Phosphorus Containing Patents (Class 501/45)
  • Patent number: 6555491
    Abstract: A composition for a water soluble glass is described. The composition is unusual in that it contains no or very small quantities (up to 5 mole %) of alkali metal compounds. The composition typically comprises: P2O5: 30 to 60 mole %; CaO: 20 to 35 mole %; MgO: 15 to 25 mole %; ZnO: 0 to 10 mole %; and optionally may contain: Ag2O or Ag2O3: 0 to 5 mole %; and/or total alkali metal compounds (e.g. Na2O and/or K2O): 0 to 5 mole %. The composition is especially suitable for processing into water soluble glass fibers or wool.
    Type: Grant
    Filed: January 18, 2001
    Date of Patent: April 29, 2003
    Assignee: Giltech Limited
    Inventor: David Michael Healy
  • Publication number: 20030064876
    Abstract: The thermoplast-based glass/plastic compounds according to the invention contain a low melting point sulfophosphate glass having the following composition: 4 to 10% Li2O; 4 to 10% Na2O; 4 to 8% K2O; 1 to 2% CaO; 35 to 37% ZnO; 0 to 3% La2O3; 19 to 22% P2O5 and 19 to 22% SO3, a high-performance thermoplast, an organic additive and/or a mineral filling material and optionally also carbon black and/or a sterically hindered phosphite or phenol.
    Type: Application
    Filed: October 15, 2002
    Publication date: April 3, 2003
    Inventors: Robert Greiner, Heinrich Kapitza, Manfred Ochsenkuehn
  • Patent number: 6538805
    Abstract: In accordance with the invention, the present invention provides for a polymer comprised of a general composition. The polymer has a first rare earth element, a second rare earth element, one of the elements of Group VIA, one of the elements of Group VA, a first fully halogenated organic group, a second fully halogenated organic group. A method of manufacturing the polymer is also disclosed.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: March 25, 2003
    Assignee: Photon-X, Inc.
    Inventors: Robert A. Norwood, Anthony F. Garito, Anna Panackal
  • Patent number: 6528443
    Abstract: A composition for a water soluble glass is described. The composition is unusual in that it contains no or very small quantities (up to 5 mole %) of alkali earth metal compounds. The composition typically comprises P2O5: 40 to 60 mole %; B2O3: 0 to 10 mole %; Na2O: 30 to 40 mole %; K2O: 5 to 10 mole %; Ag2O: 0 to 5 mole %; and up to a total of 5 mole % of other compounds such as CaO, MgO etc. The composition is especially suitable for processing into water soluble glass fibers or wool since the melting point is very low, usually less than 350° C.
    Type: Grant
    Filed: January 18, 2001
    Date of Patent: March 4, 2003
    Assignee: Giltech Limited
    Inventor: David Michael Healy
  • Patent number: 6528442
    Abstract: To provide an optically transparent film containing 0.01 to 20% by weight glass forming oxide consisting of Nb2O5, V2O5, B2O3, SiO2, and P2O6; 0.01 to 20% by weight Al2O3 or Ga2O3; and 0.01 to 5% by weight hard oxide of ZrO2 and TiO2 as required; balance being ZnO, and a sputtering target for forming such a film. This sputtering target reduces occurrence of particles during sputtering, decreases the number of interruption or discontinuance of sputtering to improve production efficiency, and forms a protective film for optical disks with large transmittance and low reflectance.
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: March 4, 2003
    Assignee: Nikko Materials Company, Limited
    Inventors: Katsuo Kuwano, Hideo Takami
  • Patent number: 6529675
    Abstract: The invention is directed to optical devices comprising a solid-state structured glass substrate having at least one waveguide incorporated therein, particularly waveguides and lasers incorporating such structure. The invention is also directed to methods for modifying such devices and their properties. The waveguides and lasers of the invention provide advantageous high power and increased slope efficiency and find use, for example, in telecommunications applications.
    Type: Grant
    Filed: January 27, 2000
    Date of Patent: March 4, 2003
    Assignee: The United States of America as represented by the Secretary of Commerce
    Inventors: Joseph S. Hayden, David L. Veasey
  • Patent number: 6514891
    Abstract: The present invention related to a dielectric composition of a solid state display. The dielectric composition can be P2O5—ZnO-BaO glass, SiO2—ZnO-Ba2O3 glass of PbO—ZnO—B2O3 glass, and an oxide filler with a binary compound including PbTiO3 or a ternary compound including PbTiO3 and PbZrO3.
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: February 4, 2003
    Assignee: LG Electronics Inc.
    Inventor: Yoon Kwan Lee
  • Patent number: 6511931
    Abstract: The present invention provides a ground coat composition for use in forming an enamel layer on sheet steel that exhibits good spot acid resistance, a satin finish, good bond, and is easy-to-clean. The composition according to the invention includes a glass component that includes a blend of from about 40% to about 70% by weight of a first glass portion including one or more alkali aluminophosphate frits, up to about 30% by weight of a second glass portion including one or more zirconia-phosphate frits, and up to about 30% by weight of a third glass portion including one or more alkali borosilicate frits.
    Type: Grant
    Filed: July 16, 2001
    Date of Patent: January 28, 2003
    Assignee: Ferro Corporation
    Inventor: Charles A. Baldwin
  • Publication number: 20020139147
    Abstract: The present invention relates to resorbable glass scaffolds for use in biological applications and methods for making same. Specifically, these scaffolds are composed of phosphate glass fibers, where the rate of dissolution into biological fluids is controlled by the length of time the glass is held above its melt temperature prior to spinning the fiber.
    Type: Application
    Filed: January 30, 2001
    Publication date: October 3, 2002
    Inventors: Victor F. Janas, Kevor S. Tenhuisen
  • Publication number: 20020137620
    Abstract: Disclosed is a zinc phosphate glass consisting essentially, expressed in terms of mole percent on the oxide basis, of 31-34% P2O5, 0-2% Al2O3, 5-11% Li2O, 5-13% Na2O, 3-7% K2O, with Li2O+Na2O+K2O being 10-28%, 20-45% ZnO, 0-10% CaO, 0-10% BaO, 0-10% SrO, with CaO+BaO+SrO being 3-12%, and 0-2% SiO2, said glass exhibiting a stable glass transition temperature below 450° C., a working temperature below 500° C., and a water durability of no more than 5×10−7 g/cm2/min after immersion in water at 95° C. for 24 hours. The low-temperature glass of the present invention is particularly useful for producing glass/polymer blends. Glass/polymer blends containing the glass of the present invention are also disclosed.
    Type: Application
    Filed: January 4, 2002
    Publication date: September 26, 2002
    Inventor: Candance Jo Quinn
  • Publication number: 20020128141
    Abstract: Glass frit compositions, calculated in mole percent on an oxide basis, consisting essentially of 24.5 to 29.0% P2O5; 1.0 to 5.0% B2O3; 1.0 to 2.0% Al2O3; and sufficient amounts of SnO and ZnO (51.5 to 66.5% SnO, and 5.0-12.0% ZnO), wherein the molar ratio of SnO:ZnO is in the range of about 5.0:1 to 12:1, and 0.0 to 2.0% SiO2. The glass compositions exhibit, under NMR spectroscopic analysis of 11B nuclei, a signal containing at least two peaks at a chemical shift in the range of approximately −18 to −25 ppm. The frit compositions exhibit long term stability, durability, and resistance to attack against moisture in high temperature and humidity conditions and are capable of attaching optical fiber Bragg gratings without the use of a hermetic chamber and the like. An optoelectronic device that employs a sealing material that comprises a frit made from the glass compositions.
    Type: Application
    Filed: March 16, 2001
    Publication date: September 12, 2002
    Inventors: Carol L. Buhrmaster, Robert Morena, Kamjula P. Reddy, Randall E. Youngman
  • Patent number: 6409396
    Abstract: The present invention relates to a fiber optic system including a light source, a fiber optic transmission component, a receiver or transmitter of radiation, and an interference filter. The interference filter may include a glass substrate with at least two interference layers coated thereon. The glass substrate can include: Oxide Range P2O5 30-70 Al2O3  5-15 R′O  5-15 R′ = Mg, Ca, Sr, Ba, Zn, Pb R2O R = Li, Na, K 15-40 where the glass substrate has a coefficient of, thermal expansion of 130-210×10−7/° C. at 30° C. to 70° C.
    Type: Grant
    Filed: July 30, 2001
    Date of Patent: June 25, 2002
    Assignee: Schott Glass Technologies, Inc.
    Inventors: Alexander J. Marker, III, Sally Pucilowski, Joseph Hayden
  • Publication number: 20020061809
    Abstract: The present invention provides a composition for use in forming a white porcelain enamel coating on aluminized or galvanized steel. The composition according to the present invention includes a solids portion including a glass component and a white pigment. The glass component includes one or more glass frits including by weight from about 30% to 50% P2O5, from about 15% to about 30% Al2O3, from about 8% to about 40% X2O where X=Na and/or K, up to about 30% TiO2, up to about 12% B2O3, up to about 10% K2O, up to about 10% ZnO, up to about 8% SiO2, up to about 7% La2O3, up to about 5% Li2O, and up to about 15% F. The white pigment include TiO2.
    Type: Application
    Filed: August 17, 2001
    Publication date: May 23, 2002
    Applicant: Ferro France S.A.R.L.
    Inventors: Alain Aronica, Emmanuel Marinho, David Coutouly, Luc Allemeersch, Christophe Reb
  • Patent number: 6383961
    Abstract: A composition of a dielectric for a plasma display panel in user for fabricating a dielectric thick film for a front substrate having a low sintering temperature, a low thermal expensive coefficient, a high dielectric constant and a high withstand voltage. The composition of a dielectric is a P2O5—ZnO—PbO glass having composition ratios of 30˜60 wt % of P2O5, 5˜40 wt % of PbO, 0˜5 wt % of MgO, 0˜5 wt % of CaO, 0˜10 wt % of La2O3, 0˜5 wt % of SrO, 1˜5 wt % of Al2O3, 0˜2 wt % of Sb2O3, 0˜2 wt % of As2O3, 5˜25 wt % of BaO, and 0˜5 wt % of TeO2.
    Type: Grant
    Filed: May 17, 2000
    Date of Patent: May 7, 2002
    Assignee: LG Electronics Inc.
    Inventor: Byung-Gil Ryu
  • Patent number: 6376398
    Abstract: A dielectric composition for a plasma display panel. In the dielectric composition, a P2O5—ZnO—BaO group glass is used. Accordingly, the dielectric composition is capable of meeting optical, thermal and electrical characteristic requirements of a dielectric layer and allows the dielectric layer to have a light weight.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: April 23, 2002
    Assignee: LG Electronics Inc.
    Inventors: Yoon Kwan Lee, Byung Gil Ryu
  • Publication number: 20020042337
    Abstract: An optical glass having a high refractive index and high dispersion characteristics that is suited to application to precision press molding to precisely mold the shape of final products for objectives not requiring grinding or polishing. An optical glass exhibiting a refractive index in the range of from 1.75 to 2.0, an Abbé number in the range of from 20 to 28.5. Optical parts comprised of this glass; press-molding materials comprised of this glass; methods of manufacturing the same; and methods of manufacturing molded glass products employing these materials.
    Type: Application
    Filed: June 29, 2001
    Publication date: April 11, 2002
    Inventors: Xuelu Zou, Hiromasa Tawarayama, Kazutaka Hayashi, Hiroshi Kawazoe
  • Patent number: 6355586
    Abstract: A low melting point glass consisting essentially of, as represented by mol % based on the following oxides: Mol % SnO   2 to 37.5, ZnO 5 to 73, P2O5 16 to 50,  Li2O 0 to 9,  Na2O 0 to 9,  K2O 0 to 9,  Al2O3 0 to 20, B2O3 0 to 30, SiO2 0 to 20, MgO 0 to 35, CaO 0 to 35, SrO 0 to 35, BaO 0 to 35, In2O3 0 to 10, WO3 0 to 10, wherein SnO+ZnO+P2O5+B2O3 is at least 76 mol %, Li2O+Na2O+K2O is from 0 to 9 mol %, MgO+CaO+SrO+BaO is from 0 to 35 mol %, and the molar ratio of SnO to ZnO is less than 1.
    Type: Grant
    Filed: January 31, 2000
    Date of Patent: March 12, 2002
    Assignee: Asahi Glass Company, Limited
    Inventors: Hiroshi Usui, Yasuko Dotani, Ryuichi Tanabe, Tsuneo Manabe
  • Patent number: 6352950
    Abstract: A family of alkali-tungsten-tellurite glasses that consist essentially of, as calculated in mole percent, 10-90% TeO2, at least 5% W03 and at least 0.5% R2O where R is Li, Na, K, Cs, Tl and mixtures, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: March 5, 2002
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Adam J. G. Ellison
  • Patent number: 6344425
    Abstract: A family of fluorotellurite glasses, the composition of which consist essentially of, as calculated in mole percent, 30-75% TeO2, 15-60% ZnF2 and 0.005-10% of an oxide of erbium, thulium or holmium, and amplifying optical components produced from these glasses.
    Type: Grant
    Filed: November 19, 1999
    Date of Patent: February 5, 2002
    Assignee: Corning Incorporated
    Inventor: Bruce G. Aitken
  • Publication number: 20020010065
    Abstract: An optical glass wherein an amount of change in refractive index (&Dgr;n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43W, pulse repetition rate of 5 kHz and pulse width of 4OO ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.
    Type: Application
    Filed: June 1, 2001
    Publication date: January 24, 2002
    Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
  • Patent number: 6333282
    Abstract: The present invention provides an optical glass for precision molding, having excellent properties, i.e. yield temperature (At) of at most 550° C., refractive index (nd) of at least 1.83 and Abbe number (&ngr;d) of at most 26.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented, in term of atoms for making up the glass, by the following chemical composition (wt %) P2O5 14.0 to 31.0% B2O3   0 to 5.0% GeO2   0 to 14.0% Sum of P2O5 + B2O3 + GeO2 14.0 to 35.0% Li2O   0 to 6.0% Na2O  2.5 to 14.0% Sum of Li2O + Na2O  2.5 to 15.0% Nb2O5 22.0 to 50.0% WO3   0 to 30.0% Bi2O3  5.0 to 36.0% BaO   0 to 22.0%.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: December 25, 2001
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Koji Nakahata, Koichi Tsuchiya, Shinobu Nagahama
  • Publication number: 20010031691
    Abstract: A glass includes (a) a matrix containing a compound of at least one nonmetallic element; and (b) a particle selectively formed in the matrix. This particle is made of the at least one nonmetallic element. A process for producing such glass includes (a) providing a blank glass containing a compound of at least one nonmetallic element; (b) condensing a pulsed laser beam to a focal point in the blank glass such that a particle is selectively formed in the blank glass at a position corresponding to the focal point, the particle being made of the at least one nonmetallic element dissociated from the compound; and (c) moving the focal point in the blank glass to produce a pattern of the particle. The glass is suitable for optical functional elements.
    Type: Application
    Filed: February 21, 2001
    Publication date: October 18, 2001
    Inventors: Kiyotaka Miura, Seiji Fujiwara, Takuya Teshima, Natsuya Nishimura, Yoshinori Kubota
  • Patent number: 6292292
    Abstract: Disclosed are cost-effective, compact, optically pumped, high gain, rare earth polymer materials such as, erbium (Er3+) perfluoro polymers, optical fibers made from the materials and waveguide amplifiers made from the materials having low-loss at telecommunications wavelengths for operation in communications network systems. The polymer amplifier is based on the use of novel high performance rare earth (RE) polymer materials. The new discovered highly transparent RE polymer materials are directly synthesized at high RE ion concentrations (˜1020−1021 rare earth ion/cm3˜10% wt) with each metal ion encapsulated and physically buffered by insulating, covalently bonded, perfluorinated phosphate ligands that then form the high temperature stable, polymer backbone matrix. This is distinctly different from widely studied inorganic glasses and single crystals where RE ion salts are doped directly into the host but only to relatively low levels (<0.1% wt).
    Type: Grant
    Filed: February 18, 2000
    Date of Patent: September 18, 2001
    Assignee: Photon-X
    Inventors: Anthony F. Garito, Robert A. Norwood, Renyuan Gao, Anna Panackal
  • Patent number: 6287995
    Abstract: A sealing glass composition for bonding the upper plate and the lower plate of a flat panel display device is described. The sealing glass composition includes a low melting point glass containing PbO of less than 20% and having a sintering temperature of less than 500° C. The sealing glass composition contains a low component of PbO to thereby decrease environmental contamination and increase work efficiency. Also, the sealing glass prevents the deformation and cracking of a substrate caused by thermal and mechanical stress and reduces the sintering temperature to thereby enhance the airtightness of the sealing glass.
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: September 11, 2001
    Assignee: LG Electronics Inc.
    Inventor: Yoon Kwan Lee
  • Patent number: 6284685
    Abstract: Devices are made comprising a tin-phosphorous oxyfluoride glass, which has been exposed to light, preferably shorter in wavelength than the absorption edge of the glass, to change the refractive index change of the glass. The glasses can be used to form planar and fiber devices, including core/clad structures for guiding light.
    Type: Grant
    Filed: March 23, 2000
    Date of Patent: September 4, 2001
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, Robert W. Boyd, Stojan Radic, Paul A. Tick
  • Patent number: 6277775
    Abstract: A GeAs sulphide glass family of transparent glasses having transmission far into the infrared portion of the spectrum, containing a source of phosphorus ion as a co-dopant to effect dispersion of a rare earth metal ion dopant in the glass, an optical component comprising the glass, and a method of dispersing a rare earth metal ion in the glass.
    Type: Grant
    Filed: January 25, 2000
    Date of Patent: August 21, 2001
    Assignee: Corning Incorporated
    Inventor: Bruce G. Aitken
  • Patent number: 6277776
    Abstract: A low temperature fluorophosphate glass useful for joining single-mode fluoride and silica optical fibers includes 5 to 7 mol % InF3, 20 to 35 mol % PbF2 and 57.5 to 75 mol % P2O5. An alkali for maintaining a low glass transition temperature can be included. Up to 25% (glass molar basis) of the P2O5 can be replaced by PbO.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: August 21, 2001
    Assignee: IPG Photonics Corporation
    Inventors: Alexis Clare, Wesley King, Ian Grainge Clarke
  • Patent number: 6228787
    Abstract: This invention relates to fluorescent photosensitive glasses and a process for the production thereof. The fluorescent photosensitive glasses according to the present invention employ silicate or phosphate glass compositions including minor amounts of one or more fluorescent agents (e.g., ytterbium (Yb), samarium (Sm), europium (Eu)) and one or more photosensitive agents (e.g., erbium (Er), thulium (Tm), praseodymium (Pr), ytterbium (Yb), holmium (Ho), samarium (Sm), cerium (Ce), dysprosium (Dy), terbium (Tb), neodymium (Nd)). The inventive fluorescent photosensitive glass can be used in photographic applications, florescent displays and computer memories.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: May 8, 2001
    Inventor: Eugen Pavel
  • Patent number: 6225244
    Abstract: A glass for a near infrared absorption filter, which has spectral characteristics that it efficiently transmits light in a wavelength region of from ultraviolet region to 600 nm and selectively absorbs light in a near infrared region of a wavelength of larger than about 600 nm, a near infrared absorption filter formed of the above glass, and a solid-state image sensing device to which the above filter is applied, the glass comprising, by cationic %, 35 to 54% of P, 20 to 47% of Zn, 0 to 8% of the total, R, of Li, Na, K and Cs which are monovalent metal elements, 0 to 17% of the total, M, of Mg, Ca, Ba, Sr and Pb which are divalent metal elements, the total of R and M being 1 to 22%, 0.1 to 7% of As, 0.2 to 9% of Cu and 0 to 6% of Al.
    Type: Grant
    Filed: January 20, 1999
    Date of Patent: May 1, 2001
    Assignee: Hoya Corporation
    Inventor: Hironori Oguma
  • Patent number: 6194333
    Abstract: A dielectric composition for a plasma display panel that is capable of satisfying the required characteristics of a dielectric applied to an barrier rib and a dielectric layer of a plasma display panel. The dielectric composition includes a parent glass of P2O5—PbO—K2O group and an oxide filler. The dielectric has relatively low sintering temperature and dielectric constant, a high reflectivity and a reduced amount of PbO component, so that it can minimize an environment contamination and reduce a weight of the device.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: February 27, 2001
    Assignee: LG Electronics Inc.
    Inventor: Byung Gil Ryu
  • Patent number: 6156684
    Abstract: In a light polarization control element using a stress-optical coefficient glass, the stress-optical coefficient glass is substantially composed of a phosphorous acid glass containing 20 to 60 percent by weight of P.sub.2 O.sub.5 and 40 to 73 percent by weight of BaO and PbO.
    Type: Grant
    Filed: June 16, 1998
    Date of Patent: December 5, 2000
    Assignee: Hoya Corporation
    Inventors: Kouichi Sato, Kazuo Tachiwana
  • Patent number: 6103648
    Abstract: A composition for a bulk conducting glass comprising P.sub.2 O.sub.5, V.sub.2 O.sub.5, PbO, and FeO, the ratio of the molar percentage of P.sub.2 O.sub.5 to V.sub.2 O.sub.5 being in the range of about 1 to about 6, and the P.sub.2 O.sub.5 and V.sub.2 O.sub.5 being present in an aggregate amount of at least about 50 mole percent, the PbO being present in the glass in an amount in excess of 15 mole percent, and the FeO being present in amount of about 0 to about 30 mole percent. The composition may also include MnO or Sb.sub.2 O.sub.3 in an amount of up to about 2 mole percent. The composition may be formed into fibers for use in microchannel plates and other devices where bulk conductivity in glass is advantageous.
    Type: Grant
    Filed: May 28, 1998
    Date of Patent: August 15, 2000
    Assignee: Circon Corporation
    Inventor: Jay J. L. Yi
  • Patent number: 6093484
    Abstract: Phosphate or flurorophosphate glass surfaces are polished to smooth, highly accurate surfaces using a glass polishing liquid having a pH approximating the pH of the glass being polished. A highly polished glass surface results suitable for use optical filters and solid camera devices and solid image sensors. Phosphate and fluorophosphate glass filters and the like so formed have hair-like surface flaws, if any, of a width of 7 .mu.m or less.
    Type: Grant
    Filed: April 2, 1998
    Date of Patent: July 25, 2000
    Assignee: Hoya Corporation
    Inventor: Hironori Oguma
  • Patent number: 6048811
    Abstract: A fusion sealing material, and a fusion seal prepared therefrom, consisting essentially of at least 65% of a SnO--ZnO--P.sub.2 O.sub.5 glass fit, up to 10% of a crystallization catalyst and 0-25% of an additive that decreases the effective CTE of a seal prepared with the material.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: April 11, 2000
    Assignee: Corning Incorporated
    Inventor: Robert Morena
  • Patent number: 5965469
    Abstract: The present invention provides a glass composition for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, and copper alloys, which includes between about 10 and about 25 mole percent Na.sub.2 O, between about 10 and about 25 mole percent K.sub.2 O, between about 4 and about 15 mole percent Al.sub.2 O.sub.3, between about 35 and about 50 mole percent P.sub.2 O.sub.5, B.sub.2 O.sub.3 in a concentration not exceeding 10 mole percent, and MXO in a concentration not exceeding 12 mole percent, wherein MXO is a metal oxide selected from the group consisting of PbO, BaO, CaO and MgO or a mixture thereof. This composition is suitable to hermetically seal to components for use in RF-interconnection applications.
    Type: Grant
    Filed: March 20, 1998
    Date of Patent: October 12, 1999
    Assignee: Sandia Corporation
    Inventors: Riley D. Kilgo, Richard K. Brow, Larry Kovacic
  • Patent number: 5952399
    Abstract: A dental material based on an organic polymerisable binding agent has a content ofA) one or more mixed apatites of the typeA1) A.sub.10 (XO.sub.4).sub.6 Z.sub.2 +/B*.sub.10-u C*.sub.u (Y*).sub.6 Z'.sub.2 and/orA2) A'.sub.10-r (X'O.sub.4).sub.6-s Z".sub.2-t +/B'.sub.r (Y').sub.s Q.sub.t -B".sub.10-u' C'.sub.u' (Y").sub.6 Z'".sub.2 and/orA3) A".sub.10-r' (X"O.sub.4).sub.6-s' Z"".sub.2-t' +/A'".sub.r' (X'"O.sub.4).sub.s' +/B'".sub.10-u" C".sub.u" (Y'").sub.6 Z'"".sub.2in which the formulae assume the significance specified in the description, in a quantity that is effective for the absorption of ions from the biological application environment of the dental material. The polymerisable dental material has variably adjustable transparency, good polishability, high strength and the capacity to release and absorb ions into and from a biological environment. Also described is a process for using the mixed apatites A1), A2) and/or A3) in polymerisable dental materials.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: September 14, 1999
    Assignee: Degussa Aktiengesellschaft
    Inventor: Harald Rentsch
  • Patent number: 5880045
    Abstract: Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole %.iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: March 9, 1999
    Assignee: Brookhaven Science Associates
    Inventors: Hui Cao, Jay W. Adams, Paul D. Kalb
  • Patent number: 5840638
    Abstract: Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole % iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.
    Type: Grant
    Filed: December 23, 1996
    Date of Patent: November 24, 1998
    Assignee: Brookhaven Science Associates
    Inventors: Hui Cao, Jay W. Adams, Paul D. Kalb
  • Patent number: 5755998
    Abstract: According to the present invention, there is provided a fluorophosphate fluorescent glass, capable of converting invisible ultraviolet rays into visually observable visible rays with a high efficiency and available for controlling the optical axis of a laser beam such as excimer laser, etc. The feature of this fluorescent glass consists in a fluorophosphate fluorescent glass capable of exhibiting fluorescence in the visible region, having a chemical composition comprising, at least, (I) phosphorus (P), oxygen (O) and fluorine (F), as glass constituting components, and (II) at least one member selected from the group consisting of divalent europium, terbium, samarium and manganese, as a fluorescent agent, the divalent europium being contained as an essential component and at least one of samarium and manganese being contained as an essential component when terbium is contained.
    Type: Grant
    Filed: November 20, 1996
    Date of Patent: May 26, 1998
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Yamazaki, Masaaki Otsuka, Shinobu Nagahama, Naruhito Sawanobori
  • Patent number: 5714244
    Abstract: A material is impregnated with an aqueous solution containing precursors of a glass-containing phosphate base modified at least by the presence of zinc oxide, then dried and heat treated to form an internal oxidation protection constituted by the modified phosphate glass-containing base. The precursors are introduced into the aqueous solution so as to form a glass-containing base in which the molar ratio between the glass modifying oxides, comprising zinc oxide, and the glass forming oxides, principally comprising or consisting of phosphoric anhydride, is sufficiently high, in particular at least 0.6, preferably 0.9, to confer a resistance to corrosion by moisture on the glass-containing phosphate base.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: February 3, 1998
    Assignee: Societe Europeenne de Propulsion
    Inventors: Rodolphe Delaval, Gerard Palavit, Jacques Rey, Michel Laxague, Jacques Thebault
  • Patent number: 5668066
    Abstract: A near infrared absorption filter glass containing______________________________________ P.sub.2 O.sub.5 35.about.50% Li.sub.2 O 0.about.5% Na.sub.2 O 0.about.12% K.sub.2 O 0.about.20% Cs.sub.2 O 0.about.20% R.sub.2 O (in which R is an alkali metal) 1.5.about.20% ZnO 17.about.48% MgO 0.about.7% CaO 0.about.7% SrO 0.about.7% BaO 0.about.12% R'O (in which R' is an alkaline earth metal) 0.about.15% CuO 0.2.about.12% ______________________________________ in which % stands for % by weighthas excellent transmittance characteristics in the ultraviolet region over conventional phosphate-based glass, has glass stability and processability which enable the mass production, and further has sufficient weatherability.
    Type: Grant
    Filed: July 24, 1996
    Date of Patent: September 16, 1997
    Assignee: Hoya Corporation
    Inventors: Hironori Oguma, Kazuo Tachiwana
  • Patent number: 5609660
    Abstract: Polymeric compositions having a polymeric component and an inorganic filler which undergoes a crystal (phase) inversion within the operating temperature range of the composition are provided. The present invention relates to a method for reducing the water sensitivity of particles of a crystallized phosphate glass. The particles are composed of P.sub.2 O.sub.5 and one or more cations selected from the group consisting of magnesium, cobalt, arsenic, zinc, iron, aluminum, and zirconium. The method includes nitriding the particles.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 11, 1997
    Assignee: Corning Incorporated
    Inventors: Gaylord L. Francis, Ronald E. Johnson, Paul A. Tick, Lung-Ming Wu
  • Patent number: 5529960
    Abstract: The subject invention is directed at wherein either a portion of the ZnO or alkali metals, or both, found in prior art glasses, is replaced by Cu.sub.2 O, i.e., cuprous or monovalent copper. In addition to the Cu.sub.2 O substitution, the inventive glass contains a required metal oxide constituent which is necessary to enhance durability. More specifically, the present invention discloses a glass consisting essentially of, expressed in terms of mole percent on the oxide basis, of about 42-54% P.sub.2 O.sub.5, 10-30% Cu.sub.2 O, 10-30% R.sub. O and 3-12% of a component selected from the group consisting of 0-7% MoO.sub.3, 0-10 Fe.sub.2 O.sub.3, 0-10% Al.sub.2 O.sub.3 and 0-7%WO.sub.3. In addition, the composition includes up to a total of 45% of optional ingredients in the indicated proportions selected from the group consisting of 0-15% MgO, 0-20% CaO, 0-20% SrO, 0-20% BaO, 0-25% MgO+CaO+SrO+BaO, 0-35% ZnO, 0-10% MnO, 0-2% CeO.sub.2, 0-10% B.sub.2 O.sub.3, 0-2% Ln.sub.2 O.sub.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: June 25, 1996
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, George H. Beall, James E. Dickinson, Jr.
  • Patent number: 5529961
    Abstract: The subject invention is directed at glasses wherein either a portion of the ZnO or alkali metals, or both, is replaced by Cu.sub.2 O, i.e., monovalent copper. Specifically, the present invention is directed at a glass consisting essentially of, expressed in terms of mole percent on the oxide basis, 28-42% P.sub.2 O.sub.5, 15-30% Cu.sub.2 O, 10-30% R.sub.2 O, wherein R.sub.2 O is selected from the group consisting of 0-15% Li.sub.2 O, 0-20% Na.sub.2 O, and 0-10% K.sub.2 O, and up to a total of 45% of optional ingredients in the indicated proportions selected from the group consisting of 0-10% Al.sub.2 O.sub.3, 0-15% MgO, 0-20% CaO, 0-20% SrO, 0-20% BaO, 0-25% MgO+CaO+SrO+BaO, 0-35% ZnO, 0-10% MnO, 0-2% CeO.sub.2, 0-2% Ln.sub.2 O.sub.3, 0-10 Al.sub.2 O.sub.3 0-10% B.sub.2 O.sub.3, 0-10 Fe.sub.2 O.sub.3 0-10% Al.sub.2 O.sub.3 +B.sub.2 O.sub.3 +Fe.sub.2 O.sub.3, 0-7% MoO.sub.3 0-7% WO.sub.3 0-7% MoO.sub.3 +WO.sub.3, and 0-8% F, the latter as analyzed in weight percent.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: June 25, 1996
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, George H. Beall, James E. Dickinson, Jr.
  • Patent number: 5519555
    Abstract: A magnetic head for use in a magnetic recording and reproducing system, which head is excellent in magnetic properties, resistance to abrasion, durability and mass-producibility, comprises a pair of magnetic cores each having a substrate and a magnetic alloy film formed on the substrate, the cores being disposed in a manner such that the magnetic alloy films are opposed to and slightly spaced apart from each other, and glass bondings disposed between the magnetic alloy films to integrate the pair of magnetic cores, and a process for producing the same, and a magnetic recording and reproducing system using the magnetic head.
    Type: Grant
    Filed: August 3, 1994
    Date of Patent: May 21, 1996
    Assignee: Hitachi, Ltd.
    Inventors: Takashi Naitoh, Takashi Namekawa, Seiichi Yamada, Kunihiro Maeda, Kenkichi Inada
  • Patent number: 5518970
    Abstract: The present invention relates generally to a novel and unique class of gly materials and methods of making such materials in which substantially all of the anions are nitride ions, in contrast to the oxide ions of conventional optical glasses, or the fluoride ions of the more recently discovered fluoride optical glasses. The chemical nature of these new glasses dispose the glassy materials to a remarkable combination of desirable properties, including, but not limited to, high hardness, high refractive index and high softening temperature.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: May 21, 1996
    Assignee: Arizona Board of Regents acting on behalf of Arizona State University
    Inventors: Paul F. McMillan, C. Austen Angell, Tor Grande, John R. Holloway
  • Patent number: 5510301
    Abstract: The present invention is directed to the preparation of frit pastes suitable for sealing together preformed glass parts, being especially suitable for sealing glass panels to funnels of cathode ray tubes. The pastes comprise a mixture of frit particles, a lacquer, and at least one additive in an amount of 0.0005-2% by weight total of the lacquer. The preferred additives are selected from the group of alkyl organic phosphate esters, a mixed titanium ortho ester complexes, and substituted sorbitols in the polyol acetal family.
    Type: Grant
    Filed: October 24, 1994
    Date of Patent: April 23, 1996
    Inventors: Kimberly S. Fink, Joshua U. Otaigbe
  • Patent number: 5455211
    Abstract: The present invention relates generally to a novel and unique class of gly materials and methods of making such materials in which substantially all of the anions are nitride ions, in contrast to the oxide ions of conventional optical glasses, or the fluoride ions of the more recently discovered fluoride optical glasses. The chemical nature of these new glasses dispose the glassy materials to a remarkable combination of desirable properties, including, but not limited to, high hardness, high refractive index and high softening temperature.
    Type: Grant
    Filed: April 19, 1994
    Date of Patent: October 3, 1995
    Assignee: Arizona Board of Regents acting on behalf of Arizona State University
    Inventors: Paul F. McMillan, C. Austen Angell, Tor Grande, John R. Holloway
  • Patent number: 5364819
    Abstract: A Faraday rotator glass composition based on a fluoride glass, phosphate glass, fluorophosphate glass or a mixture thereof is doped with a lanthanide in a concentration sufficient to provide a Verdet constant above at least 2870 deg/Tesla-meter [(1 min/cm-Oe).times.(1.667.times.10.sup.4)=1 deg/Tesla-meter] and optical transmission above at least 50 percent in a 25 mm thick polished glass sample at least at one wavelength in the 200 to 400 nm wavelength region. The Faraday rotator glass also includes monovalent non-lanthanide cations such as Na, Li, K or mixtures thereof in a concentration sufficient to provide a Verdet constant above at least 2870 deg/Tesla-meter and optical transmission above at least 50 percent in a 25 mm thick polished glass sample at least at one wavelength in the 200 to 400 nm wavelength region.
    Type: Grant
    Filed: April 28, 1993
    Date of Patent: November 15, 1994
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: James L. Dexter, David G. Cooper, Douglas H. Blackburn, David C. Cranmer, Dale A. Kauffman
  • Patent number: 5334559
    Abstract: A glass consisting essentially of (on an oxide composition basis):______________________________________ Mole % ______________________________________ P.sub.2 O.sub.5 50-70 Al.sub.2 O.sub.3 4-13 Na.sub.2 O 10-35 La.sub.2 O.sub.3 0-6 Ln.sub.2 O.sub.3 >0-6 Sum R'O 0-20 (R' = Mg, Ca, Sr, Ba, Zn and Pb) Sum R.sub.2 O 0-18 (R = Li, K, Rb, Cs) ______________________________________wherein Ln.sub.2 O.sub.3 represents the sum of the oxides of active lasing lanthanides of atomic number 58-71.
    Type: Grant
    Filed: February 1, 1993
    Date of Patent: August 2, 1994
    Assignee: Schott Glass Technologies, Inc.
    Inventor: Joseph S. Hayden