And Yttrium Or Rare Earth (i.e., Elements With Atomic Numbers 39 Or 57-71) Patents (Class 501/64)
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Publication number: 20040254057Abstract: The invention relates to bismuth oxide glass, containing germanium oxide, a method for the production thereof, the use thereof and a glass fiber consisting of said inventive glass.Type: ApplicationFiled: March 8, 2004Publication date: December 16, 2004Inventors: Bianca Schreder, Rudiger Sprengard, Ulrich Peuchert, Martin Letz, Joseph s Hayden, Sally Pucilowski
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Patent number: 6831791Abstract: An optical system for optical communications is composed of a transparent material having a refractive index distribution formed by changing the molar ratio of metal oxide with valence of 2 or more. The metal oxide with valence of 2 or more includes, for example, Fe2O3. Using such an optical system for optical communications, optical communication components such as an optical fiber collimator and an optical isolator are composed.Type: GrantFiled: December 29, 2003Date of Patent: December 14, 2004Assignee: Olympus CorporationInventors: Mitsuru Namiki, Hirofumi Tsuchida
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Patent number: 6831030Abstract: A high transmittance glass sheet is provided that is formed of a soda-lime-silica glass composition containing, expressed in wt. %, less than 0.020% of total iron oxide in terms of Fe2O3 and 0.006 to 2.0% of zinc oxide. The glass sheet allows the formation of nickel sulfide particles to be suppressed by the addition of a zinc compound to a glass raw material.Type: GrantFiled: September 5, 2002Date of Patent: December 14, 2004Assignee: Nippon Sheet Glass Company, Ltd.Inventors: Akihiro Koyama, Isamu Kuroda, Nobuyuki Yamamoto, Yasunori Seto
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Publication number: 20040242396Abstract: A matrix glass for a cathode ray tube panel having excellent melt shapability and properties necessary for a cathode ray tube panel and a panel for a cathode ray tube are provided. The matrix glass is for use as a cathode ray tube panel glass after chemical strengthening, comprises, by mol %, 45 to 70% of SiO2, 0.1 to 20% of Al203, 7 to 20% of Li2O, 0.1 to 20% of Na2O, 1 to 13% of SrO, 0.1 to 3% of TiO2, 0.1 to 10% of ZrO2 and 0.01 to 1% of CeO2, and (1) exhibits a temperature of 980° C. or lower at a viscosity of 103 Pa·s or (2) contains none of MgO and CaO. The panel for a cathode ray tube is obtained by chemical strengthening of a shaped product formed of the above matrix glass.Type: ApplicationFiled: January 24, 2003Publication date: December 2, 2004Inventor: Yoichi Hachitani
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Publication number: 20040242397Abstract: An optical glass that has a refractive index (nd) of 1.56-1.66, an Abbe number (vd) of 52-63, and a transformation temperature of 420° C.-580° C., as provided by compositions including as essential components (a) SiO2, (b) B2O3, (c) BaO, (d) Y2O3, (e) Li2O, and (f) one or more from CaO, MgO, SrO, and ZnO, and optionally one or more components from (g) Na2O, (h) K2O, (i) Al2O3, and (j) ZrO2.Type: ApplicationFiled: May 21, 2004Publication date: December 2, 2004Applicant: HIKARI GLASS CO., LTD.Inventor: Yoshiyuki Nakayama
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Patent number: 6825142Abstract: The present invention generally relates to an interference filter including a glass substrate, useful in fiber optic systems.Type: GrantFiled: January 7, 2002Date of Patent: November 30, 2004Assignee: Schott Glass Technologies, Inc.Inventors: Sally Pucilowski, David G. Krashkevich
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Publication number: 20040235636Abstract: Compositions for producing a glass substrate comprise SiO2 with a weight percentage (wt %) from 55% to 70%, Al2O3 from 10 wt % to 18 wt %, B2O3 from 10 wt % to 15 wt %, CaO from 0 wt % to 10 wt %, SrO from 0 wt % to 4 wt %, and a particular composition for forming a network structure of SiO2 from 0.01 wt % to 10 wt %, in which the particular composition can be selected from a group consisting of Y2O3 and La2O3.Type: ApplicationFiled: December 29, 2003Publication date: November 25, 2004Applicant: Picvue Optoelectronics International, Inc.Inventors: Hsien-Yin Tsai, Chien-Sheng Yeh
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Patent number: 6821628Abstract: The cooking panel is made from an opaque glass-ceramic material uniformly colored throughout and having keatite mixed crystals as the predominant crystalline phase. The cooking panel is made by ceramicizing a ceramicizable glass or a transparent glass-ceramic with high quartz mixed crystals as the predominant crystalline phase in a definite color location range with a brightness parameter value (L*) less than 85 and a color shade and chromaticity according to its later service and wear pattern. The cooking panel makes deposited material, such as dirt and the like, less conspicuous.Type: GrantFiled: December 9, 1999Date of Patent: November 23, 2004Assignee: Schott GlasInventors: Bernd Schultheis, Waldemar Weinberg, Monica Cotlear De Witzmann, Roland Dudek, Friedrich Siebers, Klaus Schoenberger
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Publication number: 20040229743Abstract: A short optical glass is disclosed which is particularly suited for the applications imaging, projection, telecommunication, optical information technology and/or laser technology, also particularly suited for fiber applications (light guides or imaging guides). Preferably, the glass has a refractive index of 1.54≦nd≦1.62 and an Abbe coefficient of 48≦vd=57. It further has good attenuating and ion exchange characteristics, good chemical stability and good crystallization stability. The glass comprises 35 to 50 wt.-% SiO2, 0.1 to 6 wt.-% B2O3, 0.1 to 7 wt.-% Al2O3, 0.1 to 4 wt.-% P2O5, 4 to 24 wt.-% R2O (alkali oxides), 6 to 14.5 wt.-% BaO, 0 to 12 wt.-% other RO (alkaline earth oxides), 14 to 25 wt.-% ZnO, 0 to 5 wt.-% La2O3, 0 to 10 wt.-% ZrO2, wherein R2O is an alkali oxide, RO is an alkaline earth oxide other than BaO, wherein Li2O is 6 wt.Type: ApplicationFiled: February 27, 2004Publication date: November 18, 2004Inventors: Silke Wolff, Ute Woelfel, Uwe Kolberg, Holger Kasprzik
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Publication number: 20040229744Abstract: A method is provided for making clear glass having an azure edge coloration and low amber surface coloration in a non-vacuum float glass system. The method includes processing batch materials in a non-vacuum float glass system to provide a final glass product including: 1 SiO2 65-75 wt. %; Na2O 10-20 wt. %; CaO 5-15 wt. %; MgO 0-5 wt. %; Al2O3 0-5 wt. %; K2O 0-5 wt.Type: ApplicationFiled: May 14, 2003Publication date: November 18, 2004Inventor: Robert B. Heithoff
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Patent number: 6815385Abstract: A tungsten sealing glass for use in a fluorescent lamp, said glass having a composition of, by mass percent, 65-76% SiO2, 10-25% B2O3, 2-6% Al2O3, 0.5-5.8% MgO+CaO+SrO+BaO+ZnO, 3-8% Li2O+Na2O+K2O, 0.01-4% Fe2O3+CeO2, 0.1-5% TiO2, 0.1-10% TiO2+Sb2O3+PbO, and 0-2% ZrO2, wherein Na2O/(Na2O+K2O)≦0.6.Type: GrantFiled: July 15, 2003Date of Patent: November 9, 2004Assignee: Nippon Electric Glass Co., Ltd.Inventors: Hiroyuki Kosokabe, Koichi Hashimoto
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Publication number: 20040220038Abstract: A short optical glass is disclosed which does not comprise any silver, copper, thallium, lead or boron and is particularly suited for the application imaging, projection, telecommunication, optical information technology, and/or laser technology, also particularly suited for fiber applications (light guides or imaging guides). Preferably the glass has a refractive index of 1.55≦nd≦1.65 and an Abbe coefficient of 48≦vd≦57 and also has good attenuating and ion exchange characteristics, good chemical stability and good crystallization stability. The glass comprises 35 to <50 wt.-% SiO2; 1 to 10 wt.-% Al2O3; 5 to 15 wt.-% Na2O+K2O+CS2O+Li2O; 20 to 30 wt.-% BaO; 0 to 15 wt.-% ZnO; 0 to 10 wt.-% La2O3; 0 to 10 wt.-% ZrO2; 0 to 6 wt.-% P2O5; 0 to 8 wt.-% MgO+CaO+SrO; 0 to 3 wt.-% of other oxides, and Cs2O<1, Li2O<1, and TiO2<1 wt.-%.Type: ApplicationFiled: February 24, 2004Publication date: November 4, 2004Inventors: Silke Wolff, Ute Woelfel, Uwe Kolberg, Holger Kasprzik
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Publication number: 20040209757Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: 1 total iron (expressed as Fe2O3): 0.01 to 0.30% erbium oxide (e.g., Er2O3): 0.01 to 0.30%.Type: ApplicationFiled: February 25, 2004Publication date: October 21, 2004Applicant: Guardian Industries Corp.Inventors: Leonid Landa, Ksenia A. Landa, Scott V. Thomsen, Richard Hulme
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Patent number: 6806216Abstract: Zinc-containing optical glass materials with a refractive index nd between 1.52 and 1.66, an Abbe number vd of between 35 and 54 and a composition (in % by weight based on oxide) of: SiO2 38-58, ZnO 0.3-42, PbO 0-<30, ZnO+PbO 20-55, Li2O 0-<3, Na2O 0-14, K2O 0-12, Li2O+Na2O+K2O≧2, F 0-3, MgO 0-6, CaO 0-<5, SrO 0-6, BaO 0-<0.9, B2O3 0-<1, Al2O3 0-<1.5 and ZrO2 0-<2 and, if appropriate, refining agents in the customary amounts.Type: GrantFiled: December 1, 2000Date of Patent: October 19, 2004Assignee: Schott GlasInventors: Ina Mitra, Danuta Grabowski, Uwe Kolberg, Paul Kissl
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Patent number: 6800574Abstract: In one aspect, the invention provides glass beads and optical devices comprising the glass beads. In other aspects, the invention provides methods of making said glass beads and rapid glass screening methods that use glass beads. Glass beads of the invention comprise greater than 80 weight percent silica, active rare earth dopant, and modifying dopant. In another embodiment the glass beads comprise greater than 80 weight percent silica and at least 5 weight percent germania. In another embodiment, glass beads comprise and from about 20 to about 90 anion mole percent of non-oxide anion.Type: GrantFiled: October 24, 2001Date of Patent: October 5, 2004Assignee: 3M Innovative Properties CompanyInventor: Mark T. Anderson
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Publication number: 20040180775Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments of making glass according to examples of the invention, the glass batch may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: 1 total iron (expressed as Fe2O3): 0.01 to 0.30% erbium oxide (e.g., Er2O3): 0.01 to 0.30% cerium oxide (e.g., CeO2): 0.005 to 0.30%.Type: ApplicationFiled: March 29, 2004Publication date: September 16, 2004Applicant: Guardian Industries Corp.Inventors: Leonid Landa, Ksenia A. Landa, Scott V. Thomsen, Richard Hulme
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Patent number: 6790799Abstract: A glass panel for a color cathode ray tube, which has a linear absorption coefficient of X-ray with a wavelength of 0.06 nm of from 30 to 38 cm−1 and which has a layer having a compression stress of at least 70 MPa formed by a chemical strengthening method at least at short axis end portions and/or long axis end portions of the outer surface of a face portion and at a center portion of the inner surface of the face portion.Type: GrantFiled: May 7, 2002Date of Patent: September 14, 2004Assignee: Asahi Glass Company, LimitedInventors: Yuichi Kuroki, Tsunehiko Sugawara
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Patent number: 6784129Abstract: The ultraviolet/infrared absorbent low transmittance glass has a grayish green color shade, low visible light transmittance, low total solar energy transmittance, and low ultraviolet transmittance, and is suitable for a rear window of a vehicle and capable of protecting privacy. The glass is formed of a base glass including: 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO, wherein a total amount of MgO and CaO is between 5 and 15 wt. %; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O, wherein a total amount of Na2O and K2O is between 10 and 20 wt. %; and 0 to 5 wt. % B2O3, and colorants including: more than 0.95 wt. % and less than 1.2 wt. % total iron oxide (T-Fe2O3) expressed as Fe2O3; 0.001 to 0.0180 wt. % CoO; and 0.003 to 0.2 wt. % NiO.Type: GrantFiled: October 3, 2002Date of Patent: August 31, 2004Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Hiromitsu Seto, Yukihito Nagashima, Shigekazu Yoshii
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Patent number: 6780801Abstract: The present invention provides a raw material composition for soda-lime glass capable of effectively suppressing formation of nickel sulfide (NiS) in the course of melting of the glass raw material. A nickel sulfide (NiS) impurity present in soda-lime glass is formed in a high-temperature vitrification step in which metal particles containing Ni and an Ni component of stainless steel used for the interior of a melting furnace, which are mixed into glass raw material, react at high temperature with a sulfur (S) component in Na2SO4 serving as a glass raw material. However, when an additive containing an oxide, a chloride, a sulfate, or a nitrate of a metal is added in a very small amount and in advance to glass raw material, formation of NiS by the reaction between Ni and S in the course of melting can be suppressed or completely eliminated.Type: GrantFiled: March 6, 2000Date of Patent: August 24, 2004Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Chihiro Sakai, Yoshikazu Toshikiyo
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Publication number: 20040157721Abstract: The invention relates to a coloured soda-lime glass of blue hue, containing more than 2 wt. % of MgO, more than 1.1 wt. % of Fe2O3, less than 0.53 wt. % of FeO and less than 0.13 wt. % of MnO2, and presenting under Illuminant A and for a glass thickness of 4 mm, a transmission factor (TLA4) higher than 15%, a selectivity (SE4) higher than 1.2 and a dominant wavelength (&lgr;D) and a purity of excitation (P) such that they are located in the CIE chromaticity co-ordinate diagram inside a triangle whereof the apices are defined by the point representing the illuminant source C and the points whereof the co-ordinates (&lgr;D, P) are (490,19) and (476,49) respectively. Said glass is particularly suitable for motor vehicle side windows, rear windows and sun roof.Type: ApplicationFiled: February 5, 2004Publication date: August 12, 2004Inventors: Marc Foguenne, Dominique Coster
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Publication number: 20040157723Abstract: The invention concerns a soda-lime glass. Said coloured glass contains at least 5 parts per million of Co by weight and 0.5 to 0.9 wt. % Fe2O3 oxide. The amount of ferrous iron by weight of Fe2+ atoms relative to the total weight of iron atoms present in the glass ranges between 25 and 45%. Said glass further comprises chromium and/or vanadium. The glass has a light transmission factor TLA4 ranging between 10 and 50% and an energy transmission wavelength less than 491 nm. Said glass is particularly suited for producing blue-tinted glazing for motor vehicles.Type: ApplicationFiled: December 19, 2002Publication date: August 12, 2004Inventors: Marc Foguenne, Dominique Coster, Laurent Delmotte
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Patent number: 6773816Abstract: The invention relates to driving glasses in which a thermic ray reflection layer 2 made of a metal or an organic substance is provided on the outer surface of a glass matrix 1, and an anti-reflection layer 3 is provided on the inner surface thereof, werein the glass matrix 1 contains neodymium oxide Nd2O3 of 1 through 12% by weight and praseodymium oxide Pr6O11 of 0.5 through 8% by weight, and forms an absorption peak of light transmittance at a wavelength of 510 through 540 nm and a wavelength of 570 through 590 nm.Type: GrantFiled: December 31, 2002Date of Patent: August 10, 2004Assignees: O.M.G. Kabushiki Kaisha, Inui Lens Co., Ltd.Inventor: Takashi Tsutsumi
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Publication number: 20040152580Abstract: Glass, glass compositions, methods of preparing the glass compositions, microfluidic devices that include the glass composition, and methods of fabricating microfluidic devices that include the glass composition are disclosed. The borosilicate glass composition includes silicon dioxide (SiO2) in a range from about 60% to 74% by total composition weight; boric oxide (B2O3) in a range from about 9% to 25% by total composition weight; aluminum oxide (Al2O3) in a range from about 7% to 17% by total composition weight; and at least one alkali oxide in a range from about 2% to 7% by total composition weight. In addition, the borosilicate glass has a coefficient of thermal expansion (CTE) that is in a range between about 30×10−7/° C. and 55×10−7/° C. Furthermore, the borosilicate glass composition resists devitrification upon sintering without the addition of an inhibitor oxide.Type: ApplicationFiled: December 2, 2003Publication date: August 5, 2004Inventor: Paulo Marques
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Publication number: 20040145297Abstract: Glass comprises essentially 20-70% SiO2, 10-50% TiO2+Nb2O5+SnO2+Ta2O5+WO3+CeO2, 0-50% MgO+CaO+SrO+BaO+ZnO, and 0-30% B2O3+Al2O3, in molar percentage terms based on the oxides; and has a resistivity of at most 1015 &OHgr;·cm at 20° C. A method for production of glass is to produce the glass under such a condition that a redox represented by [Fe2+]/([Fe2+]+[Fe3+]) where Fe is present in the glass, is at least 0.6.Type: ApplicationFiled: January 14, 2004Publication date: July 29, 2004Applicant: ASAHI GLASS COMPANY LIMITEDInventors: Tetsuya Nakashima, Kei Maeda
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Publication number: 20040142810Abstract: The invention relates to a glass having the composition (in % by weight, based on oxide) SiO2 about 78.5—about 79.5, B2O3 about 13.0—about 14.0, Al2O3 about 2.0—about 3.0, Na2O about 4.5—about 5.5, K2O 0—about 0.6, which may be used in the production of thermal shock-resistant beverage containers, particularly teapots, coffee machine jugs and baby-milk bottles.Type: ApplicationFiled: November 17, 2003Publication date: July 22, 2004Inventors: Christian Kunert, Johannes Roettgers, Roland Leroux, Peter Brix
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Patent number: 6764972Abstract: A compositional range for a mother glass composition for graded index lenses which has a desired refractive index and is less apt to be devitrified and to develop cracks upon ion exchange was obtained by incorporating at least a given amount of one or more ingredients which are selected from oxides of metal elements ranging from yttrium, atomic number 39, to tantalum, atomic number 73, and which are less apt to cause glass coloration into a glass based on SiO2—TiO2—Li2O—Na2O and containing no lead oxide. In particular, a compositional range in which a large angular aperture is obtained and devitrification is less apt to occur was obtained by incorporating Ta2O5 and ZrO2 in a specific proportion and in specific amounts.Type: GrantFiled: October 11, 2001Date of Patent: July 20, 2004Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Tetsuro Yoshii, Jun Yamaguchi
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Publication number: 20040102304Abstract: The present invention is a bronze and gray glass composition. The composition comprises 68 to 75% SiO2, 10 to 18% Na2O, 5 to 15% CaO, 0 to 10% MgO, 0 to 5% Al2O3, and 0 to 5% K2O, where CaO+MgO is 6 to 15% and Na2O+K2O is 10 to 20%, and colorants comprising: 0.22 to 0.39 wt. % total iron as Fe2O3 wherein the ratio of FeO/total Fe as Fe2O3 is 0.35 to 0.64; 0.1 to 0.5 wt. % manganese compound as MnO2; 0 to 1.2 wt. % cerium oxide as CeO2; and 2 to 10 ppm selenium, and 0 to 20 ppm cobalt as cobalt oxide. The colored glass has the following spectral properties at 4.0 mm. thickness: 65 to 78% light transmittance using Illuminant A (LTA) and using Illuminant C has a dominant wavelength of 493 to 577 nanometers with an excitation purity up to 7%.Type: ApplicationFiled: November 21, 2002Publication date: May 27, 2004Inventors: Edward Nashed Boulos, James Victor Jones
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Publication number: 20040079258Abstract: The invention relates to the use of ions of weakly basic oxides as linking ions for polyacids in cements, preferably polyelectrolyte cements. Suitable ions comprise elements of the scandium series, for example, Sc3+, Y3+, La3+, Ce4+ and all subsequent tri- and tetra-valent lanthanides and the ions Mg2+, Zn2+, Ga2+, In2+. The application of said ions permits a regulation of the cement reaction without surface treatment of the glass powder.Type: ApplicationFiled: December 8, 2003Publication date: April 29, 2004Inventors: Stefan Hoescheler, Markus Mikulla, Gabriele Rackelmann, Volker Bambach
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Publication number: 20040077478Abstract: It is an object of the present invention to provide a clad glass composition for graded-index rod lens for covering, during manufacturing, a preform glass composition lens of a graded-index rod lens that does not include PbO, in which the composition substantially does not include PbO, and expressed in mol % includes SiO2: 45 to 65, Na2O: 3 to 30, K2O: 0 to 10, MgO: 0 to 15, BaO: 0 to 20, where Na2O+K2O: 3 to 35 and MgO+BaO: 0 to 25, and furthermore includes B2O3: 0 to 15, ZnO: 0 to 10, TiO2: 0 to 10, Y2O3: 0 to 7, ZrO2: 0 to 7, Nb2O5: 0 to 7, In2O3: 0 to 7, La2O3: 0 to 7, Ta2O5: 0 to 10, where B2O3+ZnO+TiO2+Y2O3+ZrO2+Nb2O5+In2O3+La2O3+Ta2O5: 0 to 20, and a content of at least one of TiO2 and La2O3 is substantially 0 mol %.Type: ApplicationFiled: September 3, 2003Publication date: April 22, 2004Applicant: NIPPON SHEET GLASS CO., LTD.Inventors: Teruhide Inoue, Kunihiro Nomiyama, Yoshikazu Toshikiyo, Yukihito Nagashima
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Publication number: 20040067835Abstract: A laminated glass having a low haze ratio and an excellent infrared rays shield performance and a glass composition suitable for use in a laminated glass and easy with respect to melting and molding works, which is a glass composition comprising 65 to 74% of SiO2, 0 to 5% of B2O3, 1.9 to 2.5% of Al2O3, 1.0 to 3.0% of MgO, 5 to 10% of CaO, 0 to 10% of SrO, 0 to 10% of BaO, 0 to 5% of Li2O, 13 to 17% of Na2O, 0.5 to 5% of K2O, 0 to 0.40% of TiO2 and 0.3 to 2.0% of total iron oxide in terms of Fe2O3, on a weight basis, in which the sum of MgO, CaO, SrO and BaO is from 10 to 15% and the sum of Li2O, Na2O and K2O is from 14 to 20%, wherein the glass composition has a visible light transmittance of 80% or more as measured with the CIE Standard illuminant A and a total solar energy transmittance of not more than 62% at a thickness of 2.1 mm, and a laminated glass using a glass sheet made of that glass composition.Type: ApplicationFiled: September 24, 2003Publication date: April 8, 2004Applicant: NIPPON SHEET GLASS CO., LTD.Inventors: Hiromitsu Seto, Nobuyuki Yamamoto, Hiroyuki Tanaka
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Publication number: 20040067836Abstract: The present invention is a green soda-lime-silica glass composition. The composition comprises 68 to 75% SiO2, 10 to 18% Na2O, 5 to 15% CaO, 0 to 10% MgO, 0 to 5% Al2O3, and 0 to 5% K20, where CaO+MgO is 6 to 15% and Na2O+K20 is 10 to 20%, and colorants comprising: 0.3 to 0.8 wt. % total iron as Fe2O3 wherein the ratio of FeO/total Fe as Fe2O3 is 0.35 to 0.62; 0.05 to 0.5 wt. % manganese compound as MnO2; 0 to 0.1 wt. % titanium oxide as TiO2; and 0 to 1 wt. % cerium oxide as CeO2. The colored glass has the following spectral properties at 4.0 mm. thickness: 65 to 81% light transmittance using Illuminant A (LTA) and using Illuminant C has a dominant wavelength of 494 to 555 nanometers with an excitation purity of 2 to 9%.Type: ApplicationFiled: October 4, 2002Publication date: April 8, 2004Inventors: Edward Nashed Boulos, James Victor Jones
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Patent number: 6716779Abstract: A silicate based composition for optical glass used as a substrate for thin film optical interference filters having a stable transmission band center wavelength and bandwidth has a relatively high coefficient of thermal expansion, high Young's modulus and high optical transmittance in the near infrared (NIR) wavelength range of about 950 nm to about 1600 nm. The coefficient of thermal expansion of the glass composition is adjustable to particular values to result in minimal wavelength shift in filters made by depositing thin films of particular dielectric materials onto a substrate made of the glass, the composition being varied from a preferred baseline composition consisting of about 43.2% SiO2, 7% Al2O3, 12.7% CaO, 7.3% SrO, 7.8% Li2O, 13.2% Na2O, 8.0% K2O, 0.7% ZrO, and 0.1% Sb2O3, the baseline composition having a coefficient of thermal expansion of about 112×10−7/° C. over the temperature range of −30° C. to +70° C., a Young's modulus E of 88.Type: GrantFiled: August 14, 2001Date of Patent: April 6, 2004Assignees: OptoElectronics International, Inc.Inventor: Jacob W. Lin
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Patent number: 6716780Abstract: A glass composition including from 0.10 to 2.0% yttrium oxide (e.g., Y2O3) and employing in its colorant portion iron (total iron expressed as Fe2O3), erbium (e.g., Er2O3), and/or holmium (e.g., Ho2O3). In certain embodiments, the glass may be grey in color.Type: GrantFiled: September 26, 2001Date of Patent: April 6, 2004Assignee: Guardian Industries Corp.Inventors: Ksenia A. Landa, Leonid Landa, Anthony V. Longobardo, Scott V. Thomsen, David R. Hall, Jr.
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Publication number: 20040063564Abstract: A glass substrate for use as the substrate of an information recording medium such as a magnetic disk, magneto-optical disk, DVD, or MD or of an optical communication device, and a glass composition for making such a glass substrate, contains the following glass ingredients: 45 to 75% by weight of SiO2; 1 to 20% by weight of Al2O3; 0 to 15% by weight, zero inclusive, of B2O3; SiO2+Al2O3+B2O3 accounting for 65 to 90% by weight; a total of 7 to 20% by weight of R2O compounds, where R=Li, Na, and K; and a total of 0 to 12% by weight, zero inclusive, of R′O compounds, where R′=Mg, Ca, Sr, Ba, and Zn. Moreover, the following conditions are fulfilled: B2O3=0% by weight, or Al2O3/B2O3≧1.0; and (SiO2+Al2O3+B2O3)/(the total of R2O compounds+the total of R2O compounds)≧3.Type: ApplicationFiled: June 13, 2003Publication date: April 1, 2004Applicant: MINOLTA CO., LTD.Inventors: Hideki Kawai, Toshiharu Mori
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Publication number: 20040053768Abstract: An optical fiber has a fiber core with a higher refractive index and a cladding surrounding the core with a lower refractive index. The fiber core is made of a multi-component oxide glass composition which consists of a glass-forming component and two Raman-active components. The glass former is SiO2 and the Raman active components are of Li2O and Nb2O5. The concentration of the glass former is between 30 and 90 mol % and of the Raman active components is up to 50 mol % in total. The composition may further include a glass-modifying component of alkaline such as Li2O, Na2O, K2O, Rb2O, Cs2O or earth-alkaline such as BeO, MgO, CaO, SrO, BaO in a concentration of up to 40 mol %.Type: ApplicationFiled: July 11, 2003Publication date: March 18, 2004Applicant: ALCATELInventors: Ekaterina Bourova, Stephanie Blanchandin, Jerome Garapon
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Publication number: 20040043886Abstract: A light blue flat glass which is soda-lime-silica glass and which contains Nd in such an amount that the content based on Nd2O3 represented by mass percentage, is from 0.001 to 0.1%, and no Co or Co in such an amount that the content based on CoO as represented by mass percentage, is less than 0.1 ppm.Type: ApplicationFiled: September 3, 2003Publication date: March 4, 2004Applicant: ASAHI GLASS COMPANY LIMITEDInventors: Shuichi Akada, Masato Ooe
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Patent number: 6680266Abstract: The invention relates to low-alkali or alkali-free alkaline-earth aluminoborosilicate glasses of the following composition (in wt.-% on an oxide basis) SiO2>49-65; B2O3 0.5-4.5; Al2O3>10-23; MgO>2.7-7; CaO 0.5-10; SrO>15-22; BaO 0.5-7; provided that MgO+CaO+SrO+BaO>20-35; SnO2 0-2; ZrO2 0-2; ZrO2 0-2; TiO20-2; CeO20-1.5; ZnO 0-1; Na2O 0-2; K2O 0-2; provided that Na2O+K2O equals 0-3. The inventive glasses are especially suitable for use as substrates in thin film photovoltaic technology and as glasses for bulbs.Type: GrantFiled: June 14, 2002Date of Patent: January 20, 2004Assignee: Schott GlasInventors: Ulrich Peuchert, Peter Brix, Andreas Hübner
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Patent number: 6677260Abstract: The present invention is directed at a family of glasses capable of absorbing UV radiation and filtering yellow light in the visible region of the spectrum, the family of glasses having a composition consisting essentially, in terms of weight percent on the oxide basis, of: 55-95.7% SiO2, 0-28% B2O3, 0.5-18% Al2O3, 0-4% SrO, 0-13% BaO, 0-13% CaO, 0-8% MgO, 0-7.5% Na2O, 0-9.5% K2O, 0-1.5% Li2O, 0-1.5% Sb2O3, 0.4-4.5% Nd2O3, and 0.1-1% CeO2. Glasses of the present invention are capable of employment as envelopes for tungsten-halogen lamps and other high temperature light sources, as well as sealed-beam incandescent headlights. Also, the glasses can be used as for other applications where high contrast and enhanced visible properties of transmitted or reflected visible light can be a benefit, such as opthalmic glass, computer screens with enhanced contrast properties, or glass hosts for lasers.Type: GrantFiled: June 21, 2001Date of Patent: January 13, 2004Assignee: Corning IncorporatedInventors: Richard H. Crane, Laura O. De Angelis, William L. Haynes, Ronald L. Stewart
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Patent number: 6667257Abstract: A modified silica glass composition for providing a reduction in the multiphonon quenching for a rare-earth dopant comprising: SiO2 in a host material; a rare-earth dopant; a first SiO2 modifier; and a second SiO2 modifier; such that said first modifier and said second modifier reduce multiphonon quenching of the rare-earth dopant contained therein.Type: GrantFiled: October 2, 2001Date of Patent: December 23, 2003Assignee: The United States of America as represented by the Secretary of the NavyInventors: Brian J. Cole, Michael L. Dennis
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Patent number: 6660073Abstract: A porcelain composition for dental restorations comprising a leucite crystallite phase and a glass matrix phase, wherein the leucite crystallites possess diameters not exceeding about 10 micron. Preferably, the porcelain composition has a maturing temperature from about 750° to about 1050° C. and a coefficient of thermal expansion from about 12×10−6/° C. to about 17.5×10−6/° C., and comprises: Component Amount (wt. %) SiO2 57-66 Al2O3 7-15 K2O 7-15 Na2O 7-12 Li2O 0.5-3.Type: GrantFiled: August 8, 2000Date of Patent: December 9, 2003Assignee: Jeneric/Pentron IncorporatedInventors: Carlino Panzera, Lisa M. Kaiser
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Publication number: 20030216241Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments of making glass according to examples of the invention, the glass batch may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: 1 total iron (expressed as Fe2O3): 0.01 to 0.30% erbium oxide (e.g., Er2O3): 0.01 to 0.30% cerium oxide (e.g., CeO2): 0.005 to 0.30%.Type: ApplicationFiled: June 10, 2003Publication date: November 20, 2003Applicant: Guardian Industries Corp.Inventors: Leonid Landa, Ksenia A. Landa, Scott V. Thomsen, Richard Hulme
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Publication number: 20030207746Abstract: The present invention is a thulium doped silicate glass having an excellent fluorescent emission in the 1.4 &mgr;m band, and the usage thereof. The silicate glass of this invention includes: 65˜95 mol % SiO2; 0.5˜30 mol % bivalent metal oxide consisting of one or more material selected from ZnO, BaO, SrO and PbO; and 1˜15 mol % of SnO2 or TiO2, wherein 3˜30 mol % oxygen of the glass composition are replaced with fluorine, and 0.01˜1 mol % of thulium ions are doped, and the fluorescence lifetime of the 3H4 level of the Tm3+ is more than 50 &mgr;s. The silicate glass can be easily formed into a waveguide, such as optical fiber, and it has an excellent ability to splice with the optical fiber for transmission. They have excellent chemical durability and the characteristic of 1.4 &mgr;m band fluorescent emission by suppressing the non-radiative transition through multi-phonon relaxation. Thus they have long fluorescence lifetime of the 3H4 of Tm3+.Type: ApplicationFiled: December 31, 2002Publication date: November 6, 2003Inventors: Doo Hee Cho, Yong Gyu Choi, Hong Seok Seo, Bong Je Park
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Patent number: 6642163Abstract: A CRT funnel of a non beam-index type is made of a lead glass which contains 10-30 mass % of PbO and has an X-ray absorption coefficient of 40 cm−1 or more at 0.6 Å. The lead glass further contains Sb2O3 and an additive including at least one of CeO2 and SnO2. In case where the additive includes CeO2, it is preferable that the content of CeO2 is not smaller than 0.01 mass % and is smaller than 0.5 mass %. In case where the additive includes SnO2, the content of SnO2 preferably falls within a range of 0.001-2 mass %.Type: GrantFiled: December 20, 2001Date of Patent: November 4, 2003Assignee: Nippon Electric Glass Co., Ltd.Inventors: Hiroshi Komori, Hiroki Yamazaki
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Patent number: 6626986Abstract: Potassium-zinc-silicate glasses are described which because of their high chemical stability as well as their optical properties and favorable working properties are suitable in particular as coating or veneering materials for ceramic dental suprastructures and thus for the preparation of all-ceramic dental restorations, such as crowns or bridges.Type: GrantFiled: June 22, 2001Date of Patent: September 30, 2003Assignee: Ivoclar Vivadent AGInventors: Marcel Schweiger, Volker Rheinberger, Wolfram Höland
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Publication number: 20030181309Abstract: An alkaline-earth aluminosilicate glass having a composition (in % by weight, based on oxide) of SiO2>55 - 64; Al2O3 13 - 18; B2O3 0 - 5.5; M5O 0 - 7; CaO 5.5 - 14; SrO 0 - 8; BaO 6 - 17; ZrO2 0 - 2; CeO2 0 - 0.3; TiO2 0 - 0.5; CoO 0.01 - 0.035; Fe2O3 0.005 - 0.05; and NiO 0 - 0.Type: ApplicationFiled: February 3, 2003Publication date: September 25, 2003Applicant: SCHOTT GLASInventors: Christian Kunert, Karin Naumann, Franz Ott, Ottmar Becker
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Publication number: 20030181308Abstract: A phosphor layer 12 is composed of tri-band phosphor particles 12a bound together by a binder 12a. A material as the main component of the binder 12b is a mixture of (1) a compound formed by calcium oxide, barium oxide, and boron oxide, and (2) calcium pyrophosphate. Dissolved in the main component material of the binder 12a is a luminescent component that converts ultraviolet radiation of 254 nm to ultraviolet radiation of longer wavelengths or to visible light. Examples of such a luminescent component include an oxide of gadolinium (Gd), terbium (Tb), europium (Eu), neodymium (Nd), or dysprosium (Dy), each of which belongs to lanthanum series, and an oxide of thallium (Tl), tin (Sn), lead (Pb), or bismuth (Bi), each of which belongs to 3B, 4B, or 5B group.Type: ApplicationFiled: March 13, 2003Publication date: September 25, 2003Inventors: Tomoko Atagi, Masanobu Ito
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Publication number: 20030176269Abstract: Highly durable silica glass comprising silica having incorporated therein aluminum and at least one element (M) selected from group 2A elements, group 3A elements and group 4A elements of the periodic table. Preferably, the sum of aluminum and element (M) is at least 30 atomic % based on the amount of total metal elements in the silica glass, and the atomic ratio of aluminum to element (M) is in the range of 0.05 to 20.Type: ApplicationFiled: March 10, 2003Publication date: September 18, 2003Applicant: TOSOH CORPORATIONInventors: Kazuyoshi Arai, Tsutomu Takahata, Shinkichi Hashimoto, Hideaki Kiriya, Yoshinori Harada
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Publication number: 20030175142Abstract: A target material for deposition of rare-earth doped optical materials is described. The rare-earth ions, for example erbium and ytterbium, is prealloyed with host materials. In some embodiments a ceramic target material can be formed by pre-alloying Er2O3 and/or Yb2O3 with Al2O3 and/or SiO2. In some embodiments, a metal target material can be formed by pre-alloying Er and/or Yb with Al and/or Si. In some embodiments, ceramic or metallic tiles are formed which can be mounted on a backing plate. In some embodiments, an intermetallic mixture can be formed and flame sprayed onto the backing plate.Type: ApplicationFiled: March 16, 2002Publication date: September 18, 2003Inventors: Vassiliki Milonopoulou, Richard E. Demerary, Ravi B. Mullapudi
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Patent number: 6620748Abstract: An optical amplifying glass comprising a matrix glass and, added thereto, from 0.01 to 10 wt % of Er, characterized in that said matrix glass substantially comprises, as represented by mol %, 20 to 80 of Bi2O3, 0 to 74.89 of B2O3, 0 to 79.99 of SiO2, 0.01 to 10 of CeO2, 0 to 50 of Li2O, 0 to 50 of TiO2, 0 to 50 of ZrO2, 0 to 50 of SnO2, 0 to 30 of WO3, 0 to 30 of TeO2, 0 to 30 of Ga2O3 and 0 to 10 of Al2O3, with the proviso that said matrix glass contains at least one of B2O3 and SiO2.Type: GrantFiled: April 20, 2001Date of Patent: September 16, 2003Inventors: Naoki Sugimoto, Yutaka Kuroiwa, Setsuro Ito, Setsuhisa Tanabe, Teiichi Hanada
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Patent number: 6617789Abstract: A glass for covering electrodes, which consists, as represented by mass percentage based on the following oxides, essentially of: Mass percentage PbO 44 to 68% Bi2O3 0 to 18%, B2O3 19 to 23%, SiO2 1.2 to 5%, Al2O3 2 to 6%, ZnO 4 to 9%, CuO 0.1 to 0.5%, In2O3 1.1 to 2%, SnO2 0 to 1%, and CeO2 0 to 1%.Type: GrantFiled: October 9, 2001Date of Patent: September 9, 2003Assignees: Asahi Glass Company, Limited, Fujitsu Hitachi Plasma Display LimitedInventors: Hitoshi Onoda, Yumiko Aoki, Tsuneo Manabe, Satoshi Fujimine, Michifumi Kawai, Shoichi Iwanaga