Abstract: Compositions useful as bone fillers or dental composites are provided which may include a sterilizing agent.

Abstract: Compositions useful as bone fillers or dental composites are provided which may include a sterilizing agent.

Abstract: Disclosed is a sealing glass composition that turns, when fired at a temperature of 900-1150° C., into a crystallized glass having a thermal expansion coefficient of 80-110×10?7/° C. in the range of 50-850° C. The composition is substantially free of both boron oxide and barium oxide, and comprises SiO2: 43-53 mol %, CaO: 12-33 mol %, MgO: 12-33 mol %, La2O3: 1-7 mol %, and ZnO: 0-4.5 mol %.

Abstract: Transparent, dyed cook top or hob with improved color display capability, consisting of a glass ceramic with high quartz mixed crystals as predominant crystal phase, whereby the glass-ceramic contains none of the chemical refining agents arsenic oxide and/or antimony, with transmission values of greater than 0.1% in the range of the visible light within the entire wavelength range greater than 450 nm, a light transmission in the visible of 0.8-2.5% and a transmission in the infrared at 1600 nm of 45-85%.

Abstract: A lithium-containing, transparent glass-ceramic material is provided. The material has low thermal expansion and has an amorphous, lithium-depleted, vitreous surface zone. The zone is at least 50 nm thick on all sides and encloses a crystalline interior, which has high transmission. The material includes a transition region connecting the zone and the interior.

Abstract: Methods for producing Polymer Derived Ceramic (PDCs) particles and bulk ceramic components and compositions from partially cured gelatinous polymer ceramic precursors and unique bulk composite PDC ceramics and unique PDC ceramic particles in size and composition. Methods of making fully dense PDCs over approximately 2 ?m to approximately 300 mm in diameter for applications such as but not limited to proppants, hybrid ball bearings, catalysts, and the like. Methods can include emulsion processes or spray processes to produce PDCs. The ceramic particles and compositions can be shaped and chemically and materially augmented with enhancement particles in the liquid resin or gelatinous polymeric state before being pyrolyzed into ceramic components. The resulting ceramic components have a very smooth surface and are fully dense, not porous as ceramic components from the sol-gel process.

Abstract: Universal glasses are provided which have the composition, in percent by weight on an oxide basis, 65-75 of SiO2, 11-18 of Al2O3, 5-10 of MgO, 5-10 of CaO, which are free of B2O3, SrO, BaO, CeO2 and PbO and have a hydrolytic resistance in the first class in accordance with DIN ISO 719, an acid resistance at least in the second class in accordance with DIN 12116 and an alkali resistance at least in the second class in accordance with DIN ISO 695.

Abstract: A vitreous or glass-ceramic jointing material, which has a coefficient of thermal expansion ?(20-750) of ?7·10?6 K?1 and is free of BaO and SrO except for at the most impurities and is suitable for producing joint connections between chromium-containing alloys or chromium-containing steels.

Abstract: The invention relates to a glass ceramic comprising article, wherein the integral, non-post-processed and non-reworked glass ceramic comprising article comprises at least three different types of microstructures. The microstructures differ in the number and/or size of the crystallites contained per unit volume, and/or in the composition of the crystallites, and/or in the composition of the residual glass phases. The different microstructures are characterized by different relative ion content profiles across a cross-section perpendicular to the transition areas. The relative ion content profiles are determined from intensities which are determined using secondary ion mass spectrometry, and each of the three different types of microstructures preferably has different intensity plateaus for individual ions, wherein the individual ions are components of the main crystal phases.

Abstract: The invention relates to a powder comprising more than 70% of glass-ceramic and/or refractory particles, a particle of said powder being classed in the fraction called “matrix” or in the fraction called “aggregate” according to whether it is smaller than, or equal to 100 ?m, or bigger than 100 ?m, respectively, the aggregate, representing more than 60% of the powder, comprising: more than 40% of particles of a glass-ceramic material having a crystallization rate of higher than 50% and a thermal expansion value, measured at 700° C., of less than 0.3%, called “glass-ceramic grains”; less than 35% of particles of a refractory material different from a glass-ceramic material, called “refractory grains”, the quantity of refractory grains being higher than 10% if the aggregate comprises more than 40% of glass-ceramic grains having a thermal expansion value, measured at 700° C., of less than or equal to 0.

Abstract: A white light emitting glass-ceramic. The chemical formula of the glass-ceramic is aSiO2.bAl2O3.cNaF.dCeF3.nDyF3.mAg, wherein a, b, c, d, n and m are, by mol part, 25-50, 15-30, 10-30, 10-25, 0.01-1 and 0.01-1, respectively, and a+b+c+d-100. A method for producing said glass-ceramic is also provided. Silver ion is doped in the glass-ceramic in the form of silver particles by means of sintering and reduction annealing treatment, and thus the luminescence properties of rare earth ion is improved.

Abstract: A bonded ceramic component which is resistant to reactive halogen-containing plasmas, said component comprising ceramic portions which are bonded together by a bonding material which includes an oxyfluoride glass-ceramic-comprising transition area between interfaces of the ceramic portions, where the transition area includes from at least 0.1 volume % amorphous phase up to about 50 volume % amorphous phase.

Abstract: The invention relates to a glass having SiO2, Na2O and CaO as main components, which comprises two amorphous phases having different compositions, one of the two phases being in the form of inclusions dispersed in the volume of the other phase and comprising crystalline particles. Such a glass has good mechanical strength, in particular good resistance to scratch propagation and allows improved tempering. This glass furthermore has a pleasant aesthetic appearance.

Abstract: The invention relates to a glass-ceramic material having SiO2, Na2O and CaO as main components and comprising crystalline particles of SiO2 dispersed homogeneously in the volume of an amorphous matrix. Such a material has good mechanical strength, in particular good resistance to scratch propagation and allows improved tempering. This material furthermore has a pleasant aesthetic appearance.

Abstract: A process for preparing roofing granules includes forming kaolin clay into green granules and sintering the green granules at a temperature of at least 900 degrees Celsius to cure the green granules until the crystalline content of the sintered granules is at least ten percent as determined by x-ray diffraction.

Abstract: To provide a ceramic member having a thermal expansion coefficient close to that of silicon and has satisfactory workability, a probe holder formed by using this ceramic member, and a method of manufacturing the ceramic member. For this purpose, at least mica and silicon dioxide are mixed and an external force oriented in one direction is caused to act on this mixed mixture to sinter the mixture. It is more preferable that, in the mixture, a volume content of the mica is 70 to 90 volume % and a volume content of the silicon dioxide is 10 to 30 volume %.

Abstract: A method of fabricating a one crystalline phase lithium silicate glass ceramic and the manufacture of machinable blocks for dental appliances using a CAD/CAM device. The resulting glass ceramic contains a thermodynamically stable lithium silicate crystal through each of the steps of the process due to its specific material formulation.

Abstract: A method is described for making a float glass convertible into a glass ceramic, by which a largely crystal fault-free glass can be produced. In this method the glass is cooled from a temperature (TKGmax), at which a crystal growth rate is at a maximum value (KGmax), to another temperature (TUEG), at which practically no more crystal growth occurs, with a cooling rate, KR, in ° C. min?1 according to: KR UEG KGmax ? ? ? ? T UEG KGmax 100 · KG ? ? max , wherein ?T=TKGmax?TUEG, and KGmax=maximum crystal growth rate in ?m min?1. The float glass has a thickness below an equilibrium thickness, a net width of at least 1 m and has no more than 50 crystals with a size of more than 50 ?m, especially no crystals with a size of more than 10 ?m, per kilogram of glass within the net width.

Abstract: A ceramic particle with at least two microstructural phases comprising an amorphous phase, representing between 30 volume percent and 70 volume percent of the particle, and a first substantially crystalline phase comprising a plurality of predominately crystalline regions distributed through the amorphous phase is disclosed. A process for making the ceramic particle is also disclosed.

Abstract: A colorless transparent colloid-former-containing glass that is convertible into a colorless transparent glass ceramic or a metal colloid-colored glass ceramic via respective heat treatments contains a combination of one or more metal colloid formers and one or more redox partners. The metal colloid formers are preferably oxides containing Au, Ag, As, Bi, Nb, Cu, Fe, Pd, Pt, Sb and/or Sn. The redox partners are preferably oxides containing As, Ce, Fe, Mn, Sb, Sn and/or W, with the proviso that the redox partner must be different from the metal colloid former. The glass advantageously contains from 0.97 to 1.9 wt. % SnO2, 0.93 to 3.0 wt. % As2O3, or 1.59 to 6.0 wt. % of Sb2O3 as redox partner.

Abstract: A novel metal/ceramic hybrid material in which the void space of the ceramic is filled with metal. The metal may be bonded to the ceramic, for example by formation of a metal oxide. The metal may be introduced into the ceramic as small particles in a suspension then heated to melt the metal, allowing bonding to the ceramic or better filling of the void space. The hybrid material may be used in a variety of applications.

Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools.

Abstract: The colorless transparent colloid-former-containing glass that is convertible into a colorless transparent glass ceramic or a metal colloid-colored glass ceramic via respective heat treatments contains a combination of one or more metal colloid formers and one or more redox partners. The metal colloid formers are compounds containing Au, Ag, As, Bi, Nb, Cu, Fe, Pd, Pt, Sb and/or Sn. The redox partners are compounds containing As, Ce, Fe, Mn, Sb, Sn and/or W, with the proviso that the redox partner must be different from the metal colloid former.

Abstract: A method for producing a ceramic material is disclosed. A ceramic raw material mixture is produced by comminuting and mixing starting materials containing Pb, Zr, Ti, Nd and oxygen. Nickel or an nickel compound is introduced. The raw material mixture is calcined and a ceramic is sintered.

Abstract: The present invention relates to borosilicate glass compositions for a sintering agent, dielectric compositions containing the borosilicate glass compositions and a multilayer ceramic capacitor using the dielectric compositions. Borosilicate glass compositions for a sintering agent according to an aspect of the invention include an alkali oxide, an alkaline earth oxide and a rare earth oxide, can sinter ceramic dielectrics at low temperatures and improve the hot insulation resistance of a multilayer ceramic capacitor. Correspondingly, dielectric compositions including these borosilicate glass compositions and a multilayer ceramic capacitor using the dielectric compositions can be sintered at a low temperature of 1100° C. or less and have high hot insulation resistance, thereby ensuring high levels of reliability.

Abstract: Disclosed are processes for preparing conductive glass-ceramic membranes and methods of using them in hydrogen or proton separation.

Abstract: There is provided a Low Temperature Co-fired Ceramic (LTCC) composition, an LTCC substrate comprising the same, and a method of manufacturing the same. The LTCC composition includes 20 to 70 parts by weight of ceramic powder; and 30 to 80 parts by weight of glass component for low-temperature sintering, wherein the ceramic powder has plate-shaped ceramic powder particles and globular ceramic powder particles, and the ceramic powder has a content ratio of the globular ceramic powder particles with respect to the plate-shaped ceramic powder particles in a range of 0 to 1.

Abstract: Pressable glass-ceramic compositions for dental purposes of the composition I, II or III I II III (percent by weight) (percent by weight) (percent by weight) ZrO2 17-70%? ZrO2/Al2O3 15-70%? Al2O3 15-70%? SiO2 17-59%? SiO2 17-59%? SiO2 17-59%? Al2O3 ?2-15% ZrO2 ?2-15% ZrO2 ?2-15% Y2O3 ??0-6% Y2O3 ??0-6% Y2O3 ??0-6% K2O 3-12.5%? K2O 3-12.5%? K2O 3-12.5%? Na2O 0.2-8.5%?? Na2O 0.2-8.5%?? Na2O 0.2-8.5%?? Li2O 0-1.5% Li2O 0-1.5% Li2O 0-1.5% CaO 0.3-2% CaO 0.3-2% CaO 0.3-2% B2O3 0.1-5% B2O3 0.1-5% B2O3 0.1-5% F 0-2.5% F 0-2.5% F 0-2.5% CeO2 0.2-2% CeO2 0.2-2% CeO2 0.2-2% TiO2 0-1.5% TiO2 0-1.5% TiO2 0-1.5% are particularly suitable for the manufacturing of ceramic veneer frames.

Abstract: A composite powder includes a plurality of loose particles having discrete regions of a first material and discrete regions of a second material that is different than the first material. At least one of the first material and the second material is a chemical precursor to a third material.

Abstract: A method of fabricating a composite powder includes forming a plurality of loose particles having discrete regions of a first material and discrete regions of a second material that is different than the first material. At least one of the first material and the second material includes a chemical precursor to a third, different material.

Abstract: The invention relates to an antimicrobial phosphate glass having the following composition in percent by weight on an oxide basis: P2O5>66-80 percent by weight; SO30-40 percent by weight; B203 0-1 percent by weight; Al2O3>6.2-10 percent by weight; SiO2 0-10 percent by weight; Na2O>9-20 percent by weight; CaO 0-25 percent by weight; MgO 0-15 percent by weight; SrO 0-15 percent by weight; BaO 0-15 percent by weight; ZnO>0-25 percent by weight; Ag2O 0-5 percent by weight; CuO 0-10 percent by weight; GeO2 0-10 percent by weight; TeO2 0-15 percent by weight; Cr2O3 0-10 percent by weight; J 0-10 percent by weight; F 0-3 percent by weight.

Abstract: Optical glass constituted by an amorphous matrix and crystal grains dispersed in the amorphous matrix, wherein the amorphous matrix comprises a first oxide of at least one of silicon oxide and phosphor oxide and a second oxide of at least one of titanium oxide and zirconium oxide, and wherein the crystal grains is at least one of titanium oxide, zirconium oxide and silicon, an average grain size of the titanium oxide grain being 3 nm to 20 nm, and the average grain size of the silicon crystal being 3 nm to 8 nm.

Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.

Abstract: Disclosed herein is a ceramic comprising: at least two different metal oxides, the at least two different metal oxides comprising TiO2 and La2O3 or TiO2 and BaO; less than 20% by weight SiO2; less than 20% by weight B2O3; and less than 40% by weight P2O5; the ceramic having a glass transition temperature, Tg, and a crystallization onset temperature, Tx, and the difference between Tg and Tx is at least 5K. The ceramic may comprise additional metal oxides. Also disclosed herein is a method of making an article using the ceramic; typically, the ceramic is heated above the Tg, shaped, and then cooled.

Abstract: The amorphous and/or partially crystalline glass solders are particularly suitable for high-temperature applications, e.g. in fuel cells or sensors in the exhaust gas stream of internal combustion engines. The glass solder is characterized by a linear coefficient of thermal expansion in the temperature range from 20° C. to 300° C. of 8.0×10?6 K?1 to 11.0×10?6 K?1 and a hemisphere temperature of 820° C. to 1100° C. and is suitable for laser bonding.

Abstract: The invention proposes a method for producing glass ceramics which is particularly well suited as light conversion material, especially for down conversion. One initially produces a starting glass, containing (on an oxide basis) 5-50% by weight of SiO2, 5-50% by weight of Al2O3 and 10-80% by weight of at least one oxide selected from the from the group formed by Y2O3, Lu2O3, Sc2O3, Gd2O3, Yb2O3, Ce2O3, as well as 0.1-30% by weight of at least one oxide selected from the group formed by B2O3, Th2O3, and oxides of the lanthanoids, except Lu2O3, Gd2O3, Yb2O3, Ce2O3. Thereafter, the material is heated up for ceramization at a heating rate of at least 100 K/min to a temperature in the range of between 1000° C. to 1400° C. until crystallites are formed that contain a garnet phase. Thereafter, the material is cooled down to room temperature. Alternatively, controlled cooling-down from the molten state is possible.

Abstract: The present invention relates to a glass composition comprising crystalline phases, and to glass flakes produced therefrom. These glass flakes can be used as base substrate for effect pigments. The glass flakes can furthermore be used in paints, coatings, printing inks, plastics and in cosmetic formulations. The glass flakes are converted into glass-ceramics, and are present in one of the following composition ranges I or II in % by weight: I: 40-50 SiO2, 10-20 B2O3, 10-20 Na2O, 15-30 TiO2; II: 10-60 SiO2, 5-30 B2O3, 5-40 TiO2, 2-20 Nb2O5, 2-20 Fe2O3, 5-40 Na2O+K2O+CaO+SrO+BaO.

Abstract: Presently described are retroreflective articles, such as pavement markings, that comprise transparent microspheres partially embedded in a (e.g., polymeric) binder. Also described are (e.g., glass-ceramic) microspheres, methods of making microspheres, as well as compositions of glass materials and compositions of glass-ceramic materials. The microspheres generally comprise lanthanide series oxide(s), titanium oxide (TiO2), and optionally zirconium oxide (ZrO2).

Abstract: The invention relates glass ceramic articles suitable for use as electronic device housing or enclosures which comprise a glass-ceramic material. Particularly, a glass-ceramic article housing/enclosure comprising a glass-ceramic material exhibiting both radio and microwave frequency transparency, as defined by a loss tangent of less than 0.5 and at a frequency range of between 15 MHz to 3.0 GHz, a fracture toughness of greater than 1.5 MPa·m1/2, an equibiaxial flexural strength (ROR strength) of greater than 100 MPa, a Knoop hardness of at least 400 kg/mm2, a thermal conductivity of less than 4 W/m° C. and a porosity of less than 0.1%.

Abstract: A ceramic substrate has a base material composed of an amorphous phase and particles composed of a crystalline phase and dispersed in the base material. Some of the particles are permitted to protrude from at least one surface of the base material.

Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools.

Abstract: The present invention relates to a glass-ceramic plate intended for example to cover or accommodate at least one heating element, in particular intended to serve as a hob, said plate being at least partly coated with at least one nanoscale layer based on a metallic material having a refractive index greater than that of the glass-ceramic. The invention also relates to the process for manufacturing the plate, to the screen-printable composition deposited on the plate, and to the cooking appliance comprising said plate.

Abstract: A process for producing an optical glass fiber from crystal-glass phase material. In one embodiment, the process includes the step of providing a molten crystal-glass phase material in a container, wherein the temperature of the molten crystal-glass phase material is at or above the melting temperature of the molten crystal-glass phase material, Tm, to allow the molten crystal-glass phase material is in liquid phase. The process further includes the step of cooling the molten crystal-glass phase material such that the temperature of the molten crystal-glass phase material, T1, is reduced to below Tm to cause the molten crystal-glass phase material to be changed from the liquid phase to a viscous melt.

Abstract: The invention relates to synthetic hybrid rock compositions, articles of manufacture and related processes employing mineral waste starting materials such as mine tailings, mine development rock, ash, slag, quarry fines, and slimes, to produce valuable articles of manufacture and products, which are characterized by superior physical and structural characteristics, including low porosity, low absorption, increased strength and durability, and retained plasticity. The resulting materials are compositionally and chemically distinct from conventional synthetic rock materials as demonstrated by scanning electron microprobe analysis, and are useful in a wide variety of applications, particularly with respect to commercial and residential construction.

Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.

Abstract: A method for preparing a composition including mineral particles, that is swelling TOT-TOT interlayer particles, formed by interlayering between: at least one non-swelling mineral phase formed by a stack of elementary laminae of the phyllogermanosilicate 2/1 type and of formula —(SixGe1?x) 4M3O10(OH)2—, and at least one swelling mineral phase formed by a stack of elementary laminae of the phyllogermanosilicate 2/1 type and at least one interlaminar space between two consecutive elementary laminae, the swelling mineral phase being of formula —(SixGe1?x)4M3??O10(OH)2, (M2+)??.nH2O. The composition is prepared by subjecting a gel containing silicon, germanium and metal, of chemical formula —(SixGe1?x)4M3O11,nH2O—, in the liquid state to a hydrothermal treatment which is carried out over a defined period of time and at a temperature of between 150° C. and 300° C.

Abstract: Presently described are retroreflective articles, such as pavement markings, that comprise transparent microspheres partially embedded in a (e.g., polymeric) binder. Also described are (e.g., glass-ceramic) microspheres, methods of making microspheres, as well as compositions of glass materials and compositions of glass-ceramic materials. The microspheres generally comprise lanthanide series oxide(s), titanium oxide (TiO2), and optionally zirconium oxide (ZrO2).

Abstract: The transparent polycrystalline optoceramic has single crystallites and at least 95 percent by weight of the single crystallites have a cubic pyrochlore or fluorite structure. The optoceramic is composed of an oxide of stoichiometry: A2+xByDzE7 wherein 0<x<1, 0<y<2, 0<z<1.6 and 3x+4y+5z=8; wherein A is at least one trivalent rare earth cation; B is at least one tetravalent cation; D is at least one pentavalent cation; and E comprises at least one divalent anion. Refractive, diffractive or transmissive optical elements are made with these optoceramics.

Abstract: The invention provides an antimicrobial phosphate glass composition including, in weight percent based on oxide: greater than 45 to 90 of P2O5, 0 to 60 of B2O3, 0 to 40 of SiO2, 0 to 20 weight percent of Al2O3, 0 to 30 of SO3, 0 to 0.1 of Li2O, 0 to 0.1 of Na2O, 0 to 0.1 of K2O, 0 to 40 of CaO, 0 to 40 of MgO, 0 to 15 of SrO, 0 to 40 of BaO, 0 to 40 of ZnO, 0 to 5 of Ag2O, 0 to 15 of CuO, 0 to 10 of Cr2O3, 0 to 10 of I—, 0 to 10 of TeO2, 0 to 10 of GeO2, 0 to 10 of TiO2, 0 to 10 of ZrO2, 0 to 10 of La2O3, 0 to 5 of Nb2O3, 0 to 5 of CeO2, 0 to 5 of Fe2O3, 0 to 5 of WO3, 0 to 5 of Bi2O3, and 0 to 5 of MoO3.

Abstract: A coating including a bond layer deposited on a substrate. The bond layer includes a rare earth silicate and a second phase, the second phase including at least one of silicon, silicides, alkali metal oxides, alkali earth metal oxides, glass ceramics, Al2O3, TiO2, Ta2O5, HfO2, ZrO2, HfSiO4, ZrSiO4, HfTiO4, ZrTiO4, or mullite. The coating may provide thermal and/or environmental protection for the substrate, especially when the substrate is a component of a high-temperature mechanical system.