And Lead Patents (Class 501/60)
  • Patent number: 11760685
    Abstract: Glass-based articles that include a hydrogen-containing layer extending from the surface of the article to a depth of layer. The hydrogen-containing layer includes a hydrogen concentration that decreases from a maximum hydrogen concentration to the depth of layer. The glass-based articles exhibit a high Vickers indentation cracking threshold. Glass compositions that are selected to promote the formation of the hydrogen-containing layer and methods of forming the glass-based article are also provided.
    Type: Grant
    Filed: August 31, 2022
    Date of Patent: September 19, 2023
    Assignee: Corning Incorporated
    Inventors: Timothy Michael Gross, Georgiy M Guryanov
  • Patent number: 8846555
    Abstract: Disclosed are silica and fluoride doped lead-bismuth-gallium heavy metal oxide glasses for visible to mid-wave Infrared Radiation transmitting optics and preparation thereof.
    Type: Grant
    Filed: June 25, 2012
    Date of Patent: September 30, 2014
    Assignee: Schott Corporation
    Inventors: Simi George, Sally Pucilowski
  • Patent number: 8741793
    Abstract: The present invention relates to a vitreous material possessing visual effects, particularly of fluorescence, when it is lit by ultraviolet light in the visible spectrum. These glasses are particularly applicable to the manufacture of decorative objects.
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: June 3, 2014
    Assignee: Commissariat a l'Energie Atomique et aux Energies Alternatives
    Inventors: Olivier Renard, Céline Noel
  • Patent number: 8431500
    Abstract: The space glass has a composition, in wt. % based on oxide content, of: SiO2, 5-65; B2O3, 0-40; Al2O3, 0-12; PbO, 25-50; Na2O 0-8; K2O, 0-20; ? alkali metal oxides, at least 0.25; and at least 0.1 wt. % of a total amount of three or more doping agents selected from CeO2, MoO3, Bi2O3, WO3, Ag2O, SnO2, Sb2O3 and As2O3. In addition, it contains one or more of the following doping agents in the following amounts: at most 1 wt. %, CeO2; at most 0.02 wt. %, As2O3; at most 0.3 wt. %, Sb2O3; and at most 0.5 wt. %, SnO2. Light-weight optical systems for space are made from it, because of its high radiation resistance. A preferred process for making space glass includes melting the oxide starting ingredients at 1050° C. to 1200° C. to form a melt and refining the melt at 1230° C. to 1350° C.
    Type: Grant
    Filed: June 21, 2010
    Date of Patent: April 30, 2013
    Assignee: Schott AG
    Inventors: Burkhard Speit, Silke Wolff, Thorsten Doehring
  • Patent number: 8431501
    Abstract: The space glasses have a composition, in wt. % based on oxide content, including SiO2, 12-45; B2O3, 0-4; Al2O3, 0-4; TiO2, 0-5; PbO, 50-82; Na2O, 0-4; K2O, 0-8; and at least 0.1 wt. % of a total amount of at least three doping agents selected from CeO2, MoO3, Bi2O3, WO3, Ag2O, SnO2, Sb2O3 and As2O3. Light-weight and space-saving optical systems for outer space applications can be made with these space glasses, which have high UV- and VIS-transmittance and high transmittance stability, because of their high radiation resistance based on their dopant content. A preferred process for making the space glass includes melting the above-stated oxide ingredients in a quartz crucible at 1050° C. to 1200° C. to form a melt and refining the melt at 1230° C. to 1350° C.
    Type: Grant
    Filed: June 21, 2010
    Date of Patent: April 30, 2013
    Assignee: Schott AG
    Inventors: Burkhard Speit, Silke Wolff, Thorsten Doehring
  • Patent number: 8193109
    Abstract: Ceramic materials with a matrix which contains at least one carbide, at least one carbide-forming element and carbon, and which furthermore contain a dispersed phase of carbon particles with spherical shape and an average diameter of 0.2 ?m to 800 ?m, a process for their production and their use for thermal insulation, as a protective layer in ceramic armoring against mechanical action, or as a friction layer in brake disks or clutch disks.
    Type: Grant
    Filed: June 7, 2007
    Date of Patent: June 5, 2012
    Assignee: Audi AG
    Inventors: Andreas Kienzle, Ingrid Kratschmer
  • Publication number: 20100323875
    Abstract: The optical glasses have increased refractive indices and are useful for making space-saving and light-weight imaging optics with lenses of different glass types for use in different objects travelling in space. The optical glasses are suitable for production of optics having low total weight, which is decisive for space applications. These space glasses have high UV- and VIS-transmittance in a range of between 300 and 800 nm and high stability of transmittance over a period of years, because their aging has been greatly limited.
    Type: Application
    Filed: June 21, 2010
    Publication date: December 23, 2010
    Inventors: Burkhard Speit, Silke Wolff, Thorsten Doehring
  • Publication number: 20100323874
    Abstract: The optical glasses have increased refractive indices and are useful for making space-saving and light-weight imaging optics with lenses of different glass types for use in different objects travelling in space. The optical glasses are suitable for production of optics having low total weight, which is decisive for space applications. These space glasses have high UV- and VIS-transmittance in a range of between 300 and 800 nm and high stability of transmittance over a period of years, because their aging has been greatly limited.
    Type: Application
    Filed: June 21, 2010
    Publication date: December 23, 2010
    Inventors: Burkhard Speit, Silke Wolff, Thorsten Doehring
  • Patent number: 7605098
    Abstract: A substantially white powder for use as a filler and/or extender derived from by-products of manufacturing vitreous low alkali, low iron glass fibers, and a method for producing the powder. The filler has very low alkalinity and by virtue of its being essentially free of crystalline silica is non-hazardous to health and therefore safe for consumer-based and industrial-based uses.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: October 20, 2009
    Assignee: Albacem, LLC
    Inventors: Raymond T. Hemmings, Robert D. Nelson, Philip L. Graves, Bruce J. Cornelius
  • Publication number: 20080149863
    Abstract: The invention relates to a process for manufacturing flat glass rich in lead oxide, comprising the continuous floating, in a float plant with a neutral gaseous atmosphere, of a glass comprising at least 30% lead oxide by weight on a bath of molten metal having a higher density than that of the glass. The invention allows flat glass rich in lead, useful for protection against X-rays, to be produced.
    Type: Application
    Filed: February 14, 2005
    Publication date: June 26, 2008
    Applicant: SAINT-GOBIN GLASS FRANCE
    Inventors: Ramon Rodriguez Cuartas, Christian Bouigeon, Juan Luis Fernandez Suarez
  • Publication number: 20080085827
    Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the clear glass includes a low amount of iron coupled with zinc oxide and/or erbium oxide in amounts designed to provide a neutral color. While the erbium oxide is used to provide for neutral color, the zinc oxide binds sulfur into whitish-colored zinc sulfide thereby reducing the amount of sulfur that binds/bonds with iron in the glass to form sulfides of iron which is/are brownish in color. Thus, the use of the zinc oxide helps make the glass more neutral in color. In certain example embodiments, the use of the erbium oxide brings the a* color value of the resulting glass closer to zero, whereas the use of the zinc oxide brings the b* value of the resulting glass closer to zero.
    Type: Application
    Filed: October 6, 2006
    Publication date: April 10, 2008
    Inventors: Scott V. Thomsen, Ksenia A. Landa, Richard Hulme, Leonid M. Landa, Leonid M. Landa
  • Patent number: 7316740
    Abstract: Lithium silicate materials are described which can be easily processed by machining to dental products without undue wear of the tools and which subsequently can be converted into lithium silicate products showing high strength.
    Type: Grant
    Filed: August 6, 2004
    Date of Patent: January 8, 2008
    Assignee: Ivoclar Vivadent AG
    Inventors: Marcel Schweiger, Volker M. Rheinberger, Harald Bürke, Wolfram Höland
  • Patent number: 7196027
    Abstract: An optical glass wherein an amount of change in refractive index (?n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43 W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.
    Type: Grant
    Filed: June 1, 2001
    Date of Patent: March 27, 2007
    Assignee: Kabushiki Kaisha Ohara
    Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
  • Patent number: 7144633
    Abstract: Disclosed are glass compositions, glass fiber compositions, glass fiber battery separators, glass fiber filter media, battery additives and active materials formed with glass compositions disclosed, glass fiber radiation shields, and glass fiber paper compositions. Certain embodiments include, among other components, bismuth oxide. Certain embodiments include about 0.5–30% bismuth oxide of the composition by weight and silica oxide at about 54–70% of the composition by weight. Embodiments may also include other components. For example, zinc oxide can make up about 0.01–3% of the composition by weight.
    Type: Grant
    Filed: July 21, 2004
    Date of Patent: December 5, 2006
    Assignee: Evanite Fiber Corporation
    Inventors: George Zguris, John Windisch, Patrick Svoboda, Yuri Vulfson
  • Patent number: 7091143
    Abstract: A glass funnel suitable for a chemical strengthening method of an electric field application type without impairing the safety of a cathode ray tube. A glass funnel for a cathode ray tube, characterized in that glass at a body portion 3 contains at least Na2O and K2O, the conductivity of said glass at the strain point is at least 4×10?6 S/cm, the conductivity at 150° C. is at most 5×10?12 S/cm, and a compressive stress layer is formed by a chemical strengthening method on at least part of the outer surface of the body portion 3.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: August 15, 2006
    Assignees: The Circle for the Promotion of Science and Engineering, Asahi Glass Company, Limited
    Inventors: Shuichi Shibata, Tetsuji Yano, Jaeho Lee, Yuichi Kuroki, Mikio Ueki
  • Patent number: 7074732
    Abstract: Zinc-containing optical glass materials with a refractive index nd between 1.52 and 1.66, an Abbe number ?d of between 35 and 54 and a composition (in % by weight based on oxide) of: SiO2 38–58, ZnO 0.3–42, PbO 0–<30, ZnO+PbO 20–55, Li2O 0–<3, Na2O 0–14, K2O 0–12, Li2O+Na2O+K2O ?2, F 0–3, MgO 0–6, CaO 0–<5, SrO 0–6, BaO 0–<0.9, B2O3 0–<1, Al2O3 0–<1.5 and ZrO2 0–<2 and, if appropriate, refining agents in the customary amounts.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: July 11, 2006
    Assignee: Schott Glas
    Inventors: Ina Mitra, Danuta Grabowski, Uwe Kolberg, Paul Kissl
  • Patent number: 7041165
    Abstract: The invention concerns a method for making cold-process bituminous mixes, using a bitumen-type emulsion in aqueous phase and aggregates. It consists of treating said aggregates with an agent providing hydrophobicity, prior to mixing said emulsion with said aggregates.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: May 9, 2006
    Assignee: Totalfinaelf France
    Inventor: Michel Malot
  • Patent number: 6989633
    Abstract: An alkaline-earth aluminosilicate glass having a composition (in % by weight, based on oxide) of SiO2>55-64; Al2O3 13-18; B2O3 0-5.5; M5O 0-7; CaO 5.5-14; SrO 0-8; BaO 6-17; ZrO2 0-2; CeO2 0-0.3; TiO2 0-0.5; CoO 0.01-0.035; Fe2O3 0.005-0.05; and NiO 0-0.
    Type: Grant
    Filed: February 3, 2003
    Date of Patent: January 24, 2006
    Assignee: Schott AG
    Inventors: Christian Kunert, Karin Naumann, Franz Ott, Ottmar Becker
  • Patent number: 6903038
    Abstract: A glass comprising in mole percent based on oxide: SiO2 55-70 PbO 30-38 Na2O >0-4.5 K2O ?0-2.5 and essentially free of TiO2.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: June 7, 2005
    Assignee: Schott Glass Technologies, Inc.
    Inventors: Joseph S. Hayden, Sally Pucilowski
  • Patent number: 6865909
    Abstract: A method for producing CRT funnel glass having a glass composition containing MgO, CaO, SrO, BaO and ZnO as essential components. Further, the total content of MgO, CaO, SrO, BaO and ZnO falls within a range of 5 to 13 mass %. As a glass material of the CRT funnel glass, CRT panel glass or CRT neck glass may be used. The method comprises preparing the glass material so as to contain MgO, CaO, SrO, BaO, and ZnO as essential components and so that the total content of MgO+CaO+SrO+BaO+ZnO falls within a range of 5 to 13 mass %; and melting the glass material.
    Type: Grant
    Filed: July 7, 2004
    Date of Patent: March 15, 2005
    Assignee: Nippon Electric Glass Co., Ltd
    Inventors: Hiroshi Komori, Hiroki Yamazaki
  • Patent number: 6806216
    Abstract: Zinc-containing optical glass materials with a refractive index nd between 1.52 and 1.66, an Abbe number vd of between 35 and 54 and a composition (in % by weight based on oxide) of: SiO2 38-58, ZnO 0.3-42, PbO 0-<30, ZnO+PbO 20-55, Li2O 0-<3, Na2O 0-14, K2O 0-12, Li2O+Na2O+K2O≧2, F 0-3, MgO 0-6, CaO 0-<5, SrO 0-6, BaO 0-<0.9, B2O3 0-<1, Al2O3 0-<1.5 and ZrO2 0-<2 and, if appropriate, refining agents in the customary amounts.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: October 19, 2004
    Assignee: Schott Glas
    Inventors: Ina Mitra, Danuta Grabowski, Uwe Kolberg, Paul Kissl
  • Publication number: 20040048730
    Abstract: An optical glass wherein an amount of change in refractive index (&Dgr;n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.
    Type: Application
    Filed: September 18, 2003
    Publication date: March 11, 2004
    Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
  • Publication number: 20040038798
    Abstract: A CRT funnel of a non beam-index type is made of a lead glass which contains 10-30 mass % of PbO and has an X-ray absorption coefficient of 40 cm−1 or more at 0.6 Å. The lead glass further contains Sb2O3 and an additive including at least one of CeO2 and SnO2. In case where the additive includes CeO2, it is preferable that the content of CeO2 is not smaller than 0.01 mass % and is smaller than 0.5 mass %. In case where the additive includes SnO2, the content of SnO2 preferably falls within a range of 0.001-2 mass %.
    Type: Application
    Filed: September 2, 2003
    Publication date: February 26, 2004
    Applicant: NIPPON ELECTRIC GLASS CO., LTD.
    Inventors: Hiroshi Komori, Hiroki Yamazaki
  • Publication number: 20040033879
    Abstract: The invention relates to a method of preparing a cone glass for a display tube. The cone glass according to the invention is obtained by mixing a first portion of glass fragments having a known composition with a second portion of vitrifying materials, wherein the first portion contains glass fragments of cone glass and screen glass of a display tube, and wherein the composition of the second portion is chosen to be such that at least one of the physical properties of X-ray absorption, electrical resistance, thermal coefficient of expansion and viscosity is in a desired range.
    Type: Application
    Filed: August 11, 2003
    Publication date: February 19, 2004
    Inventor: Jan Gerard Jacob Peelen
  • Patent number: 6642163
    Abstract: A CRT funnel of a non beam-index type is made of a lead glass which contains 10-30 mass % of PbO and has an X-ray absorption coefficient of 40 cm−1 or more at 0.6 Å. The lead glass further contains Sb2O3 and an additive including at least one of CeO2 and SnO2. In case where the additive includes CeO2, it is preferable that the content of CeO2 is not smaller than 0.01 mass % and is smaller than 0.5 mass %. In case where the additive includes SnO2, the content of SnO2 preferably falls within a range of 0.001-2 mass %.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: November 4, 2003
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hiroshi Komori, Hiroki Yamazaki
  • Patent number: 6617789
    Abstract: A glass for covering electrodes, which consists, as represented by mass percentage based on the following oxides, essentially of: Mass percentage PbO 44 to 68% Bi2O3 0 to 18%, B2O3 19 to 23%, SiO2 1.2 to 5%, Al2O3 2 to 6%, ZnO 4 to 9%, CuO 0.1 to 0.5%, In2O3 1.1 to 2%, SnO2 0 to 1%, and CeO2 0 to 1%.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: September 9, 2003
    Assignees: Asahi Glass Company, Limited, Fujitsu Hitachi Plasma Display Limited
    Inventors: Hitoshi Onoda, Yumiko Aoki, Tsuneo Manabe, Satoshi Fujimine, Michifumi Kawai, Shoichi Iwanaga
  • Publication number: 20030050176
    Abstract: To suppress breakage of glass for an electric lamp in a process in which the glass that has already been formed is processed further, a glass composition for an electric lamp is provided. The glass composition contains, expressed in mol %, 70 to 85% of SiO2, 12 to 17% of R2O, and 2 to 8.5% of MO (where R represents at least one selected from Li, Na and K, and M represents at least one selected from Mg, Ca, Sr, Ba, Zn and Pb). In the glass composition, the respective contents of CaO, MgO, BaO and SrO satisfy the relationship, CaO+MgO>BaO+SrO. The glass composition has a brittleness index value B determined by the Vickers hardness test of 7,000 m−½. Preferably, the contents of SrO and BaO are 0 to 0.5% and 0.1 to 1%, respectively. More preferably, the respective contents of K2O and Na2O satisfy the relationship, K2O>Na2O.
    Type: Application
    Filed: August 30, 2002
    Publication date: March 13, 2003
    Applicant: Matsushita Electric Industrial Co., Ltd.
    Inventors: Akira Kawase, Tomoko Atagi, Masanobu Ito
  • Publication number: 20030032543
    Abstract: On producing CRT funnel glass, Fe2O3 is added in a range of 0.05 to 1 mass % into a glass material of the CRT funnel glass so that a fluctuation of transmittance of light having a wavelength of 1,050 nm becomes 10% or less in a thickness of 10 mm of the CRT funnel glass. As a glass material of the CRT funnel glass, CRT panel glass or CRT frit may be used.
    Type: Application
    Filed: July 10, 2002
    Publication date: February 13, 2003
    Applicant: NIPPON ELECTRIC GLASS CO., LTD.
    Inventors: Hiroshi Komori, Hiroki Yamazaki
  • Publication number: 20030032544
    Abstract: CRT funnel glass has a glass composition containing MgO, CaO, SrO, BaO and ZnO as essential components. Further, the total content of MgO, CaO, SrO, BaO and ZnO falls within a range of 5 to 13 mass %. As a glass material of the CRT funnel glass, CRT panel glass or CRT neck glass may be used.
    Type: Application
    Filed: July 24, 2002
    Publication date: February 13, 2003
    Applicant: NIPPON ELECTRIC GLASS CO., LTD
    Inventors: Hiroshi Komori, Hiroki Yamazaki
  • Publication number: 20020115552
    Abstract: A CRT funnel of a non beam-index type is made of a lead glass which contains 10-30 mass % of PbO and has an X-ray absorption coefficient of 40 cm−1 or more at 0.6 Å. The lead glass further contains Sb2O3 and an additive including at least one of CeO2 and SnO2. In case where the additive includes CeO2, it is preferable that the content of CeO2 is not smaller than 0.01 mass % and is smaller than 0.5 mass %. In case where the additive includes SnO2, the content of SnO2 preferably falls within a range of 0.001-2 mass %.
    Type: Application
    Filed: December 20, 2001
    Publication date: August 22, 2002
    Applicant: Nippon Electric Glass Co., Ltd.
    Inventors: Hiroshi Komori, Hiroki Yamazaki
  • Patent number: 6437501
    Abstract: In an X-ray absorbing CRT bulb glass containing 10-40 weight % PbO and having an absorption coefficient not smaller than 40 cm−1 with respect to an X-ray having a wavelength of 0.6 angstrom, the glass contains 0.06-10 weight % Fe2O3 to thereby suppress lead from leaching into water in the atmosphere or in the ground where the CRT is wasted and dumped, so as to avoid the environmental pollution by the lead leached in the ground.
    Type: Grant
    Filed: April 18, 2000
    Date of Patent: August 20, 2002
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Hiroshi Komori
  • Patent number: 6436857
    Abstract: The present invention provides a method for inducing a refractive index change in a lead silicate glass material comprising: providing a lead silicate glass material; and irradiating the lead silicate glass material to increase the index of refraction of said lead silicate glass material. The present invention also provides a photo-induced lead silicate glass grating.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: August 20, 2002
    Assignee: University of New Mexico
    Inventors: Steven R. J. Brueck, Xiangcun Long
  • Patent number: 6416235
    Abstract: The specification describes processes for the manufacture of glass ferrules for optical fiber connectors wherein the glass ferrules have a composition comprising silicon oxide, alkali metal oxide, and aluminum oxide to which is added 1-35% of lead oxide.
    Type: Grant
    Filed: September 14, 2000
    Date of Patent: July 9, 2002
    Assignee: Fitel USA Corp.
    Inventor: Eliezer M. Rabinovich
  • Publication number: 20020058577
    Abstract: A glass comprising in mole percent based on oxide: 1 SiO2 55-70 PbO 30-38 Na2O  >0-4.5 K2O   0-2.5 and essentially free of TiO2.
    Type: Application
    Filed: August 16, 2001
    Publication date: May 16, 2002
    Applicant: SCHOTT GLASS TECHNOLOGIES, INC.
    Inventors: Joseph S. Hayden, Sally Pucilowski
  • Publication number: 20020010065
    Abstract: An optical glass wherein an amount of change in refractive index (&Dgr;n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43W, pulse repetition rate of 5 kHz and pulse width of 4OO ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.
    Type: Application
    Filed: June 1, 2001
    Publication date: January 24, 2002
    Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
  • Publication number: 20010017044
    Abstract: Zinc-containing optical glass materials with a refractive index nd between 1.52 and 1.66, an Abbe number &ngr;d of between 35 54 and a composition (in % by weight based on oxide) of: SiO2 38-58, ZnO 0.3-42, PbO 0-<30, ZnO+PbO 20-55, Li2O 0-<3, Na2O 0-14, K2O 0-12, Li2O+Na2O+K2O≧2, F 0-3, MgO 0-6, CaO 0-<5, SrO 0-6, BaO 0-<0.9, B2O3 0-<1, Al2O3 0-<1.5 and ZrO2 0-<2 and, if appropriate, refining agents in the customary amounts.
    Type: Application
    Filed: December 1, 2000
    Publication date: August 30, 2001
    Inventors: Ina Mitra, Danuta Grabowski, Uwe Kolberg, Paul Kibl
  • Patent number: 6251811
    Abstract: A funnel glass containing PbO for a cathode ray tube, wherein when the composition is represented by wt % based on oxides, the content of SrO is at least 1.0 wt %, the content of BaO is at least 1.0 wt %, and the ratio of the content of PbO to the total amount of PbO, SrO, BaO, CaO and MgO, is at most 0.69, and whereby the lead elution A of the glass as measured by the following method A is at most 1.0 &mgr;g/cm2, and the X-ray absorption coefficient at a wavelength of 0.6 Å is at least 40 cm−1: Method A: The glass is immersed in distilled and deionized water at 90° C. for 20 hours, whereupon the glass is taken out, and the amount of lead in the distilled and deionized water is measured by inductively coupled plasma emission spectrometry, and the measured value of the amount of lead is divided by the surface area of the glass, and the product is taken as the lead elution A.
    Type: Grant
    Filed: June 30, 1999
    Date of Patent: June 26, 2001
    Assignee: Asahi Glass Company Ltd.
    Inventors: Osamu Yanagisawa, Yuichi Kuroki, Ryousuke Akagi
  • Patent number: 6218775
    Abstract: A cathode ray tube with an improved tubular glass neck member having a softening point in the range of 640-650° C., an annealing temperature in the range of 460-472° C., a strain point in the range of 420-425° C., a coefficient of thermal expansion in the range of 94-97×10−7/° C., and a linear x-ray absorption value of at least 100 cm−1 and a composition, as calculated in weight % on an oxide basis, consisting essentially of 46.5-49.5% SiO2, 1.5-2% Al2O3, 0.5-1.5% Na2O, 10-12% K2O, 2-3% SrO, 1-1.8% BaO, 32-34% PbO, 1-1.5% ZnO and a fining agent.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: April 17, 2001
    Assignee: Corning Incorporated
    Inventor: David A. Tammaro
  • Patent number: 5807611
    Abstract: The present invention relates to a ceramic coating composition comprising a preceramic material such as silicon oxide precursors, silicon carbonitride precursors, silicon carbide precursors, and silicon nitride precursors and a flux material such as B.sub.2 O.sub.3, PbO.sub.2, P.sub.2 O.sub.5, and Bi.sub.2 O.sub.3. The present invention also relates to a substrate such as an electronic device having said coating applied and ceramified thereon.
    Type: Grant
    Filed: October 4, 1996
    Date of Patent: September 15, 1998
    Assignee: Dow Corning Corporation
    Inventors: Clayton R. Bearinger, Robert Charles Camilletti, Loren Andrew Haluska, Keith Winton Michael
  • Patent number: 5622904
    Abstract: A glass material for molding an optical element and including lead and a lead compound is processed chemically and physically and includes a modificative ion component set such that an atomic concentration of the modificative ion component in a range of 600 angstroms from a glass surface layer has a concentration gradient approximated by a curve represented by the following formula (1). ##EQU1## wherein, reference numeral Y designates an atomic concentration of a modificative ion shown by atomic percent. Reference numeral X designates a depth from an uppermost glass surface layer. Each of coefficients A0 to A10 is set to a constant. Symbol 0 designates a power. Reference numeral e(x) designates an error component.
    Type: Grant
    Filed: February 28, 1995
    Date of Patent: April 22, 1997
    Assignee: Ricoh Company, Ltd.
    Inventors: Katsuyuki Ohkubo, Tomoaki Sugawara, Hiroyuki Endou, Hiroshi Ueno, Akihito Minato
  • Patent number: 5565389
    Abstract: The invention relates to a glass of high refractive index suitable for the close-vision part of multifocal, in particular phototropic multifocal, spectacle lenses. The glass has a composition (in % by weight, based on oxide) of:SiO.sub.2 28-40; B.sub.2 O.sub.3 0-8.5; Li.sub.2 O 0-1; Na.sub.2 O 0-2.5; K.sub.2 O 0-5; CaO 0-6; SrO 0-6; BaO 6-12; ZnO 9-16; PbO 32-40; TiO.sub.2 0.3-7; ZrO.sub.2 0.4-5; .SIGMA. Li.sub.2 O+Na.sub.2 O+K.sub.2 O 0-5, anda refractive index n.sub.e of 1.66-1.81, an expansion coefficient .alpha..sub.20-300 of 5.7-6.8.times.10.sup.-6 K.sup.-1, a softening point of 650.degree.-700.degree. C. and a glass transition temperature Tg of 520.degree.-560.degree. C.
    Type: Grant
    Filed: August 31, 1995
    Date of Patent: October 15, 1996
    Assignee: Deutsche Spezialglas A.G.
    Inventor: Reinhard Kassner
  • Patent number: 5475528
    Abstract: An optical signal amplifier comprising an optical waveguide fiber integrated by thallium ion exchange in a boron-free silicate glass doped with up to 5 weight % erbium oxide, the glass having a base composition, as calculated in weight percent on an oxide basis, consisting essentially of______________________________________ SiO.sub.2 38-67 Al.sub.2 O.sub.3 1.5-4.5 Na.sub.2 O 0-20 ZnO 1.5-8 K.sub.2 O 0-25 Li.sub.2 O 0-1 Na.sub.2 O + K.sub.2 O 15-30 PbO 0-37 BaO 0-7 P.sub.2 O.sub.5 0-10 P.sub.2 O.sub.
    Type: Grant
    Filed: March 25, 1994
    Date of Patent: December 12, 1995
    Assignee: Corning Incorporated
    Inventor: Pascale LaBorde
  • Patent number: 5449645
    Abstract: This invention is directed to the production of glass bodies containing crystallites of PbS and/or PbSe. The crystallite-containing bodies are formed by the thermal crystallization in situ of glass bodies having compositions essentially free from CdO and consisting essentially, expressed in terms of weight percent on the oxide basis except for fluorine, sulfur, and selenium which are expressed in terms of weight percent on the elemental basis, of______________________________________ SiO.sub.2 58-65 RO 0-15 Na.sub.2 O 10-15 F 1-3.5 ZnO 5-17 S 0-3 Al.sub.2 O.sub.3 0.5-5 Se 0-3 PbO 3-6 S + Se 1-3 ______________________________________wherein RO consists of at least one alkaline earth metal oxide in the indicated proportions selected from the group consisting of 0-5% BeO, 0-5% MgO, 0-15% CaO, 0-10% SrO, and 0-10% BaO.
    Type: Grant
    Filed: August 26, 1994
    Date of Patent: September 12, 1995
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, George B. Hares, Dennis W. Smith
  • Patent number: 5420080
    Abstract: A high efficiency wavelength up-conversion transparent glass ceramics composition is provided containing a rare earth ion, which can be applied to short wavelength solid lasers, full color displays, infrared light detecting sensors, etc. The ceramic composition has the following chemical composition, in which fluoride fine crystals containing rare earth ions are preferentially precipitated:______________________________________ SiO.sub.2 10-60 mol % AlO.sub.1.5 0-40 mol % GaO.sub.1.5 0-40 mol % PbF.sub.2 5-60 mol % CdF.sub.2 0-60 mol % GeO.sub.2 0-30 mol % TiO.sub.2 0-10 mol % ZrO.sub.2 0-10 mol % ReF.sub.3 or ReO.sub.1.5 0.05-30 mol % (Re = Er, Tm, Ho, Yb, Pr, etc.).
    Type: Grant
    Filed: August 25, 1994
    Date of Patent: May 30, 1995
    Assignees: Sumita Optical Glass, Inc., Nippon Telegraph and Telephone Corporation
    Inventors: Yuhu Wang, Junichi Ohwaki
  • Patent number: 5366939
    Abstract: A gradient index optical element for use in optical lens such as a camera or microscope is disclosed. The optical element comprises at least one of first metal dopants selected from La, Zr, Sn, In, Y, Ge, Zn, Ba, Ca, As, Sr, Ga and Gd distributed in solvent with a slope, and at least one of second metal dopants selected from Nb, Ta, Ti, Bi, Pb, Sb, Zr, Sn, In, Y and Tl, which is distributed equally in the solvent so as to satisfy following equation as absolute amount;.vertline..DELTA.C.sub.f /.DELTA.C.sub.g .vertline..multidot.100.ltoreq.5wherein .DELTA.C.sub.g is a difference between maximum value and minimum value of equivalent value of metal oxides of the first metal doping and .DELTA.C.sub.f is a difference between maximum value and minimum value of equivalent value of metal oxides of the second metal doping.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: November 22, 1994
    Assignee: Olympus Optical Company Limited
    Inventors: Yuko Kurasawa, Satoshi Noda, Morinao Fukuoka
  • Patent number: 5308652
    Abstract: Articles formed of lead glass or crystal are treated in order to minimize the tendency for the article to leach lead or other heavy metals into products, such as alcohols or acidic foods, placed in contact therewith. In a preferred embodiment, flasks formed of glass containing between about 12% and 40% by weight lead oxide are provided with a thin layer or slip of kaolin, and heated at a temperature and for a time sufficient to exchange lead ions in the flask with ions other than lead in the kaolin layer. Preferably, the layer is applied as a thixotropic barbotin (slip) of pure hydrated aluminum silicate, and coated flasks are exposed to a temperature of between about 300.degree. C. and the strain point of the glass forming the flask and for a time ranging between about 3 and about 6 hours; rapid heating and cooling is avoided.
    Type: Grant
    Filed: March 31, 1993
    Date of Patent: May 3, 1994
    Assignee: Compagnie des Cristalleries de Baccarat
    Inventor: Gerard Cornier
  • Patent number: 5256606
    Abstract: The present invention relates to a moisture resistant low melting point glass composition for a magnetic head and a magnetic head utilizing it. Said glass composition may be composed of 28-35% PbO, 38-50% SiO.sub.2, 3-10% R.sub.2 O, 3-8% TeO.sub.2, and 1-5% TiO.sub.2 in terms of mole ratio, or 30-40% PbO, 30-40% SiO.sub.2, 10-20% B.sub.2 O.sub.3, 8% or less TeO.sub.2 and 10% or less Bi.sub.2 O.sub.3, cr 30-40% PbO, 30-40% SiO.sub.2, 10-20% B.sub.2 O.sub.3, and 0-8% TeO.sub.2, or 30-40% PbO, 30-40% SiO.sub.2, 10-20% B.sub.2 O.sub.3, and 0-10% Bi.sub.2 O.sub.3.
    Type: Grant
    Filed: May 28, 1992
    Date of Patent: October 26, 1993
    Assignee: Alps Electric Co., Ltd.
    Inventor: Satoshi Maki
  • Patent number: 5206189
    Abstract: An improved method for the production of a monolithic multicomponent oxide glass is achieved by forming an oxide host gel by a sol-gel process, placing the host gel in an aqueous solution of a salt of at least one metal selected from the group consisting of Li, Na, K, Rb, Cs, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and Pb, precipitating the metal salt in the gel and sintering the gel containing the precipitated salt. The method can incorporate large amounts of metals into the glass which are otherwise difficult or impossible to incorporate into precursor gels by conventional methods.
    Type: Grant
    Filed: October 25, 1991
    Date of Patent: April 27, 1993
    Assignees: Instituto Guido Donegani S.p.A., Enichem S.p.A.
    Inventor: J. Brian Caldwell
  • Patent number: 5192718
    Abstract: A family of lead silicate glasses particularly adapted to drawing of tubing for use in the neck section of a cathode ray tube. The glasses have internal liquidi below 750.degree. C., electrical resistivities over 8.0 ohm-cm (Log R.sub.350.degree. C.) and linear x-ray absorption values of at least 95 cm.sup.-1 at a wavelength of 0.6 Angstrom units. Their compositions consist essentially of, in weight percent as calculated on an oxide basis, 46-51% SiO.sub.2, 0.5-2% Al.sub.2 O.sub.3, 0.3-3% Na.sub.2 O, 9-13% K.sub.2 O, 2.5-6% SrO, 1-4% BaO, 30-33% PbO, 0-2% ZnO and 0.3-1% Sb.sub.2 O.sub.3.
    Type: Grant
    Filed: October 24, 1991
    Date of Patent: March 9, 1993
    Assignee: Corning Incorporated
    Inventor: Paul S. Danielson
  • Patent number: 5140109
    Abstract: Disclosed is a container package for a semiconductor element, which comprises a vessel having in the interior thereof a space for containing a semiconductor element, which comprises an insulating substrate and a lid member, an external lead terminal for connecting the semiconductor element contained in the vessel to an electric circuit and a sealing agent for sealing the vessel and external lead terminal, wherein the external lead terminal is composed of an electroconductive material having a permeability lower than 210 (CGS) and a thermal expansion coefficient of from 9.times.10.sup.-6 to 12.times.10.sup.-6 /.degree.C.
    Type: Grant
    Filed: August 27, 1990
    Date of Patent: August 18, 1992
    Assignee: Kyocera Corporation
    Inventors: Hiroshi Matsumoto, Hiroaki Inokuchi