Coal And Water Patents (Class 48/99)
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Patent number: 8992640Abstract: The disclosed embodiments include systems for using an expander. In a first embodiment, a system includes a flow path and a gasification section disposed along the flow path. The gasification section is configured to convert a feedstock into a syngas. The system also includes a scrubber disposed directly downstream of the gasification section and configured to filter the syngas. The system also includes a first expander disposed along the flow path directly downstream from the scrubber and configured to expand the syngas. The syngas comprises an untreated syngas.Type: GrantFiled: February 7, 2011Date of Patent: March 31, 2015Assignee: General Electric CompanyInventors: Khodaram Rustom Khosravian, Ronald Frederick Tyree, Patrick Joseph McKenna
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Patent number: 8845770Abstract: A gasification system including a gasifier, a feed injector, and a fuel feed system that includes a first feed line, a second feed line, and a controller that includes a processor. The processor is programmed to enable the first feed line to supply a fuel gas into the feed injector, enable the second feed line to supply oxygen into the feed injector, receive instructions to add a slurry to the gasifier, prevent the first feed line from supplying the fuel gas into the feed injector, enable the first feed line to supply the slurry into the feed injector, enable the second feed line to simultaneously supply the oxygen and the inert gas into the feed injector, and prevent the second feed line from supplying the inert gas into the feed injector.Type: GrantFiled: August 25, 2011Date of Patent: September 30, 2014Assignee: General Electric CompanyInventors: Ronald Frederick Tyree, Huan Van Ho
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Publication number: 20140259924Abstract: Methods and systems for gasifier system are provided. The system includes a two-stage particulate separator having a side draw-off connector configured as a first virtual impactor, the first virtual impactor configured to separate a substantially particulate free flow of a reaction product from a particulate laden flow of the reaction product. The two-stage particulate separator also includes a transfer line coupled downstream of said draw-off connector, a second virtual impactor coupled downstream of the transfer line, and a quench chamber coupled downstream from the second virtual impactor, such that the quench chamber is configured to receive at least the particulate laden flow of the reaction product.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: GENERAL ELECTRIC COMPANYInventor: Thomas Frederick Leininger
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Publication number: 20140223908Abstract: A system and method of integrated waste management having a source of a combustible waste material, a separator for separating the combustible waste material from a recyclable material, an airless drier for drying the combustible waste material to generate a pyrolysis feedstock, and a pyrolyser for pyrolysing the pyrolysis feedstock to form char and pyrogas. The system and method for power generation may also use an oxidiser for the high-temperature oxidation of syngas generated from the pyrolysis feedstock to generate heat for power production.Type: ApplicationFiled: April 22, 2014Publication date: August 14, 2014Inventor: John Gerard Sweeney
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Publication number: 20140223822Abstract: A method and system for producing synthesis gas comprising CO, CO2, and H2 from a carbonaceous stream using an oxygen containing stream. A stream containing a carbonaceous material, and a stream containing oxygen are injected into a gasification reactor, where the carbonaceous stream is partially oxidised to obtain a raw synthesis gas. The raw synthesis gas is removed from the gasification reactor and directed into a quenching section wherein a liquid, preferably water, is injected in the form of a mist.Type: ApplicationFiled: February 4, 2014Publication date: August 14, 2014Applicant: Shell Oil CompanyInventors: Robert Erwin VAN DEN BERG, Franciscus Gerardus VAN DONGEN, Thomas Paul VON KOSSAK-GLOWCZEWSKI, Hendrik Jan VAN DER PLOEG, Pieter Lammert ZUIDEVELD
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Publication number: 20140223823Abstract: A process and a reactor for the of a carbonaceous feed. The reactor has a reactor chamber; steam generating heat exchange units; at least one steam drum; and recirculation lines for circulating water and steam between one or more of the heat exchange units and the steam drum. The steam drum further includes a steam feed line for transporting steam via a heat exchange unit and a superheated steam line to a superheated steam header. The superheated steam line is split into a return line leading to a heat exchange line through the steam drum, and a header feed line.Type: ApplicationFiled: September 19, 2012Publication date: August 14, 2014Inventors: Ibrahim Kar, Manfred Schmitz-Goeb
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Publication number: 20140208649Abstract: Disclosed embodiments include a feedstock preparation system that includes a first slurry preparation system that may receive a first portion of a solid fuel to generate a first fuel slurry using the first portion of the solid fuel and a liquid and second slurry preparation system separate from the first slurry preparation system that may receive a second portion of the solid fuel and the first fuel slurry. The second slurry preparation system may produce a second fuel slurry using the second portion of the solid fuel and the first fuel slurry. The first fuel slurry has a first particle size distribution and the second fuel slurry has a second particle size distribution, and the first and second particle size distributions are different.Type: ApplicationFiled: January 31, 2013Publication date: July 31, 2014Applicant: GENERAL ELECTRIC COMPANYInventors: Raul Eduardo Ayala, Judith Pauline Oppenheim
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Publication number: 20140093447Abstract: Disclosed is an apparatus and method for capturing the hot humid gases from a gypsum board dryer and utilizing those gases in the production of a synthetic gas (referred to as “syngas”). The syngas produced can then be utilized within a gypsum board plant to reduce the amount of natural gas needed. The method utilizes the heated water vapor (H2O) and carbon dioxide (CO2) found within the flue gas of a board dryer. The H2O and CO2 are used in a gasification process to yield the syngas.Type: ApplicationFiled: September 30, 2013Publication date: April 3, 2014Inventor: John W. College
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Patent number: 8551213Abstract: A system of coal gasification and direct ironmaking attains both heat recovery in a coal-based direct ironmaking process and a reduction in equipment investment in a coal gasification process. A waste heat boiler in the system recovers heat of gas exhausted from a coal gasification furnace. A heater in exhaust gas lines of a heat reduction furnace in the coal-based direct ironmaking process superheats the steam generated by and exhausted from the waste heat boiler. A superheated steam line supplies the steam superheated by the heater as an oxidant to the coal gasification furnace.Type: GrantFiled: September 25, 2009Date of Patent: October 8, 2013Assignee: Kobe Steel, Ltd.Inventors: Masataka Tateishi, Masahiro Motoyuki
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Publication number: 20130247465Abstract: A hydrocarbon feedstock gasifier (gasifier) is provided with: a heat transmission surface disposed within a gasification region of a gasifier configured from a pressure vessel for generating produced gas by partially oxidizing coal which is a hydrocarbon feedstock; a heat exchanger disposed on the path of a circulation line for a circulation medium circulating within the heat transmission surface and for exchanging the heat of the circulation medium; and a circulation pump for circulating the circulation medium.Type: ApplicationFiled: January 24, 2012Publication date: September 26, 2013Inventors: Yoshinori Koyama, Takao Hashimoto, Katsuhiro Ota, Hiromi Ishii, Shozo Kaneko
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Patent number: 8506672Abstract: A system of coal gasification and direct ironmaking attains both heat recovery in a coal-based direct ironmaking process and a reduction in equipment investment in a coal gasification process. A waste heat boiler in the system recovers heat of gas exhausted from a coal gasification furnace. A heater in exhaust gas lines of a heat reduction furnace in the coal-based direct ironmaking process superheats the steam generated by and exhausted from the waste heat boiler. A superheated steam line supplies the steam superheated by the heater as an oxidant to the coal gasification furnace.Type: GrantFiled: September 25, 2009Date of Patent: August 13, 2013Assignee: Kobe Steel, Ltd.Inventors: Masataka Tateishi, Masahiro Motoyuki
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Patent number: 8298306Abstract: The invention provides a process that comminutes fuel solids in a steam-driven shear field, with controlled water content and catalyst, with gasification of the particles entrained in the vented steam. Unlike conventional gasification methods the invention requires no dioxygen to be present, and produces dry friable ash that has significant marketable value as a material in its own right.Type: GrantFiled: February 10, 2009Date of Patent: October 30, 2012Inventor: David Walker Taylor
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Publication number: 20110314736Abstract: The invention relates to a treatment chain for thermochemically converting a wet biomass feed (1) by gasification, which comprises a device (4) for gasifying the feed (3), and a reactor (9) for steam conversion of the CO, which includes water supply means (10), for delivering a syngas (17) having a defined H2/CO ratio, a drying chamber (2) into which the wet feed (1) is injected prior to its subsequent treatment in the gasification device (4), this drying chamber (2) being supplied with a hot gas (15) withdrawn downstream from the gasification device (4) and recycled by pressurizing means (13) into the drying chamber (2).Type: ApplicationFiled: December 23, 2008Publication date: December 29, 2011Applicant: Total Raffinage MarketingInventor: Pierre Crespin
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Patent number: 7789920Abstract: A reactor, system and method for producing hydrogen features a reactor containing a heating stream channel and a hydrogen channel with a reaction channel positioned there between. A heat transfer sheet separates the heating stream channel and the reaction channel and a porous support plate separates the reaction channel and the hydrogen channel. A membrane constructed from palladium, vanadium, copper or alloys thereof covers the porous support plate. The heating stream channel receives a heating stream so that heat is provided to the reaction channel through the heat transfer sheet. A catalyst is positioned in the reaction channel and the reaction channel receives a reaction stream including a mixture of supercritical water and a hydrocarbon fuel so that hydrogen is produced in the reaction channel and is passed through the membrane into the hydrogen channel.Type: GrantFiled: April 9, 2007Date of Patent: September 7, 2010Assignee: Chart Industries, Inc.Inventors: Zhijun Jia, Lawrence A. Stryker, Douglas Decker
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Patent number: 7638070Abstract: Methods and apparatus may permit the generation of consistent output synthesis gas from highly variable input feedstock solids carbonaceous materials. A stoichiometric objectivistic chemic environment may be established to stoichiometrically control carbon content in a solid carbonaceous materials gasifier system. Processing of carbonaceous materials may include dominative pyrolytic decomposition and multiple coil carbonaceous reformation. Dynamically adjustable process determinative parameters may be utilized to refine processing, including process utilization of negatively electrostatically enhanced water species, process utilization of flue gas (9), and adjustment of process flow rate characteristics. Recycling may be employed for internal reuse of process materials, including recycled negatively electrostatically enhanced water species, recycled flue gas (9), and recycled contaminants.Type: GrantFiled: October 6, 2008Date of Patent: December 29, 2009Assignee: Thermo Technologies, LLCInventors: Dennis E. J. Johnson, Grigori A. Abramov, Richard A. Kleinke, Marcus A. Wiley
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Publication number: 20090249691Abstract: Apparatus for gasifying a solid fuel that supplies a solid fuel such as coal by dry condition to a gasification furnace of an entrained-bed type is constructed so as to be able to collect the char discharged from the gasification furnace and re-supply the char to the furnace without using a lock hopper and without changing the char into slurry form. The char discharged from the gasification furnace along with produced gases 53 produced in the gasification furnace is brought into contact with water by a gas cooler 9 and collected. After being dehydrated by a dehydrator 10, the collected char is loaded into a mill 2 or a raw-coal bunker 1. For loading into the raw-coal bunker 1, the char is dried by a drying machine 14, preferably, after the dehydration. According to the present invention, a mixture of the collected char and water can be re-supplied to the gasification furnace without using a lock hopper or a dry feeder.Type: ApplicationFiled: February 1, 2006Publication date: October 8, 2009Applicants: HITACHI, LTD., ELECTRIC POWER DEVELOPMENT CO., LTD., BARCOCK-HITACHI K.K.Inventors: Toru Akiyama, Fumihiko Kiso, Shinji Tanaka, Hirofumi Okazaki, Fumihiko Hanayama, Kazunori Sato, Takahiro Nishida, Hiroshi Takezaki, Akio Ueda, Makoto Takeda
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Patent number: 6997965Abstract: A method of the gasification of coal using oxygen and steam is provided wherein the coal is gasified at a temperature of from 1000 to 2500° C. and a pressure of from 1 to 100 kg/cm2 using oxygen generated by electrolyzing water and steam having a temperature of from 300 to 600° C. attained by heat exchange heat with a high temperature gas generated by the coal gasification. In the method, a remarkably higher efficiency and low carbon dioxide emission is attained.Type: GrantFiled: May 8, 2001Date of Patent: February 14, 2006Assignees: Toyo Engineering Corporation, The Institute of Applied EnergyInventor: Yukuo Katayama
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Apparatus for converting coal into fuel cell quality hydrogen and sequestration-ready carbon dioxide
Patent number: 6911057Abstract: An apparatus for burning coal to produce substantially pure hydrogen for use in fuel cells, together with “sequestration ready” carbon dioxide and a stream of oxygen depleted air for powering gas turbines. The apparatus includes two fluidized bed reactors and a third transfer line reactor. The first reactor is supplied with coal particles or “char” and fluidized with high temperature steam. The second reactor is fluidized with high temperature steam and the third reactor is fluidized by compressed air. Solids circulated among these three reactors include a mixture of materials containing coal, calcium compounds (present as CaO, CaCO3 and mixtures thereof) and iron compounds (present as FeO, Fe2O3 and mixtures thereof).Type: GrantFiled: September 30, 2003Date of Patent: June 28, 2005Assignee: General Electric CompanyInventor: Richard K. Lyon -
Patent number: 6827751Abstract: An apparatus which is capable of supporting a process for gasifying a variety of hydrocarbon-containing materials. The resulting hydrogen-containing gas is suitable for use in various combustion processes and for petrochemical processes. A hydrocarbon-containing material is mixed with natural gas (or other suitable hydrocarbon gas) under pressure. The suspended material and gas are then injected under pressure into an acceleration/gasification tube. Intense heat (provided by an external energy source) is applied to the mixture as it travels through this tube, resulting in the cracking of the hydrocarbon chains and the release of additional energy. The released bond energy, along with the addition of the external energy, rapidly expands the gas and causes the velocity of the moving mixture to rise sharply as it proceeds down the tube. The acceleration/gasification tube is connected to a diffuser, which is essentially an expansion nozzle with a series of heat exchangers to cool the rapidly expanding gas.Type: GrantFiled: October 28, 2003Date of Patent: December 7, 2004Inventors: Thomas W. Kaufman, Verner Christensen
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Publication number: 20040163311Abstract: A method of producing a H2 rich gas stream includes supplying an O2 rich gas, steam, and fuel to an inner reforming zone of a fuel processor that includes a partial oxidation catalyst and a steam reforming catalyst or a combined partial oxidation and stream reforming catalyst. The method also includes contacting the O2 rich gas, steam, and fuel with the partial oxidation catalyst and the steam reforming catalyst or the combined partial oxidation and stream reforming catalyst in the inner reforming zone to generate a hot reformate stream. The method still further includes cooling the hot reformate stream in a cooling zone to produce a cooled reformate stream. Additionally, the method includes removing sulfur-containing compounds from the cooled reformate stream by contacting the cooled reformate stream with a sulfur removal agent.Type: ApplicationFiled: February 27, 2004Publication date: August 26, 2004Inventors: Shabbir Ahmed, Sheldon H. D. Lee, John David Carter, Michael Krumpelt, Deborah J. Myers
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Publication number: 20030106266Abstract: A method and apparatus for conversion of solid and liquid fuels to a synthesis gas, steam and/or electricity in which about 10% to about 40% of a solid fuel and/or a liquid fuel is introduced into a gasifier and gasified, resulting in formation of a synthesis gas. The remaining portion of the solid fuel and/or liquid fuel is introduced into a first stage of a multi-stage combustor, resulting in formation of products of combustion and ash and/or char. The synthesis gas is introduced into a second stage of the multi-stage combustor disposed downstream of the first stage and overfire oxidant is introduced into a third stage of the multi-stage combustor disposed downstream of the second stage. The ash and/or char from the multi-stage combustor is then recycled into the gasifier.Type: ApplicationFiled: December 10, 2001Publication date: June 12, 2003Inventors: Bruce Bryan, Iosif Rabovitser
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Patent number: 5855631Abstract: A catalytic gasification process and system for producing medium grade BTU gas including a gasification reactor having an inner air gasification zone, an outer steam gasification zone, a synthetic coal reaction zone, and an upper lime treating zone. The process and system of the present invention further includes a synthetic coal heating vessel which provides superheated recycled synthetic coal to the gasification reactor and a limestone treating vessel which provides superheated air and CO.sub.2 to the gasification reactor. The novel process and system of the present invention provides for the production of a medium grade BTU gas and several commercially valuable by-products with virtually no solid or liquid waste products.Type: GrantFiled: May 6, 1997Date of Patent: January 5, 1999Inventor: Arnold M. Leas
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Patent number: 5776212Abstract: A catalytic gasification system for producing medium grade BTU gas including a gasification reactor having an inner air gasification zone, an outer steam gasification zone, a synthetic coal reaction zone, and an upper lime treating zone. The system of the present invention further includes a synthetic coal heating vessel which provides superheated recycled synthetic coal to the gasification reactor and a limestone treating vessel which provides superheated air and CO.sub.2 to the gasification reactor. The system of the present invention provides for the production of a medium grade BTU gas and several commercially valuable by-products with virtually no solid or liquid waste products.Type: GrantFiled: September 13, 1996Date of Patent: July 7, 1998Inventor: Arnold M. Leas
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Patent number: 5439491Abstract: Apparatus is disclosed for the allothermic gasification of coal with steam. The gasifier is horizontally arranged with heat exchange tubes in separate gasification and pyrolysis zones so that a heat exchange medium is used in both zones.Type: GrantFiled: April 21, 1994Date of Patent: August 8, 1995Assignee: Bergwerksverband GmbHInventors: Helmut Kubiak, Hans J. Schroter, Gunther Gappa, Heinrich Kalwitzki, Klaus Knop
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Patent number: 5370715Abstract: Organic wastes of diverse types including toxic materials are converted to synthesis gas or molecular hydrogen or methanol and an inorganic solid residue by heating the material to 1200 .degree. C. or higher in the presence of steam in a chemically reducing atmosphere. The gassified wastes travel along a vertical flow path in a sealed reactor vessel. Heat is applied by vertically extending recuprative heaters situated at both lower and upper regions along the flow path to provide a high temperature zone of sufficient length to thermally decompose the wastes during a single passage along the path. Steam may be provided by intermixing liquid water, which may be dirty and/or contaminated, into the wastes prior to entry of the wastes into the reaction chamber thereby avoiding any need for an external boiler and pure water. The apparatus realizes a very high throughput and does not release any pollutants into the air, ground or water.Type: GrantFiled: April 27, 1993Date of Patent: December 6, 1994Inventors: Robert N. Kortzeborn, William D. Gwinn
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Patent number: 4756722Abstract: Part of the synthesis gas produced by coal gasification in an allothermically heated fluidized bed reactor is burned after removal of dust and sulfur and serves as a source of energy to heat the reactor by indirect heat exchange and to produce the steam required for the gasification process. The flue gas exiting from the heat exchanger of the reactor can be used to perform work in expansion turbines. The rest of the synthesis gas is available for use in downstream processes, such as iron ore reduction, or can be burned and used to perform work in turbines to produce electric current. The result is a process that is environmentally safer and operates with a better yield than direct coal burning or autothermal coal gasification, but requires no outside source of energy, such as nuclear power, as prior art allothermal coal gasification processes do.Type: GrantFiled: March 10, 1987Date of Patent: July 12, 1988Assignee: M.A.N. GHHInventors: Klaus Knop, Gunter Wolters, Helmut Kubiak
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Patent number: 4448588Abstract: An integrated apparatus for the gasification of coal alone or with other carbon-containing materials such as solid municipal wastes, biomass and sewage sludges, wherein the endothermic heat required by the gasification reaction is supplied at least in a significant part by the exothermic reaction of CaO in the form of calcined lime or dolomite with carbon dioxide. The CO.sub.2 is recycled to provide a high CO.sub.2 vapor pressure for the exothermic reaction. The calcium carbonate formed in the reaction is decomposed in a combustor to produce the CaO which is recycled to the gasification stage.Type: GrantFiled: April 20, 1982Date of Patent: May 15, 1984Inventor: Shang-I Cheng
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Patent number: 4304574Abstract: The retort chamber for generating gas by applying hot steam to coal in a fluidized bed is heated by meandering tubes, dipping into the bed, and being suspended from long, hollow boxes which, in turn, are particularly suspended in the retort chamber. The boxes support also manifold tubes connected to the heating tubes and being further connected to a heating fluid feed and distribution as well as a collecting and discharge system.Type: GrantFiled: March 17, 1980Date of Patent: December 8, 1981Assignees: Mannesmannrohren-Werke AG, Bergwerksverband GmbHInventors: Guenter Buchner, Johannes Alkemper, Rainer Durrfeld, Heinz Gaessler
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Patent number: 4290779Abstract: A solar-powered fluidized bed gasification system for gasifying carbonaceous material. The system includes a solar gasifier (10) which is heated by fluidizing gas and steam. Energy to heat the gas and steam is supplied by a high heat capacity refractory honeycomb (16) which surrounds the fluid bed reactor zone (14). The high heat capacity refractory honeycomb (16) is heated by solar energy focused on the honeycomb (16) by solar concentrator (32) through solar window (20). The fluid bed reaction zone (14) is also heated directly and uniformly by thermal contact of the high heat capacity ceramic honeycomb (16) with the walls of the fluidized bed reactor (12).Provisions are also made for recovering and recycling catalysts used in the gasification process. Back-up furnace (50) is provided for start-up procedures and for supplying heat to the fluid bed reaction zone (14) when adequate supplies of solar energy are not available.Type: GrantFiled: May 15, 1980Date of Patent: September 22, 1981Inventors: Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch, Shaik A. Qader
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Patent number: 4212652Abstract: Apparatus and system for producing high pressure gas, such as high pressure coal gas from coal, air and water. Pulverized coal is introduced into a rising stream of steam in a central reaction column of a retort to constitute a fluidized or entrained bed. The coal reacts with the steam to form a gas consisting of hydrogen, carbon monoxide, carbon dioxide, nitrogen, methane and higher hydrocarbons. The retort is constructed so that product gas and air may be burned in an annular chamber surrounding the central reaction column to produce hot flue gas. The hot flue gas is used to drive a turbine which in turn, drives a compressor which introduces compressed air into the annular chamber. Steam tubes may be disposed in the annular space so that the steam introduced to the central reaction chamber may be super-heated by the hot flue gas.Type: GrantFiled: April 5, 1978Date of Patent: July 15, 1980Inventor: Anthony A. duPont
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Patent number: 4203731Abstract: A gas making retort includes a substantially upright mixing chamber opening into a first horizontal refractory cylinder which encloses a second horizontal refractory cylinder. The second cylinder encloses two centrally positioned refractory circular gas out take tubes directly opposite to each other. Each of the cylinders has a cylindrical passageway for the introduction of a mixture of air, steam and a carbonaceous material from the mixing chamber into a gas making space defined between the internal ends of the gas out take tubes wherein a partial combustion of the mixture takes place.Type: GrantFiled: December 15, 1977Date of Patent: May 20, 1980Inventors: Wayne Bailey, Robert Kemp
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Patent number: 4153427Abstract: This invention is directed to a system for feeding coal into a gasifier operating at high pressures. A coal-water slurry is pumped to the desired pressure and then the coal is "dried" prior to feeding the coal into the gasifier by contacting the slurry with superheated steam in an entrained bed dryer for vaporizing the water in the slurry.Type: GrantFiled: February 23, 1978Date of Patent: May 8, 1979Assignee: The United States of America as represented by the United States Department of EnergyInventors: Larry A. Bissett, Gary R. Friggens, James P. McGee
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Patent number: 4137052Abstract: Apparatus and system for producing coal gas from coal, air and water. Pulverized coal is introduced into a rising stream of air and steam in a retort to constitute a fluidized or entrained bed. The coal reacts with the steam and air to form a gas consisting of hydrogen, carbon monoxide, carbon dioxide, nitrogen, methane and higher hydrocarbons. In some cases the air may be eliminated to produce nitrogen-free gas. In other instances, the production of methane and higher hydrocarbons may be suppressed to produce a gas consisting primarily of hydrogen and carbon monoxide. The retort is constructed so that product gas and air may be burned in an annular space surrounding the central reaction column to produce hot flue gas. Steam tubes may be disposed in the annular space so that the steam and air introduced to the central reaction chamber may be super-heated by the hot flue gas.Type: GrantFiled: August 17, 1977Date of Patent: January 30, 1979Inventors: Anthony A. du Pont, Joseph A. Connell
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Patent number: 4135885Abstract: A chemical reactor with a first upstream fluid bed which primarily burns coal and a second downstream fluid bed which primarily desulfurizes.Type: GrantFiled: January 3, 1977Date of Patent: January 23, 1979Assignee: Wormser Engineering, Inc.Inventors: Alex F. Wormser, Stephen P. Perkins
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Patent number: 4101295Abstract: Apparatus for converting coal into a gas substitute in which a slurry mix of pulverized coal and water is heated to form an emulsion which is then successively passed through a catalytic chamber and a convertor chamber.The catalyzed emulsion mix is heated to destructive distillation temperatures in the convertor chamber as superheated steam is introduced into the convertor chamber to effect a continuous destructive distillation process. The products of destructive distillation are then successively scrubbed, condensed and passed through separators to separate the solids and free hydrogen from the gaseous constituents with a portion of the distillation products not comprising the final natural gas substitutes being recycled to the burner as fuel to generate the heating temperatures necessary to perform the method. The condensed water is also recycled to form the slurry or the steam introduced into the convertor.Type: GrantFiled: August 16, 1976Date of Patent: July 18, 1978Inventor: John H. Sadler
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Patent number: 4080181Abstract: A gas generator is provided for the production of gas from fuel and steam under conditions of high pressure and temperature. The requisite temperature is preferably provided by a nuclear reactor. The gas generator includes a cylinder wth a hollow interior. Extending transversely through the hollow interior of the cylinder is a container. Tubular heat exchangers are vertically arranged over the length, width and height of the cylinder in such a manner that the density of heating surfaces decreases along the length of the container.Type: GrantFiled: November 8, 1976Date of Patent: March 21, 1978Assignee: Bergwerksverband GmbHInventors: Paul Peter Feistel, Karl Heinrich Van Heek, Harald Juntgen, Rainer Durrfeld
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Patent number: 4062656Abstract: A fluidized bed apparatus having an outer vessel provided at a lower region with a plenum chamber as well as a grid situated directly above the plenum chamber and carrying a plurality of nozzles through which gas flows from the plenum chamber into the space in the vessel above the grid. These nozzles provide a given pressure drop in the gas flowing therethrough while as the gas flows from the plenum chamber through each nozzle there is also provided by way of a suitable structure a preliminary pressure drop, so that a two-stage pressure drop is provided in the gas flowing through each nozzle from the plenum chamber into the vessel above the grid. In this way it is possible to achieve a flow of gas above the grid sufficient to maintain the particles suspended in the fluidized bed while attrition of the particles is maintained at a minimum so that very little if any fines flow out of the vessel with gas which is formed therein.Type: GrantFiled: May 12, 1976Date of Patent: December 13, 1977Assignee: Exxon Research and Engineering CompanyInventors: Don E. Blaser, Arthur C. Worley
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Patent number: 4032305Abstract: The relatively small degree of backmixing of gas in a well-arranged fast fluidized bed is exploited to introduce heat into a fluidized bed reaction system wherein a fluidized bed treatment zone receiving heat and for the purpose of conducting an endothermic treatment of matter can have a gas atmosphere, such as relatively pure steam, that is maintained independently of and without admixture by any gas or gases that are associated with a step for introducing the heat. The treatment advantageously constitutes a treatment of a carbonaceous matter, such as coal or petroleum or municipal solid waste, with hot steam for purpose of gasifying or carbonizing or cracking the matter. The arrangement is also useful for a broad range of endothermic chemical or physical treatment of matter at high temperature.Type: GrantFiled: October 7, 1974Date of Patent: June 28, 1977Inventor: Arthur M. Squires
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Patent number: 4029481Abstract: A self powered blue water gas generator includes a sealed retort forming a vertical column and having an input air lock coupled to receive carbonaceous material and a lower output air lock. The column includes a grate positioned within the column and disposed to receive impinging carbonaceous material passed through the input air lock. The grate and column are heated through conduction by burners communicating with the interior of the column and positioned outside and below the column to establish a vertical temperature gradient therewithin. Blue water gas produced within the column by carbonaceous material refluxing within the column fuels the burners and is extracted for utilization by a pipe communicating with the interior of the column. A steam pipe is positioned beneath the grate and within the column for producing steam beneath the grate.After initial fire up the generator is self-powered by its own product and produces blue water gas having an increased CO yield with decreased CO.sub.2 production.Type: GrantFiled: March 3, 1975Date of Patent: June 14, 1977Assignee: Q.sup.2 CorporationInventors: Stuart M. Oliver, Sanford J. Parsons
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Patent number: 3971639Abstract: A process and apparatus for gasifying coal to produce carbon monoxide and hydrogen in which a first stream of coal is burned without bed formation in a combustion zone in the presence of water under oxidation conditions to produce gases containing carbon dioxide and steam. A second stream of coal is maintained as a fluid bed in a separate gasifier zone by upflowing carbon dioxide and steam from the combustion zone while being gasified under reducing conditions to produce carbon monoxide and hydrogen. Char produced in the fluid bed is elutriated overhead and material in the fluid bed is prevented from direct entry into the combustion zone. The ratio of carbonaceous material to ash in the char removed overhead is lower than the average ratio of carbonaceous material to ash in the solids in the fluid bed.Type: GrantFiled: December 23, 1974Date of Patent: July 27, 1976Assignee: Gulf Oil CorporationInventor: Charles W. Matthews