Abstract: Ceramic fibers based on silicon carbide, silicon nitride or silicon carbonitride are treated with hydrofluoric acid, e.g., with a 3% to 30% aqueous solution of HF, to strip surface impurities therefrom, to reduce critical surface defects and to enhance the rupture strength thereof.

Abstract: A vitreous product which can be used in agriculture is disclosed. With the exception of nitrogen, this vitreous product contains all the major and minor mineral elements which are essential for the nutrition of plants.The vitreous products can contain the following constituents, taken in the following proportions by weight:______________________________________ SiO.sub.2 25 to 65% Fe.sub.2 O.sub.3 1 to 15% P.sub.2 O.sub.5 1 to 15% B.sub.2 O.sub.3 0.01 to 2% K.sub.2 O 5 to 35% MnO 0.01 to 3% CaO 11 to 35% ZnO 0.01 to 3% MgO 1 to 10% CuO 0.01 to 2% SO.sub.3 0.01 to 1% MoO.sub.3 0.01 to 3% Na.sub.2 O 0 to 2% Al.sub.2 O.sub.3 0 to 25%.

Abstract: An oxynitride glass, a process for preparing same and a fiber thereof, in the glass which has Si--M.sub.1 --M.sub.2 --O--N system and contains SiO.sub.2, Si.sub.3 N.sub.4 and M.sub.1 O in amounts which, as mole %, satisfy the following equations (a) and (b):(SiO.sub.2 +3Si.sub.3 N.sub.4 +M.sub.1 O) X 100 / (100+2Si.sub.3 N.sub.4)=65 to less than 100 (a)(SiO.sub.2 +3Si.sub.3 N.sub.4)/M.sub.1 O=0.7 to 2.3 (b)wherein M.sub.1 is Ca, or Ca and Mg; M.sub.2 is at least one of the metal selected from the group consisting of Al, Sr, La, Ba, Y, Ti, Zr, Ce, Na, K, Sb, B, Cr, Pb, V and Sn, said glass containing 0-40 mole% SiO.sub.2, 26-70 mole % CaO, 0-20 mole % MgO, and over O to not more than 22 at % M.sub.2.

Abstract: Microcrystalline alpha-alumina based ceramic articles comprising at least 60% alumina by weight in which substantially all the alumina is in the alpha phase having a uniform grain structure comprising alpha alumina crystallites with an average crystallite size less than 0.5 micrometer and a density greater than 90% theoretical are disclosed. Ceramic articles particularly useful as high modulus refractory fibers, among other shaped bodies such as beads, flakes, coatings, and shaped or randomly-shaped abrasive particles, are produced from a unique sol-gel process wherein hydroxy iron polymers are utilized to nucleate the alpha alumina transformation. An inherent advantage of the unique process disclosed is the resulting fine grained microstructure which is essential if a ceramic article such as an alpha alumina fiber is to have reasonable strength.

Abstract: Porous, silica-rich shapes have improved strength and abrasion resistance by leaching the precursor glass shape in preconditioned acid having silica ion and at least one common ion that is also present in the precursor glass shape. The precursor glass shapes have shapes such as fibers, hollow fibers, tubes, rods, beads, hollow spheres and plates and compositions having 30-75 volume percent silica and at least 10-65 volume percent nonsiliceous acid extractable components. Preconditioning of the acid solution results from a pretreatment of the acid with compounds that dissociate into the ions when added to the acid solution or with shapes, particles or fragments of glass compositions different from or similar to the glass shape to be leached so long as the glass composition has extractable material to provide the silica ion and at least one common ion.

Abstract: An inorganic, polycrystalline, ferroelectric fiber with a diameter of from about 1 micron to 1 millimeter, a porosity of less than about 40 percent, a density of at least about 60 percent of theoretical density, and a carbonaceous material content of from about 0 to about 5 percent. The fiber consists essentially of grains of which substantially 100 percent are from about 0.01 to about 5.0 microns in size; the ratio of the size of the largest grain in the fiber to the smallest grain in the fiber is no greater than about 10.

Abstract: A method for preparing substrates for VLS fiber producing reactions and a method for preparing SiC fibers by the VLS process. The first method includes the steps of forming an alcohol sol containing a fiber growth promoter material precursor, applying the sol to at least one surface of the substrate and drying the sol. More particularly, the steps can include forming a sol of colloidal hydrous metal oxide particles in a liquid, the metal oxide being a fiber growth promoter material precursor and the liquid being capable of dissolving a salt of the metal and of wetting the substrate surface as a sol, applying the sol to at least one surface of the substrate and drying the sol.

Abstract: The invention relates to alkaline resistant glasses, particularly glass fibers, which comprise silica, calcia and at least one lanthanide series metal oxide effective to enhance the alkali resistance of the glasses.

Abstract: A vitreous product which can be used in agriculture is disclosed. With the exception of nitrogen, this vetreous product contains all the major and minor mineral elements which are essential for the nutrition of plants.The vitreous products can contain the following constituents, taken in the following proportions by weight:______________________________________ SiO.sub.2 25 to 65% Fe.sub.2 O.sub.3 1 to 15% P.sub.2 O.sub.5 1 to 15% B.sub.2 O.sub.3 0.01 to 2% K.sub.2 O 5 to 35% MnO 0.01 to 3% CaO 11 to 35% ZnO 0.01 to 3% MgO 1 to 10% CuO 0.01 to 2% SO.sub.3 0.01 to 1% MoO.sub.3 0.01 to 3% Na.sub.2 O 0 to 2% A1.sub.2 O.sub.

Abstract: A composite member includes circumferentially extending ceramic fibers in a metallic matrix. A rotor member integrally includes such a ceramic fiber/metal matrix composite member to reinforce a homogeneous remainder portion of the rotor member with respect to centrifugally induced stresses. Method of making are included in the disclosure.

Abstract: A process for treating a halide, e.g. fluoride, glass composition, characterized by contacting a melt of the composition (3) with dry oxygen (6). Oxygen, simply on contact with a fluoride glass melt, converts transition metals, e.g. from Fe(II) to Fe(III), from one stable state to another and thereby reduces loss at transmission wavelengths in optical fibre, e.g. the loss at 2.6 .mu.m attributabel to Fe(II).

Abstract: The invention relates to glass fiber compositions and fibers having use as a reinforcement element of cement-base products. As such, the composition is able to resist attack of strongly basic media.The fibers of the invention comprise the following constituents, in proportions by weight:SiO.sub.2 --56 to 68%,ZrO.sub.2 --14 to 17%,Na.sub.2 O--12 to 20%,K.sub.2 O--0 to 8%,Al.sub.2 O.sub.3 --1 to 9%,and wherein the sum of Na.sub.2 O and K.sub.2 O is between 14 and 22%, and wherein the sum of SiO.sub.2 and Al.sub.2 O.sub.3 is less than 70%.

Abstract: A continuous, monofilamentous, alkali-resistant glass fiber especially useful in cementitious products is conveniently prepared from a glass-forming composition comprising a magnesium silicate such as talc and a calcium carbonate such as limestone. Either the fiber itself or a strand comprising a plurality of the fiber is advantageously coated with an alkali-resistant polymer such as butadiene-styrene to provide additional alkali resistance.

Abstract: Glass fibers having a low dielectric constant composed of a glass having a dielectric constant of not more than 5 and comprising:SiO.sub.2 45-65% by weight,Al.sub.2 O.sub.3 9-20% by weight,B.sub.2 O.sub.3 13-30% by weight,CaO+MgO+ZnO 4-10% by weight,Li.sub.2 O+Na.sub.2 O+K.sub.2 O 0-5% by weight,Based on the total weight of the glass, the total proportion of SiO.sub.2, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, CaO, MgO, ZnO, Li.sub.2 O, Na.sub.2 O, and K.sub.2 O being at least 95% by weight.

Abstract: A process for preparing a cartridge for disposal of a radioactive waste liquid, which comprises filling glass fibers in a mold, heat-treating the fibers for partial fusion and molding them into a molded product of a predetermined shape, wherein at least one member selected from the group consisting of boric acid, silicic acid, lithium borate, lithium silicate, zinc borate, zinc silicate, an organic silane, a silica sol, an oil emulsion, and an alumina sol, is applied to the glass fibers or to the molded product.

Abstract: A fiber glass is provided for filling in a defect or hollow portion of bone. The fiber glass comprises calcium phosphate as a main ingredient and has a negative zeta potential. The calcium phosphate has a molar ratio of Ca/P of not less than 0.2 and less than 0.6 and the total content of CaO plus P.sub.2 O.sub.5 in the fiber glass is less than 80 wt %. The fiber glass is of long filament form or staple fiber form. The fiber glass of long filament form may be woven to form a woven filler.

Abstract: Refractory fibers comprising a homogeneous mixture of 60 to 95 weight percent amorphous alumina and 40 to 5 weight percent amorphous phosphorus pentoxide. The fibers optionally can contain chloride, and up to 20 weight percent carbon derived from the alumina precursor material. Other organic residues can be present. The fibers are useful in the manufacture of fireproof consumer fabrics as well as reinforcement or polymeric composites.

Abstract: A multicomponent ceramic article which can be a fiber or particle comprises a continuous ceramic matrix phase and at least one in situ-generated discontinuous ceramic or metal phase. Particles can include shapes in the form of beads, flakes, granules, and microspheres.

Abstract: A method for manufacturing a discontinuous fiber reinforced glass matrix composites by injection molding using an injection nozzle that separates substantially all of a multifilament yarn into individual fibers resulting in a composite having greater crack resistance. The method comprises impregnating continuous filament yarn with glass matrix powders comprising glass, glass-ceramic powders or a mixture thereof. The impregnated multifilament yarn is chopped into discontinuous lengths and exposed to a temperature sufficient so that the matrix material softens. Pressure is applied to the heated impregnated multifilament yarn sufficient to displace the yarn into a mold through an injection nozzle contoured such that sufficient die-wall shear forces are generated to separate substantially all of the multifilament yarn into individual filaments. A mold pressure is maintained sufficient to prevent relaxation of the composite until the strain point of the glass is reached.

Abstract: A reinforcing inorganic fiber composed of an internal layer and a surface layer, whereinsaid internal layer is composed of an inorganic material containing silicon, either titanium or zirconium, carbon and oxygen which is(i) an amorphous material consisting substantially of Si, M, C and O, or(ii) an aggregate consisting substantially of ultrafine crystalline particles with a particle diameter of not more than 500 .ANG. of .beta.-SiC, MC, a solid solution of .beta.-SiC and MC and MC.sub.1-x, wherein M represents titanium or zirconium, and x is a number represented by 0<x<1, or(iii) a mixture of the amorphous material (i) and the aggregate (ii), andsaid surface layer is composed of an inorganic material consisting of silicon, either titanium or zirconium, and oxygen and optionally not more than 5% by weight of carbon which is(iv) an amorphous material consisting substantially of Si, M and O,(v) an aggregate composed of crystalline SiO.sub.2 and MO.sub.

Abstract: Reduced boron containing glass fibers are provided which have a refractive index similar to that of higher boron-containing glass fiber compositions. The glass fibers with a refractive index in the range of greater than 1.5495 to around 1.57 have in weight percent SiO.sub.2 - 55-56.5, CaO - 20-23, Al.sub.2 O.sub.3 14.5-15.5, B.sub.2 O.sub.3 - 5 to 5.8, R.sub.2 O - 1-1.5, wherein R is an alkali metal and F.sub.2 - 0.4 to 0.6. In addition, the glass fiber composition can have minor constituents such as TiO.sub.2 of up to around 0.6 weight percent and an MgO of up to around 0.3 weight percent and ferric oxide of up to around 0.3 weight percent. Basically, the glass fibers have a reduced content of both B.sub.2 O.sub.3 and CaO over standard glass fiber compositions such as E-glass and 621-glass and also has elevated amounts of alkali and of refractory constituents such as SiO.sub.2 and Al.sub.2 O.sub.3. The glass fibers are formed with an elevated temperature of 40.degree. to 50.degree. F. (22.degree.-28.degree.

Abstract: An improved glass composition, especially suitable for glass fiber manufacture having good fiberizing characteristics and good physical properties, and containing typically 40.0% to 65.0% silica, 4.0% to 11.0% aluminum oxide, 6.0% to 20.0% sodium oxide, 5.0% to 8.0% magnesium oxide and 6.0% to 17.0% calcium oxide, 4.0% to 12.0% ferric and ferrous oxide, and 0.0% to 7.0% potassium oxide.

Abstract: A SiO.sub.2 13 B.sub.2 O.sub.3 fiber glass composition is disclosed which contains a reduced amount of B.sub.2 O.sub.3 in comparison with conventional D glass to thereby improve the water resistance and heat resistance. The fiber glass composition of the present invention has a dielectric constant of 4.5 or less for 1 MHz at the room temperature, a strain point of 485.degree. C. or more, and improved water resistance. The composition consists essentially of, by weight SiO.sub.2 70-80%, Al.sub.2 O.sub.3 0-2.0%, B.sub.2 O.sub.3 15.0-21.5%, MgO 0-1.0%, CaO 0-2.0%, Li.sub.2 O 0-2.0%, Na.sub.2 O 0-3.0%, and K.sub.2 O 0-3.0%, Li.sub.2 O+Na.sub.2 O+K.sub.2 O=2.0-5.0%.

Abstract: Glass fibers for insulation uses are produced by means of a centrifugal spinner which introduces glass streams into an annular attenuating blast adjacent the periphery of the spinner. An improved product quality and/or production rate as well as prolonged spinner life are obtained by selection and utilization of a novel combination of structural and operating parameters characterized in particular by a spinner diameter and peripheral speed substantially greater than conventionally employed.

Abstract: This invention is directed to the production of inorganic crystalline fibers containing a minor amount of Mo0.sub.3 and/or W0.sub.3 and/or As.sub.2 0.sub.3 and wherein the predominant crystal phase is selected from the group of a fluormica, a fluoramphibole, canasite, potassium and/or sodium fluorrichterite, fluorapatite, and a lithium-containing, beta-spodumene-type crystal.

Abstract: A solid vitreous composition has the formula: Te.sub.100-x-z X.sub.x Z.sub.z wherein x represents chlorine, bromine or iodine, Z represents sulfur and/or selenium; x represents the molar percentage of X and ranges from 5 to 67; z represents the molar percentage of Z and ranged from 0 to 60; it being understood that the sum (x+z) ranges from 33 to 85. A method for the preparation of this composition is disclosed as is its use in the field of optoelectronics and infra-red transmission.

Abstract: A process for treating a halide, e.g. fluoride, glass composition, characterized by contacting a melt of the composition with dry oxygen. Oxygen, simply on contact with a fluoride glass melt, converts transition metals, e.g. from Fe(II) to Fe(III), from one stable state to another and thereby reduces loss at transmission wavelengths in optical fiber, e.g. the loss at 2.7 .mu.m attributable to Fe(II).

Abstract: A fiber glass is provided for filling in a defect or hollow portion of bone. The fiber glass comprises calcium phosphate as a main ingredient and has a negative zeta potential. The calcium phosphate has a molar ratio of Ca/P of not less than 0.2 and less than 0.6 and the total content of CaO plus P.sub.2 O.sub.5 less than 80 wt %. The fiber glass is of long filament form or staple fiber form. The fiber glass of long filament form may be woven to form a woven filler.

Abstract: The invention relates to glasses formed from naturally occurring zeolites which are modified by inclusion of additional alumina.

Abstract: The invention relates to glasses formed from modified naturally occurring zeolites and in particular to alkaline-resistant glasses containing a high calcia loading.

Abstract: A continuous inorganic fiber consisting of Si, N and O has excellent physical, chemical and electrically insulating properties, is superior to carbon fiber in wettability with metal, is low in reactivity with metal, and can be used not only as a reinforcing fiber for fiber-reinforcing type metals and fiber-reinforcing type ceramics, but also in electrical insulating materials and in heat-resistant materials.

Abstract: A water resistant, devitrification resistant glass fiber consisting essentially of SiO.sub.2, Al.sub.2 O.sub.3, CaO, MgO, B.sub.2 O.sub.3, Na.sub.2 O, and F.sub.2 and/or Fe.sub.2 O.sub.3 and/or TiO.sub.2 and/or K.sub.2 O and/or SO.sub.3 in trace amounts, said glass fiber having a delta T of at least about 365.degree. F. and a durability (% fiber weight loss at 96.degree. C.) in water for 24 hours of less than about 0.9%.

Abstract: Glass fibers having the following constituents in the ranges of proportions indicated: SiO.sub.2, 57-70 wt. %; Al.sub.2 O.sub.3, 2-7 wt. %; CaO, 5-10 wt. %; MgO, 0-4 wt. %; B.sub.2 O.sub.3, 0-4.5 wt. %; and F, 0.5-4 wt. %; and wherein B.sub.2 O.sub.3 and F are present in amounts according to the relationship:3.ltoreq.B.sub.2 O.sub.3 +1.5 F.ltoreq.6.5and wherein the fibers also contain the alkali oxides Na.sub.2 O and K.sub.2 O, in amounts according to the relationship:16 wt. %<Na.sub.2 O+K.sub.2 O<20 wt. %.The glass fibers are used advantageously in thermal and/or acoustic insulation.

Abstract: A fiber glass is provided for filling in a defect or hollow portion of bone. The fiber glass comprises calcium phosphate as a main ingredient and has a negative zeta potential. The calcium phosphate has a molar ratio of Ca/P of not less than 0.2 and less than 0.6 and the total content of CaO plus P.sub.2 O.sub.5 in the fiber glass is less than 80 wt %. The fiber glass is of long filament form or staple fiber form. The fiber glass of long filament form may be woven to form a woven filler.

Abstract: This invention relates to the production of high elastic modulus, high strength, corrosion-resistant oxynitride glass fibers for improved fiber-reinforced composites. The incorporation of nitrogen into silicon-yttrium-aluminum oxide glasses enhances the properties of bulk glass. This invention is the first demonstration that such glasses can be made into fibers. The addition of nitrogen to practically any oxide glass fiber composition will produce improvements in properties similar to those shown for the silicon-yttrium-aluminum system.

Abstract: A spun or drawn glass fiber for use in the area of medical implants, and particularly as a reinforcement for bioabsorbable polymeric orthopaedic and dental implants. The glass fiber is bioabsorbable and has sufficient tensile strength and elasticity to be used as a reinforcement. It is made up of 5-50% calcium oxide (CaO), 50-95% phosphorous pentoxide (P.sub.2 O.sub.5), 0-5% calcium fluoride (CaF.sub.2), 0-5% water (H.sub.2 O), and 0-10% XO wherein X is either a single magnesium, zinc or strontium ion or two sodium, potassium, lithium, or aluminum ions and when X is aluminum the O represents three oxygen ions.

Abstract: Glass fibers having suitable properties for reinforcing electrical laminates have a defined viscosity-liquidus relationship, a low coefficient of thermal expansion, a high elastic modulus, and a low dielectric constant.

Abstract: A mixture containing 35 to 65% by weight of Al.sub.2 O.sub.3, 30 to 60% by weight of SiO.sub.2, 1.5 to 4% by weight of Cr.sub.2 O.sub.3, and 0.01 to 0.1% by weight of carbon, the balance being unavoidable impurities, is melted, and amorphous fibers are formed from said molten material by blowing or spinning. The fibers are heated rapidly to a temperature of 950.degree. C. to 1,150.degree. C., held at that temperature for several to about a dozen minutes, and cooled rapidly to ordinary room temperature.

Abstract: A devitrification resistant, sulfuric acid resistant and water resistant glass fiber consisting essentially of SiO.sub.2, Al.sub.2 O.sub.3, CaO, MgO, Na.sub.2 O and/or K.sub.2 O, B.sub.2 O.sub.3, and optionally Fe.sub.2 O.sub.3, and/or TiO.sub.2 and/or F.sub.2, said glass fiber having delta T of at least about 395.degree. F. and a durability (% fiber weight loss at 96.degree. C.) in water for 24 hours of less than about 1.6% and in 10% H.sub.2 SO.sub.4 for 24 hours of less than about 1.1%.

Abstract: Non-fused hollow glass microspheres that consist primarily of silicate are rendered more water-resistant by treatment with multivalent metals. The hollow microspheres are slurried with water and then a solution of a multivalent metal salt such as Al.sub.2 (SO.sub.4).sub.3 is added to the slurry. The rate of the addition is controlled so that the pH can be regulated. Separating, washing and drying complete the preparation.

Abstract: A copper phosphate water soluble glass composition. The composition of the glass may be adjusted so as to release copper at a uniform preselected rate and to produce a desired pH in the resultant solution. In one application of the glass copper may be supplied to an animal from an implant formed from a cupric oxide/phosphorus pentoxide glass which also incorporates one or more glass modifying oxides such as alkali metal oxides and alumina, to control the glass solubility. Suitable glasses comprise 5-55 mole % cupric oxide + alkali metal oxides. 45-75 mole % phosphorus pentoxide, and not more than 15 mole % alumina, where the copper oxide concentration is not less than 5 mole %.

Abstract: Fiberizable glass compositions are disclosed. The glass compositions are boron-free wool glasses which are useful as insulation. The glass batch used to prepare these glass compositions contains high amounts of iron oxide.

Abstract: The resistance of insulating pieces made of fiberglass reinforced plastics against the decay products of SF.sub.6, such as occur within sealed high-voltage switching devices is unexpectedly enhanced by the use of a reinforcing fiberglass made of a low-alkali silicate glass containing neither boron nor boron-compounds.

Abstract: Continuous inorganic fibers consisting substantially of Si, Ti and C and optionally of O, said fibers being composed of (1) an amorphous material consisting substantially of Si, Ti and C and optionally of O, or (2) an aggregate consisting substantially of ultrafine crystalline particles of .beta.-SiC, TiC, a solid solution of .beta.-SiC and TiC and TiC.sub.1-x wherein 0<x<1 and having a particle diameter of not more than 500 A, in which amorphous SiO.sub.2 and TiO.sub.2 sometimes exist in the neighborhood of these ultrafine crystalline particles, or (3) a mixture of said amorphous material (1) and said aggregate (2) of ultrafine crystalline particles. The aforesaid continuous inorganic fibers can be produced by the following steps: a first step of preparing a semi-inorganic block copolymer comprising polycarbosilane blocks having a main chain skeleton composed mainly of carbosilane units of the formula --Si--CH.sub.

Abstract: An improved method of preparing a molten glass composition is presented. The constituents of the molten glass composition are classified into two or more melting groups according to mutual melting properties or characteristics such as volatility, corrosiveness or fusion point. Of the constituent groups one is selected and prepared as a molten base glass composition into which the remaining groups are sequentially introduced and homogenized into the base glass forming a molten glass composition of desired forming characteristics.

Abstract: A potassium fluoro-borate glass, including silica and optionally alumina, containing at least 20 mole % potassium computed as K.sub.2 (O,F.sub.2), and wherein there are more fluorine atoms in the glass than oxygen atoms. The range of compositions includes low refractive index glasses, some with refractive indices less than that of silica, and high coefficient of thermal expansion glasses, some with coefficients matching those of aluminum, copper and brass.

Abstract: A lead-free, fiberizable glass composition. The glass is characterized by a relatively low hardness rating and is accordingly useful in preparing friction surfaces. Its composition includes, on a weight basis, from about 45% to about 75% of silicon dioxide, from about 15% to about 30% of potassium oxide and from about 2% to about 10% of magnesium oxide.

Abstract: What is disclosed is a method of preparing carbon-containing monolithic glassy ceramics from organosilsesquioxanes, metal oxides and metal alkoxides through pyrolysis of their gels. Also disclosed are certain gel compositions used in the method and the glassy ceramics.