And Boron Patents (Class 501/61)
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Patent number: 12217905Abstract: An electronic component includes a glass ceramic layer and a conductor layer. The glass ceramic layer includes feldspar crystal phases, non-crystalline glass phases, and Al2O3 phases. The area ratio of the feldspar crystal phases in the vicinity of the conductor layer is larger than the area ratio of the feldspar crystal phases away from the conductor layer.Type: GrantFiled: October 31, 2022Date of Patent: February 4, 2025Assignee: TDK CORPORATIONInventors: Hidenobu Umeda, Masaki Takahashi, Kaori Sasaki, Nami Enomoto
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Patent number: 11733162Abstract: An ultraviolet detection material includes a composite oxide including aluminum, strontium, cerium, lanthanum and manganese, and a glass having a softening point of 900° C. or lower. The ultraviolet detection material is not excited by an electromagnetic wave having a wavelength longer than 310 nm and is excited by an electromagnetic wave having a wavelength equal to or shorter than 310 nm, thereby emitting light having a peak of an emission wavelength in 480 nm or longer and 700 nm or shorter.Type: GrantFiled: February 2, 2022Date of Patent: August 22, 2023Assignee: SHINKO ELECTRIC INDUSTRIES CO., LTD.Inventors: Michio Horiuchi, Masaya Tsuno
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Patent number: 11370697Abstract: An opaque gahnite-spinel glass ceramic is provided. The glass ceramic includes a first crystal phase including (MgxZn1-x)Al2O4 where x is less than 1 and a second crystal phase includes at least one of tetragonal ZrO2, MgTa2O6, mullite, and cordierite. The glass ceramic has a Young's modulus greater than or equal to 90 GPa, and has a hardness greater than or equal to 7.5 GPa. The glass ceramic may be ion exchanged. Methods for producing the glass ceramic are also provided.Type: GrantFiled: November 22, 2019Date of Patent: June 28, 2022Assignee: Corning IncorporatedInventors: George Halsey Beall, Alexandra Lai Ching Kao Andrews Mitchell, Charlene Marie Smith
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Patent number: 10781131Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit ?-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 60-75 SiO2; 10-18 Al2O3; 5-14 Li2O; and 4.5 B2O3. The glass-ceramics also have a Vickers initiation crack threshold of at least about 25 kgf.Type: GrantFiled: January 25, 2019Date of Patent: September 22, 2020Assignee: CORNING INCORPORATEDInventors: George Halsey Beall, Qiang Fu, Charlene Marie Smith, Randall Eugene Youngman
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Patent number: 9670089Abstract: A glass sheet has a thickness of 2 mm or less and has a refractive index nd of 1.60 or more. The glass sheet allows light emitted from an organic light-emitting layer to be efficiently extracted to the outside and has high gas-barrier properties. The glass sheet comprises 15-40 mass % of BaO.Type: GrantFiled: July 7, 2010Date of Patent: June 6, 2017Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventors: Tomoki Yanase, Takashi Murata
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Patent number: 9452949Abstract: The present invention relates to a composite material, particularly a composite material for ceramic tiles, stone cladding, surface tops (e.g. worktops), and the like. The composite materials are typically derived from waste products. The composite materials of the present invention are formed from a glass component and a non-glass mineral component (e.g. ceramics and/or glaze). Generally the composite materials do not require any binders (especially synthetic binders) to hold the materials together. Therefore, the composite materials and products made therefrom are typically recyclable.Type: GrantFiled: October 30, 2013Date of Patent: September 27, 2016Assignee: University of Central LancashireInventors: Alasdair Bremner, David Stuart Binns
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Patent number: 8431501Abstract: The space glasses have a composition, in wt. % based on oxide content, including SiO2, 12-45; B2O3, 0-4; Al2O3, 0-4; TiO2, 0-5; PbO, 50-82; Na2O, 0-4; K2O, 0-8; and at least 0.1 wt. % of a total amount of at least three doping agents selected from CeO2, MoO3, Bi2O3, WO3, Ag2O, SnO2, Sb2O3 and As2O3. Light-weight and space-saving optical systems for outer space applications can be made with these space glasses, which have high UV- and VIS-transmittance and high transmittance stability, because of their high radiation resistance based on their dopant content. A preferred process for making the space glass includes melting the above-stated oxide ingredients in a quartz crucible at 1050° C. to 1200° C. to form a melt and refining the melt at 1230° C. to 1350° C.Type: GrantFiled: June 21, 2010Date of Patent: April 30, 2013Assignee: Schott AGInventors: Burkhard Speit, Silke Wolff, Thorsten Doehring
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Patent number: 8431500Abstract: The space glass has a composition, in wt. % based on oxide content, of: SiO2, 5-65; B2O3, 0-40; Al2O3, 0-12; PbO, 25-50; Na2O 0-8; K2O, 0-20; ? alkali metal oxides, at least 0.25; and at least 0.1 wt. % of a total amount of three or more doping agents selected from CeO2, MoO3, Bi2O3, WO3, Ag2O, SnO2, Sb2O3 and As2O3. In addition, it contains one or more of the following doping agents in the following amounts: at most 1 wt. %, CeO2; at most 0.02 wt. %, As2O3; at most 0.3 wt. %, Sb2O3; and at most 0.5 wt. %, SnO2. Light-weight optical systems for space are made from it, because of its high radiation resistance. A preferred process for making space glass includes melting the oxide starting ingredients at 1050° C. to 1200° C. to form a melt and refining the melt at 1230° C. to 1350° C.Type: GrantFiled: June 21, 2010Date of Patent: April 30, 2013Assignee: Schott AGInventors: Burkhard Speit, Silke Wolff, Thorsten Doehring
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Publication number: 20120129680Abstract: High-lead content crystal glass shows with advantage the refraction index higher than 1.58, high light transmission, increased mechanical solidity and chemical resistance is suitable, especially, for the production and refinement of glass jewellery products, decorative and utility objects, including chandelier trimmings and semi-finished products. This glass contains, presented in % wt., 48 to 53% of silica SiO2, 30 to 33% of lead monoxide PbO, 10 to 13% of the sum of potassium oxide and sodium oxide K2O+Na2O, 1 to 3% of calcium oxide CaO, 0.5 to 1% of zinc oxide ZnO, 0.5 to 1% of boron trioxide B2O3, less than 0.3 % of barium monoxide BaO, less than 0.3% of aluminium oxide AI2O3, 0.2 to 0.5% of antimony trioxide Sb2O3, 0.007 to 0.01% of oxides of iron.Type: ApplicationFiled: June 9, 2010Publication date: May 24, 2012Inventors: Jan Korensky, Kveta Sazavova, Jiri Vavrena
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Publication number: 20100323874Abstract: The optical glasses have increased refractive indices and are useful for making space-saving and light-weight imaging optics with lenses of different glass types for use in different objects travelling in space. The optical glasses are suitable for production of optics having low total weight, which is decisive for space applications. These space glasses have high UV- and VIS-transmittance in a range of between 300 and 800 nm and high stability of transmittance over a period of years, because their aging has been greatly limited.Type: ApplicationFiled: June 21, 2010Publication date: December 23, 2010Inventors: Burkhard Speit, Silke Wolff, Thorsten Doehring
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Publication number: 20100323875Abstract: The optical glasses have increased refractive indices and are useful for making space-saving and light-weight imaging optics with lenses of different glass types for use in different objects travelling in space. The optical glasses are suitable for production of optics having low total weight, which is decisive for space applications. These space glasses have high UV- and VIS-transmittance in a range of between 300 and 800 nm and high stability of transmittance over a period of years, because their aging has been greatly limited.Type: ApplicationFiled: June 21, 2010Publication date: December 23, 2010Inventors: Burkhard Speit, Silke Wolff, Thorsten Doehring
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Patent number: 7816292Abstract: A glass powder or a glass-ceramic powder is provided that includes multicomponent glasses with at least three elements, where the glass powder or a glass-ceramic powder has a mean particle size of less than 1 ?m. In some embodiments, the mean particle size is less than 0.1 ?m, while in other embodiments the mean particle size is less than 10 nm.Type: GrantFiled: May 25, 2005Date of Patent: October 19, 2010Assignee: Schott AGInventors: Jose Zimmer, Johann Daimer, Matthias Rindt, Susanne Kessler, Joern Besinger, Karine Seneschal-Merz
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Publication number: 20100215993Abstract: There is provided a glass substrate which has the properties required in the use as a substrate for an information recording medium of the next generation such as a perpendicular magnetic recording system, and can be applied as a substrate for an information recording medium of the next generation particularly on the premise of using the glass substrate in a dynamic environment. More particularly, there is provided a glass substrate for an information recording medium which has sufficiently high surface hardness, has a good balance between specific gravity and mechanical strength, and has high strength to withstand high speed rotation or drop impact, and which can be produced with a high productivity adequate for a direct press method, without the occurrence of bubbles in the glass blank or reboil upon pressing even if arsenic components or antimony components are not substantially used.Type: ApplicationFiled: February 23, 2010Publication date: August 26, 2010Applicant: OHARA INC.Inventors: Toshitaka Yagi, Naoyuki Goto
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Patent number: 7217672Abstract: An optical glass wherein an amount of change in refractive index (?n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.Type: GrantFiled: September 18, 2003Date of Patent: May 15, 2007Assignee: Kabushiki Kaisha OharaInventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
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Patent number: 7196027Abstract: An optical glass wherein an amount of change in refractive index (?n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43 W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.Type: GrantFiled: June 1, 2001Date of Patent: March 27, 2007Assignee: Kabushiki Kaisha OharaInventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
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Patent number: 7041165Abstract: The invention concerns a method for making cold-process bituminous mixes, using a bitumen-type emulsion in aqueous phase and aggregates. It consists of treating said aggregates with an agent providing hydrophobicity, prior to mixing said emulsion with said aggregates.Type: GrantFiled: October 23, 2001Date of Patent: May 9, 2006Assignee: Totalfinaelf FranceInventor: Michel Malot
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Patent number: 7037868Abstract: The present invention provides zinc-free glass frits that can be used to formulate glaze compositions that develop glossy surfaces when fired on ceramic products such as floor tile and wall tile. The zinc-free glass frits include, by weight, from about 50% to about 70% SiO2, from about 5% to about 20% CaO, from about 3% to about 15% Al2O3, up to about 20% BaO, up to about 15% B2O3, up to about 10% K2O, up to about 10% Na2O, up to about 10% ZrO2, up to about 5% MgO and up to about 5% PbO and less than 0.5% ZnO. Glaze compositions comprising the zinc-free glass frits can be fired using conventional double fast firing, single fast firing, and gres porcellanato ceramic firing cycles.Type: GrantFiled: December 10, 2003Date of Patent: May 2, 2006Assignee: Ferro CorporationInventors: Jose Antonio Pascual Herrero, Juan Uso Villanueva, Antonio Manuel Querol Villalba
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Patent number: 6989633Abstract: An alkaline-earth aluminosilicate glass having a composition (in % by weight, based on oxide) of SiO2>55-64; Al2O3 13-18; B2O3 0-5.5; M5O 0-7; CaO 5.5-14; SrO 0-8; BaO 6-17; ZrO2 0-2; CeO2 0-0.3; TiO2 0-0.5; CoO 0.01-0.035; Fe2O3 0.005-0.05; and NiO 0-0.Type: GrantFiled: February 3, 2003Date of Patent: January 24, 2006Assignee: Schott AGInventors: Christian Kunert, Karin Naumann, Franz Ott, Ottmar Becker
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Patent number: 6806216Abstract: Zinc-containing optical glass materials with a refractive index nd between 1.52 and 1.66, an Abbe number vd of between 35 and 54 and a composition (in % by weight based on oxide) of: SiO2 38-58, ZnO 0.3-42, PbO 0-<30, ZnO+PbO 20-55, Li2O 0-<3, Na2O 0-14, K2O 0-12, Li2O+Na2O+K2O≧2, F 0-3, MgO 0-6, CaO 0-<5, SrO 0-6, BaO 0-<0.9, B2O3 0-<1, Al2O3 0-<1.5 and ZrO2 0-<2 and, if appropriate, refining agents in the customary amounts.Type: GrantFiled: December 1, 2000Date of Patent: October 19, 2004Assignee: Schott GlasInventors: Ina Mitra, Danuta Grabowski, Uwe Kolberg, Paul Kissl
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Publication number: 20040198582Abstract: The present invention provides an optical element including a silver halide-containing glass material having a concentration of less than 0.001 wt % cerium; and a refractive index pattern formed in the silver halide-containing glass material, the refractive index pattern including regions of high refractive index and regions of low refractive index, the difference between the refractive indices of the high refractive index regions and the low refractive index regions being at least 4×10−5 at a wavelength of 633 nm. The present invention also provides methods for making optical elements from siliver halide-containing glass materials.Type: ApplicationFiled: April 1, 2003Publication date: October 7, 2004Inventors: Nicholas F. Borrelli, George B. Hares, Joseph F. Schroeder
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Publication number: 20040048730Abstract: An optical glass wherein an amount of change in refractive index (&Dgr;n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.Type: ApplicationFiled: September 18, 2003Publication date: March 11, 2004Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
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Patent number: 6699605Abstract: In a sintered glass ceramic product including at least three layers each of which is formed by a glass ceramic material, the layers are stacked to be substantially symmetrical in a stacking direction and integrally sintered. Among the sintered layers, each of outermost layers and an inner layer adjacent thereto have crystal phases different from each other. Each of the outermost layers and the inner layer have thermal expansion coefficients &agr;1 and &agr;2 selected so that the relationship given by 0<&agr;2−&agr;1<5 ppm is satisfied.Type: GrantFiled: August 20, 2002Date of Patent: March 2, 2004Assignee: Nippon Electric Glass Co., LTDInventors: Yoshio Umayahara, Yoshikatsu Nishikawa, Kazuyoshi Shindo
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Publication number: 20030064879Abstract: An optical glass includes SiO2; PbO; B2O3; not less than 0.1 mass % of TeO2; and not less than 0.4 mass % of Li2O.Type: ApplicationFiled: May 21, 2002Publication date: April 3, 2003Applicant: KABUSHIKI KAISHA OHARAInventors: Michiko Ogino, Yoshio Mori, Masahiro Onozawa, Junko Ishioka
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Patent number: 6498116Abstract: Coating and filler materials for localized thermal processing of glazed ceramics and other brittle and low thermal conductivity materials. The coating materials include oxide compositions that exhibit coefficients of thermal expansion which are less than about 8×10−6/° C. and glass transition temperatures which are less than about 400° C. The filler materials include particulate oxide materials which do not substantially react during localized thermal processing of glazed ceramics and other brittle and low thermal conductivity materials. The coating and filler materials are useable together as a composite material for repairing cavities having depths greater than about 2 mm.Type: GrantFiled: May 4, 2000Date of Patent: December 24, 2002Assignee: Rutgers, the State UniversityInventors: Richard Long Lehman, Yuya Umezu, Jie Li, Daniel Ely Murnick, James Colaizzi
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Patent number: 6432853Abstract: The present invention is directed at a leaded copper boroaluminosilicate glass, having coefficients of thermal expansion (CTES) of between 25-55×10−7/°C. (over a range of 25-300° C.) and a softening point in the range of 550-725° C., being suitable for use as a sealing glass, especially for borosilicate glasses, and having a composition consisting essentially, in terms of weight percent on an oxide basis, of 27-60 SiO2, 3-14 Al2O3, 9-28 B2O3, 0.0-10 R2O, 0.1-40 PbO, 0.1-11 CuO, where R2O is an alkali oxide selected from the group consisting of Li2O, Na2O, K2O, Rb2O and Cs2O.Type: GrantFiled: June 1, 2000Date of Patent: August 13, 2002Assignee: Corning IncorporatedInventors: George B. Hares, Dianna M. Young
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Publication number: 20010017044Abstract: Zinc-containing optical glass materials with a refractive index nd between 1.52 and 1.66, an Abbe number &ngr;d of between 35 54 and a composition (in % by weight based on oxide) of: SiO2 38-58, ZnO 0.3-42, PbO 0-<30, ZnO+PbO 20-55, Li2O 0-<3, Na2O 0-14, K2O 0-12, Li2O+Na2O+K2O≧2, F 0-3, MgO 0-6, CaO 0-<5, SrO 0-6, BaO 0-<0.9, B2O3 0-<1, Al2O3 0-<1.5 and ZrO2 0-<2 and, if appropriate, refining agents in the customary amounts.Type: ApplicationFiled: December 1, 2000Publication date: August 30, 2001Inventors: Ina Mitra, Danuta Grabowski, Uwe Kolberg, Paul Kibl
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Patent number: 6214482Abstract: A dielectric layer for use in a magneto-optic storage medium contains a compound glass of SiO2—MO2, SiO2—M2O3, or SiO2—M2O5 and combinations thereof where M is selected from Zr, Ti, Al, Nb, Y, Sn, In, Ta and Sb.Type: GrantFiled: April 7, 1994Date of Patent: April 10, 2001Assignee: Information Business Machines CorporationInventors: Christopher Vincent Jahnes, Fletcher Jones, Joseph Skinner Logan, Michael Allen Russak
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Patent number: 5747399Abstract: In order to provide a glass which can be sealed to tungsten and Kovar and has a solarization resistance against the ultraviolet ray, and which is adaptable for use in a fluorescent lamp of a reduced size used as a light source for a lighting device in a liquid crystal display (13). The glass for use in a fluorescent lamp which consists essentially, by weight, of SiO.sub.2 55-79%, B.sub.2 O.sub.3 12.5-25%, Al.sub.2 O.sub.3, 0.5-10% Li.sub.2 O+Na.sub.2 O+K.sub.2 O 1-16%, ZrO.sub.2 0.01-5%, TiO.sub.2 +PbO+Sb.sub.2 O.sub.3 0.05-11%.Type: GrantFiled: September 10, 1996Date of Patent: May 5, 1998Assignee: Nippon Electric Glass Co., Ltd.Inventors: Hiroyuki Kosokabe, Koichi Hashimoto
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Patent number: 5565389Abstract: The invention relates to a glass of high refractive index suitable for the close-vision part of multifocal, in particular phototropic multifocal, spectacle lenses. The glass has a composition (in % by weight, based on oxide) of:SiO.sub.2 28-40; B.sub.2 O.sub.3 0-8.5; Li.sub.2 O 0-1; Na.sub.2 O 0-2.5; K.sub.2 O 0-5; CaO 0-6; SrO 0-6; BaO 6-12; ZnO 9-16; PbO 32-40; TiO.sub.2 0.3-7; ZrO.sub.2 0.4-5; .SIGMA. Li.sub.2 O+Na.sub.2 O+K.sub.2 O 0-5, anda refractive index n.sub.e of 1.66-1.81, an expansion coefficient .alpha..sub.20-300 of 5.7-6.8.times.10.sup.-6 K.sup.-1, a softening point of 650.degree.-700.degree. C. and a glass transition temperature Tg of 520.degree.-560.degree. C.Type: GrantFiled: August 31, 1995Date of Patent: October 15, 1996Assignee: Deutsche Spezialglas A.G.Inventor: Reinhard Kassner
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Patent number: 5304518Abstract: A hybrid package comprising a glass ceramic substrate and an aluminum nitride substrate bonded thereto, said glass ceramics substrate has a thermal expansion coefficient substantially the same as that of the aluminum nitride substrate.Type: GrantFiled: June 18, 1991Date of Patent: April 19, 1994Assignee: Asahi Glass Company Ltd.Inventors: Kazuo Sunahara, Naosi Irisawa, Katumasa Nakahara, Kazunari Watanabe, Mitsuo Takabatake
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Patent number: 5283210Abstract: A low temperature sintering, low dielectric inorganic composition is a ternary inorganic composition comprising cordierite, quartz glass and lead borosilicate glass, wherein if the amounts of the cordierite, quartz glass and lead borosilicate glass are represented by X, Y and Z (wt %) respectively, the composition of the ternary system falls within the range encircled by the following four points (a) to (d) including the lines between each neighboring two points:(X=35; Y=0; Z=65) (a)(X=65; Y=0; Z=35) (b)(X=0; Y=65; Z=35) (c)(X=0; Y=35; Z=65) (d)The inorganic composition has a dielectric constant substantially lower than that of the conventional composition while maintaining high reliability such as an ability of being sintered at a low temperature, high insulation properties and high resistance to water as well as excellent mechanical properties such as strength.Type: GrantFiled: June 29, 1992Date of Patent: February 1, 1994Assignee: NEC CorporationInventors: Keiichiro Kata, Yuzo Shimada
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Patent number: 5265327Abstract: A process for fabricating microchannel plates produces large area microchannel plates that have channel exit openings as small as 0.5 micron, MTF .about.1, pitch-limited resolution (a factor of 10 potential improvement in resolution) and at a cost of $0.40/sq. centimeter, and with funneling controlled as to configuration and exit opening size and shape. Microchannels may be rectangular in cross section, or rectangular, or trapezoidal, or other configuration, including straight sided, chevron or balloon sided. Microchannels of differing configurations may be interspersed, for reasons of alignment or to control pixel characteristics. Material choice may include glass, ceramic, metal, alloy and plastics, plus dopants. This materials flexibility, and the improved geometrical uniformity lead to higher signal-to-noise ratio and lower outgassing, and to a significant improvement in performance.Type: GrantFiled: September 13, 1991Date of Patent: November 30, 1993Inventors: Sadeg M. Faris, Kanti Jain
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Patent number: 5204289Abstract: This invention provides a composite article comprising mullite bubbles dispersed in one of a glass matrix and a glass-ceramic matrix, and a method of making the same. The composite ceramic article of the present invention is useful in applications requiring a material having a low dielectric constant, low dissipation factor, thermal expansion properties compatible with silicon, and good mechanical strength. The composite ceramic article of the present invention is particularly useful as a substrate for thick film circuits, housings for integrated circuit assemblies (i.e., covers), and materials such as gyrotron windows, that require transparency to microwaves or millimeter waves, in addition to acceptable power transmission efficiencies.Type: GrantFiled: October 18, 1991Date of Patent: April 20, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventor: Kyung H. Moh
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Patent number: 5204292Abstract: An optical glass for a press lens composed of 25 to 41 mol % of SiO.sub.2, 10 to 30 mol % of B.sub.2 O.sub.3, 18 to 40 mol % of PbO, 1 to 10 mol % of Na.sub.2 O, 1 to 15 mol % of K.sub.2 O, 2 to 20 mol % of Li.sub.2 O, and 0.3 to 3 mol % of Al.sub.2 O.sub.3.Type: GrantFiled: April 1, 1991Date of Patent: April 20, 1993Assignee: Alps Electric Co., Ltd.Inventor: Tooru Michimata
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Patent number: 5162826Abstract: This invention relates to the production of glasses exhibiting a refractive index between about 1.66-1.81, a softening point between about 625.degree.-675.degree. C., a strain point between about 455.degree.-490.degree. C., a linear coefficeint of thermal expansion (25.degree.-300.degree. C.) between about 53-65.times.10.sup.-7 /.degree.C., and good chemical durability which consist essentially, in weight percent, of:______________________________________ SiO.sub.2 24-42 Li.sub.2 O 0.2 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 0-3.5 Al.sub.2 O.sub.3 3-7.5 Na.sub.2 O 0-2 ZrO.sub.2 0-2.5 B.sub.2 O.sub.3 2-7.5 K.sub.2 O 0-3 TiO.sub.2 0-8 PbO 35-57 La.sub.2 O.sub.3 0-8 La.sub.2 O.sub.3 + ZrO.sub.2 4-12.sub.Type: GrantFiled: June 17, 1991Date of Patent: November 10, 1992Assignee: Corning IncorporatedInventors: David W. Morgan, Michel Prassas
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Patent number: 5118643Abstract: A ceramic composition for forming a ceramic dielectric body having a dielectric constant of less than about 4.2 at 1 MHz and a linear thermal expansion coefficient of 2.5-3.0 ppm/.degree. C. from room temperature to 200.degree. C. The composition comprises a mixture of finely divided particles of 25-50 vol. % borosilicate glass and 50-75 vol. % titanium silicate glass. The composition can be used with a polymeric binder to produce an unfired green tape which is co-fireable with high conductivity metallurgies such as gold, silver and silver/palladium.Type: GrantFiled: October 25, 1990Date of Patent: June 2, 1992Assignee: Aluminum Company of AmericaInventors: Jau-Ho Jean, Tapan K. Gupta
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Patent number: 5089172Abstract: A thick film conductor composition adapted to be bonded to an aluminum nitride substrate is provided which comprises a sufficient amount of conductive metallic material to render the conductor composition electrically conductive when bonded to the substrate, a glass frit binder for the metallic material capable of being bonded to the substrate, and a lithium containing compound capable of reacting with the substrate upon heating so as to aid in adherently bonding the conductor composition to the aluminum nitride substrate. A thick film conductor bonded onto the surface of an aluminum nitride substrate as well as a method of producing the same are also provided.Type: GrantFiled: August 31, 1987Date of Patent: February 18, 1992Assignee: Ferro CorporationInventors: Kevin W. Allison, Dana L. Hankey, Edward Stadnicar, Jr., Gordon J. Roberts
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Patent number: 5079193Abstract: An encapsulant composition comprising a lead zinc silicoborate glass which forms a crystalline phase of Zn.sub.2 SiO.sub.4 and ZnB.sub.2 O.sub.4 when it is fired at 650.degree.-800.degree. C.Type: GrantFiled: July 31, 1990Date of Patent: January 7, 1992Assignee: E. I. Du Pont de Nemours and CompanyInventor: Paul C. Donohue
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Patent number: 5075261Abstract: A sealing material for sealing electronic parts is composed of a low-melting-point glass and a filler which has its surface modified by coating with ZnO and is compatible with low melting point glass.Type: GrantFiled: May 15, 1990Date of Patent: December 24, 1991Assignee: Nippon Electric Glass Co., Ltd.Inventor: Toshio Yamanaka
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Patent number: 5073524Abstract: Cerium-doped radiation-shielding glasses in the system of SiO.sub.2 -PbO-alkali metal oxides, with a high absorption coefficient for high-energy X-ray and/or gamma- and, respectively, neutron radiation which are resistant to discoloration and exhibit a discharge stability of >5.times.10.sup.8 rad, consist essentially of (in % by weight)______________________________________ SiO.sub.2 35-56 Na.sub.2 O K.sub.2 O 12-21 Cs.sub.2 O PbO.sub.2 24-46 CeO.sub.2 0.5-2.5 CuO + Fe.sub.2 0-0.05; ______________________________________for absorption of neutrons, the isotope Li.sup.6 can furthermore be onctained therein, and SiO.sub.2 can be substituted by B.sub.2 O.sub.3 and/or Gd.sub.2 O.sub.3 in an amount of up to 10% by weight and Gd.sub.2 O.sub.3 is present.Type: GrantFiled: June 6, 1990Date of Patent: December 17, 1991Assignee: Schott GlaswerkeInventor: Burkhard Speit
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Patent number: 5068210Abstract: A dense, sintered ceramic material having a low dielectric constant, a low firing temperature, and a low coefficient of thermal expansion is provided from a mixture of 0-30 wt. % alumina, 30-60 wt. % fused silica, and 30-70 wt. % of a glass comprised of PbO, B.sub.2 O.sub.3, and SiO.sub.2. The mixture has a minimum sintering temperature in the range of 800.degree.-900.degree. C., and can be formed by conventional manufacturing techniques. It is particularly useful for the fabrication of single or multilayer electronic circuit substrates.Type: GrantFiled: May 17, 1988Date of Patent: November 26, 1991Assignee: Tektronix, Inc.Inventors: John F. DiLazzaro, James L. McAlpin, Joanne R. Mark
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Patent number: 5057464Abstract: A radiation shielding glass consisting esentially of 40.0% to 60.0% SiO.sub.2, 25.0% to 45.0% of PbO, 1.5% to 2.0% CeO.sub.2, 4.5% to 12.0% Na.sub.2 O, 2.0% to 9.0% K.sub.2 O, 0% to 5.0% B.sub.2 O.sub.3, and 0% to 10.0% BaO, Na.sub.2 O/(Na.sub.2 O+K.sub.2 O) being 0.5 to 0.8. The glass has a high radiation shielding capacity and is excellent in a resistance to browning by the gamma ray irradiation and an improved dielectric breakdown. The glass is useful for a window glass of an irradiation room of the gamma ray.Type: GrantFiled: February 9, 1990Date of Patent: October 15, 1991Assignee: Nippon Electric Glass Co., Ltd.Inventors: Yoshiharu Miwa, Kazuhiko Asahi
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Patent number: 5047371Abstract: The present invention relates to a glass/ceramic sealing system. A sealing glass having a coefficient of thermal expansion in excess of 160.times.10.sup.-7 in/in/.degree. C. is provided. The glass is useful for matched sealing of copper and copper based alloys. The glass is capable of ceramization, greatly increasing the resistance of the glass to moisture penetration and fracture due to mechanical damage. The temperature of ceramization has been designed so that a solutionized copper alloy leadframe is age hardened during ceramization. The glass has particular utility in the manufacture of electronic packages and multi-layer circuitry.Type: GrantFiled: September 2, 1988Date of Patent: September 10, 1991Assignee: Olin CorporationInventor: Satyam C. Cherukuri
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Patent number: 5028567Abstract: A glass-ceramic obtained by heat treating a parent glass in which specific amounts of MgO and PbO are added to the SiO.sub.2 - Al.sub.2 O.sub.3 - ZnO - TiO.sub.2 system glass has a wide range of coefficients of thermal expansion and improved fineness in diameters of crystals and also improved chemical durability or thermal expansion curve.Type: GrantFiled: May 24, 1988Date of Patent: July 2, 1991Assignee: 501 Kabushiki Kaisha OharaInventors: Naoyuki Gotoh, Makoto Hayasaka
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Patent number: 5015909Abstract: A glass composition consisting essentially of the following components present in the glass in the following mole percent ranges is shown:CHART I ______________________________________ CHEMICAL COMPOSITION RANGES mole percent ______________________________________ SiO.sub.2 58-68 Al.sub.2 O.sub.3 0-2 K.sub.2 O + Rb.sub.2 O + Cs.sub.2 O 0-3 PbO 10-15 Bi.sub.2 O.sub.3 0.3-2.1 MgO + CaO + BaO 10-20.4 B.sub.2 O.sub.3 0-4 As.sub.2 O.sub.3 + Sb.sub.2 O 0.1-1.1 ______________________________________A glass composition for manufacturing a high performance microchannel plate is also shown. A microchannel plate made from a glass composition consisting essentially of components in the glass range as defined above is also shown. A method for making a non-porous glass tubing comprising a hollowed out central area and having a transformation temperature in range of about 570.degree. C. to about 610.degree. C., a liquidus temperature below 1000.degree. C.Type: GrantFiled: December 29, 1989Date of Patent: May 14, 1991Assignee: Circon CorporationInventors: William J. S. Zhong, John A. Williams
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Patent number: 5008176Abstract: An information recording disk for recording an information signal along a track defined by a depression on the disk as a change of physical property of a recording material deposited on the track comprises a disk-shaped glass substrate made of a glass and carries a groove corresponding to the track. The groove has a surface roughness substantially smaller as compared to the surface roughness caused at a bottom surface of a groove on a silica glass substrate when both the disk-shaped glass substrate and silica glass substrate are dry-etched under same conditions. The disk-shaped glass substrate comprises SiO.sub.2 component and one or both of Al.sub.2 O.sub.3 and BaO components with substantially no alkali components. Further, a recording layer comprised of the recording material which changes in physical property responsive to a projected energy beam is deposited on the substrate such that the depression is formed in correspondence with the track.Type: GrantFiled: September 28, 1988Date of Patent: April 16, 1991Assignee: Victor Company of Japan, Ltd.Inventors: Tetsuya Kondo, Noboru Kawai
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Patent number: 5001086Abstract: There is disclosed a sintered, alpha-cordierite solid solution glass-ceramic body in which the properties of coefficient of thermal expansion and modulus of rupture are stabilized and controlled by using a combination of two dopants in the glass during sintering and crystallization. There is further disclosed the method of producing such bodies, and controlling such properties, through the use of the two dopants.Type: GrantFiled: October 26, 1989Date of Patent: March 19, 1991Assignee: Corning IncorporatedInventors: Gerald B. Carrier, Gaylord L. Francis, Robert J. Paisley, Donald M. Trotter, Jr., Kathleen A. Wexell
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Patent number: 4980319Abstract: Alkali silicate glasses, colorized with Co.sup.2+ or with Co.sup.2+ and Ni.sup.2+, and having the composition:______________________________________ SiO.sub.2 52-71% by weight PbO 2.9-16.8% by weight SnO.sub.2 0.1-1.65% by weight Na.sub.2 O 6.7-16.7% by weight K.sub.2 O 0.5-9.9% by weight Na.sub.2 O + K.sub.2 O 13.3-18.3% by weight [NiO + CoO 0.1-4.4% by weight Ni.sub.2 O.sub.3 + Co.sub.2 O.sub.3 ] As.sub.2 O.sub.3 + Sb.sub.2 O.sub.3 0.05-0.5% by weight .SIGMA. RO 0-8.6% by weight B.sub.2 O.sub.3 0-8.5% by weight Al.sub.2 O.sub.3 0-0.55% by weight ZnO 0-10.5% by weight, ______________________________________in which R is Mg, Ca, Sr, Ba or a combination thereof, are disclosed. The composition of the present invention is not to include CeO.sub.2. The alkali silicate glasses of the invention are useful as optical filter glasses.Type: GrantFiled: November 13, 1989Date of Patent: December 25, 1990Assignee: Schott GlaswerkeInventor: Burkhard Speit
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Patent number: 4966926Abstract: An encapsulant composition comprising a lead zinc silicoborate glass which forms a crystalline phase of Zn.sub.2 SiO.sub.4 and ZnB.sub.2 O.sub.4 when it is fired at 650.degree.-800.degree. C.Type: GrantFiled: August 11, 1989Date of Patent: October 30, 1990Assignee: E. I. Du Pont de Nemours and CompanyInventor: Paul C. Donohue
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Patent number: 4961998Abstract: Dielectric ink, paste and tape compositions having controlled thermal expansion contain a mixture of glasses wherein at least one glass has a coefficient of thermal expansion (CTE) below the CTE of the substrate to which the dielectric composition is applied and at least one glass has a CTE above the CTE of said substrate. The dielectric compositions significantly reduce or eliminate warpage of the substrate.Type: GrantFiled: February 10, 1989Date of Patent: October 9, 1990Assignee: National Starch and Chemical Investment Holding CorporationInventors: Robert E. Senkalski, Donald L. Hasenmayer