And Yttrium Or Rare Earth (i.e., Elements With Atomic Numbers 39 Or 57-71) Patents (Class 501/64)
  • Publication number: 20040254057
    Abstract: The invention relates to bismuth oxide glass, containing germanium oxide, a method for the production thereof, the use thereof and a glass fiber consisting of said inventive glass.
    Type: Application
    Filed: March 8, 2004
    Publication date: December 16, 2004
    Inventors: Bianca Schreder, Rudiger Sprengard, Ulrich Peuchert, Martin Letz, Joseph s Hayden, Sally Pucilowski
  • Patent number: 6831791
    Abstract: An optical system for optical communications is composed of a transparent material having a refractive index distribution formed by changing the molar ratio of metal oxide with valence of 2 or more. The metal oxide with valence of 2 or more includes, for example, Fe2O3. Using such an optical system for optical communications, optical communication components such as an optical fiber collimator and an optical isolator are composed.
    Type: Grant
    Filed: December 29, 2003
    Date of Patent: December 14, 2004
    Assignee: Olympus Corporation
    Inventors: Mitsuru Namiki, Hirofumi Tsuchida
  • Patent number: 6831030
    Abstract: A high transmittance glass sheet is provided that is formed of a soda-lime-silica glass composition containing, expressed in wt. %, less than 0.020% of total iron oxide in terms of Fe2O3 and 0.006 to 2.0% of zinc oxide. The glass sheet allows the formation of nickel sulfide particles to be suppressed by the addition of a zinc compound to a glass raw material.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: December 14, 2004
    Assignee: Nippon Sheet Glass Company, Ltd.
    Inventors: Akihiro Koyama, Isamu Kuroda, Nobuyuki Yamamoto, Yasunori Seto
  • Publication number: 20040242396
    Abstract: A matrix glass for a cathode ray tube panel having excellent melt shapability and properties necessary for a cathode ray tube panel and a panel for a cathode ray tube are provided. The matrix glass is for use as a cathode ray tube panel glass after chemical strengthening, comprises, by mol %, 45 to 70% of SiO2, 0.1 to 20% of Al203, 7 to 20% of Li2O, 0.1 to 20% of Na2O, 1 to 13% of SrO, 0.1 to 3% of TiO2, 0.1 to 10% of ZrO2 and 0.01 to 1% of CeO2, and (1) exhibits a temperature of 980° C. or lower at a viscosity of 103 Pa·s or (2) contains none of MgO and CaO. The panel for a cathode ray tube is obtained by chemical strengthening of a shaped product formed of the above matrix glass.
    Type: Application
    Filed: January 24, 2003
    Publication date: December 2, 2004
    Inventor: Yoichi Hachitani
  • Publication number: 20040242397
    Abstract: An optical glass that has a refractive index (nd) of 1.56-1.66, an Abbe number (vd) of 52-63, and a transformation temperature of 420° C.-580° C., as provided by compositions including as essential components (a) SiO2, (b) B2O3, (c) BaO, (d) Y2O3, (e) Li2O, and (f) one or more from CaO, MgO, SrO, and ZnO, and optionally one or more components from (g) Na2O, (h) K2O, (i) Al2O3, and (j) ZrO2.
    Type: Application
    Filed: May 21, 2004
    Publication date: December 2, 2004
    Applicant: HIKARI GLASS CO., LTD.
    Inventor: Yoshiyuki Nakayama
  • Patent number: 6825142
    Abstract: The present invention generally relates to an interference filter including a glass substrate, useful in fiber optic systems.
    Type: Grant
    Filed: January 7, 2002
    Date of Patent: November 30, 2004
    Assignee: Schott Glass Technologies, Inc.
    Inventors: Sally Pucilowski, David G. Krashkevich
  • Publication number: 20040235636
    Abstract: Compositions for producing a glass substrate comprise SiO2 with a weight percentage (wt %) from 55% to 70%, Al2O3 from 10 wt % to 18 wt %, B2O3 from 10 wt % to 15 wt %, CaO from 0 wt % to 10 wt %, SrO from 0 wt % to 4 wt %, and a particular composition for forming a network structure of SiO2 from 0.01 wt % to 10 wt %, in which the particular composition can be selected from a group consisting of Y2O3 and La2O3.
    Type: Application
    Filed: December 29, 2003
    Publication date: November 25, 2004
    Applicant: Picvue Optoelectronics International, Inc.
    Inventors: Hsien-Yin Tsai, Chien-Sheng Yeh
  • Patent number: 6821628
    Abstract: The cooking panel is made from an opaque glass-ceramic material uniformly colored throughout and having keatite mixed crystals as the predominant crystalline phase. The cooking panel is made by ceramicizing a ceramicizable glass or a transparent glass-ceramic with high quartz mixed crystals as the predominant crystalline phase in a definite color location range with a brightness parameter value (L*) less than 85 and a color shade and chromaticity according to its later service and wear pattern. The cooking panel makes deposited material, such as dirt and the like, less conspicuous.
    Type: Grant
    Filed: December 9, 1999
    Date of Patent: November 23, 2004
    Assignee: Schott Glas
    Inventors: Bernd Schultheis, Waldemar Weinberg, Monica Cotlear De Witzmann, Roland Dudek, Friedrich Siebers, Klaus Schoenberger
  • Publication number: 20040229743
    Abstract: A short optical glass is disclosed which is particularly suited for the applications imaging, projection, telecommunication, optical information technology and/or laser technology, also particularly suited for fiber applications (light guides or imaging guides). Preferably, the glass has a refractive index of 1.54≦nd≦1.62 and an Abbe coefficient of 48≦vd=57. It further has good attenuating and ion exchange characteristics, good chemical stability and good crystallization stability. The glass comprises 35 to 50 wt.-% SiO2, 0.1 to 6 wt.-% B2O3, 0.1 to 7 wt.-% Al2O3, 0.1 to 4 wt.-% P2O5, 4 to 24 wt.-% R2O (alkali oxides), 6 to 14.5 wt.-% BaO, 0 to 12 wt.-% other RO (alkaline earth oxides), 14 to 25 wt.-% ZnO, 0 to 5 wt.-% La2O3, 0 to 10 wt.-% ZrO2, wherein R2O is an alkali oxide, RO is an alkaline earth oxide other than BaO, wherein Li2O is 6 wt.
    Type: Application
    Filed: February 27, 2004
    Publication date: November 18, 2004
    Inventors: Silke Wolff, Ute Woelfel, Uwe Kolberg, Holger Kasprzik
  • Publication number: 20040229744
    Abstract: A method is provided for making clear glass having an azure edge coloration and low amber surface coloration in a non-vacuum float glass system. The method includes processing batch materials in a non-vacuum float glass system to provide a final glass product including: 1 SiO2 65-75 wt. %;  Na2O 10-20 wt. %;  CaO 5-15 wt. %;  MgO 0-5 wt. %; Al2O3 0-5 wt. %; K2O 0-5 wt.
    Type: Application
    Filed: May 14, 2003
    Publication date: November 18, 2004
    Inventor: Robert B. Heithoff
  • Patent number: 6815385
    Abstract: A tungsten sealing glass for use in a fluorescent lamp, said glass having a composition of, by mass percent, 65-76% SiO2, 10-25% B2O3, 2-6% Al2O3, 0.5-5.8% MgO+CaO+SrO+BaO+ZnO, 3-8% Li2O+Na2O+K2O, 0.01-4% Fe2O3+CeO2, 0.1-5% TiO2, 0.1-10% TiO2+Sb2O3+PbO, and 0-2% ZrO2, wherein Na2O/(Na2O+K2O)≦0.6.
    Type: Grant
    Filed: July 15, 2003
    Date of Patent: November 9, 2004
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hiroyuki Kosokabe, Koichi Hashimoto
  • Publication number: 20040220038
    Abstract: A short optical glass is disclosed which does not comprise any silver, copper, thallium, lead or boron and is particularly suited for the application imaging, projection, telecommunication, optical information technology, and/or laser technology, also particularly suited for fiber applications (light guides or imaging guides). Preferably the glass has a refractive index of 1.55≦nd≦1.65 and an Abbe coefficient of 48≦vd≦57 and also has good attenuating and ion exchange characteristics, good chemical stability and good crystallization stability. The glass comprises 35 to <50 wt.-% SiO2; 1 to 10 wt.-% Al2O3; 5 to 15 wt.-% Na2O+K2O+CS2O+Li2O; 20 to 30 wt.-% BaO; 0 to 15 wt.-% ZnO; 0 to 10 wt.-% La2O3; 0 to 10 wt.-% ZrO2; 0 to 6 wt.-% P2O5; 0 to 8 wt.-% MgO+CaO+SrO; 0 to 3 wt.-% of other oxides, and Cs2O<1, Li2O<1, and TiO2<1 wt.-%.
    Type: Application
    Filed: February 24, 2004
    Publication date: November 4, 2004
    Inventors: Silke Wolff, Ute Woelfel, Uwe Kolberg, Holger Kasprzik
  • Publication number: 20040209757
    Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: 1 total iron (expressed as Fe2O3): 0.01 to 0.30% erbium oxide (e.g., Er2O3): 0.01 to 0.30%.
    Type: Application
    Filed: February 25, 2004
    Publication date: October 21, 2004
    Applicant: Guardian Industries Corp.
    Inventors: Leonid Landa, Ksenia A. Landa, Scott V. Thomsen, Richard Hulme
  • Patent number: 6806216
    Abstract: Zinc-containing optical glass materials with a refractive index nd between 1.52 and 1.66, an Abbe number vd of between 35 and 54 and a composition (in % by weight based on oxide) of: SiO2 38-58, ZnO 0.3-42, PbO 0-<30, ZnO+PbO 20-55, Li2O 0-<3, Na2O 0-14, K2O 0-12, Li2O+Na2O+K2O≧2, F 0-3, MgO 0-6, CaO 0-<5, SrO 0-6, BaO 0-<0.9, B2O3 0-<1, Al2O3 0-<1.5 and ZrO2 0-<2 and, if appropriate, refining agents in the customary amounts.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: October 19, 2004
    Assignee: Schott Glas
    Inventors: Ina Mitra, Danuta Grabowski, Uwe Kolberg, Paul Kissl
  • Patent number: 6800574
    Abstract: In one aspect, the invention provides glass beads and optical devices comprising the glass beads. In other aspects, the invention provides methods of making said glass beads and rapid glass screening methods that use glass beads. Glass beads of the invention comprise greater than 80 weight percent silica, active rare earth dopant, and modifying dopant. In another embodiment the glass beads comprise greater than 80 weight percent silica and at least 5 weight percent germania. In another embodiment, glass beads comprise and from about 20 to about 90 anion mole percent of non-oxide anion.
    Type: Grant
    Filed: October 24, 2001
    Date of Patent: October 5, 2004
    Assignee: 3M Innovative Properties Company
    Inventor: Mark T. Anderson
  • Publication number: 20040180775
    Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments of making glass according to examples of the invention, the glass batch may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: 1 total iron (expressed as Fe2O3): 0.01 to 0.30% erbium oxide (e.g., Er2O3): 0.01 to 0.30% cerium oxide (e.g., CeO2):  0.005 to 0.30%.
    Type: Application
    Filed: March 29, 2004
    Publication date: September 16, 2004
    Applicant: Guardian Industries Corp.
    Inventors: Leonid Landa, Ksenia A. Landa, Scott V. Thomsen, Richard Hulme
  • Patent number: 6790799
    Abstract: A glass panel for a color cathode ray tube, which has a linear absorption coefficient of X-ray with a wavelength of 0.06 nm of from 30 to 38 cm−1 and which has a layer having a compression stress of at least 70 MPa formed by a chemical strengthening method at least at short axis end portions and/or long axis end portions of the outer surface of a face portion and at a center portion of the inner surface of the face portion.
    Type: Grant
    Filed: May 7, 2002
    Date of Patent: September 14, 2004
    Assignee: Asahi Glass Company, Limited
    Inventors: Yuichi Kuroki, Tsunehiko Sugawara
  • Patent number: 6784129
    Abstract: The ultraviolet/infrared absorbent low transmittance glass has a grayish green color shade, low visible light transmittance, low total solar energy transmittance, and low ultraviolet transmittance, and is suitable for a rear window of a vehicle and capable of protecting privacy. The glass is formed of a base glass including: 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO, wherein a total amount of MgO and CaO is between 5 and 15 wt. %; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O, wherein a total amount of Na2O and K2O is between 10 and 20 wt. %; and 0 to 5 wt. % B2O3, and colorants including: more than 0.95 wt. % and less than 1.2 wt. % total iron oxide (T-Fe2O3) expressed as Fe2O3; 0.001 to 0.0180 wt. % CoO; and 0.003 to 0.2 wt. % NiO.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: August 31, 2004
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Hiromitsu Seto, Yukihito Nagashima, Shigekazu Yoshii
  • Patent number: 6780801
    Abstract: The present invention provides a raw material composition for soda-lime glass capable of effectively suppressing formation of nickel sulfide (NiS) in the course of melting of the glass raw material. A nickel sulfide (NiS) impurity present in soda-lime glass is formed in a high-temperature vitrification step in which metal particles containing Ni and an Ni component of stainless steel used for the interior of a melting furnace, which are mixed into glass raw material, react at high temperature with a sulfur (S) component in Na2SO4 serving as a glass raw material. However, when an additive containing an oxide, a chloride, a sulfate, or a nitrate of a metal is added in a very small amount and in advance to glass raw material, formation of NiS by the reaction between Ni and S in the course of melting can be suppressed or completely eliminated.
    Type: Grant
    Filed: March 6, 2000
    Date of Patent: August 24, 2004
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Chihiro Sakai, Yoshikazu Toshikiyo
  • Publication number: 20040157721
    Abstract: The invention relates to a coloured soda-lime glass of blue hue, containing more than 2 wt. % of MgO, more than 1.1 wt. % of Fe2O3, less than 0.53 wt. % of FeO and less than 0.13 wt. % of MnO2, and presenting under Illuminant A and for a glass thickness of 4 mm, a transmission factor (TLA4) higher than 15%, a selectivity (SE4) higher than 1.2 and a dominant wavelength (&lgr;D) and a purity of excitation (P) such that they are located in the CIE chromaticity co-ordinate diagram inside a triangle whereof the apices are defined by the point representing the illuminant source C and the points whereof the co-ordinates (&lgr;D, P) are (490,19) and (476,49) respectively. Said glass is particularly suitable for motor vehicle side windows, rear windows and sun roof.
    Type: Application
    Filed: February 5, 2004
    Publication date: August 12, 2004
    Inventors: Marc Foguenne, Dominique Coster
  • Publication number: 20040157723
    Abstract: The invention concerns a soda-lime glass. Said coloured glass contains at least 5 parts per million of Co by weight and 0.5 to 0.9 wt. % Fe2O3 oxide. The amount of ferrous iron by weight of Fe2+ atoms relative to the total weight of iron atoms present in the glass ranges between 25 and 45%. Said glass further comprises chromium and/or vanadium. The glass has a light transmission factor TLA4 ranging between 10 and 50% and an energy transmission wavelength less than 491 nm. Said glass is particularly suited for producing blue-tinted glazing for motor vehicles.
    Type: Application
    Filed: December 19, 2002
    Publication date: August 12, 2004
    Inventors: Marc Foguenne, Dominique Coster, Laurent Delmotte
  • Patent number: 6773816
    Abstract: The invention relates to driving glasses in which a thermic ray reflection layer 2 made of a metal or an organic substance is provided on the outer surface of a glass matrix 1, and an anti-reflection layer 3 is provided on the inner surface thereof, werein the glass matrix 1 contains neodymium oxide Nd2O3 of 1 through 12% by weight and praseodymium oxide Pr6O11 of 0.5 through 8% by weight, and forms an absorption peak of light transmittance at a wavelength of 510 through 540 nm and a wavelength of 570 through 590 nm.
    Type: Grant
    Filed: December 31, 2002
    Date of Patent: August 10, 2004
    Assignees: O.M.G. Kabushiki Kaisha, Inui Lens Co., Ltd.
    Inventor: Takashi Tsutsumi
  • Publication number: 20040152580
    Abstract: Glass, glass compositions, methods of preparing the glass compositions, microfluidic devices that include the glass composition, and methods of fabricating microfluidic devices that include the glass composition are disclosed. The borosilicate glass composition includes silicon dioxide (SiO2) in a range from about 60% to 74% by total composition weight; boric oxide (B2O3) in a range from about 9% to 25% by total composition weight; aluminum oxide (Al2O3) in a range from about 7% to 17% by total composition weight; and at least one alkali oxide in a range from about 2% to 7% by total composition weight. In addition, the borosilicate glass has a coefficient of thermal expansion (CTE) that is in a range between about 30×10−7/° C. and 55×10−7/° C. Furthermore, the borosilicate glass composition resists devitrification upon sintering without the addition of an inhibitor oxide.
    Type: Application
    Filed: December 2, 2003
    Publication date: August 5, 2004
    Inventor: Paulo Marques
  • Publication number: 20040145297
    Abstract: Glass comprises essentially 20-70% SiO2, 10-50% TiO2+Nb2O5+SnO2+Ta2O5+WO3+CeO2, 0-50% MgO+CaO+SrO+BaO+ZnO, and 0-30% B2O3+Al2O3, in molar percentage terms based on the oxides; and has a resistivity of at most 1015 &OHgr;·cm at 20° C. A method for production of glass is to produce the glass under such a condition that a redox represented by [Fe2+]/([Fe2+]+[Fe3+]) where Fe is present in the glass, is at least 0.6.
    Type: Application
    Filed: January 14, 2004
    Publication date: July 29, 2004
    Applicant: ASAHI GLASS COMPANY LIMITED
    Inventors: Tetsuya Nakashima, Kei Maeda
  • Publication number: 20040142810
    Abstract: The invention relates to a glass having the composition (in % by weight, based on oxide) SiO2 about 78.5—about 79.5, B2O3 about 13.0—about 14.0, Al2O3 about 2.0—about 3.0, Na2O about 4.5—about 5.5, K2O 0—about 0.6, which may be used in the production of thermal shock-resistant beverage containers, particularly teapots, coffee machine jugs and baby-milk bottles.
    Type: Application
    Filed: November 17, 2003
    Publication date: July 22, 2004
    Inventors: Christian Kunert, Johannes Roettgers, Roland Leroux, Peter Brix
  • Patent number: 6764972
    Abstract: A compositional range for a mother glass composition for graded index lenses which has a desired refractive index and is less apt to be devitrified and to develop cracks upon ion exchange was obtained by incorporating at least a given amount of one or more ingredients which are selected from oxides of metal elements ranging from yttrium, atomic number 39, to tantalum, atomic number 73, and which are less apt to cause glass coloration into a glass based on SiO2—TiO2—Li2O—Na2O and containing no lead oxide. In particular, a compositional range in which a large angular aperture is obtained and devitrification is less apt to occur was obtained by incorporating Ta2O5 and ZrO2 in a specific proportion and in specific amounts.
    Type: Grant
    Filed: October 11, 2001
    Date of Patent: July 20, 2004
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Tetsuro Yoshii, Jun Yamaguchi
  • Publication number: 20040102304
    Abstract: The present invention is a bronze and gray glass composition. The composition comprises 68 to 75% SiO2, 10 to 18% Na2O, 5 to 15% CaO, 0 to 10% MgO, 0 to 5% Al2O3, and 0 to 5% K2O, where CaO+MgO is 6 to 15% and Na2O+K2O is 10 to 20%, and colorants comprising: 0.22 to 0.39 wt. % total iron as Fe2O3 wherein the ratio of FeO/total Fe as Fe2O3 is 0.35 to 0.64; 0.1 to 0.5 wt. % manganese compound as MnO2; 0 to 1.2 wt. % cerium oxide as CeO2; and 2 to 10 ppm selenium, and 0 to 20 ppm cobalt as cobalt oxide. The colored glass has the following spectral properties at 4.0 mm. thickness: 65 to 78% light transmittance using Illuminant A (LTA) and using Illuminant C has a dominant wavelength of 493 to 577 nanometers with an excitation purity up to 7%.
    Type: Application
    Filed: November 21, 2002
    Publication date: May 27, 2004
    Inventors: Edward Nashed Boulos, James Victor Jones
  • Publication number: 20040079258
    Abstract: The invention relates to the use of ions of weakly basic oxides as linking ions for polyacids in cements, preferably polyelectrolyte cements. Suitable ions comprise elements of the scandium series, for example, Sc3+, Y3+, La3+, Ce4+ and all subsequent tri- and tetra-valent lanthanides and the ions Mg2+, Zn2+, Ga2+, In2+. The application of said ions permits a regulation of the cement reaction without surface treatment of the glass powder.
    Type: Application
    Filed: December 8, 2003
    Publication date: April 29, 2004
    Inventors: Stefan Hoescheler, Markus Mikulla, Gabriele Rackelmann, Volker Bambach
  • Publication number: 20040077478
    Abstract: It is an object of the present invention to provide a clad glass composition for graded-index rod lens for covering, during manufacturing, a preform glass composition lens of a graded-index rod lens that does not include PbO, in which the composition substantially does not include PbO, and expressed in mol % includes SiO2: 45 to 65, Na2O: 3 to 30, K2O: 0 to 10, MgO: 0 to 15, BaO: 0 to 20, where Na2O+K2O: 3 to 35 and MgO+BaO: 0 to 25, and furthermore includes B2O3: 0 to 15, ZnO: 0 to 10, TiO2: 0 to 10, Y2O3: 0 to 7, ZrO2: 0 to 7, Nb2O5: 0 to 7, In2O3: 0 to 7, La2O3: 0 to 7, Ta2O5: 0 to 10, where B2O3+ZnO+TiO2+Y2O3+ZrO2+Nb2O5+In2O3+La2O3+Ta2O5: 0 to 20, and a content of at least one of TiO2 and La2O3 is substantially 0 mol %.
    Type: Application
    Filed: September 3, 2003
    Publication date: April 22, 2004
    Applicant: NIPPON SHEET GLASS CO., LTD.
    Inventors: Teruhide Inoue, Kunihiro Nomiyama, Yoshikazu Toshikiyo, Yukihito Nagashima
  • Publication number: 20040067835
    Abstract: A laminated glass having a low haze ratio and an excellent infrared rays shield performance and a glass composition suitable for use in a laminated glass and easy with respect to melting and molding works, which is a glass composition comprising 65 to 74% of SiO2, 0 to 5% of B2O3, 1.9 to 2.5% of Al2O3, 1.0 to 3.0% of MgO, 5 to 10% of CaO, 0 to 10% of SrO, 0 to 10% of BaO, 0 to 5% of Li2O, 13 to 17% of Na2O, 0.5 to 5% of K2O, 0 to 0.40% of TiO2 and 0.3 to 2.0% of total iron oxide in terms of Fe2O3, on a weight basis, in which the sum of MgO, CaO, SrO and BaO is from 10 to 15% and the sum of Li2O, Na2O and K2O is from 14 to 20%, wherein the glass composition has a visible light transmittance of 80% or more as measured with the CIE Standard illuminant A and a total solar energy transmittance of not more than 62% at a thickness of 2.1 mm, and a laminated glass using a glass sheet made of that glass composition.
    Type: Application
    Filed: September 24, 2003
    Publication date: April 8, 2004
    Applicant: NIPPON SHEET GLASS CO., LTD.
    Inventors: Hiromitsu Seto, Nobuyuki Yamamoto, Hiroyuki Tanaka
  • Publication number: 20040067836
    Abstract: The present invention is a green soda-lime-silica glass composition. The composition comprises 68 to 75% SiO2, 10 to 18% Na2O, 5 to 15% CaO, 0 to 10% MgO, 0 to 5% Al2O3, and 0 to 5% K20, where CaO+MgO is 6 to 15% and Na2O+K20 is 10 to 20%, and colorants comprising: 0.3 to 0.8 wt. % total iron as Fe2O3 wherein the ratio of FeO/total Fe as Fe2O3 is 0.35 to 0.62; 0.05 to 0.5 wt. % manganese compound as MnO2; 0 to 0.1 wt. % titanium oxide as TiO2; and 0 to 1 wt. % cerium oxide as CeO2. The colored glass has the following spectral properties at 4.0 mm. thickness: 65 to 81% light transmittance using Illuminant A (LTA) and using Illuminant C has a dominant wavelength of 494 to 555 nanometers with an excitation purity of 2 to 9%.
    Type: Application
    Filed: October 4, 2002
    Publication date: April 8, 2004
    Inventors: Edward Nashed Boulos, James Victor Jones
  • Patent number: 6716779
    Abstract: A silicate based composition for optical glass used as a substrate for thin film optical interference filters having a stable transmission band center wavelength and bandwidth has a relatively high coefficient of thermal expansion, high Young's modulus and high optical transmittance in the near infrared (NIR) wavelength range of about 950 nm to about 1600 nm. The coefficient of thermal expansion of the glass composition is adjustable to particular values to result in minimal wavelength shift in filters made by depositing thin films of particular dielectric materials onto a substrate made of the glass, the composition being varied from a preferred baseline composition consisting of about 43.2% SiO2, 7% Al2O3, 12.7% CaO, 7.3% SrO, 7.8% Li2O, 13.2% Na2O, 8.0% K2O, 0.7% ZrO, and 0.1% Sb2O3, the baseline composition having a coefficient of thermal expansion of about 112×10−7/° C. over the temperature range of −30° C. to +70° C., a Young's modulus E of 88.
    Type: Grant
    Filed: August 14, 2001
    Date of Patent: April 6, 2004
    Assignees: OptoElectronics International, Inc.
    Inventor: Jacob W. Lin
  • Patent number: 6716780
    Abstract: A glass composition including from 0.10 to 2.0% yttrium oxide (e.g., Y2O3) and employing in its colorant portion iron (total iron expressed as Fe2O3), erbium (e.g., Er2O3), and/or holmium (e.g., Ho2O3). In certain embodiments, the glass may be grey in color.
    Type: Grant
    Filed: September 26, 2001
    Date of Patent: April 6, 2004
    Assignee: Guardian Industries Corp.
    Inventors: Ksenia A. Landa, Leonid Landa, Anthony V. Longobardo, Scott V. Thomsen, David R. Hall, Jr.
  • Publication number: 20040063564
    Abstract: A glass substrate for use as the substrate of an information recording medium such as a magnetic disk, magneto-optical disk, DVD, or MD or of an optical communication device, and a glass composition for making such a glass substrate, contains the following glass ingredients: 45 to 75% by weight of SiO2; 1 to 20% by weight of Al2O3; 0 to 15% by weight, zero inclusive, of B2O3; SiO2+Al2O3+B2O3 accounting for 65 to 90% by weight; a total of 7 to 20% by weight of R2O compounds, where R=Li, Na, and K; and a total of 0 to 12% by weight, zero inclusive, of R′O compounds, where R′=Mg, Ca, Sr, Ba, and Zn. Moreover, the following conditions are fulfilled: B2O3=0% by weight, or Al2O3/B2O3≧1.0; and (SiO2+Al2O3+B2O3)/(the total of R2O compounds+the total of R2O compounds)≧3.
    Type: Application
    Filed: June 13, 2003
    Publication date: April 1, 2004
    Applicant: MINOLTA CO., LTD.
    Inventors: Hideki Kawai, Toshiharu Mori
  • Publication number: 20040053768
    Abstract: An optical fiber has a fiber core with a higher refractive index and a cladding surrounding the core with a lower refractive index. The fiber core is made of a multi-component oxide glass composition which consists of a glass-forming component and two Raman-active components. The glass former is SiO2 and the Raman active components are of Li2O and Nb2O5. The concentration of the glass former is between 30 and 90 mol % and of the Raman active components is up to 50 mol % in total. The composition may further include a glass-modifying component of alkaline such as Li2O, Na2O, K2O, Rb2O, Cs2O or earth-alkaline such as BeO, MgO, CaO, SrO, BaO in a concentration of up to 40 mol %.
    Type: Application
    Filed: July 11, 2003
    Publication date: March 18, 2004
    Applicant: ALCATEL
    Inventors: Ekaterina Bourova, Stephanie Blanchandin, Jerome Garapon
  • Publication number: 20040043886
    Abstract: A light blue flat glass which is soda-lime-silica glass and which contains Nd in such an amount that the content based on Nd2O3 represented by mass percentage, is from 0.001 to 0.1%, and no Co or Co in such an amount that the content based on CoO as represented by mass percentage, is less than 0.1 ppm.
    Type: Application
    Filed: September 3, 2003
    Publication date: March 4, 2004
    Applicant: ASAHI GLASS COMPANY LIMITED
    Inventors: Shuichi Akada, Masato Ooe
  • Patent number: 6680266
    Abstract: The invention relates to low-alkali or alkali-free alkaline-earth aluminoborosilicate glasses of the following composition (in wt.-% on an oxide basis) SiO2>49-65; B2O3 0.5-4.5; Al2O3>10-23; MgO>2.7-7; CaO 0.5-10; SrO>15-22; BaO 0.5-7; provided that MgO+CaO+SrO+BaO>20-35; SnO2 0-2; ZrO2 0-2; ZrO2 0-2; TiO20-2; CeO20-1.5; ZnO 0-1; Na2O 0-2; K2O 0-2; provided that Na2O+K2O equals 0-3. The inventive glasses are especially suitable for use as substrates in thin film photovoltaic technology and as glasses for bulbs.
    Type: Grant
    Filed: June 14, 2002
    Date of Patent: January 20, 2004
    Assignee: Schott Glas
    Inventors: Ulrich Peuchert, Peter Brix, Andreas Hübner
  • Patent number: 6677260
    Abstract: The present invention is directed at a family of glasses capable of absorbing UV radiation and filtering yellow light in the visible region of the spectrum, the family of glasses having a composition consisting essentially, in terms of weight percent on the oxide basis, of: 55-95.7% SiO2, 0-28% B2O3, 0.5-18% Al2O3, 0-4% SrO, 0-13% BaO, 0-13% CaO, 0-8% MgO, 0-7.5% Na2O, 0-9.5% K2O, 0-1.5% Li2O, 0-1.5% Sb2O3, 0.4-4.5% Nd2O3, and 0.1-1% CeO2. Glasses of the present invention are capable of employment as envelopes for tungsten-halogen lamps and other high temperature light sources, as well as sealed-beam incandescent headlights. Also, the glasses can be used as for other applications where high contrast and enhanced visible properties of transmitted or reflected visible light can be a benefit, such as opthalmic glass, computer screens with enhanced contrast properties, or glass hosts for lasers.
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: January 13, 2004
    Assignee: Corning Incorporated
    Inventors: Richard H. Crane, Laura O. De Angelis, William L. Haynes, Ronald L. Stewart
  • Patent number: 6667257
    Abstract: A modified silica glass composition for providing a reduction in the multiphonon quenching for a rare-earth dopant comprising: SiO2 in a host material; a rare-earth dopant; a first SiO2 modifier; and a second SiO2 modifier; such that said first modifier and said second modifier reduce multiphonon quenching of the rare-earth dopant contained therein.
    Type: Grant
    Filed: October 2, 2001
    Date of Patent: December 23, 2003
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Brian J. Cole, Michael L. Dennis
  • Patent number: 6660073
    Abstract: A porcelain composition for dental restorations comprising a leucite crystallite phase and a glass matrix phase, wherein the leucite crystallites possess diameters not exceeding about 10 micron. Preferably, the porcelain composition has a maturing temperature from about 750° to about 1050° C. and a coefficient of thermal expansion from about 12×10−6/° C. to about 17.5×10−6/° C., and comprises: Component Amount (wt. %) SiO2 57-66 Al2O3  7-15 K2O  7-15 Na2O  7-12 Li2O 0.5-3.
    Type: Grant
    Filed: August 8, 2000
    Date of Patent: December 9, 2003
    Assignee: Jeneric/Pentron Incorporated
    Inventors: Carlino Panzera, Lisa M. Kaiser
  • Publication number: 20030216241
    Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments of making glass according to examples of the invention, the glass batch may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: 1 total iron (expressed as Fe2O3):  0.01 to 0.30% erbium oxide (e.g., Er2O3):  0.01 to 0.30% cerium oxide (e.g., CeO2): 0.005 to 0.30%.
    Type: Application
    Filed: June 10, 2003
    Publication date: November 20, 2003
    Applicant: Guardian Industries Corp.
    Inventors: Leonid Landa, Ksenia A. Landa, Scott V. Thomsen, Richard Hulme
  • Publication number: 20030207746
    Abstract: The present invention is a thulium doped silicate glass having an excellent fluorescent emission in the 1.4 &mgr;m band, and the usage thereof. The silicate glass of this invention includes: 65˜95 mol % SiO2; 0.5˜30 mol % bivalent metal oxide consisting of one or more material selected from ZnO, BaO, SrO and PbO; and 1˜15 mol % of SnO2 or TiO2, wherein 3˜30 mol % oxygen of the glass composition are replaced with fluorine, and 0.01˜1 mol % of thulium ions are doped, and the fluorescence lifetime of the 3H4 level of the Tm3+ is more than 50 &mgr;s. The silicate glass can be easily formed into a waveguide, such as optical fiber, and it has an excellent ability to splice with the optical fiber for transmission. They have excellent chemical durability and the characteristic of 1.4 &mgr;m band fluorescent emission by suppressing the non-radiative transition through multi-phonon relaxation. Thus they have long fluorescence lifetime of the 3H4 of Tm3+.
    Type: Application
    Filed: December 31, 2002
    Publication date: November 6, 2003
    Inventors: Doo Hee Cho, Yong Gyu Choi, Hong Seok Seo, Bong Je Park
  • Patent number: 6642163
    Abstract: A CRT funnel of a non beam-index type is made of a lead glass which contains 10-30 mass % of PbO and has an X-ray absorption coefficient of 40 cm−1 or more at 0.6 Å. The lead glass further contains Sb2O3 and an additive including at least one of CeO2 and SnO2. In case where the additive includes CeO2, it is preferable that the content of CeO2 is not smaller than 0.01 mass % and is smaller than 0.5 mass %. In case where the additive includes SnO2, the content of SnO2 preferably falls within a range of 0.001-2 mass %.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: November 4, 2003
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Hiroshi Komori, Hiroki Yamazaki
  • Patent number: 6626986
    Abstract: Potassium-zinc-silicate glasses are described which because of their high chemical stability as well as their optical properties and favorable working properties are suitable in particular as coating or veneering materials for ceramic dental suprastructures and thus for the preparation of all-ceramic dental restorations, such as crowns or bridges.
    Type: Grant
    Filed: June 22, 2001
    Date of Patent: September 30, 2003
    Assignee: Ivoclar Vivadent AG
    Inventors: Marcel Schweiger, Volker Rheinberger, Wolfram Höland
  • Publication number: 20030181309
    Abstract: An alkaline-earth aluminosilicate glass having a composition (in % by weight, based on oxide) of SiO2>55 - 64; Al2O3 13 - 18; B2O3 0 - 5.5; M5O 0 - 7; CaO 5.5 - 14; SrO 0 - 8; BaO 6 - 17; ZrO2 0 - 2; CeO2 0 - 0.3; TiO2 0 - 0.5; CoO 0.01 - 0.035; Fe2O3 0.005 - 0.05; and NiO 0 - 0.
    Type: Application
    Filed: February 3, 2003
    Publication date: September 25, 2003
    Applicant: SCHOTT GLAS
    Inventors: Christian Kunert, Karin Naumann, Franz Ott, Ottmar Becker
  • Publication number: 20030181308
    Abstract: A phosphor layer 12 is composed of tri-band phosphor particles 12a bound together by a binder 12a. A material as the main component of the binder 12b is a mixture of (1) a compound formed by calcium oxide, barium oxide, and boron oxide, and (2) calcium pyrophosphate. Dissolved in the main component material of the binder 12a is a luminescent component that converts ultraviolet radiation of 254 nm to ultraviolet radiation of longer wavelengths or to visible light. Examples of such a luminescent component include an oxide of gadolinium (Gd), terbium (Tb), europium (Eu), neodymium (Nd), or dysprosium (Dy), each of which belongs to lanthanum series, and an oxide of thallium (Tl), tin (Sn), lead (Pb), or bismuth (Bi), each of which belongs to 3B, 4B, or 5B group.
    Type: Application
    Filed: March 13, 2003
    Publication date: September 25, 2003
    Inventors: Tomoko Atagi, Masanobu Ito
  • Publication number: 20030176269
    Abstract: Highly durable silica glass comprising silica having incorporated therein aluminum and at least one element (M) selected from group 2A elements, group 3A elements and group 4A elements of the periodic table. Preferably, the sum of aluminum and element (M) is at least 30 atomic % based on the amount of total metal elements in the silica glass, and the atomic ratio of aluminum to element (M) is in the range of 0.05 to 20.
    Type: Application
    Filed: March 10, 2003
    Publication date: September 18, 2003
    Applicant: TOSOH CORPORATION
    Inventors: Kazuyoshi Arai, Tsutomu Takahata, Shinkichi Hashimoto, Hideaki Kiriya, Yoshinori Harada
  • Publication number: 20030175142
    Abstract: A target material for deposition of rare-earth doped optical materials is described. The rare-earth ions, for example erbium and ytterbium, is prealloyed with host materials. In some embodiments a ceramic target material can be formed by pre-alloying Er2O3 and/or Yb2O3 with Al2O3 and/or SiO2. In some embodiments, a metal target material can be formed by pre-alloying Er and/or Yb with Al and/or Si. In some embodiments, ceramic or metallic tiles are formed which can be mounted on a backing plate. In some embodiments, an intermetallic mixture can be formed and flame sprayed onto the backing plate.
    Type: Application
    Filed: March 16, 2002
    Publication date: September 18, 2003
    Inventors: Vassiliki Milonopoulou, Richard E. Demerary, Ravi B. Mullapudi
  • Patent number: 6620748
    Abstract: An optical amplifying glass comprising a matrix glass and, added thereto, from 0.01 to 10 wt % of Er, characterized in that said matrix glass substantially comprises, as represented by mol %, 20 to 80 of Bi2O3, 0 to 74.89 of B2O3, 0 to 79.99 of SiO2, 0.01 to 10 of CeO2, 0 to 50 of Li2O, 0 to 50 of TiO2, 0 to 50 of ZrO2, 0 to 50 of SnO2, 0 to 30 of WO3, 0 to 30 of TeO2, 0 to 30 of Ga2O3 and 0 to 10 of Al2O3, with the proviso that said matrix glass contains at least one of B2O3 and SiO2.
    Type: Grant
    Filed: April 20, 2001
    Date of Patent: September 16, 2003
    Inventors: Naoki Sugimoto, Yutaka Kuroiwa, Setsuro Ito, Setsuhisa Tanabe, Teiichi Hanada
  • Patent number: 6617789
    Abstract: A glass for covering electrodes, which consists, as represented by mass percentage based on the following oxides, essentially of: Mass percentage PbO 44 to 68% Bi2O3 0 to 18%, B2O3 19 to 23%, SiO2 1.2 to 5%, Al2O3 2 to 6%, ZnO 4 to 9%, CuO 0.1 to 0.5%, In2O3 1.1 to 2%, SnO2 0 to 1%, and CeO2 0 to 1%.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: September 9, 2003
    Assignees: Asahi Glass Company, Limited, Fujitsu Hitachi Plasma Display Limited
    Inventors: Hitoshi Onoda, Yumiko Aoki, Tsuneo Manabe, Satoshi Fujimine, Michifumi Kawai, Shoichi Iwanaga