And Yttrium Or Rare Earth (i.e., Elements With Atomic Numbers 39 Or 57-71) Patents (Class 501/64)
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Publication number: 20100126218Abstract: A soda-lime-silica glass for solar collector cover plates and solar mirrors has less than 0.010 weight percent total iron as Fe2O3, a redox ratio of less than 0.350, less than 0.0025 weight percent CeO2, and spectral properties that include a visible transmission, and a total solar infrared transmittance, of greater than 90% at a thickness of 5.5 millimeters, and reduced solarization. In one non-limiting embodiment of invention, the glass is made by heating a pool of molten soda-lime-silica with a mixture of combustion air and fuel gas having an air firing ratio of greater than 11, or an oxygen firing ratio of greater than 2.31. In another non-limiting embodiment of the invention, streams of oxygen bubbles are moved through a pool of molten glass. In both embodiments, the oxygen oxidizes ferrous iron to ferric iron to reduce the redox ratio.Type: ApplicationFiled: November 21, 2008Publication date: May 27, 2010Applicant: PPG INDUSTRIES OHIO, INC.Inventors: Larry J. Shelestak, Ronald L. Shewenninger
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Publication number: 20100122728Abstract: A high transmission low iron glass includes antimony, has reduced total alkali content, and increased silica content, and is suitable for use in photovoltaic devices (e.g., solar cells) or the like. A method of making the glass is also provided. In certain example embodiments, the glass composition may be made on a pattern line with a highly positive batch redox.Type: ApplicationFiled: November 17, 2008Publication date: May 20, 2010Inventors: Kevin R. Fulton, Richard Hulme, Scott V. Thomsen
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Publication number: 20100108914Abstract: The borosilicate glass with improved solarization-resistance has a transmittance curve within an area bounded by respective curves defined by the corresponding equations ?=1.7·(??277) and ?=1.6·(??284) in a wavelength range of 283 nm to 325 nm. This glass has a composition, in wt. % based on oxide content, of: 55-82, SiO2; 10-20, B2O3; 1-10, Al2O3; 0-5, Li2O; 0-10, Na2O; 0-10, K2O; 0-10, ?M2O; 0-5, MgO; 0-10, CaO; 0-5, SrO; 0-15, BaO; 0-15, ?MO; 0-3, ZrO2; 0-5, ZnO; 0-2, CeO2; 0-3, WO3; 0-2, SnO2: 0-0.1, Fe2O3; 0.05-2, MoO3; 0-5, Bi2O3; 0-1, TiO2 and 0-5, oxides of selected rare earth and Group IVB to VIIIB elements. The transmittance is adjusted by varying the MoO3 content and if necessary the TiO2 and Bi2O3 content. The glass is especially suitable for use in a weathering apparatus.Type: ApplicationFiled: October 14, 2009Publication date: May 6, 2010Inventors: Joerg Hinrich Fechner, Franz Ott
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Patent number: 7710656Abstract: The transparent polycrystalline optoceramic has single crystallites and at least 95 percent by weight of the single crystallites have a cubic pyrochlore or fluorite structure. The optoceramic is composed of an oxide of stoichiometry: A2+xByDzE7 wherein 0<x<1, 0<y<2, 0<z<1.6 and 3x+4y+5z=8; wherein A is at least one trivalent rare earth cation; B is at least one tetravalent cation; D is at least one pentavalent cation; and E comprises at least one divalent anion. Refractive, diffractive or transmissive optical elements are made with these optoceramics.Type: GrantFiled: May 8, 2008Date of Patent: May 4, 2010Assignee: Schott AGInventors: Ulrich Peuchert, Yvonne Menke
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Publication number: 20100099546Abstract: The invention relates to a transparent and essentially colorless ?-quartz glass-ceramic material which is free of TiO2, As2O3, Sb2O3 and phosphates; articles formed from said glass-ceramic material; lithium aluminosilicate glasses, precursors for said glass-ceramic material; and methods of producing said glass-ceramic material and said articles formed from said glass-ceramic material.Type: ApplicationFiled: November 29, 2006Publication date: April 22, 2010Inventors: Bruce G. Aitken, Marie Jacqueline Monique Comte, Lothar Wondraczek
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Patent number: 7700870Abstract: A high transmission and low iron glass is provided for use in a solar cell. The glass substrate may be patterned on at least one surface thereof. Antimony (Sb) is used in the glass to improve stability of the solar performance of the glass upon exposure to ultraviolet (UV) radiation and/or sunlight. The combination of low iron content, antimony, and/or the patterning of the glass substrate results in a substrate with high visible transmission and excellent light refracting characteristics.Type: GrantFiled: May 5, 2005Date of Patent: April 20, 2010Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Ksenia A. Landa, Richard Hulme, Anthony V. Longobardo, Leonid Landa, Anna Broughton
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Patent number: 7700507Abstract: An optical glass which has an Abbe's number (?d) of 50 to 59, has the property of not easily reacting with a press mold, a low-temperature softening property, excellent glass stability and high refractivity, and is suitable for precision press-molding. The optical glass comprising B2O3 and SiO2 as essential components and having a B2O3 and SiO2 total content (B2O3+SiO2) of 45 to 70 by mol % and an SiO2 content/B2O3 content molar ratio (SiO2/B2O3) of from 0.1 to 0.5, the optical glass further comprising, by mol %, 5 to 15% of La2O3, 0.1 to 8% of Gd2O3, provided that the total content of La2O3 and Gd2O3 is 8% or more, 0 to 10% of Y2O3, 3 to 18% of Li2O, provided that the molar ratio of the content of Li2O to the total content of B2O3 and SiO2 [Li2O/(B2O3+SiO2)] is over 0 but not more than 0.2, 0.Type: GrantFiled: September 14, 2005Date of Patent: April 20, 2010Assignee: Hoya CorporationInventors: Yoshiko Kasuga, Xuelu Zou
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Patent number: 7691763Abstract: A glass composition for forming a blue colored glass is disclosed. The glass composition is made up of a base glass portion, iron oxide, and at least one first additive compound selected from Nd2O3 in an amount up to 1 weight percent and/or CuO in an amount up to 0.5 weight percent. The base glass portion has the following components: SiO2 from 66 to 75 weight percent; Na2O from 10 to 20 weight percent; CaO from 5 to 15 weight percent; MgO from 0 to 5 weight percent; Al2O3 from 0 to 5 weight percent; B2O3 from 0 to 5 weight percent; and K2O from 0 to 5 weight percent. The total iron in the glass composition ranges from 0.3 to 1.2 weight percent, and the glass composition has a redox ratio ranging from 0.15 to 0.65.Type: GrantFiled: March 2, 2007Date of Patent: April 6, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Mehran Arbab, Robert B. Heithoff, Larry J. Shelestak, Dennis G. Smith
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Patent number: 7687418Abstract: The X-ray opaque glass is characterized by a composition, in mol %, of SiO2, 75-98; Yb2O3, 0.1 to 40; and ZrO2, 0 to 40. Preferred embodiments of the glass are free of Al2O3 and B2O3. The glass is produced from the glass batch by melting at a temperature of at least 1500° C. in an iridium or iridium alloy vessel with the assistance of high-frequency radiation. In preferred embodiments of the glass production process at least one raw material ingredient is present in the batch as a nanoscale powder. The glass is useful in dental applications, optical applications, and biomedical applications, or for photovoltaics, or as a target material in PVD processes.Type: GrantFiled: December 28, 2004Date of Patent: March 30, 2010Assignee: Schott AGInventors: Ulrich Peuchert, Uwe Kolberg, Joern Besinger
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Patent number: 7687419Abstract: A glass substrate used as a substrate of an information recording medium such as a magnetic disk, magneto-optical disk, DVD, or MD, and a glass composition used to make such a glass substrate, contains the following glass ingredients: 40 to 70% by weight of SiO2; 1 to 20% by weight of Al2O3; 0 to 10% by weight, zero inclusive, of B2O3; SiO2+Al2O3+B2O3 accounting for 60 to 90% by weight; a total of 3.0 to 15% by weight of R2O compounds, where R=Li, Na, and K; a total of 2.0 to 15% by weight of R?O compounds, where R=Mg, and Zn; and a total of 1.0 to 20% by weight of MOx (TiO2+ZrO2+LnxOy), where LnxOy represents at least one compound selected from the group consisting of lanthanoid metal oxides, Y2O3, Nb2O5, and Ta2O5. Here, the following condition is fulfilled: 0.070<(total content of R?O compounds)/(SiO2+Al2O3+B2O3)<0.200.Type: GrantFiled: October 4, 2004Date of Patent: March 30, 2010Assignee: Konica Minolta Opto, Inc.Inventor: Hideki Kawai
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Publication number: 20100072406Abstract: A glass composition for ultraviolet light is provided. The glass composition for ultraviolet light contains Lu, Si, and O in an amount of 99.99 weight % or more in total. The glass composition contains Lu in an amount of 26% or more and 39% or less in cation percent and Si in an amount of 61% or more and 74% or less in cation percent.Type: ApplicationFiled: November 5, 2008Publication date: March 25, 2010Applicant: CANON KABUSHIKI KAISHAInventors: Tomohiro Watanabe, Taihei Mukaide
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Patent number: 7682999Abstract: Glass composition intended for the manufacture of windows that absorb ultraviolet and infrared radiation, comprising the oxides below, in contents varying within the following limits by weight: SiO2 65-80% Al2O3 0-5% B2O3 0-5% CaO ?5-15% MgO 0-2% Na2O ?9-18% K2O ?0-10% BaO 0-5% characterized in that it additionally comprises the absorbent agents below, in contents varying within the following limits by weight: Fe2O3 (total iron) 0.7 to 1.6% CeO2 0.1 to 1.2% TiO2 ??0 to 1.5% the glass having a redox factor of 0.23 or less and containing no tungsten oxide WO3.Type: GrantFiled: February 6, 2006Date of Patent: March 23, 2010Assignee: Saint-Gobain Glass FranceInventor: Laurent Teyssedre
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Patent number: 7683000Abstract: A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably <=0.10; even more preferably <=0.08; and most preferably <=0.05) and a % FeO (i.e., ferrous content) of from 0.0001 to 0.05%. In certain example embodiments, in order to compensate for yellow or yellow-green coloration a small amount of cobalt (Co) may be provided in the glass to enable it to realize a more neutral color.Type: GrantFiled: December 17, 2008Date of Patent: March 23, 2010Assignee: Guardian Industries Corp.Inventors: Ksenia A. Landa, Leonid Landa, Richard Hulme, Scott V. Thomsen
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Publication number: 20100045164Abstract: The invention concerns a glass composition for a glass body of an illuminating means with external electrodes, wherein the quotient of the loss angle (tan ?[10?4]) and the dielectric constant (??) amounts to tan ?[10?4]/??<5, i.e., tan ?/??<5×10?4). In this way, the total power loss of the illuminating means with external electrodes can be minimized in a targeted manner by means of the glass properties.Type: ApplicationFiled: December 29, 2005Publication date: February 25, 2010Inventors: Joerg Fechner, Martin Letz, Steffen Reichel, Franz Ott, Brigitte Hueber
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Patent number: 7666806Abstract: A glass composition that includes a base glass composition including: SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent and BaO 0 to 1 weight percent, and a colorant and property modifying portion including total iron from 0.25 to 0.9 weight percent, Cr2O3 from 6 PPM to 400 PPM, Er2O3 from 0.3 to 3.0 weight percent, and TiO2 from 0.1 to 0.8 weight percent, wherein the glass composition has a redox ratio ranging from 0.15 to 0.62.Type: GrantFiled: November 2, 2005Date of Patent: February 23, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, Dennis G. Smith, James M. Baldauff
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Publication number: 20100041539Abstract: An optical glass is provided that includes a refractive index (nd) of no less than 1.75 and an Abbe number (vd) of no less than 10 as optical constants. A Bi2O3 content is no less than 10% by weight to no more than 80% by weight. The content of SiO2 is lower than the content of B2O3. The total content of SiO2+B2O3 is from no less than 1% by weight to no more than 60% by weight. The content of RO is from no less than 0.1% by weight to no more than 50% by weight. R represents one or more elements selected from the group consisting of Zn, Ba, Sr, Ca, and Mg. The optical glass has at least one of the properties of being substantially free from opacification and/or being substantially devitrified within the glass body under the conditions of a reheating testing.Type: ApplicationFiled: October 22, 2009Publication date: February 18, 2010Applicant: OHARA, INC.Inventors: Atsushi Nagaoka, Jie Fu, Michiko Ogino
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Patent number: 7659222Abstract: An optical glass comprising SiO2, B2O3 and La2O3 and one or more oxides selected from the group consisting of ZrO2, Nb2O5 and Ta2O5, having a refractive index of 1.83 or over and an Abbe number of 35 or over and being free of F.Type: GrantFiled: May 20, 2005Date of Patent: February 9, 2010Assignee: Kabushiki Kaisha OharaInventor: Koji Shimizu
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Publication number: 20100029460Abstract: The present invention provides a glass for anodic bonding having a low thermal expansion coefficient and capable of being subjected to laser beam micromachining. The present invention is a glass for anodic bonding having a base glass composition containing 1 to 6 mol % of Li2O+Na2O+K2O and having an average linear expansion coefficient of 32×10?7 K?1 to 39×10?7 K?1 in a temperature range of room temperature to 450° C. This glass further contains 0.01 to 5 mol % of a metal oxide as a colorant relative to the base glass composition, and has an absorption coefficient of 0.5 to 50 cm?1 at a particular wavelength within 535 nm or less.Type: ApplicationFiled: February 21, 2008Publication date: February 4, 2010Applicant: NIPPON SHEET GLASS COMPANY, LIMITEDInventors: Masanori Shojiya, Hirotaka Koyo, Koichi Sakaguchi, Satoshi Jibiki
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Patent number: 7648930Abstract: The glass for a fluorescent light with a high hydrolytic resistance, which has composition, in % by weight based on oxide content of: SiO2, 63-75; B2O3, 15-18; Al2O3, 3.2-4.5; Na2O, 1-2; K2O, 2-6; ?Na2O+K2O, 3-8; MgO, 0-8; CaO, 0-10; SrO, 0-10; BaO, 0-10; ZnO, 0-5; ?MgO+CaO+SrO+BaO+ZnO, 0-10; ZrO2, 0-3; CeO2, 0-10; Fe2O3, 0-1; WO3, 0-3; Bi2O3, 0-5; MoO3, 0-3; TiO2, 0-10; ?Hf+Ta+W+Re+Os+Ir+Pt+La+Pr+Nd+Sm+Eu+Gd+Tb+Dy+Ho+Er+Tm+Yb+Lu in oxidic form, 0 to 5% by weight, as well as one or more conventional refining agents. The glass is characterized in that it contains no lithium and has a weight ratio of Na2O to K2O of less than one.Type: GrantFiled: May 19, 2006Date of Patent: January 19, 2010Assignee: Schott AGInventors: Joerg Fechner, Franz Ott
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Publication number: 20100009154Abstract: A strengthened glass that does not exhibit frangible behavior when subjected to impact or contact forces, and a method of strengthening a glass. The glass may be strengthened by subjecting it to multiple, successive, ion exchange treatments. The multiple ion exchange treatments provide a local compressive stress maximum at a depth of the strengthened layer and a second local maximum at or near (e.g., within 10 ?m) the surface of the glass.Type: ApplicationFiled: July 10, 2009Publication date: January 14, 2010Inventors: Douglas Clippinger Allan, Adam James Ellison, Sinue Gomez
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Patent number: 7632767Abstract: A glass composition that has improved infrared absorptivity while preventing the visible light transmittance from decreasing excessively. The glass composition includes: the following components, expressed in mass %: 65<SiO2?75; 0?B2O3?5; 0?Al2O3?5; 0?MgO<2; 10<CaO?15; 0?SrO?10; 0?BaO?10; 0?Li2O?5; 10?Na2O?15; 0?K2O?5; and 0?TiO2?0.5, where 10<MgO+CaO+SrO+BaO?20 and 10?Na2O+K2O?17.5; MnO 0 to 300 mass ppm; and the following components as colorants, expressed in mass %: 0.4?T—Fe2O3?1.0, where T—Fe2O3 is total iron oxide expressed as Fe2O3; and 0?CeO2?2.0. The mass ratio of FeO expressed as Fe2O3 to T—Fe2O3 is 20 to 44%. The wavelength at which a minimum transmittance is obtained in a range of 550 to 1700 nm is at least 1065 nm. The transmittance that is obtained at a wavelength of 1650 nm is not higher than the transmittance that is obtained at a wavelength of 730 nm.Type: GrantFiled: March 15, 2006Date of Patent: December 15, 2009Assignee: Nippon Sheet Glass Company, LimitedInventors: Yukihito Nagashima, Harunori Murakami
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Patent number: 7625830Abstract: The present invention provides a blue glass that can be essentially free of selenium and cobalt but still has a blue color and desired luminous transmittance. Additionally, the amount of iron present is comparable to conventional soda-lime-silica glass. The glass of the present invention can have a soda-lime-silica glass base portion, with major colorants that provide the blue color.Type: GrantFiled: February 10, 2005Date of Patent: December 1, 2009Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, James M. Baldauff
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Patent number: 7622410Abstract: A grey glass composition employing in its colorant portion, in certain example embodiments, iron, cobalt, nickel, and at least one of erbium and titanium. The use of erbium and/or titanium has been found to improve coloration of the grey glass, and improve tunability of the same. In certain example embodiments, the ratio of cobalt oxide to nickel oxide is from 0.22 to 0.30 in order to achieve desired coloration in certain example embodiments.Type: GrantFiled: February 23, 2005Date of Patent: November 24, 2009Assignee: Guardian Industries Corp.Inventors: Anthony V. Longobardo, Leonid Landa, Ksenia A. Landa, Scott V. Thomsen
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Publication number: 20090286058Abstract: [Object] This invention relates to crystal glass article not containing lead or barium that can be chemical strengthened easily and that is highly alkali-resistant and equivalent to lead crystal glass in quality. [Solving Means] Crystal glass article that can be chemical strengthened easily and that is highly alkali-resistant and equivalent to lead crystal glass in quality can be produced with a glass composition containing: 62% to 65% by weight of SiO2; 2% to 3.2% by weight of Al2O3; 10% to 12% by weight of Na2O; 8% by weight to less than 10.0% by weight of K2O; 3% to 4.2% by weight of CaO; 2% to 3.2% by weight of SrO; 6% to 7.2% by weight of ZnO; 2.2% to 3% by weight of TiO2; 0% to 0.4% by weight of Sb2O3; and 0% to 1.2% by weight of SnO2+Y2O3+La2O3+ZrO2.Type: ApplicationFiled: August 31, 2006Publication date: November 19, 2009Inventors: Noriaki Shibata, Hirokazu Toyoda
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Publication number: 20090286091Abstract: A rare-earth-containing glass material having a composition, expressed in mole percentages on and oxide basis, comprising: SiO2: 66-75 Al2O3: 11-17 B2O3: 0-4 MgO: 1-6.5 CaO: 2-7 SrO: 0-4 BaO: 0-4 Y2O3: 0-4 La2O3: 0-4 Y2O3+La2O3: 0.1-4. The inclusion of Y2O3 and/or La2O3 in the composition reduces the T2.3 of the glass thereby allowing higher annealing-point glasses to be produced. The glass is particularly useful for low-temperature polycrystalline silicon-based semiconductor devices.Type: ApplicationFiled: May 12, 2009Publication date: November 19, 2009Inventors: Paul Stephen Danielson, Matthew John Dejneka, Adam James Ellison, Timothy J. Kiczenski
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Publication number: 20090286667Abstract: An optically detectable, floatable arsenic- and antimony-free, glazable lithium-aluminosilicate glass that can be prestressed and the glass ceramic converted therefrom are described. The glass or the glass ceramic has a composition (in % by weight based on oxide) of essentially SiO2 55-69, Al2O3 19-25, Li2O 3.2-5, Na2O 0-1.5, K2O 0-1.5, MgO 0-2.2, CaO 0-2.0, SrO 0-2.0, BaO 0-2.5, ZnO 0-<1.5, TiO2 1-3, ZrO2 1-2.5, 0.1-<1, ?TiO2+ZrO2+SnO2 2.5-5, P2O5 O-3, Nd2O3 0.01-0.6, CoO 0-0.005, F 0-1, B2O3 0-2.Type: ApplicationFiled: February 26, 2009Publication date: November 19, 2009Inventors: Friedrich SIEBERS, Hans-Werner Beudt, Bernd Rudinger, Gerbard Lautenschlager, Klaus Schneider, Michael Jacquorie, Wolfgang Schmidbauer
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Patent number: 7612004Abstract: A family of glasses from the rare earth alumino-silicate (RE2O3—Al2O3—SiO2) ternary system exhibiting high strain point and low liquidus temperatures; preferably the La2O3—Al2O3—SiO2 ternary system. The glasses are excellent candidates for electronics applications and have the following composition, expressed in mole percent and calculated from the glass batch on an oxide basis: 60-85% SiO2, 10-25% Al2O3, and 4-15% RE2O3.Type: GrantFiled: August 16, 2006Date of Patent: November 3, 2009Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Matthew J. Dejneka, Adam J. G. Ellison, Thomas E. Paulson
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Patent number: 7612003Abstract: The invention relates to a bulk-tinted red glass formed from a glass batch based on a soda-lime-silica composition, to a process for manufacturing red glass and to a bulb obtained from a blank or a tube manufactured with such a glass. The batch comprises, per 100% by weight of the batch, 0.1 to 1% by weight of copper, 0.2 to 2% by weight of tin and 0.01 to 2.5% by weight of oxide of the lanthanide group and/or 0.01 to 0.5% by weight of silver in silver oxide or nitrate form.Type: GrantFiled: July 20, 2006Date of Patent: November 3, 2009Assignee: VermontInventors: Christian Lefevre, Francois Lepesqueux
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Publication number: 20090258778Abstract: The present invention relates to preparing an improved lithium silicate glass ceramic for the manufacture of blocks for dental appliance fabrication using a CAD/CAM process. The lithium silicate material has a chemical composition that is different from those reported in the prior art including 8 to 10% of germanium dioxide in the final composition. The softening points are close to the crystallization final temperature of 800° C. indicating that the samples will support the temperature process without shape deformation. The resulting material has improved castability and higher density.Type: ApplicationFiled: April 11, 2008Publication date: October 15, 2009Inventor: Rodolfo Castillo
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Patent number: 7598190Abstract: The present invention relates to an ultraviolet and infrared absorptive greenish glass (the first glass) containing in weight % expression at least coloring components of 0.3-0.5% of total Fe2O3, 0.8-2.0% CeO2, 0.8-2.0% TiO2, and 0.10-0.25% of FeO. This first glass may be an ultraviolet and infrared absorptive greenish glass (the second glass) in which CeO2 amounts to 0.8-1.5% and TiO2 amounts to 0.8-1.5%, and which contains at least 0.1-0.7% SnO as a coloring component. Each glass is characterized in each glass at 5 mm thickness is 9% or less in ultraviolet transmittance (Tuv) according to ISO/DIS9050, 1% or less in 350 nm wavelength transmittance (T350), 70% or greater in 550 nm wavelength transmittance (T550), and 25% or less in 1100 nm wavelength transmittance (T1100).Type: GrantFiled: October 29, 2004Date of Patent: October 6, 2009Assignee: Central Glass Company, LimitedInventors: Yasushi Taguchi, Koji Misaka
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Patent number: 7598191Abstract: Glass for gas discharge tubes, which are used in fluorescent lamps, EEFL lamps, LCD displays, computer monitors, telephone displays and TFT displays, and a process for making it are described. The glass contains, in % by weight based on oxide content: SiO2, 60-75; B2O3, >25-35; Al2O3, 0-10; Li2O, 0-10; Na2O, 0-20; K2O, 0-20; MgO, 0-8; CaO, 0-20; SrO, 0-5; BaO, 0-5; ZnO, 0-3; ZrO2, 0-5; TiO2, 0-10; Fe2O3, 0-0.5; CeO2 0-0.5; MnO2, 0-1.0; Nd2O3, 0-1.0; WO3, 0-2; Bi2O3, 0-5; MoO3, 0-5; As2O3, 0-1; Sb2O3, 0-1; SO42?, 0-2; Cl-, 0-2 and F?, 0-2, wherein ?Li2O+Na2O+K2O=0-25% by weight; ?MgO+CaO+SrO+BaO=0-20; ?Fe2O3+CeO2+TiO2+PbO+As2O3+Sb2O3 is at least 0-10; and ?PdO+PtO3+PtO2+PtO+RhO2+Rh2O3+IrO2+Ir2O3 is from 0.00001-0.1.Type: GrantFiled: July 11, 2005Date of Patent: October 6, 2009Assignee: Schott AGInventors: Joerg Fechner, Franz Ott, Brigitte Hueber
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Patent number: 7596968Abstract: Glass, glass compositions, methods of preparing the glass compositions, microfluidic devices that include the glass composition, and methods of fabricating microfluidic devices that include the glass composition are disclosed. The borosilicate glass composition includes silicon dioxide (SiO2) in a range from about 60% to 74% by total composition weight; boric oxide (B2O3) in a range from about 9% to 25% by total composition weight; aluminum oxide (Al2O3) in a range from about 7% to 17% by total composition weight; and at least one alkali oxide in a range from about 2% to 7% by total composition weight. In addition, the borosilicate glass has a coefficient of thermal expansion (CTE) that is in a range between about 30×10?7/° C. and 55×10?7/° C. Furthermore, the borosilicate glass composition resists devitrification upon sintering without the addition of an inhibitor oxide.Type: GrantFiled: January 18, 2008Date of Patent: October 6, 2009Assignee: Corning IncorporatedInventor: Paulo Marques
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Publication number: 20090239102Abstract: To provide glass for a data storage medium substrate, whereby high heat resistance can be obtained. Glass for a data storage medium substrate, which comprises, as represented by mol percentage based on the following oxides, from 55 to 70% of SiO2, from 2.5 to 9% of Al2O3, from 0 to 10% of MgO, from 0 to 7% of CaO, from 0.5 to 10% of SrO, from 0 to 12.5% of BaO, from 0 to 2.5% of TiO2, from 0.5 to 3.7% of ZrO2, from 0 to 2.5% of Li2O, from 0 to 8% of Na2O, from 2 to 8% of K2O and from 0.5 to 5% of La2O3, provided that the total content of Al2O3 and ZrO2 (Al2O3+ZrO2) is at most 12%, and the total content of Li2O, Na2O and K2O (R2O) is at most 12%.Type: ApplicationFiled: June 3, 2009Publication date: September 24, 2009Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Tatsuo NAGASHIMA, Kensuke Nagai, Tetsuya Nakashima, Kei Maeda
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Publication number: 20090239008Abstract: The low-sodium-oxide glass and glass tube, which have the following chemical components 55.0-70.0% SiO2, 2.0-4.0% Al2O3, 3.0-7.0% MgO, and CaO, 2.0-5.0% SrO, 9.0-12.0% BaO, 2.0-4.0% Li2O, 0-0.15% Na2O, 12.0-14.0% K2O, 0.1-0.6% CeO2, (0.03%) Fe2O3, and (0.15%) SO3, replace the borosilicate glass, with improvements to the physical properties and chemical durability, transmittance percentage controlled in the wave length interval at 313 nanometers (nm.), for maximum effectiveness for the light bulb manufacturing industry and also for other industries.Type: ApplicationFiled: March 20, 2009Publication date: September 24, 2009Applicant: L. LIGHTING GLASS COMPANY LIMITEDInventor: Somchai Ovutthitham
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Publication number: 20090239122Abstract: A glass ceramic material sealed fuel cell device, including a first fuel cell portion and a sealant layer bonded to the first cell portion. The sealant layer includes at least three metal oxides RO-M2O3—SiO2 combined together. R is selected from the group consisting of zinc, strontium, calcium, magnesium and combinations thereof. M is selected from the group consisting of aluminum, boron, lanthanum, iron and combinations thereof. RO is present in an amount of between about 45 mol % and about 55 mol %. M2O3 is present in an amount of between about 5 mol % and about 10 mol %. SiO2 is present in an amount of about 40 mol %. RO includes RnO present in an amount of at least about 5 mol %.Type: ApplicationFiled: June 4, 2008Publication date: September 24, 2009Inventors: Richard K. Brow, Signo Tadeu Dos Reis, Glendon M. Benson
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Publication number: 20090227439Abstract: The present invention has an object to provide an optical glass which has middle refractive index and low dispersibility, a low yield point (Ts) and a liquidus temperature (L.T.) and excellent weather resistance, and is suitable for mold press molding. The present invention relates to an optical glass comprising, in mass % on oxide basis, SiO2: 20 to 40%, B2O3: 10 to 30%, SrO: 10 to 30%, Al2O3: 5.5 to 15%, La2O3: 0.5 to 11%, Li2O: 3 to 12%, CaO: 0 to 10%, BaO: 0 to 9.5%, and ZnO: 0 to 10%.Type: ApplicationFiled: March 13, 2009Publication date: September 10, 2009Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Kenji Imakita, Naoki Sugimoto
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Patent number: 7585801Abstract: A glass composition that includes a base glass composition including: SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent and BaO from 0 to 1 weight percent, and a colorant and property modifying portion including total iron from 0.5 to 0.8 weight percent, Er2O3 from 0.05 to 0.5 weight percent, Se from 1 PPM to 4 PPM, and CoO from 1 PPM to 15 PPM, wherein the glass composition has a redox ratio ranging from 0.25 to 0.35.Type: GrantFiled: November 2, 2005Date of Patent: September 8, 2009Assignee: PPG Industries Ohio, Inc.Inventor: Larry J. Shelestak
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Publication number: 20090221413Abstract: Pressable glass-ceramic compositions for dental purposes of the composition I, II or III I II III (percent by weight) (percent by weight) (percent by weight) ZrO2 17-70%? ZrO2/ 15-70%? Al2O3 15-70% Al2O3 SiO2 17-59%? SiO2 17-59%? SiO2 17-59% Al2O3 ?2-15% ZrO2 32-15%? ZrO2 2-15% Y2O3 ??0-6% Y2O3 ??0-6% Y2O3 0-6% K2O 3-12.5%? K2O 3-12.5%? K2O 3-12.5% Na2O 0.2-8.5%?? Na2O 0.2-8.5%?? Na2O 0.2-8.5% Li2O 0-1.5% Li2O 0-1.5% Li2O 0-1.5% CaO 0.3-2% CaO 0.3-2% CaO 0.3-2% B2O3 0.1-5% B2O3 0.1-5% B2O3 0.1-5% F 0-2.5% F 0-2.5% F 0-2.5% CeO2 0.2-2% CeO2 0.2-2% CeO2 0.2-2% TiO2 0-1.5% TiO2 0-1.5% TiO2 0-1.5% are particularly suitable for the manufacturing of ceramic veneer frames.Type: ApplicationFiled: March 6, 2009Publication date: September 3, 2009Applicant: HERAEUS HOLDING GMBHInventor: Jurgen STEIDL
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Publication number: 20090217978Abstract: Certain example embodiments of this invention relate to a high transmission low iron glass, which is highly oxidized and made using the float process, for use in photovoltaic devices such as solar cells or the like. In certain example embodiments, the glass composition used for the glass is made via the float process using an extremely high and positive batch redox in order to reduce % FeO to a low level and permit the glass to consistently realize a combination of high visible transmission (Lta or Tvis), high infrared (IR) transmission, and high total solar (TS) transmission. The glass substrate may be patterned or not patterned in different example embodiments of this invention.Type: ApplicationFiled: May 5, 2009Publication date: September 3, 2009Applicant: Guardian Industries Corp.Inventors: Scott V. Thomsen, Richard Hulme, Leonid M. Landa, Ksenia A. Landa
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Publication number: 20090220761Abstract: A glass that is ion exchangeable to a depth of at least 20 ?m (microns) and has a internal region having a tension of less than or equal to 100 MPa. The glass is quenched or fast cooled from a first temperature above the anneal point of the glass to a second temperature that is below the strain point of the glass. In one embodiment, the glass is a silicate glass, such as an alkali silicate glass, an alkali aluminosilicate glass, an aluminosilicate glass, a borosilicate glass, an alkali aluminogermanate glass, an alkali germanate glass, an alkali gallogermanate glass, and combinations thereof.Type: ApplicationFiled: February 26, 2009Publication date: September 3, 2009Inventors: Matthew John Dejneka, Adam James Ellison, Sinue Gomez
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Patent number: 7582580Abstract: The present invention provides an optical glass including, by mass %: 46 to 70 of B2O3; 3 to 10 of Li2O; 5 to 15 of Y2O3; 0 to 46 of SiO2: 0 to 20 of Al2O3: 0 to 40 of MgO+CaO+SrO+BaO; 0 to 30 of La2O3; and 0 to 10 of ZrO2+TiO2+Gd2O3.Type: GrantFiled: August 21, 2008Date of Patent: September 1, 2009Assignee: Asahi Glass Company, LimitedInventors: Hiroyuki Ohkawa, Jun Sasai, Naoki Sugimoto
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Patent number: 7576021Abstract: A mother glass composition for graded index lenses, comprising the following glass components in mol %: 40?SiO2?65, 1?TiO2?10, 0?MgO?22, 2?Li2O?18, 2?Na2O ?20, 6?Li2O+Na2O?38, and from 0.1 to 15 mol % of any two or more of CaO, SrO and BaO, a graded index lens using the mother glass composition, a manufacturing method of the graded index lens, and an optical product and an optical instrument using the graded index lens, are provided.Type: GrantFiled: April 5, 2005Date of Patent: August 18, 2009Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Taro Miyauchi, Kazuya Ohkawa, Tatsufumi Shiba, Tomizou Matsuyama
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GLASS COMPOSITION FOR LAMP, LAMP, BACKLIGHT UNIT AND METHOD FOR PRODUCING GLASS COMPOSITION FOR LAMP
Publication number: 20090201664Abstract: A glass composition which contains Ce ions as a component substantially comprises, in terms of oxides, SiO2: 55 to 75 wt %, B2O3: 6 to 25 wt %, CeO2: 0.01 to 5 wt %, SnO: 0.01 to 5 wt %, Al2O3: 0 to 10 wt %, Li2O: 0 to 10 wt %, Na2O: 0 to 10 wt %, K2O: 0 to 10 wt %, MgO: 0 to 5 wt %, CaO: 0 to 10 wt %, SrO: 0 to 10 wt %, BaO 0 to 10 wt %, TiO2: 0 to 1.0 wt %, Fe2O3: 0.01 to 0.2 wt %, Sb2O3: 0 to 5 wt %, ZrO2: 0.01 to 5 wt %. By having such constituents, the glass composition is capable of suppressing transmission of ultraviolet light and solarization, and thus the glass composition hardly suffers from initial coloring or coloring during lamp production.Type: ApplicationFiled: March 28, 2006Publication date: August 13, 2009Inventors: Atsushi Motoya, Yasurou Niguma -
Publication number: 20090181843Abstract: The present invention provides a glass article using a glass composition including a base glass composition and colorants. The base glass composition includes, expressed in mass %: 65 to 80% of SiO2; 0 to 5% of Al2O3; 0 to 10% of MgO; 0 to 15% of CaO; 5 to 15% of MgO+CaO; 10 to 18% of Na2O; 0 to 5% of K2O; 10 to 20% of Na2O+K2O; and 0 to 5% of B2O3, and the colorants consist essentially of, expressed in mass %: 0.6% to 1.0% of T-Fe2O3; 0.026 to 0.8% of TiO2; 0 to 2.0% of CeO2; 0.01 to 0.03% of CoO; 0 to 0.0008% of Se; and 0.06 to 0.20% of NiO. The glass article has a grayish color tone, and has a visible light transmittance in a range of 15% to 40%, which is measured with the illuminant A at a thickness of 3.1 mm.Type: ApplicationFiled: October 31, 2006Publication date: July 16, 2009Applicant: Nippon Sheet Glass Company, LimitedInventors: Hiromitsu Seto, Akihiro Koyama, Yukihito Nagashima
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Patent number: 7560404Abstract: A novel glass composition is disclosed. The glass composition includes a base glass composition made up of SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent, B2O3 0 to 5%, and MnO2 0 to 0.5%, and a colorant and property modifying material portion made up of total iron up to 0.65 weight percent, Se ranging from 2 PPM to 10 PPM, at least one UV absorber selected from CeO2, V2O5, TiO2 and MoO3, CoO up to 20 PPM, and Cr2O3 up to 75 PPM, wherein the glass composition has a redox ratio ranging from 0.2 to 0.6.Type: GrantFiled: September 8, 2005Date of Patent: July 14, 2009Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, Mehran Arbab, Dennis G. Smith
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Patent number: 7560402Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the clear glass includes a low amount of iron coupled with zinc oxide and/or erbium oxide in amounts designed to provide a neutral color. While the erbium oxide is used to provide for neutral color, the zinc oxide binds sulfur into whitish-colored zinc sulfide thereby reducing the amount of sulfur that binds/bonds with iron in the glass to form sulfides of iron which is/are brownish in color. Thus, the use of the zinc oxide helps make the glass more neutral in color. In certain example embodiments, the use of the erbium oxide brings the a* color value of the resulting glass closer to zero, whereas the use of the zinc oxide brings the b* value of the resulting glass closer to zero.Type: GrantFiled: October 6, 2006Date of Patent: July 14, 2009Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Leonid M. Landa, legal representative, Richard Hulme, Ksenia A. Landa
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Patent number: 7560403Abstract: Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass includes a low amount of iron coupled with erbium (Er, including an oxide thereof) designed to provide a neutral color and high transmittance. In certain example embodiments, the amount of SO3 in the glass composition is increased in order to provide increased visible transmission, without sacrificing neutral color. The glass may optionally include a small amount of cobalt (Co, including an oxide thereof) in certain example instances.Type: GrantFiled: October 17, 2006Date of Patent: July 14, 2009Assignee: Guardian Industries Corp.Inventors: Ksenia A Landa, Leonid M. Landa, Scott V. Thomsen, Richard Hulme
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Patent number: 7557053Abstract: Certain example embodiments of this invention relate to a high transmission low iron glass, which is highly oxidized and made using the float process, for use in photovoltaic devices such as solar cells or the like. In certain example embodiments, the glass composition used for the glass is made via the float process using an extremely high and positive batch redox in order to reduce % FeO to a low level and permit the glass to consistently realize a combination of high visible transmission (Lta or Tvis), high infrared (IR) transmission, and high total solar (TS) transmission. The glass substrate may be patterned or not patterned in different example embodiments of this invention.Type: GrantFiled: October 17, 2006Date of Patent: July 7, 2009Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Richard Hulme, Leonid M. Landa, Ksenia A. Landa
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Publication number: 20090129061Abstract: The invention relates to aluminoborosilicate glasses as a glass casing body of a lighting means, especially for background illumination, which glass composition is equally suitable for use in lighting means with external contacting as well as for lighting means with internal contacting.Type: ApplicationFiled: November 20, 2008Publication date: May 21, 2009Inventors: Jorg Fechner, Franz Ott, Christof Kass
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Patent number: 7535179Abstract: The lamp bulb for discharge lamps is made from an aluminosilicate glass with a transformation temperature Tg>600° C. The aluminosilicate glass has a composition (in % by weight, based on oxide content) of SiO2>55-64; Al2O3, 13-18; B2O3, 0-5.5; MgO, 0-7; CaO, 5-14; SrO, 0-8; BaO, 6-17; ZrO2, 0-2; TiO2, 0-5, but may contain small amounts of CeO2 and/or Fe2O3, for anti-solarization and fining agents, such as SnO2, Sb2O3 and/or As2O3. The lamp bulbs for the discharge lamps of the invention may include a melted-in molybdenum electrode and/or an electrode feed or they may be free of any internal electrodes. A method for making the lamp bulbs is also described.Type: GrantFiled: March 20, 2003Date of Patent: May 19, 2009Assignee: Schott AGInventors: Brigitte Hueber, Juergen Achatz, Franz Ott, Joerg Fechner