Halogen Containing Crystalline Phase (e.g., Fluormica, Etc.) Patents (Class 501/3)
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Patent number: 11781039Abstract: Solutions are disclosed for preventing the settling of an abrasive, while maintaining the polishing performance of a polishing composition. Solutions are disclosed for improving the redispersibility of an abrasive while maintaining the polishing performance. Polishing compositions for use in polishing a semiconductor substrate according to the present disclosure include an abrasive, a layered compound, and a dispersion medium.Type: GrantFiled: December 22, 2017Date of Patent: October 10, 2023Assignee: FUJIMI INCORPORATEDInventors: Tomoaki Ishibashi, Hiroki Kon
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Patent number: 11518707Abstract: A glass-ceramic comprising, in weight percent on an oxide basis, of 50 to 70% SiO2, 0 to 20% Al2O3, 12 to 23% MgO, 0 to 4% Li2O, 0 to 10% Na2O, 0 to 10% K2O, 0 to 5% ZrO2, and 2 to 12% F, wherein the predominant crystalline phase of said glass-ceramic is a trisilicic mica, a tetrasilicic mica, or a mica solid solution between trisilicic and tetrasilicic, and wherein the total of Na2O+Li2O is at least 2 wt. %; wherein the glass-ceramic can be ion-exchanged.Type: GrantFiled: March 18, 2020Date of Patent: December 6, 2022Assignee: CORNING INCORPORATEDInventors: George Halsey Beall, John Philip Finkeldey, Charlene Marie Smith
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Patent number: 11332405Abstract: A glass-ceramic includes SiO2 in a range of 40 mol. % to 80 mol. %; Al2O3 in a range of 5 mol. % to 20 mol. %; MgO in a range of 5 mol. % to 20 mol. %; and at least one of B2O3, ZnO, and TiO2, each in a range of 0 mol. % to 10 mol. %, such that the glass-ceramic further comprises a magnesium aluminosilicate crystalline phase at a concentration in a range of 5 wt. % to 80 wt. % of the glass-ceramic.Type: GrantFiled: July 9, 2019Date of Patent: May 17, 2022Assignee: CORNING INCORPORATEDInventors: George Halsey Beall, Heather Debra Boek, Ling Cai, Mark Owen Weller
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Patent number: 11225433Abstract: A sintered machinable glass-ceramic is provided. The machinable glass-ceramic is formed by mixing phyllosilicate material having a sheet structure, with a glass fit and firing the mixture at relatively low temperatures to sinter the phyllosilicate, while maintaining the sheet-like morphology of the phyllosilicate and its associated cleaving properties. The sintered machinable glass-ceramic can be machined with conventional metal working tools and includes the electrical properties of the phyllosilicate. Producing the sintered machinable glass-ceramic does not require the relatively high-temperature bulk nucleation and crystallization needed to form sheet phyllosilicate phases in situ.Type: GrantFiled: December 2, 2016Date of Patent: January 18, 2022Assignee: Ferro CorporationInventors: Srinivasan Sridharan, George E. Sakoske, John J. Maloney, Cody Gleason, Gregory R. Prinzbach, Bradford Smith, Chih Cheng Wang
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Patent number: 10889522Abstract: Disclosed are a wollastonite crystallized glass for an artificial tooth and a method for coloring same, the method enabling a production of a uniform shade without degrading the physical properties of a crystallized glass by means of simply adding a small amount of coloring additive powder when preparing the crystallized glass.Type: GrantFiled: October 27, 2016Date of Patent: January 12, 2021Assignee: SOONCHUNHYANG UNIVERSITY INDUSTRY ACADEMY COOPERATION FOUNDATIONInventors: Jae-Chul Bang, Si-Won Sung, Young-Joo Song, Seung-Bum Park
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Patent number: 10730791Abstract: Embodiments of a glass-based article including a first surface and a second surface opposing the first surface defining a thickness (t) of about 3 millimeters or less (e.g., about 1 millimeter or less), and a stress profile, wherein all points of the stress profile between a thickness range from about 0·t up to 0.3·t and from greater than 0.7·t, comprise a tangent that is less than about ?0.1 MPa/micrometers or greater than about 0.1 MPa/micrometers, are disclosed. In some embodiments, the glass-based article includes a non-zero metal oxide concentration that varies along at least a portion of the thickness (e.g., 0·t to about 0.3·t). In some embodiments, the concentration of metal oxide or alkali metal oxide decreases from the first surface to a point between the first surface and the second surface and increases from the point to the second surface. The concentration of the metal oxide may be about 0.05 mol % or greater or about 0.5 mol % or greater throughout the thickness.Type: GrantFiled: October 8, 2015Date of Patent: August 4, 2020Assignee: Corning IncorporatedInventors: Guangli Hu, Charlene Marie Smith, Zhongzhi Tang, Steven Alvin Tietje
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Patent number: 9771300Abstract: A white glass contains, in terms of mole percentage on the basis of the following oxides, from 50 to 80% of SiO2, from 0 to 10% of Al2O3, from 11 to 30% of MgO, from 0 to 15% of Na2O and from 0.5 to 15% of P2O5.Type: GrantFiled: January 23, 2015Date of Patent: September 26, 2017Assignee: ASAHI GLASS COMPANY, LIMITEDInventors: Takahiro Sakagami, Seiki Ohara, Junko Miyasaka, Hiroyuki Hijiya, Kazutaka Ono
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Patent number: 9327993Abstract: The present invention relates to a method for preparing nanoparticles at least partially consisting of rare earth fluoride, characterized in that said fluoride is produced, in a solution, from a salt of the corresponding rare earth element and from a charge-transfer complex of formula (I), where Ra, Rb, and Rc are as defined in claim 1.Type: GrantFiled: June 21, 2010Date of Patent: May 3, 2016Assignees: UNIVERSITE CLAUDE BERNARD LYON I, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventors: Frédéric Chaput, Cédric Desroches, Stéphane Parola
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Patent number: 9321695Abstract: The invention provides a method for manufacturing a glass-ceramic composite using natural raw material and waste glasses. The invention provides a method for manufacturing a white glass-ceramic composite using waste glass and a whitening agent. The invention also provides a method for manufacturing a colored glass-ceramic composite using waste glass, the whitening agent and a coloring agent.Type: GrantFiled: January 8, 2013Date of Patent: April 26, 2016Assignee: King Abdulaziz City for Science and Technology (KACST)Inventors: Mohammed A Binhussain, Paolo Colombo, Enrico Bernardo, Majed A Binmajed, Mauro Marangoni, Hamad H Atalasi, Amer M Alajmi
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Patent number: 8936732Abstract: A white light emitting glass-ceramic. The chemical formula of the glass-ceramic is aSiO2.bAl2O3.cNaF.dCeF3.nDyF3.mAg, wherein a, b, c, d, n and m are, by mol part, 25-50, 15-30, 10-30, 10-25, 0.01-1 and 0.01-1, respectively, and a+b+c+d-100. A method for producing said glass-ceramic is also provided. Silver ion is doped in the glass-ceramic in the form of silver particles by means of sintering and reduction annealing treatment, and thus the luminescence properties of rare earth ion is improved.Type: GrantFiled: July 22, 2010Date of Patent: January 20, 2015Assignee: Ocean's King Lighting Science & Technology Co., Ltd.Inventors: Mingjie Zhou, Wenbo Ma, Fangyi Weng
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Publication number: 20150004418Abstract: A bonded ceramic component which is resistant to reactive halogen-containing plasmas, said component comprising ceramic portions which are bonded together by a bonding material which includes an oxyfluoride glass-ceramic-comprising transition area between interfaces of the ceramic portions, where the transition area includes from at least 0.1 volume % amorphous phase up to about 50 volume % amorphous phase.Type: ApplicationFiled: September 8, 2014Publication date: January 1, 2015Applicant: Applied Materials, Inc.Inventors: Jennifer Y. Sun, Ren-Guan Duan, Kenneth S. Collins
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Patent number: 8298970Abstract: In one aspect the invention is directed to a machinable glass-ceramic having a high degree of crystallinity (greater than 50 Vol. %), high mechanical strength (MOR>150 MPa) In accordance with the invention, the machinable glass-ceramics described herein consists essentially of, in weight percent, 35-55% SiO2, 6-18% Al2O3, 12-27% MgO, 3-12% F, 5-25% SrO, 0-20% BaO and 1-7% K2O. The machinable glass-ceramics of the invention have a dielectric constant of <8 (typically being in the range of 6-8) at 25° C. and 1 KHz; a loss tangent of <0.002 at 25° C. and 1 MHz; a CTE in the range of 80-120×10?7/° C. in the temperature range of 25-300° C.; a Poisson's ration of approximately 0.25; and a porosity of 0%.Type: GrantFiled: September 7, 2011Date of Patent: October 30, 2012Assignee: Corning IncorporatedInventor: George Halsey Beall
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Patent number: 8263508Abstract: A phosphosilicate glass ceramic with nanoscale fluoroapatite and leucite crystals. The glass ceramic is very similar to natural tooth material in terms of its optical properties. The glass ceramic has a low linear thermal expansion coefficient and a low pressing temperature and is therefore particularly suitable for pressing on metal alloys to produce dental restoration.Type: GrantFiled: December 3, 2009Date of Patent: September 11, 2012Assignee: Ivoclar Vivadent AGInventors: Urs Bolle, Marcel Schweiger, Elke Apel, Wolfram Höland, Volker Rheinberger
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Patent number: 8133828Abstract: Glass-ceramic compositions exhibiting high reliability and tensile strength are described. The compositions can include crystal phases including roedderite and/or potassium fluorrichterite. The glass-ceramic compositions are bioactive, and can be used as components of a wide variety of biomedical devices such as dental restorations.Type: GrantFiled: May 13, 2009Date of Patent: March 13, 2012Assignee: The Ohio State University Research FoundationInventors: Isabelle L. Denry, Julie A. Holloway
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Publication number: 20110319253Abstract: In one aspect the invention is directed to a machinable glass-ceramic having a high degree of crystallinity (greater than 50 Vol. %), high mechanical strength (MOR>150 MPa) In accordance with the invention, the machinable glass-ceramics described herein consists essentially of, in weight percent, 35-55% SiO2, 6-18% Al2O3, 12-27% MgO, 3-12% F, 5-25% SrO, 0-20% BaO and 1-7% K2O. The machinable glass-ceramics of the invention have a dielectric constant of <8 (typically being in the range of 6-8) at 25° C. and 1 KHz; a loss tangent of <0.002 at 25° C. and 1 MHz; a CTE in the range of 80-120×10?7/° C. in the temperature range of 25-300° C.; a Poisson's ration of approximately 0.25; and a porosity of 0%.Type: ApplicationFiled: September 7, 2011Publication date: December 29, 2011Inventor: George Halsey Beall
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Patent number: 8048816Abstract: The invention relates to opaque, colored glass-ceramic articles and to the production of opaque, colored glass-ceramic articles which can be readily formed to a desired shape using standard metal-working tools. The glass-ceramic material used to make such articles contains mica crystals as the predominant phase. The desired color is obtained through the addition of a colorant system to the precursor glass. In a particular embodiment the invention is directed to a black glass-ceramic article, the black color being obtained by the addition of iron oxides in levels as high as 20 wt %, which can yield a glass-ceramic having an iron-rice mica phase and/or a glass ceramic having an iron-rich mica phase plus an iron oxide phase.Type: GrantFiled: April 20, 2009Date of Patent: November 1, 2011Assignee: Corning IncorporatedInventors: George Halsey Beall, Linda Ruth Pinckney, Steven Alvin Tietje
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Patent number: 8021999Abstract: In one aspect the invention is directed to a machinable glass-ceramic having a high degree of crystallinity (greater than 50 Vol. %), high mechanical strength (MOR>150 MPa) In accordance with the invention, the machinable glass-ceramics described herein consists essentially of, in weight percent, 35-55% SiO2, 6-18% Al2O3, 12-27% MgO, 3-12% F, 5-25% SrO, 0-20% BaO and 1-7% K2O. The machinable glass-ceramics of the invention have a dielectric constant of <8 (typically being in the range of 6-8) at 25° C. and 1 KHz; a loss tangent of <0.002 at 25° C. and 1 MHz; a CTE in the range of 80-120×10?7/° C. in the temperature range of 25-300° C.; a Poisson's ration of approximately 0.25; and a porosity of 0%.Type: GrantFiled: May 26, 2009Date of Patent: September 20, 2011Assignee: Corning IncorporatedInventor: George Halsey Beall
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Publication number: 20110092353Abstract: The invention relates glass ceramic articles suitable for use as electronic device housing or enclosures which comprise a glass-ceramic material. Particularly, a glass-ceramic article housing/enclosure comprising a glass-ceramic material exhibiting both radio and microwave frequency transparency, as defined by a loss tangent of less than 0.5 and at a frequency range of between 15 MHz to 3.0 GHz, a fracture toughness of greater than 1.5 MPa·m1/2, an equibiaxial flexural strength (ROR strength) of greater than 100 MPa, a Knoop hardness of at least 400 kg/mm2, a thermal conductivity of less than 4 W/m° C. and a porosity of less than 0.1%.Type: ApplicationFiled: July 2, 2009Publication date: April 21, 2011Applicant: CORNING INCORPORATEDInventors: Jaymin Amin, Lorrie Foley Beall, George Halsey Beall, Matthew John Dejneka, Linda Ruth Pinckney, Katherine Rose Rossington
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Publication number: 20110021336Abstract: A phosphosilicate glass ceramic with nanoscale fluoroapatite and leucite crystals. The glass ceramic is very similar to natural tooth material in terms of its optical properties. The glass ceramic has a low linear thermal expansion coefficient and a low pressing temperature and is therefore particularly suitable for pressing on metal alloys to produce dental restoration.Type: ApplicationFiled: December 3, 2009Publication date: January 27, 2011Applicant: Ivoclar Vivadent AGInventors: Urs Bolle, Marcel Schweiger, Elke Apel, Wolfram Höland, Volker Rheinberger
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Patent number: 7867933Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.Type: GrantFiled: October 17, 2008Date of Patent: January 11, 2011Assignee: Ivoclar Vivadent AGInventors: Elke Apel, Wolfram Holand, Marcel Schweiger, Christian Ritzberger, Harald Burke, Volker M. Rheinberger
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Publication number: 20090318277Abstract: In one aspect the invention is directed to a machinable glass-ceramic having a high degree of crystallinity (greater than 50 Vol. %), high mechanical strength (MOR>150 MPa) In accordance with the invention, the machinable glass-ceramics described herein consists essentially of, in weight percent, 35-55% SiO2, 6-18% Al2O3, 12-27% MgO, 3-12% F, 5-25% SrO, 0-20% BaO and 1-7% K2O. The machinable glass-ceramics of the invention have a dielectric constant of <8 (typically being in the range of 6-8) at 25° C. and 1 KHz; a loss tangent of <0.002 at 25° C. and 1 MHz; a CTE in the range of 80-120×10?7/° C. in the temperature range of 25-300° C.; a Poisson's ration of approximately 0.25; and a porosity of 0%.Type: ApplicationFiled: May 26, 2009Publication date: December 24, 2009Inventor: George Halsey Beall
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Publication number: 20090274869Abstract: The invention relates to opaque, colored glass-ceramic articles and to the production of opaque, colored glass-ceramic articles which can be readily formed to a desired shape using standard metal-working tools. The glass-ceramic material used to make such articles contains mica crystals as the predominant phase. The desired color is obtained through the addition of a colorant system to the precursor glass. In a particular embodiment the invention is directed to a black glass-ceramic article, the black color being obtained by the addition of iron oxides in levels as high as 20 wt %, which can yield a glass-ceramic having an iron-rice mica phase and/or a glass ceramic having an iron-rich mica phase plus an iron oxide phase.Type: ApplicationFiled: April 20, 2009Publication date: November 5, 2009Inventors: George Halsey Beall, Linda Ruth Pinckney, Steven Alvin Tietje
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Patent number: 7547652Abstract: The invention relates to vitreous compositions, in particular of the vitroceramic type, transparent to infrared, production and uses thereof. Said compositions comprise in mol. %: Ge 5-40, Ga<1, S+Se 40-85, Sb+As 4-40, MX 2-25, Ln 0-6, adjuncts 0-30, where M=at least one alkaline metal, selected from Rb, Cs, Na, K and Zn, X=at least one atom of chlorine, bromine or iodine, Ln=at least one rare earth and adjunct=at least one additive comprising at least one metal and/or at least one metal salt with the sum of all molar percentages of the components present in said composition being 100.Type: GrantFiled: July 5, 2004Date of Patent: June 16, 2009Assignees: Centre National De La Recherche Scientifique, Universite Rennes 1Inventors: Xianghua Zhang, Jacques Lucas, Hongli Ma, Jean-Luc Adam
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Publication number: 20080254964Abstract: Object: To provide a machineable glass ceramic which has excellent machineable properties and various other physical property values. Solution: A machineable glass ceramic comprises a glass matrix having substantially only fluorine phlogopite crystals dispersed therein, wherein an average dimension in the directions of major axes of said fluorine phlogopite crystals is less than 5 ?m. The machineable glass ceramic constituted as above is produced by forming and degreasing glassy powder containing at least Si, Al, Mg, K, F and O, and thereafter by sintering the same at temperatures of 1000-1100 degrees centigrade.Type: ApplicationFiled: December 21, 2007Publication date: October 16, 2008Applicant: Toto Ltd.Inventors: Shogo Shimada, Takayuki Ide, Masakatsu Kiyohara, Akio Matsumoto
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Patent number: 7306845Abstract: Nanoscale particles, particle coatings/particle arrays and corresponding consolidated materials are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.Type: GrantFiled: October 29, 2004Date of Patent: December 11, 2007Assignee: NeoPhotonics CorporationInventors: Craig R. Horne, Pierre J. DeMascarel, Christian C. Honeker, Benjamin Chaloner-Gill, Herman A. Lopez, Xiangxin Bi, Ronald J. Mosso, William E. McGovern, James T. Gardner, Sujeet Kumar, James A. Gilliam, Vince Pham, Eric Euvrard, Shivkumar Chiruvolu, Jesse Jur
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Patent number: 7172649Abstract: The disclosure relates to a leucite glass ceramic doped with nanoscale metal oxide, to a doped leucite glass ceramic powder suitable for its production, to a method for producing the doped leucite glass ceramic, to its use as dental material, to a dental product containing it and to the use of the nanoscale metal oxide powders for the production of the doped glass ceramic or of the doped leucite glass ceramic powder.Type: GrantFiled: December 30, 2003Date of Patent: February 6, 2007Assignees: Chemichl AGInventors: Thomas Conrad, Gerhard Meyer
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Patent number: 6984261Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.Type: GrantFiled: February 5, 2003Date of Patent: January 10, 2006Assignee: 3M Innovative Properties CompanyInventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
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Patent number: 6849334Abstract: Nanoscale particles, particle coatings/particle arrays and corresponding consolidated materials are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.Type: GrantFiled: March 15, 2002Date of Patent: February 1, 2005Assignee: NeoPhotonics CorporationInventors: Craig R. Horne, Pierre J. DeMascarel, Christian C. Honeker, Benjamin Chaloner-Gill, Herman A. Lopez, Xiangxin Bi, Ronald J. Mosso, William E. McGovern, James T. Gardner, Sujeet Kumar, James A. Gilliam, Vince Pham, Eric Euvrard, Shivkumar Chiruvolu, Jesse Jur
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Patent number: 6797048Abstract: The present invention provides a method for preparing a glass-ceramic containing leucite crystals, comprising the steps of: mixing (1) a glassy material comprising 53 to 65 wt. % of SiO2, 13 to 23 wt. % of Al2O3, 9 to 20 wt. % of K2O and 6 to 12 wt. % of Na2O and (2) synthetic leucite seed crystals comprising 53 to 64 wt. % of SiO2, 19 to 27 wt. % of Al2O3 and 17 to 25 wt. % of K2O, and heat-treating the mixture at 750 to 950° C. for 1 to 5 hours; and a dental porcelain powder and a metal-ceramic restoration both comprising a glass-ceramic prepared by the method. The porcelain comprising the glass-ceramic prepared by the method is substantially free of opacification and decrease in the coefficient of thermal expansion, during fusion-bonding to a metal frame.Type: GrantFiled: July 3, 2002Date of Patent: September 28, 2004Assignee: Yamamoto Precious Metal Co., Ltd.Inventors: Takeshi Hoshikawa, Masatoshi Yamazoe, Hirohisa Yamamoto, Teruo Anraku
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Patent number: 6683714Abstract: A birefringence minimizing fluoride crystal vacuum ultraviolet (“VUV”) optical lithography lens element is provided for use with lithography wavelengths<230 nm. The VUV lithography lens element has an optical axis encompassed by a lens perimeter with the fluoride crystal lens having a variation in crystallographic orientation direction which tilts away from the optical center axis towards the lens perimeter to provide minimal birefringence. The invention includes a birefringence minimizing fluoride crystal optical lithography lens blank with a variation in crystallographic orientation direction across the blank.Type: GrantFiled: October 31, 2001Date of Patent: January 27, 2004Assignee: Corning IncorporatedInventors: Gautam Meda, Michael Rivera, Michael W. Price
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Patent number: 6649326Abstract: The invention provides a UV below 200 nm lithography method. The invention includes providing a below 200 nm radiation source for producing <200-nm light, providing a plurality of mixed cubic fluoride crystal optical elements, with the fluoride crystals comprised of a combination of alkaline earth cations having different optical polarizabilities such as to produce an overall isotropic polarizability which minimizes the fluoride crystal spatial dispersion below 200 nm, transmitting <200-nm light through the cubic fluoride crystal optical elements, forming a lithography pattern with the light, reducing the lithography pattern and projecting the lithography pattern with the cubic fluoride crystal optical elements onto a UV radiation sensitive lithography printing medium to form a printed lithographic pattern. The invention includes making the mixed fluoride crystals and forming optical element therefrom.Type: GrantFiled: June 21, 2002Date of Patent: November 18, 2003Assignee: Corning IncorporatedInventors: Douglas C. Allan, Nicholas F. Borrelli, Charlene M. Smith, Robert W. Sparrow
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Patent number: 6645285Abstract: Micaceous glass-ceramics are useful in the fabrication of single and multi-unit dental restorations including but not limited to orthodontic appliances, bridges, space maintainers, tooth replacement appliances, splints, crowns, partial crowns, dentures, posts, teeth, jackets, inlays, onlays, facing, veneers, facets, implants, abutments, cylinders, and connectors by machining the glass-ceramic using CAM/CAM devices. The micaceous glass-ceramics are provided in a plurality of shades and colors to adequately match the colors and shades of teeth found in 95% or more of the human population.Type: GrantFiled: February 4, 2002Date of Patent: November 11, 2003Assignee: Pentron CorporationInventors: Dmitri Brodkin, Carlino Panzera, Paul Panzera
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Patent number: 6635591Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.Type: GrantFiled: April 2, 2001Date of Patent: October 21, 2003Assignee: Minolta Co., Ltd.Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
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Patent number: 6620747Abstract: A low-temperature-sintering apatite glass ceramic is described which is characterized by a high chemical stability, a low coefficient of expansion as well as high translucency and which is particularly suitable on its own or together with glasses or other glass ceramics as coating or veneering material for ceramic dental restorations.Type: GrantFiled: June 22, 2001Date of Patent: September 16, 2003Assignee: Ivoclar Vivadent AGInventors: Marcel Schweiger, Volker Rheinberger, Wolfram Höland
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Publication number: 20030091934Abstract: The invention provides a UV below 200 mm lithography method. The invention includes providing a below 200 mm radiation source for producing <200-nm light, providing a plurality of mixed cubic flouride crystal optical elements, with the fluoride crystals comprised of a combination of alkaline earth cations having different optical polarizabilities such as to produce an overall isotropic polarizability which minimizes the fluoride crystal spatial dispersion below 200 nm, transmitting <200-nm light through the cubic fluoride crystal optical elements, forming a lithography pattern with the light, reducing the litographic patter and projecting the lithography pattern with the cubic fluoride crystal optical elements onto a UV radiation sensitive lithography printing medium to form a printed lithographic pattern. The invention includes making the mixed fluoride crystals and forming optical element thereform.Type: ApplicationFiled: June 21, 2002Publication date: May 15, 2003Inventors: Douglas C. Allan, Nicholas F. Borrelli, Charlene M. Smith, Robert W. Sparrow
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Publication number: 20020193230Abstract: The invention refers to a material which is chemically long-term stable in a neutral or slightly acid environment and which can be used both as bioactive bone replacement material, e.g. in the form of a coating applied onto metallic prosthesis sticks by thermal spraying, and as substrate material in biotechnology, e.g. in the form of a ceramic sheet. According to the invention, said material comprises 15-45% by weight CaO, 40-45% by weight P2O5, 10-40% by weight ZrO2 and fluoride, said material further comprises two crystalline phases being apatite and calcium zirconium phosphate, and a secondary glass phase. Said material has a very high chemical long-term stability, compared to known materials which can also be produced by means of a melting process.Type: ApplicationFiled: June 13, 2002Publication date: December 19, 2002Inventors: Georg Berger, Ute Ploska
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Patent number: 6479417Abstract: The present invention relates to transparent microspheres (i.e., beads) that impart yellow color to retroreflected light. The microsphere preferably comprise titania plus alumina, zirconia, and/or silica and iron oxide, manganese oxide, or mixtures thereof. More particularly, the present invention relates to fused microspheres that impart yellow color to retroreflected light having both transparency and mechanical properties suitable, for example, for lens elements in retroreflective articles.Type: GrantFiled: January 18, 2001Date of Patent: November 12, 2002Assignee: 3M Innovative Properties CompanyInventors: Matthew H. Frey, Charles J. Studiner, III, Kenton D. Budd, Toshihro Kasai, Stephen B. Roscoe, Chikafumi Yokoyama, John E. Bailey
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Publication number: 20020157570Abstract: Micaceous glass-ceramics are useful in the fabrication of single and multi-unit dental restorations including but not limited to orthodontic appliances, bridges, space maintainers, tooth replacement appliances, splints, crowns, partial crowns, dentures, posts, teeth, jackets, inlays, onlays, facing, veneers, facets, implants, abutments, cylinders, and connectors by machining the glass-ceramic using CAM/CAM devices. The micaceous glass-ceramics are provided in a plurality of shades and colors to adequately match the colors and shades of teeth found in 95% or more of the human population.Type: ApplicationFiled: February 4, 2002Publication date: October 31, 2002Inventors: Dmitri Brodkin, Carlino Panzera, Paul Panzera
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Patent number: 6461988Abstract: Transparent solid microspheres that contain titania plus alumina, zirconia, and/or silica in a total content of at least about 75% by weight, based on the total weight of the solid microspheres, wherein the total content of alumina, zirconia, and titania is greater than the content of silica.Type: GrantFiled: March 30, 2001Date of Patent: October 8, 2002Assignee: 3M Innovative Properties CompanyInventors: Kenton D. Budd, Toshihiro Kasai, Stephen B. Roscoe, Chikafumi Yokoyama, John E. Bailey
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Publication number: 20020132719Abstract: The invention provides a high quality identifiable fluoride crystalline optical microlithography lens element blank for formation into an lens element of a microlithography system. The highly qualified fluoride crystalline characteristics of the fluoride optical lithography lens blank ensure its beneficial performance in the demanding microlithography manufacturing regime which utilizes high energy short wavelength ultraviolet laser sources. The fluoride crystalline optical lithography lens element blanks are comprised of multiple adjoining abutting crystalline subgrains with low boundary angles.Type: ApplicationFiled: April 11, 2002Publication date: September 19, 2002Inventors: Alexandre M. Mayolet, Michael A. Pell
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Patent number: 6395657Abstract: The invention provides a high quality identifiable fluoride crystalline optical microlithography lens element blank for formation into an lens element of a microlithography system. The highly qualified fluoride crystalline characteristics of the fluoride optical lithography lens blank ensure its beneficial performance in the demanding microlithography manufacturing regime which utilizes high energy short wavelength ultraviolet laser sources. The fluoride crystalline optical lithography lens element blanks are comprised of multiple adjoining abutting crystalline subgrains with low boundary angles.Type: GrantFiled: April 16, 2001Date of Patent: May 28, 2002Assignee: Corning IncorporatedInventors: Alexandre M. Mayolet, Michael A. Pell
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Patent number: 6352949Abstract: A glass ceramic material for storing energy of X-rays and releasing said energy by photo-stimulation comprising a fluoride glass matrix containing micro-crystalline particles, said particles having an average particle size, d, so that d<2 &mgr;m and said glass ceramic shows in a XRD spectrum a continuous spectrum of said glass matrix and discrete peaks superimposed on said continuous spectrum. Said glass matrix contains preferably zirconium ions and ions selected from the group consisting of alkali ions and alkaline earth ions, at least 5 mole % of the fluoride ions is replaced by bromide and/or chloride ions and at least 0.01 mole % of cations selected from the group consisting of transition metal ions, rare earth metal ions, In+, Ga+, Tl+, and Pb2+ is present.Type: GrantFiled: June 15, 2000Date of Patent: March 5, 2002Inventors: Peter Willems, Johann-Martin Spaeth, Stefan Schweizer, Andrew Edgar, Luc Struye, Paul Leblans
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Publication number: 20020022563Abstract: A low-temperature-sintering apatite glass ceramic is described which is characterized by a high chemical stability, a low coefficient of expansion as well as high translucency and which is particularly suitable on its own or together with glasses or other glass ceramics as coating or veneering material for ceramic dental restorations.Type: ApplicationFiled: June 22, 2001Publication date: February 21, 2002Applicant: Ivoclar Vivadent AGInventors: Marcel Schweiger, Volker Rheinberger, Wolfram Holand
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Patent number: 6306784Abstract: Alkali silicate glasses are described which, in view of their good chemical stability and their optical properties and processing properties, are particularly suitable as a coating or veneering material for ceramic dental frameworks and hence for the production of all-ceramic dental restorations such as crowns or bridges.Type: GrantFiled: June 9, 2000Date of Patent: October 23, 2001Assignee: Ivoclar AGInventors: Helga Drescher, Martin Frank, Volker Rheinberger, Wolfram Höland
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Patent number: 6280863Abstract: An apatite glass ceramic is described which is characterized by good chemical stability, a low expansion coefficient and high translucence, and is particularly suitable, by itself or together with glasses or other glass ceramics, as a veneering material for ceramic dental restorations.Type: GrantFiled: June 12, 1998Date of Patent: August 28, 2001Assignee: Ivoclar AGInventors: Martin Frank, Helga Drescher, Wolfram Höland, Volker Rheinberger
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Patent number: 6281151Abstract: The present invention relates to a transparent glass-ceramic material which includes a glass matrix and a crystalline phase of lanthanum fluoride crystals in the glass matrix, where the transparent glass-ceramic material contains no silica. The present invention further relates to a method of producing the transparent glass-ceramic material.Type: GrantFiled: January 24, 2000Date of Patent: August 28, 2001Assignee: Corning IncorporatedInventor: Paul A. Tick
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Patent number: 6245700Abstract: Transparent solid microspheres that contain titania plus alumina, zirconia, and/or silica in a total content of at least about 75% by weight, based on the total weight of the solid microspheres, wherein the total content of alumina, zirconia, and titania is greater than the content of silica.Type: GrantFiled: July 27, 1999Date of Patent: June 12, 2001Assignee: 3M Innovative Properties CompanyInventors: Kenton D. Budd, Toshihiro Kasai, Stephen B. Roscoe, Chikafumi Yokoyama, John E. Bailey
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Patent number: 6200137Abstract: An apatite glass ceramic is described which is characterized by good chemical stability, a low expansion coefficient and high translucence, and is particularly suitable, by itself or together with glasses or other glass ceramics, as a veneering material for ceramic dental restorations.Type: GrantFiled: June 12, 1998Date of Patent: March 13, 2001Assignee: Ivoclar AGInventors: Wolfram Höland, Martin Frank, Helga Drescher, Volker Rheinberger
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Patent number: 6136909Abstract: A method for producing a conductive polyaniline/layered inorganic nanocomposite having a conductivity greater than 10.sup.-1 S/cm is disclosed. The method comprises the steps of: (a) forming a reaction mixture comprising water, an aniline monomer, a protonic acid, an oxidizing agent, and a layered silicate which has been subjected to an acid treatment or is intercalated with polyethylene glycol; and (b) subjecting said reaction mixture to oxidative polymerization to form a conductive polymeric nanocomposite having said layered silicate dispersed in a polymeric matrix of polyaniline.Type: GrantFiled: June 17, 1999Date of Patent: October 24, 2000Assignee: Industrial Technology Research InstituteInventors: Chien-Shiun Liao, Li Kuei Lin
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Patent number: 6130178Abstract: The present invention is directed at a glass-ceramic having high strength and toughness and containing miserite as a predominant crystal phase. The glass-ceramic has a composition calculated in terms of a weight percent on the oxide basis comprising 40-68% SiO.sub.2, 12-35% CaO, 8-20% CaF.sub.2, 4-10.5% K.sub.2 O, 0-5% Al.sub.2 O.sub.3, 0-5% B.sub.2 O.sub.3, 0-15% P.sub.2 O.sub.5, 0-4% R.sub.2 O.sub.3, wherein R represents Y.sup.3+ and rare earth metals in the lanthanide series, and 0-5% of optional constituents selected from the group consisting of MgO, SrO, BaO, Na.sub.2 O, Nb.sub.2 O.sub.5, ZrO.sub.2, and ZnO, and 0-10% of optional constituents selected from the group consisting of Nb.sub.2 O.sub.5 and TiO.sub.2 and 0-2% Li.sub.2 O as an optional constituent. The glass-ceramic may contain secondary phases of cristobalite (SiO.sub.2), fluorite (CaF.sub.2), xonotlite (Ca.sub.6 Si.sub.6 O.sub.17 F.sub.2), and fluorapatite (Ca.sub.5 (PO.sub.4).sub.Type: GrantFiled: April 5, 1999Date of Patent: October 10, 2000Assignee: Corning IncorporatedInventors: Ronald L. Andrus, George H. Beall, Linda R. Pinckney, Christine C. Wolcott