Phosphorus Containing Patents (Class 501/45)
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Patent number: 6555491Abstract: A composition for a water soluble glass is described. The composition is unusual in that it contains no or very small quantities (up to 5 mole %) of alkali metal compounds. The composition typically comprises: P2O5: 30 to 60 mole %; CaO: 20 to 35 mole %; MgO: 15 to 25 mole %; ZnO: 0 to 10 mole %; and optionally may contain: Ag2O or Ag2O3: 0 to 5 mole %; and/or total alkali metal compounds (e.g. Na2O and/or K2O): 0 to 5 mole %. The composition is especially suitable for processing into water soluble glass fibers or wool.Type: GrantFiled: January 18, 2001Date of Patent: April 29, 2003Assignee: Giltech LimitedInventor: David Michael Healy
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Publication number: 20030064876Abstract: The thermoplast-based glass/plastic compounds according to the invention contain a low melting point sulfophosphate glass having the following composition: 4 to 10% Li2O; 4 to 10% Na2O; 4 to 8% K2O; 1 to 2% CaO; 35 to 37% ZnO; 0 to 3% La2O3; 19 to 22% P2O5 and 19 to 22% SO3, a high-performance thermoplast, an organic additive and/or a mineral filling material and optionally also carbon black and/or a sterically hindered phosphite or phenol.Type: ApplicationFiled: October 15, 2002Publication date: April 3, 2003Inventors: Robert Greiner, Heinrich Kapitza, Manfred Ochsenkuehn
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Patent number: 6538805Abstract: In accordance with the invention, the present invention provides for a polymer comprised of a general composition. The polymer has a first rare earth element, a second rare earth element, one of the elements of Group VIA, one of the elements of Group VA, a first fully halogenated organic group, a second fully halogenated organic group. A method of manufacturing the polymer is also disclosed.Type: GrantFiled: November 28, 2000Date of Patent: March 25, 2003Assignee: Photon-X, Inc.Inventors: Robert A. Norwood, Anthony F. Garito, Anna Panackal
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Patent number: 6528443Abstract: A composition for a water soluble glass is described. The composition is unusual in that it contains no or very small quantities (up to 5 mole %) of alkali earth metal compounds. The composition typically comprises P2O5: 40 to 60 mole %; B2O3: 0 to 10 mole %; Na2O: 30 to 40 mole %; K2O: 5 to 10 mole %; Ag2O: 0 to 5 mole %; and up to a total of 5 mole % of other compounds such as CaO, MgO etc. The composition is especially suitable for processing into water soluble glass fibers or wool since the melting point is very low, usually less than 350° C.Type: GrantFiled: January 18, 2001Date of Patent: March 4, 2003Assignee: Giltech LimitedInventor: David Michael Healy
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Patent number: 6528442Abstract: To provide an optically transparent film containing 0.01 to 20% by weight glass forming oxide consisting of Nb2O5, V2O5, B2O3, SiO2, and P2O6; 0.01 to 20% by weight Al2O3 or Ga2O3; and 0.01 to 5% by weight hard oxide of ZrO2 and TiO2 as required; balance being ZnO, and a sputtering target for forming such a film. This sputtering target reduces occurrence of particles during sputtering, decreases the number of interruption or discontinuance of sputtering to improve production efficiency, and forms a protective film for optical disks with large transmittance and low reflectance.Type: GrantFiled: December 7, 2000Date of Patent: March 4, 2003Assignee: Nikko Materials Company, LimitedInventors: Katsuo Kuwano, Hideo Takami
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Patent number: 6529675Abstract: The invention is directed to optical devices comprising a solid-state structured glass substrate having at least one waveguide incorporated therein, particularly waveguides and lasers incorporating such structure. The invention is also directed to methods for modifying such devices and their properties. The waveguides and lasers of the invention provide advantageous high power and increased slope efficiency and find use, for example, in telecommunications applications.Type: GrantFiled: January 27, 2000Date of Patent: March 4, 2003Assignee: The United States of America as represented by the Secretary of CommerceInventors: Joseph S. Hayden, David L. Veasey
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Patent number: 6514891Abstract: The present invention related to a dielectric composition of a solid state display. The dielectric composition can be P2O5—ZnO-BaO glass, SiO2—ZnO-Ba2O3 glass of PbO—ZnO—B2O3 glass, and an oxide filler with a binary compound including PbTiO3 or a ternary compound including PbTiO3 and PbZrO3.Type: GrantFiled: July 10, 2000Date of Patent: February 4, 2003Assignee: LG Electronics Inc.Inventor: Yoon Kwan Lee
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Patent number: 6511931Abstract: The present invention provides a ground coat composition for use in forming an enamel layer on sheet steel that exhibits good spot acid resistance, a satin finish, good bond, and is easy-to-clean. The composition according to the invention includes a glass component that includes a blend of from about 40% to about 70% by weight of a first glass portion including one or more alkali aluminophosphate frits, up to about 30% by weight of a second glass portion including one or more zirconia-phosphate frits, and up to about 30% by weight of a third glass portion including one or more alkali borosilicate frits.Type: GrantFiled: July 16, 2001Date of Patent: January 28, 2003Assignee: Ferro CorporationInventor: Charles A. Baldwin
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Publication number: 20020139147Abstract: The present invention relates to resorbable glass scaffolds for use in biological applications and methods for making same. Specifically, these scaffolds are composed of phosphate glass fibers, where the rate of dissolution into biological fluids is controlled by the length of time the glass is held above its melt temperature prior to spinning the fiber.Type: ApplicationFiled: January 30, 2001Publication date: October 3, 2002Inventors: Victor F. Janas, Kevor S. Tenhuisen
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Publication number: 20020137620Abstract: Disclosed is a zinc phosphate glass consisting essentially, expressed in terms of mole percent on the oxide basis, of 31-34% P2O5, 0-2% Al2O3, 5-11% Li2O, 5-13% Na2O, 3-7% K2O, with Li2O+Na2O+K2O being 10-28%, 20-45% ZnO, 0-10% CaO, 0-10% BaO, 0-10% SrO, with CaO+BaO+SrO being 3-12%, and 0-2% SiO2, said glass exhibiting a stable glass transition temperature below 450° C., a working temperature below 500° C., and a water durability of no more than 5×10−7 g/cm2/min after immersion in water at 95° C. for 24 hours. The low-temperature glass of the present invention is particularly useful for producing glass/polymer blends. Glass/polymer blends containing the glass of the present invention are also disclosed.Type: ApplicationFiled: January 4, 2002Publication date: September 26, 2002Inventor: Candance Jo Quinn
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Publication number: 20020128141Abstract: Glass frit compositions, calculated in mole percent on an oxide basis, consisting essentially of 24.5 to 29.0% P2O5; 1.0 to 5.0% B2O3; 1.0 to 2.0% Al2O3; and sufficient amounts of SnO and ZnO (51.5 to 66.5% SnO, and 5.0-12.0% ZnO), wherein the molar ratio of SnO:ZnO is in the range of about 5.0:1 to 12:1, and 0.0 to 2.0% SiO2. The glass compositions exhibit, under NMR spectroscopic analysis of 11B nuclei, a signal containing at least two peaks at a chemical shift in the range of approximately −18 to −25 ppm. The frit compositions exhibit long term stability, durability, and resistance to attack against moisture in high temperature and humidity conditions and are capable of attaching optical fiber Bragg gratings without the use of a hermetic chamber and the like. An optoelectronic device that employs a sealing material that comprises a frit made from the glass compositions.Type: ApplicationFiled: March 16, 2001Publication date: September 12, 2002Inventors: Carol L. Buhrmaster, Robert Morena, Kamjula P. Reddy, Randall E. Youngman
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Patent number: 6409396Abstract: The present invention relates to a fiber optic system including a light source, a fiber optic transmission component, a receiver or transmitter of radiation, and an interference filter. The interference filter may include a glass substrate with at least two interference layers coated thereon. The glass substrate can include: Oxide Range P2O5 30-70 Al2O3 5-15 R′O 5-15 R′ = Mg, Ca, Sr, Ba, Zn, Pb R2O R = Li, Na, K 15-40 where the glass substrate has a coefficient of, thermal expansion of 130-210×10−7/° C. at 30° C. to 70° C.Type: GrantFiled: July 30, 2001Date of Patent: June 25, 2002Assignee: Schott Glass Technologies, Inc.Inventors: Alexander J. Marker, III, Sally Pucilowski, Joseph Hayden
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Publication number: 20020061809Abstract: The present invention provides a composition for use in forming a white porcelain enamel coating on aluminized or galvanized steel. The composition according to the present invention includes a solids portion including a glass component and a white pigment. The glass component includes one or more glass frits including by weight from about 30% to 50% P2O5, from about 15% to about 30% Al2O3, from about 8% to about 40% X2O where X=Na and/or K, up to about 30% TiO2, up to about 12% B2O3, up to about 10% K2O, up to about 10% ZnO, up to about 8% SiO2, up to about 7% La2O3, up to about 5% Li2O, and up to about 15% F. The white pigment include TiO2.Type: ApplicationFiled: August 17, 2001Publication date: May 23, 2002Applicant: Ferro France S.A.R.L.Inventors: Alain Aronica, Emmanuel Marinho, David Coutouly, Luc Allemeersch, Christophe Reb
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Patent number: 6383961Abstract: A composition of a dielectric for a plasma display panel in user for fabricating a dielectric thick film for a front substrate having a low sintering temperature, a low thermal expensive coefficient, a high dielectric constant and a high withstand voltage. The composition of a dielectric is a P2O5—ZnO—PbO glass having composition ratios of 30˜60 wt % of P2O5, 5˜40 wt % of PbO, 0˜5 wt % of MgO, 0˜5 wt % of CaO, 0˜10 wt % of La2O3, 0˜5 wt % of SrO, 1˜5 wt % of Al2O3, 0˜2 wt % of Sb2O3, 0˜2 wt % of As2O3, 5˜25 wt % of BaO, and 0˜5 wt % of TeO2.Type: GrantFiled: May 17, 2000Date of Patent: May 7, 2002Assignee: LG Electronics Inc.Inventor: Byung-Gil Ryu
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Patent number: 6376398Abstract: A dielectric composition for a plasma display panel. In the dielectric composition, a P2O5—ZnO—BaO group glass is used. Accordingly, the dielectric composition is capable of meeting optical, thermal and electrical characteristic requirements of a dielectric layer and allows the dielectric layer to have a light weight.Type: GrantFiled: April 7, 2000Date of Patent: April 23, 2002Assignee: LG Electronics Inc.Inventors: Yoon Kwan Lee, Byung Gil Ryu
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Publication number: 20020042337Abstract: An optical glass having a high refractive index and high dispersion characteristics that is suited to application to precision press molding to precisely mold the shape of final products for objectives not requiring grinding or polishing. An optical glass exhibiting a refractive index in the range of from 1.75 to 2.0, an Abbé number in the range of from 20 to 28.5. Optical parts comprised of this glass; press-molding materials comprised of this glass; methods of manufacturing the same; and methods of manufacturing molded glass products employing these materials.Type: ApplicationFiled: June 29, 2001Publication date: April 11, 2002Inventors: Xuelu Zou, Hiromasa Tawarayama, Kazutaka Hayashi, Hiroshi Kawazoe
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Patent number: 6355586Abstract: A low melting point glass consisting essentially of, as represented by mol % based on the following oxides: Mol % SnO 2 to 37.5, ZnO 5 to 73, P2O5 16 to 50, Li2O 0 to 9, Na2O 0 to 9, K2O 0 to 9, Al2O3 0 to 20, B2O3 0 to 30, SiO2 0 to 20, MgO 0 to 35, CaO 0 to 35, SrO 0 to 35, BaO 0 to 35, In2O3 0 to 10, WO3 0 to 10, wherein SnO+ZnO+P2O5+B2O3 is at least 76 mol %, Li2O+Na2O+K2O is from 0 to 9 mol %, MgO+CaO+SrO+BaO is from 0 to 35 mol %, and the molar ratio of SnO to ZnO is less than 1.Type: GrantFiled: January 31, 2000Date of Patent: March 12, 2002Assignee: Asahi Glass Company, LimitedInventors: Hiroshi Usui, Yasuko Dotani, Ryuichi Tanabe, Tsuneo Manabe
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Patent number: 6352950Abstract: A family of alkali-tungsten-tellurite glasses that consist essentially of, as calculated in mole percent, 10-90% TeO2, at least 5% W03 and at least 0.5% R2O where R is Li, Na, K, Cs, Tl and mixtures, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.Type: GrantFiled: May 31, 2000Date of Patent: March 5, 2002Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Adam J. G. Ellison
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Patent number: 6344425Abstract: A family of fluorotellurite glasses, the composition of which consist essentially of, as calculated in mole percent, 30-75% TeO2, 15-60% ZnF2 and 0.005-10% of an oxide of erbium, thulium or holmium, and amplifying optical components produced from these glasses.Type: GrantFiled: November 19, 1999Date of Patent: February 5, 2002Assignee: Corning IncorporatedInventor: Bruce G. Aitken
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Publication number: 20020010065Abstract: An optical glass wherein an amount of change in refractive index (&Dgr;n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43W, pulse repetition rate of 5 kHz and pulse width of 4OO ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.Type: ApplicationFiled: June 1, 2001Publication date: January 24, 2002Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
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Patent number: 6333282Abstract: The present invention provides an optical glass for precision molding, having excellent properties, i.e. yield temperature (At) of at most 550° C., refractive index (nd) of at least 1.83 and Abbe number (&ngr;d) of at most 26.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented, in term of atoms for making up the glass, by the following chemical composition (wt %) P2O5 14.0 to 31.0% B2O3 0 to 5.0% GeO2 0 to 14.0% Sum of P2O5 + B2O3 + GeO2 14.0 to 35.0% Li2O 0 to 6.0% Na2O 2.5 to 14.0% Sum of Li2O + Na2O 2.5 to 15.0% Nb2O5 22.0 to 50.0% WO3 0 to 30.0% Bi2O3 5.0 to 36.0% BaO 0 to 22.0%.Type: GrantFiled: August 9, 2000Date of Patent: December 25, 2001Assignee: Sumita Optical Glass, Inc.Inventors: Koji Nakahata, Koichi Tsuchiya, Shinobu Nagahama
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Publication number: 20010031691Abstract: A glass includes (a) a matrix containing a compound of at least one nonmetallic element; and (b) a particle selectively formed in the matrix. This particle is made of the at least one nonmetallic element. A process for producing such glass includes (a) providing a blank glass containing a compound of at least one nonmetallic element; (b) condensing a pulsed laser beam to a focal point in the blank glass such that a particle is selectively formed in the blank glass at a position corresponding to the focal point, the particle being made of the at least one nonmetallic element dissociated from the compound; and (c) moving the focal point in the blank glass to produce a pattern of the particle. The glass is suitable for optical functional elements.Type: ApplicationFiled: February 21, 2001Publication date: October 18, 2001Inventors: Kiyotaka Miura, Seiji Fujiwara, Takuya Teshima, Natsuya Nishimura, Yoshinori Kubota
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Patent number: 6292292Abstract: Disclosed are cost-effective, compact, optically pumped, high gain, rare earth polymer materials such as, erbium (Er3+) perfluoro polymers, optical fibers made from the materials and waveguide amplifiers made from the materials having low-loss at telecommunications wavelengths for operation in communications network systems. The polymer amplifier is based on the use of novel high performance rare earth (RE) polymer materials. The new discovered highly transparent RE polymer materials are directly synthesized at high RE ion concentrations (˜1020−1021 rare earth ion/cm3˜10% wt) with each metal ion encapsulated and physically buffered by insulating, covalently bonded, perfluorinated phosphate ligands that then form the high temperature stable, polymer backbone matrix. This is distinctly different from widely studied inorganic glasses and single crystals where RE ion salts are doped directly into the host but only to relatively low levels (<0.1% wt).Type: GrantFiled: February 18, 2000Date of Patent: September 18, 2001Assignee: Photon-XInventors: Anthony F. Garito, Robert A. Norwood, Renyuan Gao, Anna Panackal
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Patent number: 6287995Abstract: A sealing glass composition for bonding the upper plate and the lower plate of a flat panel display device is described. The sealing glass composition includes a low melting point glass containing PbO of less than 20% and having a sintering temperature of less than 500° C. The sealing glass composition contains a low component of PbO to thereby decrease environmental contamination and increase work efficiency. Also, the sealing glass prevents the deformation and cracking of a substrate caused by thermal and mechanical stress and reduces the sintering temperature to thereby enhance the airtightness of the sealing glass.Type: GrantFiled: May 21, 1999Date of Patent: September 11, 2001Assignee: LG Electronics Inc.Inventor: Yoon Kwan Lee
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Patent number: 6284685Abstract: Devices are made comprising a tin-phosphorous oxyfluoride glass, which has been exposed to light, preferably shorter in wavelength than the absorption edge of the glass, to change the refractive index change of the glass. The glasses can be used to form planar and fiber devices, including core/clad structures for guiding light.Type: GrantFiled: March 23, 2000Date of Patent: September 4, 2001Assignee: Corning IncorporatedInventors: Nicholas F. Borrelli, Robert W. Boyd, Stojan Radic, Paul A. Tick
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Patent number: 6277775Abstract: A GeAs sulphide glass family of transparent glasses having transmission far into the infrared portion of the spectrum, containing a source of phosphorus ion as a co-dopant to effect dispersion of a rare earth metal ion dopant in the glass, an optical component comprising the glass, and a method of dispersing a rare earth metal ion in the glass.Type: GrantFiled: January 25, 2000Date of Patent: August 21, 2001Assignee: Corning IncorporatedInventor: Bruce G. Aitken
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Patent number: 6277776Abstract: A low temperature fluorophosphate glass useful for joining single-mode fluoride and silica optical fibers includes 5 to 7 mol % InF3, 20 to 35 mol % PbF2 and 57.5 to 75 mol % P2O5. An alkali for maintaining a low glass transition temperature can be included. Up to 25% (glass molar basis) of the P2O5 can be replaced by PbO.Type: GrantFiled: June 21, 1999Date of Patent: August 21, 2001Assignee: IPG Photonics CorporationInventors: Alexis Clare, Wesley King, Ian Grainge Clarke
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Patent number: 6228787Abstract: This invention relates to fluorescent photosensitive glasses and a process for the production thereof. The fluorescent photosensitive glasses according to the present invention employ silicate or phosphate glass compositions including minor amounts of one or more fluorescent agents (e.g., ytterbium (Yb), samarium (Sm), europium (Eu)) and one or more photosensitive agents (e.g., erbium (Er), thulium (Tm), praseodymium (Pr), ytterbium (Yb), holmium (Ho), samarium (Sm), cerium (Ce), dysprosium (Dy), terbium (Tb), neodymium (Nd)). The inventive fluorescent photosensitive glass can be used in photographic applications, florescent displays and computer memories.Type: GrantFiled: July 27, 1998Date of Patent: May 8, 2001Inventor: Eugen Pavel
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Patent number: 6225244Abstract: A glass for a near infrared absorption filter, which has spectral characteristics that it efficiently transmits light in a wavelength region of from ultraviolet region to 600 nm and selectively absorbs light in a near infrared region of a wavelength of larger than about 600 nm, a near infrared absorption filter formed of the above glass, and a solid-state image sensing device to which the above filter is applied, the glass comprising, by cationic %, 35 to 54% of P, 20 to 47% of Zn, 0 to 8% of the total, R, of Li, Na, K and Cs which are monovalent metal elements, 0 to 17% of the total, M, of Mg, Ca, Ba, Sr and Pb which are divalent metal elements, the total of R and M being 1 to 22%, 0.1 to 7% of As, 0.2 to 9% of Cu and 0 to 6% of Al.Type: GrantFiled: January 20, 1999Date of Patent: May 1, 2001Assignee: Hoya CorporationInventor: Hironori Oguma
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Patent number: 6194333Abstract: A dielectric composition for a plasma display panel that is capable of satisfying the required characteristics of a dielectric applied to an barrier rib and a dielectric layer of a plasma display panel. The dielectric composition includes a parent glass of P2O5—PbO—K2O group and an oxide filler. The dielectric has relatively low sintering temperature and dielectric constant, a high reflectivity and a reduced amount of PbO component, so that it can minimize an environment contamination and reduce a weight of the device.Type: GrantFiled: April 27, 1999Date of Patent: February 27, 2001Assignee: LG Electronics Inc.Inventor: Byung Gil Ryu
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Patent number: 6156684Abstract: In a light polarization control element using a stress-optical coefficient glass, the stress-optical coefficient glass is substantially composed of a phosphorous acid glass containing 20 to 60 percent by weight of P.sub.2 O.sub.5 and 40 to 73 percent by weight of BaO and PbO.Type: GrantFiled: June 16, 1998Date of Patent: December 5, 2000Assignee: Hoya CorporationInventors: Kouichi Sato, Kazuo Tachiwana
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Patent number: 6103648Abstract: A composition for a bulk conducting glass comprising P.sub.2 O.sub.5, V.sub.2 O.sub.5, PbO, and FeO, the ratio of the molar percentage of P.sub.2 O.sub.5 to V.sub.2 O.sub.5 being in the range of about 1 to about 6, and the P.sub.2 O.sub.5 and V.sub.2 O.sub.5 being present in an aggregate amount of at least about 50 mole percent, the PbO being present in the glass in an amount in excess of 15 mole percent, and the FeO being present in amount of about 0 to about 30 mole percent. The composition may also include MnO or Sb.sub.2 O.sub.3 in an amount of up to about 2 mole percent. The composition may be formed into fibers for use in microchannel plates and other devices where bulk conductivity in glass is advantageous.Type: GrantFiled: May 28, 1998Date of Patent: August 15, 2000Assignee: Circon CorporationInventor: Jay J. L. Yi
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Patent number: 6093484Abstract: Phosphate or flurorophosphate glass surfaces are polished to smooth, highly accurate surfaces using a glass polishing liquid having a pH approximating the pH of the glass being polished. A highly polished glass surface results suitable for use optical filters and solid camera devices and solid image sensors. Phosphate and fluorophosphate glass filters and the like so formed have hair-like surface flaws, if any, of a width of 7 .mu.m or less.Type: GrantFiled: April 2, 1998Date of Patent: July 25, 2000Assignee: Hoya CorporationInventor: Hironori Oguma
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Patent number: 6048811Abstract: A fusion sealing material, and a fusion seal prepared therefrom, consisting essentially of at least 65% of a SnO--ZnO--P.sub.2 O.sub.5 glass fit, up to 10% of a crystallization catalyst and 0-25% of an additive that decreases the effective CTE of a seal prepared with the material.Type: GrantFiled: August 21, 1998Date of Patent: April 11, 2000Assignee: Corning IncorporatedInventor: Robert Morena
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Patent number: 5965469Abstract: The present invention provides a glass composition for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, and copper alloys, which includes between about 10 and about 25 mole percent Na.sub.2 O, between about 10 and about 25 mole percent K.sub.2 O, between about 4 and about 15 mole percent Al.sub.2 O.sub.3, between about 35 and about 50 mole percent P.sub.2 O.sub.5, B.sub.2 O.sub.3 in a concentration not exceeding 10 mole percent, and MXO in a concentration not exceeding 12 mole percent, wherein MXO is a metal oxide selected from the group consisting of PbO, BaO, CaO and MgO or a mixture thereof. This composition is suitable to hermetically seal to components for use in RF-interconnection applications.Type: GrantFiled: March 20, 1998Date of Patent: October 12, 1999Assignee: Sandia CorporationInventors: Riley D. Kilgo, Richard K. Brow, Larry Kovacic
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Patent number: 5952399Abstract: A dental material based on an organic polymerisable binding agent has a content ofA) one or more mixed apatites of the typeA1) A.sub.10 (XO.sub.4).sub.6 Z.sub.2 +/B*.sub.10-u C*.sub.u (Y*).sub.6 Z'.sub.2 and/orA2) A'.sub.10-r (X'O.sub.4).sub.6-s Z".sub.2-t +/B'.sub.r (Y').sub.s Q.sub.t -B".sub.10-u' C'.sub.u' (Y").sub.6 Z'".sub.2 and/orA3) A".sub.10-r' (X"O.sub.4).sub.6-s' Z"".sub.2-t' +/A'".sub.r' (X'"O.sub.4).sub.s' +/B'".sub.10-u" C".sub.u" (Y'").sub.6 Z'"".sub.2in which the formulae assume the significance specified in the description, in a quantity that is effective for the absorption of ions from the biological application environment of the dental material. The polymerisable dental material has variably adjustable transparency, good polishability, high strength and the capacity to release and absorb ions into and from a biological environment. Also described is a process for using the mixed apatites A1), A2) and/or A3) in polymerisable dental materials.Type: GrantFiled: September 30, 1997Date of Patent: September 14, 1999Assignee: Degussa AktiengesellschaftInventor: Harald Rentsch
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Patent number: 5880045Abstract: Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole %.iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.Type: GrantFiled: July 27, 1998Date of Patent: March 9, 1999Assignee: Brookhaven Science AssociatesInventors: Hui Cao, Jay W. Adams, Paul D. Kalb
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Patent number: 5840638Abstract: Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole % iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.Type: GrantFiled: December 23, 1996Date of Patent: November 24, 1998Assignee: Brookhaven Science AssociatesInventors: Hui Cao, Jay W. Adams, Paul D. Kalb
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Patent number: 5755998Abstract: According to the present invention, there is provided a fluorophosphate fluorescent glass, capable of converting invisible ultraviolet rays into visually observable visible rays with a high efficiency and available for controlling the optical axis of a laser beam such as excimer laser, etc. The feature of this fluorescent glass consists in a fluorophosphate fluorescent glass capable of exhibiting fluorescence in the visible region, having a chemical composition comprising, at least, (I) phosphorus (P), oxygen (O) and fluorine (F), as glass constituting components, and (II) at least one member selected from the group consisting of divalent europium, terbium, samarium and manganese, as a fluorescent agent, the divalent europium being contained as an essential component and at least one of samarium and manganese being contained as an essential component when terbium is contained.Type: GrantFiled: November 20, 1996Date of Patent: May 26, 1998Assignee: Sumita Optical Glass, Inc.Inventors: Masaaki Yamazaki, Masaaki Otsuka, Shinobu Nagahama, Naruhito Sawanobori
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Patent number: 5714244Abstract: A material is impregnated with an aqueous solution containing precursors of a glass-containing phosphate base modified at least by the presence of zinc oxide, then dried and heat treated to form an internal oxidation protection constituted by the modified phosphate glass-containing base. The precursors are introduced into the aqueous solution so as to form a glass-containing base in which the molar ratio between the glass modifying oxides, comprising zinc oxide, and the glass forming oxides, principally comprising or consisting of phosphoric anhydride, is sufficiently high, in particular at least 0.6, preferably 0.9, to confer a resistance to corrosion by moisture on the glass-containing phosphate base.Type: GrantFiled: November 30, 1995Date of Patent: February 3, 1998Assignee: Societe Europeenne de PropulsionInventors: Rodolphe Delaval, Gerard Palavit, Jacques Rey, Michel Laxague, Jacques Thebault
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Patent number: 5668066Abstract: A near infrared absorption filter glass containing______________________________________ P.sub.2 O.sub.5 35.about.50% Li.sub.2 O 0.about.5% Na.sub.2 O 0.about.12% K.sub.2 O 0.about.20% Cs.sub.2 O 0.about.20% R.sub.2 O (in which R is an alkali metal) 1.5.about.20% ZnO 17.about.48% MgO 0.about.7% CaO 0.about.7% SrO 0.about.7% BaO 0.about.12% R'O (in which R' is an alkaline earth metal) 0.about.15% CuO 0.2.about.12% ______________________________________ in which % stands for % by weighthas excellent transmittance characteristics in the ultraviolet region over conventional phosphate-based glass, has glass stability and processability which enable the mass production, and further has sufficient weatherability.Type: GrantFiled: July 24, 1996Date of Patent: September 16, 1997Assignee: Hoya CorporationInventors: Hironori Oguma, Kazuo Tachiwana
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Patent number: 5609660Abstract: Polymeric compositions having a polymeric component and an inorganic filler which undergoes a crystal (phase) inversion within the operating temperature range of the composition are provided. The present invention relates to a method for reducing the water sensitivity of particles of a crystallized phosphate glass. The particles are composed of P.sub.2 O.sub.5 and one or more cations selected from the group consisting of magnesium, cobalt, arsenic, zinc, iron, aluminum, and zirconium. The method includes nitriding the particles.Type: GrantFiled: June 7, 1995Date of Patent: March 11, 1997Assignee: Corning IncorporatedInventors: Gaylord L. Francis, Ronald E. Johnson, Paul A. Tick, Lung-Ming Wu
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Patent number: 5529960Abstract: The subject invention is directed at wherein either a portion of the ZnO or alkali metals, or both, found in prior art glasses, is replaced by Cu.sub.2 O, i.e., cuprous or monovalent copper. In addition to the Cu.sub.2 O substitution, the inventive glass contains a required metal oxide constituent which is necessary to enhance durability. More specifically, the present invention discloses a glass consisting essentially of, expressed in terms of mole percent on the oxide basis, of about 42-54% P.sub.2 O.sub.5, 10-30% Cu.sub.2 O, 10-30% R.sub. O and 3-12% of a component selected from the group consisting of 0-7% MoO.sub.3, 0-10 Fe.sub.2 O.sub.3, 0-10% Al.sub.2 O.sub.3 and 0-7%WO.sub.3. In addition, the composition includes up to a total of 45% of optional ingredients in the indicated proportions selected from the group consisting of 0-15% MgO, 0-20% CaO, 0-20% SrO, 0-20% BaO, 0-25% MgO+CaO+SrO+BaO, 0-35% ZnO, 0-10% MnO, 0-2% CeO.sub.2, 0-10% B.sub.2 O.sub.3, 0-2% Ln.sub.2 O.sub.Type: GrantFiled: December 30, 1994Date of Patent: June 25, 1996Assignee: Corning IncorporatedInventors: Bruce G. Aitken, George H. Beall, James E. Dickinson, Jr.
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Patent number: 5529961Abstract: The subject invention is directed at glasses wherein either a portion of the ZnO or alkali metals, or both, is replaced by Cu.sub.2 O, i.e., monovalent copper. Specifically, the present invention is directed at a glass consisting essentially of, expressed in terms of mole percent on the oxide basis, 28-42% P.sub.2 O.sub.5, 15-30% Cu.sub.2 O, 10-30% R.sub.2 O, wherein R.sub.2 O is selected from the group consisting of 0-15% Li.sub.2 O, 0-20% Na.sub.2 O, and 0-10% K.sub.2 O, and up to a total of 45% of optional ingredients in the indicated proportions selected from the group consisting of 0-10% Al.sub.2 O.sub.3, 0-15% MgO, 0-20% CaO, 0-20% SrO, 0-20% BaO, 0-25% MgO+CaO+SrO+BaO, 0-35% ZnO, 0-10% MnO, 0-2% CeO.sub.2, 0-2% Ln.sub.2 O.sub.3, 0-10 Al.sub.2 O.sub.3 0-10% B.sub.2 O.sub.3, 0-10 Fe.sub.2 O.sub.3 0-10% Al.sub.2 O.sub.3 +B.sub.2 O.sub.3 +Fe.sub.2 O.sub.3, 0-7% MoO.sub.3 0-7% WO.sub.3 0-7% MoO.sub.3 +WO.sub.3, and 0-8% F, the latter as analyzed in weight percent.Type: GrantFiled: December 30, 1994Date of Patent: June 25, 1996Assignee: Corning IncorporatedInventors: Bruce G. Aitken, George H. Beall, James E. Dickinson, Jr.
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Patent number: 5519555Abstract: A magnetic head for use in a magnetic recording and reproducing system, which head is excellent in magnetic properties, resistance to abrasion, durability and mass-producibility, comprises a pair of magnetic cores each having a substrate and a magnetic alloy film formed on the substrate, the cores being disposed in a manner such that the magnetic alloy films are opposed to and slightly spaced apart from each other, and glass bondings disposed between the magnetic alloy films to integrate the pair of magnetic cores, and a process for producing the same, and a magnetic recording and reproducing system using the magnetic head.Type: GrantFiled: August 3, 1994Date of Patent: May 21, 1996Assignee: Hitachi, Ltd.Inventors: Takashi Naitoh, Takashi Namekawa, Seiichi Yamada, Kunihiro Maeda, Kenkichi Inada
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Patent number: 5518970Abstract: The present invention relates generally to a novel and unique class of gly materials and methods of making such materials in which substantially all of the anions are nitride ions, in contrast to the oxide ions of conventional optical glasses, or the fluoride ions of the more recently discovered fluoride optical glasses. The chemical nature of these new glasses dispose the glassy materials to a remarkable combination of desirable properties, including, but not limited to, high hardness, high refractive index and high softening temperature.Type: GrantFiled: May 24, 1995Date of Patent: May 21, 1996Assignee: Arizona Board of Regents acting on behalf of Arizona State UniversityInventors: Paul F. McMillan, C. Austen Angell, Tor Grande, John R. Holloway
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Patent number: 5510301Abstract: The present invention is directed to the preparation of frit pastes suitable for sealing together preformed glass parts, being especially suitable for sealing glass panels to funnels of cathode ray tubes. The pastes comprise a mixture of frit particles, a lacquer, and at least one additive in an amount of 0.0005-2% by weight total of the lacquer. The preferred additives are selected from the group of alkyl organic phosphate esters, a mixed titanium ortho ester complexes, and substituted sorbitols in the polyol acetal family.Type: GrantFiled: October 24, 1994Date of Patent: April 23, 1996Inventors: Kimberly S. Fink, Joshua U. Otaigbe
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Patent number: 5455211Abstract: The present invention relates generally to a novel and unique class of gly materials and methods of making such materials in which substantially all of the anions are nitride ions, in contrast to the oxide ions of conventional optical glasses, or the fluoride ions of the more recently discovered fluoride optical glasses. The chemical nature of these new glasses dispose the glassy materials to a remarkable combination of desirable properties, including, but not limited to, high hardness, high refractive index and high softening temperature.Type: GrantFiled: April 19, 1994Date of Patent: October 3, 1995Assignee: Arizona Board of Regents acting on behalf of Arizona State UniversityInventors: Paul F. McMillan, C. Austen Angell, Tor Grande, John R. Holloway
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Patent number: 5364819Abstract: A Faraday rotator glass composition based on a fluoride glass, phosphate glass, fluorophosphate glass or a mixture thereof is doped with a lanthanide in a concentration sufficient to provide a Verdet constant above at least 2870 deg/Tesla-meter [(1 min/cm-Oe).times.(1.667.times.10.sup.4)=1 deg/Tesla-meter] and optical transmission above at least 50 percent in a 25 mm thick polished glass sample at least at one wavelength in the 200 to 400 nm wavelength region. The Faraday rotator glass also includes monovalent non-lanthanide cations such as Na, Li, K or mixtures thereof in a concentration sufficient to provide a Verdet constant above at least 2870 deg/Tesla-meter and optical transmission above at least 50 percent in a 25 mm thick polished glass sample at least at one wavelength in the 200 to 400 nm wavelength region.Type: GrantFiled: April 28, 1993Date of Patent: November 15, 1994Assignee: The United States of America as represented by the Secretary of the NavyInventors: James L. Dexter, David G. Cooper, Douglas H. Blackburn, David C. Cranmer, Dale A. Kauffman
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Patent number: 5334559Abstract: A glass consisting essentially of (on an oxide composition basis):______________________________________ Mole % ______________________________________ P.sub.2 O.sub.5 50-70 Al.sub.2 O.sub.3 4-13 Na.sub.2 O 10-35 La.sub.2 O.sub.3 0-6 Ln.sub.2 O.sub.3 >0-6 Sum R'O 0-20 (R' = Mg, Ca, Sr, Ba, Zn and Pb) Sum R.sub.2 O 0-18 (R = Li, K, Rb, Cs) ______________________________________wherein Ln.sub.2 O.sub.3 represents the sum of the oxides of active lasing lanthanides of atomic number 58-71.Type: GrantFiled: February 1, 1993Date of Patent: August 2, 1994Assignee: Schott Glass Technologies, Inc.Inventor: Joseph S. Hayden