Phosphorus Containing Patents (Class 501/45)
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Patent number: 7994082Abstract: Preforms for precision press molding made of optical glass, optical elements, and methods of manufacturing the same are provided. The preforms are suited to precision press molding having a broad range of dispersion characteristics, a low glass transition temperature, a low sag point, and good resistance to devitrification while containing no PbO. The optical element is obtained by precision press molding the preform. One example of the preform has a refractive index (nd) of greater than or equal to 1.7 and an Abbé number (vd) of less than or equal to 32. The other example of the preform has an Abbé number (vd) exceeding 32.Type: GrantFiled: June 29, 2004Date of Patent: August 9, 2011Assignee: Hoya CorporationInventors: Xuelu Zou, Yoshiko Kasuga, Yasuhiro Fujiwara
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Patent number: 7989377Abstract: Provided is an optical glasses that has high refractivity and low dispersion and anomalous partial dispersion capability and that has excellent processability and devitrification resistance and ensures that the occurrence of striae can be inhibited, the optical glass including an optical glass having a refractive index (nd) of 1.54 to 1.60, an Abbe's number (vd) of 65 to 78, a partial dispersion ratio of 0.530 or more, a specific gravity of 4.0 or less and a viscosity, measured at its liquidus temperature, of 4 dPa·s or more and an optical glass comprising as cationic components, by cationic %, 20 to 50% of p5+, 0.1 to 20% of Al3+, 0.1 to 20% of Mg2+, 0 to 20% of Ca2+, 0 to 20% of Sr2+, 0.1 to 30% of Ba2+ and 0 to 10% of Y3+, and further comprising, as anionic components, F? and O2?, wherein the ratio of the content of Mg2+ to the content of Al3+, Mg2+/Al3+, based on cationic %, is 1.2 or less.Type: GrantFiled: December 4, 2007Date of Patent: August 2, 2011Assignee: Hoya CorporationInventor: Youichi Hachitani
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Patent number: 7989376Abstract: New and improved compositions of doped fluorophosphate glasses for lasers have a high refractive index (nD) of approximately 1.6 to 1.7, high transmission in the near infrared part of the spectrum and a wide glass forming domain. These glass systems, Ba(PO3)2—Al(PO3)3—BaF2-Dopants, utilize dopants from the group of: oxides or fluorides of the rare earth elements: Sm, Eu, Nd, Er, Yb, Tm, Tb, Ho and Pr: as well as MnO; and mixtures thereof. The composition of glass includes chemical durability, efficiency of laser use in the infrared spectrum and improved duration of luminescence. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.Type: GrantFiled: January 21, 2002Date of Patent: August 2, 2011Assignee: AFO Research, Inc.Inventor: Alfred A. Margaryan
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Publication number: 20110124485Abstract: A glass composition being suitable for precision mold press forming, having superior resistance to devitrification, having optical constants (a refractive index, an Abbe number, and the like) required for aspherical lenses, and a low glass transition temperature. There is provided an optical glass comprising 5 mol % to 60 mol % of a B2O3 component, and 0.2 mol % to 60 mol % of a TeO2 component, by mol % on the basis of oxides. Further, there is provided an optical glass mentioned above having optical constants with a refractive index (nd) of 1.80 to 2.20, and an Abbe number (?d) of 16 to 40. Still further, there is provided an optical glass mentioned above having a glass transition temperature (Tg) of no more than 680° C.Type: ApplicationFiled: January 19, 2011Publication date: May 26, 2011Applicant: OHARA INC.Inventor: Jie FU
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Patent number: 7939483Abstract: Water-soluble glass as corrosion protector in dishwashing machines A zinc-containing, water-soluble glass composition comprising from 41 to 54 mole % of P2O5, 10 to 30 mole % of alkali oxides, up to 5 mole % of SO3 and up to 25 mole % of ZnO.Type: GrantFiled: March 31, 2010Date of Patent: May 10, 2011Assignee: Reckitt Benckiser N.V.Inventor: Karlheinz Ulrich Gerhard Hahn
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Patent number: 7930901Abstract: Provided are optical glasses having a phosphate-containing composition that can materialize highly useful optical properties including high-refractivity and high-dispersion properties; an optical glass comprising P2O5, SiO2 and Li2O as essential components, comprising Na2O and K2O as optional components, having an Li2O/(Li2O+Na2O+K2O) molar ratio of from ? to 1 and having an Abbe's number (?d) of 30 or less, and an optical glass comprising P2O5, SiO2 and Li2O as essential components, having the property of transmittance that when light is caused to vertically enter one of two plane and mutually parallel optically polished surfaces of a sample of the glass having a thickness of 10.0±0.1 mm and caused to exit from the other surface, the wavelength at which the transmittance represented by the ratio of transmitted light intensity to incidence light intensity (transmitted light intensity/incidence light intensity) comes to be 70% is 510 nm or less, having a refractive index (nd) of 1.Type: GrantFiled: December 10, 2008Date of Patent: April 26, 2011Assignee: Hoya CorporationInventors: Yasuhiro Fujiwara, Xuelu Zou
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Patent number: 7906445Abstract: An optical glass includes P2O5, B2O3, Li2O, Na2O, K2O, CaO, TiO2, Bi2O3, Nb2O5 and WO3 each of which is in an amount in a predetermined range.Type: GrantFiled: June 4, 2008Date of Patent: March 15, 2011Assignee: Konica Minolta Opto, Inc.Inventor: Akio Oogaki
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Patent number: 7892996Abstract: A lead-free sealing material is provided, which contains a glass with a composition including 47.5-67.5 mole % SnO, 2.5-15 mole % MgO, and 30-40 mole % P2O5. The lead-free sealing material has excellent chemical durability, low melting temperature, and good flowability during heating. The lead-free material is particularly suitable to be used as a sealing material. The lead-free sealing material may additionally contain low-thermal-expansion powdered fillers to reduce the thermal expansion coefficient of the resulting sealing material.Type: GrantFiled: June 30, 2008Date of Patent: February 22, 2011Assignees: Tatung Company, Tatung UniversityInventors: Jiin-Jyh Shyu, Chih-Hsien Yeh
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Publication number: 20100331164Abstract: Sealing materials for use with membrane supports, and in particular to sealing materials that can be used to form a glassy coating on the exterior surface of a membrane support to prevent gases from entering or exiting the support via the support's exterior walls.Type: ApplicationFiled: June 30, 2009Publication date: December 30, 2010Inventors: Lisa Ann Lamberson, Robert Michael Morena
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Publication number: 20100317504Abstract: A P2O5—BaO—ZnO—Nb2O5 type optical glass contains 25-50 wt. % P2O5, 15-35 wt. % BaO, 1-25 wt. ZnO, and 3-10 wt. % Nb2O5. The optical glass has a high refractive index (particularly preferably the refractive index nd of 1.6 or more), low dispersion (an Abbe number ?d of 42 or more), a low deformation point, and improved resistance to devitrification upon molding, and is suitable for precision-mold press molding or other molding processes and also suitable for transfer of a fine structure.Type: ApplicationFiled: February 9, 2009Publication date: December 16, 2010Applicant: National Institute of Advanced Industrial Sciences and TechnologyInventors: Tatsuo Hidaka, Junichi Nakamura, Yoshitaka Mayumi, Hidekazu Hashima, Kohei Fukumi, Naoyuki Kitamura, Junji Nishii
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Publication number: 20100310856Abstract: Embodiments relate to a transparent body comprising a matrix material and a plurality of non-metal particles positioned in the matrix material. The matrix material may be selected from the group consisting of glass materials, ceramic materials, and semiconductor materials. The non-metal particles may have a mean particle size of no greater than 150 nm. The non-metal particles may be present in the body at a volume fraction of no greater than 3 percent. The non-metal particles may have a composition different than that of the matrix. Other embodiments are described and claimed.Type: ApplicationFiled: June 4, 2010Publication date: December 9, 2010Inventor: Stephen W. Freiman
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Publication number: 20100298111Abstract: An optical glass has a composition including: 40 to 65 mass % of P2O5, and 0 to less than 5 mass % of Li2O+Na2O+K2O. In the optical glass, (MgO+CaO)/(Li2O+Na2O+K2O) which is a ratio of the total content expressed in mass % of MgO and CaO to the total content expressed in mass % of Li2O, Na2O, and K2O, is in a range from 6 to 38.Type: ApplicationFiled: May 19, 2010Publication date: November 25, 2010Inventor: Akio Oogaki
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Publication number: 20100292066Abstract: A glass material for mold pressing, comprised of a core portion comprised of a multicomponent optical glass containing at least one readily reducible component selected from among W, Ti, Bi, and Nb, and a covering portion covering the surface of said core portion, comprised of a multicomponent glass containing none or a lower quantity of said readily reducible component than is contained in said core portion. A glass material for mold pressing comprising a core portion comprised of a fluorine-containing multicomponent optical glass and a covering portion covering the surface of said core portion, comprised of a multicomponent glass containing none or a lower quantity of fluorine than is contained in said core portion. A method for manufacturing an optical glass element comprising heat softening a glass material that has been preformed into a prescribed shape, and conducting press molding with a pressing mold, employing the above glass material of the invention.Type: ApplicationFiled: March 28, 2007Publication date: November 18, 2010Inventors: Xuelu Zou, Yasuhiro Fujiwara, Hiroshi Kohno, Kohichiro Shiraishi
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Publication number: 20100273633Abstract: The present invention relates to an optical glass containing, in terms of mass % on an oxide basis, P2O5: from 10 to 18%; Bi2O3: from 37 to 64%; Nb2O5: from 5 to 25%; Na2O: from more than 4.1 to 10%; K2O: from 0 to 2%; Li2O: from 0 to 0.2%; WO3: from 0 to less than 20%; TiO2: from 0 to 3%; and B2O3: from 0 to 2%, and having a refractive index nd of 1.98 or more and an Abbe's number ?d of 20 or less.Type: ApplicationFiled: April 26, 2010Publication date: October 28, 2010Applicant: ASAHI GLASS COMPANY LIMITEDInventor: Kenji KITAOKA
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Patent number: 7816292Abstract: A glass powder or a glass-ceramic powder is provided that includes multicomponent glasses with at least three elements, where the glass powder or a glass-ceramic powder has a mean particle size of less than 1 ?m. In some embodiments, the mean particle size is less than 0.1 ?m, while in other embodiments the mean particle size is less than 10 nm.Type: GrantFiled: May 25, 2005Date of Patent: October 19, 2010Assignee: Schott AGInventors: Jose Zimmer, Johann Daimer, Matthias Rindt, Susanne Kessler, Joern Besinger, Karine Seneschal-Merz
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Patent number: 7799714Abstract: The optical glass comprises equal to or greater than 5 mole percent of P2O5, has an Abbé number of equal to or greater than 58 and a glass transition temperature of equal to or less than 570 degree Celsius, and has an alkalinity resistance defined as a rate of weight reduction of equal to or less than 17 micrograms/(cm2·hour) when the surface of said optical glass which has been optically polished is immersed in 0.01 mole/liter of NaOH aqueous solution at 50 degree Celsius.Type: GrantFiled: October 2, 2006Date of Patent: September 21, 2010Assignee: Hoya CorporationInventor: Yasuhiro Fujiwara
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Publication number: 20100222197Abstract: Transition metal doped Sn phosphate glass compositions and methods of making transition metal doped Sn phosphate glass compositions are described which can be used for example, in sealing applications.Type: ApplicationFiled: February 27, 2009Publication date: September 2, 2010Inventor: Bruce Gardiner Aitken
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Patent number: 7767605Abstract: Provided is an optical glass having high refractivity and high dispersibility, having good moldability in precision pressing, and having high transmittance and good internal quality, of which the transmittance reduction with time is prevented. The optical glass has a Pt content of at most 1.5 ppm, and is characterized in that, when a sample of the glass polished on both surfaces and having a thickness of 10 mm is irradiated with UV and/or visible light at a light-receiving energy of at most 0.4 mW·cm?2 for at least 200 hours, then the difference in the internal transmittance to light having a wavelength of 420 nm, before and after the irradiation (before irradiation—after irradiation) of the sample, as calculated in terms of the sample having a thickness of 10 mm, is at most 0.1.Type: GrantFiled: July 14, 2006Date of Patent: August 3, 2010Assignee: Ohara, Inc.Inventors: Michiko Ogino, Masahiro Onozawa
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Patent number: 7754629Abstract: Disclosed are glass materials generally belonging to the P2O5—ZnO—TeO2 system and process for making the same. The glass may comprise Bi2O3 as well. The high refractive index and low Tg materials are particularly suitable for refractive lens elements for use in portable optical devices. The process involves the use of P2O5 source materials with reduced amounts of reducing agents or a step of removing the reducing agents from such source materials by an oxidizing step such as calcination.Type: GrantFiled: February 7, 2007Date of Patent: July 13, 2010Assignee: Corning IncorporatedInventors: Bruce Gardiner Aitken, James Edward Dickinson, Jr., Sinue Gomez
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Patent number: 7741236Abstract: A zinc and bismuth containing, water-soluble glass composition comprising from 10 to 75 mole % P2O5, 5-50 mole % alkali metal oxide, up to 40 mole % ZnO and up to 40 mole % Bi2O3.Type: GrantFiled: May 29, 2009Date of Patent: June 22, 2010Assignee: Reckitt Benckiser N.V.Inventors: Karlheinz Ulrich Gerhard Hahn, Karin Werner
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Patent number: 7737064Abstract: Optical glass having a refractive index (nd) of 1.75 or greater, and an Abbe number (?d) falling within the range of 15 to 40, which is suitable for molding by precision mold press is provided. The optical glass is characterized by including B2O3+SiO2 in an amount of 10 to 70%, Bi2O3 in an amount of 5% or more and less than 25%, RO+Rn2O in an amount of 5 to 60% (wherein R represents one or more selected from a group consisting of Zn, Ba, Sr, Ca, and Mg; and Rn represents one or more selected from a group consisting of Li, Na, K, and Cs), with each component in the range expressed in oxide-based mole, and is characterized in that transparency in the visible region is high, and that the transition point (Tg) is 520° C. or lower. The optical glass is characterized by having a spectral transmittance of 70% or greater at a wavelength of 550 nm, for a thickness of 10 mm.Type: GrantFiled: April 27, 2006Date of Patent: June 15, 2010Assignee: O'Hara, Inc.Inventor: Jie Fu
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Patent number: 7732358Abstract: A modified alkali silicate composition for forming an inorganic network matrix. The modified alkali silicate matrix is made by reacting an alkali silicate (or its precursors such as an alkali hydroxide, a SiO2 source and water), an acidic inorganic composition, such as a reactive glass, water and optional fillers, additives and processing aids. An inorganic matrix composite can be prepared by applying a slurry of the modified aqueous alkali silicate composition to a reinforcing medium and applying the temperature and pressure necessary to consolidate the desired form. The composite can be shaped by compression molding as well as other known fabrication methods. A notable aspect of the invention is that, although composite and neat resin components prepared from the invention can exhibit excellent dimensional stability to 1000° C. and higher, they can be prepared at the lower temperatures and pressures typical to organic polymer processing.Type: GrantFiled: August 30, 2004Date of Patent: June 8, 2010Assignee: Goodrich CorporationInventors: Anthony M. Mazany, John W. Robinson, Craig J. Cartwright
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Patent number: 7704903Abstract: The invention provides an antimicrobial phosphate glass composition including, in weight percent based on oxide: greater than 45 to 90 of P2O5, 0 to 60 of B2O3, 0 to 40 of SiO2, 0 to 20 weight percent of Al2O3, 0 to 30 of SO3, 0 to 0.1 of Li2O, 0 to 0.1 of Na2O, 0 to 0.1 of K2O, 0 to 40 of CaO, 0 to 40 of MgO, 0 to 15 of SrO, 0 to 40 of BaO, 0 to 40 of ZnO, 0 to 5 of Ag2O, 0 to 15 of CuO, 0 to 10 of Cr2O3, 0 to 10 of I—, 0 to 10 of TeO2, 0 to 10 of GeO2, 0 to 10 of TiO2, 0 to 10 of ZrO2, 0 to 10 of La2O3, 0 to 5 of Nb2O3, 0 to 5 of CeO2, 0 to 5 of Fe2O3, 0 to 5 of WO3, 0 to 5 of Bi2O3, and 0 to 5 of MoO3.Type: GrantFiled: March 8, 2005Date of Patent: April 27, 2010Assignee: Schott AGInventors: Karine Seneschal, José Zimmer, Jörg Hinrich Fechner, Bianca Schreder
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Publication number: 20100065882Abstract: A glass-covered light-emitting element and a glass-covered light-emitting device are provided, which are covered with a glass having a low glass transition point and a thermal expansion coefficient close to that of the light-emitting element. The glass-covered light-emitting element includes a semiconductor light-emitting element having a principal surface, and a P2O5—ZnO—SnO type glass covering the principal surface of the semiconductor light-emitting element, and the glass consists essentially of, as represented by mol % based on the following oxides, from 20 to 45% of P2O5, from 20 to 50% of ZnO and from 20 to 40% of SnO, and the glass has a glass transition point of at least 290° C. and at most 450° C., and a thermal expansion coefficient of at most 105×10?7/° C.Type: ApplicationFiled: November 19, 2009Publication date: March 18, 2010Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Syuji Matsumoto, Yasuko Osaki, Nobuhiro Nakamura
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Patent number: 7670974Abstract: A low dispersion optical glass comprising, given as molar percentages, 28 to 50 percent of P2O5; more than 20 percent but not more than 50 percent of BaO; 1 to 20 percent MgO; a sum of Li2O, Na2O, and K2O exceeding 3 percent (with 0 to 25 percent of Li2O, greater than or equal to 0 percent and less than 10 percent of Na2O, and 0 to 12 percent of K2O); more than 0 percent but not more than 15 percent of ZnO; 0 to 25 percent of B2O3; 0 to 5 percent of A12O3; 0 to 8 percent of Gd2O3; 0 to 20 percent of CaO; 0 to 15 percent of SrO; and 0 to 1 percent of Sb2O3; with a sum of oxide contents of P, Ba, Mg, Li, Na, K, Zn, B, Al, Gd, Ca, Sr, and Sb being greater than or equal to 98 percent. The optical glass comprises no La2O3. The press molding preform is comprised of the optical glass.Type: GrantFiled: April 16, 2004Date of Patent: March 2, 2010Assignee: Hoya CorporationInventors: Yasuhiro Fujiwara, Xuelu Zou
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Publication number: 20100029459Abstract: The present invention provides novel glasses, methods of formulating glasses having a reduced stress-optic coefficient at visible wavelengths under anisotropic stress, and novel optical systems comprising a such glass.Type: ApplicationFiled: July 26, 2007Publication date: February 4, 2010Inventors: Josef Wilson Zwanziger, Marie Helene Guignard
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Patent number: 7651966Abstract: A substantially alkaline resistant calcium-iron-phosphate (CFP) glass and methods of making and using thereof. In one application, the CFP glass is drawn into a fiber and dispersed in cement to produce glass fiber reinforced concrete (GFRC) articles having the high compressive strength of concrete with the high impact, flexural and tensile strength associated with glass fibers.Type: GrantFiled: March 30, 2007Date of Patent: January 26, 2010Assignees: Mo-Sci Corporation, The Curators of the University of MissouriInventors: Richard K. Brow, Signo T. Reis, Mariano Velez, Delbert E. Day
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Patent number: 7645314Abstract: Di-ammonium phosphate, murate of potash and gypsum are the conventional phosphorous, potassium and sulfur fertilizers respectively. Application of gypsum to soil can cause an increase calcium load on soil and polluted surface and underground water. The most successful technique is application of phosphorous-potassium-sulfur glass which can be added directly to the soil. Main feature of the present invention is formulation and making of a composition of high phosphorous, potassium and sulfur containing glass free from alkali like Na2O, Li2O and ZnO, which are toxic to the plants. Such glasses are capable of slow release of phosphorous, potassium and sulfur required in the area of agriculture, fungicide, pesticide and weedicides etc. The present invention also emphasize optimization of nutrient content, reduction of calcium load on the soil, minimization of surface and under-ground water pollution and maintenance of acidic environment near the plant roots in the soil.Type: GrantFiled: December 6, 2004Date of Patent: January 12, 2010Assignee: Council of Scientific & Industrial ResearchInventors: Nisha Biswas, Gour Krishna Das Mahapatra, Koushik Ghosh
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Patent number: 7638448Abstract: The lead-free optical glass can be used in the fields of imaging, sensor technology, microscopy, medical technology, digital projection, photolithography, laser technology, wafer/chip technology, as well as of telecommunications, optical communication engineering and optics/lighting in the automotive sector. It has a refractive index nd of 1.82?nd?2.00 and/or an Abbe number vd of 18?vd?28 with good chemical stability, excellent crystallization stability and the following composition, in wt. based on oxide content, of: P2O5 12-35 Nb2O5 30-50 Bi2O3 ?2-13 GeO2 0.1-7?? Li2O ?6 Na2O ?6 K2O ?6 Cs2O ?6 MgO ?6 CaO ?6 SrO ?6 BaO ???7-<17 ZnO ?6 TiO2 ?7 ZrO2 ?7 WO3 ?2-14 F ??6.Type: GrantFiled: August 8, 2007Date of Patent: December 29, 2009Assignee: Schott AGInventors: Silke Wolff, Simone Monika Ritter, Ute Woelfel
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Patent number: 7637124Abstract: New and improved compositions of doped and co-doped bismuth fluorophosphate glasses for lasers is disclosed that have a high refractive index (nD) of approximately 1.6 and higher, high transmission in the near infrared part of the spectrum, and a wide glass forming domain. The disclosed glass systems Al(PO3)3—Ba(PO3)2—Bi(PO3)3—BaF2+RFx+dopands use dopants from the group of oxides and or fluorides of rare earth elements Nd, Er, Yb, Tm, Tb, Ho, Sm, Eu and Pr as well as MnO and mixtures thereof over 100 percent (wt %) of the glass-base composition. These glasses have high chemical durability, radiation resistance, efficiency of laser use in the infrared and blue spectrum, and improved duration of luminescence.Type: GrantFiled: June 21, 2009Date of Patent: December 29, 2009Assignee: AFO Research, Inc.Inventors: Alfred A. Margaryan, Ashot A. Margaryan
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Publication number: 20090314033Abstract: A glass material for mold pressing, comprising a core portion comprised of an optical glass with a degree of abrasion FA of 200 or higher and a covering portion comprised of a second glass covering at least a portion of the surface of said core portion. A method for manufacturing an optical glass element, wherein a glass material that has been preformed to a prescribed shape is heat softened and press molded with a pressing mold and the outer perimeter portion of the molded product obtained is removed by mechanical processing. The above-mentioned glass material for mold pressing is used as the glass material. To provide a means whereby an optical element does not bear scratches on optically functional surfaces through contact during handling after the press molding of press molded glass products despite being comprised of a glass material with a high degree of abrasion, and a means whereby even when scratched, the function of the optical element finally obtained is unaffected.Type: ApplicationFiled: March 28, 2007Publication date: December 24, 2009Inventors: Xuelu Zou, Yasuhiro Fujiwara
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Publication number: 20090317772Abstract: The present application provides dental compositions, and methods of making and using dental compositions that include a calcium and phosphorus releasing glass. Such dental compositions can be useful for delivering ions to the oral environment.Type: ApplicationFiled: November 7, 2005Publication date: December 24, 2009Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Richard P. Rusin, Kevin M. Cummings, Sumita B. Mitra, Paul A. Burgio, Tsi-Zong Tzou, David S. Arney
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Publication number: 20090291822Abstract: A lead-free sealing material is provided, which contains a glass with a composition including 47.5-67.5 mole % SnO, 2.5-15 mole % MgO, and 30-40 mole % P2O5. The lead-free sealing material has excellent chemical durability, low melting temperature, and good flowability during heating. The lead-free material is particularly suitable to be used as a sealing material. The lead-free sealing material may additionally contain low-thermal-expansion powdered fillers to reduce the thermal expansion coefficient of the resulting sealing material.Type: ApplicationFiled: June 30, 2008Publication date: November 26, 2009Applicants: TATUNG COMPANY, TATUNG UNIVERSITYInventors: Jiin-Jyh Shyu, Chih-Hsien Yeh
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Patent number: 7618909Abstract: A precision press-molding preform for producing an optical element for use in an imaging device using a CCD type or MOS type solid image-sensing device, which is formed of a glass composition containing, by mol %, 25 to 45% of P2O5, 0.5 to 10% of CuO, 0 to 10% of B2O3, 0 to 10% of Al2O3, 2 to 30% of Li2O, 0 to 25% of Na2O, 0 to 15% of K2O, the total content of Li2O, Na2O and K2O being 3 to 40%, 3 to 45% of BaO, 0 to 30% of ZnO, 0 to 20% of MgO, 0 to 20% of CaO, 0 to 20% of SrO, 0 to 10% of Bi2O3, 0 to 5% of La2O3, 0 to 5% of Gd2O3 and 0 to 5% of Y2O3, the total content of these components being at least 98%, and a precision press-molding preform, which is formed of a phosphate glass containing CuO, an alkali metal oxide, BaO and ZnO and having a BaO content/ZnO content molar ratio (BaO/ZnO) of greater than 1.Type: GrantFiled: April 1, 2008Date of Patent: November 17, 2009Assignee: Hoya CorporationInventors: Yasuhiro Fujiwara, Xuelu Zou
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Publication number: 20090275460Abstract: An optical glass having optical constants of a refractive index (nd) within a range from 1.50 to 1.65 and an Abbe number (? d) within a range from 50 to 65 and a glass transition temperature (Tg) of 400° C. or below wherein the shortest wavelength (? 80) at which transmittance is 80% is 370 nm or below.Type: ApplicationFiled: November 22, 2006Publication date: November 5, 2009Applicant: OHARA INC.Inventor: Masaaki Miyata
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Patent number: 7608551Abstract: New and improved compositions of doped and co-doped bismuth fluorophosphate glasses for lasers is disclosed that have a high refractive index (nD) of approximately 1.6 and higher, high transmission in the near infrared part of the spectrum, and a wide glass forming domain. The disclosed glass systems Al(PO3)3—Ba(PO3)2—Bi(PO3)3—BaF2+RFx+dopands use dopants from the group of oxides and or fluorides of rare earth elements Nd, Er, Yb, Tm, Tb, Ho, Sm, Eu and Pr as well as MnO and mixtures thereof over 100 percent (wt %) of the glass-base composition. These glasses have high chemical durability, radiation resistance, efficiency of laser use in the infrared and blue spectrum, and improved duration of luminescence.Type: GrantFiled: July 5, 2005Date of Patent: October 27, 2009Inventors: Alfred A. Margaryan, Ashot A. Margaryan
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Patent number: 7603876Abstract: An optical glass that has high-refractivity and high-dispersion properties, that is less colored and that is suitable for a shapable glass material for press-shaping and various optical elements, the optical glass containing, as glass components and by mass %, 10 to 32% of P2O5, 27 to 65% of Nb2O5, 10 to 30% of BaO, 0 to 12% of B2O3, more than 0% but not more than 20% of TiO2, more than 0% but not more than 10% of total of Li2O, Na2O and K2O, and more than 0% but not more than 1%, based on the total content of the said glass components, of Sb2O3, and having a light transmittance that is 50% at a wavelength of 420 nm or shorter.Type: GrantFiled: August 13, 2004Date of Patent: October 20, 2009Assignee: Hoya CorporationInventor: Koichiro Shiraishi
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Patent number: 7595272Abstract: A low-dispersion optical glass suitable for producing a quality preform from a molten glass and suitable for precision press-molding, which is a fluorophosphate glass containing, as essential cationic components, P5+, Al3+, at least two members selected from Mg2+, Ca2+, Sr2+ and Ba2+ as divalent cationic components (R2+) and Li+ and containing, by cationic %, 10 to 45% of P5+, 5 to 30% of Al3+, 0 to 20% of Mg2+, 0 to 25% of Ca2+, 0 to 30% of Sr2+, 0 to 33% of Ba2+, 1 to 30% of Li+, 0 to 10% of Na+, 0 to 10% of K+, 0 to 5% of Y3+, and 0 to 15% of B3+, the molar ratio of the content of F? to the total content of F? and O2?, F?/(F?+O2?), being 0.25 to 0.85, the optical glass having a refractive index (Nd) of 1.40 to 1.58 and an Abbe's number (?d) of 67 to 90.Type: GrantFiled: March 27, 2006Date of Patent: September 29, 2009Assignee: Hoya CorporationInventors: Mikio Ikenishi, Xuelu Zou
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Publication number: 20090239731Abstract: A zinc and bismuth containing, water-soluble glass composition comprising from 10 to 75 mole % P205, 5-50 mole % alkali metal oxide, up to 40 mole % Zn0 and up to 40 mole % Bi203.Type: ApplicationFiled: May 29, 2009Publication date: September 24, 2009Applicant: RECKITT BENCKISER N.V.Inventors: Karlheinz Ulrich Gerhard Hahn, KARIN WERNER
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Patent number: 7585798Abstract: A lead-free glass material for use in sealing, which has a glass composition being free of lead and exhibits high performance in the range of choices for the material to be sealed, the sealing processability, the sealing quality and the like, has a glass composition including four types of metal oxides of V2O5, ZnO, BaO and P2O5 as essential ingredients.Type: GrantFiled: July 8, 2005Date of Patent: September 8, 2009Assignee: Yamato Electronic Co., Ltd.Inventors: Masahiro Yoshida, Yasuo Hatate, Tsugumitsu Sarata, Yoshimitsu Uemura, Tomoyuki Honda
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Publication number: 20090211299Abstract: Synthetic sintered YPO4 composite materials comprising excess amount of Y2O3 in the composition and process for making such materials. The Y2O3-modified sintered YPO4 composite material exhibits improved mechanical properties compared to stoichiometric YPO4 materials. The modified YPO4 materials can be used to produce different components used in the glass-making process such as, for example, an isopipe.Type: ApplicationFiled: February 27, 2008Publication date: August 27, 2009Inventor: Cameron Wayne Tanner
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Patent number: 7553785Abstract: The lead-free, arsenic-free, preferably gadolinium-free and fluorine-free, optical glass has a refractive index of 1.86?nd?1.95, an Abbe number of 19?vd?24, a transformation temperature of ?595° C., preferably ?550° C., good crystallization stability, good processing properties and production properties. The optical glass is free of Na2O, frre of B2O3 and has a composition (based on oxide content in % by weight) of P2O5, 14-31; Nb2O5, 22-50; Bi2O3, 5-36; WO3, >10-25; GeO2, 0-14; Li2O, 0-6; K2O, 0-6; Cs2O, 1-7; MgO, 0-6; CaO, 0-6; SrO, 0-6; BaO, 0-6; ZnO, 0-6; TiO2, 0-4; ? alkali oxides, 2-12; ? alkaline earth oxides, 0-10; ? Nb2O5, WO3, Bi2O3?50 and fining agents, 0-2.Type: GrantFiled: August 15, 2006Date of Patent: June 30, 2009Assignee: Schott AGInventors: Simone Monika Ritter, Ute Woelfel, Stefanie Hansen
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Patent number: 7531473Abstract: A new ytterbium-phosphate glass and a method for producing the same are disclosed. The glass finds special use in forming laser glass. Previously the level of ytterbium that could be incorporated into a phosphate glass without leading to formation of crystals or devitrification was limited. It has been found that much higher levels of ytterbium can be incorporated if an initial glass melt is formed from phosphate and ytterbium prior to adding the other components. Using the present process ytterbium-phosphate glasses having up to 30 mole percent ytterbium can be created. The new glasses function as well and often better than previous ytterbium containing glasses as laser glasses especially when combined with one or more of the lasing ions erbium oxide, neodymium oxide, holmium oxide or thulium oxide.Type: GrantFiled: August 23, 2005Date of Patent: May 12, 2009Assignee: Kigre, Inc.Inventor: John D. Myers
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Patent number: 7531474Abstract: Disclosed is an optical glass having high-refractivity and high-dispersion properties and having little coloring, said glass containing P2O5, Nb2O5 and TiO2 as glass components, containing Sb2O3 in an amount of over 0% by weight but not more than 1% by weight based on the total content of the glass components excluding Sb2O3, having a refractive index (nd) of 1.91 or more and an Abbe's number (?d) of 21 or less and having a light transmittance that comes to be 70% at a wavelength of 500 nm or less.Type: GrantFiled: January 21, 2005Date of Patent: May 12, 2009Assignee: Hoya CorporationInventor: Kouichiro Shiraishi
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Patent number: 7521670Abstract: The invention discloses a standard for referencing luminescence signals, having an optically transparent base material comprising a lanthanum phosphate glass, a fluorophosphate glass, a fluor-crown glass, a lanthanum glass, a glass-ceramic formed therefrom or a lithium aluminosilicate glass-ceramic, the base material including a bulk doping with at least one constituent which is luminescent and comprises at least one rare earth and/or a nonferrous metal, in particular cobalt, chromium or manganese.Type: GrantFiled: February 24, 2006Date of Patent: April 21, 2009Assignees: Schott AG, BAM Bundesanstalt fuer Materialforschung und -pruefungInventors: Axel Engel, Rainer Haspel, Ute Resch-Genger, Katrin Hoffmann, Doris Ehrt, Uwe Kolberg, Joseph S. Hayden, Michael Stelzl
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Publication number: 20090075804Abstract: A method of making a glass-ceramic from at least two different metal oxides is disclosed. The method includes providing the two different metal oxides as a glass, heating the glass above the glass transition temperature of the glass to form a coalesced shape; and heating the coalesced shape to a temperature above the crystallization onset temperature of the glass, thereby forming a glass-ceramic comprising at least 1% by volume crystallites, wherein the crystallites have an average size of less than 1 micrometer. The difference between the glass transition temperature and the crystallization onset temperature is at least 25K.Type: ApplicationFiled: November 26, 2008Publication date: March 19, 2009Inventor: Anatoly Z. Rosenflanz
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Publication number: 20090069165Abstract: Optical glass having a refractive index (nd) of 1.75 or greater, and an Abbe number (?d) falling within the range of 15 to 40, which is suitable for molding by precision mold press is provided. The optical glass is characterized by including B2O3+SiO2 in an amount of 10 to 70%, Bi2O3 in an amount of 5% or more and less than 25%, RO+Rn2O in an amount of 5 to 60% (wherein R represents one or more selected from a group consisting of Zn, Ba, Sr, Ca, and Mg; and Rn represents one or more selected from a group consisting of Li, Na, K, and Cs), with each component in the range expressed in oxide-based mole, and is characterized in that transparency in the visible region is high, and that the transition point (Tg) is 520° C. or lower. The optical glass is characterized by having a spectral transmittance of 70% or greater at a wavelength of 550 nm, for a thickness of 10 mm.Type: ApplicationFiled: April 27, 2006Publication date: March 12, 2009Inventor: Jie Fu
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Publication number: 20090069166Abstract: Optical glass having a refractive index (nd) of 1.85 or greater, and an Abbe number (?d) falling within the range of 10 to 30, which is suited for molding by precision mold press is provided. The optical glass is characterized by including B2O3+SiO2 in an amount of 3 to 60%, Bi2O3 in an amount of 25 to 80%, RO+Rn2O in an amount of 5 to 60% (wherein R represents one or more selected from a group consisting of Zn, Ba, Sr, Ca, and Mg; and Rn represents one or more selected from a group consisting of Li, Na, K, and Cs), with each component in the range expressed in oxide-based mole percentage, and is characterized in that transparency in the visible region is high, and that the transition point (Tg) is 480° C. or lower. The optical glass is characterized by having a spectral transmittance of 70% or greater at a wavelength of 600 nm for a thickness of 10 mm.Type: ApplicationFiled: April 27, 2006Publication date: March 12, 2009Inventor: Jie Fu
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Patent number: 7501366Abstract: Optical glasses are described, which are useful for imaging, sensors, microscopy, medical technology, digital protection, photolithography, laser technology, wafer/chip technology, as well as telecommunication, optical communications engineering and optics/lighting in the automotive sector, with a refractive index of 1.80?nd?1.95 and an Abbe value from 19??d?28 with excellent chemical resistance and stability to crystallization. These optical glasses have a composition, in weight. % based on oxide content, of: P2O5, 14-35; Nb2O5, 45-50; Li2O, 0-4; Na2O, 0-4; K2O, 0.5-5; BaO, 17-23; ZnO, 0.1-5; TiO2, 1-<5; ZrO2, 0-6; and Sb2O3, 0.1-2.Type: GrantFiled: March 16, 2007Date of Patent: March 10, 2009Assignee: Schott AgInventors: Silke Wolff, Stefanie Hansen, Ute Woelfel
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Patent number: 7482293Abstract: An optical glass suitable for mold forming at a low temperature including, in percent by weight, 9-25 percent of P2O5, 1-20 percent of GeO2, 12-28 percent of Nb2O5, 1-7 percent of TiO2, 0-55 percent of Bi2O3, 0-38 percent of WO3, 0-3 percent of SiO2, 0-5 percent of B2O3, 0-2 percent of Al2O3, 0-5 percent of Li2O, 0-11 percent of Na2O, 0-5 percent of K2O, 0-3 percent of Ta2O5, 0-1 percent of Sb2O3, at most 13 percent of at least one R2O selected from the group consisting of Li2O, Na2O and K2O, and at most 15 percent of at least one XO selected from the group consisting of CaO, SrO, BaO and ZnO. The optical glass essentially contains no environmental and human harmful components, facilitates mass production and is stable against devitrification near its softening temperature.Type: GrantFiled: May 31, 2007Date of Patent: January 27, 2009Assignee: Asia Optical Co., IncInventors: Tsung-yuen Tsai, Hsiang-jen Shih