube for causing endothermic reaction for converting a fuel gas with hydrocarbon, steam, and the like mixed therein into a hydrogen-enriched gas using a catalyst, a combustor for generating a combustion gas for heating the reaction tube, a heat insulating layer for preventing the radiation of the combustion gas, and a combustion gas passage disposed around the reaction tube and allowing the combustion gas to flow therethrough, and a passage for air or fuel gas disposed around the fuel gas passage, a heat insulating layer being disposed around the outer peripheral surface of this passage.

Abstract: The heat required for the steam reforming reaction is generated by flameless catalytic combustion. The heat thus-generated is passed to a steam reforming reactor zone by means of heat pipes.

Abstract: A stepped support and seal plate (44) is sealed to firing tube (18) with an axially compressed seal (62). It carries sleeves (24) and is sealed thereto by gasket seals (55). A diagonal movement seal (69) seals plate (44) to the wall of pressure vessel (10). Bellows (76) has a straight portion (77) at the hot end. Insulation (14) is tapered to provide variations in heat transfer from the bellows to provide a uniform strain pattern in the bellows.

Abstract: A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

Abstract: A fuel reforming apparatus includes a reaction tube for causing endothermic reaction for converting a fuel gas with hydrocarbon, steam, and the like mixed therein into a hydrogen-enriched gas using a catalyst, a combustor for generating a combustion gas for heating the reaction tube, a heat insulating layer for preventing the radiation of the combustion gas, and a combustion gas passage disposed around the reaction tube and allowing the combustion gas to flow therethrough, and a passage for air or fuel gas disposed around the fuel gas passage, a heat insulating layer being disposed around the outer peripheral surface of this passage.

Abstract: The vessel is a fuel/steam reformer which has an annular chamber containing a catalyst bed. The annular chamber is surrounded by a heating zone and heat pipes from the heating zone extend through the interior of the catalyst bed whereby the catalyst is concurrently heated from inside and outside of the bed. A burner is positioned coaxially of the annular chamber to supply the required heat. Raw fuel is fed into a vaporizing chamber below the catalyst bed and after vaporization, rises through the catalyst bed for conversion to a hydrogen rich fuel gas. The fuel gas is collected in a chamber above the catalyst bed. The device is particularly useful for compact methanol fuel cell power plants.

Abstract: An apparatus for an endothermic reaction of a gas such as steam reforming having a cylindrical vessel which is provided therein a fuel gas supply room, a combustion catalyst holding wall, a flue gas passage room, and a reaction room, all of which are cylindrical or annular and coaxially piled in this order, the catalyst holding wall having a combustion catalyst holding layer on a flue gas passage room side thereof and the reaction room having a product gas passage; whereby a mixture of a fuel gas and an oxygen containing gas passes through the catalyst holding wall from the supply room into the flue gas passage room, being burnt by the catalyst to become a flue gas and to generate combustion heat, and the flue gas is discharged while the heat is given to the reaction room mainly by radiation from the catalyst layer; a raw material gas passes through the reaction room reacting endothermically to become a product gas, which is discharged through the product gas passage in countercurrent heat exchange arrangemen

Abstract: The present invention relates to a reformer for producing a hydrogen rich gas by reaction of natural gas with steam by a catalytic action with heating, and particularly to the heater in the reformer, where the heating section of the heater is composed of a heating section by burner combustion and a heating section by catalytic combustion, and a stable combustion less susceptible to fluctuations in the feed rate or pressure of fuel or air can be obtained by the catalytic combustion.

Abstract: Improved heat utilization is achieved in a process for the catalytic steam reforming of hydrocarbons to form a product stream rich in hydrogen by (a) first passing the process gas through a first portion of catalyst comprising 25-75% of the total steam reforming catalyst (whereby the heat needed for the endothermic reactions during reforming and for heating the process gas is supplied partly from a moderately hot flue gas generated by combustion of a fluid fuel and partly from the product stream) and then (b) passing the partly reformed process gas through the remaining portion of the reforming catalyst. In this second step, the heat needed for the further endothermic reactions and for heating the process gas is supplied by a hot flue gas, the hot flue gas thereby being cooled to form the moderately hot flue gas mentioned unde (a). A reactor for use in this process is also described.

Abstract: The reformer is designed for use with a large fuel cell power plant capable of producing megawatts of power, as, for example, would be used by a public utility. The catalyst tubes in the reformer have their upper ends at staggered elevations so as to be capable of having their temperatures individually monitored by infrared temperature sensors. The catalyst tubes are mounted on a floating support within the reformer housing so as to be free to undergo expansion and contraction during periods of internal temperature variation as the reformer is operated. The floating support is preferably formed from fuel manifolds suspended in the reformer housing. Baffles are included in the reformer housing for evenly distributing heat to the catalyst tube arrays. The reformer has a long burner tube which is approximately the same length as the catalyst tubes.

Abstract: An apparatus for making hydrogen from a hydrocarbon feedstock and steam using heat stored in a vessel followed by the regeneration of the vessel to restore the heat. Regeneration is done by preheating within the vessel a hydrogen purge gas and steam. Downstream of the conventional reform catalyst, the preheated gases are mixed with an oxygen containing gas so that they combust within the vessel in a fuel lean mode and heat material disposed in the vessel. This is the heat which is used in converting the hydrogen feedstock to hydrogen. The addition of steam in the regeneration process to recover the heat remaining in the vessel following the hydrogen make cycle simplifies reactor bed design and improves operational flexibility. Incorporation of a regeneratable sulfur absorber in the vessel facilitates the removal of up to 90% of the feedstock sulfur.

Abstract: An apparatus for conducting an endothermic catalytic reaction wherein closed ended, i.e., double pass, externally heated reformer tubes are employed. The inner return tube are insulated so that there is only a small temperature drop between the reacted gas leaving the catalyst zone and entering the return tubes and the gas leaving the return tubes. The outer, closed end, tubes preferably have fins to increase the surface area, and are surrounded by sheaths through which a heating medium passes. The heating medium is preferably hot gas obtained by subjecting the primary reformed gas to secondary reforming.

Abstract: A hydrocarbon converter furnace has an upper convection heating zone and a lower radiant heating zone, and tubing extends in those zones to convey a fluid hydrocarbon feed and steam in sequence through the convection and radiant heating zones. The tubing includes a feed section and branches therefrom in the radiant section of the furnace, the feed section and branches arranged so that the hydrocarbon and steam flow from the feed section to said branches; also provided is valving for controlling the relative rates of flow in the branches to reduce differential coking in the branches.

Abstract: The device catalytically reforms a raw hydrocarbon fuel to a hydrogen rich gas for fueling a fuel cell stack. The device is compact so as to be usable in mobile or temporary applications, such as in vehicles, trailors, as an emergency generator or the like. The device has generally cylindrical housing with an axial burner and a helical catalyst tube outside of the burner and inside of the housing. A refractory heat shield sleeve is interposed between the burner and the helical tube so that heat from the burner progresses to one end of the housing and then passes between the heat shield and housing side wall to envelop the catalyst tube. A gas deflector and swirler may be disposed at the end of the heat shield to properly direct the hot gases from the burner to the catalyst tube. Raw fuel is percolated through the catalyst tube and converted therein to a hydrogen rich gaseous fuel.