Alkaline Earth Or Magnesium Containing Patents (Class 501/135)
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Publication number: 20090062107Abstract: A translucent ceramic contains a main component composed of a tungsten-bronze-type compound represented by a general formula {(Sr, Ba)NbvOw} (wherein v satisfies the relationship 1.8?v?2.2 and w represents a positive number for maintaining electrical neutrality), wherein some Nb atoms are replaced with atoms of at least one of Zn and Mg, and the replacement ratio is 0.004 or more in terms of the molar ratio. It is preferable that at least one of Sn and Bi is added in an amount of 0.15 parts by weight or more in terms of SnO2 and Bi2O3, respectively, to 100 parts by weight of the main component, and that the molar ratio of Ba in the (Sr, Ba) site is in the range of 0.25 to 0.50. It is also preferable that the translucent ceramic contains Na in an amount of less than 25 parts by mole relative to 100 parts by mole of the sum of Sr and Ba, or La in an amount of less than 11 moles relative to 100 parts by mole of the sum of Sr and Ba.Type: ApplicationFiled: November 20, 2008Publication date: March 5, 2009Applicant: MURATA MANUFACTURING CO., LTD.Inventor: Teppei Kubota
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Patent number: 7498082Abstract: A dielectric ceramic composition including dielectric particles comprising a main ingredient phase having barium titanate as its main ingredient and a diffusion phase present at the periphery of said main ingredient phase, wherein when an average value of the depth where sub ingredient elements present at said diffusion phase diffuses from a surface of said diffusion phase toward a center of said dielectric particle is designated as an average diffusion depth, a dispersion of the average diffusion depth among the dielectric particles is, in terms of CV value, 5 to 30%. According to the present invention, an electronic device excellent in all of the dielectric constant, high temperature accelerated life, TC bias, and IR temperature dependency can be provided.Type: GrantFiled: November 7, 2006Date of Patent: March 3, 2009Assignee: TDK CorporationInventors: Kazushige Ito, Akira Sato, Akitoshi Yoshii, Masayuki Okabe, Atsushi Takeda, Takaki Shinkawa
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Publication number: 20090048089Abstract: 0.5 to 30 parts by weight of a hexagonal celsian powder is added to 100 parts by weight of a ceramic raw material powder to give a mixture. The mixture is sintered to give a ceramic porcelain so as to precipitate monoclinic celsian in the ceramic porcelain.Type: ApplicationFiled: September 9, 2008Publication date: February 19, 2009Applicants: NGK Insulators, Ltd., Soshin Electric Co., Ltd.Inventors: Takeshi Oobuchi, Tadashi Otagiri, Yoshinori Ide
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Publication number: 20090046410Abstract: Dielectric ceramics represented as: CaxZrO3+aMn+bLi+cB+dSi and comprising: based on 100 mol of CaxZrO3 (where 1.00?x?1.10), 0.5?a?4.0 mol, and 6.0?b+c+d?15.0 mol, in which 0.15?b/(c+d)?0.55, and 0.20?d/c?3.30 or multi-layer ceramic capacitor using the same.Type: ApplicationFiled: June 27, 2008Publication date: February 19, 2009Applicant: Taiyo Yuden Co., Ltd.Inventor: Sinsuke TAKEOKA
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Publication number: 20090048088Abstract: A glass fiber composition comprises about 52-65 weight % SiO2; less than or equal to 4 weight % Al2O3; about 7-16 weight % Fe2O3; greater than 6 weight % and less than or equal to about 14 weight % R2O; about 6-25 weight % CaO; less than or equal to 10 weight % MgO; and about 10-25 weight % RO; wherein R2O represents alkali metal oxides and RO represents alkaline earth metal oxides. Preferably, the glass fiber composition has a liquidus temperature of less than 2350° F.; and a viscosity at a liquidus temperature of the glass fiber composition of greater than 500 poise; and fire resistant glass fiber formed from the glass fiber composition has a biodissolution rate of greater than 50 ng/cm2/hr.Type: ApplicationFiled: August 15, 2007Publication date: February 19, 2009Inventor: Elam A. Leed
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Publication number: 20090023578Abstract: A ceramic powder contains a principal component that is a perovskite-type complex oxide represented by the formula ANbO3 (A is at least one selected from alkali metal elements and contains 10 mole percent or more of K) and also contains 0.0001 mole or more of an element per mole of the principal component. The element is at least one selected from the group consisting of Yb, Y, In, Nd, Eu, Gd, Dy, Sm, Ho, Er, Tb, and Lu. The ceramic powder preferably further contains at least one selected from the group consisting of Ti, Zr, and Sn. This enables that a non-deliquescent alkali niobate-based ceramic powder is produced at a high yield.Type: ApplicationFiled: October 3, 2008Publication date: January 22, 2009Applicant: MURATA MANUFACTURING CO., LTD.Inventors: Ryoko Katayama, Shinichiro Kawada
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Publication number: 20090011921Abstract: A dielectric porcelain composition here contains as main components BaO, Nd2O3, TiO2, MgO and SiO2 at the given ratios and as subordinate components ZnO, B2O3, CuO and an alkaline earth metal oxide RO (R: an alkaline earth metal) at given ratios, preferably with the addition of Ag as an optional subordinate component, so that it can have low-temperature sintering capability stable and reliable enough to permit a conductor formed of Ag, an alloy containing Ag as a main component or the like to be used as an internal conductor.Type: ApplicationFiled: March 14, 2006Publication date: January 8, 2009Applicant: TDK CORPORATIONInventors: Tomohiro Arashi, Yasuharu Miyauchi
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Publication number: 20090004438Abstract: A dielectric ceramic composition includes about 10% to about 40% by weight of BaO, about 20% to about 65% by weight of SiO2, about 6% to about 40% by weight of Al2O3, about 1% to about 15% by weight of B2O3, about 0.3% to about 3% by weight of Cr2O3, and about 1% to about 40% by weight of ZrO2. A multilayer ceramic substrate has a laminated structure including an inner layer portion and outer layer portions that have a smaller thermal expansion coefficient than that of the inner layer portion. The use of the dielectric ceramic composition for the outer layer portions enables the ceramic to be resistant to erosion caused by a plating liquid used for plating external conductive films, thus maintaining good adhesiveness between the external conductive films and the outer layer portions.Type: ApplicationFiled: September 16, 2008Publication date: January 1, 2009Applicant: MURATA MANUFACTURING CO., LTD.Inventor: Jun URAKAWA
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Publication number: 20080300129Abstract: The present invention relates to a method of producing a ceramic material comprising the steps of: a) mixing a first clay composition comprising silica and a silicate mineral with a second clay composition; and b) firing the mixed clay composition from step a) to form a ceramic product. The present invention also relates to an engobe clay composition, sanitary ware and methods of productions thereof.Type: ApplicationFiled: August 4, 2008Publication date: December 4, 2008Applicant: Caroma Insdustries LimitedInventor: Emile Saleh
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Publication number: 20080284338Abstract: A polycrystalline body includes aluminum oxide, magnesium oxide, zirconium oxide, and lutetium oxide. The lutetium oxide is present in an amount of at least 10 ppm of the weight of the ceramic body, and the magnesium and zirconium oxides are present at a molar ratio of from 0.5:1 to 3:1.Type: ApplicationFiled: May 14, 2007Publication date: November 20, 2008Inventors: Karthik Sivaraman, Shuyi Qin, Ming Gao
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Publication number: 20080269043Abstract: A ceramic insulating material, in particular for sensor elements for determining the concentration of gas components in gas mixtures, is based on an alkaline earth-containing ceramic. The insulating material contains a hexaaluminate of the alkaline earth metal and at least one mixed compound of the alkaline earth metal with an acid oxide, the molar ratio of hexaaluminate to the sum of mixed compounds in the insulating material being 1.3 to 4.0.Type: ApplicationFiled: November 9, 2005Publication date: October 30, 2008Inventors: Thomas Wahl, Ulrich Eisele, Thomas Koehler, Bernd Schumann, Karl-Hermann Friese, Juergen Sindel, Stefan Nufer, Frank Buse
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Patent number: 7442344Abstract: It is an object of the present invention to provide a ceramic member with excellent balance between oxygen ion conductivity and endurance (resistance to cracking and the like), an oxygen ion permeation module and a chemical reactor such as an oxygen separator, using such a ceramic member. The ceramic member with oxygen ion conductivity in accordance with the present invention has a perovskite-type crystal structure and a composition represented by the general formula: (Ln1?xMx)(Ti1?yFey)O3 (where Ln represents at least one element selected from lanthanoids, and M represents at least one element selected from the group containing Sr, Ca, and Ba, 0<x<1, 0.4?y<1, x+y?1). The oxygen ion permeation module composed by employing such a ceramic member can be used as a structural component of an oxygen separator, an oxidation reactor (for example, a reactor for partial oxidation of hydrocarbons), and the like.Type: GrantFiled: November 7, 2002Date of Patent: October 28, 2008Assignees: Chubu Electric Power Co., Inc., Noritake Co., LimitedInventors: Takehiro Suzuki, Atsushi Fukaya, Hisatomi Taguchi, Shigeo Nagaya, Kiyoshi Komura, Syozo Watanabe
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Patent number: 7435697Abstract: A ceramic powder composition, ceramic material, and laminated ceramic condenser comprised thereof. The composition includes ceramic powders comprising (SrxCa1-x)TiyZr1-yO3, and a sintering aid, wherein x is between 0 and 1, and y is between 0 and 0.1. The sintering aid is Ma2O, MbO, Mc2O3, MdO2, or a combination thereof. Element Ma comprises Li, Na, K, or a combination thereof. Element Mb comprises Be, Mg, Ca, Sr, Ba, or a combination thereof. Element Mc comprises B, Al, Ga, or a combination thereof. Element Md comprises Si, Ge, or a combination thereof.Type: GrantFiled: December 7, 2005Date of Patent: October 14, 2008Assignee: Darfon Electronics Corp.Inventors: Ting-An Chien, Hsiu-Hsiang Pei
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Patent number: 7431984Abstract: A hybrid lens (3) has a structure in which a resin layer (2) composed of an ultraviolet curable resin is formed on the surface of a lens base material (1) composed of translucent ceramic. The lens base material (3) is composed of translucent ceramic containing as a main component an oxide with a perovskite structure represented by A{M,(B1, B2)}O3 (A is at least one selected from Ba, Sr and Ca, B1 is at least one selected from In, Y, Zn and Mg, B2 is at least one selected from Ta and Nb, and M is at least one selected from Ti, Zr, Hf and Sn) and at least Fe and Cu as sub-components. When the Fe content and Cu content in the translucent ceramic are x and y, respectively, 3x+y is 40 ppm by weight or less so that the hybrid lens (3) having excellent uniformity in optical properties and no crack defect can be obtained.Type: GrantFiled: March 27, 2007Date of Patent: October 7, 2008Assignee: Murata Manufacturing Co., Ltd.Inventors: Yuji Kintaka, Satoshi Kuretake, Nobuhiko Tanaka
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Publication number: 20080236723Abstract: A production method of a dielectric ceramic composition at least including a main component including a dielectric oxide having perovskite-type crystal structure expressed by a formula ABO3 (note that in the formula, “A” indicates one or more elements selected from Ba, Ca, Sr and Mg, and that “B” indicates one or more elements selected from Ti, Zr and Hf) comprises steps of preparing a main component material including said dielectric oxide expressed by ABO3; preparing a subcomponent material including a composite oxide expressed by M4R6O(SiO4)6 (note that “M” indicates at least one selected from Ca and Sr, and that “R” indicates at least one selected from Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu); mixing said main component material and subcomponent material to obtain a dielectric ceramic composition material; and firing said dielectric ceramic composition material.Type: ApplicationFiled: March 18, 2008Publication date: October 2, 2008Applicant: TDK CORPORATIONInventors: Tomoaki Nonaka, Hiroshi Sasaki, Tsutomu Odashima, Tetsuo Takaishi, Takahiro Harada
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Publication number: 20080227621Abstract: A glass includes SiO2, Na2CO3, K2CO3, CaO and ceramic particles which is composed of a combination of ALO3, MgO, and ZrO2 to emit infrared rays.Type: ApplicationFiled: March 13, 2007Publication date: September 18, 2008Inventor: Hsin-Mao Hsieh
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Publication number: 20080214500Abstract: The present invention relates to ceramic precursor powder compositions and chemically bonded ceramic (CBC) materials, Ca-aluminate and/or calcium silicate, and a composite biomaterial with prolonged shelf time of the precursor, suitable for orthopaedic applications with improved injectability. The present invention also relates to a method of manufacturing said cured material, bioelements, implants, or drug delivery carrier materials made by said cured material, a kit comprising the ceramic precursor powder and hydration liquid, as well as the use of said ceramic precursor powder and hydration liquid, or said cured material, for orthopaedic and dental applications.Type: ApplicationFiled: March 1, 2007Publication date: September 4, 2008Inventors: Leif Hermansson, Hakan Engqvist
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Publication number: 20080169445Abstract: A piezoelectric ceramic composition includes a bismuth layer compound containing at least Sr, Bi and Nb, e.g., (Sr0.9Nd0.1)Bi2Nb2O9, as a main component and 2 parts by weight or less (excluding 0 part by weight), preferably 0.04 part by weight to 0.5 part by weight, of Cu in terms of CuO relative to 100 parts by weight of the main component. From the viewpoint of improvement in sinterability, 0.1 part by weight to 2 parts by weight of Mn in terms of MnCO3 relative to 100 parts by weight of the main component is preferably contained. As a result, it is possible to obtain a piezoelectric ceramic composition resisting no deterioration in piezoelectricity even when a rapid temperature change occurs, and an advantageous piezoelectric component, such as a piezoelectric actuator or a piezoelectric resonator, manufactured using the piezoelectric ceramic composition.Type: ApplicationFiled: March 24, 2008Publication date: July 17, 2008Applicant: MURATA MANUFACTURING CO., LTD.Inventors: Hirozumi Ogawa, Masahiko Kimura, Kosuke Shiratsuyu
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Patent number: 7396790Abstract: A translucent ceramic having a high light transmittance is provided. It contains a perovskite compound having a composition represented by a general formula: (Ba1-s-tSrsCat)(MxB1yB2z)vOw (where M contains at least one of Sn, Zr and Hf, B1 represents at least one of Mg, Zn, Y and In, B2 represents at least one of Ta and Nb, each of conditions of 0?s?0.99, 0.01?t?0.45, x+y+z=1, 0<x?0.9, 1.00?z/y?2.40, and 0.97?v?1.05 is satisfied, and w represents a positive number for maintaining electrical neutrality) as a primary component. This translucent ceramic can be used as, for example, an objective lens (2) of an optical pickup (9) to provide advantages. In another aspect some of M is replaced by Ti.Type: GrantFiled: September 10, 2007Date of Patent: July 8, 2008Assignee: Murata Manufacturing Co., Ltd.Inventors: Satoshi Kuretake, Yuji Kintaka
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Patent number: 7397332Abstract: A high-frequency dielectric ceramic composition that has excellent dielectric properties, such as a large ?r, a large Q-value, and a small absolute value of ?f, even in a high-frequency region, such as a microwave region or a millimeter wave region, and that can be fired at 1400° C. or less, which is much lower than before, is provided. The high-frequency dielectric ceramic composition contains 100 parts by weight of main component and 0.005-0.300 parts by weight (on a B2O3 basis) of accessory boron compound. The main component has a composition formula of (1?y)xCaTiaO1+2a?(1?y)(1?x)Ca(M1z/3M22/3)bO1+2b-yLnAlcO(3+3c)/2, wherein x and y denote moles , and x, y, z, a, b, c, and ? (wherein ?=(1?y)x) satisfy the following relationships: 0.56?x?0.8, 0.08?y?0.18, 0.980?z<1.000, ??0.65, 0.985?a?1.05, 0.9?b?1.02, and 0.9?c?1.05.Type: GrantFiled: September 5, 2007Date of Patent: July 8, 2008Assignee: Murata Manufacturing Co., LtdInventor: Tatsuya Ishikawa
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Patent number: 7393803Abstract: A dielectric ceramic composition of the present invention contains, as a main component, a tungsten-bronze-type composite oxide represented by a composition formula (K1-yNay)Sr2Nb5O15 (wherein 0?y<0.2) and, as an auxiliary component, Mn in an amount in the range of 0.1 to 40 parts by mole relative to 100 parts by mole of the main component.Type: GrantFiled: October 17, 2007Date of Patent: July 1, 2008Assignee: Murata Manufacturing Co., Ltd.Inventors: Toshikazu Takeda, Nobuyuki Wada, Yukako Takahashi
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Patent number: 7390426Abstract: The present invention has an object to provide piezoelectric ceramics containing no lead, having a high Curie point, and further, having excellent piezoelectric properties, particularly large Qmax. The piezoelectric ceramics contain, as a main component, a bismuth layer-structured compound having (MII1-xLnx)Bi4Ti4O15 crystals (MII is an element selected from Sr, Ba, and Ca, Ln is an element selected from lanthanoids, and x is within a range of 0<x?0.5) and further contain, as secondary components, at least one of Mn oxide and Co oxide, and lanthanoid, wherein the lanthanoid being the secondary component is contained within a range of 0.02 to 0.12 wt % in terms of oxide thereof.Type: GrantFiled: March 19, 2004Date of Patent: June 24, 2008Assignee: TDK CorporationInventors: Takeo Tsukada, Tomohisa Azuma, Masakazu Hirose
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Patent number: 7381671Abstract: Disclosed is a ferroelectric ceramic composition that does not contain harmful lead and that have satisfactory sinterability, as well as a nonlinear optical element including the ferroelectric ceramic composition. The ferroelectric ceramic composition includes a main component represented by a general formula (Ba1-x-ySrxCay)Ag1-dNb5O15-d/2 and having a tungsten bronze structure; and auxiliary components represented by a general formula aMnO2+bSiO2 (wherein a and b each represent parts by weight with respect to 100 parts by weight of the main component), wherein x, y, a, b, and d meet expressions 0.1?x+y?0.8, a+b?5, and 0?d?0.6.Type: GrantFiled: November 17, 2004Date of Patent: June 3, 2008Assignee: Murata Manufacturing Co., Ltd.Inventor: Yoshifumi Ogiso
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Patent number: 7347983Abstract: Complex ceramic oxides of the general formula Mg2MM?O6+x where M=Rare metal ion or Yttrium or Lanthanum and M?=Sn, Sb, Zr, Hf, Ta, and Nb; and where ?0.5<x<0.5; having a defective pyrochlore structure are useful for active and passive electronic applications, as dielectrics, catalyst sensors, hosts for radioactive waste, etc. This process for the preparation of this class of compounds comprises: (i) mixing the compounds of magnesium, M and M? to get the molar ratio as 2:1:1 (ii) the mixture obtained in step (i) along with a wetting medium may be ball milled or mixed; (iii) the resultant slurry may be dried to obtain dry powder, (iv) the resultant mixture may be heated to a temperature in the range of 1000-1600° C. for the duration ranging from 3 hours to 50 hours, either in a single step or by taking out the reactant after heating, checking for the structure formation and heating again after grinding, if necessary.Type: GrantFiled: March 31, 2003Date of Patent: March 25, 2008Assignee: Council of Scientific & Industrial ResearchInventors: Jose James, Selvaraj Senthilkumar, Kallumelthekethil Vasudevan Pillaj Oonnikrishnan Nair
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Patent number: 7344654Abstract: A piezoelectric ceramic composition has the composition formula (Pb(a-b)Meb){(Ni(1-c)/3Znc/3Nb2d/3)zTixZr(1-x-z)}O3, wherein Me represents at least one element selected from the group consisting of Ba, Sr and Ca; a, b, d, and x satisfy the inequalities 0.975?a?0.998, 0?b?0.05, 1<d?1.3, and 0.39?x?0.47; and c and z are located in a region surrounded by lines connecting Point A (z=0.25, c=0.1), Point B (z=0.25, c=0.85), Point C (z=0.1, c=0.6), Point D (z=0.075, c=0.5), Point E (z=0.05, c=0.2), and Point F (z=0.05, c=0.1) or located on the lines in the z-c plane. Therefore, the piezoelectric ceramic composition is effective in achieving a large piezoelectric constant, a small dielectric constant, and a high Curie point. A piezoelectric actuator contains the piezoelectric ceramic composition.Type: GrantFiled: June 22, 2007Date of Patent: March 18, 2008Assignee: Murata Manufacturing Co., Ltd.Inventors: Koji Ogiso, Atsushi Yamamoto, Koichi Hayashi
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Publication number: 20080063881Abstract: Multilayer ceramic chip capacitors which satisfy COG requirements and which are compatible with reducing atmosphere sintering conditions so that non-noble metals such as nickel and nickel alloys thereof may be used for internal and external electrodes are made in accordance with the invention. The capacitors exhibit desirable dielectric properties (high capacitance, low dissipation factor, high insulation resistance), excellent performance on highly accelerated life testing, and very good resistance to dielectric breakdown. The dielectric layers comprise a strontium zirconate matrix doped with other metal oxides such as TiO2, MgO, B2O3, CaO, Al2O3, SiO2, and SrO in various combinations.Type: ApplicationFiled: September 13, 2006Publication date: March 13, 2008Inventors: Walter J. Symes, Mohammed H. Megherhi, Elisabeth W.J. Romer, Mike S.H. Chu, Wilibrordus J.L.M.J Coppens
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Patent number: 7341970Abstract: Compositions, and articles having low thermal expansion suitable for high temperature applications, such as automotive exhaust treatment and method of manufacturing such articles are disclosed.Type: GrantFiled: March 28, 2005Date of Patent: March 11, 2008Assignee: Corning IncorporatedInventors: Douglas Munroe Beall, Matthew John Dejneka, Christy Lynn Powell
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Publication number: 20080020921Abstract: The aforementioned modified ceramic formulations are conventional and made from a ceramic mold with an oxide mixture base in different proportions that have been modified by adding metals, metal mixtures and non-oxidizing metal alloys with fusion points of greater than 1100° C. and granulometry of less than 100 microns. This procedure consists of the application of the aforementioned formulations upon the ceramic part to be decorated, followed by the firing and subsequent grinding. Its use is for the ceramics industry.Type: ApplicationFiled: December 17, 2004Publication date: January 24, 2008Inventors: Victor Montins Nebot, Maria Jose Cabrera Ibanez
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Publication number: 20080020920Abstract: A ceramics sintered body improved in corrosion resistance to a molten metal and a method for producing such a ceramics sintered body. The ceramics sintered body includes boron nitride, titanium diboride, a calcium compound and titanium nitride and having a relative density of 92% or more, wherein the content of the calcium compound in terms of CaO is from 0.05 to 0.8% by weight, and a peak intensity by X-ray diffraction of the (200) plane derived from titanium nitride is from 0.06 to 0.15 relative to a peak intensity of the (002) plane of BN. Further, a method for producing a ceramics sintered body, which is applicable to the ceramics sintered body, and an exothermic body for metal vapor deposition constituted by the ceramics sintered body are also disclosed.Type: ApplicationFiled: December 10, 2004Publication date: January 24, 2008Inventors: Hiroshi Yokota, Fumio Tokunaga, Kentaro Iwamoto, Masamitu Kimura, Shoujiro Watanabe
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Patent number: 7319081Abstract: A thin film capacity element composition includes a first bismuth layer-structured compound having positive temperature characteristics, that a specific permittivity rises as the temperature rises, in at least a part of a predetermined temperature range and a second bismuth layer-structured compound having negative temperature characteristics, that a specific permittivity declines as a temperature rises, in at least a part of said predetermined temperature range at any mixing ratio; wherein the bismuth layer-structured compound is expressed by a composition formula of CaxSr(1-x)Bi4Ti4O15.Type: GrantFiled: November 18, 2003Date of Patent: January 15, 2008Assignee: TDK CorporationInventors: Yukio Sakashita, Hiroshi Funakubo
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Patent number: 7309450Abstract: Provided is a piezoelectric ceramic with a wider operating temperature range capable of obtaining a larger amount of displacement and being easily sintered, as well as being superior in terms of ultra-low emission, environmental friendliness and ecology. A piezoelectric substrate 1 comprises a composition including a perovskite-type oxide (Na1?x?y?zKxLiyAgz)(Nb1?wTaw)O3 and a tungsten bronze-type oxide M(Nb1?vTav)2O6 (M is an element of Group 2 in the long form of the periodic table of the elements). The values of x, y and z are preferably within a range of 0.1?x?0.9, 0?y?0.2, and 0?z?0.05, respectively. The content of the tungsten bronze-type oxide is preferably 5.3 mol % or less. Thereby, a higher Curie temperature and a larger amount of displacement can be obtained, and sintering can be more easily carried out.Type: GrantFiled: June 14, 2002Date of Patent: December 18, 2007Assignee: TDK CorporationInventors: Masaru Nanao, Yasuharu Miyauchi, Tamotsu Ishiyama, Masahito Furukawa, Shogo Murosawa, Yoshiko Gokita
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Patent number: 7303692Abstract: Piezoelectric ceramics of the formula Pb(1-z)Mz(Mg1/3Nb2/3)x(ZryTi1-y)1-xO3 where M can be either Sr or Ba or both, and x is between 0.3 and 0.6, y is between 0.2 and 0.5, and z is between 0.04 and 0.08. The piezoelectric ceramic is provided as a composite perovskite structure, and may additionally include materials or dopants such as: PbO, HfO2, TeO2, WO3, V2O5, CdO, Tm2O3, Sm2O3, Ni2O3, and MnO2. The piezoelectric ceramics can be used to fabricate piezoelectric elements for a wide variety of devices that can be fabricated to exhibit high power applications including miniaturized displacement elements, buzzers, transducers, ultrasonic sensors and ultrasonic generators, and the like.Type: GrantFiled: April 11, 2005Date of Patent: December 4, 2007Assignee: Piezotech, LLCInventor: De Liufu
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Patent number: 7304008Abstract: Thermochromic material comprising a thermochromic component and a binder, wherein the thermochromic component is crystal phases based on oxides of heavy metals of I, II, III, IV, V, VI, VII, VIII groups of the Periodic System selected from the group consisting of compounds of the following general formulae: (i) (Bi2O3)1-z(MxOy)z where z=0–0.Type: GrantFiled: May 15, 2001Date of Patent: December 4, 2007Assignee: EurokeraInventors: Anna Vasilievna Belykh, Alexandr Mikhailovich Efremov, Mikhail Dmitrievich Mikhailov
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Patent number: 7297322Abstract: A process for producing powders of metal compound containing oxygen including the steps of: feeding at least one material selected from a liquid material and a solution material obtained by dissolving solid ingredient in organic solvent via a liquid flow controller into a vaporizer; vaporizing the materials in the vaporizer; adding oxygen; heating; cooling; and crystallizing. Also disclosed is the product formed by this process, and apparatus used in performing the process. The process and the apparatus enable easily mass-producing fine powders of metal compound containing oxygen used as materials for optical crystals, nonlinear crystals or magneto-optical crystals with reasonable production cost.Type: GrantFiled: March 11, 2005Date of Patent: November 20, 2007Assignee: Japan Pionics Co., Ltd.Inventors: Yukichi Takamatsu, Koji Kiriyama, Akira Asano, Takafumi Ishii
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Patent number: 7297650Abstract: The production of low-loss, tunable composite ceramic materials with improved breakdown strengths is disclosed. The composite materials comprise ferroelectric perovskites such as barium strontium titanate or other ferroelectric perovskites combined with other phases such as low-loss silicate materials and/or other low-loss oxides. The composite materials are produced in sheet or tape form by methods such as tape casting. The composite tapes exhibit favorable tunability, low loss and tailorable dielectric properties, and can be used in various microwave devices.Type: GrantFiled: April 13, 2005Date of Patent: November 20, 2007Assignee: Paratek Microwave, Inc.Inventors: Luna H. Chiu, Xubai Zhang, Louise C. Sengupta
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Patent number: 7294597Abstract: A translucent ceramic principally contains a composition represented by the formula Ba{Tix1Mx2(Mg1-tZnt)y(Ta1-uNbu)z}vOw, wherein M is at least one selected from the group consisting of Sn, Zr, and Hf; w is a positive number for maintaining the electrical neutrality; x1+x2+y+z=1; 0.015?x1+x2?0.90; 0<x1?0.90; 0?x2?0.60; 1.60?z/y?2.40; 1.00?v?1.05; 0<t<1; and 0?u?1. The translucent ceramic has high linear transmittance over a wide wavelength range and a large refractive index, is controllable in refractive index and Abbe number in a wide range, and is not birefringent. Therefore, lenses (2) made of the translucent ceramic are suitable for optical pickups (9) and other devices that must be small-sized and thin.Type: GrantFiled: March 9, 2005Date of Patent: November 13, 2007Assignee: Murata Manufacturing Co., Ltd.Inventor: Yuji Kintaka
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Patent number: 7294164Abstract: This invention relates to an aluminum titanate body having a narrow pore size distribution as characterized by the relation (d50?d10)/d50 being less than 0.50 corresponding to a high degree of interconnected porosity. The body also preferably exhibits a low coefficient of thermal expansion of less than 15×10?7 C?1, high porosity of at least 38% by volume, and at least 0.10% by weight metal oxide, the metal being either yttrium, calcium, bismuth, a lanthanide metal or combinations of thereof. MOR is preferably at least 450 psi. Median pore diameter is preferably at least 8 microns. The inventive ceramic body is particularly useful as a wall-flow filter for a diesel exhaust. A method of fabrication is provided where the sintering temperature is preferably between 1375°-1550° C.Type: GrantFiled: July 28, 2005Date of Patent: November 13, 2007Assignee: Corning IncorporatedInventor: Gregory A. Merkel
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Patent number: 7291321Abstract: A perovskite catalyst is prepared using a ceramic sol-sol methodology comprising preparing slurry in water of an alkaline earth metal salt, a powdered metal salt and a powdered transition metal oxide, adding a polymeric binder to form a paste, drying and comminuting the paste into a powder and heating the powder with a temperature profile to calcination temperatures. In one embodiment the slurry is formed of titanium oxide with barium carbonate and tin chloride in deionized water, and more specifically by a mixture according to Ba (1-0.05x)+TiO2+SnCl2(0.05x) where x is in moles. The perovskite catalyst is preferably used in a process for oxidative coupling of methane. Catalyst performance is enhanced through the addition of halides to the feed gas in the reaction.Type: GrantFiled: April 28, 2004Date of Patent: November 6, 2007Assignee: HRD Corp.Inventors: Ebrahim Bagherzadeh, Abbas Hassan, Aziz Hassan
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Patent number: 7276462Abstract: Provided is a dielectric composition which, when applied to an electron emitter, enables suppression of reduction of electron emission quantity with passage of time. The dielectric composition contains, as a primary component, a PMN-PZ-PT ternary solid solution composition represented by the following formula PbxBip(Mgy/3Nb2/3)aTib-zMzZrcO3 [wherein x, p, and y satisfy the following relations: 0.85?x?1.05, 0.02?p?0.1, and 0.8?y?1.0; a, b, and c are decimal numbers falling within a region formed by connecting the following five points (0.550, 0.425, 0.025), (0.550, 0.150, 0.300), (0.100, 0.150, 0.750), (0.100, 0.525, 0.375), and (0.375, 0.425, 0.200); z satisfies the following relation: 0.02?z?0.10; and M is at least one element selected from among Nb, Ta, Mo, and W], and contains Ni in an amount of 0.05 to 2.0 wt. % as reduced to NiO.Type: GrantFiled: August 23, 2005Date of Patent: October 2, 2007Assignee: NGK Insulators, Ltd.Inventors: Hirofumi Yamaguchi, Kei Sato, Toshikatsu Kashiwaya
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Patent number: 7247590Abstract: The composite dielectric of the present invention contains an aromatic liquid crystal polyester and a dielectric ceramic powder arranged in the aromatic liquid crystal polyester, wherein the dielectric ceramic powder exhibits a Q value greater than 650 at a frequency of 1 GHz by perturbation. A wiring board comprising a composite dielectric sheet made of a composite dielectric having such a characteristic exhibits a high dielectric constant and a low dielectric dissipation factor, thereby yielding less transmission loss, and thus can favorably be used in electronic instruments driven in high-frequency regions.Type: GrantFiled: July 1, 2004Date of Patent: July 24, 2007Assignee: TDK CorporationInventors: Kenichi Kawabata, Takaaki Morita
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Patent number: 7203055Abstract: Disclosed herein is a method of manufacturing a multilayered ceramic capacitor by a spin coating process, and a multilayered ceramic capacitor obtained by the above method. The method of the current invention provides a plurality of dielectric layers formed by spin coating, in which the process of coating the dielectric layer and the process of printing the inner electrode can be provided as a single process. Therefore, the thickness of the dielectric layer is easily controlled while the dielectric layer is formed to be thin. Further, since the dielectric layers and the inner electrodes are formed successively, the processes of separating and layering the dielectric layers, and the process of compressing the ceramic multilayered body can be omitted. Thereby, the ceramic multilayered body need not be compressed, and thus, a pillowing phenomenon does not occur in the multilayered ceramic capacitor.Type: GrantFiled: December 15, 2004Date of Patent: April 10, 2007Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Hyo Soon Shin, Seung Hyun Ra, Yong Suk Kim, Hyoung Ho Kim, Ho Sung Choo, Jung Woo Lee
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Patent number: 7172985Abstract: A dielectric ceramic, and capacitor with the ceramic, wherein the ceramic has: about 94–99.9 wt % a first component defined by Formula 1; [(Ca1-xSrx)O]m(Zr1-yTiy)O2Formula 1 wherein: x is no more than about 0.6; and y is no more than about 0.1; and m is at least about 0.85 to no more than about 1.15; and about 0.1–5 wt % a secondary component defined by Formula 2; aSiO2-b[?B2O3-(1??)Li2O]-cAOFormula 2 wherein: a, b and c are selected to lie within the region defined by points A(a=15, b=0, c=85), B(a=70, b=0, c=30), C(a=0, b=70, c=30) and D(a=0, b=15, c=85) of a ternary diagram wherein a is mole percent SiO2; b is mole percent ?B2O3-(1??)Li2O; and c is mole percent AO and a+b+c=100 including the lines BC, CD and AD but excluding the line AB; ? is 0 to 1; A is selected from Mg, Ca, Sr, Ba or a combination thereof; and 0–2 wt % MnO2.Type: GrantFiled: June 7, 2005Date of Patent: February 6, 2007Assignee: Kemet Electronics CorporationInventors: Pascal G. Pinceloup, James J. Beeson
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Patent number: 7172984Abstract: A ceramic fuse housing is provided for surface mount circuit protectors, wherein a selectively destructible fuse is at least partially retained within the fuse housing. The fuse housing being formed of between 80% to 90% alumina and 20% to 10% zirconia, wherein 5% to 25% of the zirconia is in a tetragonal phase.Type: GrantFiled: June 17, 2004Date of Patent: February 6, 2007Assignee: Heany Industies, Inc.Inventors: S. Scott Zolnier, Charles E. Aldridge, Clifford W. Rabidoux, Peter R. Mundt
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Patent number: 7157396Abstract: A method of production of a reduction resistant dielectric ceramic composition having a superior low frequency dielectric characteristic and further improved in accelerated lifetime of insulation resistance, specifically a method of production of a dielectric ceramic composition containing a main component including a dielectric oxide of a specific composition, a first subcomponent including a V oxide, a second subcomponent containing an Al oxide, a third subcomponent containing an Mn oxide, and a fourth subcomponent containing a specific sintering aid in a specific ratio, including a step of mixing at least part of the materials of the subcomponents excluding one or both of at least the material of the third subcomponent and material of the fourth subcomponent with the starting materials prepared for obtaining the material of the main component to prepare the pre-reaction material, a step of causing the prepared pre-reaction material to react to obtain a reacted material, and a step of mixing the materials oType: GrantFiled: November 22, 2004Date of Patent: January 2, 2007Assignee: TDK CorporationInventors: Yasuo Watanabe, Kenta Endoh, Wataru Takahara
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Patent number: 7151067Abstract: A porous catalyst layer containing mixed conducting oxide having substantially a perovskite structure and containing a first element selected from Co and Fe, and a second element selected from In, Sn and Y arranged in the B site in the perovskite structure is contiguous to a second surface (1a) of a selective oxygen-permeable dense continuous layer (1) containing mixed conducting oxide. A porous intermediate catalyst layer (3) containing mixed conducting oxide and at least one of Co, Fe, Mn and Pd is contiguous to a first layer (1b) of the dense continuous layer (1). A porous reactive catalyst layer (4) provided with a metal catalyst selected from at least one of Ni, Co, Ru, Rh, Pt, Pd, Ir and Re and a support is continguous to the porous intermediate catalyst layer (3) in a manner to sandwich between the dense continuous layer (1) and the porous reactive catalyst layer (4).Type: GrantFiled: October 11, 2002Date of Patent: December 19, 2006Assignees: Nippon Steel Corporation, Teikoku Oil Co., Ltd.Inventors: Tadashi Sakon, Wataru Ito, Hitoshi Dohnomae, Toru Nagai, Hideki Kurimura, Shouichi Kaganoi, Youhei Suzuki, Takashi Ito
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Patent number: 7119040Abstract: Most of the dielectric ceramic compositions consist of three or more different lead-based or non-lead ceramics. These materials and their solid solutions can give high dielectric constants (er>10000) but the disadvantage is large fluctuations in the dielectric constant with increasing or decreasing temperature. Most applications of these materials are therefore concentrated on the utilization of their dielectric constants at a specific temperature. This invention provides a dielectric composite of the general formula (x)[Pb(In1/2Nb1/2)O3]:(1?x)[Pb(Mg1/3Nb2/3)O3] having improved stability of dielectric constant in the working temperature range.Type: GrantFiled: July 26, 2004Date of Patent: October 10, 2006Assignee: The Hong Kong Polytechnic UniversityInventors: Karim Baba-Kishi-Zadeh, Cheuk-Wai Tai
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Patent number: 7105145Abstract: Ferroelectric metal oxide crystalline particles are produced by first producing nanoparticles of a ferroelectric metal oxide and dispersing the nanoparticles in a gas phase. Then, the nanoparticles are processed by heat treatment with the nanoparticles being maintained in the gas phase in a dispersed state. The nanoparticles may be produced by using a laser ablation method. The ferroelectric metal oxide may have a perovskite crystal structure.Type: GrantFiled: October 30, 2002Date of Patent: September 12, 2006Assignee: RIKENInventors: Kwang-Soo Seol, Kazuo Takeuchi, Takeshi Miyagawa, Yoshimichi Ohki
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Patent number: 7098160Abstract: A dielectric ceramics includes a main ingredient, and a supplemental ingredient in an amount of 0.05 to 2 wt % for the main ingredient. The main ingredient is expressed by xBiO3/2-yCaO-zNbO5/2 and is within a scope of a specified quadrilateral region in a ternary system diagram, and the supplemental ingredient is a glass composition including at least SiO2, Li2O and MO (M includes at least one of Ca, Sr and Ba). A ceramic electronic component is produced by co-firing a dielectric layer composed of the dielectric ceramics and a conductive layer mainly composed of silver, and has a low degradation in Q value and excellent microwave characteristics.Type: GrantFiled: August 6, 2004Date of Patent: August 29, 2006Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Hidenori Katsumura, Ryuichi Saito, Hiroshi Kagata
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Patent number: 7094720Abstract: A dielectric ceramic composition is provided which exhibits a high unloaded quality factor (Qu) and permits regulation of the relative dielectric constant (?r) and the temperature coefficient (?f) of resonance frequency (fo) within specific ranges in accordance with use or application of the composition. A dielectric resonator is also provided which includes a resonator main body formed from the composition. The dielectric ceramic composition contains, as metallic components, Ba, Zn, Nb, Ta, and Sb, and the amounts of the metallic components, as reduced to their oxides, satisfy the following relations expressed in mol %: 57.5?BaO?62.6; 16.0?ZnO?22.2; 0<Nb2O5?20.6; 0<Ta2O5?20.6; and 0<Sb2O3?5.9.Type: GrantFiled: March 24, 2003Date of Patent: August 22, 2006Assignee: NKG Spark Plug Co., Ltd.Inventors: Takashi Oba, Hisashi Koduka, Kazuhisa Itakura
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Patent number: 7090785Abstract: A perovskite compound of the formula, (Na1/2Bi1/2)1-xMx(Ti1-yM?y)O3±z, where M is one or more of Ca, Sr, Ba, Pb, Y, La, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb and Lu; and M? is one or more of Zr, Hf, Sn, Ge, Mg, Zn, Al, Sc, Ga, Nb, Mo, Sb, Ta, W, Cr, Mn, Fe, Co and Ni, and 0.01<x<0.3, and 0.01<y<0.3, and z<0.1 functions as an electromechanically active material. The material may possess electrostrictive or piezoelectric characteristics.Type: GrantFiled: August 5, 2003Date of Patent: August 15, 2006Assignee: Massachusetts Institute of TechnologyInventors: Yet-Ming Chiang, Sossity A. Sheets, Gregory W. Farrey, Nesbitt W. Hagood, IV, Andrey Soukhojak, Haifeng Wang