Titanate, Zirconate, Stannate, Niobate, Or Tantalate Or Oxide Of Titanium, Zirconium, Tin, Niobium, Or Tantalum Containing (e.g., Dielectrics, Etc.) Patents (Class 501/134)
  • Publication number: 20080264565
    Abstract: A ceramic article which is resistant to erosion by halogen-containing plasmas used in semiconductor processing. The ceramic article includes ceramic which is multi-phased, typically including two phase to three phases. The ceramic is formed from yttrium oxide at a molar concentration ranging from about 50 mole % to about 75 mole %; zirconium oxide at a molar concentration ranging from about 10 mole % to about 30 mole %; and at least one other component, selected from the group consisting of aluminum oxide, hafnium oxide, scandium oxide, neodymium oxide, niobium oxide, samarium oxide, ytterbium oxide, erbium oxide, cerium oxide, and combinations thereof, at a molar concentration ranging from about 10 mole % to about 30 mole %.
    Type: Application
    Filed: April 27, 2007
    Publication date: October 30, 2008
    Inventors: Jennifer Y. Sun, Ren-Guan Duan, Jie Yuan, Li Xu, Kenneth S. Collins
  • Publication number: 20080258358
    Abstract: Slip containing at least one aluminium oxide powder and at least one unstabilized zirconium dioxide powder, wherein a) the zirconium dioxide powder i) has a mean particle diameter of less than 300 nm, ii) shows only the monoclinic phase and the tetragonal phase in the X-ray diffraction pattern, with the proportion of tetragonal phase at room temperature being from 20 to 70%, and iii) is present in a proportion of from 2 to 20% by weight, based on the total amount of the slip, b) the aluminium oxide powder i) has a mean particle diameter of more than 300 nm and ii) is present in a proportion of from 80 to 98% by weight, based on the total amount of the slip, and c) the solids content, as the sum of aluminium oxide and zirconium dioxide, is from 50 to 85% by weight, based on the total amount of the slip.
    Type: Application
    Filed: April 27, 2006
    Publication date: October 23, 2008
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Monika Oswald, Klaus Deller, Wolfgang Kollenberg, Dieter Nikolay
  • Patent number: 7439202
    Abstract: A glass ceramic composition is used for a multilayer ceramic substrate 2 including glass ceramic layers 3 laminated, the multilayer ceramic substrate 2 being used for a multilayer ceramic module 1. The glass ceramic composition includes a first ceramic powder mainly composed of forsterite, a second ceramic powder mainly composed of at least one component selected from CaTiO3, SrTiO3 and TiO2, and a borosilicate glass powder containing Li2O, MgO, B2O3, SiO2, ZnO and Al2O3. The glass ceramic composition contains 3 percent by weight or more of the borosilicate glass powder and further contains at least one additive selected from the group consisting of CaO, BaO and SrO.
    Type: Grant
    Filed: May 24, 2007
    Date of Patent: October 21, 2008
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Naoya Mori, Yoichi Moriya, Jun Urakawa, Yasutaka Sugimoto
  • Publication number: 20080254970
    Abstract: A niobium compound, ammonium(bisaquo oxobisoxalato)niobate (NH4)[Nb(O)(C2O4)2(H2O)2] and hydrates thereof, is described along with formulations containing the same and methods for creating a product specification for a batch, lot, or shipment of such compounds, comprising specifying at least one property value for said batch, lot, or shipment.
    Type: Application
    Filed: September 16, 2006
    Publication date: October 16, 2008
    Applicant: H.C. Starck GmbH
    Inventors: Karsten Beck, Hady Seyeda, Udo Sulkowski, Axel Rosenkranz
  • Patent number: 7431808
    Abstract: An electrically conductive titanium dioxide sputter target with an electrical resistivity of less than 5 ?-cm, which contains as an additive at least one doping agent or a mixture of doping agents in an amount of less than 5 mole %. The doping agent or agents are selected from the group including indium oxide, zinc oxide, bismuth oxide, aluminum oxide, gallium oxide, antimony oxide, and zirconium oxide. This treatment renders the titanium dioxide sputter target suitable for use in a direct-current sputtering process without any negative effects on the properties of the coating.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: October 7, 2008
    Assignee: W.C. Heraeus GmbH & Co., KG
    Inventors: Markus Schultheis, Christoph Simons, Martin Weigert
  • Publication number: 20080231667
    Abstract: A ferroelectric film having a columnar structure constituted by a plurality of columnar grains, and containing as a main component a perovskite oxide which has a composition expressed by a compositional formula A1+?[(ZrxTi1-x)1-yMy]Oz, where A represents one or more A-site elements including lead (Pb) as a main component, M represents one or more of vanadium (V), niobium (Nb), tantalum (Ta), and antimony (Sb) as one or more B-site elements, zirconium (Zr) and titanium (Ti) are also B-site elements, 0<x?0.7, 0.1?y?0.4, ? is approximately zero, z is approximately 3, and ? and z may deviate from 0 and 3, respectively, within ranges of ? and z in which the composition expressed by the compositional formula A1+?[(ZrxTi1-x)1-yMy]Oz can substantially form a perovskite structure.
    Type: Application
    Filed: March 20, 2008
    Publication date: September 25, 2008
    Applicant: FUJIFILM Corporation
    Inventors: Takami ARAKAWA, Takamichi FUJII
  • Patent number: 7419926
    Abstract: Disclosed are sintered bodies that include: (a) 30 to 100 mol % of NbOx, wherein 0.5<x<1.5; and (b) 0 to 70 mol % of MgO. The sintered bodies may be used as inert apparatuses in the production of niobium suboxide powder or niobium suboxide anodes, or as chemically resistant components in chemical apparatuses.
    Type: Grant
    Filed: October 12, 2004
    Date of Patent: September 2, 2008
    Assignee: H.C. Starck GmbH
    Inventors: Christoph Schnitter, Gerhard Wötting
  • Publication number: 20080203627
    Abstract: Disclosed are ceramic articles comprising a sintered phase ceramic composition containing, as expressed on a weight percent oxide basis: a(Al2TiO5)+b(ZrTiO4)+c(Y2O3)+d(YPO4) wherein “a, b, c, and d” represent weight fractions of each component such that (a+b+c+d)=1.00 and wherein 0.5<a?0.95; 0?b?0.5, 0.0?c?0.10, and 0?d?0.5. Also disclosed are precursor batch compositions and methods for manufacturing the ceramic articles disclosed herein.
    Type: Application
    Filed: February 27, 2007
    Publication date: August 28, 2008
    Inventors: Steven Bolaji Ogunwumi, Cameron Wayne Tanner
  • Patent number: 7417001
    Abstract: A glass ceramic composition for glass ceramic layers laminated in multilayer ceramic substrate included in multilayer ceramic module is provided. The glass ceramic composition contains a first ceramic powder mainly composed of forsterite, a second ceramic powder mainly composed of at least one material selected from CaTiO3, SrTiO3 and TiO2, and a borosilicate glass powder containing Li2O, MgO, B2O3, SiO2, ZnO and possibly Al2O3. The content of the borosilicate glass powder is about 3 percent by weight or more. The borosilicate glass powder further contains at least one additive selected from the group consisting of CaO, BaO and SrO.
    Type: Grant
    Filed: November 27, 2006
    Date of Patent: August 26, 2008
    Assignee: Murata Manufacturing Co., Ltd
    Inventors: Naoya Mori, Yoichi Moriya, Jun Urakawa, Yasutaka Sugimoto
  • Patent number: 7408292
    Abstract: The invention relates to a piezoelectric ceramic material having the general composition ABO3 with at least a proportion of the PZT ceramic having a composition of the invention with Cu cations. The proportion of Zr and Ti cations is selected based upon the content of Cu cations, such that the ceramic material is tailored to the morphotropic phase boundary. The invention further discloses a method for producing a ceramic material of this type.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: August 5, 2008
    Assignee: EPCOS AG
    Inventors: Adalbert Feltz, Heinz Florian, Marion Ottlinger, Sigrid Ragossnig, Peter Sedlmaier
  • Patent number: 7405173
    Abstract: An alumina-titanium oxide-zirconia fused grain presenting, for a total of 100%, the following chemical composition: Al2O3: more than 10% and less than 50%; TiO2: more than 10% and less than 40%; ZrO2: more than 50%; and impurities: less than 2%; the percentages being percentages by weight on the basis of the oxides. The invention is applicable to slide gates for continuous casting of steel.
    Type: Grant
    Filed: January 31, 2007
    Date of Patent: July 29, 2008
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Samuel Marlin, Jerome Latournerie
  • Publication number: 20080176732
    Abstract: A ceramic composition including a first ceramic material and a second ceramic material that is in the form of nano-, submicron-, or micron-sized particles, in which the first ceramic material has a lower melting point than the second ceramic material, and, when the first ceramic material melts into a liquid and the second ceramic material remains particulate, the second ceramic material floats at the top of the liquid. Also disclosed is a variant of this composition including a first ceramic material and a second ceramic material, in which the second ceramic material has a melting point higher than the first ceramic material, and, when the first ceramic material melts into a liquid, the second ceramic material partially or completely dissolves in the liquid.
    Type: Application
    Filed: March 14, 2008
    Publication date: July 24, 2008
    Applicant: AST Products, Inc.
    Inventors: Ih-Houng Loh, Geoffrey Wen-Tai Shuy
  • Patent number: 7402938
    Abstract: A piezoelectric single crystal device is provided exhibiting excellent piezoelectric properties, within a specific high-temperature range of Trrt° C. to (Trt?20)° C., where Trt represents a transformation temperature between a pseudocubic system and a tetragonal system. Specifically, the piezoelectric single crystal device is composed of a single crystal having a composition represented by [Pb(Mg,Nb)O3](1-X)·[PbTiO3](X), where X is within the range of 0.26 to 0.29 and having a complex perovskite structure, wherein a specific inductive capacity at 25° C. is 5,000 or more, and a specific inductive capacity at the transformation temperature between a pseudocubic system and a tetragonal system of the above-described single crystal is 2.5 times or more larger than the specific inductive capacity at 25° C.
    Type: Grant
    Filed: October 25, 2005
    Date of Patent: July 22, 2008
    Assignee: JFE Mineral Co., Ltd.
    Inventors: Mitsuyoshi Matsushita, Yosuke Iwasaki
  • Patent number: 7399723
    Abstract: There is provided a dielectric ceramic material in which the firing temperature dependency of the relative dielectric constant can be suppressed and the mechanical strength can be improved. Specifically, there is provided a dielectric ceramic material including: main constituents given by a composition located in the region, in a ternary diagram of ZrO2, SnO2 and TiO2 shown in FIG. 1, bounded by point A, point B, point C, point D, point E and point F; and ZnO: 0.5 to 5 wt %, NiO: 0.1 to 3 wt %, and SiO2: 0.008 to 1.5 wt % in relation to the total weight of the main constituents. The dielectric ceramic material can include Nb2O5: 0.2 wt % or less and K2O: 0.035 wt % or less in relation to the total weight of the main constituents.
    Type: Grant
    Filed: October 4, 2006
    Date of Patent: July 15, 2008
    Assignee: TDK Corporation
    Inventors: Isao Kanada, Ryohei Nakano, Tatsuya Kikuchi, Hisashi Kobuke, Masaru Abe, Kouji Tashiro, Matsumi Watanabe
  • Patent number: 7390426
    Abstract: The present invention has an object to provide piezoelectric ceramics containing no lead, having a high Curie point, and further, having excellent piezoelectric properties, particularly large Qmax. The piezoelectric ceramics contain, as a main component, a bismuth layer-structured compound having (MII1-xLnx)Bi4Ti4O15 crystals (MII is an element selected from Sr, Ba, and Ca, Ln is an element selected from lanthanoids, and x is within a range of 0<x?0.5) and further contain, as secondary components, at least one of Mn oxide and Co oxide, and lanthanoid, wherein the lanthanoid being the secondary component is contained within a range of 0.02 to 0.12 wt % in terms of oxide thereof.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: June 24, 2008
    Assignee: TDK Corporation
    Inventors: Takeo Tsukada, Tomohisa Azuma, Masakazu Hirose
  • Patent number: 7387745
    Abstract: The invention relates to piezoelectric ceramic materials based on the system Pb(Zr,Ti)O3, i.e. solid solutions of lead zirconate PbTO3, characterized by having very good dielectric and electromechanical properties that can be adopted for different uses by modifying the composition. The piezoelectric ceramic materials based on the system Pb(Zr,Ti)O3 are modified in order to obtain a high level of piezoelectric activity. The invention provides piezoelectric ceramic materials based on lead zirconate titanate (PZT) having the crystal structure of perovskite with formula A2+B4+O32?, which are characterized by a substitution of heterovalent acceptor and donator ions at Zr/Ti sites.
    Type: Grant
    Filed: September 20, 2002
    Date of Patent: June 17, 2008
    Assignee: CeramTec AG
    Inventor: Gunter Helke
  • Publication number: 20080135798
    Abstract: A nano-size lead-free piezoceramic powder and a method of mechanochemically synthesizing the same are provided. The nano-size lead-free piezoceramic powder can have a basic component of (KxNa1-x)NbO3, where x ranges from 0 to 1. A weight ratio of a milling ball to a raw powder can be set, and then the milling ball and the raw powder can be provided into a milling container at the set ratio. Nano-size lead-free piezoceramic powder can be mechanochemically synthesized using a high-energy ball mill device.
    Type: Application
    Filed: November 14, 2007
    Publication date: June 12, 2008
    Inventors: Jae Ho Jeon, Jung Yeul Yun
  • Publication number: 20080125305
    Abstract: Aluminum titanate precursor batch compositions comprising a recycled aluminum titanate component, at least a portion of the recycled aluminum titanate component being comprised of a recycled pre-reacted aluminum titanate composition or alternatively of an un-reacted green aluminum titanate precursor composition, and methods for producing aluminum titanate ceramic articles utilizing the inventive batch compositions.
    Type: Application
    Filed: November 29, 2006
    Publication date: May 29, 2008
    Inventors: John Paul Day, Robert John Locker, David Lambie Tennent, Christopher John Warren
  • Publication number: 20080124504
    Abstract: A method for manufacturing an inorganic honeycomb structure that resists water damage after drying comprises compounding a base batch mixture including inorganic powders, a batch cross-link agent, an aqueous vehicle, and a cross-linkable batch constituent, and forming the batch mixture into a honeycomb core or skin component while reacting the cross-link agent with cross-linkable batch constituent.
    Type: Application
    Filed: November 29, 2006
    Publication date: May 29, 2008
    Inventors: Margaret Kathleen Faber, Robert Gordon Lawrence, Weiguo Miao, Jianguo Wang
  • Patent number: 7374994
    Abstract: A bismuth titanium silicon oxide having a pyrochlore phase, a thin film formed of the bismuth titanium silicon oxide, a method for forming the bismuth-titanium-silicon oxide thin film, a capacitor and a transistor for a semiconductor device including the bismuth-titanium-silicon oxide thin film, and an electronic device employing the capacitor and/or the transistor are provided. The bismuth titanium silicon oxide has good dielectric properties and is thermally and chemically stable. The bismuth-titanium-silicon oxide thin film can be effectively used as a dielectric film of a capacitor or as a gate dielectric film of a transistor in a semiconductor device. Various electronic devices having good electrical properties can be manufactured using the capacitor and/or the transistor having the bismuth-titanium-silicon oxide film.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: May 20, 2008
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Young-jin Cho, Yo-sep Min, Young-soo Park, Jung-hyun Lee, June-key Lee, Yong-kyun Lee
  • Patent number: 7368408
    Abstract: A glass-ceramic composition contains first ceramic particles principally containing forsterite; second ceramic particles principally containing at least one selected from the group consisting of calcium titanate, strontium titanate, and titanium oxide; and borosilicate glass particles containing about 3% to 15% lithium oxide, about 20% to 50% magnesium oxide, about 15% to 30% boron oxide, about 10% to 45% silicon oxide, about 6% to 20% zinc oxide, 0% to about 15% aluminum oxide, and at least one additive selected from the group consisting of calcium oxide, barium oxide, and strontium oxide on a weight basis. The content of the borosilicate glass particles is about 3% or more; the lower limit of the content of the additive is about 2%; and the upper limit of the additive content is about 15%, about 25%, or about 25% when the additive is calcium oxide, barium oxide, or strontium oxide, respectively, on a weight basis.
    Type: Grant
    Filed: August 22, 2006
    Date of Patent: May 6, 2008
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Naoya Mori, Yoichi Moriya, Jun Urakawa, Yasutaka Sugimoto
  • Patent number: 7368097
    Abstract: Process for preparing nanocrystalline lithium titanate spinels by reacting lithium hydroxide and a titanium alkoxide at elevated temperature in a reaction mixture which forms water of reaction.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: May 6, 2008
    Assignee: BASF Aktiengesellschaft
    Inventor: Hans-Josef Sterzel
  • Patent number: 7368407
    Abstract: A sintering temperature can be lowered to 1,200° C. by adding from 15% by weight or more to 35% by weight or less of rutile-type titanium dioxide into forsterite. By carrying out sintering at such a low temperature, a sintered product can be obtained in which sintering was carried out while retaining the respective crystal phases of the forsterite and rutile-type titanium dioxide. Such a sintered product is an excellent high-frequency ceramic composition, wherein the high quality factor Q·f value derived from forsterite is hardly impaired, and, the absolute value of the temperature coefficient ?f is controlled to 30 ppm/° C. or less by rutile-type titanium dioxide.
    Type: Grant
    Filed: May 28, 2004
    Date of Patent: May 6, 2008
    Assignees: Yasufuku Ceramics Co., Ltd., Marusu Glaze Co., Ltd.
    Inventors: Tsutomu Tsunooka, Hitoshi Ohsato, Tomonori Sugiyama
  • Patent number: 7365958
    Abstract: Crystal grains mainly composed of barium titanate have a mean grain size of not more than 0.2 ?m. The volume per unit cell V that is represented by a product of lattice constant (a, b, c) figured out from the X-ray diffraction pattern of the crystal grains is not more than 0.0643 nm3. Thereby, a dielectric ceramics having high relative dielectric constant can be obtained. A multilayer ceramic capacitor comprises a capacitor body and an external electrode that is formed at both ends of the capacitor body. The capacitor body comprises dielectric layers composed of the dielectric ceramics, and internal electrode layers. The dielectric layers and the internal electrode layers are alternately laminated.
    Type: Grant
    Filed: October 25, 2005
    Date of Patent: April 29, 2008
    Assignee: Kyocera Corporation
    Inventors: Youichi Yamazaki, Yumiko Itoh, Kousei Kamigaki, Kiyoshi Matsubara
  • Patent number: 7351674
    Abstract: An insulating ceramic composition forming insulating ceramic layers (3) stacked in a multilayer ceramic substrate (2) used in a monolithic ceramic electronic component, such as a multilayer ceramic module (1). The insulating ceramic composition contains a first ceramic powder mainly containing forsterite, a second ceramic powder mainly containing at least one compound selected from the group consisting of CaTiO3, SrTiO3, and TiO2, and a borosilicate glass powder. The borosilicate glass powder contains 3 to 15 percent by weight of lithium in terms of Li2O, 30 to 50 percent by weight of magnesium in terms of MgO, 15 to 30 percent by weight of boron in terms of B2O3, 10 to 35 percent by weight of silicon in terms of SiO2, 6 to 20 percent by weight of zinc in terms of ZnO, and 0 to 15 percent by weight of aluminum in terms of Al2O3. The insulating ceramic composition can be fired at a temperature of 1000° C.
    Type: Grant
    Filed: February 2, 2005
    Date of Patent: April 1, 2008
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Naoya Mori, Yoichi Moriya, Jun Urakawa, Yasutaka Sugimoto
  • Patent number: 7344654
    Abstract: A piezoelectric ceramic composition has the composition formula (Pb(a-b)Meb){(Ni(1-c)/3Znc/3Nb2d/3)zTixZr(1-x-z)}O3, wherein Me represents at least one element selected from the group consisting of Ba, Sr and Ca; a, b, d, and x satisfy the inequalities 0.975?a?0.998, 0?b?0.05, 1<d?1.3, and 0.39?x?0.47; and c and z are located in a region surrounded by lines connecting Point A (z=0.25, c=0.1), Point B (z=0.25, c=0.85), Point C (z=0.1, c=0.6), Point D (z=0.075, c=0.5), Point E (z=0.05, c=0.2), and Point F (z=0.05, c=0.1) or located on the lines in the z-c plane. Therefore, the piezoelectric ceramic composition is effective in achieving a large piezoelectric constant, a small dielectric constant, and a high Curie point. A piezoelectric actuator contains the piezoelectric ceramic composition.
    Type: Grant
    Filed: June 22, 2007
    Date of Patent: March 18, 2008
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Koji Ogiso, Atsushi Yamamoto, Koichi Hayashi
  • Patent number: 7341970
    Abstract: Compositions, and articles having low thermal expansion suitable for high temperature applications, such as automotive exhaust treatment and method of manufacturing such articles are disclosed.
    Type: Grant
    Filed: March 28, 2005
    Date of Patent: March 11, 2008
    Assignee: Corning Incorporated
    Inventors: Douglas Munroe Beall, Matthew John Dejneka, Christy Lynn Powell
  • Patent number: 7323806
    Abstract: A thin-film piezoelectric element has a substrate, a lower electrode, a piezoelectric portion, and an upper electrode that are sequentially formed on the substrate. The piezoelectric portion has a dielectric thin film that has an alkali niobium oxide-based perovskite structure expressed by general formula (NaxKyLiz)NbO3 (0<x<1, 0<y<1, 0?z<1, x+y+z=1), and a high voltage-withstand dielectric that has a dielectric strength voltage greater than that of the dielectric thin film.
    Type: Grant
    Filed: December 23, 2005
    Date of Patent: January 29, 2008
    Assignee: Hitachi Cable, Ltd.
    Inventors: Kenji Shibata, Hideki Sato
  • Publication number: 20080010960
    Abstract: Disclosed are plugging mixtures for a ceramic wall flow filter, comprising an aluminum titanate precursor reactive batch composition including an alumina source, a silica source, and a titania source; a sintering aid; an organic binder; and a liquid vehicle. Also disclosed are ceramic wall flow filters comprised of end plugs formed from the plugging mixtures of the present invention and methods for the manufacture thereof.
    Type: Application
    Filed: July 14, 2006
    Publication date: January 17, 2008
    Inventors: Robert John Paisley, Patrick David Tepesch
  • Patent number: 7319081
    Abstract: A thin film capacity element composition includes a first bismuth layer-structured compound having positive temperature characteristics, that a specific permittivity rises as the temperature rises, in at least a part of a predetermined temperature range and a second bismuth layer-structured compound having negative temperature characteristics, that a specific permittivity declines as a temperature rises, in at least a part of said predetermined temperature range at any mixing ratio; wherein the bismuth layer-structured compound is expressed by a composition formula of CaxSr(1-x)Bi4Ti4O15.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: January 15, 2008
    Assignee: TDK Corporation
    Inventors: Yukio Sakashita, Hiroshi Funakubo
  • Publication number: 20080009404
    Abstract: There is provided a dielectric ceramic material in which the firing temperature dependency of the relative dielectric constant can be suppressed and the mechanical strength can be improved. Specifically, there is provided a dielectric ceramic material including: main constituents given by a composition located in the region, in a ternary diagram of ZrO2, SnO2 and TiO2 shown in FIG. 1, bounded by point A, point B, point C, point D, point E and point F; and ZnO: 0.5 to 5 wt %, NiO: 0.1 to 3 wt %, and SiO2: 0.008 to 1.5 wt % in relation to the total weight of the main constituents. The dielectric ceramic material can include Nb2O5: 0.2 wt % or less and K2O: 0.035 wt % or less in relation to the total weight of the main constituents.
    Type: Application
    Filed: October 4, 2006
    Publication date: January 10, 2008
    Applicant: TDK CORPORATION
    Inventors: Isao Kanada, Ryohei Nakano, Tatsuya Kikuchi, Hisashi Kobuke, Masaru Abe, Kouji Tashiro, Matsumi Watanabe
  • Patent number: 7312558
    Abstract: In a piezoelectric element, a cubic or tetragonal orientation control layer (15) is provided on a first electrode layer (14), and formed on the orientation control layer (15) is a piezoelectric layer (16) having a rhombohedral or tetragonal crystalline structure and made of lead zirconate titanate to which a Pb-containing complex perovskite compound expressed by the chemical formula Pb(AaBb)O3 has been added in an amount that is from 1 mol % to 50 mol %. The piezoelectric layer (16) is formed so that the crystal grains thereof become columnar grains which extend in the thickness direction of the piezoelectric layer (16) and in which the ratio of the average cross-sectional diameter to the length is from 1/50 to 1/14.
    Type: Grant
    Filed: April 1, 2005
    Date of Patent: December 25, 2007
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Satoru Fujii, Takeshi Kamada, Atsushi Tomozawa, Eiji Fujii
  • Patent number: 7309450
    Abstract: Provided is a piezoelectric ceramic with a wider operating temperature range capable of obtaining a larger amount of displacement and being easily sintered, as well as being superior in terms of ultra-low emission, environmental friendliness and ecology. A piezoelectric substrate 1 comprises a composition including a perovskite-type oxide (Na1?x?y?zKxLiyAgz)(Nb1?wTaw)O3 and a tungsten bronze-type oxide M(Nb1?vTav)2O6 (M is an element of Group 2 in the long form of the periodic table of the elements). The values of x, y and z are preferably within a range of 0.1?x?0.9, 0?y?0.2, and 0?z?0.05, respectively. The content of the tungsten bronze-type oxide is preferably 5.3 mol % or less. Thereby, a higher Curie temperature and a larger amount of displacement can be obtained, and sintering can be more easily carried out.
    Type: Grant
    Filed: June 14, 2002
    Date of Patent: December 18, 2007
    Assignee: TDK Corporation
    Inventors: Masaru Nanao, Yasuharu Miyauchi, Tamotsu Ishiyama, Masahito Furukawa, Shogo Murosawa, Yoshiko Gokita
  • Patent number: 7309949
    Abstract: A piezoelectric/electrostrictive porcelain composition capable of being manufactured at a comparatively low firing temperature is provided, as well as a piezoelectric/electrostrictive ceramic or a piezoelectric/electrostrictive portion which is dense and superior in crystallinity and which has superior piezoelectric/electrostrictive characteristics and durability even under high temperature and high humidity conditions. The piezoelectric/electrostrictive porcelain composition includes a piezoelectric/electrostrictive component containing lead titanate zirconate, and 0.5 to 5% by mass of glass component containing 8% by mass or less of silicic acid.
    Type: Grant
    Filed: February 23, 2005
    Date of Patent: December 18, 2007
    Assignee: NGK Insulators, Ltd.
    Inventors: Toshikatsu Kashiwaya, Yukihisa Takeuchi, Yuya Kikuta
  • Patent number: 7304008
    Abstract: Thermochromic material comprising a thermochromic component and a binder, wherein the thermochromic component is crystal phases based on oxides of heavy metals of I, II, III, IV, V, VI, VII, VIII groups of the Periodic System selected from the group consisting of compounds of the following general formulae: (i) (Bi2O3)1-z(MxOy)z where z=0–0.
    Type: Grant
    Filed: May 15, 2001
    Date of Patent: December 4, 2007
    Assignee: Eurokera
    Inventors: Anna Vasilievna Belykh, Alexandr Mikhailovich Efremov, Mikhail Dmitrievich Mikhailov
  • Patent number: 7303692
    Abstract: Piezoelectric ceramics of the formula Pb(1-z)Mz(Mg1/3Nb2/3)x(ZryTi1-y)1-xO3 where M can be either Sr or Ba or both, and x is between 0.3 and 0.6, y is between 0.2 and 0.5, and z is between 0.04 and 0.08. The piezoelectric ceramic is provided as a composite perovskite structure, and may additionally include materials or dopants such as: PbO, HfO2, TeO2, WO3, V2O5, CdO, Tm2O3, Sm2O3, Ni2O3, and MnO2. The piezoelectric ceramics can be used to fabricate piezoelectric elements for a wide variety of devices that can be fabricated to exhibit high power applications including miniaturized displacement elements, buzzers, transducers, ultrasonic sensors and ultrasonic generators, and the like.
    Type: Grant
    Filed: April 11, 2005
    Date of Patent: December 4, 2007
    Assignee: Piezotech, LLC
    Inventor: De Liufu
  • Patent number: 7297650
    Abstract: The production of low-loss, tunable composite ceramic materials with improved breakdown strengths is disclosed. The composite materials comprise ferroelectric perovskites such as barium strontium titanate or other ferroelectric perovskites combined with other phases such as low-loss silicate materials and/or other low-loss oxides. The composite materials are produced in sheet or tape form by methods such as tape casting. The composite tapes exhibit favorable tunability, low loss and tailorable dielectric properties, and can be used in various microwave devices.
    Type: Grant
    Filed: April 13, 2005
    Date of Patent: November 20, 2007
    Assignee: Paratek Microwave, Inc.
    Inventors: Luna H. Chiu, Xubai Zhang, Louise C. Sengupta
  • Patent number: 7297322
    Abstract: A process for producing powders of metal compound containing oxygen including the steps of: feeding at least one material selected from a liquid material and a solution material obtained by dissolving solid ingredient in organic solvent via a liquid flow controller into a vaporizer; vaporizing the materials in the vaporizer; adding oxygen; heating; cooling; and crystallizing. Also disclosed is the product formed by this process, and apparatus used in performing the process. The process and the apparatus enable easily mass-producing fine powders of metal compound containing oxygen used as materials for optical crystals, nonlinear crystals or magneto-optical crystals with reasonable production cost.
    Type: Grant
    Filed: March 11, 2005
    Date of Patent: November 20, 2007
    Assignee: Japan Pionics Co., Ltd.
    Inventors: Yukichi Takamatsu, Koji Kiriyama, Akira Asano, Takafumi Ishii
  • Patent number: 7294164
    Abstract: This invention relates to an aluminum titanate body having a narrow pore size distribution as characterized by the relation (d50?d10)/d50 being less than 0.50 corresponding to a high degree of interconnected porosity. The body also preferably exhibits a low coefficient of thermal expansion of less than 15×10?7 C?1, high porosity of at least 38% by volume, and at least 0.10% by weight metal oxide, the metal being either yttrium, calcium, bismuth, a lanthanide metal or combinations of thereof. MOR is preferably at least 450 psi. Median pore diameter is preferably at least 8 microns. The inventive ceramic body is particularly useful as a wall-flow filter for a diesel exhaust. A method of fabrication is provided where the sintering temperature is preferably between 1375°-1550° C.
    Type: Grant
    Filed: July 28, 2005
    Date of Patent: November 13, 2007
    Assignee: Corning Incorporated
    Inventor: Gregory A. Merkel
  • Publication number: 20070228318
    Abstract: Piezoelectric performance is improved in a piezoelectric ceramic having a perovskite-type crystal structure expressed by a general formula ABO3 and the B-site element including niobium. The piezoelectric ceramic has a perovskite-type crystal structure in which plural octahedrons formed of oxygen are arranged to share vertices thereof and elements are located at a center of eight octahedrons and at a center of each octahedron; wherein an element located at the center of eight octahedrons is A-site element, an element located at the center of each octahedron is B-site element, and a general formula of the perovskite-type crystal structure is ABO3; the B-site element includes niobium (Nb); and bismuth (Bi) content in composition of the piezoelectric ceramic is 100 ppm by weight or less.
    Type: Application
    Filed: March 28, 2007
    Publication date: October 4, 2007
    Applicant: FUJIFILM Corporation
    Inventor: Shigenori Yuuya
  • Publication number: 20070227643
    Abstract: An object of the present invention is to provide internal electrode paste capable of preventing dripping and blurring, etc. of paste even when a solvent ratio is increased and an electrode material powder ratio is decreased in the paste and, moreover, capable of forming a uniform internal electrode layer without any printing unevenness so as to obtain a thin internal electrode layer: comprising an electrode material powder, a solvent and a binder resin; wherein a molecular structure of the binder resin comprises both of a first structure unit (an acetal group derived from acetaldehyde) and a second structure unit (a butyral group derived from butylaldehyde).
    Type: Application
    Filed: March 23, 2007
    Publication date: October 4, 2007
    Applicant: TDK CORPORATION
    Inventors: Yasushi Iijima, Shigeki Sato, Tomoko Nakamura
  • Patent number: 7276461
    Abstract: A dielectric ceramic composition having a relative dielectric constant ?r of 15-25 allowing formation of a laminated ceramic part having an appropriate size, capable of being sintered at a temperature lower than 800-1000° C. allowing incorporation and lamination of low resistance conductor of Cu or Ag through simultaneous sintering, and having a low dielectric loss tan ? (high Q-value) and a temperature coefficient ?f of resonant frequency has an absolute value not larger than 50 ppm/° C. The dielectric ceramic composition contains 3-30 parts by weight of lead-free low melting point glass containing 50 to 75 wt % of ZnO, 5 to 30 wt % of B2O3, 6 to 15 wt % of SiO2, 0.5 to 5 wt % of Al2O3, and 3 to 10 wt % of BaO, based on 100 parts by weight of major component expressed by a general formula of x?Zn2TiO4-(1?x??y?)ZnTiO3-y?TiO2 where 0.15<x?<0.8 and 0?y??0.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: October 2, 2007
    Assignee: UBE Industries, Ltd.
    Inventors: Takafumi Kawano, Koichi Fukuda
  • Patent number: 7271114
    Abstract: A ceramic powder having a perovskite structure is manufactured by synthesizing a ceramic powder by a dry synthesis process and then heat-treating the synthesized ceramic powder in a solution. The dry synthesis method includes a solid phase synthesis method, an oxalate method, a citric acid method and a gas phase synthesis method.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: September 18, 2007
    Assignee: Taiyo Yuden Co., Ltd.
    Inventors: Chie Kawamura, Atsushi Tanada, Hirokazu Chazono
  • Patent number: 7267783
    Abstract: This invention provides a piezoelectric ceramic composition that does not contain lead, can be sintered at a normal pressure and is excellent in at least one of a piezoelectric constant, an electro-mechanical coupling coefficient, a dielectric loss, a relative dielectric constant and a Curie point, its production method, and a piezoelectric device and a dielectric device each utilizing the piezoelectric ceramic composition. The invention relates to a piezoelectric composition expressed by the general formula {Lix(K1?yNay)1?x}(Nb1?zSbz)O3, each of x, y and z respectively falling within composition ranges of 0?x?0.2, 0?y?1.0 and 0?z?0.2 (with the exception of x=z=0), and its production method. The invention further relates to a piezoelectric device having a piezoelectric body formed of the piezoelectric ceramic composition described above and a dielectric device having a dielectric body formed of the piezoelectric ceramic composition described above.
    Type: Grant
    Filed: March 19, 2003
    Date of Patent: September 11, 2007
    Assignee: DENSO CORPORATION
    Inventors: Tatsuhiko Nonoyama, Toshiatsu Nagaya, Yasuyoshi Saito, Kazumasa Takatori, Takahiko Homma, Hisaaki Takao
  • Patent number: 7264744
    Abstract: A piezoelectric ceramic and a piezoelectric device capable of being fired at a low temperature and improving piezoelectric properties are provided. The piezoelectric ceramic and the piezoelectric device includes Pba[(Znb/3Nb2/3)xTiyZrz]O3 (where 0.94?a?1.02, 1<b?3, x+y+z=1, 0.05?x<0.125, 0.275<y?0.5, 0.375<z?0.6) or (Pbe·fMef)[(Zng/3Nb2/3)uTivZrw]O3 (where 0.96?e?1.03, 0.01?f?0.1, 1<g?3, u+v+w=1, 0.05?u<0.125, 0.275<v?0.5, 0.375<w?0.6, and Me indicates Sr, Ba or Ca). When an excessive amount of Zn is included, the firing temperature can be lower, and the piezoelectric properties can be improved.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: September 4, 2007
    Assignee: TDK Corporation
    Inventors: Masaru Nanao, Masahito Furukawa, Hideya Sakamoto, Takeo Tsukada
  • Patent number: 7265071
    Abstract: A dielectric ceramic composition characterized as containing a dielectric material which contains a dielectric composition represented by the compositional formula a.Li2O-b.(CaO1?x—SrOx)-c.R2O3-d.TiO2 (wherein x satisfies 0?x<1; R is at least one selected from La, Y and other rare-earth metals; and a, b, c and d satisfy 0?a?20 mol %, 0?b?45 mol %, 0<c?20 mol % and 40?d?80 mol %) and at least one of oxides of Group 4 and Group 14 metallic elements of the Periodic Table.
    Type: Grant
    Filed: February 14, 2005
    Date of Patent: September 4, 2007
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Takashi Umemoto, Rintaro Aoyagi, Hiroshi Nonoue, Kenichiro Wakisaka
  • Patent number: 7261833
    Abstract: Aqueous coating slurries useful in depositing a dense coating of a ceramic electrolyte material (e.g., yttrium-stabilized zirconia) onto a porous substrate of a ceramic electrode material (e.g., lanthanum strontium manganite or nickel/zirconia) and processes for preparing an aqueous suspension of a ceramic electrolyte material and an aqueous spray coating slurry including a ceramic electrolyte material. The invention also includes processes for depositing an aqueous spray coating slurry including a ceramic electrolyte material onto pre-sintered, partially sintered, and unsintered ceramic substrates and products made by this process.
    Type: Grant
    Filed: July 12, 2004
    Date of Patent: August 28, 2007
    Assignee: NexTech Materials, Ltd.
    Inventors: Matthew M. Seabaugh, Scott L. Swartz, William J. Dawson, Buddy E. McCormick
  • Publication number: 20070197370
    Abstract: A lead zirconate titanate type composition contains a three-component system lead zirconate titanate (X), which may be represented by the general formula of Pb(Ni, Nb)O3—PbZrO3—PbTiO3, an (A) constituent, which is Pb in excess of a quantity conforming to a stoichiometric ratio, a (B) constituent, which is Zn, and a (C) constituent, which is at least one kind of rare earth element selected from the group consisting of Ce, Yb, and Dy, the (A) constituent, the (B) constituent, and the (C) constituent being added to the three-component system lead zirconate titanate (X).
    Type: Application
    Filed: February 23, 2007
    Publication date: August 23, 2007
    Applicant: FUJIFILM Corporation
    Inventors: Takashi Nakamura, Takami Arakawa
  • Patent number: 7259120
    Abstract: An aluminum titanate ceramic article having a predominant crystal phase of aluminum titanate and a material composition including aluminum, titanium, silica, an alkaline earth metal (e.g., at least one selected from the group of strontium, calcium, barium, or combinations), and a rare earth metal (e.g., at least one selected from the group consisting of yttrium, lanthanum, and combinations) and methods of making such aluminum titanate bodies are described. An oxide of yttrium metal or lanthanide metals is preferably used as a sintering aid in combination with the other compositional components to enable firing of the resulting green body at a lower heating temperature of less than 1500° C., and more preferably between 1400°-1450° C., with a preferable hold time of less than 8 hours, more preferably of 6 to 8 hours.
    Type: Grant
    Filed: February 22, 2005
    Date of Patent: August 21, 2007
    Assignee: Corning Incorporated
    Inventors: Adam James Gillmar Ellison, Patrick David Tepesch, Christopher John Warren
  • Patent number: 7255815
    Abstract: The present invention relates to a round and spherical titanium dioxide scouring media and a method for producing the media. The scouring media is effective in removing titanium dioxide buildup on the walls of a titanium dioxide reaction vessel. The method consists of forming green titanium dioxide pellets in a high intensity mixer by mixing commercially available titanium dioxide dust and water. The high intensity mixer produces substantially round and spherical green pellets which are subsequently sized and sintered in a kiln to form round and spherical titanium dioxide sintered pellets that are suitable as a scouring media. The high intensity mixer allows the operator to closely control the size and shape of the pellets during the forming process to produce substantially round and spherical green pellets. Because the sintered titanium dioxide pellets are substantially round and spherical in shape, they are much less abrasive to the walls of the reaction vessel.
    Type: Grant
    Filed: March 24, 2003
    Date of Patent: August 14, 2007
    Assignee: Carbo Ceramics Inc.
    Inventors: Claude Krause, Steve Canova